Professional Documents
Culture Documents
Textbook of Solid Wastes Management
Textbook of Solid Wastes Management
SonfldWa-stes
I\Iiemegl@m@mG
I
r IOBAL H. KHAN
Sen.or P oiesso...Ci,vr.
Ph.DlBadrod
8 Enl.ronmenrdr
Eng
Jamra Nliitia slamia New DerhL -
,]ee.,ng.
I NAVED AHSAN
LeciLirer, Deparheni ot Crvrt Enoineenno
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Jam,a Mitlia tstamta. New d. h
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? gBLtSHERS & DtsTRtBUTORS
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4596t1-A,11 Darya canj, New Dethi _r ro
Websjie I httpr/www.cbspd.com
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Preface
Ihis book has evolved out of our teaching, research aod cgggUltancv work
iD the field ofsolid wastes Eraoagerlent. It is iDteDded as a t€xt book for
undi@and
students of envitonoental engineering both at Dostgt-aduate
ievel. Auenpl has been Dade ro include aI relevan:6;ffiincludirr;;fr;As
and guidelines issued by the central and state gov€mmeDts il1 this regatd.
Ihis book should therefore be of intetest trot only to students and teachers
but also to etrgiaeers working itr the field ofsolid wastes managemeDt.
NuDe(ous solved a]ld unsolved Dumerical problems have been included for
effective !99!g!94i0! ofthe issues by studeats and engineers.
The varioustopics include the geDeratiotr, coDlposition, collection and
treatheDt options ofsolid wastes, disposal ofwaste on laddlill including
enginee ng aspech oflandfiIl disposal systems.
I{azardous *"stes including hdustrial wastes ed biooedical wastes, have
a high hazard poteDtial. A s€parate chapterhas tL€retore bee! alevojed to
this categgll of wastes
Aj!!!!4g!ishing fealure ofrhis book is tbe empbasis oo tbe use ofIT
tools in rhe ir@Eient ald operations of a solid GGG-anagement system.
The book should thetefoie be ofiBterestto urbaD plaDners.
We hav€ also included several Case Studies l.om our consultaDcv.
Mary friends andcolleagues havehelped h !be endevour. to all of'whom
we wish to express out siDcere thaols. Thants are alio dGio CBS publishers
for bringing out lhis rext book.
Thl6'ksiilialso due
ro rhe AII lldia Council forTechnical Educatio! for
tbeir suppon i!
bringing out ttris book.
ADy comments or suggestiotrs fot i&proveoent wilt be gratefully
acknowledged.
Iqbal E. Khrn
Nrved Ahsatr
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r Contents
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List of tigures I
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Fig. 1,1 I
Fig- 1-2
Fig. 1,3
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Fig. 1.4
Fig.2.1
Fig.2.2
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Fr" l.r
Fig.2.4 I
Fig. 2.5
Fig. 2.5
fig. 2.5
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Fig. 2.6
FiE 2.7 I
Fig. 2.8
Fig. 2.9
Fig.2.10
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Fig.2.11
Fig.2.l2 I
Fig.2.13
Fig.2.l4
Fig.2.15 I
Fig.3.l
Fig.3.l
Fig.3.1
Fig- 3-2
4.
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6. Ilaz3rdous Wastes Management atrd Site ReEediation .......................'.............".'.... 123
t22
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Characteristics ofHazado[s Wastes ..................... ............... 123
Managementofl{azardousWastes.-.,..,.,.,..................-.,.--.,.,.,,-,..,..-.-,--.....-..........124 T
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Chemical Oddalion....................... 128
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Risk Assessment in Siting ofa Hazardous Waste Disposal Facility--Case Study
Fig.3.3 Twical LayoutPlan ola Landfll ......... -- - -.........10
Fig.3.,1 various TlPes ofcell Layou6 . ... . .. . .. . . .........'.71
Fig.3.5 TFical Cross-section oflandfill Cove ....... ........ 74
Fig.3.6 Sxrface Water Drainage Charmel .... ...-- ............ 75
Fig.3,7 TypicalMoaitoringlnstrumentationatLandfiilSite.................-..---.-.......76
Fig. 3.8 Sarnpler
Cirab . . .. .. . " " 77
Fig.3.9 GromdwalerMoritoringwelt ......:rr::,.=.-?s
Fig,3.10 Aii Quality Monitoring in Vado
Probe for 7e - "" -" ..'-.-' -': :-:: " 79
7-'1L
Iig. 4,9 LeachateReckculation System ..... .... "_ "'- " 101
Fig.,l.lo Sketch ofa Twicai Aemted Lagoon """ " "i02
Fig.4.1l ActivaledsludEeProcess...-....... ......... " " "" ' 103
Fig. 4.12 RoraijngBiological Cortactor... .... . . "_ "" 103
Fig.4.13 TricklingFihe ""." "" ' 103
Fig.,t.l4 Two Stage Anaerobic Tleatment Process "'- " "" 104
Fig.4.15 USB Reactor. "- -" '105
Fig.,t.16 Twicat Sequence ofPhysicavchemical Tleatmmt "" "" "" "" " 105
Fig.5,1 Phases in Lardfillcas Generation ...... """ "" "111
Fig.5.2 Palh\%ys oflandfill Gas Migmtion..... " "" 1l4
Fig.5.3 Components ofcas Collection Syslem . ...... " 116
Fig.5.4 Gas Eilraction well ... ............. .....-... -.."-'.- " 117
Fig.5.5 Combination ofcas Erf'action Well aid Leachate CoUection Well . ........ .... ' 118
Fig.5.6 flare Bumer. -.....""" " i19
Fig.5.7 TwicalAnangementofcaswells...... ... " "' l2O
Fig.5.8 Schematic oflnfta-red CO? Detector .. .. -"-"" "\21
fig.6.1 Rootzone T€atment System . ...... " ,' " "" 146
Fig.6.2 various Routes ofExPosue .. ....- ",' " " "" 149
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Fig,6.3 StagesinlcA
Fig.6.4 Fiow Diagam for Production ofBar Soap
.-..................153
................ 153
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Fig.7.1 T$ical Distributio! ofPru .................
Fig.7.2 LeopoleMatri.(
...................... i66
.................. 168 I
Fig.7.3 Typical Value Function craphs SOr; NO,: Odoi
(a) (r)
Fig.7.4 Parameter lmponance Units ...............
(c) (d) pH .................... 169
....................... 174
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Chapter
Irutrod.uction
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I Management ofsolid \r,astes is a maj or challenge these days for the administmtors.
engineers and planners. Huge volumes ofsolid $astes are generated and
need to be collecled. tnnsporred and l'inally disposed off. These operaiions
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have to be carried oui speedily and efJlcienrly without incurring excessive
cosl ordamage to environment. Unfortunately in manv deve lopi ng couo!ries,
the system for maraging wasies is primitive and cannol cope with the huge
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volumes ofwas!es being generated.
In developing couniries, it is common to find large heaps of garbage
feslering all over th€ ci!y. The problem gers further complicated due ro
r large populalion and 1be obsoleie techniques emp loyed for s,asre management.
lnsanitary melhods adopled ior disposal of solid rvastes is a serious
health concern. Techniques and rechnologies however are avajlable and
indigenous methods can be deve loped for man aging ihese wastes properl)- .
I land pollution and air qualiry deierioration_ Fig. t.l sho\Ls the tikely
sources of 'mpdc j on air. udter .nd land en\ tronment.
Water infiltrating through the wasres generates Ieachate, which can
I ultimately mix with the ground water. Dust and Iifier scattered by wind
are responsible for deteriorarion ofair qualit) in !he vicinity ofdisposal
siles- Insanitary method of disposal of wastes also produces odor and
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2 ATextbook ol Salid Wastes Managenent
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releases noxious gases posing high risk to human health Some
health hazards dlre to solid wastes are presented in Table 1' l
ofthe environmental and 1
Table r.r I Some Environmenlal Haz ards Due to Solid Wastes
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Gastroi estinal disorders, jaundice, dianhe4 respiratory
infection, dermal diseases. etc. Also sometimes may cause
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of solid wastes management.
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_ FodenrE/f es I
J/Z-
rr7'//, 3k"
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Conlam.aled Groond Wale.
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institutjonsl
areas, construction and demolition wastes, and wastes from
munic;pat serrices. GW
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4 A Textbaok ol Sohd Wastes Managenent
is normally assumedto include all the wastes generated by acommunily excepl the industrial
\\'astes. The !erm n rricipal solid \9dstes .will interchangeably be used as solid wastes itr'''''
this book.
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waste generated varies with rhe Iifestyle ofthe people. ll has been estimated that each American
generates wastes about 4000 times his bodyqeigh!; each Wesl European 1000 times; and
each cit;zen ofthe developingcountries Iike lndia about 150 times. The United States alone
generates more than 200 million tons ofwasles ayear-an amounl "enough to fill a convoy
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ofgarbage-trucks stretching eighl times around the globe"-
rDeihi, aboul6000ions ofMSW are generateC everY day. Theaverage per capita generarion
ofMSwinlndiancitiesis0.4-0.6k9/day.Thequanlitiesofwastesgeneratedinsomeoi
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the cities in India and comparison ofwastes Seneralion with other countries are sho$ n in
Table 1.2 and lable l.3respecli\ely.
The population ofthe $orld is steadily increasing, but 90% ofthe yearly;ncrease of I
world population is confined only to seven couniries e.g. Ifldia, Pakistan, Bangladesh,
lndonesia.,China. Nigeria and Brazil- India s population is currently increasing by about
15 millions per year. I
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Table 1.2: Quanlities of
cnv
w?s1es and Per Capila Generation
u aste
in Indian Cities
s Generatrcnttant dar) I
\Kgldar)
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2.
AHMEDABAD
BANGALORE
BHOPAL
1683
2000
546
0.585
0.484
0.514
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BOMBAY 5355 0.436
5. CALCUTTA 3692 0.383
6. DELHI 5700 4.574
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7. LI\DERABAD 1566 0.382
E, JAIPUR 580 0.398
9. XANPUR r200 0.640
10. LUCKNO\} 1010 0.623
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ll. MADR{S 3124 0.657
t2- SLIRAT 900 0 600
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Tabl. I.3: Quantities ofwastes in Different Countries
Qu a n 1 i rt ( KE/c ap i t a/dar)
t. India 0..10-0.60
2. USA
3. UK 0.95- i.00
Singapore 0.60-0.90
5. Japan 1.00-1.20
Composition oI MSW
The composilion.'f ftunicipal solld *astes is .ire term that describes ihe distribution
of each component of wastes by its percent weight of the total. The information is
required for the selection of suitable treatment and disposal methods. For instance,
MSW conlaining high percentage of biodegradable wastes e.g. food wastes and yard
wastes are suitable for cofirposting. Similarly, ifrecyclable materials like paper, plaslic,
cardboards, glass are presented in solid wastes, these materials should be recovered
and rec) c led.
The composition of MSW has been studied extensively. The precise composition
depends upon the Iocalily, season ollhe year, standard ofliving, Ianduse etc. Important
conslituents of MSW generated in Indian cities are food wastes, paper, cardboard.
plastics, rubber, textile, leather, yard wastes, wood, glass, tis, aluminium and olher metals,
and silt/di.1and construction and demolition wastes. Typical composition ofMSW geneiated
in Delhi is give, in Table 1.4.
Trble 1.4: Composition ofMunicipal Solid Wastes in Delhi
S No.
20-30
3-5
Card Board 3-4
4-6
Te*ile 0.2-0.5
)-2
0.2-0.5
20-30
t-2
Class 0 -2-a -7
Metals 0.2-0.5
30-40
Wastes from high income goup localities is usually heavy in pape.and packaging, while in
low income group areas, the predominant constituen! is usually food wastes.
Construction a.d demoliti;n wastes consti te a significanrjroponion ofwasres tn areas
where these activities are in progress.
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Composition ofwastes from commercial ateas depends upon the nature ofactivities.
Around offices and institutions usually paper and packaging are the major components
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while close to vegetable and fruits markets, food wastes are predominanl. Similarly,
wastes near daiD, farms will be high in animal feed and manure while in rhe wastes
from slaughter houses bones, blood and animal body parts will be commonly found.
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Efiicient managemenr of wastes requires an integrated wastes management pian. Techniques
-na r. lhno logier itr_: ;i;----.. "nd the choice depends largely on lhe compoaitions ofwastes.
Wastes Minimization:
Wastes should be ideally minimized at rhe sorrrce of irs generarion.
Reducticn can be affected in many ways but the following lechniques are iommonly
employed-
+
(i)
(ii)
(iii)
Minimizing the amount ofthe material used in the manufacture of a product
Increasing rhe useful life ofthe producr
Reducing the amount ofmaterialused for packaging and marketing ofconsumer goods.
Materi3l balance studies and environmental audits ofindustries can effectively help in
devising straregies for reducing wastes generation.
Wastesreduction can also beachieved in household and commercial unitsihrough increased
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public awareness ofimproved buying paftem and through reuse ofproducts. For example,
the same carry bag can be used repetitively instead oftaking a new bag forshopping every
time.
Material Recovery and Recycling: Municipal solid wastes consist ofvarious materials
e-g. papet cardboard, plastics. metals, glass, rubber Many ofthese components are suitable
for recycling and reuse. The process involves separation and collection ofthese materials, I
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preparation ofmaterjals for reuse and remanufacture. Significant amount ofmoney can be
earned through selling out ofthese recovered materials. h efficienrly reduces the quantiry
ofq'astes and thus reduces the load on the disposal facilities which in turn reducesthe cosl
ofhandling and disposal. For ,nstance. fusing ofgiass particles to clay for making ceramic
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:i.-'".TI"Tir':il;:T:1: ::fl:;i:h?':r''"' ftj makins Porlester nber ror manuracturins
.."r r,o," *"pr.a.,"1,-;-';;;il;i;",'.:j,l;:X::,".[
o: these metals from ores
1T;,lXi,i::;fi ::i:l;H#, J;
\lastes Translormation: Wasres rransform?tion
is the physicai. chemicai or biological
.onversion of sasies for an) beneficial Du
",.r u,.o,,po.,;ng.,nu.;dr-;:;.,;r;"'r:3;ji,:f"iffilii",::?;.1l,.T,1il"rp,9::i;
are erFployed lor tl i( purDore. Se\
eral o\ Drodu.r. orii.."e process., in rt ;";;
energ) erc can be recoverea. seJecrion oiaiuitaul" . ;;rr:,
ofwaste translormation as well
,."r,"1'qr" i"p"rar'roii'ffiili*,".
as on the composlrlon ot wastec
lblume Reduction, Volume reduction of\.\astes
is carried our before irs final disDosat.
incrudes It
size redLrcrion rhrorsh .hreddins,
rcduc rion rhrough com pacrion. Volume
s,ze;";;;i;;;;;;;",;;il;[;:r,.; ,,,.
,".i"rrnanr,-a;.po.'ri. "' '-"'_ reduc
'qurtro.. ol $aslesalso redL'es rhe land drea requrJemenl
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(ii) Moisture Content
(iii) Particle Size and size distribution
(i') Irield Capacity and
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()) Permeabilily.
Specific Weight
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Speci{ic weighl oi.runicipal solid waste is defined as the weight ofwastes per unit volume
. .- tons/m3. Il ia usualltlpeci;:l as Ioose, uncompacted, or compacted. Specific weights
are requlred rc assess lhe total volume oi was13. tb3t rt!st be managr ' It has both spatial
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and temporal \ aflanons.
Specific weighl of the municipai solid wastes is required iD the design ofvarious equipment
e.g. fo. processing units, for lransporration and for estimating the required capacity of I
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disposalsites.
Specific weight ofthe solid wastes is determined by means ofacubical container, usually
o0 c'n r0 cnr ' o0 crn 'n si7e. The conlainer is filled to o\erflow whh the \ asie taking
. _ ;-!t
soecral rare
special care tolo avol0 seaesarlon or comDaclron,
avoid sEde-dation compaction. Loss ofthe
Loss or Ine rlne particulaie material should
fine Danlcura
. .. 2 be a\oioed. The coni;iner is-tamped
+-.--r-,'__ ..,"i)lr-_.
-_:trathr edge FinallriKe-cbnrainer
thricdb! Iiftine it 6 cm above lhe eround and dropping
do$n squarel]. After th* consolidalion, lhe top ofthe contaider is Ievelled with the tielp ofa
is weighed and the speciJic weight is calculated as foll.,ws:
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Specific Weight = (i/*. - Iri)/,/.
where ,/.. is weight ofcontainer {illed with the wastes (kg);
Ir', is weight ofenpty container (kg); and
( 1.1)
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t' is volume ofcontainer (mr)
Specific weights ofvarious components ofmunicipal solid$aste are presented in Table 1.5.
class
0.05-0.15
0.15-0-3
0.l-0.2
0.r0
0.23
0.15
o.l5
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0.1-0.2
silr/AshIDirr 0.6-l -5 120
Moisturc Content
The moisture conteil ofsolid wastes is the weight ofwater in it expressed as a percentage
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ofits wet or dry weighl. Usually il is lhe wet qeight which is commonly used.
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To dete.mine the moisture content, weigh the entire sample to obtain the wet weight
( tr;). tt is then dried in an oven at I 05oC till its mass becomes constant. ln case combustible
material is presentthe temperature shall not exceed 70 to ?5"C. Afterdryingthe dry weight
(lt'd) is measured. Moistute conteni ofmunicipal solid wastes is then obrained as follows.
M.C.=(fi/"-Ya)/W" (1.2)
Moisture content is an important pammeter affecting various processing opemtions e.g.
composting. Usual values of moisture content in the differeot compooents ofmunicipal
solid wastes are given in Table L6.
Moisturc Cartenl
50-80 60
Paper & Cardboard 4-10 6
Plastics t-4 2
Textiles 5- 15 t0
l-4 2
5-10 8
30-80 60
10-30 20
Glass l-3 2
Metals l-3 2
SilrAsh./Dirt t0-30 t5
Sorr.e, iSEM (2000).
Field Cepacity
The field capacity ofsolid wastes is defined as the total amoBnt ofmoisrure thai can be
held ;n a wastes sample under the gravitational force. It is an importanr parameter, which
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10 A Textbook ot Sotid Wastes Management
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lzo
90
m I
E5U
z
E50
g
f.o
10
i0 3o
Mesh siz€ (cm) --__--|
Fig. 1.2: Typicat particle Size Distributjon
of MSW
Field capacity ofsolid wastes vades wirh
the degiee ofcompaction. Typically
capaciry ofuncompacted municiDal the field
j,,", u. .".,i.i
solid v
il;#fi :; ;.:iil::x,HT:iJH:,1?,.,,
percenl A co, umn
" "",
Permeability
The p€rm€abilit) or hydraulic conducriviry
ofwastes is defined as the ease with which
uurd,can flo$ rtuough rhe asreliiliiilironanr a
" pu."r.r". thur gou..n. ii. ,""...r,
lrqulds and gases in the landfill. permeabi
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shape and sLe or wast;; ;;;;;;;;,: ;;::g,;'#li::il:llf"}:."fi ::l*HlflJi:
the wastes, Compacted wastes have lower
permeaoltrry.
Sahpling ol MSW for physical Composition
Collecrion of samples is rhe first sren in
esrimariDg rhe composition ofmunicipal
wasles Frequency and timing ofsamires soiid
colection should be carefirrl decided
rrutj.represenlarive sampres. sampre c;Iectionshourd io ensure
ll rs rmpofianl to note thal the larqer the n umber extent or er a tuilri; ril;.il**",
ol samples.
the resu)r( the more representative are
Locarion ofsampring starion is also imporunr
in physicaranarysis of [,rsw. rdea
". sampling are rhe transfer sration localed ali orer the ciry.
lor ocarions
Samples should b€ collecled
:::L-*_T"P
differenr rocarions as possibre and shoutd
enure area. Samples may also be collected
frc
be u"];;;;;;r;i#J;l;;;.
Colecrion of samptes a, ;;.;; ;i;;;;;;:T.Iasle Processins uniB or ar disposal facilities.
,reco,.ct.df,o;;;;,ffi;i;fi;ilI:ill-Jf,,lii.l*,liJi,ill,lil?ll;[;]^T,l'ii
!rastes is not accumle iftrucks collect \yastes from different areas in on€ trip. In gefleral,
one sample each should b€ collected randomly ftom each identified truck (ASTM D 52j t).
Ifmore than one sample are needed these should be collected from ditferenr parts oflhe
load in the.truck.
Sample size ofabout 200 to 300 Ib (i.e. abour 100 ro 150 kg) is considered optimum as
recommended in ASIM (D 5231). Following are some ofrhe common procedures ofsamDle
collecrion. Often combinarion ofthese procedures is also used.
. Oblaining a composire sample from material raken from predetermined Doints in rhe
load e.g. each corner and meddle ofeach sidel;
. Coning and quartering;
. Collecting a grab sample from a randomly selected point using a fronlend loader;
. Manuaily collecting a columE ofwaste from a ranqgqlly selected location.
ln coning and quanering. d large quanlil) ofwasre is rnixed ro make h uniform. the
mixed waste is tben arraDged in a round pile in the form ofa cone (coning), and one quarter
is randomly picked up (quartering). ASTM recommends coning and quartering, beginning
with approximarely 1000 lb of waste, to obrain a sample of200 to 300 lb. This method is
tir.e consuming and requires large space. It may also reduce accuracy as mixing may cause
various waste components totrash and stick together.
A more common method is to coilect grab samples using a front-end Ioader. This is a
relatively quick method. Sampling through the fronlend loade. alsoreduces the chances of
bglassociated \ th manualcollection. Howeveriarge objects e.g. emptv cardboard carons
may faildown while the loader bucket is lifted. Special care needs to betaken to avoid such
conditions.
Proximate Analysis
Proximate analysis ofmunjcipal soiid wastes is canied outto dejermine itsmoisture contenr,
voiatile combustible matter, fixed ca.bon, and ash coitteot. Volatile combustibie matter is
the loss ofweight on ignition ofthe dded waste sample at 95ooc in a covered crucible.
Fixed carbon is the combustible residue that is left afler the volatile matter is removed
from the waste. Ash content is determined as the weight of residue ofwaste aftercombustion
in an open crucible.
Carbon 50.0-60.0
Petcentage b! seight
50.0
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Hydrogen
Oxyge,
Nitrogen
Sdfrr
6.0-8.0
30.040.0
2-0-4.0
6.5
32.0
2.5 I
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0.3-0_4 0.3
5_0-10.0 50
So,/rc€, ISEM (2000).
MSW Componeht
Tabl€ 1.8: Chemical Compositiofl ofVr,rious Componenr! ofMSW
Percentape 6 dn *ei?ht
{ otba4 Hydtogen Orygen | rogen SuAu;
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Ash
20-40
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45-75 6-12 1-2 0.2-0.4
Paper & Cardboad 30-60 5-10 30-40 0.-0.3 0.i,0.2 5-10
Plaslics 50-E0 E-10 15-20 <0.r <0.1 6- 10
30-40
II
Textiles 40-50 5-8 t-2 0.r-0.2 3-1
Rubber 60-74 8-10 1-2 l5-20
50-60 6'8 10-12 8-r0 4.2-0.4 8-10
45-50 4-6 30-40 3-4 0.3-0.4 6-8
45-50 5-6 <0.1 0.5-1.5
Glars 0.5-0.6 0.1-0.2 a-2-0.1 <0.1 98-99
Metals 4-5 0.4-0.6 3-4 <0.1 90-95
3-4 0.4,0.6
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Si]rAsh/Dirt 20-30 3-5 0 l-01 60-70
So,rrcer Li! snd Liptak ( 1996).
Preparation of;amples fotvarioustesls and the test rnethods arediscussed in the following
section.
Pr€paratioD of Samplq Municipal solid wastes are oftm heterogmeous in nature. A repress,-1tive
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sample for laboratory therefore testing requires a large q uantity of samp ies say I O- I 0O kg.
Firsl, the basic operations e-g. drying, gdndinB, and mixing are canied out. From this iromogenized
sample a fraction weighing about 100 to 2OO mg may be extracted for detailed a;lvsis.
Details of methods of preparation of sarDples for chemicai analysis are described i; lSl
9234 - 1919.
The Iarge samples are dried ir) an oven.lnitial mass ofthe sample is \yeighed and then
dried al a temperature between 7O and ?5.C for 24 hours ifthe material i; combustible
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otherwise it cao be dried at 105 + l.C. However ifrnicrobial tests a,.e also to be ca iedour
drying is carried out at 40 to 50.C. After drying, the material is aliowed to cool down
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preferably in a desiccato.. The sample is again weighed and placed in lhe oven for further
drying. This procedure ofweighing, dryiDg, and cooling is repeated till the difference in
weight ofbetween two successive cycles is less than one percent ofthe total previous loss
illmass.
The dried sample is then placed in a hammer mill, grinding mill or in a pulverizer to
reduce its particle size upto 2 mm. Final mixing and homogenization is accomplished by
using a rotatingmixer. The pulverized material is placed in the mixer and allowed to mix for
at least 2 hours. Finally, ifdesired, the mixed sahple can be sieved to separate it into different
sizes.
tr Carboir and Hydrogeu Analysis: Carbon and hydrogen are partofthe uitimate analysis of
II
municipal solid wastes and can be used for calcdation ofcombustion par:alneters. The detemination
ofcarbon and hydrogen involves burning ofsampies to lonieit carbon to carboil dioxide
and hydrogento water The combustion is caried out in a stream olhigh purity oxygen- The
sEeam passes lhrough the sample and a train ofa water absorber, a carbon dioxide absorber,
and a second water absorber, Carbon dioxide and waterarethus recovered inthe absorytion
train. Typical apparatus rcquired for this test is shown in Fig. I .3.
iI uit
Ir
E,EG,H,l, = cornbusrDn J,K.L=absorptionr€in
B,c,D = oxyg€n puilylng train J: li6r wat€r absoder
B= li6t
waler absorbsr K = ca.bon dioxide absorbe.
C = carbon dioxid€ abso.b€r
D s6c6nd wal6r absodet
=
I for about 20 min. Oxygen supply is continued forten minutes thereafter. The absorbers are
thea detached and allowed to cool down to room tempeaature.
r
Percentage ofcarbon and hydrogen in the sample is calculated as:
Carbon = (A/B) t 2,t.289 (1.8)
Hydrogen = (C/B) x I1.19 (1.e)
I
I
is increase iD weight ofcarbon dioxide absorber (g);
-Bweight ofsample (g);and
r
C is increase in weight ofwater absorbers G).
Nitrogen Amlysis: NiEogen is also an inportant pa.rameter as it afecs the mte ofbiodegradation
ofthe waste. Percentage ofnitrogen can be determined either by Kjeldahl-Gunning Test
Method (Fig. 1.4) or by the Acid Titration Test Method. Both ofthese tests involve conversion
I ofnitrogen in the solid wasles into ammonium salts by destructive digestion with a hot,
I
I
I
t
14 A Textbook of Soliel Wastes Management I
catalyzed mixture ofconcenmted sulfuric acid and potassium sulfare. The salrs are subseouentlv
decomposed :n a hol alkaline solurion from which ammonia is reco!ered by disrillarion and
l!s amounr derermined bj rirrarion.
I
T
t
I
t
t
t
I
I
a = dt€ctrtc heaier
B = Kjotdahr dtg€siton fiask
C = KjBtdaht conn.cling bu b
D = cond6nsor
E = connectlng lub€
F = rec€iving flask
1
I
I
tr
L
I
II Modified Dulong formula
iolid sasres e,g.
can also be used ior determination ofener&v content
Energycontent(Btu/lb)=145C+610(H?-Orl8)+40S+l0N
lvhere C is carbon fraction, H2 is hydrogen fraction, O, is oxygen fraction, S is sulfur
fraction, N is nitrogen fraciion-all values being percent by weight-
ofmunicipal
(1-10)
t Typical values ofenergy content various components ofmunicipal solid wasies are
!r
presenred in Table 1.9.
I imponant characteristic as il gives an idea oflhe biodegradability ofthe waste and helps in
the seleclion of appropriare processinB technique.
I
Rubb€r 23000
tsrher 17000
6500
18500
I Glass
Melals
SilrAsh
t40
700
r
7000
Biodeg@dability ol MSW
I Biodegradability olorganic fraction ofMSW is often described by its volatile solid content
as determined by ignition at550oC. However such criteda of describing the biodegradability
of the organic fraction of MSW can be roisleading, as some of organic components of
I MSW (e.9. newsp nt, tree trimmings)are highly volatile but low in biodegadability. Lignin
content is a better index ofthe biodegradable fraction determined by using Eq.l.l l.
BF = 0.83 - 0.028 LC (1.r1)
t
The biodegradability ofvarious componenls ofMSW based on lignin content is presented
in Table Ll0.
t
T
I
I
16 A Texlbook of Solid Wastes Management I
Tsble 1,10: Biodegradable Fractjon ofCoftponents of MWS
1
(%)
1-r5
(%)
0.4 0.82 I
Paper
r--r i-.
& Cardboard
ISEM/:0001.
92-96
50-90
22.0
4.0
0.21
4.72
t
MSW STATISTICS OF DELHI: CASE STUDY
The Department ofstatistics, Ministr) ofPlanning and Progranme Implementation, Covernment I
of India has launched a program ofDevelopment of Statistics in Environmental Sector.
Quality and quantity ofsolid wastes are ofcritical importance in the design and manageolent
ofSolid Wastes Management Systems. The lndian Society ofEnvironmenlal Management I
i
(ISEM) hascompleted one such project e.g. developmenl ofadatabaseby collecting,analyzing
and updatingthe data pertaining to Solid Wastes in Delhi.
Delhi is spread over an a.ea ofabout 1500 sq. km. The collection and disposal ofsolid
wastes is the responsibility ofMunicipal Corporation ofDelhi (MCD) and New Delhi Municipal
Council (NDMC). MCD has dlvided the entire area under its jurisdiction ir1 l2 zones in
addition 1o the one NDMC zone e.g.:
(l) South Zone (8) Karol Bagh Zone
I
(2) Centrd Zone (9) Najafcarh Zone
(3) Wesi Zone
(4) Shahdra (South) Zone
(10) Sadar Paharganj Zone
( l1) Narela Zone
I
(5) Shahdra (North) Zone ( 12) Rohini Zone
(6) Chy Zone
(7) Civil Lines Zone
( l3) NDMC Zone
I
The Conservancy and Sanitation Engineering (CSE) DepattmentofMCD employs a iarge
staff, both skilled and unskilled, for solid wastes management (Table 1.11). There are about
3E000 safai karamcharis engaged in collection and depositing the solid wastes in receptacles
I
(Dhalaos/dustbins) located all over the city. A briefdescription of machinery and other
miscellaneous equipments employed bythe MCD for solid wastes management is presented
I
1
s
l.
tL
I
Lr Trbl.l.rr: StaIT Engag€d in SolidWalres Managem€nt
,a lo Stalf
ir
I, Di.e.to.-cum-Chief Ergincer 2
:, Jt. Director-cum Suptd. Engineer 5
Additional Depury Commissioner I
i Administrative Ofiicer 1
5. Executiv€ EnsiD.er (Civil, Auro, E&M) 20
6. Astt. Ensineer (CiviLElecrMech./Auio) 48
7. Junior E sineer (CivilEl€cnMech.) t76
E, Sanjtary Suptd. 22
9. Chief Sanitary Inspector 33
I 10. r
11. Astt. Sanitary Inspector
208
666
r
t2- Sanitary Cuid€ 603
13. Safai Karamcharis 38,311
14 Driver 941
Sou..: MCD.
I Tsble 1.12: Machinery and Facilities employed for Sotid Wastes Management
r l.
2.
3.
Machinery and other Facilities
Central Siore
DhalaoandBirs
I
2500
I
11
Workshop (WheelBanow) I
5. Tipp€rTrucks 510
6_ Loader 84
I
7. Bulldozer 26
Som?r MCD.
I s ,\b.
Tablc r.r3: Landfill Sitcs in Delhi
r l.
2.
3.
SLF Ghazipur lEasr Dclhi)
SLF OkhlaPh I (C€n1ral Delhi)
SLF Bhals\ra (North Delhi)
70
32
40
r The quantity ofmunicipal solid wastes generated in Delhi has been consistently rising
overtheyears (Table l.l4).In 1992, the minimum monthly generation ofwaste *ai80226
r
tons (February) andthe maximum was 97224 tons (November). The average dailygeneration
for the ) ear I ao: works out ro be 2933 rons. Hoqever rn 1998. the minimum E!;nerarion
was I23736 lons (February) and the maximum of 167560 tons tDecember). This amounis
ro an average daily generatior}of49l4 tons per day i.e. an increase of l6j .5o/a oyet 1992
r
r
!
I
1A A Texbook ot Sotd Wastes Management T
Table
1992
I.l4:
1993
Quantiry ofMSW Generared in Delhj(tons)
I
127830 168292 i5608,1
85t50 99730 11102E 93332 129120 t66212 149426
91302 104186 106116 1t2728
'to2384 165406 1496 t4
95586 151044 133974 149254 159336 164614
I
97224 98542
95960 99796
107538 116666 151406 l56t t4 155072
106532 177060 t44112 156228 167500
TOTAL t07072 1219034 1322421 t2\525a 1547416 tx,6x2 1793682 974776
Qry/day
Soutce:MCD.
3340 3673 3574 4239 5222 49t4 5327
I
Anal) sis ofdata reveajs rhar oresenriv 2verage daily generation
in Dethi is abour 5lO0 rons. Ii is obse;!ed ,f,i,,f,.rriSw
dhalaos and then transpo(cd for fina .
ofmunic;pal so.rd wasles
c;r.;.;";;;[,::t];cl* ,,
:sat. physicai aialr.,, .fa"," ,"r.j.,ir, *.
I
I
brodegradabte componenr is abour rll"o of roral.
The recvclrhl. ::^:'..- I2on
ana.iniruaes paper lnJ"",au""J, u.-". pi".,iJi;: "^_.^---; ;" Ebour
i;:i;:ffi::Iionentrrs
Hazaroous wastes are found freouen.h .ommingled
wilh the municipalw^t".. Uiiirur.ty
ir reaches rhe tandfilrs u here ir is leached ro rhe
er"r^a *"i. i
"lii'"!, i;;;:rr:; il,;",
health.
DalasBtistics revealrhat
:."111'11:ll:r:r*
a large fraclion
.ltabte f;r
ofMSW can berecycled and reused. Neighborhood
biodesradabre wasres rrom,estaenrial a,.lr. i,;.,
i""*"i
I
or Dlornedrcai q astes. it is recommended rhat a cenrral
small unirs which cannor afford independent lreatment
A computer program has beeo develoned for database
facility is appropri",.
facilil;es.
managemenr
i*"i"ii, ,*
ofsolid l}asres in
I
I
Delhi. Using $is software Irsu dara for diiferenr
marurcr thus co.stituting a valuable daabase.
.;;";;f D;i;l;:;'b":;o;;";;:;",,"
use of ,u.i"*
Informalion systems (cls) faciritates the operalron """i;i*.hrj;;.. "*oJ"*rr"
ancl monitoring ofrhe sorid wasres
rnanagefient system. It is sugiqested t}at acomputerized
and sharing of information.
Thestatistics and analyses ofthe MSWdata can be
e.g. treatmenl alternarives. technology selection,
network bet".dev.r"p.i
I
the sotid wasre. rhe MunicipatAcr is trre
nrst tegistati;n in rh; ,i,ii-ii,o'*il'o'.i'lIiio,"
which deals wirh en!ironmenut oolirtion carr.ed
b1 riuntcipatsotia wlr.s.
