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➢Joining n-type material with p-type material causes excess electrons in the n-type
material to diffuse to the p-type side and excess holes from the p-type material to
diffuse to the n-type side.
➢Resulting a charge separation which can flown to external circuit and hence
convert light energy to electric energy
Formation of a PN-Junction
➢Joining n-type material with p-type material causes excess electrons in the n-type
material to diffuse to the p-type side and excess holes from the p-type material to
diffuse to the n-type side.
➢Movement of electrons to the p-type side exposes positive ion cores in the n-type
side while movement of holes to the n-type side exposes negative ion cores in the
p-type side, resulting in an electron field at the junction and forming the depletion
region.
➢In equilibrium, the net current (diffusion and entrainment) is zero for both
electrons and holes, because the diffusion current is equal and opposite to the
drag current for both carriers.
➢Junction diodes pn are the basis not only of solar cells, but many other electronic
devices, such as LEDs, laser diodes and bipolar junction transistors (BJTs).
Interesting things happen when you put an N-type material in
contact with a P-type material.
Before making the contact:
Ping Hsu 4
P-type boundary N-type
(Negatively charged!) layer (Positively charged!)
In the boundary layer, the free electrons in the N-type materials
combine with the holes in the P-type. Consequently, the P-type
side of the boundary layer is negatively charged and N-type side
is positively charged.
5
The
Ping Hsuboundary lay is called PN-junction or depletion region.
n-type and p-type materials brought together.
V0 depends on...????
V0 = (KT/q) ln(NAND/ni2)
E
Semiconductor devices have three modes of operation:
Under steady state there are external inputs such as light or applied voltage, but
the conditions do not change with time. Devices typically operate in steady state
and are either in forward or reverse bias.
➢3. Transient
If the applied voltage changes rapidly, there will be a short delay before the solar
cell responds. As solar cells are not used for high speed operation there are few
extra transient effects that need to be taken into account.
Bias of PN Junctions
• electron in conduction band at
N side decrease exp with high E
• holes in V band at P side decreases
exp with lower E level
• Due to concentration diff, electrons
from n side should move to p side, but
faces potential barrier as C band at p
is higher than n side.
•Only few e can diffuse to p side,
giving diffusion current of e from p-n
•E at p side are minorities but at highr
energy level, can easily drift to n side
due to E field in depletion region
•This gives electron drift current from
n-p
•Same things happens for holes of p
side diffusion and holes from n side
drift
Forward Bias PN Junctions
➢Forward bias occurs when a voltage is applied across the solar cell such that the
electric field formed by the P-N junction is decreased. It eases carrier diffusion across
the depletion region, and leads to increased diffusion current.
V0 – VA in forward bias
Both electron diff and hole diff current flow from p to n in forward biasing
Net current is known forward bias current
Reversed Bias PN Junctions
➢Reverse bias occurs when a voltage is applied across the solar cell such that
the electric field formed by the P-N junction is increased. Diffusion current
decreases.
Ideal Diodes
The diode equation gives an expression for the current through a diode as a
function of voltage. The Ideal Diode Law, expressed as:
where:
I = the net current flowing through the diode;
I0 = "dark saturation current", the diode
leakage current density in the absence of light;
V = applied voltage across the terminals of the diode;
q = absolute value of electron charge;
k = Boltzmann's constant; and
T = absolute temperature (K).
The "dark saturation current" (I0) is an extremely important parameter which
differentiates one diode from another. I0 is a measure of the recombination in a
device. A diode with a larger recombination will have a larger I0.
Note that:
I0 increases as T increases; and
I0 decreases as material quality increases.
At 300K, kT/q = 25.85 mV, the "thermal voltage".
Non-Ideal Diodes
For actual diodes, the expression becomes:
where:
n = ideality factor, a number between 1 and 2 which typically
increases as the current decreases.
PN Junction under illumination: Solar cell
PN Junction under illumination: Solar cell
net charge increase + at P and – at N build up a potential difference across P-N junction
This photo voltage due to light is photovoltaic effect
PN Junction under illumination: Solar cell
Role of diffusion length?
The -1 term in the above equation can usually be neglected. The exponential term
is usually >> 1 except for voltages below 100 mV. Further, at low voltages the light
generated current IL dominates the I0 (...) term so the -1 term is not needed under
illumination.
