Chemistry work sheet for grade 12th

I. Give the correct answer for the following questions.

1. Identify the conjugate acid- base pairs from the following reactions.

A. HPO42- + HSO4- ↔ H2PO4- +SO42-

B. HSO3- + CH3NH2 ↔ SO32- + CH3NH3+

2. Identify the amphiprotic species among the following.

A. NH3 B. HCO3- C. H2O D. NH4+ E. HS- F. HCOO-

3. 0.1M solution of acetic acid ,chlorous acid , hydrofluoric acid and nitrous acid contain the
following equilibrium concentrations.

Acid [acid] [conjugate base] [H3O+]

CH3COOH 0.099M 0.0013M 0.0013 M

HClO2 0.072M 0.028M 0.028 M

HF 0.092M 0.0081M 0.0081 M

HNO2 0.093M 0.0069M 0.0069 M

A. arranges the solution of these acids in order of increasing acid strength.

B. Which of these acids have the strongest base?

4. A 0.1M solution of HNO2 is 7.1% ionized at equilibrium .what is

A. [H+] and PH C.[ OH-] and POH

B. Ka value of HNO2

5. The ka value of CH3COOH, HCOOH, HOCl and HOBr are 1.8x10 -5,1.7x10-4 ,3.0x10-8 and
5x10-9 respectively. A 0.06M of which of acid solution

A.is the most reactive

B. has the smallest PH value. C. Contain the lowest concentration of H+

D. the lowest POH values?

6. Equal volume of two acids with PH= 2 and PH=3 are mixed .what is the new PH?

7. An indicator, HIn has an ionization constant ,Kin=1.0x10 -5 .if the molecular form HIn of the
indicator is yellow and the In is green. What is the color of a solution containing the indicator
when its PH is A. 3 B.7 C.5
8. How long it will take to deposited calcium from 600ml of a 0.4M CaSO 4 solution using a
current of 6A?

9. What will be the concentration of Cd(NO3)2 in a solution after 3A has passed for 5hrs in 900ml
of a solution that was originally 0.3M (pt electrode used).

10. How many gram of Na and Cl 2 would be produced if a current of 25A is used for 8hrs into
molten NaCl?

11. for Zinc- silver cell, the overall reaction is Zn(s)+2Ag + → Zn+2 (aq) `+ 2Ag(S).Suppose the
concentration of Zn2+ in Zn//Zn2+ half cell is maintained at 1.0M.If the measured cell voltage is
1.2volt ,what must be the concentration of Ag+ in the Ag//Ag+ half cell?

12. Balance the following reaction by ion electron method.

A. Sn2+ + cr2O7-2 → Sn+4 + cr3+ acidic medium.

B. H2S + NO3- → S8 + NO basic medium.

13. Calculate the standard cell potential for the reaction

2Al(s) + 3Cu (aq) → 3cu(s) + 2Al3+(aq)

14. List at least 3 the difference between galvanic cell and electrolytic cell?

15. Define electroplating with examples? Which metal is at anode and cathode and what is the
electrolyte?

16. Write the advantage and disadvantage of lead storage battery and fuel cell?

17. What is the salt bridge and list its use clearly?

18. define disproportionation reaction and give two examples?

19. what is the oxidation number of Cr in ( NH4)2Cr2O7 ?

20. Calculate the PH when the following amounts of 0.1M NaOH solution have been added to
50ml of 0.1M HCl solution. A.40ml B.49.90 C. 50ml D.70ml E.100ml