Corporarion Act. I957 contain; rhe foilowirrgsections
*;;;;i";;;il,
relevant to solid wastes manag€ment
in Delhi
I
I
I
It
It Sefijon 42 (c) O^bligatory
r ;iil;;;"il;X"*1,.:::
,:a\enging
Seciion 350
S.ciion 352 ;-Ji:;l ::: :::y:5":,1"c ;;:;""i:i,Jil',oo,.n,n
Secrion 353 lliJll?3,fl "":"t::,:::-". ;;;;1 ffi ;::::l:;',1;f nn.
l3
*",p,;;; i;'";r;
""".p'""r;., ;;5::#::,r,"T;:;
r
Seciion 358 3:::,1::::.-", --o
commissioner,s power,,i g", p."rr.". ."-"r""igllii,::1::T".
","
Recently the Govemrnent oflndia
ha s laid down detailed rules
s'a$e management. and guidelines for solid
il#**[g{*{#,}i#JiilH"t$ffi
Wasi (M"nagement & Handring)
"*"."i..
or,5
Rures
t RespoDsibility of Municipal
l;?;[*i;lTjf
I Authoritv: I
I rmr.:****u*g[r***$*ffi
I Porrerof thcDistrictMagistrateorthe
or
for the enforcemenl
of,r,. p." iii" r,
Debntua^-_r--:^_-- _,
rft ueputy commissioner orrhe conceS:::l*9:II::1"^1.::
' '5
u rsL snall have
r,'"r".
^.
,n. oisrricr Masisrrale
the o\ erall resDonsibiliT)
I "r'"
"
Stale Boards to MoDitor Enforcemert
:l1I:::',I" :"::
r
as rne.case ma] be. rhe poiturion
conrr", folluuon controt Board or
I ffi
Co.
:Trit"# lff:t r",^Titt:H ;.""r,j].illii!i;"["JJffix',*,ffi[::
itsmanageftenrandhanafirr- " ""-" "' "'tIna[ersotmunicipalsolid trasledisposaland
I
Wasle (garbage, dry leaves) shall not be burnt.
(!iii) Stray animals shall not be allowed to move around waste storage facilities orat any
other place ;n city/town, and shall be managed as per State laws-
Municipal authority shall notify lvasle collectiofl schedule and the likely method to be
adopred for public benefit in a ciry iown.
Segregation of Municipal SolA fi'asles: M]jtr.iclpal authority shall oryaoize awareness prograns
I
for segregation ofwastes and shall encourage recycline/reuse ofseFegated materiais. Muricipal
3lurority shali undenake phaseC pr.r ams !o er,sir.e that the community is fully involved in
waste segregalion.
I
Slorage oJ Municipal Solid Wsstes: MIf.icipa.l arthorities shall eslablish and mainlain storage
facilities in such a manner as not to create unlygienic/insanitary conditions around it. Foilowing
criteria shall be taken into account while esrabiishingand maintaining storage facilities:
I
(i) Storage facilities shall be crealed/established by taking inlo account quantities of
waste generation in a given area and the population density. A storage facility shall
a
(ii)
be so sited such thatthe user finds it easy to approach.
Storage facilities to be set up by Municipal authorities or by any other agency shall
be so designed thaa waste slored is not exposed to open atmosphere and shall be
I
(iii)
aesthetically acceptable and user-friendly.
Storage facilities or bins shall have 'easy to operate' design for handling, transfer
and trafl sportation of waste.
I
(ir) Manual handlingofwaste slrall be prohibited. If unavoidabie dueto constrainls, manual
handling shall be carried out under proper precaution with due care for safety of workers.
Trunspo ation of Manicipal SolU Wasles: yehicles used for tiansporta!;on of wastes
I
shall be covered. Wastes should nol be visible to public, nor exposed toopen environment.
The following criteria shall be met:
(i)
I
I
The storage facilities set up by Municipal authorjties shall be daily attended for
clearing of\Yastes.
(ri) Collection and tmnsportation vehicles shall be so designedthat muliiple handling of
wastes, priorlo final disposal, is avoided.
I
I
I
.......
r
, ) d.uetoheav)metals.pesticidesoran)othercon,"airunra_____-'-'*,,*,,,,,
r,
'h?rr
wasteconrainingrecoverablemalerialshallfollo\rtherouteofrecycling.
Disposal of Municipal Solid Wastes: Landltlling
shali be restricted to n^n-hi^,_tan...r.
inen*asreandorheiwas'.rr,",",.no,r,i,"ii."i,r,".#ffi;il::T:i[:;;t:lir..i::i[iJ!.
Landfill;ng shallalso.be carried out for resroues ot wasre
processing facilities as well as
ror pre-processins reie*s fiom waste nrocsssi.g
shall be avoided unless it is found unsuitabi;r
r".iri,iJ, r"ranit;;;ili:J;"r,.
o. r;rr ins* rarion oiuli;;;;; r;;ffi:' l:;:ffi XffiIif;::i"JHfr:::,ff:HTyffi::
Landfilting sha meei the folowing crireria:
(i) Landfillsiling and construcrion shallbe done afterorooercare
H^'-a., i-.-".
p,oi.i;;ir;;;il"iH;#:*::"j*;
of ciries having popuratio, ou", nr" r".i
shatt.b€co-nducredbyMunicipalaulhorjrlb"irr*..r..1i"r"rii.."t"'"""',
(ir) rro! s ton tor firture Iand fi ll shes
r
shal I be included in the land'use pian ofcity/town.
(iiir Landfiljsiteshallcomptywirhrhenormsforcontrot ofairanjwate;d;.;"jrrd
surface waEr) pollution and otherenvinon tental
norms as laid down in the speciflcatioas/
standards.
(iy) Waste at disposal site shall not be burnt. Sites where
waste is to be burnt shall be
monitored for cornpliance.
A^[.trual Rrports: The State pollution Conrrol Boards
of Union renrrories sha, prepare and submiiro;. -c;;;;i;;ii;ii*
and pollution Conlr^t a^_-id
Annual Reriew Repon wirh r;gard to rhe implern.nt"rion lffiffiIIT:
of ,fr.." .ri"._;; r;il;
before 30lh Jur,e. The Centratpolurion Conrrot
Boara snalt prepare rt e con.;;*i;"_;r"l ".
I revie\r reporr on managemenr of hunicipat sotid was,..
aiong wirh iis recommendarions befor; I5rh Septembe,
Accidenl R€porting: When an) accidenl occurs.lt
ili;;;fi ;;;"';';;Hi6:',1*""r,
er.ry yea.._'
I
any municipal solid wastes collection,
segregation. srorage, processing lrearmenr and ai.p"."f
transportarion of such wasres. rhe Municipat aurt oit,y
f^.iiiif".i"rdfil.ti.';;;;;;"_
to rhe District Magisrrate or rhe Depr-rry Commtssione, "r,"riio,it
*iit,-.ii;;i;;;i;:"r,
ofrt e conc..n;;.j;;,ilr:",..
I EXAMPLES
Exerhplel.l:Aresidentialareaconsislingofl5OOhouseshasanaverageoffourresidenls
I
per house. Forestimaring rhe quantii,
of;lid wasre genemted. rh; f;li;;;;;;r:;J";;r,
r ere made at disposal siLe for a period ofone week.
I I
II
III
l0
25
8
l5
2
300
150
I
0.J0 r00
I
I
I
I
2 A Te,ttbook of Solid Wastes Manegement
I
Determine the unit rate ofsolid wastes generation'
Solutionl
I
Using the numbe. oftdps, volume and specific weigh!
during o{le week may be calculated as:
the totai weight of solid \'aste generat€d
I
I
oJ Nunber of tiPs Specific wtghl
Type (Kg)
(mr) tks/m')
15 300 45,000
I IO
II
III
E
25
2
0.50
,orsl (Kgw.ek)
150
100
2,400
1,250
48;650
I
The unit genetation rate = I;
Total quantity of wastes
of-houses ,
Residents per House
I
I
Exrmolel.2:Eslimatethemoislureconlent,densityandenergycontentofasolidwaste
sample that has folloqing comPonenls Lsesuirabledala I
l4
40 I
Cardboard
Plasrics
9
9
t2 I
I
5
6
Solrtion:
' ' MoisIUre
ti) Conlenl
urir* [" rypi""f a"" moislllre contenl ofmunicipal
"n
io t0O kgofsample ma) be calculaled as:
solid wastes' ttle dry mass corresponding
t
14
Moisturc Content (o/.)
70
Dry Mass
4.20
\kz)
I
Cardboard
40
9
9
t2
6
5
2
60
37.60
8.5s
E.92
4.80
I
Tin cans
5
6
20
3
Totrl
4.00
5.82
7-3.89
I
I
I
t
I Moisrure Contenr =
/ioo - 7la9 r- ^^
l-:m-]100 = 261 l016
iiri Densi!y
Using the typical dataofMSW, lhe volume correspordingto 1000 kg ofsample may be
Twical DensjelKgrl.3)
14 290 0.483
40 85 4.706
Cardboard r9 50 1.E00
Plastics 9 65 1.38J
2 105
5 240 0.20€
6 90 0-667
10.392
14 4,650 65,100
40 t6,750 6,70,000
Cardboard 9 16,300 1,46,700
Plani6 9 32,600 2.93,400
t2 6,500 78,000
5 1E,600 93,000
6 700 4,200
Totd 13,50,400
Assuming the ash content as 4%, the unit energy content (on ash free dry basis)
I
I
24 A TexlDook al Sottd Wastes Managoment
I
Example 1.3: Derive an approximate moleculai formula for the organic portion ofa solid
wasres sample s irh the following composition:
I
Codponent
15
I
Cardboald 5
5 I
I
l0
5
Using the chemical composition obtained determine th! energy content of this solid
Solution: I
Using the lypical data of moisture conte!1 and ultimale analysis ofthe combustible
components, the chemical composition corresponding to 100 kg oi sample rnay be calculated
r
Conpanent Moist
Mdrs(kg)
Dry
Mass C
C hedical
H
O
Cadponents (kg)
N S Ash
I
Food
Paper
wastes l5
45 12.3
Cardboard 5 4.75
4.50
C&bon
Hydrogen
Oxfgen
3
,ud$ (kg)
29.482
.938 + 2.283 = 6-221
26.767 + t8-266 = 45.033
34.684
7.318
52.98
I
Nitro8en
SulfiE
0_442
0.127
0.472
0.149 a
t
3-73 4.388
a
a
The above mass composition ofthe chemicals may be conveftedto the molar composition
/ <1oa.
= 117G4.684r- r420l.'.1 l8 - ai::J * 93r0.r40,_ 21r0.4,2r
= 12700.83 KJ/Kg
The above formula is with sulfur. The same may be convened without sulfur as:
I
HydJDgen 6.159 2t5.36
Oxygen 2.815 98.40
Ninogen 0.029 1.00
tulfn 0.004
I EXERCISE
L What is rhe 3 R's prircip le ofwasre managemenr.
this principle:
cive examples. What are lhe main advantases of
I 2. For
l.
a residenrialarea ofDelhigive typical composition ofMSW. Commenr on seasonal variarion.
Whar are the hazardous waste constituenls ofMSW in an urban residentiat colony? Cohpare it
with that ofwaste from ruralarea.
I 4. Des cribe briefly the Municipal Solid Was.es (Management& Handling) Rules,2000_
5. A solid vaste landfill has an i,t ritu dry densiry of0.65 ,m3. The fietd capacity is atained at a
moisture conlenlof4oo/o. Determine how mLrch additionatwaler it can hold ifthe inirialmoisture
I
I
I
I
I
I
I
Chapter I
I
llection arud, Pro cessirog
I
Co
of Soli.d Wastes I
I
Wastes generated need to be collected and transported regularly for its
management. processing and final disposal. processing of r+astes is desirable
I
before irs final disposatfor enrironmental fiiotGiiiin-'. Segregarion-6fi6lii
wastes at the source is necessary for propermanagement o-i[nicipal solid
wastes. [t can have significant impact on the lrearment and disposal methods.
I
Pxocessing techniques in solid \yaste managenient include Seglegation;
Reductjorl Resource Recovery & Recycling: Thermal, Biological and Chemical
Conversion etc. Various techniques and technologies have been developed I
around the world to transform various components ofwastes into useful items
e.g. fuel, mw material for manufacturing useful products. This chapterdeals
with the collection and transportation methods and with the wastes p;ocessing. I
SEGFEGATION OF MSW AT SOURCE
Segregation ofwastes is prcferable atthe source itself. Rgcovery recycling
and reduction all become easy for segegated waste componens. Components
I
such as paper, cardboards, plastics, and metals should be separated out for
recyclin8 orreuse. Biodegadable wasres such as food \rasres ard yard \ya$es
should be separated. as these are suiEble forcomposting. Bags oi66;hiners I
mzy be identified suitab,y through color codes for storing different q?es
ofwastes separately prior to its transportation and disposal.
COLLECTION OF MSW
I
Municipal solid *astes are usually pioked up from a variety ofsources e.g.
households, institutions, colnmercia-liEitrG:litany types of hauling vehiclJs
or carts are employed for tfaDsferring these wastes to the nearest transfer
I
station where the contents ofthesevehicles are emptied. Collection systems
for municipal solid wastes are broadly categorized as:
(i) Collection of ComminglglWastes; and
I
(ii) Collection of Segregated Wastes
I
I
I
:
Flg.2.t: Open Bor Type Handcart Flg. 2.2: Ca wilh Sgparate Bins
Handcarts are used for household and commercial units. Due'to their small size, these
are suitable fo!collection ofwastes froln narrow streets. Open box type ofhandca(s with
two or three wheels are commonly used (Fig.2.1). The usual capacity is about 2OO kg of
MSW and its size is about 0-4 m3. A worker can easily push it provjded the cafi is in g;od
working condition. Segegated municipal solid wastes are transferred in separate bins
iFig.
2.2). The operationai disladce ofahandcart is about one kilometer. Nearby transfer stations
are lherefore required for empr) ing ofhandcans.
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28 A TexlDook al Solid Wastes Managetnent I
Pedal tricycles are also used for tmnsfer of wastes. This type of vehicle reduces
travelling time and can operale over a Iarger distance. These can also be made single box
the
I
I
type, or with several bins for collection ofsegregated wastes. A tyDical pedal tricycie
used
;n India is shown in Fig. 2.3.
I
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t
I
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I
F19.2.3: TypjcalTricycte used lor Wa$es Coleclion
Motorized tricycles are normaliy ofa larger capacity tha, a handcart or pedal tricycle I
and can carry upto 2.0 n3 ofwastes. lts relatively high speed enables it to operate o;er
greater distance i.e. upto about l0 km. But it does not operate well on rough
rnside a sanitary Iandfill-
a
roads e.g.
I
I
Tractor type ofmotor vehicles are almost universaliy available in developing countfles.
These have se\eral advanbges e.g.:
. Mainienance facilities are readily available;
.
.
Its cost is low as compared to other heavy vehicles e.g. trucks:
It is a, ideal vehicle for operating on landfills due to its large tyres and high iorqde.
Despite its low speed ofabout 20 km/hr, jt offerc one ofthe cheapest methods oftransport I
ofsolid lvastes for volumes ofupto 6.0 m3 per trip. Agricultural ;actors and trailers (iig.
2.4) are often used as acoupled unit forcollectjon ofrefuse from households orcommercial
storage points. The trailer is also suitable as a transfer station because ofthe ease
with I
I
which the tractor can be separated from the trailer.
TRANSFER STATIONS
I
Transfer stations are open or closed structures built by civic autho ties atvarious locations
in the city. Wastes collected lrom various sources (e.g_ househoids, comntercial establish_
t
T
I,
Collecfan and Pbcessing of Solidwasas 29
rn€nts) by hauling vehicles is first transferred to
these staaions. Fromthes€ tmnsfer stations,
uasles are then rransponed ro rhe final
dlsposal ,it",..g. l;;;;.;;;;;
landfills. Various r) pes ofrransfer slarions are discussed "orp".ipiu;.
betos ",
!
!
t
I
I
I Ftg. 2.5 (r): Meialic conlainer
The size ofbin at a ransfer sktion depends
to be received. fhese should be construcred
upon lhe quantiry ofmunicipal solid wasles
!
at sutrable Iocarion so as to minimize the
distance. Setection of sires for rhese rransfer sr^ti"., j. haul
t;.;;; i;;';;;,;;.fi;ll"-
!
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30 A Textbook ot Sotid Wastes Wnagement I
Poo.ly maintained transfer stations are malodorous and harm
wonder the public displays an acure NIMBv sFdrom" (N.t
L
the aesthetics ofthe area. No
Mtil; t;rd;.;;;;;;"Fr. I
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Fig.2.5 (D): Masonry Brn
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T
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Flg. 2.5 (c): Typica, Dhatao
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I Collection and prccessing
I
of Sotid Wastes 31
refl ecdng srmilar aritude are
also common e.s.
t.i,-1yii., rt;;,:*.ii]'ii'"li;ElJilNA (Bu;rd AbsoruieivNothinsAn)ryhere
"f.io.
A propertl mainrained tran f.r. iturton
r _.neseshoutdbesited\*i,t,in.".,|..",t,o,,rll1,l-o.tcreareunh)gienicorinsanilar)condirions.
ac-
s
;i..;;;
eouble and useFfriero,,
sio
JJlcn"ers'
I ransier srarions should be aesrheri.ally
that *asres srored are nor open ro ar,.nosphere.
t TRANSPoRTATIoN
-l
oF Msw
ransporlaiion of municipal solid wasre.
ro'drsposat to processing units or
inc ludes carrying wastes from
at ldndfill sites. I ransponation
lransfer statio,s
I
etiecttre and efficienl These are of\arious s).stems should be cosr
types e.g. Hauled Conrainer
statronery Container System aSCS) Sysrem 1HCSl,
InahauledcontainersJstemonl\ oneD€
needed to drire the vehrcle and ior
and unloading olconia';:;;. ;o-'^J":H:Y-js loading
ae,acrring ani crrarn, o.:;;;;;;;;;;#,ilT;nr",:il::li:1i,':_.X;1".:,,1"r arachins and
/
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I
32 A Toxbook ol Solid Wastes Managdnent I
COLLECTION ROUTES
Cost oftransportation fo.ms a substa.tial part ofthe oveiall budget in the wastes management
s)'stem. The transportation route ofvehicles should therefore be carefitlly optimized both
I
from environmenlal and economic point ofview.
Routes may be optimized on the basis ofexperience and intuition or by observing some
simple rules e.g. avoiding repetitious travel ofvehicles, oravoiding peak hours.
I
Alieinatively, a model may be developed utilizing Geographic Inforhation System (GIS)
based on computer analysis oftravel data to obtain aaoptimal route.
A number of possible altematives are first identified and then keeping in view the constraints, I
the best possible environmental and econornic option (BPEEO) may be selected.
MATERIAL SEPARATION
rip.
I
Segregation and separation of reusable/r€cyclable compooents ofsolid wastes is best carried
outatthe source ofits generation. However, special equipment may be installedand facjlities I
I
created at suitable locations e.g. near tl:lnsfer stations. Such facilities are commonly developed
in manycountries. Material sepaEtion can also be caried out at the site of wastes processing
units to separate out commingled MSW into usable components. Waste components such as
t
paper, plastics, glass. and hetals can be recovered from MSW for manufacturingnew products.
The cost ofmanufacturing such products from recovered waste components is usually onty a
fraction ofthe cost incured in manufacturing it from raw materials. The organjc portions of
solid wasles can be recovered as a feedstock forrcomposting for olher biological processes
or as refuse derived fuel for use in thermal processingand forenergy recovery.
Many oflhe segregaled components can be sold off to eam signifr cant revenues substanrially
offsettingthe cost ofwaste management. Some operations commonly employed for material I
I
separation are as follo$si
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T
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r
Collectioh and prcc€ssing ol
Solicl4astes 33
t. Density Separation
2. Ejecrk and Magneric Field Separation
3. rJensttlcation
I Density Separatioh
Marerials are separated by lheir resDecrivr
r
are used t.
mare,iats. th.se a.. gene;",];:;;;;.1-ttoltate our Iighler material from the heavy
sord wasre r. passed th,orgt u ,,ron" flom elass commrngied municipal
cunenr q hire t;e heavie;
.rrr1l-lfa:1lc:
arr' Lishrer mareriar moves wirh rhe air
;;i;;; ;;ii:;il::' "r
I orJ;'*,t ;;:;
se,rre ro the bonom componenrs
";;,,;:l,iit,fll,l,i,",jlj,iiili;,X,luuier
Electric and Magnetic Field Separation
Matedahare separated b) their electosratic
cha
I
magneric propenies Tlpical applicarions
include separarion offerr;r;;;;:;il; fit-id tommingled wastes Marerialsarigenerally
separared alter shreddint.; ,,;;;"1,#;1,:" based on conve)or belr me-chanism
rs shown in rie. 2 o sepa,^,";:;;i;
;;:.;:;:'Jiraror
,aSneric s)srems r arso known as
,r.a io ,".o,.i;;;;;, ;"i.;r"il'*" scaiping,
I ",. "rro
'r'#r:nT,
.lr
'L':d"
"i f al
€r
d!
Fig.2.6: Nlagneltc Separaror based
on Conveyor Bell Mechanism
I
I
34 A Texbook of Solict Wastes Managenent
Densitication
I
Densification or compaclion is carried out to increase the
so as to reduce transporration volumes and ro racitirat.
density ofrecovered matedals
storage.'vaii;;; t;;;;iqr*'..g. I
I
baling, cutring, pelletingarc available fordensificurio" ofOotf,
rf,?.orrnLg-f.i i..'"1"1g.,"a
municipal solid wastes.
Typical applicalions include:
(i) ofbaling for card board. paper. plasrics. aluminuft cans;
I
use
(ii) ofcubing and pellerr'ng for the production ofrefr.rse derived
use
fuel (RDF).
Baling is a compaclion process usually canied our under
high pressure e.g. I0O_150
t:ns m?.by using mechanic-at equipmenrs caled balers. Materiats-iik'e
atumrnum caxs are usuall) baled to reduce their volume,
Oisk
r
Shredded sotid
r Size Separation
Marerlals are separated by size and shape characteristics,
r
&osl commonly, by the use of
screens. Tt picalll. screeninp is carriert orrt
. to remove oversized materials:
. to remove undersized materials:
I .
.
.
to separaie out paper, piastic and other iight materials
glass and metals:
to seDarare lhe $a5re into li?ht combustible and heav]
from heavv materjals e.g.
non.or_buslible fracti.ns:
r
ro sepdra:e 9,as(. 5ilr and sa.,d .rom combusribie
material; and
. io remove large siones, iocks and other oversized
material from excavated
construcl;on site, soil ar
r
Various 1) pes of screens used commonly for this pu.pose
inclrrde i
(i) reciprocating screens;
(ii) troIxmelst and
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36 A Texrbook of Solid Wastes Management I
Recip.ocating Screens: Reciprocatjng screens (also known asvibrating screens) are used
for removal ofundersized materials from the rnunicipal solid wastes. Thise screens can be
designed to vibiate,.vertically or laterally_ tngeneral, inciined reciprocating screens which
I
move venicall, are Used.
Trommels: Trommels or rotatory scteens are used to segregate the municipat solid waste I
I
into various size fractions. The material is direcled to the inclined rorati;g disc screen
which tumbles overthe scrcen. The smaller sized fraction passes through the screen while
'
the oversized material is retained on the screen and is collected separaieiy.
DiscScreeDs:ltconsistsofanumberoipai.;eldiscsinsralledataceftainDitchona
horizontal shaft. Material to be segregated is fed on the rop ofdiscs. The undersiz;d ma.erjal
passes throughthe space between lhe discs and reaches the bottom.
The oversized materials
I
de overthe top ofdiscs and is collected separately. The pitch ofthe discs can
to separate out different sizes.
MATERIAL HANOLING
be adjusted
I
Affer separalion and size reduction, material has to be transferred for storage or to the
different processing/disposai facilities. Maleriai handling is rhe transfer anJstorase of I
I
reco!e.ed componenls and residues. Typical applicarions include:
(i) Conveyors forthe transport recovered materials and residues;and
(ii) rolling stock such as forklifts, frontend loaders, and various types oftrucks for
I
the movement ofrecovered materials and residues.
Weighing Mechanism
Weighing facility is requiredat resource recovery facilities to weigh the amount ofmunicipal
solid wastes received, materials recovered. and for w€ighingthe mate.ials soid ordisposed
I
off Various types ofscales are used for weighing different materials. A weigh_bridge is
required for weighing a truck and small-scaleplatform balances are required to weigi
smaller components.
the I
Storage Facilities
Material storage facility is an essential requircment a! aresource recovery centre. Matedals I
are stored a! various stages till the separated materials and residues are finally disposed
off The space required lor such facilities depends upon the amount ofwastestote handied
ard the efficiency ofresource recovery centre. The space requirement is optimized by I
I
synchronizing various operations so that storage time is minimal.
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Collection anc! ptocessing ol Solid
Wastes 3t
Selection of Equipment and Facilities
Rasre processing and maErial handjing
requires alarge number ofequipmenr
e e. screens. shredders. baler. air ctassir.i.R f^,t _I6: ..^-; and machinerv
are expensive and need," ;;;;;;-,;dft,iJXljli;ji,?r.ill,lj.Xi,Ii::i::il:ffJ.:
necessal tharduecare is hken in the purchase
ard sgbseo uem m";nro,,'"""
setecrion of appropriar..q,;pn'.r, *a phy.t.ur ^;;*^ _:,:l:-l
i;;;;;:;lilffi ff ;$:;ill,Hlii;
rs mosl important. Facrors considered
irI evaluating the processing equipmenr are briefly
Jisc,ssed belowr
. Capabitit) ,nd Retiabititv: The
'b"'" er:Pos:d.eq.uipmenl should be capable ofserving
r
r
ue aesign.a ror
u""pt"a ti u" u, exce,rent straresv
,",:i:i,:?:i;1i::ffil::,:i:ffiiil::r:Y:""ttvlralsoconservesthenarurarresour(es
una tananrrsp-,.e. o,.i;r-n;:;1i,.;;1"':t''*s municipal-Iubbish is recycled' reused
or used ro provide energy. 41Inor, arr.!fl9p€'s
I
has passed la\rs eskorishins recvclins
o. ,"ar"rion ,urg.', uifi.; ;;;;;;"r"*
i#;::'' '' "sAvolume throusr recot er1
:o-;o ". iii,,.;;.;:;;.d'til'j:.1:sres
"i'r,"and rec) cr.. .o..,r,"n ,*o.,,1v,I1;l:::::::,:i::,i::]:iisration 'ecvcling
bv
m-anasemenr on wiste
ofpaperandplastics.Thecove.nm.nr.ri ''' 'avov!I JcPa'r I(c)€res more than half
t"'.;;;;;;;; :.:;;ir::'i:J;::1,,:.:::;:l::::;:Tess
&
prograrns ror
I
out orficialr)' Private raspickers are
acrivery engag; in thi;
*,
;;;.;. ;;;r;;;::]rred
via'""i ipi'"i"p'r,",;::;;:, r'1"ff #:Ti[J:ff i"T:';:i[::Til:i.:,f li:i::
r
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38
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ATexbook of Solid Wastes Matagenent
jtems can be converted into..olyester fibers, which can be usedto manufacture carpets etc,
Japan probably is the leader;ir such techn;ques. Glass bottles are pulverized into fragments
or powder and then mixed wirh clay. The mixture isthen used for manufacturing of various
household items. Kitchen scraps are converted inlo fertilizers for farmers. Waste paper is
used for making various de.orative items. Waste cooking oil is used for making soaps.
I
It is a general percepiion thatrecycled means that the end product is inferior in quality.
However products are made from recycled materials are less costly and ofgood quality
provided ihe manufacturing methods are sujtably selected. The Negoro Sangyo Co. Ltd., I
one ofthe companies in Japan deaiing with recycled products, follows a 'cradie lo grav€
approachto p.oducts. It staned making its own.aw material from old plastics, and uses this
malerialto make new products e.g. carpettiles. I
I
Recycling ofglass metals is carried out in many ways. It can be cleansed and reused, or
it can becrushed and melted to make newproducts. Glass mustoften be separated by coloi
fcr reuse.
Crystal Clay Co. ofTokyo has developed a process to fuse glass particles to clay. The
company manufactures a newtype ofceramic tile blockthat can be used to pave sidewalks
and as sidings on buildings. These 'Crystal Clay Blocks' (naned after the compa.y) offer
numerous beirefils. They contain fragments ofwaste glass ofdifierent colom. The blocks
I
contain 709i, glass, reducingthe amounlofclay used, theteby protecting avaluable natural
resource. Under a I]ew manufacturing process, the blocks are fired al i000'C, which is
200 'C lower than the earlier system. Apa.! ftom saving energy it also reduces the carbon I
dioxide emission by 26%.
Tlre recyclable components of MSW in Delhi conslituies to about 120% oftotal volume
(Fig.2.9). The marketvalue ofrecyclable haterials ftcovered from municipalsolid wastes I
I
runs into millions of rupees, lt makes economic sense to recoverthese materials for reuse.
Such recovery wili also result in safeguarding the environment, saving the energy, conservation
ofnatural resources, and reduction in the final residuals for landfills.
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THEFMAL CONVERSION
Fig. 2.9: componenls oi MSW in Oeihi
I
Thermal conversion ofsolid'rraste includes transformation ofwastes into gasedus, liiluid,
and soijd conversion products. The process also generates energy due to burning oiwaste
Co bustion or IncineBtion,
maierials, Thermal processing also results in *rste volume reduction,
I
Pyrolysis, and Casificalionare theiechniques commonly employbd forthermal conversions.
I residues in lhe form ofash are obtained. Energy can be recoveaed by heat exchange from
ihe combustion gases. The buining ofsolid wastes is usually accomplistled in incinerators.
Diferenttypes oiincinerato* are Mass Fired, RDF Fired, Fluidized Bed type. The lnciflerator
I insriture ofAmerica (llA) classifies incinerable wastes into seven types (Table 2.1).
The Institute (llA) also sepa.ates incinerators inlo nine classes accolding to ahejr use and size
r
iTable 2.2). Minimum consnuction and perfomance standards for each class arc also prescrjbed.
Dlass Fired Incineration: Mass fired combustion systems are designed to incinerate
rhe municipal solid wastes as coliecied without oi with very liltle prior processing. The
energy produced by mass fired combustion system depends upon the composition ofmunicipal
I
Heat ,ecovery
|
I 1207.-2007"
t
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RDF Based tDcineration: In RDF fired co$bustion syslem. processed soiid waste refuse
I derived fuel (RDF) is burnt. Various components e.g. metals, glass and other noncombustibie
materials are removed to produce RDF. Since RDF is more homogeneous the system is
better conrolled for combustion and more energy is recoved.
r Fluidized Bed Incineration: A flLidized bed type combustion system includes a steel
verlical cylinder, lined inside with refractory bricks, and has a sand bed. Air nozzles called
tuyeres are provided to injecl air at high pressure. Fig. 2.11 shows a typical fluidized bed
I incinerator Solid fuel (or RDF) is injected into the cylinder. Auxiliary fuels such as natural
gas or oils may be used initially to increase the temperature ofthe bed uplo operational
Ievel which is about 14501o 1750"F. This system can also be used for burning ofsewage
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40 ATe\tbook of Sotid Wastes Managemant
I
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Trble 2.1: Clalsifi cation of Incinerable Wastes
I
S@rces: Commercial and
Refire
garbage
Rubbish and
Rubbish5o743OO0rr00 I
I
Garbage 50
Sorrresr Dorhestic Moislure
Content 50
3 9+"c. Ca*age65 5 2s00 t5o0
Anirnal ard vegeEble
Srrner:Hotels,
Rubbish 35
Moistu E
3000
I
I
r€s&uants, mai(ets, Content 70
inst'Etional, commercial
and clubs
a AdrElsoleedoEali5 Anirnatrd 5
Carcasses. organs, solid
;;;J;X;:--** ffifl,*
sorE r Hospitars,
hrlEl
Moist!,e
1000 3000 8000
(sooo,rimar,)
(3000 secondarv) I
5
laboralories,abattoirs,
Gasmus, Liquid, or
Content85
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Collectian ancl ptocassing ot Solid Wastes 41
Trbl€ 2.2: Standards ofConsrrucrion and performance
for Different Ctasses oitncinerators
"rs
b
rs
",
n
rnc'n€Btorr)' €
"''."
i.'",,g
a irecr-rJ ino
*;;;;;;;;,ffi
rrue-ted. srngle chaftber incinemtoE ryirh
se
havinga primar] chamber !orumc
J'iJ:Tj*
more than: cu fl buming are, forrlpe:
b] one veftical flue
wasre. Ihis
I
is ed
tun.ridr
".,,, d;ffi;;;#;:il';T#HI:J,t:f; i :ffi I$ l"$#:jl":frj.,,T:
IIA Chure.fed. s ingle chamber incineHor for apanrnem
buitdings uirh moE har 2cu ft buminsaE
sui,jble rorqpe Ior2 sa!re.
repdte ^-orrecomn;nded
fo,ndu;"J,",,r1,r";;;.;;;";;";;:ffi;
flue for cnrq ing deemissions o aEnospheE sprc!ide!.
T III
Iv
ufecr.teed wirh a bu]njng rare of r00 Ib ] ano suitabje
Direct-feed with a bumins rzte of75 lb,4\ more
ior buming rype O. r , or 2 wask *"
suirable for b"_dG t;;;;
I
vunicrpal incinerdo^ s,i,bre for r,,e 0. l . 2. or J wasre or a c.mbinaiior of .,e... Rared in tons
perhouror rons per da!.
VI CremaoD and parlmtogcal incineBtors ruirabje
for q?e 4 wasre.
vIl Lresrgred torspecifrc b) -produfl *aste. iwe
5 or6
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t 1
Uquid
Temperature: Tempemture ill the incinerator is maintained such that all the components in
lhe waste decompose to releasethe volatile fraction andto oxidize the fixed carbon fraction
ofwastes. All contaminants such as pathogens, volatile hydrocarbons, smoke and gases
(e.g. CO) should be complerely oxidized.
I
I
Tu rbu len.€t ProDer mixing of air wirh the solid wastes is necessary for complete combustion_
Turbulence is iherefoie created b],applying a high cu.rent ofair in the form ofswirling
motion. In rotary kiln type incinerators lhe movement ofkiln itselfprovides th€ mixing
effect. ln smai I static incinerators, raking is required at regular intervals for creating tu6ulence.
Excessive Stack Ernission s: Excessive emission iales are caused dueto avaaiety ofreasons
I
e-9. excessiveinflltration air, overcharging ofwaste, excessive negative draf! in lhe primary
chamber, low temperature in secondary chamber. Proper maintenance oftemperature in
both Frimary and secondar, chambers and controlled aii infiltration can help reducethe I
I
emission rates.
Black Smoke: Black smoke generally indicates the presence ofunburnt carbon, as a result
ofincomplete combustion ofwaste rnaterials. This could be due to overcharging olwaste
or poor temperature conditions in the chambers ordue to less amount ofair available than
is required for complete combustion. Large quantities ofhighly combustible materials e.g.
plastics, rubber in the waste may also genemte excessive blacksmoke. Genelally such materials
I
musi consiitute less than l0 percent ofthe total charge.
White Smoke: Aerosols present in the emission may rcsult i, white smoke. Excess air I
I
entering the incineralor may cause micron sized particle to move out through the stack.
Proper air and temperature cont.ol intlre chambers may reduce this problem. White smoke
is also formed due lo finely divided noncombustible minemls present in the waste stream.
Paper bags, pigments or other metallic oxides, and minerals such as calcium chloride also
generate fine inorganic particulate formingwhite smoke-
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I
Collsclion anal Processing of Sotid Wastes 4
Leakage ofSmoke from Charging Door: Leakage ofsmoke thrcugh charging doors or
orher openings in lhe combustion chamber is usually due to excessive air pressure inside
the primary chambe!. Overcharging ofwasles orexcessive amountofhighly volatile matters
presenl in the waste stream also conlribute to such problens.
Pyrolysis
Pyrolysis is a chemical change due to partial combustion ofsolid wastes in the absence of
oxygen.It is also kno\ n as thermal decomposition \yherc extemal soutce ofheat is employed.
