SAFETY DATA SHEET

Based upon Regulation (EC) No 1907/2006, as amended by Regulation (EU) No 2015/830

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product name : RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Synonyms : RE-HEALING RF3, 3% LV; RE-HEALING RF3 LV; RF3, 3% LV; RF3 LV
Registration number REACH : Not applicable (mixture)
Product type REACH : Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1 Relevant identified uses
Fire extinguishing medium: concentrate

1.2.2 Uses advised against

No uses advised against known

1.3. Details of the supplier of the safety data sheet

Supplier of the safety data sheet

Manufacturer of the product

1.4. Emergency telephone number

24h/24h:
+47 97 64 00 00 Europe, Middle East, Africa
+1 920 593 94 45 AMERICAS
+61 2 9430 63 96 ASIA-PASIFIC

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classified as dangerous according to the criteria of Regulation (EC) No 1272/2008
Class Category Hazard statements
STOT RE category 2 H373: May cause damage to the kidneys through prolonged or repeated exposure if swallowed.

2.2. Label elements

Contains: ethanediol.
Signal word Warning
H-statements
H373 May cause damage to the kidneys through prolonged or repeated exposure if swallowed.

Created by: Brandweerinformatiecentrum voor gevaarlijke stoffen vzw (BIG) Publication date: 2015-03-31
134-15828-472-en

Technische Schoolstraat 43 A, B-2440 Geel Date of revision: 2015-09-28

http://www.big.be
© BIG vzw
Reason for revision: 1
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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
P-statements
P260 Do not breathe vapours/m ist.
P314 Get m edical advice/a en on if you feel unwell.

2.3. Other hazards

No other hazards known

SECTION 3: Composition/information on ingredients

3.1. Substances
Not applicable

3.2. Mixtures

Name CAS No
Conc. (C) Classification according to CLP Note Remark
REACH Registration No EC No

57-50-1 C≥1 % (2) Constituent

200-334-9
142-31-4 C≥1 % Skin Irrit. 2; H315 (1)(8) Constituent
205-535-5 Eye Dam. 1; H318
1%<C<5% Eye Irrit. 2; H319 (1) Constituent

C≤1 % Acute Tox. 4; H302 (1)(8) Constituent

Skin Irrit. 2; H315
Eye Dam. 1; H318
Aquatic Chronic 3; H412
68139-30-0 C<2 % Eye Dam. 1; H318 (1) Constituent
268-761-3

112-34-5 C≤5 % Eye Irrit. 2; H319 (1)(2)(10) Constituent

203-961-6
107-21-1 C≤20 % Acute Tox. 4; H302 (1)(2)(6)(10) Constituent
203-473-3 STOT RE 2; H373
(1) For H-statements in full: see heading 16
(2) Substance with a Community workplace exposure limit
(6) Enumerated in Annex VI of Regulation (EC) No. 1272/2008 but the classification has been adapted after evaluation of available test data
(8) Specific concentration limits, see heading 16
(10) Subject to restrictions of Annex XVII of Regulation (EC) No. 1907/2006

SECTION 4: First aid measures

4.1. Description of first aid measures
General:
Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform
resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent
asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim
calm, avoid physical strain. Depending on the victim's condition: doctor/hospital.
After inhalation:
Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
After skin contact:
Rinse with water. Take victim to a doctor if irritation persists.
After eye contact:
Rinse with water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists.
After ingestion:
Rinse mouth with water. Do not induce vomiting. Immediately after ingestion: give lots of water to drink. Consult a doctor/medical service if you feel unwell.

4.2. Most important symptoms and effects, both acute and delayed
4.2.1 Acute symptoms
After inhalation:
EXPOSURE TO HIGH CONCENTRATIONS: Slight irritation. Central nervous system depression. Headache. Dizziness. Nausea. Feeling of weakness.
After skin contact:
Not irritating. ON CONTINUOUS EXPOSURE/CONTACT: Dry skin.
After eye contact:
Not irritating.
After ingestion:
AFTER INGESTION OF HIGH QUANTITIES: Symptoms similar to those listed under inhalation.
4.2.2 Delayed symptoms
No effects known.
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Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
4.3. Indication of any immediate medical attention and special treatment needed
If applicable and available it will be listed below.

SECTION 5: Firefighting measures

5.1. Extinguishing media
5.1.1 Suitable extinguishing media:
Adapt extinguishing media to the environment.
5.1.2 Unsuitable extinguishing media:
No unsuitable extinguishing media known.

5.2. Special hazards arising from the substance or mixture

On burning: release of toxic and corrosive gases/vapours (sulphur oxides, carbon monoxide - carbon dioxide).

5.3. Advice for firefighters

5.3.1 Instructions:
Dilute toxic gases with water spray. Take account of toxic/corrosive precipitation water.
5.3.2 Special protective equipment for fire-fighters:
Gloves. Protective clothing. Heat/fire exposure: compressed air/oxygen apparatus.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
No naked flames.
6.1.1 Protective equipment for non-emergency personnel
See heading 8.2
6.1.2 Protective equipment for emergency responders
Gloves. Protective clothing.
Suitable protective clothing
See heading 8.2

6.2. Environmental precautions

Contain released substance, pump into suitable containers. Plug the leak, cut off the supply.

6.3. Methods and material for containment and cleaning up

Take up liquid spill into inert absorbent material, e.g.: sand/earth. Scoop absorbed substance into closing containers. Clean contaminated surfaces with an excess
of water. Wash clothing and equipment after handling.

6.4. Reference to other sections

See heading 13.

SECTION 7: Handling and storage

The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.

7.1. Precautions for safe handling

Keep away from naked flames/heat. Observe strict hygiene. Keep container tightly closed.

7.2. Conditions for safe storage, including any incompatibilities

7.2.1 Safe storage requirements:
Storage temperature: No data available. Store in a cool area. Keep out of direct sunlight. Keep container in a well-ventilated place. Meet the legal
requirements.
7.2.2 Keep away from:
Heat sources, oxidizing agents.
7.2.3 Suitable packaging material:
No data available
7.2.4 Non suitable packaging material:
No data available

7.3. Specific end use(s)

If applicable and available, exposure scenarios are attached in annex. See information supplied by the manufacturer.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
8.1.1 Occupational exposure
a) Occupational exposure limit values
If limit values are applicable and available these will be listed below.