The short-circuit current (ISC), the open-circuit voltage (VOC), the fill factor (FF) and
the efficiency are all parameters determined from the IV curve.
Solar cell I-V curve
Solar cell I-V curve
Solar Cell Parameters
The current from the solar cell is the difference between IL and the forward bias
current. Under open circuit conditions, the forward bias of the junction increases to a
point where the light-generated current is exactly balanced by the forward bias
diffusion current, and the net current is zero. The voltage required to cause these two
currents to balance is called the "open-circuit voltage".
Short-Circuit Current
The short-circuit current is the current through the solar cell when the voltage across
the solar cell is zero (i.e., when the solar cell is short circuited). Usually written as ISC,
the short-circuit current is shown on the IV curve below.
Isc = -IL
The short-circuit current is due to the generation and collection of light-generated
carriers. For an ideal solar cell at most moderate resistive loss mechanisms, the
short-circuit current and the light-generated current are identical. Therefore, the
short-circuit current is the largest current which may be drawn from the solar cell.
The short-circuit current depends on a number of factors which are described
below:
➢the area of the solar cell. To remove the dependence of the solar cell area, it is
more common to list the short-circuit current density (Jsc in mA/cm2) rather than
the short-circuit current;
➢the number of photons (i.e., the power of the incident light source). Isc from a
solar cell is directly dependant on the light intensity;
➢the spectrum of the incident light. For most solar cell measurement, the
spectrum is standardised to the AM1.5 spectrum;
➢the optical properties (absorption and reflection) of the solar cell (discussed
in Optical Losses); and
➢the collection probability of the solar cell, which depends chiefly on the
surface passivation and the minority carrier lifetime in the base.
When comparing solar cells of the same material type, the most critical material
parameter is the diffusion length and surface passivation. In a cell with perfectly
passivated surface and uniform generation, the equation for the short-circuit current
can be approximated as:
where G is the generation rate, and Ln and Lp are the electron and hole diffusion
lengths respectively. Although this equation makes several assumptions which are
not true for the conditions encountered in most solar cells, the above equation
nevertheless indicates that the short-circuit current depends strongly on the
generation rate and the diffusion length.
Illuminated Current and Short Circuit Current (IL or Isc ?)
IL is the light generated current inside the solar cell and is the correct term to use in
the solar cell equation.
At short circuit conditions the externally measured current is Isc. Since Isc is usually
equal to IL, the two are used interchangeably and for simplicity and the solar cell
equation is written with Isc in place of IL.
In the case of very high series resistance (> 10 Ωcm2) Isc is less than IL and writing the
solar cell equation with Isc is incorrect.
The open-circuit voltage, VOC, is the maximum voltage available from a solar cell,
and this occurs at zero current. The open-circuit voltage corresponds to the amount
of forward bias on the solar cell due to the bias of the solar cell junction with the
light-generated current. The open-circuit voltage is shown on the IV curve below.
An equation for Voc is found by setting the net current equal to zero in the solar
cell equation to give:
➢The above equation shows that Voc depends on the saturation current of the solar
cell and the light-generated current.
➢While Isc typically has a small variation, the key effect is the saturation current,
since this may vary by orders of magnitude.
➢Silicon solar cells on high quality single crystalline material have open-circuit
voltages of up to 730 mV under one sun and AM1.5 conditions, while commercial
devices on multicrystalline silicon typically have open-circuit voltages around 600
mV.
The VOC can also be determined from the carrier concentration
Where the short-circuit current (ISC) decreases with increasing bandgap, the open-
circuit voltage increases as the band gap increases. In an ideal device the VOC is
limited by radiative recombination and the analysis uses the principle of detailed
balance to determine the minimum possible value for J0.
The FF is defined as the ratio of the maximum power from the solar cell to the product
of Voc and Isc. Graphically, the FF is a measure of the "squareness" of the solar cell I-
V curve and is also the area of the largest rectangle which will fit in the IV curve.
As FF is a measure of the "squareness" of the IV curve, a solar cell with a higher
voltage has a larger possible FF since the "rounded" portion of the IV curve takes up
less area. The maximum theoretical FF from a solar cell can be determined by
differentiating the power from a solar cell with respect to voltage and finding where
this is equal to zero. Hence:
However, the above technique does not yield a simple or closed form equation,
and extra equations are needed to find Imp and FF.
