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https://doi.org/10.1093/ce/zkad067
Advance access publication 17 November 2023
Research Article
Abstract
Thermoelectric devices are one of the technologies used either to generate electricity by applying a temperature difference using
thermal energy or as a heating/cooling system by applying an electrical voltage. The number of materials required to produce a
product is an important factor in determining its price. Production costs associated with these materials, as well as their availability
and quality, play a crucial role in price determination by manufacturers. In this context, a method that employs a uniform volume
distribution was implemented. This approach enabled the analysis to focus on other variables, thereby promoting a more precise and
relevant evaluation of overall performance. Based on the finite element method, this study investigated the influence of geometric
shape, including Rect-leg, Y-leg, Pin-leg and X-leg designs, on the performance of solar thermoelectric generators and thermoelectric
coolers. The study was conducted considering the same hot alumina junction surface that receives solar radiation; however, the ef-
fective surface, which corresponded to the heat flow area and had a similar area near the exposed surface, varied depending on the
chosen leg geometry, thus impacting the heat flux due to the variation in thermal resistance. In the case of a solar thermoelectric
generator, the Rect-leg model, having the same effective surface area, presented the lowest heat loss value resulting from convection
and radiation in the heat spreader and the hot alumina plate. Under the same conditions, the Y-leg showed the highest value. The
Rect-leg design generated, by using thermal and optical concentration, the highest output power of 0.028 and 0.054 W, and efficiency
of 3.47% and 4.7%, respectively, whereas the Y-leg generated lower values of 0.006523 and 0.018744 W for power, and 2.83% and 2.71%
for efficiency, respectively. In the case of the thermoelectric coolers, the Y-leg generated the highest temperature difference between
the hot and cold sides of 67.28 K at an electric current value of 1.8 A, whereas the Rect-leg, Pin-leg and X-leg generated ~66.25, ~67.02
and ~67.19 K at 6.1, 2.7 and 2.6 A.
Graphical Abstract
2.4 mm 2.4 mm
4.8 mm 2.4 mm 4.8 mm
4.8 mm
4.8 mm 2.4 mm
1.4 1.4 mm
A1 1.4 1.4 mm 1.4 mm
1.4
1.167 mm
1.4 1.4 mm A1
L3 A1
1.167 mm
A1
L3
A2
2.3345 mm
1.6 mm
L1 A2
0.9 L2
1.936 mm
L4 0.9 mm
L3 0.9
1.167
0.9 mm
A1
A2
0.9
A B 0.9 mm C D
Fig. 1: Geometric design of the legs (a) Rect-leg. (b) Y-leg. (c) Pin-leg. (d) X-leg.
respectively
A B A 450
B
0.035 0.05 Rect-leg 70 Rect-leg
System efficiency
0.025 50
350
0.020 0.03
40
0.015 30
0.02 300
Fig. 2: Variation of efficiency with (a) thermal concentration ratio. (b) Optical Fig.3: Variation of (a) Temperature of cold side, (b) Temperature difference with current
concentration ratio. (TH = 300 K).
Table 7: Minimum of the cold side temperature for the TECs models.
Table 6: Performance of the STEGs for thermal and optical concentration
Thermal concentration Optical concentration Model Rect-leg Y-leg Pin-leg X-leg
Rect-leg 70 0.028004 3.47 100 0.054148 4.7 Electrical current (A) 6.1 1.8 2.7 2.6
Y-leg 20 0.006523 2.83 60 0.018744 2.71
Pin-leg 30 0.010561 3.06 60 0.022214 3.21
X-leg 30 0.010603 3.07 60 0.022169 3.21
Keywords: solar thermoelectric generators; heat loss; thermoelectric coolers; coefficient of performance; leg geometry; same leg
volume; performance
operating without a condenser was conducted. This system pro- (Bi2Te3) is chosen as the base material for the design. The p- and
vided an efficiency of ~4.5% under the reference operating condi- n-type legs are connected thermally in parallel and electrically
tions [13]. In [14], modelling and analysis of a car-mounted STEG connected in series through copper electrodes. Furthermore,
with a vortex tube for hybrid vehicles were conducted. The results thermoelectric elements and copper electrodes were placed be-
depended on the speed of the vehicle, the cold air mass and the tween two alumina ceramic plates to support the mechanical
solar flow. This STEG system generated an output power and an stress between the hot and cold junctions while avoiding elec-
electric current of ~147.3 W and ~1.49 A with a vehicle speed and trical interaction.