The Netherlands
Reason for revision: 1 Publication date: 2015-03-31
Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
2-(2-butoxyethoxy)ethanol Time-weighted average exposure limit 8 h (Public occupational exposure 7.4 ppm
limit value)
Time-weighted average exposure limit 8 h (Public occupational exposure 50 mg/m³
limit value)
Short time value (Public occupational exposure limit value) 15 ppm
Short time value (Public occupational exposure limit value) 100 mg/m³
Ethaan-1,2-diol (damp) Time-weighted average exposure limit 8 h (Public occupational exposure 20 ppm
limit value)
Time-weighted average exposure limit 8 h (Public occupational exposure 52 mg/m³
limit value)
Short time value (Public occupational exposure limit value) 40 ppm
Short time value (Public occupational exposure limit value) 104 mg/m³
Ethaan-1,2-diol (druppels) Time-weighted average exposure limit 8 h (Public occupational exposure 3.9 ppm
limit value)
Time-weighted average exposure limit 8 h (Public occupational exposure 10 mg/m³
limit value)

EU
2-(2-Butoxyethoxy)ethanol Time-weighted average exposure limit 8 h (Indicative occupational 10 ppm
exposure limit value)
Time-weighted average exposure limit 8 h (Indicative occupational 67.5 mg/m³
exposure limit value)
Short time value (Indicative occupational exposure limit value) 15 ppm
Short time value (Indicative occupational exposure limit value) 101.2 mg/m³
Ethylene glycol Time-weighted average exposure limit 8 h (Indicative occupational 20 ppm
exposure limit value)
Time-weighted average exposure limit 8 h (Indicative occupational 52 mg/m³
exposure limit value)
Short time value (Indicative occupational exposure limit value) 40 ppm
Short time value (Indicative occupational exposure limit value) 104 mg/m³

Belgium
2-(2-Butoxyéthoxy)éthanol Time-weighted average exposure limit 8 h 10 ppm
Time-weighted average exposure limit 8 h 67.5 mg/m³
Short time value 15 ppm
Short time value 101.2 mg/m³
Ethylèneglycol (en aérosol) Time-weighted average exposure limit 8 h 20 ppm (M)
Time-weighted average exposure limit 8 h 52 mg/m³ (M)
Short time value 40 ppm (M)
Short time value 104 mg/m³ (M)
Saccharose Time-weighted average exposure limit 8 h 10 mg/m³
La mention “M” indique que lors d’une exposition supérieure à la valeur limite, des irritations apparaissent ou un danger d’intoxication aiguë existe. Le
procédé de travail doit être conçu de telle façon que l’exposition ne dépasse jamais la valeur limite. Lors des mesurages, la période d’échantillonnage doit
être aussi courte que possible afin de pouvoir effectuer des mesurages fiables. Le résultat des mesurages est calculé en fonction de la période
d’échantillonnage.

USA (TLV-ACGIH)
Diethylene glycol monobutyl ether Time-weighted average exposure limit 8 h (TLV - Adopted Value) 10 ppm (IFV)
Ethylene glycol Momentary value (TLV - Adopted Value) 100 mg/m³ (H)
Sucrose Time-weighted average exposure limit 8 h (TLV - Adopted Value) 10 mg/m³
(IFV): Inhalable fraction and vapor
(H): Aerosol only

Germany
2-(2-Butoxyethoxy)ethanol Time-weighted average exposure limit 8 h (TRGS 900) 10 ppm
Time-weighted average exposure limit 8 h (TRGS 900) 67 mg/m³
Ethandiol Time-weighted average exposure limit 8 h (TRGS 900) 10 ppm
Time-weighted average exposure limit 8 h (TRGS 900) 26 mg/m³

France
2-(2-Butoxyéthoxy)éthanol Time-weighted average exposure limit 8 h (VRI: Valeur réglementaire 10 ppm
indicative)
Time-weighted average exposure limit 8 h (VRI: Valeur réglementaire 67.5 mg/m³
indicative)
Short time value (VRI: Valeur réglementaire indicative) 15 ppm
Short time value (VRI: Valeur réglementaire indicative) 101.2 mg/m³
Ethylèneglycol (vapeur) Time-weighted average exposure limit 8 h (VRI: Valeur réglementaire 20 ppm
indicative)
Time-weighted average exposure limit 8 h (VRI: Valeur réglementaire 52 mg/m³
indicative)
Short time value (VRI: Valeur réglementaire indicative) 40 ppm

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Ethylèneglycol (vapeur) Short time value (VRI: Valeur réglementaire indicative) 104 mg/m³
Saccharose Time-weighted average exposure limit 8 h (VL: Valeur non 10 mg/m³
réglementaire indicative)

UK
2-(2-Butoxyethoxy)ethanol Time-weighted average exposure limit 8 h (Workplace exposure limit 10 ppm
(EH40/2005))
Time-weighted average exposure limit 8 h (Workplace exposure limit 67.5 mg/m³
(EH40/2005))
Short time value (Workplace exposure limit (EH40/2005)) 15 ppm
Short time value (Workplace exposure limit (EH40/2005)) 101.2 mg/m³
Ethane-1,2-diol particulate Time-weighted average exposure limit 8 h (Workplace exposure limit 10 mg/m³
(EH40/2005))
Ethane-1,2-diol vapour Time-weighted average exposure limit 8 h (Workplace exposure limit 20 ppm
(EH40/2005))
Time-weighted average exposure limit 8 h (Workplace exposure limit 52 mg/m³
(EH40/2005))
Short time value (Workplace exposure limit (EH40/2005)) 40 ppm
Short time value (Workplace exposure limit (EH40/2005)) 104 mg/m³
Sucrose Time-weighted average exposure limit 8 h (Workplace exposure limit 10 mg/m³
(EH40/2005))
Short time value (Workplace exposure limit (EH40/2005)) 20 mg/m³
b) National biological limit values
If limit values are applicable and available these will be listed below.
8.1.2 Sampling methods
If applicable and available it will be listed below.
1,2-ethanediol NIOSH 5500
Ethylene Glycol NIOSH 5523
Ethylene Glycol OSHA 2024
8.1.3 Applicable limit values when using the substance or mixture as intended
If limit values are applicable and available these will be listed below.
8.1.4 DNEL/PNEC values
DNEL/DMEL - Workers
sodium octyl sulphate
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 285 mg/m³
Long-term systemic effects dermal 4060 mg/kg bw/day
salt of aromatic acid
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 53.6 mg/m³
Long-term systemic effects dermal 7.6 mg/kg bw/day
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 285 mg/m³
Long-term systemic effects dermal 4060 mg/kg bw/day
2-(2-butoxyethoxy)ethanol
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 67.5 mg/m³
Long-term local effects inhalation 67.5 mg/m³
Acute local effects inhalation 101.2 mg/m³
Long-term systemic effects dermal 83 mg/kg bw/day
ethanediol
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term local effects inhalation 35 mg/m³
Long-term systemic effects dermal 106 mg/kg bw/day
DNEL/DMEL - General population
sodium octyl sulphate
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 85 mg/m³
Long-term systemic effects dermal 2440 mg/kg bw/day
Long-term systemic effects oral 24 mg/kg bw/day
salt of aromatic acid
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 13.2 mg/m³
Long-term systemic effects dermal 3.8 mg/kg bw/day
Long-term systemic effects oral 3.8 mg/kg bw/day