The efficiency of a solar cell is determined as the fraction of incident power which
is converted to electricity and is defined as:
Where:
Voc is the open-circuit voltage;
Isc is the short-circuit current;
FF is the fill factor and
η is the efficiency.
The input power for efficiency calculations is 1 kW/m2 or 100 mW/cm2. Thus the
input power for a 100 × 100 mm2 cell is 10 W and for a 156 × 156 mm2 cell is
24.3 W
Efficiency as a function of band gap
To find the efficiency as a function of band gap, the above procedure is repeated
for each band gap. There is a range of bandgaps for the optimum cell efficiency
as shown in the graph below.
Collection Probability
The light-generated current is the integration over the entire device thickness of the
generation rate at a particular point in the device, multiplied by the collection
probability at that point.
The equation for the light-generated current density (JL), with an arbitrary
generation rate (G(x))and collection probability (CP(x)), is shown below, as is the
generation rate in silicon due to the AM1.5 solar spectrum:
where:
q is the electronic charge;
W is the thickness of the device;
α(λ) is the absorption coefficient;
H0 is the number of photons at each wavelength.
Quantum Efficiency
➢The "quantum efficiency" (Q.E.) is the ratio of the number of carriers collected by
the solar cell to the number of photons of a given energy incident on the solar cell.
➢The quantum efficiency for photons with energy below the band gap is zero. A
quantum efficiency curve for an ideal solar cell is shown below.
Photocurrent and Quantum Efficiency
The photocurrent generated by a solar cell under illumination at short circuit is
dependent On the incident light. To relate the photocurrent density, Jsc, to the incident
spectrum we need the cell’s quantum efficiency (QE).
QE (E) is the probability that an incident photon of energy E will deliver one electron to
the external circuit.
J sc = q bs ( E )QE ( E ) dE
Where bs(E) is the incident spectral photon flux density, i.e., the number of photon of
energy in the range E and E+dE which are incident on unit area in unit time and q is
electronic charge.
QE depends upon the absorption coefficient of the solar cell material, the efficiency of
charge separation and the efficiency of charge collection in the device but does not
depend on the incident spectrum.
Two types of QE are used:
The difference between EQE and IQE is that loss of photons due to reflection and
transmission is not considered in EQE.
However, only those photons which are absorbed (excluding reflected and transmitted)
contribute to the solar cell current. Due to this IQE is most commonly used to study cell
performance.
EQE
IQE =
1 − R ( ) − T ( )
current density collected
QE ( E ) = EQE =
q x incident photon flux density
Spectral Response
The spectral response is conceptually similar to the quantum efficiency. The quantum
efficiency gives the number of electrons output by the solar cell compared to the number
of photons incident on the device, while the spectral response is the ratio of the current
generated by the solar cell to the power incident on the solar cell. A spectral response
curve is shown below.
Spectral response is important since it is the spectral response that is measured
from a solar cell, and from this the quantum efficiency is calculated.
The quantum efficiency can be determined from the spectral response by replacing
the power of the light at a particular wavelength with the photon flux for that
wavelength. This gives:
QE . ( nm)
SR ( A / W ) =
1239.8
The photovoltaic effect
➢The collection of light-generated carriers does not by itself give rise to power
generation. In order to generate power, a voltage must be generated as well as a
current.
➢Under short circuit conditions, there is no build up of charge, as the carriers exit the
device as light-generated current.
➢However, if the light-generated carriers are prevented from leaving the solar cell,
then the collection of light-generated carriers causes an increase in the number of
electrons on the n-type side of the p-n junction and a similar increase in holes in
the p-type material.
Tandem solar cells can either be individual cells or connected in series. Series
connected cells are simpler to fabricate but the current is the same though each cell
so this contrains the band gaps that can be used. The most common arrangement for
tandem cells is to grow them monolithically so that all the cells are grown as layers on
the on substrate and tunnel junctions connect the individual cells.
As the number of bandgaps increases the efficiency of the stack also potentially
increases. In reality, the semiconductor materials do not exist to allow for arbitrary
materials with a specific bandgap and of high quality.