Pyrolysis is an endothermic process andrequires heat from a, extemal source. Therefore it
is also termed as dest.uctive distillation. It yields gaseous, liquid and solid fractions as follows:
. Gas f.action includes hydrogen, methane, carbon rnonoxide and carbon dioxide.
. Liquid fraction includes tar or oil stream containing acetic acld, acetone, and methanol.
. Solid fract;on includes char, consisting ofcarbon and other inert materials originallv
present in MSW
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44 ATextbook ot Satid Wastis Management
T
Ihe proponion ot gases. liquid and
p)rol.rsis is carried our.
increases. rhe arnounr
char obtained depends upon the
T\pical p\roivsis r --!Jr
ofg;;or, .Jrr;;;rl
temperature at whrch
' Br Ycrr 11t r 18. z' t 2' As lemDerarure
0..,.ur", th..n",g1 .o"ni.,,"irr,,,i,iiil'il'""""'es$hilefiequanlioofliouidandchar
I
lar or oils is :1240 LJ
Gasification
Lo -,..sisabout26l00KJ m andlhaiofpyrol\ric
I
Casificalion is a process in which
o\J gen buI in Iesser amornr rhon
Dartiat , is carrted oul in the presence of
thar i. stoi.h!ombrstion required
rne 5eJr-suslaini-e p"niail;;il,;;;,r'::;;:':'eEicall) rorcomplete combu:rion I
and carbon monoiide *h;;;:;
6 0 vJ m . !\ hen p..rre
;;il.: #
oti;;';r*;X,:t
roaoour129r.r1e^/,_:T._j-,,
":|o
oblain combusrible
sases e's hvdrosen
Iheenerg)conrenrisintherangeof5.iro
anl,nslead ofair. the en..g1co:t.ni
. , "u,k.r!. compo-srtron of combu.tible gas. inc.ea"., I
i.a'rlrcatron
process conrarn: C O- r tOio obraineo from
r Cu r:u,.0,. H? I t5oo r. and C Ha r20o), and
r\t an0 other Lrace gase). Fig.2 tlsho$as\hemaricd;agrarnofagasifi";,;;;,;;-, some
I
I
I
I
I
A F€celv'ng E preh€ater
b usrntegErof F Fetoft
i:#?Xfl,
Nilc'tonaPp.'",6b' I
!:,ro
u Lnarcrng
G Gas ouriorlrom,ai.d
H Clrargrnq M |i€at
o conr;re*or
exchanger p Gas tank rorstarl-u.
O Stag sito I
Pelletizatior
FIg. 2.13: Typicat casj,ication proc€ss
I
Pelletization is a process
"*'i*' in Ms'\
of converunp d.
generar] abour I inche( in r""-,a
^-, ; ,--::"i:
",;.;o;il:i:'r';.;;1T
to]id wasle inlo small pellers of
j; :#J,:;J,."H[:::
size
lX1fi :::T[::::r:
I
I,rnotng rngredients e.g. Jime
rhes. a,e al.o.arreo
is mixed ro rhr
.e"r.,".;.,1;"i;;;;ilXj:':9ded
mareriar
and ruer perets are made.
robet5-20rons,OO,""r"iVli.,-,,,,\r}). lheaverageRDFproductionrateisfound I
I
T
t
Coltection anct ptocessing
ot Solid Wastes 45
AIOLOGICAL PNOCESSING
*$si[##****t*na+,**ffi
r:s,rl*#**[l**s*-:,
Organic Fraction ofMSW
+ O, + Nutrients +
Microorganisms
r g;rn6$$r*N**-#*,*rffi
r ,ll11T,,T:,r"
paremeters
in corhpostihe
I
i
I
I
46 A Textbcok of Solid Wastes Management I
value being 25 : i. in general, the niirogen present in lhe organic fraction ofwaste wjll be
available for biodegradation. but all the carbon available may not be biode$adable. Cn{
ratios for some ofthe organic fraclions ofmunicipal solid wastes are shown in Table 2.4.
I
C/N mtio can be adj usted by blending ofwastes ofhigh C/N ratio (e.g. saw dust, paper) with
the wastes of iow CN ratio (e.g. yard wasxes raw activated sludge).
50-550C
I
Blending and Seeding Conrolled by CN clio
AirSupply Frcquent ruming of compost T
Mixing and Tuhing Fi6t nr.n on the ihird day then on altemative days
Pathogen Control
Odor
Maintain a tempe€tu'E of final compost @ 70 cC for
to 2 hours
Coftrolled by air supply
1
t
pH Control: The pH duringthe composting process varies with lime. Initialiy when organic
components ofwastes are broken down biologically they convefi inio organic acids and r
bring down the pH level to less than 5. The desirable value ofpH for composling is between
? and 7.5. IfpH value decreases lo less than 4.5 it reduces the rate ofbioiogical conve.sion.
lf it rises to more than 8.5, some nitrogen is Iost as ammonia, I
Trble 2.4: Carbon-Nit.ogen Ratio ofVa.ious MSW Componenrs
Blending snd Seeding: Blending is carried out ro achieve the required moisture content
I
and C,rN ralio. Laboratory tests ate carried out in order to determine the proporlions of
wastes for blending. Seeding is the process ofadding microorganism culture to the wastes
to be composted. This is required to accelerate the biological decomposition ofwastes.
I
I
I
I
:
GeDerally a small quantity ofactivated sewage sludge is blended with the wastes for increasing
the rate ofcomposting process.
Mixing and Turning: Mixing and tuming are two important operations ofcomposting process.
Mixing is carried out to obtain a homogeneous mixture ofbiodegradable components. lt
also helps in uniform distribution ofnutrients and microorganisfis in the wasles, so as to
accelerate the biologjcal tiarrsforination of wastes.
Turning ofsolid wastes is earriedout at regular interval. This p.ovides suflicient amount
ofair required for aerobic conversion ofsolid waste. It is also carried out to maintain the
moisture content unifoim through the mass ofcomposting material. Regular, periodic tuming
aDd moisture control prevenls drying, caking, and air channeling in the composting material.
Pathogens Control: The control ofpathogens is important in the design ofany composting
system as their presence is a health hazard. The most important pardirete. in pathogen control
is the ambient Iemperature in the compostiog system. Most ofthe pathogens die off at a
lemperature of55 degree Celsius, though some may survive even at lemperature nore than
60oC. Pathogens can be completely removed from the composting material by maintaining
its tenperature at about 70'C for I lo 2 hours.
Odor Control: Odor control in the composting is necessar), as otherwise it will create
I nuisance in the neighborhood. Odor is produced due to insufficien! supply ofoxygen to the
wastes dudng their biodegradation. Lack ofoxygen in the wastes rcsults ir anaerobic conditions
r Benerating various malodorous o.ganic acids and gases such as arnmonia, and hydrogen sulfide.
Large sized panicles present in the wastes also prcvent flow ofair. Waste should therefore
be properly shredded, and converted into small sized particles, before these are composted.
I
to supply the oxyBen. Iurning is usually caried out for this purpose. In a static system
wastes are kepi static while the air is supplied by mechanical means such as blowers. Three
main methods ofcomposting are:
I (i)
(ii)
(iii)
windrow method,
sratic pile melhod, and
r
in-vessel method.
WiDdrov Metbod: Windrows of\rastes ofabour 1.5 to 2m heighr and 4 to 5 m w idlh are
prepared. Waste materials are shredded before haking windrows. The size ofwindro\rs
also depend upon the size ofequipnent available for tuming. A typical equipment used for
I turning of municipal solid wasle at a compost plant in New Delhi is shown in Fig. 2.14.
r
r
I
I
48 A Tenboak of Solid Wastes Managehen!
I
Turning is carried out at regurar intervars. The rnoisture content is
to 60 percent This sysrem takes about fourto six weeks to convert
compost. The composled material obtained isthen cured (i.e. allowed
mainrained between 50
rrre
to stana
w".t. ,r
"j.ln,o
"t..i ir.rrn;ng)
*ttrort
I
for a period oftwo to th.ee weeks for complete stabilization.
T
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I
Fi9.2.14: Equipmenr used torTurning ot Wastes n Windrows
I
Static Pile Method: In static pile melhod the waste is kept in sratrc piles.
Ihese piles are
provided wirh ag dofperforaredpipes,whichareusedtosupplltheiir.airmarU'efreatea
to the desired temperature. This method is faster and provide bener
I
method. The wasle malerials are composted in a perjod oftwo to four
controf tla, tfie *ina..*
*eets.. It is ttren
cured for a further period oftwo to three weeks T
I
In-vessel Method: As the name suggest in-vessel compostjng is carried
out in a ciosed
container. Various types ofvessels or containers e.g. vertical cylinders.
ho.izontat cylinJ"r",
reclanguiar or ciiculartanks can be used for composting. Mechanicalagit"tora
foa
mixing of composting marerials. Air can be supplied throigh nozzles coni"o"a "ae'ua"d
*irt tfoi*r.
The advantage ofthis system is a high degree of conrrol &er temperatur.,
This system is therefore popuiar, especjally in developed counrries.
one to t\\,o weeks for converting waste into compost but a
uir, pU, Jo, .r".
The sysrem tafes aUout
I
longer curing ieriod, about four
to ten weeks. lor complete stabilization.
Properties ot Compost
I
Compost,the finalend product of composting, is be$erthan a chemicalfenilizer
purposes. It is also ecofriendly and economically atractive.
forasriculture
Good qual;r) composr;h;u be
blackish brown in color uith an earthy odor It should be slightly moist
wiih pH;"rg;;;;;;""
I
I
6.5 and 7.5. Il should atso not conGin excessive amounr ofheavGerais. The Mini it.y oii".ri.r_"nt
I
I
Collection and prccessjog of Sotid
Wastes 49
and Foresls. Govemment oflndia vide
irr Municipal-Wastesj Managemenr
_uuu has lard do* n St:rndards tor ComDost and Hardling, Rules,
,,",.
for il. safe applicaLio; ( table _2 S;.-.-....",
C:&run 20
C1rrcmium 20
Copper 300
Lean 500
500
Nickel l0
ZE 100
2500
-\eiglllrhood
especratl)
Compor,,n, O. u ,iu61.,offi
""n location an
tn resjdential areas. The
0 capaclt)
-r_' 'r oi
vr composl
wrxPUstPlants
plants is
accordingto!ieamounrofbiodegradabiecor
accordmp ro rhp 2n^,,Dr rs Desl
best determined
delermined
^
socieries and orher \ otunrary
generared in rhe area Residenrs
welfare
sasres trom households can
d*:;;;"';,'p"l:lt in this lasks Tle enrire biodegmdable
be colle.ted a_Pclpate ren ed to the nearb) .ompos'i-ng
Tlris * ittm,nimize the Ean.p";";";:;,;;;:T."jns un ir.
orparks. gardens and ro-;,";;;il;;? ;;:; iffi li::j|i:'.'n'"To:" *"'^o toiaevero-pnenr
I Anaerobic Co.lversion
r 'ori-a "".4"i
(j) preparation ofthe organic fraction o-fsoijd
incluoes receir ing. soning. separatron
I
o
I componerrol'municipalsolidqaste)rFip:elhod!sedforbiologicalconversionoforganic
and soii ,re fiired in a'pi ; i;;1,:ij;;;:"',']')
"o
t.o,",u,.o
rnrhi'melhod ahernat'laler.otiusr.
p,.,J,ir;;;.r;r:;";,:lJiiji,:'ffj":;i'.HJ:::;:l:l,i;Ji::Jl:
! ln lrall) stabilized aerobicall)
ox)genpresenrinhepore.airi"como:sreir some arr in rhF r^,". ^r .,
as rhe.e exisl
"qru'hd5tcanosol"l'he
.,,,.i.",a,r,.","";,'.,,;;1" tj,lr;illl,lli,iili#j,T::["JilX.j:il:i;:::T:1,;:
I
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I
5o ATextbook of Solid wastes Managenent I
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t
vermiculture
Fig.2.'15: Bangalore Method ol Composlin!
I
Itis asimple, lowcost and appropriate biotechnology used for the stabilization of drganic
municipalsolid wasles usingearthworms or othel microorganisms. Eafthworms, particularlll
burrowing fpe consurne biodeg:adable organic matter and produce malerial termed as vermicasting'
I
which mainly consists ofea(hworm excreta. This process includes:
(i)
(li)
separatio, of biodegradable fraction of MSw
maintenance ofp.oper moisture and lemperature;
t
(iii)addilion ofminerals and selecled burro*ingtype ofearth worms;and
(;v) sieving !he vermicasling. The vemicasting p.oduction is formed at the rate of75 kg
per 1000 kg ofMSW.
I
CHEMICAL PROCESSING
Chemical transformalion is the process of convers;on of organic fraclion of wasles into
I
various useful compounds such as glucose. synlhetic oils, gases etc. Glucose is recovered
fiom wastes containing cellulose e.g. paper. in lhis system hydrolysis ofwaste with a weak
acid is carried out. The suspension thus obtained is heated al tempe.atures rairging belween
180 to 230'C, under a small pressure. Cellulose is converled to glucose and sugars.
I
(C6Hr0O5), (Cellulose) + H,O + acid -+ nC6Hr206 (glucose)
Methanol, often used as an alternative fuel, can also be obtained from wastes through I
I
chemical processing. Methane gas can be converted into methanol by cataiysis.
CHl + H?O - Catalyst -+ CO + 3Hr
co + 2H2 + Catalyst -+ CHroH
Ihe process involves conversion ofmethane by reacting with steam in the presence ofa
catalystto form carbon monoxide and hydrogen. Both carbon monoxide and hydrogen react
io form methanol. The syslem oitransformation ofwasles chemically is expensive- I
E xa m p
provided
EXAMPLES
le 2. I : For separation and co llection of iteds, thtee recyc I ing coniainers have been
10 each residenl ofa communily. Residents separate newspapers & cardboard,
t
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I
Collection an.l Ptocsssing ot Solielwastes 51
,",T:Hy.t:l:,:],:l-,eist.132-kg.czp;tatday.'ftietotatnumberofhousesinthecommuniry
rs r zUU (4, J .5 residents per house.
60010 of houses. are expected to participate program.
in th is
Assuming 80% material separation rate, determlne:
(i) the proportion ofthe space required fo. each group of materials
in the collection
vehicle, and
(ii) the number oft.i ps per week rcquired ifthe size olthe collection
vehicle is 11.5 m3
Solution:
(/) Dererminarion ofthe propo(ion ofspace required
Each 100 kgof MSWhasthefollowingcomponen!
Recyclable Co panents Total Weight (kg) Seporuble Weight (kg)
Generation of
= 10937.78 x 0.80 ,0.20 = 1750.04 Ks/week
cdrdboard -
= i0552.48 : 0.064 = 1955.358 Kg/week
I
Generation of rec),clable cardboard
= 1955.38 x 0.80 = 1564.28 Kg/week
Genera!ion of recyclable (newspaper + cardboardj
I
= 1750.04 + 1564.28 = 3314.32 Kg/week
Total space required for (volume of) ne\yspaperand cardboard
lil4.32
I
- _.r.,610
(5.728+5.12)
= 50.99 m3/week
"'
Space required fornewspaper and cardboard in one
I
I
tiip
3.05
=il:-,)-3!o'Il5
Number oftrips
= 5.6 t2 mr
=
so oo
I
ffi=e.08
Say 9 llips,,week.
Example 2.2: Solid wanes is collected from a locality using a hauled_container
I
ll sysrem. r he dala perl.ining to the collection actirities, are
I 5 mrn I
I
"ontainer
Average time required to drive the vehicle betlr,een consecutjve
=jOrnin
containers = i ,i,
Round trip haul disiance
Time required to pick up loaded container and to unload empty
confain", : ;: :1
Arsire time (per trip)
Haulconstant coefficients
= 8 mrn
a = 0.016 h/trip I
I
Determine the numberoftips of.he collection vehicle per aay, assum'ing
, tr;r?;'r"1j.lff
and off.t oure facror equal to 0.1S.
Solution:
The pick up time per rrip is given
where
Ph,,=pc+uc+dbc
pc
as:
I
Capacity ofcontainer = 8 mrlrrip
Container utilization factor = 0.67 .
Container pickup time = 2 min/rrip
Container unloading time = 2 minlrrip
I
r
54 ATextbook ol Solicl Wasles Managerna
t
6tr
(pc=!c=2miqgiven)
Let MRF to be located al a distance of, Km away from lhe source of MSW.
The tim erequired per trip, 1r., is
Th,.=Ph,.+s+a+bl
1,)
- 0.131- 6-0.022 -r2\)0.014
I
= (0.2082 + 0.028x) h/lrip
The time required per week
= Ir,- N" = 56 (0.2083 + 0.02E x) h/\,/eek
I
Assuming 8 hours of working day and an off-route factor
week can be calculated as:
as 0.15, the time required per
I
." =
"-m
=
r -fl6
(o 2oE3+ 0.028')
I
T
I
Collecion anc! Pbcessing ol Solkl Wasles 55
Thus r= 12.41 Km
Therefore. the MRF should be located within 12 41 Km ofthe source ofMsw
rlxamDle 2.4: A commingled MSW havingparticles of average size 3Oo mm'
is to be reduced
150- mm to 50 mm.
56 ATexbook of Solid Wastes Manegamant
Solution:
The energy consumption can be calculated by using Kick,s Law.
as foll-o\,rs: I
E= crnl+i
t=
'k
:o=cr,l]I)
ofspecific eners/,
I
i.e.,
C= 18.204 hp-h/ron
Therefore, the energy consumption mte,
I
/in^\
t = 182041(:::50.1 = 12618 hp ton T
The energy required by pianr
= E0:32.61
= 2609 hp
= 4.146 \ 2609 = 1947 KW say about 2 N{egawatt
I
Example 2.5: Glass is separated from a comrningled MSW (having g%
w^ith_a irommel screen, capacity l0o lons,/hour. Dere.mine the rec6ve"
efficiency of the.screen, if the weighr of underilow ana weigtu
ofglass conten!)
."[. ,".;i".
I
irir.;;;;;fff
""a
olgtass
have been experimentally found ro be lo tons/hour and ?.2-tons/h'ouirer;;;;,".i.--"'
Solution:
"" I
Le1, Xrepresents the MSW. and
Frepresents rhe Class to be separaled from MSW
The fracrion of$eighr of MS\\ and Glass. Xo and fo will
be a) follows:
I
Xo= 100-8=92ton,/h
fo = 8 ton/h
The total overflow ofthe screen.
= i00 - l0
I
= 90 ton/h
Fracrion ofGlass in the screen
l,r =8
orerflo\
7.2=0.8ron/h
Fraction ofMSW in the screen overflow,
,
I
X, = 90-0.8 = 89.2 ton/h
Total uoderflow ofthe screen = l0ton/h (given)
Tolal fraction ofglass in the screen underfloq
I
f: = 7.2 ton/h (given)
The fraction ofMSW in the screen underflow.
X. =
l0 -7.2 = 2.8 ton/h
I
I
I
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Co action and Pt*essing of Sotid Wastes S?
=(4f .,oo
",
=(f),roo=eox
The purity ofMSW is given as:
,,*=(J+\.'oo
=(rffi) ',oo=,,,,*
The purity ofMSW is given as:
/v\
P= '2 l.rn6
'E \ Xr+ytl --
/ ,, \
=lzE;L)' 100 = 12%
r-fto.ii'r000=4ls6K8
I
I
58 Alextbook of Solid Wastes Managenanl
I
Total oxygen required.
= 1372.36 + 43.56 =
1415.92 Kg T
Assumingthat air contains
The amount ofair required,
23.015olo
I
Assuming the density ofair as ].2928 Kg/m3, the vollrne ofair required to oxidize
1000 Kg ofwastes,
6 t 16..28 --^. ^^ .
I
-IIII8=a/:r.u.r m-
Exrmple 2.7: Residential yard waste is to be composted mixed with some activated sludge I
I
from a wastewater lreatment plant. The compositions ofyard waste and that ofthe sludge
are as follows:
C,4..I ratio
Nitrogen Content
50%
0.8%
50 6.5
75o/o
60/.
I
Determine the proportions ofyard waste and sludgelo achieve
Solution:
a blended C,N ralio of25.
I
The percentage conposition ofyard wastes and sludge, I Kg each, can be determined as:
(i) For 1 Kg ofyard wastes
\\'arerconrenr. w- 0.50 . I = 0.50 Kg
I
Dry matter = I
Nirroeen conrenr- N =
- -::
luo
0.50 = 0.50 KC
. 050= 0001 Kg I
(,i) For I Kg ofSludge
/.\
Cdrbon corrent. C =i :lN
\ N/
Carbon contenl. C
/.\
=\N/
ilN=65.0.015=0.0975Kg
I
Nitroeen conrenr. N =
-
A
+^
IUU
,025 = 0015 Kg t
Let, i. Kg ofsludge is to be blended with I Kg ofyard wastes to achieve a C,N ratio of25
c
N
-
_ C in I Kgofyard$asles
- Nin lKgolyard*asres -
x{Cin I Kgofsludge,_r<
x(Nin I K8ofsludge)'-
t
= o
0.2 + 0.0975.!
oo4+o.ot5r
x = 0.36 Kg
-'- I
Therefore, yard waste and sludge have to be blended in the rBtio of 1 : 0.16
I
I
I
Collection and Processing al Solid Wastes 59
Exsmple 2.8: D€termine the amounl ofair required for complete combustion of 1000 kg
ofa waste having chemical composition as C60HejoaoN.
Solutions:
The molecular weight oforganic component ofwaste is,
= (60 x 12) +(9s * l) + (40 ' 16) + (lx i 4)
= 1469
Percentage disribution ofC, H, O, and N in the waste is as belotyl
Che ical Co ponent
C [(60x i2)11469] x 100 = 49.01
H [(95 r lr]4691x
100 = 6.47
o [(40x 1611469] : 100 = 43.57
N [(l x 14y1469]: 100 = 0.95
Netavailable hydrogen not bound as water,
,tl <,
= 6.41 - 5:* = 1.024%
Oxygen required for oxidali on of carbon in 1 0 00 Kg of waste can be dete rm ined by
using the following equation:
C+Or-+CO2
(12') (32) (44)
O: required - /l\1000
--- 4901\,i;=
ffi.]
12
l306.ql Kg
It Example2.9: Delerminethe heat energy available in the exhauslgases Seneraled from the
combustion of 150lons/day ofa MSW with energy content of 11,000 KJ,4g and the follo\ying
chemical composition
Elemmi
Percent by weight
C
28
HONSMoisturelnen
522412020
Assumethatlhe incinerator residue contains 5% carbon. The tempemtures ofthe entering
T
T
60 A Textbook ot Sotid Wastes Menagenent
:
=s-(.2.2s".
Percentage of net available h!drosen
H) drogen in bound war = izta I z ts"
^
Bornd \yalet = 22 +2.7 5",= 24 .j 5
Amount ofwater produced from combustion ofhydrogen
=
}ftff toozs' rso) = 303?s ronyday
Gross heal energy availabie = 150 l lOl)0 x 11000 = 1.65 x 109 KJid
Loss ofheat energy can be determined as:
s..\b.
I, Dle !o unbumt carbon 0.01579 x 1.5 105 \ 32789 = 7.j66
2. Duelo inieren!moisturr
a_2v15\to :420=726
0.2a75 x 1.5 \ .Jj :2420 = 8.98
3_ Due to moisrrre in bound warer
"orkday).
Dumbcr oftrips to disposatsireper d.y is 2 (8 hours
The speed timn of rrlck is 40 knrA. ard cotre"r"";.r,r.r"
L,r"iiiJ","rri i, i.r.
.'", I
J. Discuss lheissues rn!ojved in setectin8 a,ir€ forasoUa
wastes t.ansrer rac;t,,r. r"" *rO *.
cj\ ic aurhorilles deatwirh rle \iMBy s)ndrome.
4. Dcscribe various lypes ofvehicles used tor r ranspo'tation
disadvantages. ofMsw' Give their advantagcs and
I
5 . What are the main mnsiderar;on iD rhe optimizarion
of routes for transponation of MSW?
6 . What are the comnoo techn iques for Materiat Separarion? What
are its adv"ri";";;
T
7. cive suitab le techn iques for sepamrion ofpaper, gla"",rn.t"ls_a
tn"rtInar.ri"tiZ
I
I
I
Colectbn and Prccessing of €oliclwastes 61
8. Propose a recy.ling strategy for wastes ftom institutional area. Estimate the financial implications.
9. Ioran ideal recycling an d .ecovery program ofsolid uaste from a residential area, estimatethe
residuals thal willneed 10 be ultimately dispos€d offin landfill.
I0. Whar are the various wast€s processing systcms? Givetheir suitabil;1y for Processing ofdiffercnt
ryPes of wastes cod1ponen!s.
I I Describe various rypes of inciners.ors ard th€ factors affecting their efficiency.
i : . s,har are the common problems associated wilh incinerators? Suggest suilable precautions to prevent
lj. what is the basic difference between pyolysis and gasification? Give suhability ofthese techniques
14. what technique would you suggest for processing ofyard wastes? Give reasons
i5. Whar are the significant cortrol parameters in composling? C;ve lheir optimum values and the
methods for controlling the same.
16. Write shod notes or:
(,i) Chemicalcodversion
(iii) Bangalore Merhod ofComposting
(,v) Neigiborhood Composting
I 7. Exanline the solid uaste management system in you cily zone. D€sig, an inteerated lraste maragement
system forthe same.
I
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I
Chapter I
I
Disposal of Wastes on Land,fitt I
I
i
a
j
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Wastes that can not be processed together iyith the residues need to
be
I
safely dkposed off. The long-term options ofwastes disposal include disposal
on land, disposai deep below earth,s surface and dispoial in ocean bottoms.
Land disposal is the most widelyused pmctice alloterthe world. Howeve. I
I
dumping ol solid wastes on lafld has serious environmenlal impacrs. Mosr
important, the leachate thrcugh the waste infillrates the soi] contaminating
the ground\ ater. Frequenr outbreaks of\rater borne diseases esoecialli
during rhe rain) season have been reponed in developing counrriis. Lani
disposal should therefore be caried our in a properly deslgned Iandfill
an engineered landfill.
An eDgineered landfill h not a dump but is
i.e.
I
I
a \r.aste disposal facility designed
on scientific principles to protect the environjrent and public h;alth. ihis
chapter discusses various types oflandfilis, its main components and
the
I
various operations involved in its construction and maintenance. Desigl
of
a.suitable eachate management systen and ofa gas control systeri are
.l
discussed in subsequent chapters.
I
I
cornponents. Biological decomposition ofwastes occu$ due to bacleria
present in the waste or in the cover material. It slarts immediately
afler th;
disposalofwastes inthe landfill. As aresult ofihe combination oiphysical,
chemical and bioiogical processes, the landfi ll can be consjdered as a
I
naturai
biachemical reactor.
There are basically three stages ofwastes decomposition in a Iandfill i.e.
(i) aerobic decomposition;
a
I
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F Landfill 63
I
Disposal ofwastes on
L Aeroblc OecomPosltion
Aerobic decompositiot of wastes is caused by lhe acetogenic-aerob;c
microorganisms_
L
source ofoxygen is the initially entrapPed air during waste
l:
*ft"" i" *rif"tleoxyien is exhausted Aerobic decomposition ofwastes in a Iandfill
i.llrii.Ji""ii
".i .."f1 depth'aear the surface.lhe reactioo that takes placeduring aerobic
".lyis" as under.
decomposition
tr -
CzO + H2O + biomass (microorganisns) + heat
+ Panially biodegraded maierial
tr
Highlevelsof
fr,",*"it" i"f"i."a inthe process cont butes tothe formation ofleachateenvironment'
alo*ia" a."."l""sed *hich form carbonic acids creating an acidic
"uiUon
L Facultative OecomPosition
Once the oxygen content is alepleted in the landfill, facultative microorganisms
Oo.in"nt iniiiu'ting tt aecond phase i.e. the facultative (or nonmethanogenic)
become
d€composition'
L
tt
Anaeroblc DecomPositlon
and produce methane'
In ihis phase the anaerobic (methanogenic) bacteria become active
carboo dioxide and water. This p.ocess is relativeiy slow but continues
for many years'
votatite faty acias tormed earlierbecome substmte for methanogenic bacteria Consumpt;on
oith"r" o.ionic increases the pH level to 7-s Therefore the leachate become less
""1a. phase'
chemically aggressive. The followingare the general reaclions in this
t
H2 + CO2+ CH4 + H?O
Volatile Fatly Acids , CHa + CO?
gases produced in this phase
The dominantgas Produced inthis phase is methane Other
action results
in"tra. n;t.og"n i',a tydrogensulfide. Denitrification caused by the microbial
F
U A Texlbook ol Solid WasEs Managenent
in the production ofnitrogen, while the hydrogen sulfide is produced by sulfate reducing
bacteria.
The methane generated during this phase has high calo fic value and is therefore suitzble
forenergy recovery The commencement ofthjsphase may take six months to seveml yeam
afterdisposal ofwastes on landfill site dependingupon seveft parameters e.g. pH, temperature,
level ofcompaction etc. For maximum gas production the optimal range for pH should be
between 6.7 and 7.5, andtemperature between 30 - 35.C
TYPES OF LANDFILLS
Depending upon the area of land available and the method ofdisposal employed, iandlills
can be classified as trench landfills. area tandfills, and slope landfills.
Trench Landfills: Trench landfilt is the mosr widely used merhod oftandfilling (Fig. 3.1
a). In this system solid waste is disposed off in trenches or depressions below the njtural
ground leve1. These landfills are suitable for a.eas where natural or man-made deprcssions
are avaiiab le and water lable is very deep. Earth is excavated where suitable natuml depressions
are notavailable. The s,desand base oftrench landfill are lined with impermeable materjals
to protect the groundwater
Area Landlills:Area Iandfills are on-ground landfills (Fig.3.l ,). These are provided where
natuml or man-made depressions are not available and excavatjon is difficult. Waste ftaterials
are disposed ofron the ground sutface. Waste is covered with asuitable material! usually a
1a) er of soil. The cover malerial'soil is borrosed from some other locarion.
Slope Landfills: Slope landfills are provjded in hilly areas (Fig 3.1 c). Solid wasres are
disposed off on local foothills after providing a suiiable liner and a leachate collection
system. The stability ofslopes ofthe deposited waste is an important facto. in the design
ofthese Iandfilis. In general, a wastes slope of3O to 35 degrees is considered to be safe
for solid wastes disposal, depending upon the characteristics ofsolid wastes.
Disposal ofwases on Landfill 65
COMPONENTS OF A LANDFILL
Various components ofa landfill site are defined in this section. A cross_section ofa landfill
site is given in Fig. 3.2.
Cell: The volume ofwaste deposiied in a landfill site during one operational period forms
a 'cell'. The operational period is usually one day Size ofthe celi therefore depends uPon
the daily volume ofwastes received at the landfill site. The cell systen is convenient as the
rvastes deposited in the landfill each day needs to be covered the same day.
Daily cover: waste material is provided wilh a'daily cover' with usualiy a 15 to 30 cm
thici layer ofsoil. other materials, suchas yald wastes afld composts' can also be used Lr
cover mate.ial. The cover material Prevents surface runoff from entering into the wastes so
as to reduce the leachate formation. lt helPs coltrol lhe blowing offoflitter from landfills'
+.Liit
+uft
+
Flg. 3.2: Cross"seclion ol a Landlill
6 ATexbook of Solid Wastes Managenent
Lift: A 'lift'
is the heighr ofcells. Usually lifts are provided in a landlill. Height ofeach Iift
varies from 2 to 4m, depending upon the cell volume.
Behch: A 'Bench' is provided in the abovegound landfills uhen rhe height of wasres deposfued
is more than I 0 to 20m. lt is provided after each li ft or after every alt; rnate Iift. It in;reas€s
the stability ofthe landfill slope. Benches aiso facilitate surface drainage.
Leach.te Collection System: .Leachate' is produced when surface water infiltrates inro a
landfill. The water squeezed out fiom the wastes during its compaction and consolidatron
also mixes with the leachate. It carries numerous contaminants in it. Leachate should
be
carefully collected through a suitably designed leachate collection system. It should be
treated before its release on the ground oi :r, , sewerage syslem,
Finrl Cover: The'final cover'is provided afte.the landfill site is filled to its fullcapacity.
A well designed final cover includes a gas collection layer, a impbrmeable liner. a surface
water drainage layer, and a layeroftopsoit for horticu lture. Finalcoveralso helps maintain
the aesthetics ofthe area.
Capacity: The site should have sufficient capacity to absorb waste volumes produced in
the area for a long period. Low-lying areas are suitable for reclamation by tandfi .
I_arge
depressio.s and quarrying sites are ideal sites for developing a sanitary Ia;dfill.
Separation and Shr€dding: Separation and shredding ofwaste components are important
operations in developing an engineered landfill. These operations reduce the vol;me of
wastes and make it more homogeneous. Sepamtion and shredding reducethe load on a landfill
site and increase its Iife. Many ofthe separated components can be recycled or reused.
Disposal of Wastes on Landfrn 6Z
SITE SELECTION
Public resistance to localing a landfill near their res idential area is well known.
Thegeneral
perception isthat a landfil I deteriorates the environment and is a
threat to health and p;perty.
This perception is reinforced ifcare is not taken to ensure good aesthetics
and pioper
maintenance ofthe landfrli site.
Important considerations in the selection ofa landfill site are as follows:
. t andfili should be located away from the community arcas but should be easily approachable.
There should be sufficient road netwo.k available to avoid traffic c;gestion.
the
haul distance ofwastes should be optimal.
. Land area available should be suflcjenl forat least fi\e years. Additiorally.
adeouare
area should also be available to provide various necessary faciliries e.g.
a sire oifice,
a workshop, leachate treatmeDt facility.
. Grolndwater table should be deep in the area. Desirabl e depth of water table
be low
the bottom of landfill varies with the type of subsoil and the ctimate
ofrhe reeion.
However. i! should not be Iess than 5m. Areas prone ro waler ioggjng or flo;ding
should be avoided for landfill siting.
o Soil to be used for daily cover should be available nearbv.
. Local climate e.g. temperature. wind velocity. and winj direclion should be
taken
intoaccounl in the site selecrion. Landfillshould be located in the predominanl
downwind
ofthe wind in the area
8 A Textbook of Sotid Wastes Managenent
Dejgn offilling ar€a (, Seiaion oflardfitting meood b3s€d on sire opogmphy. subsurfr.a stra:a-
elc.
(,, l€IEdL iR fitr depdl daily colg.fiiao,€ss!
hg^g:y-",r.r,-*a
rlermedIate co^r er rh ickless. rhrctness of tiner
and finat cover/
lii4 sDc.rrrarion o toperd.ionat feanEs , m,-$od jevetin&
ot compa.rioD. ao
8/adrn& t'-arsponaEon of co! er marenal. equ ipmenr rc4unemeni
$afi
Desisn oft-andfiil (,
(ii)
(.iii)
{D) Surfac€ water diversions
(, Sp€cial workire area
(,i) SilE Offce
(ui) Ub*shop for equipme.irt
('r, Equipment Pa*ing
(a) Ltttils
(r) Fq]cinS
(.r,
Monirodng f a.ilitjes!rcb.s
Planrrdon and ladscapms
D€sign Documenrt (, De\ eiopmenr ofprclimLlary sir! ptan offi arEas
1'r)
::,:yTli1llyll,
cornpterldtrthtarr. firE pre!
-,.ur pra,L€xcavdion pran. sequenriar nrr prans.