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sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 85 mg/m³
Long-term systemic effects dermal 2440 mg/kg bw/day
Long-term systemic effects oral 24 mg/kg bw/day
2-(2-butoxyethoxy)ethanol
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term systemic effects inhalation 40.5 mg/m³
Long-term local effects inhalation 40.5 mg/m³
Acute local effects inhalation 60.7 mg/m³
Long-term systemic effects oral 50 mg/kg bw/day
Long-term systemic effects oral 5 mg/kg bw/day
ethanediol
Effect level (DNEL/DMEL) Type Value Remark
DNEL Long-term local effects inhalation 7 mg/m³
Long-term systemic effects dermal 53 mg/kg bw/day
PNEC
sodium octyl sulphate
Compartments Value Remark
Fresh water 0.1357 mg/l
Marine water 0.01357 mg/l
STP 1.35 mg/l
Fresh water sediment 1.5 mg/kg sediment dw
Marine water sediment 0.15 mg/kg sediment dw
Soil 0.22 mg/kg soil dw
salt of aromatic acid
Compartments Value Remark
Fresh water 0.23 mg/l
Aqua (intermittent releases) 2.3 mg/l
STP 100 mg/l
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Compartments Value Remark
Fresh water 0.012 mg/l
Marine water 0.0012 mg/l
Aqua (intermittent releases) 0.036 mg/l
STP 1.35 mg/l
Fresh water sediment 0.422 mg/kg sediment dw
Marine water sediment 0.0422 mg/kg sediment dw
Soil 0.083 mg/kg soil dw
2-(2-butoxyethoxy)ethanol
Compartments Value Remark
Fresh water 1.1 mg/l
Marine water 0.11 mg/l
Aqua (intermittent releases) 11 mg/l
Fresh water sediment 4.4 mg/kg sediment dw
Marine water sediment 0.44 mg/kg sediment dw
Soil 0.32 mg/kg soil dw
STP 200 mg/l
Food 56 mg/kg food
ethanediol
Compartments Value Remark
Fresh water 10 mg/l
Marine water 1 mg/l
Aqua (intermittent releases) 10 mg/l
Fresh water sediment 37 mg/kg sediment dw
Marine water sediment 3.7 mg/kg sediment dw
STP 199.5 mg/l
Soil 1.53 mg/kg soil dw
8.1.5 Control banding
If applicable and available it will be listed below.

8.2. Exposure controls

The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.
8.2.1 Appropriate engineering controls
Keep away from naked flames/heat. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with
respiratory protection.
8.2.2 Individual protection measures, such as personal protective equipment

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Observe strict hygiene. Keep container tightly closed. Do not eat, drink or smoke during work.
a) Respiratory protection:
Wear gas mask with filter type A if conc. in air > exposure limit.
b) Hand protection:
Chemical-resistant gloves.
c) Eye protection:
Safety glasses.
d) Skin protection:
Protective clothing.
8.2.3 Environmental exposure controls:
See headings 6.2, 6.3 and 13

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical form Liquid
Odour Pleasant odour
Odour threshold No data available
Colour Colourless
Particle size Not applicable (liquid)
Explosion limits Not applicable
Flammability Non combustible
Log Kow Not applicable (mixture)
Dynamic viscosity Newtonian liquid
Kinematic viscosity 10 mm²/s ; 20 °C
55.5 mm²/s ; -20 °C
Melting point No data available
Boiling point > 90 °C
Flash point Not applicable
Evaporation rate No data available
Relative vapour density No data available
Vapour pressure No data available
Solubility water ; Complete
Relative density 1.14 ; 20 °C
Decomposition temperature No data available
Auto-ignition temperature Not applicable
Explosive properties No chemical group associated with explosive properties
Oxidising properties No chemical group associated with oxidising properties
pH 7-9

9.2. Other information

Minimum ignition energy Not applicable
Solidification (freezing) point -25 °C
Absolute density 1140 kg/m³ ; 20 °C

SECTION 10: Stability and reactivity

10.1. Reactivity
No data available.

10.2. Chemical stability

No data available.

10.3. Possibility of hazardous reactions

No data available.

10.4. Conditions to avoid

Keep away from naked flames/heat.

10.5. Incompatible materials

Oxidizing agents.

10.6. Hazardous decomposition products

On burning: release of toxic and corrosive gases/vapours (sulphur oxides, carbon monoxide - carbon dioxide).

SECTION 11: Toxicological information

11.1. Information on toxicological effects
11.1.1 Test results
Acute toxicity
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RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No (test)data on the mixture available
sucrose
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 29700 mg/kg Rat Literature study
sodium octyl sulphate
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 OECD 423 > 2000 mg/kg bw Rat (female) Experimental value
Dermal LD50 OECD 402 > 2000 mg/kg bw 24 h Rat (male/female) Experimental value
Inhalation Data waiving
salt of aromatic acid
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 OECD 401 > 7000 mg/kg bw Rat (male/female) Experimental value
Dermal LD50 Equivalent to OECD > 2000 mg/kg bw Rabbit Experimental value
402
Inhalation (aerosol) LC50 > 6.41 mg/l >=232 minutes Rat (male/female) Read-across
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 OECD 420 500 mg/kg bw - Rat (male/female) Read-across
2000 mg/kg bw
Dermal LD50 OECD 402 > 2000 mg/kg bw 24 h Rat (male/female) Read-across
2-(2-butoxyethoxy)ethanol
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral LD50 Equivalent to OECD 2410 mg/kg bw Mouse (male) Experimental value
401
Dermal LD50 Equivalent to OECD 2764 mg/kg bw Rabbit (male) Experimental value
402
Inhalation IRT BASF test > 29 ppm 2h Rat Experimental value
(inhalation
risk test)
ethanediol
Route of exposure Parameter Method Value Exposure time Species Value Remark
determination
Oral category 4 Annex VI
Oral LD50 BASF-internal 7712 mg/kg bw Rat (male/female) Experimental value
standards
Dermal LD50 Developmental > 3500 mg/kg bw Mouse Experimental value
toxicity study (male/female)
Inhalation (mist) LC50 Teratogenicity study > 2.5 mg/l air 6h Rat (male/female) Experimental value
Judgement is based on the relevant ingredients
Conclusion
Not classified for acute toxicity