Solar cell I-V curve
Isc = -IL
Efficiency as a function of band gap
To find the efficiency as a function of band gap, the above procedure is repeated for
each band gap. There is a range of bandgaps for the optimum cell efficiency as shown in
the graph below.
Collection Probability
The "collection probability" describes the probability that a carrier generated by light
absorption in a certain region of the device will be collected by the p-n junction and
therefore contribute to the light-generated current, but probability depends on the
distance that a light-generated carrier must travel compared to the diffusion length.
The collection probability in conjunction with the generation rate in the solar cell
determine the light-generated current from the solar cell.
The light-generated current is the integration over the entire device thickness of the
generation rate at a particular point in the device, multiplied by the collection probability
at that point.
The equation for the light-generated current density (JL), with an arbitrary generation rate
(G(x))and collection probability (CP(x)), is shown below, as is the generation rate in silicon
due to the AM1.5 solar spectrum:
where:
q is the electronic charge;
W is the thickness of the device;
α(λ) is the absorption coefficient;
H0 is the number of photons at each wavelength.
Quantum Efficiency
➢The "quantum efficiency" (Q.E.) is the ratio of the number of carriers collected by the
solar cell to the number of photons of a given energy incident on the solar cell.
➢The quantum efficiency for photons with energy below the band gap is zero. A quantum
efficiency curve for an ideal solar cell is shown below.
Photocurrent and Quantum Efficiency
The photocurrent generated by a solar cell under illumination at short circuit is
dependent On the incident light. To relate the photocurrent density, Jsc, to the incident
spectrum we need the cell’s quantum efficiency (QE).
QE (E) is the probability that an incident photon of energy E will deliver one electron to
the external circuit.
J sc = q bs ( E )QE ( E ) dE
Where bs(E) is the incident spectral photon flux density, i.e., the number of photon of
energy in the range E and E+dE which are incident on unit area in unit time and q is
electronic charge.
QE depends upon the absorption coefficient of the solar cell material, the efficiency of
charge separation and the efficiency of charge collection in the device but does not
depend on the incident spectrum.
Two types of QE are used:
The difference between EQE and IQE is that loss of photons due to reflection and
transmission is not considered in EQE.
However, only those photons which are absorbed (excluding reflected and transmitted)
contribute to the solar cell current. Due to this IQE is most commonly used to study cell
performance.
EQE
IQE =
1 − R ( ) − T ( )
current density collected
QE ( E ) = EQE =
q x incident photon flux density
Spectral Response
The spectral response is conceptually similar to the quantum efficiency. The quantum
efficiency gives the number of electrons output by the solar cell compared to the number
of photons incident on the device, while the spectral response is the ratio of the current
generated by the solar cell to the power incident on the solar cell. A spectral response
curve is shown below.
Spectral response is important since it is the spectral response that is measured from a
solar cell, and from this the quantum efficiency is calculated.
The quantum efficiency can be determined from the spectral response by replacing the
power of the light at a particular wavelength with the photon flux for that wavelength.
This gives:
QE . ( nm)
SR ( A / W ) =
1239.8
The photovoltaic effect
➢The collection of light-generated carriers does not by itself give rise to power generation.
In order to generate power, a voltage must be generated as well as a current.
➢Voltage is generated in a solar cell by a process known as the "photovoltaic effect". The
collection of light-generated carriers by the p-n junction causes a movement of electrons to
the n-type side and holes to the p-type side of the junction.
➢Under short circuit conditions, there is no build up of charge, as the carriers exit the device
as light-generated current.
➢However, if the light-generated carriers are prevented from leaving the solar cell, then the
collection of light-generated carriers causes an increase in the number of electrons on the n-
type side of the p-n junction and a similar increase in holes in the p-type material.
➢This separation of charge creates an electric field at the junction which is in opposition to
that already existing at the junction, thereby reducing the net electric field. Since the
electric field represents a barrier to the flow of the forward bias diffusion current, the
reduction of the electric field increases the diffusion current. A new equilibrium is reached
in which a voltage exists across the p-n junction.
Tandem Cells
One method to increase the efficiency of a solar cell is to split the spectrum and use a solar
cell that is optimised to each section of the spectrum.