-ior1 r,n ,. , oooi ,no noi.. r,
surlac€ waEr d,ve6ion "..ori "onro
, l,rl Compulation!fsolid wasre slor.ge votumes. qu?nriry
ofcover material,
andlifeofl d6ll
rn) D€! elopment of fnal sire ptan mc luding
nomat fiI arEas. special wod,ing
area5 dur,ng rains.,leachak conrot systern. gas
conrot iysrem, accesi
roa.s. snE ofic€ and orhersrrustu
-'*upa'dsarage monitorine
t
Es e.e, wo*shoi
p,"b"s,ido*.;;;-**''"
rrr ".,1,
prcparation ofete!arion pians lljri cross-sections ofe\cn\ared fiij,
complered f II ard phare devetopmenl
fili at various nages
rrr prepara,onofcoflsurGion
colledjon aId disposaj slsBm-
daarts for fencinp ac.6s roads- jin€rt
I
I
Disposatofwastes on Landtit 69
. A cornprehensive Environmenral trnnrcr Assessment (EIA,
should be carried our betore
finalizinsa sire
for a tandfil. The meihodolo$.and,l,.
the scope of rhe study shouid conform tJthe
_rnp"r_"
CpCB ;; ;;E;"iii.'ii.r,yiiiiui"g ;;;"1]r:::"t"S""
ChapterT).
To pres€nt the mrps witl arhoiaiions for easy and clear vjew.
I
managemenl system,
I
.Ladfilling Excavalois, Bulldozers, Dump Truck, ConpacloE, Poad gzde6, Wd€l ltI*els, d..
I
I
Dbposal al Wastes on Landfill 71
LANDFILL OPERATIONS
L3ndfil] should ope.ate 24 hours all the yearround.lt should be readyto receivethe waste
as and when it afiives at the site. Landfill operations include construction ofcells,lelelling
and compaction ofwasles, providing daily coveretc. These operations are discussed beio$'.
\*'eighing of Waste: Wastes received at the landfill site should be weighed over a weigh
bridge. It is nec€ssary to maintain a database ofthe quant:ty ofwastes received at the landfill
site.
The dimensions ofa celi depend upon the volume ofwastes to be deposited in it, taking
into account the daily volumes. To providing operating area for unloading ofwasles, it is
preferable to constrlct long and narrow cells. The longer face redules the waitingtime of
trucks for emptying. Narrow widths are desirable for controlled and orderly operations
including compaction and covering ofwastes. Height ofcells is usualiykept upto 3m which
is considered safe against any excessive settlement or sloPe failure. Cells oflarger heights
may require less amount of covering material but will increase danger ofsettlement and
slope failure. The side slope ofcell can vary between l0 to 30 percent
Spreading, Leveling 5nd Compsctior: Waste deposited in cells is spread in the cell area
with the help ofbulldozers or any other suitable machinery. Th€ wastes is then levelled and
compacted. Usually waste is compacted in layers of30 to 50 cm thickness The compaclion
72 A Texlbook of Solid Wastes Management
Providing Daily Cover: Wasles deposilgd in the cell should be covered at the end ofeach
day. Locally available soil or soil borrowed ftom nearby areas should be kepl rcady for this
purpose. In general, a layer of l5 cm thick soil is sufficient fordaily cover. Altematively
other cover materials e-g. tree leaves, yard wastes, geotextiles oaplastic sheets can also be
used for covering ofwastes.
Ssf€ty and Security: Landfill must be provided with a suitable fencing for security and
safety. To avoid health hazards to workers orusers due atiention must be paid to thetype of
wastes received. Hazardous wastes received, ifany, should be properly handl ed to avoid any
'tUorkers
exposu.e to human beings or environment. engaBed in unloading, spreading, or
compaction ofwastes should be provided with special uniform including protective shoes
and gloves etc.
. Conslruction ofapproach roads, inlemal roads and ramps for lhe free flow ofvehicle
and equipment.
. Proper surface drainage system to the groundwater ftom leachale contamination-
. Wind barriers e.g. large trees may be planted io prevent scattering oflitter.
. Leachate must. be collected and disposed off after suitable treatmenl. A leachate
lreatment facility should be provided for this pu.pose.
. Gas collection system should be monitored to check its elT:ciency. It should be
regularly maintained such that collection pipes and gas wells operate properly.
. Health checkup olworkers at sanitary landfill site should be carried ort regularly.
Proper arrangements shall be made for the supply ofdrinking water to workers.
. Any chance ofpollution due to landfill operations should be prevented by taking
suitable measures. Pollutio, likely due to some landfill operations and suitable preventive
measures are presented in Table 3.4.
FINAL COVER
After a landfill has been filled !o its full capacity it is necessary to close the landfill with a
finai cover. The final cover is provided to minimize the infiltratior) ofsurface runoff, to
prevent the release of landfill gases. lo prevent animals, birds and rodents from thriving
over landfill and to serve as a suitable layer forplanting oftrees. A landfili finalcover must
be designed 1o fulfi1l the following requirements:
Dispsal ofwast3s on Landlll 73
shouldbe durable and able to withstand climatic extremes e.g, hot/cold, dry/wet, and
freezelthaw conditions;
should be resislantto \yater and wind erosion;
shouid adjustto differential settlemenl inthe landfill;
shoutd be resistant to disruptions caused by plants, burrowing animals, worms and
insects;and
should help in landfill site reclamation at a later stage.
Prewntie Medsutes
S'ie preparation, disposal of wa,ter spraying on access roads,
wastes, u"affic dust, spreading landfilling afta, ard c.va material
soil Layer: This is the layer ofdaily soii cover placed over lhe waste.
Sand Lryer: It is a gas collection layer and is provided overthe daily soil cover ofthe final
Iayer ofthe wastes. Ii is usually a i 50 to 200 mm thick layer ofuniformly graded sand. A
network of perforated pipes is provided withinthe gas collection layer to help in the collection
ofgas migrating towards the top of landfill.
74 A Textbook of Solid Wastes Manaoement
Barrier Leyert Above the gas coliection iayer a barrier laver is provided. Barrier layer
consists ofa 200to 300 mm thick layer ofclay or a soii-bentorfite mix overlain by an HDPE
membrane. A barder layer servestwo main purposes. Fi6tly, it prgvents.the upward flory of
landfill gases tc lhe ambient atmosphere. Secondiy, it prevents the infiltration ofwater into
the landfill from external source e.g. surface runoffor rainwater falling over the landfill. A
s lope of 5 to i 0 percent is pro\'id ed i n the baftier layer, from centre towards the boundarr-
ofthe landfill in both the directions. The barrier laver minimizes the volume of leachate
and also the cos! involved in pumping, treatmentand disposal ofleachate.
Drainage Layer: A surface dminage iayer overlies the barier Iayer. lt faciljtates the flow
ofsurface water. Surface drainage layer is a sand la],er, about I O0 to 150 mm thick. Surface
water diversion channels are also provided at the periphery oflandfill, which receive water
from the drainape layer and to diver! the runoffsafely (Fig. 3.6).
Top Soil Layer: The topmost layer is ofsoil containing humus. ft supports the vegetation
over the landfill and helps in landscaping ofthe area. The thickness ofthis layer varies from
40 to IOO cm depending upon the root zone ofrhe planls selected for rhi; sire. Regular
monitoring ofthe Iandfill cover is required to check erosion due to wind or water and ro
observe the settlemenr ofthe landfi1l.
I
I
Sol
I
Fig.3.7: Typical Monitoring tnstr!m€ntation at Landfil
Sits
I
ENVIBONMENTAL I{ONITORING OF LANDFILL SITE
Monitoring of,landfill sire is req!ired lo pre!ent-the migratioo
envr ro nmenr. Mon iroring is main t) carried
ofpollutants into the sunounding
I
out for cheik ing air q uatiry. gro;;;;;;;p;-l t"""r,
and \ado7e zone conraminarion. Moniroring srations
at th€ periphery oflandliit as well as within ie ianaAff.
at a Iandfitlsire lor the co ection of data for various
are esrablishej aid probes are. ins;;iled
ftg.:.2 sfrows rypi'caii".or."*ii""
envi.inmental pari;;;;;;i;;;i",
I
ofsuirabte instrumentarion or probes depends upon rhe
characle;isil;.
well as legat requiremenrs. Special care is required for,,o,iito,in;;i "i;"it;;;;r;. ."
landfillsJe.
h;;;;;;;t"s I
t
I
I
Disposal ofwastes an Landfill 77
(i) monitoring
Air Quelity Monitoring: Monitoring of air quality at a landfill site involves
(ii) monitoring of landfill gas'
-'a.ii"" air qualiry and
ofambient
.onitoring is carried out to detect any gas migrating from the landfill
ir"f ity
"ft
* ii"-""ri....'"" intothe s;soil. various types ofsampling devices and-monitorinB
".
inr*i"nta ttu"" U""n A"veloPeal for this purpose A commoniy used grab samPler for collecting
,^. *."i.. it .r,"*" i" rig. :. A. ,Air q,aiiq is also monirored for suspended paniculate
for
;;; i'srM;. Hish volum-e sampleriare commonlv used to grab rhe sample of air
monito.ing ofSPM.
,7
(glaairool)
,/,probe
Vacuum oumD
oualilv of air in vadoze zone is monilored by usiDg a moniioring probe as sho\rn in Fig'
f. ri. iurpi., ut.o a! Yarious depths in the vadoze zon; Th's helps in detecting
^." "olleckd
any lateral migratiofl oflandfill gas
---'f-iquiJ
f". -. )
lected-by using a suction lys imeter (Fig 3 1 l lt cons ists of
a
""r*p cup "ol rc anonporous PvC tube Soil moisture is drawn into the cuP
po.ous
"".u.i"
ii."rgi i,.p"r". ty "ttuched a negative pressure collected sample isthen analyzed in the
"pplying
laboratory.
78 ATextbook ol Solid Wast$ Management
r-1--
*7SN
I
Centenng plug
I 16-l+
( /5 ch
6tun
25mm PVC probe scH 4a -J l
| 10.tr1o
) ( 1o!h
t_]
TYPkardla
lregEEl
Flg. 3.10: Probe toI Air Quality Moniioring in vadoze zon€
+
I
I
I
Filtration Assembty (mi,liDorer +
;
COD Disesrion Assemht.
Additional lnstruments tor Air euality
l
Monitorlng
Beta-Ra) Panicutare Maner ADaivzer
High volulne Sampjer wirh caseo;s
Moniroring Sysrem
fi and, sampler for gaseous monirorins
I
I
I
I
Dis6elof Wastes on Lahdfill 61
- machinery
15.
including pol lution monitonng equrpmeDt.
Pro\isionstikeueigh bridgeto meas.urequiniiryof*asre
i". f,.+i"C .qr;pr".ri'j"A
in
I
broughtat laDdfill sire,
ltre prorecrion equ;pments and orher facilities as reqrLired.
ciries \ ith more than 5 ldkh popularion.
I6. Utiliries suchas orinlinEt \.rarer {preferabl} barhing faciliries
shall
-be
provideJ ioi all
I
ro workerst end liohri
. *r,ln.J.i#;il;:ili,
I
a,ransemenls foreasy r-inrr op"*,;on.
7. Safeq Drovisions inctudineheairh insnecrion
made.
ffi ,:t"ij.X:
or."*"""ii-inrl rl.'J;;ilff;]":],"
,a/r EP<n(,(lrcar . I
18. Wastes subjected to
landfilling sha be compacted in thin layers using landfill
to achieve high density ofwastes.
19. Wastes shall be covered immediately or at the
compactors
soil r
i!h permeabi.ir) less rhan I0-_ cm sec.
,i.";t""tion.,
(a) The final cover shal I have a barriersoil layer comprising
of60 cm ofclay/amendecl
I
f b) On rop otrhe barrier soil la)er. rhere shall be
a drainase laver of I s.m
rc) Onlopofthedrainagela)er.lhereshall eau.g",u,ir.i"y.iof+S.r'ioruppon
narural plant growth and to minimize Erosron.
I
22.
(a)
In orderto preventpollution problems from landfill
shall be made:
operations, the following provisions
,r, . :f^.-Tl1::y]:'r"d
,
atso for avoidine floodi,e
r_onsrrucrron 0t a non_permeabre,;ning
r"d;r;";;;;;;;;;ffiiil:
s) srem ar ihe base aDd uariof".rt. aiioorrr
4,c.. ! rii ro$ permeaDrrrN ttnrng sysrem musr have barrier soil Iayer
I
Lclay ame;ded
soil) of minimum 60 cm thickness lvirh permeability
nor;a;;;;;;;,0 :'^'^
if waste reaching rhe tandfiI is non-biod;gradabf"
residues of waste processing facitities o; mi\ea ,u",,.
"ira
i",i.,. f". f"rltli..*]"*
i,""ir* .""i"ii""i;.i
",
I
I
I
Oisposal ofwastes on Landfill A3
S. No
0-02Ir.el
Cadnium 0.01mgfl
Clmlnilun Oexa\alent) 0.02lx.gll
L5 mg,a
Lran 0.05 mgn
Mercury 0.001me,4
Ni@e 10.0me,4
pH 6.5-7.5
Condudnity 100-200mmhoYcm
Toial dissolved solids 500 mg,
Cl orid€s 250 mgn
SulfiLs l000mgl
Color 5 Hazon units
Biochenical oryg€n Demand 30 men
Chedic2l Orygen demand 250 mg/l
26_ Where gound water is deep below the landfill, vadoze zone (vadoze water) monitoring
shall bi undertaken usingporeJiquid samplers (lysimeters) and pore-gas samplers'
21. Installation oflandfill gas control system including 8as collection system shall be
made at landfill sitetominimize odorgeneration, prcvenioff-site migration ofgases
and ro protect vegetation planted on the rehabililaied lardfili suriace.
28. The conceDtration ofmelhane gas generated at landfill site shall not exceed 25 percent
ofthe tower expiosive limit (LEL).
29. The iandfill gas from the collection facility at a landfill site shall be utilized for
eitherdirect thermalapplications or power generation, as per viability Otherwise'
4 A Tedbook of Soli.l Wastes Managenent
landfill gas shall be bumt (flared) and shall not be allowed to di.ectly escape ro the
atmosphere or for illegal tapping.
30. Ambient air quality atthe landfill site and at the vicinity shall be monilored to meet
the following.prescribed standards.
3 L The ambient air quality monitoring shall be carried out by the concemed authority as
per the following schedule:
(a) Sixtimes in a year for cities having population ofmorethan fifty lakh.
(r) Four times in a year forcities having population between ten and fifty lakh.
(c) Two times in a year for cities having population between one and ten lakh.
32. A vegetative cover shall be provided over the completed sile following guidelines
shall be followed:
(a) Selection of locally adopted percnnial plants tha! are r.sistant to drought and extreme
temperatules;
(r) Root ofthe plant shall nor disrupts the low-permeability Iayer;
(c) Selected plants shall have ability to th ve on low-nutrient soil with minimum
nutrieDt addition;
(d) Pianialion to be made in sufficient density to miniinize soit erosion
33. The posFclosure care of land{ill site shall be conducted for at least fifteen years
and longterm monitoring/care plan shall consists ofthe followingl
(a) Mainaining the integrity and efectiveness offinal covet making rcpaiN arld preventing
run-on and rud-offfrom eroding or otherwise damagingthe final cover.
(6) Monitoring leachate collection system in accordance with the requirernent.
(c) Monitoring of gound water in accordance with requircrients and maintaining gound
waterquality.
(d) Mairtaining and operating the landfill gas collection system to meet the standards.
34. Use ofclosed landfill sites for human settlement or otherwise shall be considered
after ensuing that gaseous and leachate analysis complied with the laid do$,n standards.
35. Cities and towns located on hills, shall have location-specific methods evolved for
final disposal ofsoiid wastes by the Municipal authority and ihe concerned State
Pollution Control Board. As Iandfilling in hilly areas is not an environmentally safe
option, the Municipal authority shall set up processing facilities for utilization of
biodegradable wastes. The inert and non-biodegradable *aste shall be used for building,
roads or filling up ofappropriate areas on hills.
Oispasal ofwestes on Lahdfrll 85
EXAlllPLES
lErcmple3.l:Acolonyhavingapopulationof65,000geoeratessolidwastesattherateof
2 ks/c;piu/day. The compacted specific weight ofsolid wastes in landfill is 650 kgm3 and
Itheaveiaeedepthofcompactedsolidwastesinlandfillis5m.Determinetherequiredlandfill
-gea
Solutions:
Totalsolid wastes generated from tbe colony,
=65000x2= 130,000 Kg/d
Volume ofsolid wastes
l39{o - :oo o,- , a
= 65U
Area requhed.
= 200/5 = 40 m:id
A.ea required annuallY,
= 40 x 365 = 14.600 m2lyear
= L46halYear
Example 3.2
A community generates solid wastes at a mte of75 tons/day. The soiid wastes has to be
disposedoffinlandfillcellsof5mwidthand3mlifthavingasloPeof3:linitsworking
face. Thickness ofdaily soil cover is 150 mm. Determine the ratios ofvolume ofwastes to
cover soil. Assume average specific weight ofwastes asl i) 350 kg/m3, ii) 500 kg/m3, and
iii) 600 kg/m3.
Solution:
(a) The volume ofwaste to be placed can be calcuiated as:
(i) For waste with sP. wt. of350 kg/mr
,, 75,1000- 21428 Kg ml
I'*' = .-35L ",,",
(ii) For waste with sp. wt. of500 kglml
(iir) Forwaste with sp. \Yt. of600 kg/m3
4 = --13- = *
'*".o
, t50 .^
' 15
The surface area oftop, face, and side ofthe ceil can be calculated as:
Top surface area,
4=ff=ulm
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6
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ATextbook of Solid Wastes ManagBment
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2.
l. cive
L
a neat sketoh ofatypical layout ofa landfill. Stlowvarious facilities provided at a landfill site.
ist sali€nt ciiteria foe selecting a landfill siie. which ofthese criteria you lhi.k is qitical for city
zone? Give.easons- I
3. Describe the physicaland chemical changes that take place in a,andfill during ils lif"..
4. Draw
--,,;-5.
why
a
is a
neal sketch ofacross-section of an engineered iandfill. Label its compotrents.
landfill final cover provided? Give details ofvarious layars in the cover describingtheir I
. 6
function.
. Estimate the laodfill area required for a city of one million p€ople. Use typical data for a large cig.
Assume compacred density of wasle with in the sile as 0.6lons/m3. the average deplh ofwaste is I
I
l0m. The ]andfillshould be designed for 20 years.
7. Design a suitable environmental monitoring system for a san;tary landfill site in your city zone.
S kerch the main moniloring componenls.
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Chapter
Leochate Maruagevruevrt
Water enters into a landfill site ftom vadous sources e.g rainfall, underground
watea, surface runoff water is also squeezed out ofthe wasies duting
compaction and consolidation. The leachale so fomed is highly contaminated
and carries many suspended and dissolved impurities in it. It is necessary
ro contiol this leachale flow and to prevent it from mixing wilh the
ground water- Characteristics of leachate, its controi, collection, and
treatment, are discussed in this chapter'
CHARACTERISTICS OF LEACHATE
The characte stics ol leachale vary with the type of waste deposited
in the landfill. It also changes with time depending on the physical,
chemical and biollgical reaction that take place in theland{ill A generalized
variation in the conaentration ofleachate constituents with tin:le is shown
in Fig. 4.1. The curve is th€oretical but indicates temporal variation of
leachate characteristics. The concefltration level of a constituent first
increases to rcach a peak value and lalea over a period of time it starts
decreasing. Depeodingonthe age oflandfill, theleachate can be categorized
as fresh or old leachate.
q:6
Fresh Leachate: Fresh leachate is generated in the {irst few yea$ oflandfill
waste deposition i.e. malnly during the aerobic decomposition phase. Primarily
88 A Textbook of Sotid Waites Managem€nt
pH
BODs 2,00&30,m0
COD 10,000
3.00G60,000
ToC (Toral organic Carbon) 20,000
1,00G20,000
volatile Fatty Acids 5,0m
I,000 - 25,000
Suspended Solids 3,0@
20G2,m0
Total Nitrogen 5m'
2Gt,000 4$
Total Piosphorous
5- 100 40
Total Hardness as CaCOi 30G10,000
Calcrum 3,500
20G3,000
Magncsium 1,000
5&1,m0
Sodium 250
20G2,m0
Chlorid€ sm
20G3,m0
Total Iron 500
.All l"lues
5G1,000
a
except pH sre in iner.
Old Le.chste: As the landfill matures. c.
r",.r,u," a.","".., ii. H;i; :iffiL;::::H:*1",1#::il h."",:l:f:li";l,i",l:
Afrer abour 25 to 3o years ofclosure of a landfiu, ", "ii-r.".i"" irl# ffiffJ: ,
rises ro 7-8. Typicai concenrration of conramin;r, t"
_. ttre waste islim;;;;;li; r"bt;*d
The concentration of po uranr iD the leachare
rnay not be very harrnful.
is ttren sign;ncaniiy t;;. ;i;j;#"r.
Tabl.4.2: TypicatChamcteristics of OldLeachare
pH
7.0 8.0
T!pi.al
7
I
BODJ
50 - 200
t50
COD
TOC
Voldil€ Fatly Acids
500 - 3000
i00 - 1000
50 - 100
500
250
I
50
+All l.lues exclpr pH
are in mgr.
LEACHATE OUANTITIES
be considered inthe design of
The quantity of leachate to be handled is an impofiant factor
lrnanttr. La.s" quuntities ofleachaie generated will exett a significant hydrostatic.pressure
Iiner
;;;";;;;"";;;"* ofthe landfiliThereforc, in order to design a suiiable landfill
the quantity of lea€hate
uni ui r"""t u" collection system, it is necessary to estimate
iiut witt ue eenerateo in lhe landfill Two common methods used for estimation ofquantit_Y
"*aariu.
(,') *",.;balance method lwBM);and (ii) hvdrologic evaluation
oflandfill
;il;;;",;;;
performance (HELP)
HELP MODEL
Hydrologic Evalualion ofLandfill performance (HELP)
is a popular model developed by
schroeder (1984) for estimation ofreachate gen"-ri*.
it i.!"ir*"..
as a three layer system j.e. vertical percolatio-n "i*rr"r"* rliln,r
layer, lateral arainage-la;;;:;;;;.",,
LeachateManagenent 91
layer (Fig. 4.2). Soffrrares based on this model are commercially availabie. Various input
data is required for this model as foliows:
Climatic Data Daily p.ecipitatioB, Mean monthly solar radiation, Mean monthly
tempgrature
Geotechnical Data Hydraulic Conductivity or pmeability, Soil porosit, Field Capaciry,
EvaporationCoefficient, Wiltidg Point, Minimum infihration
Rate, SCS RunoffCu e Number, Initial Soil Moisture Content
Vegetation Data Vegetation type, vegetation cover, LeafArea Indices, Winter covel
faclor, Evaporative Zone Depth
Design Data Number orLayers, Thickness of differcnt layers, Slope of layers,
Lateral flow distance, Surface layer oflandfill, Leakagefactor
(required for geonembBnes, mges between 0 - 1 ), Runofffractjon
I
3.
E3ner ervclay rayer
It I
T
Soil/clay lin6r
I I
LANDFILL LINEFS
Landfill iiners are provjded to prevent the flow ofleachate into the goundwarer. Liners are
provided botb at the bonom as well as at the sides ofa landfill. Usrjally ciay and,/or geomembrane
layers are used in the liners. The primary concern about liners is their perm;ability. The
design of a liner depends upon the characteristics ofleachale and its r;te ofgeneration.
Some liDer systems provided in the landfill sites include lhe following:
-r I
L"*. I
Flg. 4.3 (d)r Singl€ Linsr
L ///<\\ Ee ///it///: /// \ 70r{ I
Flg. 4.3 (t): Singie Composite Liner
Single Composite Liner: A single composite Iiner system comprises oftwo or more T
lalers
ofimpermeable maleriais [Fig.4.3 (6)]. cenerally geomembran; underlain by a layer
of'clay
or amended soil is provided in this system_ The thickness oflayers depends uion the leachate
head expected to build up at the bottom oflandfill. This type oflin;r syst€m is suitable
municipal solid wastes landfill sites.
for I
DoEble Composite Liner: This system is provided for a hazardous wastes landfill sites.
lD
this system two different liners are provided one overthe other \vith a sand layersandwiched
in between [Fig. 4.3(e)]. Each liner coniisrs ofa iayer ofclay or amended soil and a layer
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LeachaleManagEnent *
ofgeomembrane. The sand layer is provided with a natwork ofpipes to collect any stray
leachate infiltrating into it from the upper liner.
20-30 cm
t'n*ro
I
30.60 cm
t L
20-30 cm
?""'
30.60
. Liner material should have adequate resistance to darnage due to vehicular moveBenl,
climatic conditions, or chemical reactions with the wastes or leachate.
. lt should be inslalled boih at the base and around sides ofthe iandfill 1o soiis on all sides.
SoilClay
Among the soil liners, clay Iiner\ are considered to be effective for landfills. Clay is soil
which has grain size smaller than 0.002 mm and exhibjts cohesion. It is suitable not only
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94 ATextboak of Sold Wastes Management
: I
!
due to its low permeability but also for its potential ofattenuating the contaBinants rn
leachate. Clay liners. i.om thick usually, have permeability as low as 10-r cm/s Typical
value ofpermeability ofvarious types ofsoils is presented in Table 4.3 At sites where cla)
I
I
is not locally available it may not be economically feasibletoborow it from distant locations.
In such cases, amended soil is generally used in landfill liners. Bentonite is a common
additive. which is mixedwith the localsoilto reduce its pelrneabi litv and lo provide strength
I
Both the soil and bentonite are thoroughly mixed to obtain auniform mixture
Table4.3: Typicalvahe ofPerm€abiliB fol various Soilsand Aquifers T
Pemeabttq (. sec)
Cround-sudale Clay
Deep Clay Beds
10-5 to l0r
I0-u ao loj
I
SiM-oanr l0r to 1o-r
Fine Sands
coarse Sands
Grav€l
lo r to
tol
loj
!o tor
to 1.0
loj
I
CIay Sand a.d Grav€l mixes to{ to 1or
sandstone toj to 1ol T
l0+ to loJ
Shal€ lorr 1o lo-?
Less than
l0-{ io l0
l0r ro 1.0
10r
'?
I
Sou.e: adapled from Bouwer, I 978; Driscol, I 986
Construction of Soil Liners: A common problems in the construction ofclay or amended
I
soil liners is the formation ofc.acks. The soil should no! be allowed to dry out during its
placement. Such Iiners should be laid in thin layers, aboul 10 !o 15 cm thick. Each layer/lift
should be properly compactedusing aheaw rollerthrough several passes. Rollerfeet should
I
be sufficie tly longlo penetrate through the working Iayer right uPto rhe underlying Iayer.
This will ensure proper bonding between the successive lifts.
Problems arise when non-uniform mixture ofsoil is used. Cracks are formed as a result I
ofdifferential swelling. The quality ofthe amended soil should therefore be monitored by
carrying ou! various tests e.g. moisture content, Atterberg's limits. laboratory compaction
tests, permeabilitytests. Strict control ofmoisture content is required during compaction
as it affects the level otcompaction and permeability ofliner'
I
Geosynthetic Mate als
Use ofgeosyn!hetic materials is common in iandfills. Geotextiles, geomembranes, geonets,
I
and geogids are common types o.l geosynthetic materials. Ofthese Seotexi les and geomembmne
are important in case oflandfills.
T
ceotextiles: These are used as filters in landfills in order to prevent the movelnent ofsoil
parric les inlo dra inage syste m, The) also ac t as a cushion to protect the geome mbrane l iners.
bue ro their high permeabili$ ( I0r lo I Or cm/s), they aliow the movement of liquid while
preventing fhe movemeni ofadjacent soil particles and thus help in Preventing the clogging I
ofdrainage system-
I
t
LeachaleManagenent 95
Tensile Strength
167 Kd$nt
Tensile Streugth al leld
Tensiie Strength at bre.k
28oKlcnl
t50/.
Eloog?dion alyield
10o"/o
Elongation ar bre?k
Toughness
20 Kg
Te,I resistance initialion
104K9
Prlnc$re resisrarce
Llr temPemture bdnt€ness
',4.C
Durabilitt
2%
Carbon black Percent
Negligibte stengh change after
Accelerared hear agiflg
lmonthatll0'C
Chemical Resislance
mixtrr6 I 0ol" rlnsile srEngft chmgE over
Resistanc€ ro chemical rvaste
120 daYS 7 days
l0% tensile sE€ngth change over
R€sist to Pur€ chcmical r€agents
ce
. Movement ofheavy vehicles should not be allowed on the Seomembrane dudng its
laying. Movement ofhoofed animals onthe geoEembrane should also be prevented
by providing properfencing ofthe area.
. Geomembrane should be covered as soonas possiblewith asandlayerof20-30
cnr thickness.
Seaming oJ Geomembran eJ: The seaming ofgeomembranes can be camied ou1 in a number
ofways e.g. thermal seaming, chemical seaming, fusiol welding and mechanical methods.
fhetnal Seaning*This procedure is suitable forgeomgmbranes which arc manufactured
\r/iih the base material which is sensitive to heat (themoplastics, crystalline thermoplastics,
thermoplaslic isomers). Seaming is carried out at a temperature ofmore tian 260'C. The
prccedure involves hoi air bonding, hot wedge (knife) bonding, and dieleckic bonding. Various
thermal seaming altematives are shown in Fig.4.4.
Chemicai Seaming-Chem;cal seaming is carried out by using various chemical and base
materials e.g. cement, solvent, vulcanizing adhesives. The selection ofchemicals used forthis
LeacheteManageirdnt 97
purpose depends on composition ofgeomembrane and the field conditions in which the
seaming is to be carried out. This procedure is howevet generally avoid€d specially in hazardous
waste landfills due to the chemical aggressiveness ofthe seaming materials.
Fusion Weaing---"fh\s rnethod isused only on HDPE liners and requires a hot base product.
Specialized welders are usedto extn de a ribbon ofmoltenHDPE which melts and bonds to
the two HDPE sheets to foim a weld.
Mechanical Methods-|n this system, mecbanical seaming or taping is carried out. An extensive
quality coDlrol is required in mechanical seaming as the presence ofdirt or other foreign
rnalerials can reduce the strenglh ofseam.
. A leachate collection Iayer ofthickness of30 crn and with a cbefficient ofpermeabiuty
ofmore than I 0-2 cm/s.
. A single composite liner comprising ofa HDPE geomembrane ofthickness l.5mm
and a compacted clay or amended soil layer ol I 50 cm having a coefficient ofperneabiliry
of 10-7 cm,/s or less.
. In regions where rainfall is high, subsoil is highly permeable, or where watertable is
wilhin 2.0 m to 6.0 m belowthe base oflandfill, a double composite liner comprising
the following layeis should be piovided.
Sa plihe Frcquehct
Clry/soil Evew 500 - 1000 m3 In-situ d€nsity and moisture content, compacrion, p€r-
meabilily. grain silE disEibution. ArlederB\ Iimirs etc
Thicim€ss, daEiy,st€ngtb iou€lDess. dumbilily, chemical
resistanc€, field se€Jn streogrh, overlap, elc.
9a ATextbook ol Sold wastes Menagement
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Flg. 4.5: Leachate Collsciion Syst€m
-SoldwastB
+---soiland bentonite
40 m rHDPE Liner----J
wel l used for collection of leachate is shown i$ Fig 4 ? The leachare pumped ou! is kepl in
hoidingtanks usually constructed of RCC.
ProrectNe casing
.- lr oo mm+G] prpe)
p196
DescriptiotL/Purqose
DEinage l-ayer Hishry p.rm€able la)€r ofsand or gra!€ls to ease the lateml dninage ofleachde'
Sh;uh b€ ar least 30 cm thick, with a petrieabilitv of 10-3 cm'/sec'
Sloped T€rrace To increase the potential of lateral nigration of leachate. A slope of 2 % is
prcfeiable.
id coll€ct and drain th€ leachate. 100 mm dia HDPE or PvC pip€s \rith
Perforat€d Pipes
Derforations of 10 mm in the upPer tltre€ quaneF are prefercd'
in inveied filter, to pr*€nr the clogging ofpiPes due lo insress of sad from
FiltErlayer
dninage laler.
Sump well Used to pump out the lea.hate collecled d the boit'oB oflddfiil
,.,-.t.
._-} -':,c -<-, t'11
4:Ferus6<ts1
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(b) For above.gade coll
Flg.4.8: Typicat kak Dei€ction Sys!6rn I
The remediation ofle3tage depends upon tlle actual siG cooditions which may vary. Remediation
may be accomplished by providing a peripheral toe drain system. For a trench landfill, a
barrierwall may be constructed inthe direction ofleachate migmtion. A number of sulnpwells I
I
can also be provided for pumpingout the migrated leachate.
LEACHATE RECIBCULATION
Leachate pumped out ofthe landfills should be recirculated into the landfill sites. The re-
circuladon ofleachate i, the iandfills has many envircnmental and economic benefits. Many
organic impurities ofleachate are anaerobically digested 'rithin the landfills which helps
in the generation ofmethane gas.lthas been observed that the r.teofmethane gas produciion
I
is higher in landfills where leachate reci.culation system is provided.
Leachate also increases the moisture contentofthe wastes, which helps in its biological
decomposition as well as in the production ofmetlane gas. With the generation ofmethan€,
pH level oflandfill increases. Metals present in the leachate are precipitated and are contained
I
within the wastes. Aftera fewcycles ofrecirculation, the amount ofleachate ard impurities
in;t are significanlly reduced. This also reduces the cost involved in treatment and disposal
ofleachate.
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I
Leechateilaragenent 1O1
LEACHATE TREATMENT
Due to a variety ofphysical, chemical and biological constituents in leachate, no single
treatment method can be recommended. Following are i&portant factors in the design ofa
leachate treatnent system:
. Quantity or rate offlow ofleachate generated.
. Concenlration of various contaminants
. Available trealmenr and disposal oprions
Techniques used for leachate treatment are similar to those applied for other effluent
treatrnent methods. These include mainly biological as well as physical and chemical treatment
and are described in the following sectioos.
Biological Treatment
L€achate collected fiom laodfills has higl biochehicel and chemical oxygen demands. Treatrnent
can be carried out by usingaerobic or araerobic methods,
I
1rJ2 A Texlbook ol Solid Wastes Mahagement
I
1
?
Aerobic frcatfient
Aerobictreatmentprocessesincludelagoons.aclivatedsludgeprocess.rotatingbio]ogical :
t.i"tlini tilte$ etc. ln all these melhods' organic matters Presenl in the leachaie
"ontu"too, tor decomposNoTl
,r" aep,raaea Ur mlcroorganisms. The process requires large quantity ofoxygen
=
of oxvsen for
;;.;T";;;: ;;;;;;ioaa apptied to the sistem the hisher is the demand
method'
; .;;;,1;;;"-f"; iis essenrial to mainrain a proper organic load in erery aerobic
depths in which
Aerated Laeoons: Aerated lagoons are pon'ls with large size and small
in the liquid due to
i"""i"i" I r?rl.a. s"rrce of sippty ofoiygen is air and is diffused
with large depths'
;;;;;; ;;;"lly ""r.rsed bv wiod action where lagoons
provided to ensure
are designed
regulal supPly ofoxygen and
-""hunicat-asitatois or air diffusers are to hours A
ii, .i-it*. frtlt tv".- requires a long hyd raulic detention time i e aboutgiven Fig 4 l 0
6
l 1 E
in
ii.. lt"Jf, of ti.pr" f"go;ns and lagoons with mechanical agitalors is ' '
iaeoons Uut it in;olves an exba feature e.g. recirculation of sludge Due to the recirculaliol
rJn. f. of U*t.ria is manv r imes hi gher than-that in a lagoon This system, therefore'
"].J
i. *."i, ""1
r"oui.. hydraulic detentiontime The process also an aetation
"tmaller 'equires
"na
rani uni .enting r"nt also calied as liquid-solid separation tank
(Fig 4 11) The biornass
i
.. siuape "senies ttris tank. A smallamount ofthis sludge is recycled back iothe
greatly'
aeratiot
values
rank. I-he process is veq effeclive and reduces the BOD and COD
ofa
Rotatins Biotoqicat Contactors: The rotating biological contactor tRBC) consisls
and placed in a large reclangular tank
r".l. r_it "."i.:r, aitts attached to a horizontaishaft
the liquid and the remaining portion is
i'ru. i. rzl. il"t" ai.i.s are partially submerged in
"
LeaciateManagenenl 1O3
pyhnced 16 ihe atmosDhere. ln this process, biomass is accumulaied on the surface ofdisks'
Tfi:il:#:il;illn.ont""r i"itr, riquia air The submersed portionof disks carries
^na
organic matte; which is desraded b) the armospheric
o\)sen'
;i;;;';;;i;;;;;;,d
TricklinsFillers:AtricklingfilterconsiStsofabedofrockPiece5whichProvidefired
I'IJ;:X ill;; i;;iio,"'ri ," g'"" rig + 13 Leachare rhar is Io be lrealed is rriclled
' '
"
Sludqo
Two-Stege Reactorr A lypical two-slage anaerobic sys:em used for leachate treatment is
shown in Fig. 4.I4. The slage I reactor consists of a stirrer used to develop good contacl
between iaroorganisms and organic matter' The second stage reactor is quiescent whjch
enables settling ofsludge at the botlom. The supernatant liquid is recycled back to stage I
.eacior for fu(her 1.€almenl.