Corrosion/irritation

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Not irritating Equivalent to OECD 1; 2; 3; 4; 5; 7 days Rabbit Experimental value
405
Skin Not irritating Equivalent to OECD 1; 2; 3; 4; 5; 7 days Rabbit Experimental value
404
sucrose
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Not irritating Literature study
Skin Not irritating Literature study
sodium octyl sulphate
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Irritating OECD 405 Rabbit Read-across
Skin Irritating OECD 404 4h 24; 72 hours Rabbit Experimental value

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salt of aromatic acid
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Moderately OECD 405 1; 24; 48; 72; 168 Rabbit Experimental value Single treatment
irritating hours
Skin Slightly irritating OECD 404 4h 4; 24; 48; 72 hours Rabbit Experimental value
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Irritating OECD 405 24; 48; 72 hours Rabbit Experimental value Aqueous solution
Skin Irritating OECD 404 4h 24; 48; 72 hours Rabbit Experimental value Aqueous solution
1-propanaminium, N-(3-aminopropyl)-2-hydroxy-N,N-dimethyl-3-sulfo-, N-coco acyl derivs., hydroxides, inner salts
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Serious eye Literature study
damage
2-(2-butoxyethoxy)ethanol
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Highly irritating OECD 405 24; 48; 72 hours Rabbit Weight of evidence
Skin Slightly irritating OECD 404 24; 48; 72 hours Rabbit Experimental value
ethanediol
Route of exposure Result Method Exposure time Time point Species Value Remark
determination
Eye Not irritating BASF-internal 1; 24 hours Rabbit Experimental value
standards
Skin Not irritating BASF-internal 8 days Rabbit Experimental value
standards
Judgement of the mixture is based on test data on the mixture as a whole
Conclusion
Not classified as irritating to the skin
Not classified as irritating to the eyes
Not classified as irritating to the respiratory system

Respiratory or skin sensitisation

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No (test)data on the mixture available
sodium octyl sulphate
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing Equivalent to OECD Mouse (female) Experimental value
429
salt of aromatic acid
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing OECD 406 Guinea pig Experimental value
(female)
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing Equivalent to OECD 24; 48 hours Guinea pig Experimental value
406
2-(2-butoxyethoxy)ethanol
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing Equivalent to OECD 24; 48 hours Guinea pig Experimental value
406 (male/female)
ethanediol
Route of exposure Result Method Exposure time Observation time Species Value determination Remark
point
Skin Not sensitizing Guinea pig Guinea pig Experimental value
maximisation test (female)
Judgement is based on the relevant ingredients
Conclusion
Not classified as sensitizing for skin
Not classified as sensitizing for inhalation

Specific target organ toxicity

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

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No (test)data on the mixture available
sodium octyl sulphate
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral (diet) NOAEL Equivalent to 488 mg/kg No adverse 13 weeks (daily) Rat Read-across
OECD 408 bw/day systemic effects (male/female)
Oral (diet) LOAEL Equivalent to 1016 mg/kg Systemic effects 13 weeks (daily) Rat Read-across
OECD 408 bw/day (male/female)
Dermal NOAEL Equivalent to 10 % No effect 13 weeks (2 Mouse Read-across
OECD 411 times/week) (male/female)
Dermal LOAEL Equivalent to 12.5 % Skin Caustic 13 weeks (2 Mouse Read-across
OECD 411 burns/corrosion times/week) (male/female)
of the skin
salt of aromatic acid
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral (diet) NOAEL Equivalent to 763 mg/kg No effect 13 week(s) Rat Read-across
OECD 408 bw/day - 3534 (male/female)
mg/kg bw/day
Dermal NOAEL Equivalent to ≥ 440 mg/kg No effect 13 weeks (5 Mouse Read-across
OECD 411 bw days/week) (male/female)
Inhalation Data waiving
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral NOAEL Equivalent to 488 mg/kg No adverse 13 weeks (daily) Rat Read-across
OECD 408 bw/day systemic effects (male/female)
Oral LOAEL Equivalent to 1016 mg/kg Systemic effects 13 weeks (daily) Rat Read-across
OECD 408 bw/day (male/female)
Dermal NOAEL Equivalent to 10 % No effect 13 weeks (2 Mouse Read-across
OECD 411 times/week) (male/female)
Dermal LOAEL Equivalent to 12.5 % Haematological 13 weeks (2 Mouse Read-across
OECD 411 changes times/week) (male/female)
2-(2-butoxyethoxy)ethanol
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral NOAEL OECD 408 250 mg/kg Overall effects 90 days (continuous) Rat Experimental
bw/day (male/female) value
Dermal NOAEL Equivalent to < 200 mg/kg Skin irritation 13 weeks (daily, 5 Rat Experimental
OECD 411 bw/day days/week) (male/female) value
Inhalation NOAEL OECD 413 14 ppm Lungs 90 day(s) Rat Experimental
(male/female) value
ethanediol
Route of exposure Parameter Method Value Organ Effect Exposure time Species Value
determination
Oral (diet) NOAEL Equivalent to 150 mg/kg Kidney Change in urine 52 weeks (daily) Rat (male) Experimental
OECD 452 bw/day output value
Dermal NOAEL OECD 410 2220 mg/kg bw Histopathologic 4 weeks (daily, 5 Dog (male) Experimental
al changes days/week) value
Classification is based on the relevant ingredients
Conclusion
May cause damage to the kidneys through prolonged or repeated exposure if swallowed.
Not classified as sub-chronically toxic in contact with skin
Not classified as sub-chronically toxic if inhaled

Mutagenicity (in vitro)

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No (test)data on the mixture available
sodium octyl sulphate
Result Method Test substrate Effect Value determination
Negative with metabolic OECD 471 Bacteria (S.typhimurium) No effect Experimental value
activation, negative without
metabolic activation
Negative with metabolic Equivalent to OECD 473 Chinese hamster ovary (CHO) No effect Read-across
activation, negative without
metabolic activation
Negative with metabolic Equivalent to OECD 476 Mouse (lymphoma L5178Y No effect Weight of evidence
activation, negative without cells)
metabolic activation

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
salt of aromatic acid
Result Method Test substrate Effect Value determination
Negative with metabolic Equivalent to OECD 471 Bacteria (S.typhimurium) No effect Read-across
activation, negative without
metabolic activation
Negative with metabolic Equivalent to OECD 473 Chinese hamster ovary (CHO) No effect Read-across
activation, negative without
metabolic activation
Limited positive test result Equivalent to OECD 476 Mouse (lymphoma L5178Y Read-across
cells)
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Result Method Test substrate Effect Value determination
Negative OECD 471 Bacteria (S.typhimurium) No effect Experimental value
Negative Equivalent to OECD 476 Mouse (lymphoma L5178Y No effect Read-across
cells)
2-(2-butoxyethoxy)ethanol
Result Method Test substrate Effect Value determination
Negative Equivalent to OECD 471 Bacteria (S.typhimurium) Experimental value
Negative Equivalent to OECD 476 Chinese hamster ovary (CHO) Experimental value
ethanediol
Result Method Test substrate Effect Value determination
Negative OECD 471 Bacteria (S.typhimurium) No effect Experimental value
Negative OECD 476 Mouse (lymphoma L5178Y No effect Experimental value
cells)