a cold air fraction adjustment of ~55.5 m/s and ~0.9, respectively. In Fig. 2, the Y-leg, Pin-leg and X-leg models have the same
An experimental study of a thermocouple using solar energy volume and hot junction of the cross-sectional area of the Rect-
during the day and cold air at night was performed [15]. The vari- leg model, as shown in Relationships (1) and (2), while the leg
able leg geometry of the TEGs by leg length and cross-sectional length is variable:
area was an important factor in improving the performance of vY−leg = vPin−leg = vX−leg = vRect−leg
(1)
the device [16–21]. A comprehensive model of the multi-mission
radioisotope thermoelectric generators (MMRTGs) was developed, A1, Y−leg = A1, Pin−leg = A1,X−leg = A1,Rect−leg
(2)
in which the thermocouples (TEs) of the MMRTG consisted of
1.6 mm
1.4 1.4 mm
1 Studied geometries
1.4 1.4 mm
TEs are modelled and simulated for four diverse geometric
shapes: Rect-leg, Y-leg, Pin-leg and X-leg. The Rect-leg model
is an established geometry, whereas the other three were de-
veloped for this research. The rectangular geometry legs
of the GM200-31-14-16 module manufactured by European
Thermodynamics Ltd are the current standard leg geometry,
which was chosen as a reference (see Fig. 1). Bismuth telluride Fig. 1: Thermocouple of the GM200-31-14-16 modules
1236 | Clean Energy, 2023, Vol. 7, No. 6
1.4 1.4 mm
A1 1.4 1.4 mm 1.4 mm
1.4
1.167 mm
1.4 1.4 mm A1
L3 A1
1.167 mm
2.3345 mm
1.6 mm
L1 A2
0.9 L2
1.936 mm
L4 0.9 mm
L3 0.9
1.167
0.9 mm
A1
A2
0.9
0.9 mm
A B C D
Fig. 2: Geometric design of the legs (a) Rect-leg. (b) Y-leg. (c) Pin-leg. (d) X-leg, respectively
Solar irradiation (qs) system. The convective heat loss by convective heat in the STEGs
for all the studied models was calculated using the air properties
dependent on the ambient temperature (T), as shown in Table 2.
Tables 3 and 4 give the properties of the materials used.
Thermoelectric materials properties of p-type and n-type Bi2Te3
Qint are dependent on the temperature equations, as shown in Table
Qrad Tint
3. The thermoelectric properties at average temperatures are cal-
Thermal concentrator
QH culated. To understand the system behaviour of the STEGs, a 3D
Q rad
TH Qrad simulation is performed using a program based on the FEM. Fig. 5
P N Vacuum Environment
illustrates the flowchart showing the different stages of the simu-
lation study.
Heat Extractor Enclosure
Copper
2.2.1 Boundary conditions
Alummina plate
Rload Some assumptions related to boundary conditions are made:
Glass
(i) Heat transfer by convection and radiation on all TEG sur-
Fig. 3: Schematic diagram illustrating STEG using thermal faces is neglected except for that on the ammonia plate
concentration on the hot side.
(ii) Electrical and thermal contact resistance are not con-
sidered.
2.2 Mathematical model
(iii) There is no difference in properties as a function of pos-
To evaluate and compare the performance of the STEGs, a 3D ition.
simulation of different geometrical shapes was carried out with
the same leg volume, as shown in Fig. 2. The solar radiation, cold- The electrical power produced by the STEG depends on the tem-
side temperature and ambient temperature were set at 1000 W/ perature of the hot side generated from the concentration of solar
m2, 300 K and 298 K, respectively. An aluminium heat spreader radiation absorbed by the selective absorbent surface, the tem-
was placed on the hot side of the TEGs. Due to the different max- perature of the cold side, the Seebeck coefficient, electrical resist-
imum allowable lateral temperatures of the Bi2Te3, the operation ance and thermal conductance.