USB Reactor: A USB Reacior (UpflowSludge Blankel Reacto, is based onthe developmenl
ofa sludge blanket. ln the sludge blanket, component particles are aggregated 1o withsla'd
the hydrauiic shear ofleachate movemenl The leachate isfed from the bottom of reactor
and active anaerobic sludge solias convert the organics into methane and carbon dioxide
The reaclorhas an intemalbaffle system above the sludge blanket also known as gas- liquid
separator (Fig. 4.15). This separales out the biogas, sludge and liquid comPoneflts.
Gas]iquid
Granul.r Filtration: lt isused to remove suspended solids from leachate and is typically
employed p or to the use ofaclivated carbon adsorption to pievent c,ogging. Granular
filtration ofbiologically treated leachate may also be required in order to meet the \tale.
quality standards for its discharge in streams or drains.
FLOCCULATION/
CHEMICAL PBEClPIATION
sEDrMENrarroN
I I
f_ s,uooe
f--^-r*" I
I rrLrnarrot .
---l---')"*^" I
f.-*"r,* I
f TBE,AfED
EFFLI.]ENT
Reverse Osmcsis: Reverse osmosis can be effectively used for leachate treatment The
system invoives a semi-permeable membrane, \'hich can be flat ortubular' The wasle slreaE
oi leachate ilows throughthe membrane while the solvent is Pulled through the membrane s
pores, The remaining solutes such as organic or inorganic components do notpass through'
but become more and more concentrated on the influenl side of the membrane Foran
effective reverse osmosis, physical and chemical proPedes ofsem!Permeable membtane
musr be compaiible withthose ofthe leachate Somemembranes maybe dissolvedby leachate'
Suspended solid may also ciog the nembrane material.
Pernissible Linits'
Irlahd Sutfoce Water Public Sewers Land Disposal
m3/sec
= Ol x 10-3
= 9.504 m3/day
are l) ing belu een the base of a hazardous
ExemDle 4.2: The following rhree soit layers
:::iJ1;ffi; ""i r"i.nviie "q'if"' How long *ill Io misrate 1o
it take for leachale
the aquifer?
Depth ()
4.0 1.6 r lo-'q
Soil A
10.0 2.0 x l0-5
Soil B
t2-o 5.8xI03
Soil C
Solution:
Total travel time inyears
r /^ r.)o 12.0 I I
= 6.579 yeais
1@ ATexlbook ol Soliclwastes ManagEnenl
EXERCISE
How does the leachate characteristics change with tihe? Whai are irs environmentat implications?
whal are the majo. contaminadts in a l€achare? civc rhei: B?ical values.
Estimate ihe leachate quantit gererated per hectare ofa landfill in Delhi. Use pubtished data
What ale the advantages of using geomembrane as a liner?
Listthe precautions lo be obserued while constructing a g€omembmne liner?
Discusslhe relative advantages and disadvantages ofva ous leachatet eatmenrsystems.
Design a leachale treatment sysrm for a landfillrece'vin8 municipal.so lid wasre. Whar are tie
standards prescribed by CPCB for disposal ofleachate on land. in river, or in sewers? cive fte
blockdiagram ofa leachate treatment system and naiiealltheunirs.
Leachate co Ilected f.om alandfill site \yas found ro has the foltowine chalacteristics:
COD 25000mg/l
BOD 12000 ms/l
l0000me/l
pH 1-7
Estimate th e probable age of the landfill. Design a suitable treatment systeh for this teachare.
Chapter
I
I Land.ft,tl Gas Control
I
I I andfi!l gas is a miYlure ofvarious
gases generaled due to the biochemical
,afler. Il also conlains green house
gases e'g' Co)
I ^,,r,'i^i "r*"-i.
:;',,:l'::"l^1,::".#;"
ffi';' il;;;,
::il.a"ir"i.i ;;.
"i "r"".'[i
;iiiunantl
'li.s
p'oa"'
il;.;,lron'"n'ot'on"qu"n'es
orgas na] be erplosive'
*. rt",.iiture
landfill
of
sases e\en the.so
landf ill gas mi$alion
I .lnt. .rl.t"nt;ar"na
;;r..i';il;;;;;;i;;;.
gas'
oflandfilt
range from nuisance to damaBe
to public health'
^ayiabre-s r presens so'e potentiar environmental
I
impacts
ofLandfill Gas
Table 5.1; Potential Environmental Iflpaors
I
ir"J.*.-",r,. r-a n rr p.ople or antmals in the \ iciniq ma)
AsphYxidion ",
.,#" #rn a'; a'cmuraion of sas in anv c'nnned
"rir*r"" '
of ot-vgen
i.-. o, otlt.. u.g.u,ion "te damaged as a resuhzones'
T i"nli-""a*to
ffil"ii. ."-;.
rl"anltg"
*a' ;
misarion
biic
in rhe roor
** *In'"or-o "f r*anrr gEt e'g ammonia' cahon
some
monoxjde'
ro pra'$ and mav affeci t,e
I
plantgm$1ir
Due to malodorous gases,
i*1", ai"iia., r,igr,rvsot'ble in $arer iocreaseihe hardncss'
decrEases oH and tums waler acidic '
tl
*,itr',;"" "ie." n'tns
which are serious h€allh hazrd
gas contribute
i*r,- Jr"ira" -a In.tt -" Prerent in the landfill
t
Efred ro the gF.oitou* effec!'
t
I
1
)
Concenlrutian (ppb)
6,840
2,050
245
Chloroform
2,800
1.1-DichlorcethaDe
25,700
2,830
Dierhyl€ne chloride
7,330
EthylBenzene
3,100
Methyl ethylketone
615
1,1,1-Trichloroethane
2,080
Tdchloro€thylene
34,900
Toluene
245
1,1,2,2-Tetrachloroethane
5.240
Tetrachloroethllene
3,500
Vinylchloride
1,500
Styrenes
5,600
2,650
xylenes
-d\
i\\
1t l
100
100
60
\,
/ 20
\
PhaseII-AcidPhase:ThiSisatransitionphaseinwhichoxygenisdepletedandanaerobic
takes place nitrates and sulfates
il?;.t Jtii;;;;pin!. a, tt'"
"nu"tou;" "onversion
ii"r"ir""* .ti.r"" :ndiydrogen sulfide rermetlative and acidogenic bacteria produce
volatile fatty acids, carbon dioxide and hydrogen'
bacteria starts to
Phas€ III-Initial Methenogenic Phese: ln this phase melhanogenic phase II are
t".thane. drganic acids and hlirogen gas formed during
"..* "rJor"Ir."
ionvened into melhane and carbon dioxide'
Phaselv-stableMethsnogetricPhsse:stablernethanogenicphaseischaracterizedbyby
is o-xidized
io i. io o".""ot or ."rhane and low concentration of hydrogen Hydrogen
.;;;;i;td;;" i;.elhane since carbon dioxide is utilized for oxidation ofhvdrogen'
its concentration is also reduced inthis phase
volume of
Phsse V-Air Intrusion: Due to the biodegradation oI lhe organic wastes the
Duing serilement
,rlrrc. ."aul". _a *.".t"s in the landfills mdergo consolidarion and settlemenl_
Jirr-a* il the outerpartofthe landfill and reduces formation ofmethane'
"i*lnir,
Pbrse Vl-Methane Oxidstion: Methane pro'luced in the centre ofth€ waste is.oxidized
io caoon aioxiae, as it migBies throughthe outerpan oflandflll ln this phase nltrogen ls
also present in significant concentration in landfiil
gas'
I
T
I
112 A Texlbook of solid wastes Managem.nt
3
Phas€ VII-Cerbon dioxide Phase: 1n this phase, methane formation is negligible an. l
intruding air oxidizes solid organic carbon to carbon dioxide Finally the waste is almos:
stabilized and the site is Iike a naiural ground.
Waste Typer The naiure ofbiodegradable ftac:ion ofmaterials present in the wastes (e.9..
its molecular structure) affects both the deBradation rate and the composition of landfill
gas. Readil]_ biodegradable fractions ofwastes such as vegetable matter supPort rapid initiation
ofdecomposition process. Onthe other hand, less readily degradable matterwith high carbon
content (e.g. newspapers) support a long term produclion ofmethane r;ch landfill gas.
Specific weight: Specific weight ofsolid wasles deposited in the Iandflll affecl the amount
ofair trapped within the *astes. amount ofbiodegradable matter within the same volume.
and the vertical permeability ofwastes mass. In a well_compacled waste, the amount of air
is less and biodegradable matter is mole in a unit volume. It therefore helps in the earl)
star! of anaerobic decomposition and production of meihane.
pH: A pH of 6.5 10 8.5 is an optimal range for methane produclion. In municipal solid
wasles. acidic condilions are common and may delay melhanogenesis
Stoichiometrl Method: The mosl common technique is to use Slricliou e1r)'. ifthe chemical
composition oforganic ma11er presenl in the wastes is kno\r'n. Eq. 5.1 can be used to determine
LandfillGa. Contol '113
rhe volume ofprincipal gases i.e. methane, carbon dioxide, and ammonia generated in the
landfill.
CJ]lO.Nr+ [(44 - 6 - 2c - 3A)/41H2O -+
l(4o b - 2c - 3d)/87CH t + l@a - b + 2c + 34/8lco, + dNHl r5.l)
}rhere CJ.O"Nr'is the chemical comPosition ofthe municiPal solid wastes
I?CC Mdhods: Intergovernmental Panel on Climate Change (IPCC) has suggested guideliDes
to esrimate the quantity ofmethane generated from municipal solid wastes. Eq. 5.2 is used
to estimate the total methane emission.
CHa emission = t Msnl, t FDOC t x FD t x MEF x CR (5.2)
These methods are approximate but give a fair indication of the potential of gas
generation in a landfill.
Test Well Method: This is one ofthe mostreliable rnethods for estimating the gas Production
from an existing landfill. It involves constuction of a gas well at the landfill site and moniioring
ofquantity and quality ofgas received. The number oftest wells required for this purPose
depends upon the size oflandfill as well as the chamcteristics of\Yastes. rcceived. A general
practice is to use a factor of safety of2 for this method to arive a! a conse*ative estimate
This accounts forthe fact that all gas generated is not usualiy collected.
Rougb Approxim.tionr This method is used lo assess the quantity ofgas generated based
on rte vol;me ofwasle disposed off in landfill. It is assurned that ab6ut 6 m3 ofgas is
generated every year from eachton ofwastes. This method assumes an average landfill that
is supportingan enerry recovery system and does not accuEtely account ior the characteristics
of\rastes. Estimation from this methods may vary by as much as 50 percent.
i,Il-;F-
t:
iij:nl.ii:l
1.h and aound siie inslallaiions. 10. Exploration and oiher boI€hole5.
2. Through cove. materials. 11. Changing watel levels (e.9. cessalion ol mine
3. S6ttl6m6nl cacks, esp6cially al sile p€rimet6r. pumping) can op€n or 6lose palhways.
4. Fracluros in adjacenl rocks(includhg blasting 12. Granularmaterla lnsoakavays and pip€ o. cabl6
7. Collapsod mine workings. 15. Seruic€ €nlri6s (oas, wal€r, elecl cily, elc.)
16. Del0ctiv6 bnck{ork or honaL
g.lnducsdtractures inzoneolstralaloxlension 17. Drain pip€s. archiroclulal leaiur€s.
at sdgo ol mine subsidence area 18. Soir, generalground sudac6 (possible ingrcss
to 9ard6n sh€ds, iehls elc.)
Within Wastesr Wasres remain highly perneable even when well compacted. The presence
ofvoids inthe waste due to poorcompaction, bulky objects etc results in higher permeability
and thus more space for gas to migrate.
Site lnstallations: Landfill gas may migrate through or around any boreholes. chimneys
()r similar structures within the wastes. Surface drains that discharge offthe site and roads
also provide potential migration pathways- Similarly, olher services tothe site controlofiice'
weigh bridge or other building structures add to the migration pathways for landfill gas'
Caps: Low permeabilily Iandfill caps (final cover) and crack in landfillcaps due to differential
se;lement also provide a room for migration oflandfill gas. Gas flo$ through caps increases
with time due to the development ofdesiccation or settlement. Deep penetrating plant roots
wilhin the landfill cover also contribute to gas migralion
Lahdfillcascontrol 115
Site Perimeter: Landfill gas may vent to the aunosphere from the entire surface ofa landfill'
Bur it is particularly likely to migrate to the sudace from around its perimeter. Afler its
depositio;, \vaste can continue to settle over a numbero?years, causingfissures to develop'
Increasett gas venting at the site matgins is likely to ensue, notably where the rilaterial
boundingthe site is relatively impermeable, such as clay or a synthetic site liner'
Gas Ertraction System: The use ofan effective gas control system greatly reduces both
laterai off-site migration and venti[g ofgases through the landfill surface Migration may
however, ircrease ifthe extraction system is clogged or is not in operation for a longtime'
ln such cases, gas may migrate through the voids between extraction wells and wastes.
Oll-site Migiation Pathways
Off-site pathways could be natural orartificial Natural Pathways itclude permeable soil or
rocks, planar opetings, joi dts, faults etc. Artificial Pathways are generally due to mining or
any other construction or bo.ing activity.
Natuhl Pathwayg
Perme.ble Rocks or Soils: Landfill gas may teach the surface at some distance (hundreds
ofmeters) from the landfill site by travelling through permeable strata dePending upon its
penneabiliv. Services e.g. underground pipelines and buildings consfucted nearby are particulady
vulnemble to gas accumulation.
PIansr Openings: There are various types ofplanar discontinuities in rocks An inclined
b€ddingptane, for instance, mayrun ftom the baseofthe landfillto intersectthe iand surface
some distance away. Wherethis provides a ready gas migmtion pathway in low permeability
rocks, the migrating gas will not be detected till it reaches the surface-
B€ilding Planes: These are the basic discontinuities in sedimentary rocks, representing
breaks oi changes in se<limentation. They may be oPento a greater or lesser extent Providing
migration paths.
Joints: Joirts form parallel or sub_parallel sets. When such.loints have a high
a systematic
frequency, they may influence the movement ofgas in a direction parallel to thejointing'
Fsults: Faults are fractures along which relative disPiacemenl dfthe adjacent rocks has
occurred. They may also contribute tothe landfill gas migration.
Other Fissures: Blasting fractures ortension fractures extending for several meters into
a rock ma] occur in the \r'alls ofhard rock quarries. These may induce surface emissions at
the perimeter ofa land{i11.
Natoral Cavities: Some rocks contain cavities e.g. shallow holes or pot holes in limestones
These may b€ connectedtothe cave systems often extending several kilometers. thus provid;ng
easy paths for flow ofgas to a very large distance-
Artiticial Pathways
Mine Workings: Landfill siles are common in coal or rock mining areas. Such areas also
include disused tunnels and shafts which act as a conduits forgas. Gas migration pathways
can also be provided by fractures created by subsidence in areas overlying deep mines'
'116 Arextbook ol Solidwastes Managehent
permeabilh
N€ar S[rface Installatiods: Any service installation may provide in itself a high
various service:
mierarion route for landfill gas simply by thecrcalionofa line ofweakness
gas
ir"lraing .t..tr;.ity. .ratef se*erige etc laid down nearthe landfill may enhancethe
migration.
GAS COLLECTION
gealth' exPlosion'
The miglation of landfill gas Presents Potential for several hazards e 8 fire,
ofenergy. There is therefore considerable interest
But thJga( is also a potelntial ofsource
in the p;ssibilily of gas recovery. The objectives ofgas collection are:
Gaspu.illcaiion El6ctrLlty
syslem len€|al€.
Each ofthese components ofgas collection system has a specific role and need to be
designed properly. The feasibility ofthe system depends on the amount and rate of gas
g"n"iation. Wh"r" th" gas generation mte is high, it canbe supplied as afuel to the n*rby
ireas at a reasonable price. Ho\Yev€t ifthe rate of gas Seneration is low, it may nol
be
Gas Extractiol Wells: Gas e].traction could be achieved by lsing €ither verlical wells or
through horizontal trenches. Details ofa vertical gas well are shown iD Fi8 5 4 The size
of
Landil Gas Control 117
itrese \4elis varies between 300 mm to 500 mm including the inlemal perforated piPe of50 -
6i mm dia. Though both otthese systems arc different in layout the basic concept remaids the
sarne. Suction pressure provided by the gas pumps dl?ws the landfill 8as into the vertical/horizontal
pipingthrough the $avel backfilland the slofted PiPe. vertical pipe system is usuaily Provided
ar the time ofclosure of landfill i.e. together with the construction of landfll cov€r. On the
oderhand, horizontal pipesystem isprovidedasthe waste disPosal progesses. Gas extraction
\rells may also be provided in combination with lhe leachate collection wells (Fig 5.5).
L-oocm *-l
' oiameter
Header Pipes and PumpingUnit: A header pipe is usually provided to coltect the gas
fiom various vertical wells or from horizontal trenches. It also receives gas from a network
ofsubheader pipes which are used to join a number ofgas weils. A pumping unit is usually
connected at the end ofheader pipe to extract the gas. The caPacity ofPump depends upon
many factors e.g. quant;ty ofgas available, por€ space ofcompacled wastes.
Flaring Systeh: Landfill gas ifnot availabie in sufficient quantity or found ofpoor quality
(i.e- \r'itb low methane contenl) isnot feasible for energy recovery. In such cases, gas should
be burn! off. Various tlpes offla.e burners are available forthis purpose. These burners ale
kepr ai a suitable height. Typicallythe height offlaringburners vary from 3 to 6 m above the
landfiil surface. A Star Arm burner (F;g. 5.6) is economically available specifically for
flaringoflandfillgas.
118 Alexbook ot' Solic! W?6tes Managpnent
IT
!l
iti
*':
:
a
. 500
Well
Flg.5.5: combinaiion oi Gas Ext€cion Well and Leachale Colledion
contains various impuiiiies especially
Gas Purilic.tion System: Gas collected from landfiil
oit", lyatogen sulfide, which needto be renoved for efficient energy recovery'
u"oo..
--u"i.tlt. These are c) Iindrical
r., riJli
"na gas is removed using moisture removaltraps'
columflsfabricatedofM-s.sheet.Flanges.about5mmthickareprovidedatthetopandDonom
nqOU* gaskets are use; to prevent leakage ofgasJrom flan8es ForabsorPlion
"iti" ""fr"'..
oimoisture ttre cotumn is filled *,ith 15-20 mm size gravels and dry solid calcium
chloflde.
A cvlindricalM.s. column aboul.]00 mm diamelerand l'1 lor hyclrogen
5 m height is used
iron cuflings and lead
trinji rlrn""r1 Ihe column i, fillel with gravel l5'20 mmasi/e' membrane
acerale oowder lo absorb hydrogen sulfide gas Allemalively semFpermeable
moisture to pass through while
;"" i" ,i*a i" r,ydrogen iulfide, carbon dioxide and
"fl"*
methane is.etained. Tiese membranes are available as a flat sheel oras a hollow pipe'
in suitable
Enersv R€cote.l Generator: Gas recovered from landfills is purifled and stored
;;;i;;;;;.;#, There are a varietv ofgensets ofdifrerent capacities' commerciallv
i". g.."*i""";"\ery. using lardfiligas Us$lly a standby generator is also provided'
"r",f"il" "tel;r'iciry
Methods of Gas Collection
The collection oflandfill gas is carried ou!mainly by two
methodsl
(i) Passive Pressure Method
(ir) Acri\ e Pressure Velhod
Landlill Gas Contol 119
Passive Pressure Method: In this method the pressure of Eas jnside the Iandfill is the
main driving force which causes movement ofgas. A series ofgas vents/wells is provided
in the landfill at regular intervals. Perimeter intercepting trenches with perforated pVC
pipes can also be installed for collection ofgases, which migrate towards the periphery of
landfill. The collected gas can be slored in cylinders for energy recovery if jt has high
methane content- Ifthe gas is not generated in sufTicient quantity. the energy recovery may
nor be economically feasible.
Active Pressure Method: In this svstem, a number ofgas wells are installed in the landllll.
These wells are connected with a header, through a pipe network, which is connected to a
I blower. Negative pressure orvacuum is induced bythe blowerwhich draws outthe landfill
gas. The spacing ofgas wells is such that their radius ofinfluence overlaps (Fig. 5.7).
I
MONITORING AND OETECTION OF LANDFTLL GAS
Landfillgas monitoring is essential to ascertain sk to public health and environment, to veriry
efficiency ofgas control measures, and to face Eends in gas generation and migration_ Monitoring
I
is canjed out both within and outside the landfill.lnside monitodng is carried out to determine
the quantity andcomposilion ofgas generated. Anoutside monitoring is requiredto establish
IL
themigration paths oflandfill gas in the area sunounding the periphery oflandills. Monitoring
heips in deterrniningthe concentration ofthe constituent e.g. methane, carbon dioxide, oxygen,
hydrogen sulfide. andlo measurethe pressure, flo\{ rate and temperature ofgases.
T
16 ArgrJbook ol Solidwasles Managanenl
To{adng
Monitoring techni ques can be ciassified as intiusive and non-intrusive The choice
ofa
rechnique *iii depenion lhe scale ofinvesligalion. PurPose and objectives Non-intrusi!t
parameters without disrurbing the equilibdum
techniques foc,-rs on measuring or observing cerlain
ofthe environm"nt. Thermographic surveys' infra_red photography, light detection and mnging
(LIDAR) nonlintrusive techniques used for landfill gas monitorinS lntrusile
technioues"r"ma! "o-.o,
disturb the environment where monitoriflg is carried out This lechnique
g"n.r"ily in',,oir., .ottection of samples from monitoring boreholes which can alter ihe
eouilibrium and deplele gas concentratlon.
'The gas
deteclion basically consists ofa sensor, a processing udit, a display unit' a data
logger, id a power suppiy unit. The most imPortaft component is the sensor'
Most hydrocarbons
int .uai"tion Reliable results can be obtained from a' infra_red absolption
"tA.U "-."a
based sensor. A typical sefisol consists of an infra_red source and an inf'a-red detector
(Fig.5.8). The sensor measutes radiation absorbed by a sample ofgas The signal fluctuates
availabie1o
ana'"or."rponas to ttre percentage ofhydiocarbon present Such meters are
'''-iui" quantities ofmethane and carbon dioxide over a wide range'
measure
oiuuuf" irttru*ents based on infra-red sensors designed specificall]' foi landfill
are commonl-r
sa-s-monitorrne are auailable in the market. Fixedversions ofinFa-red analyzers
ised in ,tatio-nary insLrumenlalion of landfill gas naring and ulilization
Landfil Gas Conttol 121
EXAMPLES
Eramplc 5.1: Estimate the theoretical volume ofgas that wiil be generated in a sanitary
landfill by anaerobic digestion of 1000 kg ofMSw having approxinate chernical fornula
for its organic portion as CaoHrjoosoN.
Solution:
h is assumed ihe complete conversion ofbiode$adable organic waste to CO? and CHa by
anaerobic digestion in the IandfiU will lake place. The tolal lheoretical volume ofgas may
be estimated using the following equation:
c,nro.N, + (
4a-b- +U H:O
I -l4o
- b _k - v
)cH.
_(1q -4q)co, _dr.rH,
I (i) The weight ofmethane (CHl) gas that will be produced out of 1000 Kg ofwaste
=;i4 . t000=214s6 Ke
I (ii) The weight ofcarbon dioxide (COr) gas that will be produced out of 1000 Kg of
r =Hf;'rooo=8r2re Ke
I
I
T
12 A Textbaok al Solid Wastes Managemenl
I
T
Now, the sp. wt. ofmethane at STP =0.1176Kqt|t ?
And the sp. wt. ofcarbon dioxide at STP = 1.9783 Kg/ml :
Therefore.
(1) Theoretical volume ofm€thane gas,
i,v
-,i 01116 l!1lK - nJ
'--
(2) Theoretical volume ofcarbon dioxide gas,
_ :-:::l-:
dlnc( nj
$7Al= '-' '
Hence, total theoretica, volume ofbiogas (CH4 + CO2) that will generate,
= 383.i6 + 410.85 = 794 m3
EXEBCISE
l. Whal are the gases rel€ased from a typical landfill site? Discussthe environmental impact oftl€se
gases.
2 . How does th€ quanritv and qual ity of a landfill gas change over time?
3. Discuss vario'rs factors that affect the quantity and ccmposition oflandfill gas.
4. What are likely palhways of landfi ll gas m igration? G iye su;table rem ed ial measures to control
migmtion.
5. A MSW landfill silehasanareaof l00hawithanaveragedepthof wasteof s15m. Estimate:
(r) .heooslof inslallingagas collectionandpowerproductionsynem.
(,i) the time it willtake forthe facility io become profitable.
(irr) the volume ofbiogas likeiyto be generated.
Assume suitable va,ues for any datarequir€d.
6. Discuss various monitoring methods for landfillgas g€neration.
Cbapter
nn d, Site Rerned'iotion'
conditions, suchas high pressurea.d high ternperature, there may create hajor
accident
ha"rrds.
Chemicais whirh explode underthe effec! offlame, heat or photo_chem;cal conditions I
or are sensitive to shocks or faiction are also categorized as ha;ardous.
Reactivity: Reactivity is the process whereby a mateiial is normal ly unstable but undergoes
violent changes or reacts violenily with water
Toxicity: Any waste that has poisonous effects upon human beings or any other living
organisms
is categorized as hazardous waste. Toxicit) can b" acute orihronic a"p"ra#
typeofsubstanc€andlenglhofexposureoflheliv;ngbeingstoit.ToxicirfCluiJ..i.ti"
uiorlir"
Leaching Procedure (TCLP) test is used to idenriry roiic coisrituent of w"it".. S"*"
toxicity Ievels are as folloiys:
u.*"
Csrcinogenicity: Wastes which can cause calcerare considered as highly hazardous. Such
subsrances anacl rhe normal cells of bod) and ma1 indr.rce cancerous!r,i*f,l
of rime ",", " fJ"a
Hazzrd identificalion is required to determine a relationship, ifan), between a pollutarr
and its potenlial for causing injury to human health orenvironment. Such iri*l"i.ui
inJrA"
neurological disorders or cancer, fish kills, habitat destruction or any orf,.,
deterioration. Risk ro humans inchdes kidney and Iever damage, ski; infe"ti""r, "nri,jn."naf
t;i;i;"",
eye_ disease, neurologicai disorde* and significant increase in the r-isk
ofcaa"". nl.i *r"..,*nt
techniques involve clinical srudies, epidemiological studjes, animalstudi"..
studies.
a";;4";;i;*
It is necessary to identifylhe initial or background concentration ofthe chernicals
in the
environment before commencing any project. Any increase jn concentration
due i;
projecr provides an index ofthe Iikery exposure.It is often difficuit to determine
t;;*
the initiar
concentration ofchemicals since most ofthe epiderniological studies ar"
;ft..
the symptoms of disease manifest when the amouDt or d;ation of expoa*" ""..i.d;ui
i,",
Maintenance ofdetailed recotds and continuous monitoring ofpublic he;lth;";;r;;;;;:"","f,"'#U.
can help in accurate assessment ofexposure.
Environmental consequences ofsome categories ofhazardous {astes are presented
,Table 6.1. in
Eatnan entdl
iD HandlinglDisposal of Hazardous wastes
I
I
Aspect
Existi4 air qualily, various sources ofair pollution and dEir cumulative
AnQulEy
Hazardous waste treatment and disposal strategies are usually industry-specific and ari
best implemented on the basis ofan environmental audit of each industrial unit An envirofinen';
I
praclices
auditis a systematic, documenteal, periodicand objective revie* ofoPerations and
in the industrial unit. It ensures comPliance with rules snd regulations. It can also detect
any risk olbreakdown leadingto environmenlal problems Fuaher, the aud it can also
examine
the possibility of minimization of wasle streams.
Apart from audits, other management $rategies for hazardous waste management include
Iife cycle analysis. volume reduction, loxicity reductio ' recycling and reuse, avoiding
wasi;mixing, tnd good housekeeping practices. A periodic review ofhousekeeping procedures
(Table 6.3) is necessary. Training ofstaff is a major element in the implementation ofthese
practices in any facility.
Hazarclous4astesManagamentandsite Remediation
W
Trblc 5.3: Good Housekeeping Pracrices
a.cluntin9alloc.dion aod a@undne done for all wa$e sbEans l'aving the faci liti6
Cost
oirn"*. *nt*-o**ent -d disPosal co$srothe operations fial
Source, USEPA(1998).
(Best Possible Environme al and Economic
The well known British Practices e-g BPEEo
Nor Entaiting Excessive cost) can be
*,i""i (ilest Avaitaile Techniqu€
ii"pi.l ""j-s"fl,tirc
i"t a*la;rg ,pon lhe management strategy for hazardous wastes'
1A ATexbook ol Solid Wastes Management
Trealment and disposal techniques for hazardous wastes include Chemical Oxidatiod,
I
-
vitrification, Incinemiion, Pyrolysis, and Land disposal- Incineration, Pyrolysis and Land g
=
Disposal have been described in the Previous chapters Chemical oxidation, vitrification
and design ofhazardous wastes landfills are briefly discussed hereunder.
=
Chemical Oxidation =
Itis awell eslablished technology, capable of destroying various organic molecules including
chlorinated volatile organic carbons (vocs),
phenols and irorganics (such as cyanides)
present in the hazardous wastes. Che ical oxidation is typical ly applied to liquid hazardous
wastes and contaminated groundwater. Solid hazardous wasles mayalso be treatedthrough
this technique, Wastes may be converted to a pasle or slurry and then treated in reaction
vessels.
Chemical oxidation is carried out in "compietely mixed" tanks or "Plugflow" reactors.
Oxidizing agents are added at the entry poiflt olthe reactor. Complelemixing ofslun1 with
the oxidizing agent is achieved by mechanical mixing, pressure drop. or by injecting air
into the tank. The end producl after the redox reaclion is lesshazardous in nature and can be
disposed offon a secured landflll.
Vitrilication
Vitrification is the process of stabilizatioD and solidification of wagtes to make it structurall)
stable with a reduced potential for contaminant migration i[to the environment lr is basically
similar to glass making. The process involves meltiilg and fusion ofmaterials at high temPe.ature,
followed by rapid cooling into a non-crystalline, amorphous form- vitrificaiion has been
used extensively for soil remediation.
vitrification has several advantages as a waste management lechnique The technology
emp loys a furnace operating normally at teoperatures higie. than I 600 'C. Initially a stafier
mix ofrecycled glass, flyash, aod limestone is used to start the process- The wastes to be
Eeated are then fed into the fumace. for meliing and fi$io( for about five hours. The technolos
is used to treat the hazardous wastes andlo produce a stable Product.
Site Selection
Hazardous waste Iandfillsshould be located in an area of low population density,low altemative
landuse value,low ground water contamination potentialand less permeable subso;lstrata. The
Hazadous Wastes Managemenland Site Renedianoh 129
\{;nis!-1 ofEnviron nent and Forests (MoEF), Govemment oflndiahas also laid do!fi procedlre
:or selection ofa site for hazardous waste landfill. The steP by step procedure is as follows:
. Earmarking a'search area'taking into accountthe location ofthe waste generation
units and a 'search radius' (typically 5 to 250 km). The search area will be so chosen
that it minimizes the number ofhazatdous waste landfiils in any region or state.
. Identification ofa l;st ofpoaential sites on the basis of
. Availability of land
. Collection ofpreliminary data
. Rest ctions listed in the locational/siting crite.ia
. Collection ofp.eliminary data fiom various sources e.g. lopographic maPs, soil maps,
Ianduse plans, transpoftation maps, water use plan, flood plainmaps, geologic maps,
sateiiite imageries, goundwater naps, .ainfall data, windrose, seismicdata, sitevisils,
preliminary boreholes atd geophysical investigations.
. Selection of two best ranked sites from amongst the list of potential sites on the
basis ofthe ranking system siipulated by MoEF.
. Environmental Impact Assessment for the two sitesfor various parameters includi[g
groundwater quality, surface water quality, air quality Gases, dust, litter, odor), landuse
alteration, drainage alteration, soil erosion, ecological impacts, noise, aesthetics,
vermi., flies, traffic alleration elc.
. Assessment ofpublic perception for the two sites
. Selection offinal site
Criteria recommeflded by CPCB and US guidelines forselection ofsite for hazardous
$astes landfill are given in Table 6.4 and Table 6.5.
Tsble 6.4: CPCB Criteriafor siting Hazardous wasle Landfills
Desndhle Condilions
Surface warer Bodies No landfll shall normally be constucted within 200 m ofany lake or pond.
River No landfill shall be constucted within I00 In ofa navigable river or strem
Flood Plain No bndfill shall b€ consEucted within a I 00 ye3r flood plain. A lardfill may be
consnucied *idrin the flood plairs ofs€rondary stEans ifan eftbankment is built
along tle strem side 10 avoid flooding ofdle area. However, laodfills musl not be
buill within the flood plains ofmajor rive6 unless properly designed protection
embankhents are constucl€d amund the landfills.
I Hid'"ry
Habi6ion
No landfills shall be constucted witlin 500 m of$e nght ofway ofany slaE or
ir ional highv!'y.
be at ieast 500 m fiom a notified habitated atfr- A zone of500
A landfll site shall
I
m around a bndfill boundary should b€ declaled a no-development bufier zone
atEl dE ledfill locdion is flrlalizld.
Public Park No landfi]]shall be const ucted within 500mofapublicpark
No hndnl shall b€ constuctEd wi6in cdtical habit area including i€serwed turest
I
Critical Habitar Area
areas. A crirical habitat area is the one in which one or more en&ngered speci€s
li\€.
Table 6 4 \cantd ak p- l3O)
I
I
I
13O A Textbook ol Solid Wastes Managenent
InflFaic,n
well 10
0.6 - 2.0
well dninage
iDh
I % organic
I
Hazarclouswaaes Managonent and Sile Remedianon 131
8. Biologicol Low ecological \€lue, low speci€s Habilal for rare or endangered
E.lo$/ dive$ig and uriqueness
being transported to the landfill site. CPCB has laid down guidelines for acceptance of
wasies at hazardous waste landril sites, These aae as iollows:
. Alt wastes shall be acceptedonly ifthe truck carries aulhorized documenls indicating
the source and type ofwaste. Such wasle shall be routinely inspected visually at the
tipping area in the landfill site.
. Bulk or non-contaminated liquid ha"ardous waste or shrry-q?€ hazardous waste conlaining
free liquid or sludge, which has no!been dewatered, shall not be placed in landfi11s.
Suchwastes shall be placed inhazardous waste impoundments designed specificall!
for liquid hazardous wasle.
.lncinemble/compostablewastesoranyothertypeof\rrastefromwhichenergy/material
recovery is feasible, shall noi be placed in hazardous wastes landfills.