Mutagenicity (in vivo)

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No (test)data on the mixture available
sodium octyl sulphate
Result Method Exposure time Test substrate Organ Value determination
Negative OECD 478 Mouse (male/female) Read-across
salt of aromatic acid
Result Method Exposure time Test substrate Organ Value determination
Negative OECD 474 Mouse (male/female) Bone marrow Experimental value
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Result Method Exposure time Test substrate Organ Value determination
Negative OECD 474 Mouse (male/female) Experimental value
2-(2-butoxyethoxy)ethanol
Result Method Exposure time Test substrate Organ Value determination
Negative Equivalent to OECD Mouse (male/female) Experimental value
475
ethanediol
Result Method Exposure time Test substrate Organ Value determination
Negative Chromosome Rat (male/female) Experimental value
aberration assay

Carcinogenicity

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No (test)data on the mixture available
sodium octyl sulphate
Route of Parameter Method Value Exposure time Species Value Organ Effect
exposure determination
Oral NOEL Equivalent to > 1125 mg/kg 104 weeks (daily) Rat Read-across No neoplastic
OECD 453 bw/day (male/female) effects
salt of aromatic acid
Route of Parameter Method Value Exposure time Species Value Organ Effect
exposure determination
Subcutaneou NOAEL Equivalent to ≥ 240 mg/kg 104 weeks (5 Rat Read-across No carcinogenic
s OECD 453 bw/day days/week) (male/female) effect
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Route of Parameter Method Value Exposure time Species Value Organ Effect
exposure determination
Oral NOEL Equivalent to > 1125 mg/kg 104 weeks (daily) Rat Read-across No neoplastic
OECD 453 bw/day (male/female) effects

Reason for revision: 1 Publication date: 2015-03-31

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
ethanediol
Route of Parameter Method Value Exposure time Species Value Organ Effect
exposure determination
Oral NOAEL Not further 1000 mg/kg 24 month(s) Rat Experimental
determined bw/day (male/female) value

Reproductive toxicity

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No (test)data on the mixture available
sodium octyl sulphate
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity NOEL Equivalent to 250 mg/kg 10 day(s) Rat (female) No effect Read-across
OECD 414 bw/day
Maternal toxicity NOEL Equivalent to 250 mg/kg 10 day(s) Rat (female) No effect Read-across
OECD 414 bw/day
Effects on fertility Data waiving
salt of aromatic acid
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity NOAEL > 3000 mg/kg 10 day(s) Rat No effect Read-across
bw/day
Maternal toxicity NOAEL > 3000 mg/kg 10 day(s) Rat No effect Read-across
bw/day
Effects on fertility Data waiving
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity NOEL Equivalent to 250 mg/kg 10 day(s) Rat No effect Read-across
OECD 414 bw/day
Maternal toxicity NOEL Equivalent to 250 mg/kg 10 day(s) Rat No effect Read-across
OECD 414 bw/day
2-(2-butoxyethoxy)ethanol
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity NOAEL Equivalent to 633 mg/kg 0 - 20 days Rat Experimental
OECD 414 bw/day (gestation, value
daily)
Effects on fertility NOAEL (P) NTP continuous 720 mg/kg 14 week(s) Mouse Body weight Read-across
breeding bw/day (male/female) reduction
protocol
ethanediol
Parameter Method Value Exposure time Species Effect Organ Value
determination
Developmental toxicity NOAEC Developmental 150 mg/m³ air 6 - 15 days Rat No effect Experimental
toxicity study (gestation, value
daily)
Effects on fertility NOAEL 3 generation > 1000 mg/kg Rat No effect Experimental
study bw/day (male/female) value
Judgement is based on the relevant ingredients
Conclusion CMR
Not classified for carcinogenicity
Not classified for mutagenic or genotoxic toxicity
Not classified for reprotoxic or developmental toxicity

Toxicity other effects

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No (test)data on the mixture available

Chronic effects from short and long-term exposure

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

No effects known.

SECTION 12: Ecological information

12.1. Toxicity
RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Parameter Method Value Duration Species Test design Fresh/salt Value determination
water
Acute toxicity fishes LC50 OECD 203 270 mg/l 96 h Danio rerio Fresh water Experimental value
Acute toxicity invertebrates EC50 OECD 202 700 mg/l 48 h Daphnia magna Fresh water Literature study
Toxicity algae and other aquatic IC10 OECD 201 60 mg/l 72 h Scenedesmus Fresh water Experimental value
plants subspicatus
IC50 OECD 201 240 mg/l 72 h Scenedesmus Fresh water Experimental value
subspicatus