Tandem solar cells can either be individual cells or connected in series. Series connected cells
are simpler to fabricate but the current is the same though each cell so this contrains the
band gaps that can be used. The most common arrangement for tandem cells is to grow them
monolithically so that all the cells are grown as layers on the on substrate and tunnel
junctions connect the individual cells.
As the number of bandgaps increases the efficiency of the stack also potentially
increases. In reality, the semiconductor materials do not exist to allow for arbitrary
materials with a specific bandgap and of high quality.
1. low energy photon/High energy photon
Losses in Solar Cell: 2. Reflection loss/incomplete absorption
3. Metal coverage
4. Voltage loss
5. Fill factor loss
6. Recombination losses
Parasitic Resistances
The parasitic resistance: Sum of all resistance
due to all component through which current is
flowing as well as crustal defect and impurity
Optical Losses:
Light generated current itself proportional to light input
Recombination Losses:
By diode itself, connected to the parallel of current flow in opposite direction
Ohmic Losses:
Series Resistance (Rs): Effect on I sc
➢It is a useful parameter in solar cell analysis, particularly when examining the impact of
parasitic loss mechanisms.
The characteristic resistance of a solar
cell is the inverse of the slope of the
power line, can be given as:
➢The most common parasitic resistances are series resistance and shunt resistance.
➢In most cases and for typical values of shunt and series resistance, the key impact of
parasitic resistance is to reduce the fill factor.
➢Both the magnitude and impact of series and shunt resistance depend on the
geometry of the solar cell, at the operating point of the solar cell.
Series Resistance
➢the movement of current through the emitter and base of the solar cell;
➢the contact resistance between the metal contact and the silicon; and
The main impact of series resistance is to reduce the fill factor, although excessively high
values may also reduce the short-circuit current.
I = I sc − I o [e q (V + IRs ) / nkT − 1]
Effect of Series resistance on I-V curve
With increasing series resistance
(a) (c)
(d)
(b)
Series resistance does not affect the solar cell at open-circuit voltage since the overall
current flow through the solar cell, and therefore through the series resistance is zero.
However, near the open-circuit voltage, the I-V curve is strongly effected by the series
resistance.
A straight-forward method of estimating the series resistance from a solar cell is to find
the slope of the I-V curve at the open-circuit voltage point.
An equation for the FF as a function of series resistance can be determined by noting that
for moderate values of series resistance, the maximum power may be approximated as
the power in the absence of series resistance minus the power lost in the series
resistance. The equation for the maximum power from a solar cell then becomes:
In the above equation the fill factor which is not affected by series resistance is denoted
by FF0 and FF' is called FFS. The equation then becomes;
An empirical equation, which is slightly more accurate for the relationship between
FF0 and FFS is;
which is valid for rs < 0.4 and voc > 10, where voc is Voc /(kT/q) i.e., Open circuit voltage
normalized to the thermal voltage.
Shunt Resistance
Significant power losses caused by the
presence of a shunt resistance, RSH, are
typically due to manufacturing defects,
rather than poor solar cell design.
V
I = I sc − I o [e qV / nkT
− 1] −
Rsh
The impact of the shunt resistance on the fill factor can be calculated in a manner similar to
that used to find the impact of series resistance on fill factor. The maximum power may be
approximated as the power in the absence of shunt resistance, minus the power lost in the
shunt resistance. The equation for the maximum power from a solar cell then becomes;
RCH
= PMP (1 −
PMP )
Rsh
Assuming that the open-circuit voltage and short-circuit current are not affected by
the shunt resistance allows the impact of shunt resistance on FF to be determined
as;
In the above equation of FF, the fill factor which is not affected by shunt resistance is
denoted by FF0 and FF' is called FFSH. The equation then becomes;
An empirical equation, which is slightly more accurate for the relationship between
FF0 and FFSH is;
(c)
(a)
(b) (d)
Impact of Both Series and Shunt Resistances
In the presence of both series and shunt resistances, the IV curve of the solar cell is
given by;
and by combining the above equations, the net equation for FF becomes;
(a)
(b) (c)
(e)
(d)
Effect of Temperature
Like all other semiconductor devices, solar cells are sensitive to temperature.
Increase in temperature reduces the band gap of a semiconductor, thereby effecting most of
the semiconductor material parameters.