of the proposed models was examined under different thermal In thermal concentration, the heat flow on the concentrator
and optical concentration ratios (Cth and Copt). Different leg geom- can be calculated using the following equation [6]:
etry affects the thermal and electrical resistance of the models
studied. Therefore, the external load resistance was considered (3) Qint = τg αs qs Cth As
equal to the internal resistance of the model. Table 1 shows the The temperature generated on the hot side of the TEGs de-
parameters used in the simulation of the solar thermoelectric pends on Cth:
Solar thermoelectric generator and thermoelectric cooler performance | 1237
g β δ3 (Ts − Tair )
Table 2: Thermophysical properties of air [29,30] Ra =
(11) vλ
Properties Values Units Thermal expansion can be written as follows:
Seebeck coefficient (α) 1.291689 × 10–13 × T3 + 1.074408 × 10–9 × T2 – 9.271759 × 10–7 × T + 8.95888 × 10–6 (V/K)
Electrical conductivity (σ) (1/(–1.24614 × 10–14 × T3 – 6.429015 × 10–11 × T2 + 9.103036 × 10–8 × T – 1.049646 × 10–5)) (S/m)
Thermal conductivity (k) –1.592653 × 10–8 × T3 + 2.905845 × 10–5 × T2 – 1.58323 × 10–2 × T + 3.727526 (W/(m-K))
p-Type
Seebeck coefficient (α) 5.921376 × 10–13 × T3 – 3.274207 × 10–9 × T2 + 2.422355 × 10–6 × T – 2.743842 × 10–4 (V/K)
Electrical conductivity (σ) (1/(2.248899 × 10–14 × T3 – 1.250867 × 10–10 × T2 + 1.388189 × 10–7 × T – 2.244786 × 10–5)) (S/m)
Thermal conductivity (k) 1.251606 × 10–7 × T3 – 1.242845 × 10–4 × T2 + 3.873788 × 10–2 × T – 2.362707 (W/(m-K))
1238 | Clean Energy, 2023, Vol. 7, No. 6
A 40 B
Model [10] 3.5 GM200-31-14-16
35 Presente model
Model [10] 3.0
30
Efficiency
25
GM250-127-28-12
20 2.0
15 1.5
10 Model [10]
1.0
GM200-31-14-16 Presente model
5 Model [10]
0.5 Presente model
0
0 50 100 150 200 250 300 50 100 150 200 250 300
Fig. 6: Numerical model validation. Variation of (a) output power and (b) efficiency with Copt.
A B
800 800
700 700
600 600
Tint (K)
Tint (K)
500 500
Rect-leg Rect-leg
400 Y-leg 400 Y-leg
Pin-leg Pin-leg
X-leg X-leg
300 300
0 20 40 60 80 100 0 20 40 60 80 100
Concentration ratio (Cth) Concentration ratio (Copt)
Fig. 7: Variation in the hot-side temperature of the STEGs with (a) the thermal concentration ratio and (b) the optical concentration ratio
0.20
Heat losses (W)
0.4 0.15
0.3
0.10
0.2 Rect-leg Rect-leg
Y-leg Y-leg
0.05
0.1 Pin-leg Pin-leg
X-leg X-leg
0.0 0.00
0 20 40 60 80 100 0 20 40 60 80 100
Concentration ratio (Cth) Concentration ratio (Copt)
Fig. 8: Variation in heat losses with (a) the thermal concentration ratio and (b) the optical concentration ratio
A B
0.6
0.8
0.5
Heat flow on TEGs (W)
Heat flow on TEGs (W)
0.6
0.4
0.3 0.4
0.2
Rect-leg Rect-leg
0.2
Y-leg Y-leg
0.1 Pin-leg Pin-leg
X-leg X-leg
0.0 0.0
0 20 40 60 80 100 0 20 40 60 80 100
Concentration ratio (Cth) Concentration ratio (Copt)
Fig. 9: Variation in the heat flow on the hot side of TEGs with (a) the thermal concentration ratio and (b) the optical concentration ratio
decrease to zero for all the studied models because the Peltier current. At the lowest current values, the Y-leg model presents
effect gives the best results when the electrical current is small. the highest values of the heat released, and the Pin-leg and X-leg
The Joule heat, which offsets the cooling effect, makes a differ- models have almost the same values, while the Rect-leg model
ence when the values of the electrical current are higher. Due to gives the lowest values.
the effect of the variable leg geometry on the thermal resistance, In the cooling process, all the models studied give the same
the Y-leg, Pin-leg and X-leg models produce low heat absorption maximum performance coefficient values of ~0.695 at the dif-
at low electric current, and the Rect-leg generates high heat ab- ferent electric current values. The Y-leg model presents the max-
sorption at high electric current values, as shown in Fig. 16a. The imum COPCooling value at an electric current of 0.82 A, the Pin-leg
results show that the maximum absorption heat of the Rect-leg and X-leg models at 1.1 A, and the Rect-leg model at 2.41 A, as
is 0.178 W at electric current values of 6.1 A, and the Pin-leg and shown in Fig. 17a. For the heating process, all the studied models
X-leg are 0.081W at 2.84 A, while the Y-leg is 0.061 W at 2.05 A. give the same COPHeating value of ~1.695 at the same electric cur-
In Fig. 16b, the released heat increases with the applied electric rent values in the cooling process, as seen in Fig. 17b.