Parameter Method Value Duration Species Value determination

Toxicity soil macro-organisms NOEC DIN ISO 11268-1 100 mg/kg soil 14 day(s) Eisenia fetida Experimental value
Toxicity terrestrial plants LOEC DIN ISO 11269-2 1000 mg/kg soil 14 day(s) Avena sativa Experimental value
NOEC DIN ISO 11269-2 100 mg/kg soil 14 day(s) Avena sativa Experimental value
LOEC DIN ISO 11269-2 1000 mg/kg soil 14 day(s) Lepidium sativum Experimental value
NOEC DIN ISO 11269-2 100 mg/kg soil 14 day(s) Lepidium sativum Experimental value
LOEC DIN ISO 11269-2 10000 mg/kg soil 14 day(s) Raphanus sativus Experimental value
NOEC DIN ISO 11269-2 1000 mg/kg soil 14 day(s) Raphanus sativus Experimental value
LOEC DIN ISO 11269-2 100 mg/kg soil 14 day(s) Avena sativa Experimental value
NOEC DIN ISO 11269-2 < 100 mg/kg soil 14 day(s) Avena sativa Experimental value
LOEC DIN ISO 11269-2 100 mg/kg soil 14 day(s) Lepidium sativum Experimental value
NOEC DIN ISO 11269-2 < 100 mg/kg soil 14 day(s) Lepidium sativum Experimental value
LOEC DIN ISO 11269-2 1000 mg/kg soil 14 day(s) Raphanus sativus Experimental value
NOEC DIN ISO 11269-2 100 mg/l 14 day(s) Raphanus sativus Experimental value
sodium octyl sulphate
Parameter Method Value Duration Species Test design Fresh/salt Value determination
water
Acute toxicity fishes LC50 OECD 203 > 100 mg/l 96 h Danio rerio Semi-static Fresh water Experimental value;
system GLP
Acute toxicity invertebrates EC50 OECD 202 > 100 mg/l 48 h Daphnia magna Semi-static Fresh water Experimental value;
system Locomotor effect
Toxicity algae and other aquatic EC50 EU Method > 511 mg/l 72 h Desmodesmus Static system Fresh water Read-across; Growth
plants C.3 subspicatus rate
EC10 EU Method 199 mg/l 72 h Desmodesmus Static system Fresh water Read-across; Growth
C.3 subspicatus rate
NOEC EU Method 103 mg/l 72 h Desmodesmus Static system Fresh water Read-across; Growth
C.3 subspicatus rate
EC10 EU Method 133 mg/l 72 h Desmodesmus Static system Fresh water Read-across;
C.3 subspicatus Biomass
EC50 EU Method 511 mg/l 72 h Desmodesmus Static system Fresh water Read-across;
C.3 subspicatus Biomass
Long-term toxicity fish NOEC Other ≥ 1.357 mg/l 42 day(s) Pimephales Flow-through Fresh water Read-across; Weight
promelas system changes
Long-term toxicity aquatic NOEC OECD 211 1.4 mg/l 21 day(s) Daphnia magna Semi-static Fresh water Read-across;
invertebrates system Reproduction
LOEC OECD 211 6.86 mg/l 21 day(s) Daphnia magna Semi-static Fresh water Read-across;
system Reproduction
Toxicity aquatic micro- EC50 Equivalent to 135 mg/l 3h Activated sludge Static system Fresh water Read-across;
organisms OECD 209 Respiration
EC50 Equivalent to 188 mg/l 30 minutes Activated sludge Static system Fresh water Read-across;
OECD 209 Respiration
salt of aromatic acid
Parameter Method Value Duration Species Test design Fresh/salt Value determination
water
Acute toxicity fishes LC50 EPA OTS > 1000 mg/l 96 h Oncorhynchus Static system Fresh water Read-across
797.1400 mykiss
Acute toxicity invertebrates EC50 EPA OTS > 1000 mg/l 48 h Daphnia magna Static system Fresh water Read-across
797.1300
Toxicity algae and other aquatic EC50 EPA OTS ≥ 230 mg/l 96 h Pseudokirchnerie Static system Fresh water Read-across
plants 797.1050 lla subcapitata
Toxicity aquatic micro- EC10 OECD 209 ≥ 1000 mg/l 3h Activated sludge Static system Fresh water Experimental value
organisms

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Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Parameter Method Value Duration Species Test design Fresh/salt Value determination
water
Acute toxicity fishes LC50 OECD 203 3.6 mg/l 96 h Oncorhynchus Semi-static Fresh water Experimental value
mykiss system
Acute toxicity invertebrates EC50 OECD 202 7.1 mg/l 48 h Daphnia magna Static system Fresh water Experimental value
Toxicity algae and other aquatic ErC50 EU Method 11 mg/l 72 h Desmodesmus Static system Fresh water Experimental value;
plants C.3 subspicatus Growth rate
Long-term toxicity fish NOEC ≥ 1.357 mg/l 42 day(s) Pimephales Flow-through Fresh water Read-across
promelas system
Long-term toxicity aquatic NOEC EPA 600/4- 0.88 mg/l 7 day(s) Ceriodaphnia Flow-through Fresh water Read-across
invertebrates 89/001 dubia system
Toxicity aquatic micro- EC50 OECD 209 135 mg/l 3h Activated sludge Static system Fresh water Read-across
organisms
2-(2-butoxyethoxy)ethanol
Parameter Method Value Duration Species Test design Fresh/salt Value determination
water
Acute toxicity fishes LC50 Equivalent to 1300 mg/l 96 h Lepomis Static system Fresh water Experimental value
OECD 203 macrochirus
Acute toxicity invertebrates EC50 Equivalent to 4950 mg/l 48 h Daphnia magna Static system Fresh water Experimental value
OECD 202
Toxicity algae and other aquatic EC50 OECD 201 > 100 mg/l 96 h Desmodesmus Static system Fresh water Experimental value
plants subspicatus
Toxicity aquatic micro- EC10 Equivalent to > 1995 mg/l 30 minutes Activated sludge Static system Fresh water Experimental value
organisms OECD 209
ethanediol
Parameter Method Value Duration Species Test design Fresh/salt Value determination
water
Acute toxicity fishes LC50 EPA 600/4- 72860 mg/l 96 h Pimephales Static system Fresh water Experimental value
90/027 promelas
Acute toxicity invertebrates EC50 OECD 202 > 100 mg/l 48 h Daphnia magna Static system Fresh water Experimental value
Toxicity algae and other aquatic EC50 EPA 600/9- 6500 mg/l - 96 h Pseudokirchnerie Experimental value;
plants 78-018 13000 mg/l lla subcapitata Growth rate
Long-term toxicity fish NOEC EPA 600/4- 15380 mg/l 7 day(s) Pimephales Experimental value
90/027 promelas
Long-term toxicity aquatic NOEC EPA 600/4- 8590 mg/l 7 day(s) Ceriodaphnia sp. Fresh water Experimental value
invertebrates 90/027
Toxicity aquatic micro- EC20 ISO 8192 > 1995 mg/l 30 minutes Activated sludge Static system Fresh water Read-across
organisms

Judgement of the mixture is based on test data on the mixture as a whole

Conclusion
Slightly harmful to fishes
Slightly harmful to invertebrates (Daphnia)
Slightly harmful to algae
Harmless to activated sludge at sufficient dilution
Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008

12.2. Persistence and degradability

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Biodegradation water
Method Value Duration Value determination
OECD 301F: Manometric Respirometry Test 80.7 % 28 day(s) Experimental value
OECD 301F: Manometric Respirometry Test 42.1 % 5 day(s) Experimental value
sodium octyl sulphate
Biodegradation water
Method Value Duration Value determination
OECD 301B: CO2 Evolution Test 93 % 29 day(s) Experimental value
Phototransformation air (DT50 air)
Method Value Conc. OH-radicals Value determination
AOPWIN v1.91 42 h QSAR
salt of aromatic acid
Biodegradation water
Method Value Duration Value determination
OECD 301B: CO2 Evolution Test 93 % 28 day(s) Experimental value