Set by, Chemistry department 2016

Chemistry work sheet for grade 12th
1. List the types of polymerization reactions. 2. Define addition polymerization reaction.
3. Show the steps followed in the polymerization of styrene to polystyrene. Describe each steps?
Determine the monomers used to prepare
a. n(-OC C6H4 COO (CH2)2 O-)n b. (–NH- CH2- CO- N- CH2- CO-) n
5. Decide the type of polymerization reaction taking place between the
Monomers H2-NCH2(CH2)4CH2NH2, and COClCH2(CH2)6CH2COCl. Write the structure of the polymer.
6. Consider a polymer made from tetrachloroethylene.
a. Draw a portion of the polymer chain.
b. What is the molar mass of the polymer if it contains 3.2 × 103 tetrachloroethylene?
c. Calculate the percentage of C and Cl in the polymer?
7. Write the structure of the following polymers and also indicate the monomer units involved in the formation of
these polymers. a. Nylon 66 b. Dacron
8. Describe the major uses of nylons and polyethylene terephthalate.
Define each of the following terms: homopolymer, copolymer, monomer, polymer, natural and synthetic polymers?
9. What are some of the polymers that you encounter every day? Describe their physical properties.
10. Why do different polymers have different properties?
11. Which of the materials listed below may not be made of polymers?
leather, computer key board, automobile body, cup, rubber, meat, mirror, plastic chairs
12. Classify each of the following polymers as natural or synthetic wool, dacro, insulin, DNA, glycogen, bakelite,
cellulose, Teflon, and PVC.
13. Explain the difference between thermoplastics and thermosetting polymers, using examples.
14. What makes thermoplastic materials recyclable, whereas thermosetting ones are not?
15.List some thermoplastic polymers and describe their properties with the corresponding applications.
16. List some thermoset polymers and describe their properties and applications.
17. Why do different polymers have different properties? 18. What are plasticizers?
19. Describe the main purposes of adding plasticizers in the synthesis of polymers.
20. Why are olefins (alkenes) good monomers for addition polymerization reactions? Examine samples of LDPE
(squeeze bottles) and HDPE (milk jugs).
21. What are some of the differences in the physical properties of these substances? What is the role of a catalyst?
22. Which of the following is correct? A. A monomer is made from many polymers
B. A polymer is made from many monomers C. A monomer will always dissolve in water
D. A polymer will always react with water.
23. Most synthetic polymers are not biodegradable. This means that A. They are expensive
B. They cannot be grown in soil C. They will not decompose in soil D. They only exist for a short time
24. Polyvinyl chloride is used: A. As afoam for fire extinguishers B. To make leather-like materials C. To conduct
electricity in power stations D. As reflectors in streetlights
25. Explain the terms ‘thermosetting’ and ‘thermoplastic polymers’, with reference to molecular structure. Why are
most synthetic polymers considered to be pollutants while natural polymers are not?
26.Which of the following is a copolymer? A. Polystyrene B. Teflon C. Natural rubber D. Nylon 66
27.Which of the following are homopolymers? A. Dacron B. Bakelite C. Natural rubber D. Perspex
28. What term is used for the repeating units of a polymer?
29. What term identifies polymers composed of identical monomer unitsWhich types of polymers are non-
biodegradable? Why? 30. What is a characteristic of all condensation polymers?
31. What monomers are most commonly used in addition polymerization? A. Cycloalkanes
B. Esters C. Carboxylic acids D. Alkenes
32. What term is used to indicate a polymerization that occurs without the Growth of a chain monomer by monomer,
but instead occurs as monomers form dimers, dimers form tetramers, etc.? Which of the following statement is
incorrect about polymers? a. They are macromolecules made from smaller units. b. They can be prepared by either
condensation or addition polymerization. c. Most condensation polymers are hompolymers. d. Disposing synthetic
polymers can pollute the environment.
33. The process by which monomer units combine to form polymers, is: a. Condensation b. Thermosetting c.
Thermoplastic d. Evaporation
34. What is the molar mass of a polyethylene sample, [— CH2 —CH2—]n , when n = 4600? (Atomic mass, H = 1
and C = 12). a. 1.288 ×103 g/mol b. 1.288 × 105 g/mol c. 1.196 × 103g/mol d. 1.196 × 104 g/mol
35. Which one of the following is not formed by addition polymerization? a. Polyethylene b. Polyvinyl chloride c.
Teflon d. Dacron
36. Which one of the following polymer-monomer pairs is incorrectly matched? a. Teflon-propyleneb. PVC-
chloroethene c. Plexiglass-methyl methacrylate d. Bakelite-phenol and formaldehyde
37. Which one of the following is not a synthetic polymer? a. Nylon b. Cotton c. Teflon d. Dacron
38. Polyethylene is not used for making: a. Squeeze bottles b. Trash bags c. Electrical insulation d. Airplane
windows
39. Dacron is made by the polymerization of ___________ and ______________.
a. Terephthalic acid, ethylene b. Adipic acid, ethylene glycol
c. Terephthalic acid, ethylene glycol d. Adipic acid, hexamethylene diamine
40. Which one of the following is a thermosetting plastic? a. Polyethylene b. Polypropylene
c. Dacron d. Bakelite
41. Which of the following structures represents the monomer of CH2 CH CH CH2 n?
a. CH3CH=CHCH3 b. CH2=CH—CH=CH2 c. CH2=CH—CH2—CH3 d. None of the above
42. A disaccharide made from two glucose units that are linked by α-1,4 glycosidic bond is:
a. Cellulose b. Maltose c. Lactose d. Sucrose
43. Which one of the following disaccharide is prepared from two different monosaccharide units? a. Cellulose b.
Maltose c. Lactose d. Fructos
Part II: Short Answer Questions
1. Define each of the following terms and give an example for each:
a. Monomer b. Polymer c. Carbohydrate d. Amino acid
2. Classify each of the following polymers as natural or synthetic.
a. Polyethylene b. Polypropylene c. Cellulose d. Dacron e. Deoxyribonucleic acid
f. Polytetrafluoroethylene g. Polystyrene h. Nylons i. Cotton j. Polyvinyl chloride
3. Classify each polymer in Question 2 as an addition polymer or a condensation polymer.
4. What functional groups are involved in the addition and condensation polymerization processes?
5. Mention major uses of each of the following synthetic polymers. a. Polypropylene
b. Polyvinyl chloride c. Teflon d. Polystyrene e. Bakelitef. Nylon
6. Why are olefins (alkenes) good monomers for polymerization reactions?
7. How does the molecular-level structure of these polymers influence their physical properties?
8. Besides the extent of branching, can you think of any other structural parameters that might lead to the differences
in physical properties?
9. What kind of structural changes accompany bond-breaking and bond-forming in olefin polymerization?
10. Draw the structure of the copolymer of: a. HO–CH2CH2–OH and HOOC–CH2CH2–COOH.
11. What is the role of a catalyst?
12. Does ethylene polymerize under mild conditions in the absence of a catalyst (initiator)?
13. Teflon” is the polymer that results from the polymerization of tetrafluoroethylene.
Write a chemical formula for this reaction. What are some of the properties of Teflon?
14. A polymer’s structure influences its physical properties. Describe two structural
Variations that are possible for polypropylene but not for polyethylene.
15. Consider the polymerization of vinylidene chloride, CH 2=CCl2. What structural variations are possible in poly
(vinylidene chloride)?
16. Consider the polymerization of 1,2-dichloroethylene, H(Cl)C=C(Cl)H. What structural variations are possible in
poly(1,2-dichloroethylene).
Good luck