The decrease in the band gap of a semiconductor with increasing temperature can be
viewed as increasing the energy of the electrons in the material.
where: q is the electronic charge; D is the diffusivity of the minority carrier; L is the
diffusion length of the minority carrier; ND is the doping; and ni is the intrinsic carrier
concentration
In the above equation, many of the parameters have some temperature dependence,
but the most significant effect is due to the intrinsic carrier concentration, ni.
The intrinsic carrier concentration depends on the band gap energy (with lower band
gaps giving a higher intrinsic carrier concentration), and on the energy which the carriers
have (with higher temperatures giving higher intrinsic carrier concentrations).
The equation for the intrinsic carrier concentration is;
where: T is the temperature; h and k are constants; me and mh are the effective masses of
electrons and holes respectively; EGO is the band gap linearly extrapolated to absolute zero;
and B is a constant which is essentially independent of temperature.
Substituting these equations back into the expression for I0, and assuming that the
temperature dependencies of the other parameters can be neglected, gives;
where EG0 = qVG0. Assuming that dVoc/dT does not depend on dIsc/dT, dVoc/dT can be
found as;
The above equation shows that the temperature sensitivity of a solar cell depends on
the open circuit voltage of the solar cell, with higher voltage solar cells being less
affected by temperature. For silicon, EG0 is 1.2, and using γ as 3 gives a reduction in the
open-circuit voltage of about 2.2 mV/°C;
kT
Voc − VGO = (ln I sc − ln B − ln T )
q
dVoc k k
Now, = (ln I sc − ln B − ln T − )
dT q q
dVoc 1 kT k
= (ln I sc − ln B − ln T ) −
dT T q q
kT
VGO − Voc +
dVoc q
=−
dT T
The short-circuit current, Isc, increases slightly with temperature, since the band gap
energy, EG, decreases and more photons have enough energy to create e-h pairs.
However, this is a small effect and the temperature dependence of the short-circuit
current from a silicon solar cell is;
Q 3) A p-n junction solar cell has Voc =0.5 V and Jsc =20 mA/cm2 .A
second, of same area, has Voc =0.6 V and Jsc =16 mA/cm2. Assuming
that both cells obey the ideal diode equation, find the values of Voc
and Jsc when the two cells are connected (a) in parallel and (b) in
series.
Q 4) A solar cell has a short circuit current density of 30 mA/cm2 and open circuit
voltage of 0.6 V under one Sun illumination at room temperature. Use the ideal
diode equation to calculate the open circuit voltage which is expected under
illumination by 100 Suns, stating any assumption made. In practice an open-circuit
voltage of 0.66 V is measured. Compare this with your result and suggest reasons
for any discrepancy.
Q 5) A n-p homo-junction solar cell has emitter thickness of xn and a base thickness
of xp. If the front surface reflectivity is R and bulk absorption is α for photons of
energy E,
(a) Find an expression for the photon flux density reaching the base when the
incident flux density is b0(E).
(b) Find an expression for the flux density absorbed in the base.
(c) If each absorbed photon in base delivers exactly one electron to the contacts,
what is the photocurrent density from the cell? You may ignore the emitter
photocurrent, and assume that the space charge width is negligible.
(d) Now find an expression for the Quantum efficiency.
(e) A n-p solar cell has xn=20 μm and R=0.1 for all photon energies. At 800 nm the
absorption of the cell material is 1.0x105 m-1. A student calculates that the QE
is only 60%. What might be the reason for this.
Q 6) A semiconductor has an intrinsic carrier density ni of 2.0x1012 m-3 at 300 K. A thin slab
of this material is exposed to a light pulse of photon energy 2.1 eV and intensity 1000
W/m2 for an interval of 1 ns. If the absorption coefficient is 5x105 m-1 at 2.1 eV, calculate
the concentration of photogenerated electrons and holes immediately after the pulse. You
may neglect recombination during the light pulse. Hence find new concentration of
electrons (n) and holes (p) and the product (np) in the following cases:
(a) If the semiconductor is intrinsic (i.e., n=p in the dark)
(b) If the semiconductor is doped with a concentration of 1x1022 m-3 donor impurities,
which may be considered to be fully ionized?
(c) In which case is the rate of radiative recombination faster?