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Biodegradation water
Method Value Duration Value determination
EU Method C.4 95 % 28 day(s) Experimental value
Phototransformation air (DT50 air)
Method Value Conc. OH-radicals Value determination
AOPWIN v1.91 26 h 0.5E6 /cm³ QSAR
22 h 0.5E6 /cm³ QSAR
2-(2-butoxyethoxy)ethanol
Biodegradation water
Method Value Duration Value determination
OECD 301C: Modified MITI Test (I) > 80 % 28 day(s) Experimental value
Phototransformation air (DT50 air)
Method Value Conc. OH-radicals Value determination
AOPWIN 3.4 h 1.5E6 /cm³ Experimental value
ethanediol
Biodegradation water
Method Value Duration Value determination
OECD 301A: DOC Die-Away Test 90 % - 100 % 10 day(s) Experimental value
Phototransformation air (DT50 air)
Method Value Conc. OH-radicals Value determination
SRC AOP v1.92 46.3 day(s) 500000 /cm³ Calculated value

Conclusion
Contains readily biodegradable component(s)

12.3. Bioaccumulative potential

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Log Kow
Method Remark Value Temperature Value determination
Not applicable (mixture)
sucrose
Log Kow
Method Remark Value Temperature Value determination
-3.70 Experimental value
sodium octyl sulphate
Log Kow
Method Remark Value Temperature Value determination
OECD 107 Calculated < -2.31 20 °C
salt of aromatic acid
Log Kow
Method Remark Value Temperature Value determination
OECD 107 -1.1 23 °C Experimental value
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
Log Kow
Method Remark Value Temperature Value determination
OECD 107 ≤ -0.866 20 °C Calculated
1-propanaminium, N-(3-aminopropyl)-2-hydroxy-N,N-dimethyl-3-sulfo-, N-coco acyl derivs., hydroxides, inner salts
BCF other aquatic organisms
Parameter Method Value Duration Species Value determination
BCF < 71
Log Kow
Method Remark Value Temperature Value determination
≤ 1.65
2-(2-butoxyethoxy)ethanol
Log Kow
Method Remark Value Temperature Value determination
Equivalent to OECD 107 1 20 °C Test data
ethanediol
Log Kow
Method Remark Value Temperature Value determination
-1.36
Conclusion
Does not contain bioaccumulative component(s)

12.4. Mobility in soil

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
sucrose
Volatility (Henry's Law constant H)
Value Method Temperature Remark Value determination
4.47E-11 atm m³/mol 25 °C Estimated value
sodium octyl sulphate
(log) Koc
Parameter Method Value Value determination
log Koc Other 1.88 - 2 Experimental value
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, compds. with triethanolamine
(log) Koc
Parameter Method Value Value determination
log Koc Other 2.5 - 3.2 Read-across
2-(2-butoxyethoxy)ethanol
Percent distribution
Method Fraction air Fraction biota Fraction Fraction soil Fraction water Value determination
sediment
Mackay level I 0.01 % 0% 0.01 % 0.32 % 99.66 % QSAR
ethanediol
(log) Koc
Parameter Method Value Value determination
log Koc SRC PCKOCWIN v1.66 0 Calculated value
Volatility (Henry's Law constant H)
Value Method Temperature Remark Value determination
0.1327 Pa.m³/mol SRC HENRYWIN v3.10 25 °C Calculated value
Percent distribution
Method Fraction air Fraction biota Fraction Fraction soil Fraction water Value determination
sediment
Other 0.03 % 0% 0% 100 % Calculated value

Conclusion
Contains component(s) with potential for mobility in the soil

12.5. Results of PBT and vPvB assessment

Due to insufficient data no statement can be made whether the component(s) fulfil(s) the criteria of PBT and vPvB according to Annex XIII of Regulation
(EC) No 1907/2006.

12.6. Other adverse effects

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Global warming potential (GWP)
None of the known components is included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)
Ozone-depleting potential (ODP)
Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009)

sodium octyl sulphate

Global warming potential (GWP)
Not included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)

salt of aromatic acid

Global warming potential (GWP)
Not included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)

2-(2-butoxyethoxy)ethanol
Global warming potential (GWP)
Not included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)
Ground water
Ground water pollutant

ethanediol
Global warming potential (GWP)
None of the known components is included in the list of fluorinated greenhouse gases (Regulation (EC) No 517/2014)
Ground water
Ground water pollutant

SECTION 13: Disposal considerations

The information in this section is a general description. If applicable and available, exposure scenarios are attached in annex. Always use the relevant exposure
scenarios that correspond to your identified use.

13.1. Waste treatment methods

13.1.1 Provisions relating to waste

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Waste material code (Directive 2008/98/EC, Decision 2000/0532/EC).
07 06 04* (wastes from the MFSU of fats, grease, soaps, detergents, disinfectants and cosmetics: other organic solvents, washing liquids and mother liquors)
. Hazardous waste according to Regulation (EU) No 1357/2014.
13.1.2 Disposal methods
Recycle/reuse. Dilute. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste.
Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the
waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to
prevent risks of pollution or damage to people or animals. May be discharged to wastewater treatment installation or reed bed. Contains no organic
halogen which may add to the AOX value.
13.1.3 Packaging/Container
Waste material code packaging (Directive 2008/98/EC).
15 01 10* (packaging containing residues of or contaminated by dangerous substances).

SECTION 14: Transport information

Road (ADR)
14.1. UN number
Transport Not subject
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Hazard identification number
Class
Classification code
14.4. Packing group
Packing group
Labels
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions
Limited quantities

Rail (RID)
14.1. UN number
Transport Not subject
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Hazard identification number
Class
Classification code
14.4. Packing group
Packing group
Labels
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions
Limited quantities

Inland waterways (ADN)

14.1. UN number
Transport Not subject
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Class
Classification code
14.4. Packing group
Packing group
Labels
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions
Limited quantities

Sea (IMDG/IMSBC)
14.1. UN number
Transport Not subject
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Reason for revision: 1 Publication date: 2015-03-31
Date of revision: 2015-09-28

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 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Class
14.4. Packing group
Packing group
Labels
14.5. Environmental hazards
Marine pollutant -
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions
Limited quantities
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
Annex II of MARPOL 73/78

Air (ICAO-TI/IATA-DGR)
14.1. UN number
Transport Not subject
14.2. UN proper shipping name
14.3. Transport hazard class(es)
Class
14.4. Packing group
Packing group
Labels
14.5. Environmental hazards
Environmentally hazardous substance mark no
14.6. Special precautions for user
Special provisions
Passenger and cargo transport: limited quantities: maximum net quantity
per packaging

SECTION 15: Regulatory information

European legislation:
VOC content Directive 2010/75/EU
VOC content Remark
19 %
217 g/l
Indicative occupational exposure limit values (Directive 98/24/EC, 2000/39/EC and 2009/161/EU)
Product name Skin resorption
Ethylene glycol Skin
Plant protection products - listed ingredient
Contains component(s) included in implementing Regulation (EU) No 540/2011
European drinking water standards (Directive 98/83/EC)
sodium octyl sulphate
Parameter Parametric value Note Reference
Sodium 200 mg/l Listed in Annex I, Part C, of Directive 98/83/EC on the quality of
water intended for human consumption.
salt of aromatic acid
Parameter Parametric value Note Reference
Sodium 200 mg/l Listed in Annex I, Part C, of Directive 98/83/EC on the quality of
water intended for human consumption.