1242 | Clean Energy, 2023, Vol. 7, No. 6
A B
460
440 500
380
400
360
A B
0.035 0.06
0.030 0.05
0.025
Output power (W)
0.020
0.03
0.015
0.02
0.010
Rect-leg Rect-leg
Y-leg 0.01 Y-leg
0.005 Pin-leg Pin-leg
X-leg X-leg
0.000 0.00
0 20 40 60 80 100 0 20 40 60 80 100
Concentration ratio (Cth) Concentration ratio (Copt)
Fig. 11: Variation in the output power with (a) the thermal concentration ratio and (b) the optical concentration ratio
A B
0.035 0.05
0.030
0.04
System efficiency
System efficiency
0.025
0.020 0.03
0.015
0.02
Fig. 12: Variation in efficiency with (a) the thermal concentration ratio and (b) the optical concentration ratio
A B 0.06
Rect-leg Rect-leg
0.030
Y-leg Y-leg
0.05 Pin-leg
Pin-leg
0.025
0.03
0.015
0.02
0.010
0.005 0.01
0.000 0.00
0.00 0.05 0.10 0.15 0.20 0.00 0.05 0.10 0.15 0.20
External load resistance (ohm) External load resistance (ohm)
Fig. 13: Output power of the STEGs. (a) Thermal concentration and (b) optical concentration with external load resistance.
Efficiency
0.020 0.03
0.015
0.02
0.010
0.01
0.005
0.000 0.00
0.00 0.05 0.10 0.15 0.20 0.00 0.05 0.10 0.15 0.20
Fig. 14: Efficiency of the STEGs. (a) Thermal concentration and (b) optical concentration with external load resistance.
Cth Power (W) Efficiency (%) Copt Power (W) Efficiency (%)
Table 7: Minimum cold-side temperatures for the TEC models tration, the output power increased with the concentra-
tion ratio for all models studied.
Model Rect-leg Y-leg Pin-leg X-leg
✓ In thermal and optical concentrations, the Rect-leg model
Temperature of cold side (K) 233.75 232.72 232.98 232.81 gave the highest output power of 0.028 and 0.054 W, and
Electrical current (A) 6.1 1.8 2.7 2.6 efficiency values of 3.47% and 4.7%.
A B
450
Rect-leg 70 Rect-leg
300 30
20
250
10
200 0
0 2 4 6 8 10 12 0 2 4 6 8 10 12
A B
0.20 2.5
Rect-leg
0.18 Y-leg
0.16 Pin-leg 2.0
Absorbed heat (W)
X-leg
0.10
0.00 0.0
0 2 4 6 8 10 12 0 2 4 6 8 10 12
Fig. 16: Variation in (a) the absorbed heat (QC) and (b) the released heat (QH) with electrical current at ∆T = 30 K
A B
2.0
0.8
Rect-leg Rect-leg
1.8
0.7 Y-leg Y-leg
Pin-leg 1.6 Pin-leg
0.6 X-leg X-leg
1.4
∆T = 30 K
∆T = 30 K
COPCooling
COPHeating
0.5 1.2
0.4 1.0
0.8
0.3
0.6
0.2
0.4
0.1
0.2
0.0 0.0
0 2 4 6 8 10 12 0 2 4 6 8 10 12
Fig. 17: Variation in (a) COPCooling and (b) COPHeating values with electrical current at ∆T = 30 K
Nomenclature
TH Hot-side temperature (K) As Aluminium plate area (m2)
TC Cold-side temperature (K) k Thermal conductance of model (W/K)
∆TH Temperature difference (K) vleg Thermoelectric leg volume (m3)
σn Electrical conductivity (n-type) (S/m) Λ Thermal diffusivity
σp Electrical conductivity (p-type) (S/m) Qrad Radiation heat losses (W)
αn Seebeck coefficient (n-type) (V/K) Qconv Convection heat losses (W)
Solar thermoelectric generator and thermoelectric cooler performance | 1245
αp Seebeck coefficient (p-type) (V/K) QH Heat flow at the hot side (W)
kn Thermal conductivity (n-type) (W/(m-k)) QC Heat flow at the cold side (W)
kp Thermal conductivity (p-type) (W/(m-k)) Qint Heat flow on aluminium plate (W)
Nu Nusselt number Copt Optical concentration ratio
RG Total electrical resistance (ohms) Cth Thermal concentration ratio
RL External load resistance (ohm) μ Thomson coefficient (V/K²)
L Leg length (m) I Current (A)
A Cross-sectional area (m²) P Output power (W)
Rp Electrical resistance (p-type) (ohms) η Efficiency (%)
Rn Electrical resistance (n-type) (ohms) qs Solar radiation (W/m²)
Aopt Aperture area of the Fresnel lens (m2) hair Heat transfer coefficient (W/(m2-K))
Ateg Cross-sectional area of the ceramic (m2) ε Emissivity
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