. Iflcompatible wastes i.e. any two types ofwastes, which could result in aggressive
chemical changes after coming in contact, shall nol be placed in the same Iandfill
unit. Compatible wastes will be grouped together and placed in the same landfiil
unit (each such unit shall hale its own phase, cells etc.). Incompatible wastes
group shall be accommodated in separate landfill units.
. waste that can cause damage to the linermater;al shall eitherbe containerized before
disposal in landfillor be placed in a separate landfill unitmade ofaltemate compalible
liner material.
. E*remely hazardous wastes e.g. ndioactive wastes shall not be disposed off in hazlrdous
wastes landfills but in specially designed wastes disposal units.
. Non-hazardous wastes e.g. municipal solid wastes shall not be deposited in hazardous
wasles landfills.
. Residues system should bedesigned specifically for each landfill. Howeveraminimum
oftreated biomedicalwastes e.g. inciDerator ash caD be deposited in hazardous wastes
landfi lls.
HOSPITAL/BIOMEOICAL WASTES
An important category ofwastes, rapidly increasing in volume, is biomedical waste. These
should be properly treated and disposed off to avoid risk 1o the public health. Apart from
commoD ailments l;ke eye irritation, asthma aod other health disorders it may also lead to
deadly diseases such as AIDS, tuberculosis, and skin diseases. In Delhi, on an average a
hospilal generates 3 Kg ofwastes per bed/day including bottles, cotton, plasters, syringes,
needles, bandages, human organs, as well as wastes from X-ray and radiological departments
Hazadouswactes Managiernent and Site Remediation 133
l.
€ 3? f h!
2 9c -.=';: d
o0: F-o"i3
.9 pE+ .18
g
;>i
E.e;::o
,'na 9a=q x--
"-
b3
-"
tzie.9,2v. 912
z
=-=:'+Yt z:.-d
!
=3- 5 &=
{; : i : It
6 h Hs
ea!gc;i"iE, .{E*
:iE!zb;E5a 63Dx
v.9Zs:.93iai .!;i uaAa
35-40
Cloth & Badage
lnfectious wastes lNe€dle & Srdnge etc ) 1-2
20-30
Biodegndable
9-t2
Paper & Hardb@rd 8-12
Metals
t-2
E-r0
Bio€sistani 5-10
2-5
Colegory
heament and DisPosol
Incinerdtior/adoclaving
ttems contaftinated with blood and bodv
fluids
includins mtton. drestines' soiled Platt€! cats'
iines. u.iain es, oder maerial conBminaed
with blood
Disinfectjor/autoclaving/
u rst€s senerated from disposable items other
rhe $a
waste sharps such as tubings. cdiel€rs inEavenous ;uildioi, sluedding
DsinfeclionDischarge inlo
Liquidws(e
drains
waste senerded fiom Laboralory and washtng'
disinfectingacnvfi es
cle-aning, house keeping,
Disposal in SecurEd lardfills
So//ce MoEF(1998).
Treatmentmethodsincludebu'ial,autoclaving.incineration.microwaving.shredding.diSposal
and Land
t" h#;il:il;; i;;arment etc shtedding' lncinemtion chem ical Treatmen{'
pre t ious chaplers ' othe r sPec lallzed lecrnlques
oi,oo'ut'".t,niqu"' r,."t. been described in the
ing are discussed hereunder'
r iz. eutoctaring. ana Vicrowa!
Autoclaving
Adtoclavineorsteamsterilizationisalo*.heatprocessdesignedtoprovidedirectcontact
the waste malerials'
I'f *"itli *. ti"". in a coDtrolled manner in order to disinfect
"?*
ii"r" typ., ofautoclaves commonly used viz Gravitytype' P'e-vacuumtype' and
".",1,.""
'--j"Retori tYPe
the
pressure is used to evacuate the air from lhe treatment
in" iiir,ity ,yp"
^utoclave' ofabout 120 'C These systems require
chamler. lr typicalil operales a! a srcam remperalure
complete penerration of steam inlo the mosl
, ir oo L io minures to achieve
"""L-,r-.
_-in-u
densely packed waste load'
pi"-r""rur,yp. autociave, aii is evacualed from the treatmenl chamberby vacuum
p";;.. i;;;;ti;. is less i e about 30 - 60 minutes' Pre-vacuum svstem lvpica'lv
operate at about Il2'C
'A R"ton type consists oflarge volume treatment chambers designed for
much
"ulo.luve
temperature and pressure'
higher steam
T,b1.6.9: Color Coding and TvPe ofContainer for Disposal ofBiomedical wastes
Plasticbags
1,2,3,6
Disinfecled contaioeE/ Plsstic bass 3,6.7
Rd
Bluo^ hite Finslucenl Ptaslic bags/pu.dure proof conkjner
Plasfic bass
5,9,10
Black
Systens
Descdption Sleam stqilizaion Microwave h€ding Hi$ Mixingp!e-
(DirEct heating) (wit pEshr€ddins
N€eliejble
Moslly ash.
Chamcteristics be shredded)
Operutlng Slandads
. Combustion efficiency (CE) shall be at least99 00o/o'
Emission Standads
Concentration (mgNm3) ar 120/o CO) Coffection
150
Paniculate Matter
450
Nitrogen Oxides
50
HCI
to the follo\ring:
a vacuum autoclave, medical waste shall besubjected to arninimum
ofone pie-vacuum pulse to purgethe autoclaveofal air tle waste sha be subjeoed I
r
.
a tenperat,.lreof not less than i2l "C and pressure of 15 psi per an autoclave
-e"idence LiTe ofror Ie.5 lhan 45
miDJres: or
a temperature ofoot less than 135 oC and a pressure
of 3l psi for an autoclave
I
residence time ofnot less than 30 mioutes;
. B iomedical
\a asre shall not be considered prcperl) rreateci
I
Hazadousryastes Managenent and Stte Refiediation 139
pH 6.1 - 9.0
Suspended Solids 100m91
Oil 3d grease l0mgl
BOD 30 me,a
COD 250me4
Bio-assay test sool" ;wival of fish after 96 hours in 100% effluent
BADIOACTIVE WASTES
emlsslons
Radioactivity is deflned as lhe proPerty possessed by some elements ofsponianeous
p"rii.r.. f"l. u"tu puili"i.t ip1. o' totetimes, gamma rays (l) due to disintegralion
"i"ipt "
oflhe nucleiofaloms.
16 ATextboak of SolE Wasles Managenenl
Radiation from alpha particles loses energv very quickly when Passing through ma$er'
the
As a result, alpha particles travel only a few inches in air and can easily be stoPPed by
outer layer ofhuman skin. But they are harmful to humans ifthey are ingested and can
damage body oigant specially the lungs.
gel raaiation traveis farther as comparedto alpha radialions' These can penetrate several
layers ofhuman skin. The human body can be damaged by exPosure to a source ofbeta
radiation or by ingesting it. Betaradiation canbe stopped by an aluminum foil at least2 mm
thick.
Gamma radjation has a much smaller wavelength and can therefore penetraie much deeper'
Itcan pass completely through the human body damaging cells or can be absorbed by tissues
and bones. Damage to human health is therefore much larger. At Ieast three feet ofconcrete
or t\r'o inches oflead are required to stop 90% ofthe typical gamma radiation'
The process of unslabie nuclei giving offradialion ao reach a stable condition is called
radioaciive decay. Isotopes ofelements havingatomic number larger than 83 (Bismuth) are
radioactive. A few elemenls wilh lower atomic numbers, such as Potassium and rubidium,
in
have nalurally occurring isotopes which are also radioactive. Radioactivity is measured
the
terms ofcurie (Ci), which is defined as the quantity ofa radioactive material in which
number ofd is inlegations is 3.7 I 0ro per second. Each radioactive element has a characterisric
"
speed ofdecay, so that each elemenl can ire characterized Thetime it takes for halfofihe
element to decay, is called lhe half-life ofthe elemen!.
jn units called rcms. A rem is the amouni
The biological effecl ofradiation is neasured
of beta or g;mma radiation ihat transfers a sPecific amount of energy lo a kilogram of
matter. An;xposure of3OO.ems for 3O days would resull in death of50o/o ofthe persons
to
exposed. The permissible level for occupational radjation exposure is five rems peryear
th; whole body. It is believed that this level can be absorbed for a lifetime wiihou! any sign
ofbiological damage. lntemational Commitlee on Radiation Prolection has established strict
safety standards to ensure that exposures to workers is minimized and thai the public is not
exposed to mdiation from otherlhan the natural background (Table 6.11).
Unit
fab.ication and use offuel rods etc. AII these activities produce low-level radioactjve wastes.
Hospitals, clirics. research laboratories etc, also generatethese q/pes ofwastes, asthe useof
radioisotopes is rapidly becomingcommon e.g. in cancer trealments.
Class R Class C
Highest conc€irations
Requircs stabilizarion
S€Ieealion ClassA mustbe No need to segregate No need to segregate
segegated from B from Class C from C]ass B
ard C
Prote{tive clothing, Resins and filters
high a.tivi9 indusrial
plana
FLY ASH
Fiyash is a major by-product in the coal based fhermal power plants. It is a fine1y divided
residue resulting from the combustion ofcoal in a thermaj power plant_ It is generaliy grey
in color, abrasive, acidic. refractory in nature and has fin€ness (specific suiface) of+-000
to 8000 sq. cm per gram. The particles range in size from as much as l20 to less than 5
microns in equivalent diameter. The part ofash that falls to ihe boftom ofthe boiler during
combustion is called bottom ash, *hich is coarsor in size and is washed awav with water.
Ash. which is fine and is carried away with flue gases. is called as -Fl\ ash . li is separated
Hazadaus&asles Management and Site Renedhtion 143
Ftyash OisPosal
oi,po,ur ornr",t i,.u.ind"I.r,i::1rf;,'nlf*i:'ifilffiiJ::il.SiH'[."1]'",;"X
prperrnes rn n'E.'"'1"."-'l:],':"'
rlants 10 the ash Ponds rhrough :;,;".,,,,. r. *r;r"Uf.
;. ,.;,"r.1."*rr.,,"" ,nd mandfacturing operations. A grear deal ofof lilemlure.rs
aYarli
marerial' some of these are as
iii,]."ri,ii"ii"" is a consrrucrion
especiallv
foliows:
"iorash
SITE REMEOIATION
ofpublic interest- The burT:l]l!f**tt""
ii","."a;ution t u, t""ome one ofthe hot areas
the cosl of land makes iI ine\jtable to
i.r*i"f,, i, ,fr. ,,0- areas and the steeD rise inContaminatlon of land is usuall) due to
.tlrr" *,iii-a is nol lost due to conlaminalionindustries' This is further compounded b)
ilii"""i ii i^r"'a"rt *astes on it largelv fromof hospital. and slaushrei.lgl:: *-':'
i;:',""'.td";;;r;r;;. le g o ill or aumiing "'
pesticides' spravs also
dves' acids
il;;;;fi;'i;ffi Jclpuinit' tut'"'i""-o'edicines'
I
I
lU A Textbaok of Solid Wastes Management I
contribute significantly to the contamination oflands.Land contamination poses
health_riskto human beings and to plants in such areas. Contanination ofland
may also occur due to leachate through hazardous wastes.
serjous
oig.oundwater I
Remediation techniques for contaminaled lands depends upon
(l)
(ii)
(iii)
soil characteristics,
conlaminant characteristics. and
I
legal and social requirements.
Soil characteristics importa.r for remediation are particle size distributioo (percenrage
ofcla_y and sitt), shear strenglh, porosity and permea bility. Other imponanr
factJrs inciuOe.
I
pH,ofgroundwarer and fhe soil and rhe pesricide conteni etc. The d;prh
ofwateria;i; and
vadoze zone and moislure content ofsoil are also impodant parameters. Climatoloeical
factors e.g. the ambient air rempemture, rainfalt erc. ari also considered.
Ch"-;. ;;;"n,
I
I
naturally in the soil e.g. chlorides, sulfates. carbon. nirrogen and rhe profile
of iarious
nutrients and metals present at the sjte should be analyzei before select;ng particuiar
a
remediafion technique.
The nature and characteristics ofconlaminanl in lhe soil should be estimated.
Physicdl Tteatment
Excavation and Removal: This is a simple method suitable where volume ofsoil
I
treated is small. The contaminated soil is excavated and disposed away
secured landfill. Importantconsideration in thjs melhod are the type ofsoil,
and ihe location ofthe area
to be
irom ttte iite_on a
typ" ot"onturnin"nt
I
I
I
I
Hazardouswastes Managemen and Site Remedtalion 145
SailWsshing: The soil may be washed insitutoremove the conlaminant. A leaching agent
na) be adde; to water and a pressure gradient is maintained. Water for washing is allowed
:o ;nler lhe soil by construct,ng horizontal galleries or boreholes. The leachate is then
::iercepted or pumped out fortreatment This technique is good for nonhalogenated volatile
r.Sanics
-In
with good soil permeability but is not suitable for clays.
the ersirmethod. ihe excavatedsoil is removed and washed in a contain€r' The water
:a) enter from the lop and collected al the bottom for its treatment before it is finally
iisposed off. The washed soil may then be teplaced to its original position'
Soil Vapor Extractionl lnthis method air flow is generated through awell creating a pressure
iadie;. The air removes volatile components from the vadoze zone. This technique is
lsoecially good for halogenated, volatileand fuel hydrocarbons. Thetechnique is not suitable
if;ir perfi;ability is low or when carbon content is high or temPerature is low.
Thermal Trcatment
lBciDeretion: Thermal trealment is esPecially suitable for remediation ofcontaminants in
ihe yadoze zone. The soilmay be excavated and heated ata high temperature inthe presence
cfoxygen, i.e. at aboul 1000_1500 'C. The organics aie destroyed and lhe volalile fraction
is remived. However, metals are not destroyed. This method is good for both halogenated
and nonhalogenated coniam iflants inc luding fuel hydrocarbons. Ciay or rockfraction should
be removed from the soil before apPlying the heat.
Vitrification: In this technique heat is apPlied to the contaminaled soil causing a melt
\ah'ch moves clownward. It mobilizes the organics and destoys the volatiles For insitu
!ilrification ]arge Sraphite electrodes ate inserted in the soil in a g.id pattern (say l0 m x
l0 m grid). A high;lectric current is appiied resulting in the generation ofheat which fuses
rhe m;terial. Afier sitelsoil is cooled, the final material is iner!. The technique is good for
Iong lerm stability but consumes iarge amount ofenergy.
Chemical Tteatment
Chemical treatmentcan aiso be carried out insitu or exsitu. These areessentially stabilization
rechniqLres *hich have been extensively developed. The contamiDated soil is mixed
with a
binding material to reducemobility ofthe contaminaflts Suitable binding material s include.
lime (f;r clays) cemenl (for sands) and thermopiastic bi.ders. Thermoplastics binders are
available in a variety oftrade names Prolection may be required for soils with high content
of oil, grease, or surfactanis. Stabilization lechniques are suitable for sludges or slurries
conram-inated with inorganics. These are nol ver] effective for clays or for soils with high
organics, sulfates or chloride conlent.
Biorcfiediation
Both insitu or exsilu biolrealment melhods have been developed The contaminated soil
is
heaped in piles and allowed to deg.ade the contaminants through the natural action ofth€
micioorganisms in the soil. lmportanl factors affecting the.ate ofbioremediation lreatment
l+-
=
146 A Texl,baok of Solid Wastes Managehent
ir\clude oxygen content, I]utrient content, moisture content! pH and tempemture. Oxygen
ma) be suppljed through blowers or the soil may be frequently turned to ensure aeration in
the enlire soil mass.
Microbes require several nutrjents for their growth. These nutrients may be added if
.equired. Microbiai activities accelerated in mo ist condiaions. Therefore water may be added
to ensure a high degree ofmoisrure conrent atl ofthe iime i.e. abour 40-5Ooo. Some microbes
thrive in acidic and sorne in aikaline envhonment. pH should there{ore be maintained within
the range 6 - 8.5. The idealtemperature formicrobial activities is about 45 .C.
The success ol b ioremed iation methods deperd upon ho\\,well the above factors ar€
confoiled: Treatmentmavbe carried out insitu(e.g. composting)or the soil maybe fansferred
to a treatment plant for treatment in a controlled reactor. The treated soil can be replaced
on the sile afterrYards.
B ioireatment techniques are good for removing allbiodegmdable contaminants esDeciajlv
h) orocarbons..lnsilL mettod) are good tor nonialogenaled volatiles. jn $is Lrearmenr.ioxiciD
is greativ reduced. However this techniques is no! suitable for Iow permeabilily soils.
Slurry Biodegradation: This is an aerobic exsitu technique suitable for hvdrocarbons and
biodegradable contaminants. Theexcavated soilis mixed in a reactorwith witerand nutrienrs.
Temperarure and pH are also controlled. This technique is not good for pestjcides, heavy
metals or chlorides.
Rootzone Treatment: Il is a recent lechnique used for soil remediation. Various types of
contaminants. This technique is good for removing heavy metals present in the soil. Aeavy
meials are uptaken by roots ofthe plants along withthe moisture. There are various species
ofplants \vhich are used for soil remediation depending upon their deptl ofrooko;e and
the rype ofsoil. Schematic ofa typical rootzone treatment system is shown in Fig. 6.1.
Graves
RISK ASSESSMENT
Risk assessnent (RA) is defined as the characterization ofthe potential harmful effects on
human heahh due to exposure. It is a systematic collection of information about potenlial
I
Hazadgus Wastes Menagpnenland Site Benedbtion 147
risks and evaluating them for necessary aclion. Risk estimate ofharmful or adverse effect
on health (due to chemical releases) is often expressed as the ratio olpredicted concentation
ro no-effect (or safe) concentration.
Risk assessment may address any ofgnvilonmenial issues but it primarily focuses on
health and safety ofhumans, animals and plants. Abaodoned lEndfill .ites after closure are
ofren Iater developed for public use e.g. as parks, or other development projects. Many
noxious gases e.g. methane and mercaptines continue to be generated long after the iandfills
are closed. In all such cases a risk assessment should forh an integral part ofEIA process
for ary development project on such sites. Risk reduction measures ana! control and emergency
response options are also included in risk management.
ldentlflcation gl Hazards
This is asystematic examination ofvarious Project components and activities to determine
source ofimpact and the potential recePtor. The likely acute, chronic or fatal effects on
receptors are identified. Hazard identification can be carried out by using checklists or
though field surveys. Impacts ofvarious hazrdous substance on human health are presented
in Table 5.13.
Heakh Elfects
1. Pe$icides
. DDT lns€.licides &ncs, damageto liver, ernbrlos, ard bird eggs
. BHC lrse.licides Cancer, embryo damage
2. Penochemicals
Headaches, naus€€" Ioss ofmuscle coordi-
narion, leuk€mi4 damage to t'one mano$,
. vinylchlond€ Plasti6 Lung and liver crncer depression, darnage to
c.nlral nervous sfstem
l. He-avy M€tals
Neurotoxic; caues h€da.h€s initaiioq nertal
impqilmeiq bmin, Iiver, and kidney damase
. Ca&iiurn zinc bar&ries, fertiliz€rs Canc€r in animals. dam€e to liver ,,d kidn€rys
Chemicals ofpotential concern are identii€d using €rious indicalors e.g. toxicity, pe.sisterce,
ard mobility. A to-xicity score may & developed for each cheoical by multiplying the maximum
concentration with its carcinogedc potency factor. ID th€ case of non-carcinogenic chemicals,
the ioxicity score is obtained on dividiag the maximum concenration by areference dose.
Potency factor ofvarious carcinogens chemicajs is presented in Table 6.14.
1.75 50
Benzale .
2-q lo-2 2.9 , tO-2
CnJnium 6.1
Carbon tet achloride 0_13
Chloroio.m 6.1 x 10-3 8.1 r l0-2
Chmmium Iv 41
DDT 0.34
l,l -Dichlomethylene 0.58 1.15
Deldrir 30
1.4 x l0_2
Metnyl chlonde 7.5x103 i.+ , ro.
Nickel and compounds
PolychlonnaEd biphenyls (PCBS) 7.7 t''
!'
2,3,7,8-TCDD(dioxin) 1.56 105
Tnchbrced'ylene (TCE) 1.1 l0-2 l3xl0-'
viryl chlodde 2.3 0.295
Hdzatd Assessment
it includes determifiation ofthe probabilify ofaccidental ieleases; quantificalion ofrelease
rates and calculation ofdose; and duration of exposure. Accidental events may be due to
human enor, equipment failuie, during mnsportation, or due to a catastrophe, Various technjques
e.g. HAZAN (Hazard Analysis), HAZOP (Hazard Operability), or FTA (Fault Tree Analysis)
have been developed used forthis purpose.
Quantification ofchemical releases and rates duiing dayto day \vorking is an important
parameter of hazard assessment. Models aan be used for quantification ofexposure through
air, water, and soil exposure to receptors. Modeis can be developed for calculation ofdose-
response relationship. A flow diagram ofvarious possible routes ofchemicals exposure to
humans and animals is shown in Fig. 6.2. Health effects ofexposure to chemicals due to
broaccumularion are presented in Table 6.15.
Table 6.15: Responses to Chemicals Exposure
S€nsitive Dermalitis5 6h
Mubgeric
Embryo, Gtus binh def€.1s
Damage to DNA sEuctwe
I
I
Cartinogenic Cancers
1
I
llazadouswastes Meragiament and Site Remectation 149
5.2
Cadmiuri 81
19
Chlorcfonn 3.75
ClEmiwn l6
Copper 200
DDT 54000
I ,l -Dichlorc€thylene 5.6
DieHrin 4760
87
Nickel and compounds 47
Polychloronicated biphenyls (PCBS) 100000
2,3,7.8-TCDD(dioxin) 5000
Trichloro€$ylere (TCE) 10.6
Vnyl chloride 1.17
5,10r
0.1
T
Cadnnnrl
I
0.01
Chlorofonn 0.009
I .I -Dichlo.oelhYlene
0.06
Medryi Chlodde 0.04
I
0.0001
PCB 0.01
0.3
0.09
.l .l -Tncholoroethylene
t
1
30
cFC-11i 20
Xylene
Risk Estifiation I
ni.i",,i.u,ion.,nt.usedloLonpareahernalivestlategies,.lhisisanadditionalinD'l e\ aluallon
olher indicalors e g' the cosl ol project' R'sk
i'"',
"..i"'""
rnrl. i"g
i;;;;;";;;;i;;;;'t.k "ronc*'rlh
iia"ceptabie or nor' c''ridilines standaids
medium to which recepror is exposed'
are sel relative to the
I
Hl = Toral Dose / Rp
is lhe sum ofalle\posures e g duetoinhalation
,^hereHI is th:'h"za;;irier"Thetotaloose
: e!ii"_"'- .. rres. lhan l 0 implie'no hazard or no_ri)L
-^^.,^- --,r
lngesrrurr
h.',rprm,r
d'Lu eJ --' A ralue ofHl less
lrma\benoledlhallhereisal*a}sanelementofuncena.ntlinLheassessmenloIri.L
,, it u' u"t oi risl'q are made baseo upon e\perrence and
'l;::'$;ih;;;;,. 'iin,"''"
l",t;"'.'i;;;;.:;t"hrcharerheoreticallvPossible'rherisrcanbecompuredb)usinB
the follo\r'ing exPression (6.1)
(mglk?/dayx PotencrFactartns/k8/dav)-t
Risk = Chronic Dailv Intake
according to the body weiSht and average
The chronic dailv intake (CDI) is estimated
life exPectancy.
(tcc) 1,",og" Lif" Govt)]
CDI (thg/keida.l) = Total Dose hs) / [Body veight " ...qa.z)
Tctul Dase = Cancentratioh af.chemicat t n^E af food ' Intake rute tkg offaod.lay)
follows.
Concentration infsh h!/Kd = Cancentration in vlati(ng/l)
t mul at i oh F ac t or ( l/'kg) . (6.4)
B i o ac cu
Risk Managefient
a strategy forits
,A.tt", iaentified and estimated the next step is to develoP
rl.t i", l".n management
"
l^'."*rn"* ofrisl5 potenlialhave to be examinedto devise asuitabie
orthe risk esiimated
^1""r"* ouuio,,5 a"p'na on
:iil:?;:::;;;,"tii;il' tt'" nature and magnitude
. Derermine ifother altematives/options are available, which carry lesser risk ofexposute.
. Eslimate the cost ofavoiding and/or reducinglhe riskto acceptable limits.
S::?regi€s should be deveiopedto reduce the quantity ofha?ardous waste generated and
: ,_:ssible. to change the charactet of hazardous wastes geflerated e.8. by changing the
_-=:^:oio9, subslituting allernative raw marerials with less hazard potential.
::. rolal risk assessed must be compared with the acceptable sk to devise any risk
-,a-:gemenr plan. The risk management strategies are developed by decreasingthe chances
:: :\losuie or by decreasingthe concenuationofthe exposure - usually both. Human exposure
:::- ). limiled by isolation or by providing physical barriers or protective clothing e.g.
--5:(s or shields.
leuse. recycling and treatment of hazardous w.tste should beexamined before its is finally
: .lcsed offon a secuied landfill. k is also essential thaivarious guidelines and statulory
:i:!:sions laid down by govemment, CPCB ol other aulhorities ate implemented strictly.
:'j11) all hazzrdous emissions orwastes should be captured in acradleto gmve managemett
The obj eci of LCA is to uncover envircnmental consequences of a product or more geneml ly
the function which the product is designed to perform. It is one more decision support tool
supplying informalion ofl the environmental effecls ofproducls, It furnishes information
on the environmenlal effects ofall the stages ofa product's life cycle. This information is
very valuable to the decision maker-be it govemment, industry or individual.
There are many good reasons lo use LCA as an environmenlal management tool, It i5 a
product-oriented. integraled. scientific and quantitative approach. The use ofLCA technique
avoids problem shifting one stage of the life cycle to anotheri or replacing one sor! of
environmental problem by another. The process ofpreparation ofLCA requires time, skili
and money.lt also requires a methodolog); a greal dealofdata and software to analyze data.
It would obviously be a great help ifstanda.d databases containing data on process are available.
A unified frame$ ork for LCA needs ro be developed in our country for easy communication
and training of personnel.
The LCA methodology requires inventorization of pollution ioads of a producf at all
stages from the raw material procurement to the final d;sposal consecutively, ,ncluding
manufacturing! energy consumption, and transportaiion. The lotal pollution Ioad and its
impact on environment should be compared with sim!lar LCA ofolher alternatives. Va.ious
sLaBes of LCA are preienred in Fi8. 6.j.
Fig. 6..1 shows an ourline ofsystem boundaries for production process ofbar soap. This
indicates various aspecrs to be included in the LCA ofsoap. Tallow is the main ingredient in
soap production and irs primary ra* nalerial source is the grain fed 10 cattle. Therefore
Heza/douswastas Maragemenlend Sitd Remediation 153
+ SoId
grain production and cattle raising are included in the Iife cycle assessment
ofbar soap.
The production ofpaper for packaging the soap is also ioctuded in the system boundaries.
Fate ofboth lhe soap and its packaging are included in the life cycle analysis ofthis system
EXAMPLES
Example 6.1: A person weighirg 65 kg consumes an avgrage of50 g of fish every week.
The ish has been caught ftoln a pond with a concentration ofDDt eq-ual to l.O ppb (0.001
mg/L). Estimate the maximum lifelime risk ofcancer due to this exposure_
Solrtion:
The Bioaccumulation factor for DDT = 54000 (from Table 6.16)
The expecaed concentralion ofDDT in fisb is therefore
= Concentration in wate. x Bioaccumulatioh Faator
Ifa
= 0.001 x 54000 = 54 rng ofDDT perkg
person, weighing 65 kg. consumes 50 g (0.05 kgr of651
day) the chronic daily inrake is (Eq. 6.2),
offish
p., *..L (
(Eq.6.4)
i.e. 0.00i I kg/ I
cDl
UsingEq.6.l
=(0.0071 x 54)/6s
= 0.00593 mglkg ofbody weighr I
Risk = CDI (mg/kg/day) x Potency Facror (mg,&g/dayfr
. =0.00593x0.34
= 0.0020i7 or 2017 x 106
I
or about 2000 persons per million are at risk due to this exposu.e
Exrmple 6-.2: A worker weighing about 70 kg is exposed to a carcinogen (avemge concentration
iD air = 0.01 mg/mr)for8hoursperdayfor.]oOdalsperleuro-r".up..i-odof30r.".r.
I
Average breathing rate ofworker is l.O m3/h. Estimate the risk ofcanc;r
has a po€ncy factor of0.l {mg/kg/day)-'. Assume average Iife oflvorker
Solulion:
if the carci;ogen
to be 65 yea;s. I
From Eq. 6.3,
Totaldoseofcarcinogen=0.0img/m3xl.Om3/hx8h/dayx3O0days/yearx30),ears
= j20 mC
t
CDI
= 720l[?0 kg x 65 years : 365 days/year]
= 4.3 x 10r mg/kg/day
Risk =4.3 x l0r mg/kg/da), , 0.1 (mg/kglday)-l
(Eq.6.2)
I
= 4.3 r 10r
About 43 persons out ofone million are at risk of cancer.
T
EXERCISE
1
2
What are the main characreristics ofha2ardous yastes? Dhcuss the inpac!
. Discuss various techniques used for t.earment and disposat of hazrdous
on huma, heatth.
wastes?
l. What are the caregories ofbiomedical wastes? Discuss rhe merhod ofrreatrrent and djsposal for
I
4. How are radioacrive wanes ctassified. Explain rhe methods ofderection and
disposal ofthese T
I
)
,
Hazatttouswastes Managementancl Site Rernediation 155
=
I
I
Erup ir o nrnent o I Irnp a c t I
Assessrnerut I
I
Environment Impact Assessment is an objective analysis ofthe probable
changes in the Fhysical, biophysical and socio-economic charaiteristics I
I
ofthe environment from a proposed project. The prediction and evaluation
of the environmental consequence enables the planne$ to plan better
ireparable damage to environment and to ensure sustainable
so as to avoid
developmeDt.
Every development proj ect isplanned to changethe existing environment
for some benefit. Unfortunately often such development; bring in its
wake many unintended harmful side effects. It is essential ther;fore io
I
lake into account any likely negative impacts in plannjng a development
project. Both short term and Iongtel1 consequences are io be considered
to ensure sustainable development e_g., ..,./rjli, ation o/ existing resource,
I
/or fulfLling present needs \rithout threatening the abilit, i the futurc
generations ta meet their needs,'. A)l changes sbould howeve, be such
thalthe environment is not adversely affected. A sustainable development I
I
ensures that the developmental activities do not strain the environment
beyond its capacity and the p.oject does not overdraw from its ecological
and environmentai assets-
I
Over the last two decades most countries have enacted suitable legislaiion
requiring a comprehensive environmental impact assessment (-EIA) of
all najor projecrs at the plaDnirg stage irself. EIA is a process wheriby
information about the future environmental impacs ofa project is predictej,
assess€d and taken into account in deciding \yhether the project should
go ahead, should be modified or abandoned.
I
I
LEGAL FRAMEWORK
The Government of India has enacted a number of Acts fiom time to
time for the protecrion of environment in the country. Notable are the
I
Wat€r (Preve nrion & Conrrol ofpollurion) Act of j 974. lhe Air (prevention
I
I
Envitunmentallnpaclassessnent 157
passed in
& Control ofPollution) Aci of 1981 However, the comprehensive legislation
isii i; t.rry " *ir".tone in the field of environmental e g the Environment (Protection)
-q.i. r9g6. iit" ,{.t ptovides for the Prolection atd improverlenl of environment
and
.ri".. therewith. It consists of four shapters containing 26 sections and
"onn""t.a
io!ers Ihe enlire counrr).
tis act empowers the government to take ail necessary measures (a) for protecting
quality, and (b) for preventing, controllirg and abatjng
-J i.p.ouingit',. "nrlron;ental government is empowered lo take such fleasures as
the en.rironmlntal Poliution The
,"orl."a for laling down standards for emission or discharge of pollutanls from
"r.
i"ar.tlies or to ena.t rilevanl rules for industry (e.g' its operation, process or location)
-- as ro Drotect Ihe environment.
so
bod) ie' Ihe Central Pollution
ii. ni".rrr.* has also constiruted a regulatory prescribing
c".i.ol"gcara fcpCgl for laying down guidelines, standatds' environmental
."rii".i"" ""a for various oth;r acrivities necessary for the implementation of this
i.i pnrrui;on cont.ot Boards have also been set up by the State Governments allover
'--ii"
the country.
ioii,on."n, (Protection) Act, 1986 is a iandmark legislation thal provides much
a
made mandalor\ for uaste disposal sile( also such as land'llls and
' iDcinerarors'
iil .i.uon.. i. gi'ten on the basis of ilformation which Ihe clienl has to supPly in
tfr#"r".iuea io.rn"tischedule Il, Application Form' See Box 7 l ) lt shall be accomPanied
bv a Droiect reooit * hich shall, inler'alia, inciude ao Envilonmental lmpact Assessment
n'""J.t in"ironm.ntal Vanagemenl plan p_epared in accordance with the guidelines
issued by the Central Government and the MOEF from time-to time All imporant
,r"i"*".'".*. Power project, lndustrial project have to supply this information on the
iails of an-efl ,epon prepatea b) a comoelent agency' The procedure for carr)ing
out EIA and submilting report is spelled out in the MOEF notifications'
--ii" Control Board (CPCB) has, in its various notifications and
c""""r Polluliin
,riii"u,;ont. laid down standards for lhe control of pollution of air, waler' and major
noise
!lc. ii"uf" Lr-2.+i. violation ofsuch norms will attract penalties as per law All
I
.,
I
1* A Textbook of Sold Wastes Management I
Box 7.r: Schedule il, Application Fo.m to be submiaed alonswith th. EIA R€pon
SCHEDULE.II
APPLICATION TORM
I
l.(a)
(b\
Name and Address of the project proposed:
ln respect to item for which data are not required or is not available as- pet the
declaration of project proPonent, the projeci would be considered on that basis-
I
I
1A A Textbaok of Sohd Wasles Mana96ment I
projects in the count.y will henceforth require a clearaflce from an autonomous body,
i.e. Environmental lmpact Assessment Authority (EIAA) constituted by the government
specifically for this purpose, as per the directions oa the Supreme Court.
I
Teble 7.1: Ambient
sa.
Air Quality Standards
CO
I
PPB ttg/ 3
1 . Industrial & Mixen Use 120 45.8 120 63.8 5000
PPM
4.37 500
I
2- Residential & Rtlral 80 30.5 EO 42.6 2000 1_75 200
3-
.\orer
Sensitive
Residential
75
65
55
m
55
45
I
D Sil€nce Zone 50 4
l. Dai iime is reckoned in between 6:00 a.m. and 9:00 p.rn.
I
2. Night lime is reckoned in betseen 9:00 p.m. and 6:00 a.m.
3. Silence zone is defined as areas uprc l00n around such premises as hospitals, educatioial
institutions and couns. The silence zon€s are to be declared 5y the Competent Authority.
I
4. Mixed categories of area! should be dectared as one ofthe four above mentione{categories
byrhe Compelenl Aurhoriq and lhe conespond ing slan dards shallapply.
So/r.?, CPCB. T
Trble 7.3: Noise Limits for Automobil€
Sorcer
Passenger or Commercial vehicles Exc€eding
CPCB.
t2 MT 9i
I
PTJRPOSE OF EIA
A cost-benefi! analysis is always carried out before finalizing any projecl. However, I
all ma'or projecl plans should also be examined to ensure public health and safety,
I
Enironmental lnpact Assessnent 161
c.ralir-v ofenvironmedt and to comply with legal reqriremeots. Great care is needed in
.lery first of its kind Project.
Tablc 7.4: Warer QualirY Standards
I
Suspended
Matte.(SPM)
Paniculale
Sultur oxides
Aggravates lung illness, corod€s meials, cats€s gime on belongings and buildines,
obscurcs vision
Conodes metais, causes a.ute and chronic leafirjury, attack a wide \"!iety oftrE6,
I
NitrogEn
C2rbor
oxides
monoxide
irriktes opper Espiralory tracl desroys pain piSmenrs
Irritate eyes and nose. creales b.olr haze, causes visible le3f damage, stunts planr
growth, corodss mefals
Causes headaches, diziness, and nause4 reduces oxygen Ievel in blood, impairs
I
Hydrocarbons
meni.al pro.esses
Cases cancer retards pl&t gro*,th
I
I
Table 7.6: Important Water Contaminanls and Theirlmpacts
Suspended
I
Can lead to lhe developme ofsludge deposits ard anaErobic conditions wheo untreat€d
Solids wastewarer is discharsed h the aquatic eNiromenl
Biodegradable Genemlly me"sured as BOD and COD. Ifdischarged untreared lo rhe environment, then
r
organics biological stabilizarion ca! lead to rhe depletion ofnatural oxygen resourc€s and to the
development of sepric conditions.
Pathogens
' Dise?se vectois. Communicable d;seas6 can be trdnsmitted by the palhogenic oBanisms
in waier.
Nuti€nts
I
Both niaogen and phosphorus alongwith carnon, arc essential nuuienls for go\1,th. When
discharged lo aquatic enviroflmen! drese nunients can leld to th€ Ero,xth ofundesinble
aqualic ]ife. When dischag€d in exoessive amounts on land, they can aho lead to rhe
pollution of goundw"rer
Priodly
Pollutanls
Hea\y metals
Orgaic and ioo.ganic compounds selected on the basis of their krotan or suspected
cffcinog€nicity, mutagericily, alutE toxicit etc. Many ofihese compounds are found in
waste$ ater or leachate fiom landfills.
Heary me6ls are common in lardfillleachate and wastewder liom indusnial a.livities.
I
EIA METHODOLOGY
These may need to be removed ifde water has to b€ reused.
I
An EIA study is specific to a particular project at a particular site. The entire area
circumadjacent lo the p.oposed project should be taken into account. Usually an area
of l0 km radius all around the proposed site is considered to be the infuence zone fot
most major projects.
t
It is often difficult !o decide if a projecl is 'good' or 'bad' in the absolute sense.
Planners find it easier to lyeigh the relative merit if severai alternatives are availabie. It
is lherefore mandatory that all EIA sludies should analyze several alternatives rising
1
the same criteria.
The various alternatives or choices ma! be selected on the basis of one oi more of
the foliowing consideralions:
1
.
.
.
different siles e.g. for developing solid wastes landfill
different processes or technology e.g. a gas based or a coal based power plant
different types e,g, a surface or a underground urban transpon sysiem
a
1
I
I
Envi@nmental lmpactAss'ssment 163
Elfects
r
-iJr.:ei Turk er al (1978).
.{n ElA study isalways a multidisciplinar.v teamwork. Experts inthe areas ofair, water land
:il lurion as well as in socio-economic f eld should constituie a balanced team. Much responsibility
::srs on theleam Ieader who coordinates the efforts, meets the deadlines and is responsible
I
I
I
T
scoPing
Drr'ns
be
I
accordingly "ri*
'"#5."i*t
-'e"
houe\
amended.
ii?.ira:, is usually carried out over a period- of one y-ear' In exceplional cases
er a RaDid EIA ma) be submined on the basis oflhree
or lour monlh s sluoy'
I
";;;-;;;i; ir'
;r,""J.5 i".",r.t
n.r't,oaoloel $ill depend upon the nat,re ofihe projecl and
ri; -H"*et.,
th!-uatic elements of merhodolog) and rhe objecri\e o'
;;;;"t; ,h. same. The methoaiology for conducting an EIA study consists of four
I
distinct stePs e.g:
l Baseline Sludies
2. Pred iclion of ImPacls
I
3. Evaluationof ImPacts
4. Environmeotal Management Plan I
Each ofthese activities is discussed below'
Delphi is a group techniq ue that organizes and utilizes experts' opinion forevaluation of
.ompiex problems. It is a slructured communication system which involves two or three
iounds ofexpert estimates. Anonymous feedback is provided to all the experts after each
romd by the team leader This method enabies each participant to make independent estimates
and then revisethem with suppiemental information provided by olher Delphi Panel members.
Ihe experts then use the information frorn previous rounds to make subsequent better estimates.
Tire final round produces a consensus ofopinion on the particular Parameters at hand The
q eightage is assigned quantitalively in terms ofPIU's. This technique was evolved by Rand
Corporalion in the 50s to obBinthe most rel iable coisensus ofopinion of a grouP of experts.
A typical distributio. of PIU to all the parameters is give! in Fig. 7.1. This is for a US
\\ ater Works Project. It may be noted that assi8nment ofsuch weightages may di{Ier ifthe
,roject or its Iocation changes.
The next stage in this slep is to collect baseline information on each and every
rarameter defining ihe environment. It may be collected from both lhe primary and
secondary sources. Secondary sources include records ofmunicipal offices, meteorological
department, census bureau, pollution control authorities, remole sensing agencies,
inrernet etc. Prima.y oatd is required for verificalion ofexisting records as well as to
generate original data which are not available. Appropriate equipment and lechniques
are used to collec! such information for the respeclive parameters. For example, air
rolume samp)ers may be required for collecdng data for SPM, bore holes may be
necessary for geotechnical and groundwater informalion, a socio"economic survey
:nay be necessary for data on human interest paramelers. Tabie 7.8 presenls some of
ihe rechniques available for monitoring air pollutants. These techniques are commonly
used in an EIA study. Differen! equipments arc.equired for other parameters e.g. water
quality, noise, land pollutiolr. Many ofthese equipnents have been listed in Chapter 3.
Collection of samples and resting in the iaboratory should be carried out as per the
srandards and guidelines laid down by regulating agencies e.g. CPCB, BlS. Similarly
field tests, monitoring and related work should be underlaken and documented as per
rhe relevant and plescribed slandards.
'lable -.8: Air Qualjty Molirorins Techniques
Monitoting Technique
!
1: - e!
ES
!ri? E:
.E
E:_:_s;
E
E
;"
E=
iE, Ei .9EE t
ng ::t
3
ei
a: c: 6 3,t ig
E:E{.;E
ts!. *€i tti.i . t9
;PS
EEEEs d
?66
i 6
9
,9
st
i5'
'6
'd
a
E 6-!8i3. t i
E!ee
86.!Hiiicr: _t!Ei!i:; .s,
,9 ;iii
: 66:666aAaa 66?6
:.e
t
i
E
e
P6
ul
i i i '*:
a
q a YPB ;:9r:
6 :E- F!;:f ;3;
;-!3
s! Ei
!;
i!EE:;E 5i3;g 3i!Et.'fi
Enitonmenlal lmpacl Assessment'167
Tvw
Efre.ts ot1 Ai, Qtolity EKPetimenlal melhods I \ ind runnel warer channels)'
rong mrge Eansporl
Oualitr lmpacb liadrerna;cat moaels uimptc boL Galssran pluire. K-theory
lons rerm prcdidion r: emPEcat models
n,ir,e, O*, t*as Valhemarical models ( limple dilurion models e g for 'orl
ani water, pathway models for human exposure & dose €ffect' and iDventory
soil and Grourdwaler Htaruutic lnpacts E\penmenlal melhods (field lesrs): Malhemarical
knpacts models (dispe6ion models etc.)
I
I
1@ A Texbook of Sclicl Was@s Managamont I
Table 7 .9 lcantd. fron p. 167)
G rol dt
a t e t Qual i ty : Experirnen6l methods (in-situ farar experiments)i
Math€matical steady stde and cofipiex dispersior models
I
Efects on Soils: Mathemari.:l models (mi ngmodets, steady state models);
Mathemalical
'llodels
(€.9. for popularioq produciivity, nujrienrs cycling models);
I
evaluation t€.hniques; and inventori€s.
Experimental models (still and moving 2-D models, 3-D modets); Mabemarical
models: ehpirical models; Survey techniques (evaluation methods. visibiliw
techniques. intmror) rechniqu6)
I
A.tivitvr Mobile sources (roads, railways, airports); Srationary sources
(industries er..)
Acoustc Inp@x: Eryin]€itulrnelhods (phlsicat modetsl MdleJnaticrl modets
(qadv sree arnbientnoise models)
I
Hisher Oder Efects: Mathematical models (ehpiricat annoyance modets)!
Ac.idental lrnpacts Hazard and op€rabili, (HAZOP) studics; Event and fault tr€e analysisj
I
Cons€quence nodeling
Sr/rc.r Environmental Resourc€s ( 1982).
Thechoice ofprediction methods depends upon the time, monev. information available and
I
the importance ofparameter in a particulai EIA. Prcdiction ofihpacG helps in carrying out the
evaluation of impacts and in devising and implementing the EnviroDmental Managemenr plan.
E6
I
EnvionmenlallmpaclAssessnenl 169
Hi9h High
0 0.05 0.10 0.15 0.20 0.25 O O.O5 O.jo 0.j5 0.20 0.25
HiEh
65 7 3.5
(4 pH
(c) Odor
I
I
Eni/ironmental lnpact Assessment 171
I
'172 A Tenbook at' Solid wastes Management
I
EIA OF WASTE MANAGEMENT SYSTEMS
The systematic application ofenviionmental imPact assessment procedure to waste managemen:
I
sratesies and projectsis an impodant asPecr of wlrste managemenl Various waste managemen:
optio;s and site; aviilable for such slslems are identified- For each ofthese alternatives
p;tential impacts such as traffic, noise and aesthetic are to be evaluaied The type of $ asl'
I
handied at the facility will also influence the extent ofimpacts-
Site criteria ofa waste management facillty includes !echnical, economic socio_
poiitical and environmental considerations. Technical criteria for wast€ managemenl I
process are generally Process specific and address issues such as land requirements'
sile access, Proximity to lransportation networks, access to power' \Yater' se\rerage
etc- Economic, socio-political and environmental criteria are usuallv geoeric ann I
appiy equally to most lypes of waste facilities, although the relative imporlance of
environmental criteria can vary, depending upon the type ofwasle handled and trearmenl
or disposal process under consideration For inslance' locaL meteorological condiiions
are oi greaier importance in the siting of Power plaots. In case of landfiils a secure
hydrogeological setting is ofparamount importance. Olher environmental criteria
include avoiding ofsensitive ecosystems, protection of natural res ources, surrounding
populations
- eI(.
impa"ts from awasre facililv oPerations are (i) impacts associated wiih landuse Plannjng
and ail developments (ecolog), noise. traffic, aesthetics etc.); and (ii) impacts sPeci{ic
1o
thetype ofrvasie treatmenl process uoder consideration -4ll factors relatedto environmental
qualit), public health and socio-economic issues aretaken inlo account The pub lic concern
ii u"ut" ou", poteniial delerioration in enviror[nenlal quaiily caused bythe release
"rp""iully
.ofchemicals to air. water and land.
The medium into which the process discharges are released is impo antforoverall
assessment. In ihe case oflandfills, the land and groundwater parameters are ofprime
importance. Similarly for industries or chemical treatment plants air and surface water
are of critical importance,
The polenlially affected area can extend well beyond the immediate vjcinit) ofthe sile
processes
depending upon meteorological conditions. Forexample, emissions ftomthermal
can be deposited over an area extending upto 5 km beyond the site' Similarly, the leachate
plume of a landfill can extend to a considerable distance down the site.
The time scale over which the baseline assessment ofvarious parameters is conducted'
vades widely. For instance, in Eroundwater assessmert, spo! samples coliected from slmtegic;liy
located boreholes are generaliy sufficient But in the case ofair quality, the survey 'nav
extend for 6 to l2 monihs.
The prediction and evaluation of impacts Potentially associaied with a waste mana8ement
operation must draw upon a vride range oftechniques Qualitative methods may suffice for
quaniified
sorne parameters ..g. landscape, aesthetics For most parameters ho*ever, impacts are
and evaluated against numerical criteria (noise' air, and water qualit)', health risks) For
various types ofhazardous wastes and waste management processes i! is also necessary 1o
Baseline lnlormation
Dala was collecled for all the 35 parameters from boih the primary and secondary soutces.
Env;ronmental sampling slations were selected according to environmental sensitivity
ofthe region (with the site as the central station) covering an area of l0 km around the
site.
A resistiviiy survey was conducted for the entire area upto a depth of2O m. The Lateral
Electrical Soundings (LES) of Wenner's Eiectrode Method of Space Configuration was
used to determine laleral extension ofthe geolog;cal formations. The Schlumburger method
was used for groundwater resource assessmeut and water zoning ofarea,
Various base maps ofthe study area were prepared and updated using available remote
sensirg data and salellite imase.ies. Various maps e.g. hydrogeomorphology, vegetation
density, drainage, landuse,/landcover, setrlements, lineament/lineament density, surface
water bodies and topography have been prepared for the siudy area.
174 A Textbook ol Sotd Wastes Management
ENVIHONMEIITAL AESTHETICS(70)
Topography (20)
BOD (50)
DO (15) Sanilalion 120)
Brodiversity (60)
pll (15) Odour (10) Energy (25)
ruS (10) Employmenl (3s)
saliniiy 00)
Eosion (1s)
Prediction ol lmPacls
Prediction of impac! is an important step in an EIA study. It helps in canying out the
evaluation of impacts and in Preparing the Environmental Management Plan. There are
many mathematical modeis and methodologies available to predict the impacts The
mathematical models attempllo quanthatively describe the cause and effecl .elationships
between sources ofpollution and different elements ofthe environment, e-g. air, water,
noise. land and socio-economic aspects.
In the present study, the prediction of traffic volumes has been carried oul by
extrapolation. The predicted traffic voiume data has been used to predict the impacts
on air quality and noise level. Prediction of impacts on the water quantity & quality,
solid wasles, community health, energy, habitat and communities and on various other
parameters have been carried out on the basis of Population Projections due to the
project.
Evaluation ot lmPacls
For the evalualion of the environmeltal quaiity value function graPhs for selected
paramelers pertaining to the environmental impact have been developed adopting the
Environmental lnpactAssessment 175
Battelle Eflvironmental Evaluation System (BEES). The environmental qualily (EQ) scaie
Bas obtained for each ofthe identilied factors, through the use ofcorresponding functional
..larionship. Value function graphs were deveioPed for each ofthe 35 pammeters'
Evaluation of the environmental impacts !s:ng BEES, is 'a'i€d orli i! terms of an
index known as Environmental IniPact Unit (EIU) For each of the alttinadles' i:l€
EIUs are obtain.d usiAg the following reiationship as explained earlier:
(EILrj = (EQ)ii.(PIU)i
The resultsofthe evaluation ofimpacts onEcology' Environmental Pollution, Aesthetics,
Human lnter€sts, and overall impact evaluation are described below'
Ecotogy
Bio-diversity: The preseni vegetation is sparse and stunted. Since the area is going to
be occupied ty hotels of international standards, the area will be en.iched by extensive
plantarion ani vegetation. A large area will be develoPed as green area Therefore-, the
total impact on p:lantation/vegetation due to implementation of the project shall be
positive. The animai and bird poPulation wilt be disturbed during the constructioo
phase, but after the comPletion of project there will lie more plantation and green area
l,ailaile at this site. overall, the imPact on biodiversity will be positive due to this
p.ojec1.
Groundwater: Croundwater resources are meager, The project wilt increase the local
population with a heavy demand on water This will further deplete these resources
ihe impacr on Ep due to thls parameter will be significant and negative
Lenduse Comprtibility: The Proposed ploject will not result in any eflvironmental
project
conflict from the landuse point of view- Further, as much as 44 percent ofthe
area is kept in reserve for recreational oPen spaces. These will be developed as g'een
reserves, parks and a golf course.
The project of this;agnitude js bound to gererate direct employment as-well as
indieci jo; opportunitieJe.g. services for vadous supplies' transportation & travel
and
services, tourism information and guides, photography, recleation, entertainment
a host of other seavices,
Aesthetics
Aesthetics of the area 'will be greatly eDhanced due to this ptoject. At presetrt it is a
barren wasteland where it is scary to go iD the tright. The poachels are usitrg the site
for fuel wood. Clandestitre stone miEiDg has disfigured the t.rPography. The alea is
also us€d for dumping solid wastes creating odour and sanitation problems. Presetrtly
it is a heakh and security risk. The overall impact of the hotei project oB aesthetics
will be positive.
Human lntetest
Population: The.e will be a margiDal increase in the residertial population due to this
p.oject. The hotel guests will constitute a tramitory populatiotr. The eEployees need
not Decessarily live at the site itself.
Traftic and Tratrsport: Proper managemenl of trallic, adequate Provision ofparking
space atrd providing grade separators at busy iDtersections can loitigale the impacl or
traffic arld traDsport due to this ptoject. The overall impact oD enviroDmental quality
due to traffic \r'ill be Degative.
Energy: Energy requirements are predicted to be ofthe order of 20 to 40 MW Suitable
measures are needed to augment this projected requircment.
EmploymeDt, Ecotromy and Education: The idpact of this Project oo EQ, due to
empioymerlt, economy and education will be significaDtly high and positive. Is fact
there will be multiple aDd ripple effect extendhg over a wide area arouEd the site
Eistorical and Archaeological Sit€s, Cultural Eeritage and Sociel InieractioDs:
Ttis project will greatly boost the environmeDtal quality due to greater appreciation of
India's historical, archaeological atrd cultural heritage. This will also provide greatel
opponunities for pleasaDt socjal interactions and leisure activities. The Det effect oD
environmental qualities due to all these thre€ factots will be positive.
TheEQduetoAeslbeticsaDdHumaDlBrelestwitbiEPlementalionoflheplojtct
qualrty wrll lunner
n"rJi.lJ i.rna to ;.prove due ro this projecl The environmenlal
various positive aspecls ofihe
*".'"* *itr' trr. i-rrimentatioo of IMP ihis is 'lue to Ecoromv rhe etrvironmeDtar
ff:T;;. il*#;;,;;;i;;, EmProvtue.t' ao'r
:^;i;;;"-;,. qorsen bur caD be coDtrolled with suitable deasures
on the edvirotrmetrtal qualitv is positive'
";;::"';"t1;;;;"i-* "tt.,p"'"-t"rs iDPacr' e g' emplovment' econoEv'
s"#1i,1. i""r.i"r"re a sigDificadtly high Positive will become sigrificaDtl) Posilive
rl"ioii"n..."i r,;"r- rana uit erc sorne orler factorsplaq e g' solid rlasles Inarasemetrt'
L]fi;; #if,;;ntxi;o of "o'oi'oorn"otul t*agemeat
codmunity health etc.
T,ble ?'10: Envirof,lrental Evallration: Overali
8.8. eith E-8. vith Change in
E,Q-
E.8. \|ithott E.Q. with
Assigned PIU .EMP EMP
EMP
(En, (Eru) (EIr, (EII' (Ellr)
(Pru) C_A
B C
+26 +46
Ecology (I80, 89 115
326 +19
(500) 34',7 269 -38
Poliunon +u +24
63 63
(70) 39
211 +19 +E7
Huma! interesr (2s0) t73
'135 +t76
Total o000) 559
SPM SO,
fue/-3) Gglnl (id.'3)
Site S1 1800-4000 0-60 5-36
Sile 32 450-1300 6-16 12-47
Sites3. 560-1140 6-2r 6-3E
Naticnal Ambient Ai. Qualiry Stmdrrds 200 80 80
Table 7.16: Grcund watei amlysis oi samplcs Dear s€lected lardfilt sites
The above rating system has beetr further lefiDed by assigtriDg suitable weighiage
(otr a s cale O to 1 ) to each attribute accordiog to its iBportallce. For hsta[ce glouad$aer
protection is the most importal! parardeter aird is given a weightagc of 1; but compaction
aDal leveling is assighed a weightage of0.5. The assiglment ofr€lative weightages i.e
the parameter importance uni! (PIU) is one of the most controv€rsial decision in
environmental i Pact assessmeDt. No two experts agree on the level of iEporia!ce
(PIU) ofa pa icular attribute as il is highly subjective. Delphitechtrique and other
similar strategies are often employed to remove 'bias' iD assigning weightage. In the
presetrt stud), Delphitechnique has beetr employed for this purPose as it is most colcdonl)-
used in EIA studies.
Environmental Quality (EQ) has been detelmined by using the followilg relatioDshi! :
EQ=PIUXEru
Overall environmedtal quality at Iatrdfill site has been obtained by cuaulating the EQ
for each attribute-
Table 7- 17 preserts aE evaluation ofthe landfill sites based otr the survey and aacordi-trg
io the rating scale defined earlier. A total of 15 parameters have beetr examined and EQ
determined for each attribute as pel the EIU aDd weightage (Pru) assigled to it
Table 7.1?: Evaluatior of selected landfill sites iD Delhi
I
Envircnmental lmpact Assessment 181
only the Site 52 has a cumulative EQ of397.5 while the other two sites have EQ much'
less. An ideal sire witi uifondly good ratint should have aD EQ of i200.
Tte foilowing observatioN were made:
. Presently, Delhi is rapidly expaDdifg.-New sites have to be selected iD order to limit
ttre loads oD existi.Eg sites and to reduce haul distarces. The large discrepancy bet$€en
the load atrd caPacit! necessitates restarting some ofthe o1d sites.
. Effectiv€ measures treed to be takea to protect grould water. A Ilumber of optioDs
are available e.8. geomembraDes, clay liD€rs, barier walls. Grormdwatel flow pattem
should be carefully studied to adoptpiopet draiaage measules.
. Periodic monitoritrg should be done to check aetrace due to birds, animals, rodents
or flies. Bird oeflace has to be coEtrolled especially as some ofthe areas itr the
South have low altitude flyingclubs.
. The fianagedent ofthese sites is poor, The equipment is ofteo out oforder and in
Deed ofrepair Solid lv?ste disPosal requires ptoper maDagement *'ith adequate equipment
atrdtrahed staff.
. MaDagemeDr of landfill sites can be made much more efficient ifthe site staff is
given a short traiDing in the use otequipdelt, co1rtrol ofvarious opemtions atd
monitoring the €ffectiveness ofvarious m€asures Requirements ofaa engineered
landfill can be expl3ifled thrugh video films, lectures and site visits. T.ainiEg
modules can be developedfor each category ofstafseparately
. The aesthelics at all these siies need to be greatly i$proved UDauihorized rag pickers
fiequently make a mess ofa[ already poor dallaged durrp. TLe €g pickers aEd ot}er
unautborized persons ftequently eldaager &eir o*D health aDd become disease carriers.
lDvisible contracto$ who paytheD1 apittance for their labor usually exploit them'
These aspects Eeedto beProperly maDaged.
. Deep-rooted lrees should be Planted atrd tie sites can be developed as greerl aleas:
parks, sports gouods, parki.ngaleas, bus terminals, etc.
. ! iDally it may be emphasized that the cost estimate for implemetrting tlese measlues
is trot very hi8h but the likelybenefits are great andhave longterm value.
This study was carried out in 1993. Many implovem€Dt techniques siDce then have
beeD developed and iBplemeIrted.
ENVIRONMENTAL AUDIT
EtrviroDEeotal Audit should be canied out for all industdes to ensure enviroDmental
protectioD. An Environmental Audit (EA) is a Periodic evaluation of how well the
syst€m is working. It should be systematic, objective and documented. An audit helps
in achieviDg the following objectives:
(i) Waste minimization;
(ii) Resource oPtimization;
(iir) Public awar€ness ofthe units eavironmetrtal records; and
(iv) Compliance \r ilh l€gal requiremetrl.
Earlier, EA was mandalory for indust es as per the BnviroDpedt (Protection) Rules,
1986 as norified on 19 November 1986. Later ihis provision was amended and the
rcnn '€nvironmental audit'was diluted by 'elviroDmental statemeDt'. The legal requilemeDt
1*. ATexlbook of Solidwastes Maragenent
l1ow is that the industrial utrits should fumishrhe requisite iBfomatioo for each financial
year in the prescribed foimat i.e. Iorm V (See Box 7.2) to the Poliution Control BoarC
before 30 September ofeach Year.
6. Rules and Regulations-to ensure coapliaDce with the rules aid regulations as
per 1aw.
(v) Ia erabl€s the staff atrd employees lo iDprove th€ir technical capability and
eDviroDmental awareness.
(\i) ft safeguards the etrvirondent, and imPloves goodwill and public iEage of the
compaEy.
t
1.
2. Categor) Chloro Alkali
Dates or lvhich Auditing was xx-xxx-xxxx to xx-xxx-xxxx
(ri) Quality
S.No. Prescdbed Limit Actiral Discharge
(, PH 5.5-9 10.65
(,, TDS 5704
(iii) SS 100 204
(,v) coD 406
(v) Chloride t755
(v,) Residual Chlorine t 11.9
(v,i) Mercury 0.01 0.008
13, Assessmeot/Recommerdation:
(a) Coolingwaler can be reused for gardeniDs. This will reduce wastewater generation.
(r) House keeping needs to be upgraded.
(.) Sludge disposal arralgements is not satisfactory. The compafiy should make
suitable arrangemerits for disposal of soiid wastes as per the guidelines Iaid
down by CPCB.
(d) Staff training and awareness prograEmes may be orgaflized for minimizaiion
of vvastes and oplimum resources ulilization.
The Central Pollulior Control Board vide its notification of22nd April, 1993 has laid
down new ruies in this regard to amend the EdvilonmeDtal (Prolection) Rules, 1986
Accordingtothis notiflcalion industries are requiredto subfiit an Environmental Sta[emeDt
for each financial year endiDg 31st March in the presc b€d fomat (Form V) Presciibed
therein.
Envirc nentallmPact Assessmenl 187
(1)
(2\
(3)
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18 ATextbook of solid wastes Managenent
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PART C
EXA"PLES
Example 7.1:
About one miliion vehicles have been added otr Delhi's toads durilg the Iast five
years'
This has increased the SO, level ftom 0. 1 to 0. I 5 ppm. Estimate the impact on Envi1tr1:ntal
this parameter' Assume PIU for SO, is
Quality. Also calculate 6e change in DIU due to
10 (ou1 oftotal 1000 udts).
Solution:
(a) Bnvironmedtal Qualily
EQ (for SO, = 0.1 PPm) 0.6 (from lig. 7.3a)
EQ (for so, = 0.15 ppm) 0.3 (ftom Fig. 7.34)
chaDge in EQ 0.3 - 0.6
= 0.3
Hence- increase ofone million vehicles has negative impact oD the environmental
qualry.
(r) Change in Eru
Chatrg€ in EIU = Change in EQ x Pru
= -0.3 x 10 :-30
EXERCISE
1. Wtat is the purpose of an EIA study? Discuss various methodology adopt€d for predictior
2 List 30 iEporta!1 paraseiers to be co$idered in lhe EIA for the seleclion of the most
suitable laldfill site.
3. Explain tbe Battetle Ervirormental Evaluation System'
4. SPM level of a locality was 200 ppm. After a landfill was developed in the viciditv
the SPM
construclio, phas€ incrcased to 450 ppm DIa\r a value tuncrion graPh for SPM'
during the
Assu;ing the PIU for SPM to be 50 estiEate the change in EIU-
5. Briefly explain the foilowiDg:
value FuDction Graph, Leopold Matrix, Etrvirondetrtal Audit' Environmer'al StateBeut
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Append.ix-I I
I
Glossary
r
I
An eDvironmeDtal condilion occuring in the presence I
I
ofoxygen.
Anaerolric Environmentai condition occurring in the absence of
oxygen,
Ash
Bacteria
Incombustible residue that is oblained after bumins
a foel or soiid waste.
A shgle-ceL microscopic organism. Some bacteria could
I
be harmful as they may cause disease while pr€sence
ofsome bacteria is desirable !o stabilization ofsolia!
$aste, Bacteria can be aerobic, aDaerobic or facultative.
I
Biodegradation Process in which solid waste or othet compound can
be degraded or transformed to simpler compounds
by microorganisms.
I
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Carbonaceous Carbon compounds ptesent in solid waste
matter
CarboB dioxide A colorless, odotiess, nonpoisonous gas. Itis produced
Carlron monoxid€
durirg thermal conversion and biodegadation ofsolid
waste and forms carbonic acid $hen dissolved in wate.
A colorless. poisoDous gas with an exceedingiy f,-int
I
meEllic odor k ato p-oduced during rheftDa I conve:lion
and biodegradation ol solid wasies mder limited o!,gen
supplt.,.
I
Collectior of Process ofpicking up \\'astes from its source ofgene-
ralion e-9. households. institutions. business and
commercial centers; hauling it to rhe local transfer
t
stations,
Combustible
mat€rial
Materials presedt in the waste steam containing carbon-
aceous after can be bumie.g. paper, cardboard, food
waste, \trrood, yard waste.
t
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Aryndix'l\Glossartl 191
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192 A Textbook of Solicl Wastes Management I
MagEetic
separation
Materi6l balance
Process i! which ferrous &etals are sepatated out
using rl1agnets.
ofsolid wastes by
I
ofsolid wastes for their recyclidg aDd proper disposal.
MetheDe A colorless, odorless aDd asph,.(iatiDg gas produced during aDaerobic
decomposition of wastes.
I
Microorganisnrs Geoerally referred to any living thing Eicroscopic ia size, e.g. bacteria,
yeasts, simple Iiulgi, algae. protozolrD.
Moisture content Loss ofweight ofsolid wastes when d.ied to a cotrstaat weight at a
Orgatric Eaterial
Pathogetl
temperature of 100-105 oC.
CoBpouDds contai ng carbon coDbined triih other chemical eleme s.
This is an orgaDism(e.9. bact€ria, viruses, protozoa, atrd helmhthes),
I
Pollution
which call cause disease.
The preseDce ofcontamiDants in soil, water, or the atrDosphere due
to discharge ofrdaste streams or othe! materials,
I
Pyrolysis
RecycliDg
lrocess ofbrcaking down combustible Mstes a! high tempeBture in
the absence ofoxygen. I
I
Process ofsepamtiEg outvatious useful material from waste stleam
and processing it to make it suitable for reuse o! Ea1lufactu og of
products which may or Eay Dor be similarto the origitral product_
I
Refuse It is ofteD interchangeably used for solid wastes.
Reftse derived fuel Solid wastes remaining afler removai ofrecyclable and Don-combustible
materials- It is used for enetgl- recovery from wastes.
Reuse
Sanitary laodfill
Use ofwaste material orproduct tnore than once,
It is refenedto anengineered iaodfiil used fordisposal ofsolid wastes
thar eDsures protecrio0 ofbu.mao bealth aDd €D!iroDoeDt.
I
Screenitrg
Shr€dding
Source reduction
Method used for seg:egatirg solid wastes into different size categories.
Process used for convertitrg iarge size particles into smaller pieces.
The proc€ss ofreducing quaotiqv ofwastes at the source by adoptiog
I
Sou rce leparation
suitable measures.
Separatiotr of differetrt cordpoDeDt ofwastes at the soutce of generatioD
and storingthem in separate containers.
I
1Y!Dsler ofr{!stes
station
Process of traDsfering the wastes fro!1 colieclion vehicles to larger
sized vehicles for transportation to the dispos.l site. I
I
TiaDsfer : A faciiity where collected wastes is temporarily deposited afld then
loaded into large size vehicle for transportatiotr to the disposal site.
TraDsportatiotr of : Process of carryhg wastes fiom transier station lo the disposal sites.
I
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Appendix.ll6lossadt 1E3
Yadore Loac The zone between thc ground surface and the water table.
Volatile solids The fraction oforgadc solids tbat catr be released as gas wheD orgaoic
Eatbrial is burnt in a lcuffle firmace at 550oC.
voluDe rcduction The process used to decrease the voluEe of*?ste io order to conserve
the space occupi€d duritrg its disposal.
Waste strerE The wasle oulput ofa sowce.
Wrste Theprocess ofcotrverting wastes ftom one phase to another(i.e. solid
trrEsforBation to gas).
Site reBedistiotr The process ofreclaiming a cotrtaminated site by physical, chemical
or biological treatment.
I
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Append.i.x-II I
I
Conversion Factotrs I
I
Multiply Bv To obtaitr I
acle
acre
Abbreyiation
acre 4047
Name Abbreyiation
square meler
hectare
m2 I
I
acfe 0.4047 lla
Britishthermal Btu i.05 5 Kilojoule KJ
unit
Britishthermal Bru/ft3 per
I
37 .259 Kilojoule KJ/m3
uDit per cubic cubic meter
foo!
Br;tishthermal Btu,&-ft2
I
23. 15 8 Joules per second ,/s-m2
unit per hour per square meter
per square foot
Briiishthermal Btu&W'h per
I
1.05 5 kilojoules KJ/
u[it per kilowatt- kilowatt-hour kw-h
hour
British lhelmal Kilojoules per
I
2.326 ru&g
unit per pound kiloglam
Britishthermal Btl,totr 0.001 l6 Kilojoules per KJ/kC
uDit per ton kilogram
Cubic fool
Cubic foot
f13
ft3
0.0283 cubic meter
liter
m3
L I
I
Cubic foot f1rlmin 0.0004719 cubic meter per mr/s
per minute
Cubicyard -vd3 0.7 646 cubic meter
I
Day d 86400 s
Degree Ceisius plus 273 Kelvin K
Degree 0.s5s ('F-32) degree celsius
fahre eit
I
a
I
Awendixll\Conve6ionFacbEl 193
J
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or expedieDt for the purpose of protecting and improving the
quality ofthe enviroDment and preventing controtling and abating
environmentai pollutioD.
(2) In pa(icular, and without prejudice to the geDerality ofthe provisions
of sub-section (1), such measures tr1ay include measures with
respect 10 all or any ofthe followiog matters, namely:
(i) co-ordination of actions b!. the State covemments. officers
and other authorities: )
ia) under this Aci, or the ruies maale thereundet, or
)
/
Salient Features ol Enironment(Protection) Act, 1986 197
(r) udder any other law for the time being i]I force $'hich is relatable to the
objecls oI this Ac(i
(ii) planning and execution ofanation-wide programde forthe prevention, control
aod abatemeDt of environmetrtal pollution;
(iir) laying do\Itr standards for the quality of etrvironment in its vadous aspects;
(i},) layiDg do\ n standards foi emissior or discharge ofenvironmental pollutants
from various sources \,r'hatsoever:
Provideil that different standards for emission or discharge may be laid dow!
under this clause from differeD! souces having rcgard to the quality or composition
of the emission or discharge of edviroDmeDtal pollutants from such sources;
(r) restriction ofareas itr which ary itrdustries, opemtioDs or processes or class
of industriis, operations or processes shall not be carried ou1 or shall be
carried out subject to certain safeguards;
()i) laying down procedures aEd safeguards for the preventior of accidents which
may cause environmental pollutiod and remedial measures for such accidents;
(1ii) laying dounprocedEes aDd safeguards for the haDdling ofhazardous substarces;
(viii) examination of such manufacturing processes, oalerials and substaDces as
are likely to cause enviionmeDtal pollution;
(7}) carrying out and sponsorilg iDvestigations and research relatirg to problems
I (:)
of en\ ironmeDral pollutioD:
inspection of any premises, plaDt. equipme[t, machinery, maDufacturing or
other processes, mate als or substances add givldg, by order, ofsuch directions
to such aulhorities, officers or persoDs as it may consider [ecessary to take
steps for the prevetrtion, control atrd abatement of envi{onmental pollution;
: (ri) establishmenl or recognition of environmeatal laboratories and institutes to
carry out the functions entrustedto such envirarnmeDtal laboratories and instiotes
I
(r.iii) preparation of manuals, codes or guides relating to the prevention. contol
and abatement of eEvironmeDtal pollution;
(riv) such other maners as the Central Govemmetrt deems Decessary or expedient
for the purpose of securing the effective implementation ofthe provisions of
I this Act.
(3) The Central Go!'emme[t may, if it co$iders it flecessary o, expedient so to do
I
for the purpose ofthis Act, by order, publish€d in the Official Gazette, constitute
aD authority or autho ties by such trame or names as may be specified in the
order for the purpose of exercising and performing such ofthe powers aDd
functions (includilg the power !o issue directions under section 5) ofthe Central
r GoverDment utrder this Act and foi taking measures with lespect to slrch ofthe
nxatt€rs referred to in sub-section (2) as may be mentioned in the order aDd
subjectto the supervisiotr andcontrol ofthe Central Goverrrment aadthe provisions
t ofsuch order, such authoritv or authorities may exercise ard polvers or perforB
the funcliors or take the measures so mentioned in the order as if such authority
or authoriti€s had been €mpowered by this Act to exercise those powers or
perform those functioDs or take such measures.
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1* ATextbook of Solidwastes Managenent
I
of its functions under this Act, issue ditectiotrs itr qritiEt to any perso;, officer or
any authority and such percon, officer or autlority shall be bound to comply with
sucb directions.s
Eiplatration: For the avoidance of doubts. jt is hereby d€clared that rhe power to
issue directions under this section ircludes the power to direct:
(a) the closure. prohibition or regulatiotr ofany industry, operation o, process; or I
I
(6) stoppage or regulation ofthe supply of electricity or water or atry other service.
Rules to Regulate Envi.onmenial Pollution
(1) The Centtal Govemment 6ay, by notification iD the Official Gazette, make
rules in respect of all or any of the matte$ referred to itr section 3.
(2) Itr particular, atrd wirhout prejudice to the getrerality ofthe foregoing power,
such rules may provide for all or any ofthe followitrg matte$, namely:
I
(d)
(r)
the standards ofquality ofair, water or soil for various areas aDd purposes;a
the maximum allowable limits of concentmtion of various enviion ental I
I
pollulants (including troise) for diff€rent areas;
(c) the procedures aDd safeguards for the handlitrg of hazardous substances;t
(d) the prohibitiotr and restrictions on the handling of hazardous substances in
different areas;6
(e)
LO
the prohibition and rest ction on lhe location ofitrdusrries and tle carryitrg
oD process and operatioDs in differenl areas;?
the procedures atrd safeguards fo. the prevention of accidetrts which may
I
cause environmental pollutioD and for providing for remedial measures for
such accidents,3
I
I
PREVENTION, CONTROL, AND ABATEMENT OF ENVIRONMENTAL POLLUTION
Persons ca.rying on tndugtry Operation, etc., not to allow emission o,
Discharge of Environmental pollutanlg in excess ot the Standards
No person carrying on any industry, operation or process shall discharge or emit or
permit to be discharged or emitted any environmental pollutants in excess of such
siandards as may be prescribed-e a
a
a
I
Saliefi Faatures of EnvimnnentlPrcbcnan) Act, 1985 199
jf
reeister. document or other material objecl he has reason 10 belie\e lhal
it
this
-i'-ir-iJ *,a.".. of the comaissiotr of atr offeDce putrisbable uDder
prevent
Aci ot the rules made thereulder or that such seizure is Decessarr_ to
or Elitigale en\ ironEental pollutioo
(2\ E\erv DersoD carryiDg oD an] indusry. operation or process ofbandlitrg
aDy
tazaidou, subslance stitl be bould to render all assistance to tbe person empo*ereo
iiii" C"n,."f Co*rnnent undet sub'section (1) for carrying out the functions
if fails to do so rxithout atry reasotrable cause or
uid.. th"t .ob-.".tioo aod he
excuse, he shall be guilty of atr offeDce under this Act
Der"on , ilfujli delals or obstrucls any persons eDpo\rered b)
tbe Ceolral
-C*i.ir."irra*
(3) Ifan\
(l) in lhe performance ofhis tunclions he shall
tiru-se;tio!
be guilly of an offence uoder this Act.
(4) iiJir""it.r' oftbe Code of criminal Procedure. I973 or' in relatioo to
Ihe
i.ur"'ot:aomu *a Kashmir. or atr area in whlch tbat Code is nol io force lbe
r.."i.ior. of .o" correspoodiDg law i-D force io thal Srale or area 5hall so far
l. -"r u.. "ooti to ao)'"earch or seizures under lhis section as lbey appl) Io
""r-*"ril
i"t"* .;de uDder lbe authority of a warranl issued uDdet section-
94 of the "i Code or as the case Ea) be. under lhe correspotrdiDg pro\isioD
ot
'aid
tie said law.
for I
i.r
anaiysis;
' carie tft" sample !o be Placed in a container or conlainers which shall be
marked and sealed and ibail also be signed both by the persoE taking the
sample and the occupier or hls agenl or persoo:
I
rd) sendu'hhouldela).thecoDlainelorlhecontainerslolhelaboraloD eslablished
or recognised 5) rhe Ceolral Govemment uDder seclion l2' I
(4) When a sample is taken for analysis under sub_section (1) and the Person laking
ihe sample ;rves on the occupiea or his agent oi persol, a notice uDder ciause
(a) of sub-section (3). then': I
(a) in a case where the occupier. his agent or person wilfull) -absents. hlmself'
' ' ihe person taking the sample shall collecl the sample for anal) sis lo be placed
I
!
I
salent Features of Enl/lronmenllProloctionl
Act' 1986 2o1
Governmgnt AnalYsis
apPoinr or re'ognrse
il'" i."""-, i"'...."1 ma) b) notificaliotr in tbe ofllcialGazene
the Drescribed oualificarionsr" lo be
Govertrment
sucb DersoDs as il Ibio\s Iit aD'l havlng
il;,fi,;;;;,; fi;* "ti"_11't::|";lTX,fi".i,X[i,l#i';il]llJ,,i:::';X'.Tiii:
sent for analysis to any envlroDmetrIal
tz
by a corDpatry, every
I
I
persoD who, at the tiee lbe offence was
coomitted, was directly il cf"rg" of
aad was responsible to, the company for the conducr
l.he t'".i""* ii,n"
company._as well as rhe colopany, shall be deerned "fguilty of Ae offeoce
to be
aiorjiagiyf '
I
aDd shall be liabte to be proceeded againsl aDa purislea
I
Explanation-For tbe purpose of this section:
lo) _comlan) mears aD) body co4,orale aDd ilcludes a firm or
other associatrotr
ofhdividuals:
(r) "dir€ctor,,, in relatioa to a furE, means a parttrer in the fiftr.
Ollences by Government departmentg
(1) Where an offence uDdet this Act has beetr commilled
I
Govemmeot.
,lhe
onence and shall
by aay Departmetrt of
Head of tbe DeparteeDr suatt ue aeeoea io'ue
be liable to be proceeded agai.Esl ard punished
provided fiar qotbiDg cooraioed
;;til;;io.
ui"o.ili"f,
i! rhis seciior shall render su"t ff."J
I
Departmenr liable to aayputrisbment if he proves
ttat tne offence i;;;;il"d"?ii.
$ithout his knowledge or that he exercise all due dilig."..
of such offence.
,;;;;;; ;;;;;i:;, I
(2) NotwithstandiDg adythiDg co4tained in sub_sectioD (l),
:ll:1" hI been comnined by a D€panmetrr or c"".*r.",
urar rne orrence Das beeD comlnined wiih the consent
atlrjburable ro an\ neglecr on tbe pafl of.
where an offence uador
*i'iij. oil, a
or comivaace oi, or is
I
om"... o,1., itaD ii. H.J
Depanmenr. such officer shalt al;o be deemed "oy to hj
eJi,y ,i"i
"f
shall be Iiable to be proceeded agaiEst anal punishea aicorainet.r,_
"irt.
"ii.#';a
1
1
1
I
Selieht F€atut6 ol Ehimnmont(Protectionl Acr'
1985 N
HISCELLANEOUS
Protection ol ActionTaken In Good Falth
shall lie agaiDst the GovtTT:',:l:y
No sui! prosecution or othet Iegal Proceeding
constituted utrder this
.ti".t'"1_",1* employee of the Governmeni or aa1 authority
ofsucb authorily i! respect ol an)'tnrag
i.i", -r-r.rt*. "dicer or other enPlovee
iiiJ rJ"* ".-""aed to be dose iE go;d faith io pursuance ofthis Aot ot the rules
*"d" o, ord"r, or dir€ctiotrs issued theleunder'
Cognizancg oI OflencBa
this Act €xoePt otr a ooEPlaiat
No-"ou.t shutl tute cognizance of any offelce utrder
made by:
authorised in this behalf by
(d) the Central Govemaetrl or any authority or ofticer
that Govemaetrt,2o or
days iD lhe maoler
(r) "* *.." *1" has given noticc of not less than sixry to Eake a conplaist' 10
lii.Lri.l. "Iti. ,u.'-*ed offeoce and of his irreDtioo
authorised as aforesaid'
I;: ;;; ;";.;;;r or rhe aurhotitv or oflicer
lnlormatlon, R6Port3 or Rcturna
fuociioo uader this Act' &onr time to
The Central Govemoeut may, h relatio! to its
od"",, st'te Gou"runetrt or oth"' altho'itv to firmish toandit
':;'""':;;;;";;;;oo.
:Tloff;::fi:i;il;''iiv oi oni"' a,,v reDorts' retu.s statistics' accou'rs
h;;iffi;;;; .,.n'pt"oo' oflicer' srare Go'emment or other authoiitv sball
be boutrd to do so.
Constltutsd UndGr Sccllon
Itlembers, Officsrs and EmPloysr! of thr Aulhorlty
3 to be Public Servants
s€ction 3 aod all offioels
e,iiat" .".t"r. of the authority, coostitutetl' if ady' u'ldet in Pu$uaoce
;;;;;; .--;l;** ofsuch authority whe! actilg or purPortiog ro act
issued thercunder
H;":;:;i"[J;;j; a.'-i tr' rut" 'ua" or or<lers or directions
sectior 21 of the Itrdiar
;ffiiil'ffi;;;'ioiri. '"'u*" "tnio the meatrins of
Peml Code (45 of 1t60).
Bar ol Jutisdictlon
Nocivilcou(shallhavejudsdictioDtoetrteltainalysuitolproceeditrgid'esPeclof
issued bv the central Govemoenr or
;;;;;;;;,'*,1";,akio or ortler or rlirection
of any Povrer conferred by or in relalion to
]ii,l l!, o, officer itr
uurloriw Pursuance
its or his functions utrder this Act
Powers to Oelegate
wirh^nrnreiudicetolheDrovisioosofsub-section(3)ofsection3,theCeDttalG-overD$ent
::Y";';:f;";J;ii" ilr"r"r Gazette, subject to sirch coaditioas and
'lelesare'such of its powers and functions
il;1;;i";;;;;;;.'specified in the notificatioos' atr authority uDder sub-sectioD (3) of
under this Ac! lexcept the povrers to constitute
decessarv or exPedietrt'
;;;il;;;;;"i: ,ules uader sectioo 251 as it Eav deem
io -y om".t, state Govemmeot or other authority'
2il ATexhook of Solid Wastes Menagement
14-4-E8
NotificatioD No s 0 38e (E) dated
*:""ll,il: Tfi:"fifii Unar rradesh videI44'R8:
,riTi.l.l i.,t" c","ne No 205 dared I7-5-88 published iD fie Gazene
ir""'i-^ir." 'ii. N,ificarion No S o 488{E' dated
No 255 dated 17'5-88;
Goa atral JaDmu & KashEir
iiolNo'so ESi (E- dated 22-9- 88; published
!ide Notlllcal
in rhe Gazette No. ?49 dated 22'9 Et published ia the
;":"r;;;;il.r;;ir',,ide Nodficado! N s o 408 (E) dated 6-6-Ee;
GazeBe No 319 daled 6-6'89; i,, thc Gazene No'
id;; il;; i,#;;;o' ir" s o 41s (E) dated 25'7 -st published
414 dated 25-1-91.
rFor issuing ditections see r'4 of ltoviroEaeDt (?rotectiod)
Rules' 1986
i.schedulelliststhestao.laldsfor€ldissiotroldischargeofetr..,konmentalpollutaats
their maximum allowable liniits
frosr the inalustries, prot"t"t o' Jptiut;oot "nd
of coDcentration;
,, ;;"";;ii;i";;;Deral staDdardsfor tlischarse of effluents and their maxiauo
limits of conceotra!ioo allowable'
iii,Scledulellllistsambieotairqualitystandardsi.drespectofDoiseaoditsmaxidum
_rrt,t
allowable limirs;and
"a'"i"d"i. iv elc' from motor
standards for eEission of smoke' vapour
Jlili.].i ""a ."'.i.,, allo$able limits of rheir emission'
and
ssee r. 13 of Environment (Protectioa) Rules 1986'
Wastes (Manag€ment and Handling)
Rules' 1989;
i. Hazaralous
ffi ATextoook ol Sotd Wast66 Managemanl
ii. MaDufactEre, Storage add lmport of Ilazardous CheEicals Rules, 1989; aad
iii. Rules for the Matrufacture, Use, I&port, Export aDd Storage ofHMaldous Miclo
organisms, Gedetically-engitreered orgaoisms or Cells.
6Rule 13 suPRA.
TSee r. 5 of EDvironEent (Protection) Rules, 1986.
3see r. 12 ofEnvironmetrl (Protection) Rules atrd Schedule 11, and relevaDt Provisious
of Hazardous wastes (ManageBent and Handling) Rules, Manufactule, StoBge and
IElport of Hazardous CheEicals Rules aad Rules for the Manufacture, Use, IEPort
Expoi and Storage ofhazardous Miclo-organisds, Genetically Engineered OrgaEisEs
or Cells.
esee r. 3 of Envirotrment (Protectiotr) Rules, 14t6 atrd Schedule I.
loSee r. 13 of Environrnetrt (Protection) Rules, 1986 atrd
rsTbe Central Govemmeni has delegated ils po\*ers uader clause (b) of sub-section (i)
of sectioD 12 and section 13 ofthe Act to th€ Central Pollution Contol Board vide
Notification No. S.O. 145 (E) dat d 2l-2-91 publishod iE th. Gazette No. 12t da'.rd
27-2-91.
l6The list of laboratories/rtrstitutes recoSlised as environmetltal laboratories: aDd the
pe.sons recogpised as Gol't. AMlysts is giveu in the table (p. 223).
r?See r. 9 of EnvironmeDt (Protection) Rules, 19E6.
leSee r. 8 of Enviroament (Protectio!) Rules, 19t6.
llFor qualifications of Govt. ADalyst see r. 10 ol EnviroElteut (Protectiotr) Rules,
1985.
Salent F.aaneo ol EnibnnentlPoleltonl Ad, 19,6 2o7
20In exerciseofpowers confered utrder clause (a) ofsecaio! 19, rhe cetrtral_Govemmert
has authorised the ofrcers arld authotilies listed ia the Talle G.238) vide S.O. 394
(E) published in the Gazette No. 1t5 dated i64-t7, s.o. 237(E) published in the Gazette
No. 171 dated 29-3-89 and s.O. 656(E) dated 21-t-t9 published itr the Gazette No.
519 daled 21-8-89.
2lsee foottroto 2 otr Page 213.
22see footnote 3 otr Page 213.
asee footnote I onPag€ 214,
2asee r.6 ofE[virotrmetrt (Protection) Rules, 19t6.
:5see r. 7 ofEtrviro[metrt (?rotection) Rules, 19E6.
26See r.9 ofEavironment (Protectiotr) Rules, 1986
27For the procedure for subnnissioD of saoples to labomto es a[d the form of Iaboratory
repo see r. 8 ofEnvironment (ProlectioD) Rules, 1986.
23see r. IO ofEflviroDE]etrt (Protectiou) Rules, 19t6'
2esee r. 1I of Eivtoooetrt (protection) Rules, 19t6.
il
I
I
I
Append.ix-IV I
I
Listof Hozard.oas and Toxic I
Cheru,icals T
I
Tte Hazardous Wastes (Matragemetrl& Hatrdlilg) Rules, 19t9 have beer
laid dowD by lbe Midstry ofEEviroE&etrt aDd Fotasl. Govemmeot of lDdia.
The followirg cheBicals have beetr declared itrthese Rules, as hazardous.
I
None of the Chenical I
I
2
3
4
Ac.torc Cyaaohydride
Ac.tylc Ctlorid.
Acetylere (EthFe)
I
5 Acrolein (2-Propenal)
6
7 A]dicrrb
8 Al&iD
9 aryl Phthalat
10 AIyl Alcohol
1l Alylaoine
t2 Alpha Naphthyl Thiourca (ANTI,
13 A!:ioodiphenyl4
t4
i5
l6
17
18 AE]-Boniun Nitates i! fenilizas
19 A.EmouiuE Sulfamale
20
21 Aniline
22 Anisidine-p
23 ArtiEony ald Codpourds
24 Antimony Hydride (Stibine)
25 Arseaic Hydride (ArsiDe)
List ol Hezadous endToxb Chemicals N9
!t
5l Butanone_2
106 Chlotonitobenzetre
58 Bdoxy Ethanol
t0'l ChloroPreoe
59 Bulyl Glycidal Etber Cltorosolphotric Acid
ter 108
60 Bui)..l Peroxy acelate,
109 Chlorotrinito benzene
II 61
62
63
Buq I Peroxlisobrryrale' tert
Btrr! I Perox\ rsopropll CarboDat€ ten
Butyl Pero4maleate, ten
110
111
tl2
Chloroxuon
Chrodiue and ConPounds
Cobalt aad ComPounds
I
64 Bubl PeroxYPivalate, TCRT Copper and Com?ounds
65 But) MnY1 Ether 114 ColrmafrYI
66 Buty-tr-M€icaPta! 115
67
I
116
68 C-9. Alomalic Hldrocarbotr Flaclion t1l cresots
69 Cadmium and Colnaounds 118 Clrmidine
70 Cadmiunr oxid€ (tunes) Table (contd. onP.210)
I
71 Calciunc)anide
I
rl
zlo ATextbook of Solid Wasles Marwgehent
203
Salts, Esrers, A-Erides
Fluoroacetic Acid and Sairs, Esters,
205
Fltrorccrororic Acid4, ad Sal6, E$ers5
I
161
162
163
Diisobuq'r-al Peroxide
Dimethoate
Dimethyl Phosphoraxoido cymide Acid
206
207
GlycoiiEite (Hydroxyacetonitiite)
Guaoyl-1, 4 Nirrosamiroguaryl-1- I
I
164 Dimehyl Phthaiate 208 Heptachlor
t
I
List of Hazadous andTadc Chafiicds 211
i-fr . -iii
fion P 211,
ot,t'" ct
"^i"ot
S-
340
No. Nane of the Chenical
Phospbile (Hydrogen PhosPhide)
I
300
301
302
olel]rn
oleylaliine
OO-Diethy I S-ErhylsutphonvlEcthvl
341
342
Phosphoric Acid ard Estrs
Phosphoric Aci4 Bronethyl BioEo
(22dimethylpropyl) Br@oethvl Ln€r
PhoQhoric Acid- Bronocrhyl Bromo
I
303
304
Phosbhorotiioate
oGDiethyi S-Etbylthio!*thvl Phos'
307
308
Oo-diethyl s-PtoPYlthiometbYl
Phosphorodithioate
O.yamyl
o^Tdisulioror
347
348
349
Polybronimled Biphenyl
PoassiuE Chlorate
I
309
310
311
Oxygetr Giquid)
OxygeD Diiuo;de
350
351
352
Prorourir (1-(3,,{-Dichlorophenvl)'
3-TnazeDefi ocarboxamid€)
PropanesultoDe- I , 3
Prcpeo,-1, 2-Chloro- 1,3"Do1 Diaceiale
I
I
3t2 Paraoxon (DiethYl 4-NitiophetrYl
353 hopylene Dicbloride
Phosphare)
354 Propytene ordde
313 Faraquat
355 Prcpyleneimire
314 Paraihion
I
356
3r5 Parathion MethYt
351 Sele um Hexaiuond.
316 P is gr€eD (Bis Ac€io Hexe@e@sinito
358 SeEicarbazide Hy&ochlonde
Tenacopper)
359
I
311
360
318 PeDlabroEodiphenyl oxide
36r sodiuE Chlorate
319
362 Sodium Cyaoide
320 ?entacbloro Napbthaletre
I
363 Sodium Picramate
321
364 Sodiunc Selenite
32.2
365 StF€ne, 1, 1, 2, 2-T€tachlorcethate
323 P€ntact thritol TetsaniE'ate
366 Sulfotep
I
324
367 Sulphur Dichloride
325
368 suiphul Dioxid€
326 Perchloroethylele
359 Sulphur Triond€
321 PerchloroEethyl MercaPtEn
r
370 Sulphrric Acid
328 PeEtaDone, 2.4-Methyl
Phetrol
371 Sulphoxide, 3-Chloro!ropyloctYi
329
Phenyl Glycidal Ethei 372 Telulium
330
Phenylene p-Diamine 373 Teluritm Hexafluoride
I
331
332 PheEylmercury Acetate
T.pp
375 Terbufos
333
376 Tetrabromobisphenol-A
Tetrachloro, 2. 2, 5, 6, 2. 5 Cyclo-
I
3',17
3]5
hexadiene- I. 4-Dione
336 Phosfolrn
337 Phosgene (CdbonYl Chloride) 378 Tetrachlorodibenzo-p Dioxin. 2, l.
7, 8 (TCDD)
33E
3-t9 319 Tetiaethyl Lead
I
I
I
I
T
T Listol Hezadous andToxic Chanbals 219
S.
S. No. Nane of,he Che'nical
405 TrichloroPhenol, 2, 2' 6
3EO TetrafluoroethaDe
406 Trichlorophe$I,2' 4, 5
I
181 TcrralrethyleredisulphoEEm, e
401 Triethylmise
382 Tetramcthyl Lead
408 Triethylenemelalriae
3E3 TeEaDritrometbaae
t
409 TriEethyl Chlorosilae
3t4 Tha]iu:r & CoEPouds
410 TridethyloploPare Phosphite
385 Thiozitr
411 TriDitromiline
386 Thiodyl Cbloride
4t2 Tri toadsole,2,2,4' 6
3a1 TfPate
413 TndtobeEz€ae
388
I
Toluere
3E9 Toluidieu-2,4Diisosya$te 414 Trhitobesoic Acid
390 Totuidi€rc-O 4t5 Tdnitrocresol
TriniuoDhenetot€. 2, 4, 5
391 Toluetre 2, 6_Diisocyanatc 416
(St)"hic AciO
I 395
396
TribroEoPhesol, 2, 4' 6
Trichloro Acetyl Cbloride
421
423
.
Turp€Dtine Uranium & coEPounos
va[adiurtr & ConPounds
rr,lyl Chloride
I 401
402
403
Trichloroeth$e, I' l, i
Tdchioroethyl Silarc
T.ichloroethyteDe
TrichtoroBetbarcsdpheryl Chloride
424
429
Saarce: MOEI.
Zinc & ClEPouds
ziconiuD & ComPounds
I
404
I
I
I
II
It
T
I
I
I
I
References I
I. ADB.1991. Guidelines fot Social Analvsis
ofDevelopnent Ploiects Asian
I
2.
De!elo.Eert B.nk, Madla, Philippires
ii.- 'illirg.
.I
s"ua **,e Marase"oesl Pla! for L'diaoMegacities'
Environnental Protection' l9(2\: 1999 '
hdidz
I
^i". nii,osst
I
Del eloDrtrmr of Software for E,vironf,ellal Managemmt'
3. 'il) .a * r*ircnnehtot chattense'lo' the Nei Mittennnd
'iZ7i^',ii)n"i',' na" nkmohona cenne'NewDeLhi on 25-2TNovenber
I
1999.
4. i1-o"uonnr., *a *aslfall. M' 1988 Selectio' ofHazardous wasle
C.
i*o-r"l"jrft.-"i'. u'i'g M,rhi-attribure Tteor) and Fuzzv Se( Analvsis'
t"*,,t otta'iro"nenat Slrrt'i l8l I ): 69_8{ vater a wa'tevater'
5.
6.
tEi. Gsa. srcaora a"thodsfor the tuanination af
Aeerica! PubIic Health Association' NY'
Tsrru.Vsl-.')""",t B""k al ASrM standords-watet and Ewnon
'i""t
entat
r"t.o.va. tOo Axoerrcan Sociery for Testing andolMarerjals
I
iiili."6nz.. s',,a*a ,e netaod tot detentaalion conpoiiion
7. '""ii"2a
ASTM
al
.**,pa *mvaJ,e' Americ'tr soci€! for Testing arra Matedais'
'""r.it, Method D 5231-92'
sttuction ond Mannotins ofsanitdrv'Landlitt toh"
I
t
Sotrs, NY."r,
wilev &".1;0.
s. ;"*ll;n.l;0. a"', sa cansttuc on ond voano'iry olsan arv randflt'
Wile,t & Soos, NY
-"-*".Ii.
lobn
I
10. ls-t. C--a\arc- bdrotas.zrid edn Mccraw-Hill NY
11. s"ili, i. 1gss.,erd- L stine oJ
t2.
22(121, PP ll97-1399.
i-".*.'c
Soits. En|irondentat Science Technotost'
I5.
i.i*u*ira,t""., ci"lt flgineel-l.os seres' Mccraq'HiI tn( ' N/'
-*"Ji".-i. i.al lsso. rr, /so i a00a Handbook ' A ptocticot conprehensite
*,ae rc tSO t,A\asrc.dard: tnDlene'Q oa aad eawakacatal daaageneat
I
i.,,"- -.,t*, - CLEM l,Iomarion ser\ rce' Jarfax \ irgiDta'
I
I
I
Relerences 215
M.Kl[,lev, $A7 ' The Geotogicat DBPo'al ofNuctear Waste tl llcv &
16. ChapEar, N. A. aEd
Soff, Chichest.t.
tz.6i"'.iiJ"r',i,lsgo.BiolosicalTr€atm'ltofuazardouswast'sludg$andtrastcwater'
P ollut rcn En grceinq, MaY t99O'
Laodlills. ia
,t. n. *-a Kicidser, P 1984 2 1 Basic Biooiemical Proccsses in
'" ti'i",.""*,i
Ctrl-t *"*'r rf., c*.q'R- a StcgDa'r, P
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P l annin s Sc i ence s, 25(2): S9-102.
Sector: An Application
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41 Evans, R. B. and Schw€irzer. 1984. Assessing Hazardous Waste
Ploblems. ,nri,o,zezral
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42 Farquhai, c. J. alld Rovers, F. A. I973. cas Boductio! Duriag Rctuse
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43
45_
riDsrer M. S. I
??. Cooposting io the CoDrE$ ofMudcipal Soli d,Wa$EMdIieelnan_ b,liroMental
Mi tob iol og, 5a: 35 5-37 4.
58.
Atuedneh!' Lite,aturc R?y,"v. sotidwasre Comeosring C;uDcii, wasii;s;;;i.
Hyar.G $-reoj lhe Rote of.onsudet p,oducrs ionpaiies nsotid n;;;""
Proc. of rhe Noflheasr Sotrd wasre Composri.Es CoDfer*".. Sotia w"""
i;,;;;^.",
co.poi,;;t;;ti.
""
a
a
Washinoron Da
59 IAEA.^ia,o. Maaual on Radiotoltcot Safety ia Uraaiuh a Thotiun
Min.s aad Mitts.
satety sefles. Irrematioral CoEmissioE oD Radiarjoa prorection. pergamoE press,
NY,
60. Indian staldaIds bjururiol]qlga. tndianstondad, htethodt_ pt";.;;;;4
sahpte fu chenr at d Mkrobiotosicat Anatysis. ts:s
s+_r.t,s "ii.iir^_,
;.[;i;d;;Inh*;.
a
I
NewDelhi
61. hdian Standalds IrEtitudon I9j . rndi.n S,@d@d: tiethodlot ph\icat Anatysis and Detemihorioh
orvast,te h Satid tC\.tudhc tndariiatsotid r;.".is, gr3j.is;. ird,"r's;I*i,
.wasks
I
62 Inrlian Staldards Insiitutio n tg82- Iidian Standard: Gtidetines
ofFly As h.13: 1A153-19E2. IndiaE SlaDdards IastirutioD. New Delhi_
fot (ritizatian dad Disposat
63- 158.M.1997. Ehrirmtuentat Inpact Assesrnent
Ia
o:[ Internatioaat Eotets project in Dethi.
Indian Sociery of LrviroDmenral Managelqetrr, New Delbi.
61- lSE\1. )0oo De"elapnent o1Sdisrics m Eivircnnenot
Secto. - So!id wa:ter.lndian Socren
o'ED! iroorDeDLrl ManageDe!r. Neq DeIIj. Jaruary.20O0.
I
olwa$e Matragement' UK
6s lwr D9A. Ti'a Monilorihg af La fll Gasol lnslitule fie APe\
-
tee on sanlauon'"1!c' Apex
li"" l""-"i*. trso. r" potr oi rhe chat*an 'ond
ili#,.i. i",iiri,rla trltacenrt' u't* o'u'top'eot ti'ep"rneor' co-uemmenr orDerhi'
;;;;.;;;' L. v' c' s'' ana tiatcach' H E" eei' Env!/onmentut assess- eht'
r
I
za ATexfbookol Sotidwastes Menaganelt
"'r02. ',,iil';'flLlllli'"tl::!,iy:iil'i.fi"ii:;;*;iny"',:*,*rr*ui,....,'ur
Li:::
peirs. J. (ed r l ocob Ha:dbo.ot o!
a,,d::isi.riols. Bracxq€ll soeDce Lonoo..
Pr^;:':iyp*:#i;;';;;', ,,a
tEpacle AssessD,ml rE i,."*^"^r", w", r*,',",,
tol Pens.l. and Eduljee G 1994 hnrtto'
'""';;;;";,,;;",,';'"P.Yi':'lt"T);;
G 1994 Lnv.tto atrnpactAs,essnentro,wosprrca!deatatti
'" . Petis,
104. 'i,,i.*tJ. ard Eduljee'
r*'t'*'' John wtlev.and Soos NY
olervieq..L Poneous. A. red., dazardour
,". "^;""',. A 1985. Hazardous wane t
;*iiiiJ,ffi
*$i+ttl*r}-m***l+:':tln,''zu
tO;. n'";or"ta.l. v -a Vogel w' R'
195E'
111. Schapiro, J. lgEl. Railiation Protection: A Guide lot Scientist and Phvsiciahs' HaraaId
UdversiN Press. Cambridse.
rr:. icsirgi'..'s. rsls. M;iciPal Sotid waste Sttnev Ptotocol USBPA' ciacifllati - . -
iii. iiii"eil*". rss2.waste iharacterizotion studv'sotidvaste ManaE Bent Pton Faifsx'
Vngida
ii;. iil;ii. llis. a."ati* il ro,;c and Hazardous che icats and carcinosens Noves
Publi€ations, NJ.
,q., r-:"", F. M. and turdrer1's' R- N L 186 EcotroEic Impacts
ofHazadous wast'
r lo. i.i'ti. r'l
-.-- ::: Hazardous Yaste and Hazardous Materials 3(2)'
Ir7. Sobt1. k. C.. Obe. G. a
Quillardet, P 1999 ?enits in Lnviron'nental Mtttagenesis'Ta1lsco
Book Dist iburots, New Delhi.
rra. i"Ua W".t" C..p"sti!g Council lggl' ConPost Fa'ilitv Planning Gtide Jor Mtnicipal
So/d,7ar,e. WashiDClotr DC.
l : S iotia Vaste Uaaage;err ia Class I Cities h Ludia RePort ofthe CoEmittee constituted bv the
tlotr Suorerne Coun ofladi.- Marcb 1999'
ent En'i'ohnentdl
L:0. i'p*.., i. r. is83 A"aeroblc biotechrolos/ for Industli{wa'leqz,'etTiean
Science and Technotosr. r1(9\ '
Piess'
,2, i."-rl".lern. r. r. rss l.fuonnoring Ecologicat Chanse caEbridge Universitv 9aTbrilce
i;i ii-'|"-i. c. *arenke,t 1q94. La;dfn conpaction: settinsa Densitv standard.\ a'te
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Ind.ex
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lar nlls,70 60,63-64, 109-12, llE-119. 125, 165,
L9t- 2t0-t2
qydlo8eo aDalysis, 13
1E5,
I
Eaerey recovery, 7. 11, 32, 35. 64, 66,'70. 77.
113, 116-19, 131, 141, 191-92
EnvnorEeotal audit, 126, 181-85, 189
I
hcinelalioD,7, q. 14. J8.30.41-42. 128, r33-
31, r47, 17E, t91,
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EDviroErental impact assessmeEt (EIA), 2 1, 68-
69, 129, 156,57. i59-60, 172, 180 IrdBtriat waste, 3-4, 20, 81
Envnonmeftal ioaDagemeEr plar, 15 7, 16i, 164, Iustitutional wastes, 3
168, t70,114,177 lnregrated solid wasre mznagemeot, 6
Etrviionmenral monilodrg. 67-6E, E6, 128,131, h-v€ssel composting, 48
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F Junt dealers. 27
Field capacit), 8.9. 10,25, 89-90
Final cove!, 66, 72-75. 82. 84, 86, 114, 131
x
Flare burtrer, 119 Kjeldahl Eethod, 13-la
Fleing oflarldfill gar,
Floatatioa sepalatioo, 33
1
G
end loade! 11 Lad6[irg methods, 6E
Larxdfills, 10, 18, 28-29, 38, 62-67,71,75-76.
89. 93-95. 97- I0l. I I l- 13, I I 8,19, 124, 128-
3:, 134-35, t4r, t44. 141,151. t62. t72-
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Gas cortrol. 62, 68, 73. 83, 109, 115, 119, 173,
GasEigatioE,75, 109, 113-16, 122
73,118
Layout of larxdfi li. 69:70
Gasifica.io& 7, 38, 44, 61
Leachare. 72. 88. 90. 92. 98. 106-0?
Ger€ration ofsolid wastes, 4
Oeographic IrforEatior Systern, ?.32. 171
GeomeD:brane, 66, 83, 92-97, 99,98, 107-08
Georerlile, 04
Glass, 3, 5, 6. 8-9, 12. 15,32-35,37-39,51,
Leachare collectio!, 98
Leachat€ cort'ol,68
t0r, 104, 106, 108
Leachate treatmetrl, 67,
Legal ftahework. 156-5?, 171
I
56-5'.60,10, r28, r3r, r'6,
GovernEelt Euidelhes. 19
Groundwdter laonitoritrg, 7 7-7E,
r78
Lhers,68, 92-95. 97. 99, 173. 181
M a
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Magreti. separatiotr, 33
E Material recovely, 6,9, 132, 178, 192
Mcchaaical size reduction. 34-3 5
HaDrr1erEilis, 34 Metals.5-?.9. 12. lS. lE..26-27,32, 35, 38-
Il
Haui distarce,29. 52-53,60. 67. 191, 178 39, 48, 51. 50, 100-01, 2, t25, t34,137,
Hazardous wastes. 3. 16. 72, 81, 92, 197. 123- 1 43-47. 162, t65, 17 6, 11 8, 192
29, t3t-32. t43-44, t5t, 154, 164 Methane, 43, 45, 50, 63-64, 83-84, 100, 104,
HELP nodel, 90-91 109-13, tt7-22, t47,165, 173,192
Hois: truck collectioE. 3 1
Hospital wasre, 3. 134, 136
Hurus,45,74
Hydrogen, Il-13. 15,24-25, 43-44. 41, 50, 59-
Mekic conversioD factors, 194-95
Moisiure content, 8-9. 1 1 . 22-25 , 42. 45 -4a. 58-
89-90, 94, 9?. 100-01, 111-12,144, t46, 17E.
a
a
192
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lndex 2j23
Residentral $as(e.43
Molrtori4 o{lardfill gas' 71 -- -^ .. Residues.7,2l,36. 39. 62. 82 128, 132 136
I{u,crpalsolid waste 4 S'19'I/
rr' --
)r')u' 6
R esource tecovery, 26, 3
39.4?,51, 108 Rotathg biological cotrtactors, 102_1 03