REACH Annex XVII - Restriction

Contains component(s) subject to restrictions of Annex XVII of Regulation (EC) No 1907/2006: restrictions on the manufacture, placing on the market
and use of certain dangerous substances, mixtures and articles.
· 2-(2-butoxyethoxy)ethanol Liquid substances or mixtures which are
· ethanediol regarded as dangerous in accordance with
Directive 1999/45/EC or are fulfilling the
criteria for any of the following hazard classes
or categories set out in Annex I to Regulation
(EC) No 1272/2008:
(a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8
types A and B, 2.9, 2.10, 2.12, 2.13 categories 1
and 2, 2.14 categories 1 and 2, 2.15 types A to
F;
(b) hazard classes 3.1 to 3.6, 3.7 adverse
effects on sexual function and fertility or on
development, 3.8 effects other than narcotic
effects, 3.9 and 3.10;
1. Shall not be used in:
— ornamental articles intended to produce light or colour effects by means of different
phases, for example in ornamental lamps and ashtrays,
— tricks and jokes,
— games for one or more participants, or any article intended to be used as such, even with
ornamental aspects,2. Articles not complying with paragraph 1 shall not be placed on the
market.3. Shall not be placed on the market if they contain a colouring agent, unless
required for fiscal reasons, or perfume, or both, if they:
— can be used as fuel in decorative oil lamps for supply to the general public, and,
— present an aspiration hazard and are labelled with R65 or H304,4. Decorative oil lamps for
supply to the general public shall not be placed on the market unless they conform to the
European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee
for Standardisation (CEN).5. Without prejudice to the implementation of other Community
provisions relating to the classification, packaging and labelling of

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

Revision number: 0101 Product number: 56128 18 / 20

 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
(c) hazard class 4.1;
(d) hazard class 5.1.
dangerous substances and mixtures, suppliers shall ensure, before the placing on the market,
that the following requirements are met:
a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly,
legibly and indelibly marked as follows: “Keep lamps filled with this liquid out of the reach of
children”; and, by 1 December 2010, “Just a sip of lamp oil — or even sucking the wick of
lamps — may lead to life- threatening lung damage”;
b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are
legibly and indelibly marked by 1 December 2010 as follows: “Just a sip of grill lighter may
lead to life threatening lung damage”;
c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general
public are packaged in black opaque containers not exceeding 1 litre by 1 December 2010.6.
No later than 1 June 2014, the Commission shall request the European Chemicals Agency to
prepare a dossier, in accordance with Article 69 of the present Regulation with a view to ban,
if appropriate, grill lighter fluids and fuel for decorative lamps, labelled R65 or H304,
intended for supply to the general public.7. Natural or legal persons placing on the market
for the first time lamp oils and grill lighter fluids, labelled with R65 or H304, shall by 1
December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill
lighter fluids labelled R65 or H304 to the competent authority in the Member State
concerned. Member States shall make those data available to the Commission.’

· 2-(2-butoxyethoxy)ethanol
2-(2-butoxyethoxy)ethanol (DEGBE)
1. Shall not be placed on the market for the first time after 27 June 2010, for supply to the
general public, as a constituent of spray paints or spray cleaners in aerosol dispensers in
concentrations equal to or greater than 3 % by weight.2. Spray paints and spray cleaners in
aerosol dispensers containing DEGBE and not conforming to paragraph 1 shall not be placed
on the market for supply to the general public after 27 December 2010.3. Without prejudice
to other Community legislation concerning the classification, packaging and labelling of
substances and mixtures, suppliers shall ensure before the placing on the market that paints
other than spray paints containing DEGBE in concentrations equal to or greater than 3 % by
weight of that are placed on the market for supply to the general public are visibly, legibly
and indelibly marked by 27 December 2010 as follows: “Do not use in paint spraying
equipment”.

National legislation The Netherlands

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
Waste identification (the LWCA (the Netherlands): KGA category 03
Netherlands)
Waterbezwaarlijkheid 11

National legislation Germany

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
WGK 1; Classification water polluting based on the components in compliance with Verwaltungsvorschrift wassergefährdender
Stoffe (VwVwS) of 27 July 2005 (Anhang 4)
sodium octyl sulphate
TA-Luft 5.2.1
2-(2-butoxyethoxy)ethanol
Schwangerschaft Gruppe C
MAK 8-Stunden-Mittelwert Butyldiglykol; 10 ppm; MAK-Wert für die Summe der Luftkonzentrationen von Butyldiglykol und Butyldiglykolacetat.
ppm
MAK 8-Stunden-Mittelwert Butyldiglykol; 67 mg/m³
mg/m³
TA-Luft 5.2.5
ethanediol
Schwangerschaft Gruppe C
MAK 8-Stunden-Mittelwert Ethylenglykol; 10 ppm
ppm
MAK 8-Stunden-Mittelwert Ethylenglykol; 26 mg/m³
mg/m³
TA-Luft 5.2.5

National legislation France

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
No data available

National legislation Belgium

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
No data available

Other relevant data

RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
No data available
sucrose
TLV - Carcinogen Sucrose; A4
ethanediol
TLV - Carcinogen Ethylene glycol; A4

15.2. Chemical safety assessment

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

Revision number: 0101 Product number: 56128 19 / 20

 RE-HEALING™ RF3, 3% LOW VISCOSITY FREEZE PROTECTED FOAM CONCENTRATE
No chemical safety assessment is required.

SECTION 16: Other information

Full text of any H-statements referred to under headings 2 and 3:
H302 Harmful if swallowed.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H319 Causes serious eye irritation.
H373 May cause damage to the kidneys through prolonged or repeated exposure if swallowed.
H412 Harmful to aquatic life with long lasting effects.
(*) = INTERNAL CLASSIFICATION BY BIG
PBT-substances = persistent, bioaccumulative and toxic substances
CLP (EU-GHS) Classification, labelling and packaging (Globally Harmonised System in Europe)

Specific concentration limits CLP

sodium octyl sulphate C ≥ 20 % Eye Damage 1;H318 ECHA
10 % ≤ C < 20 % Eye Irrit 2;H319 ECHA
sulfuric acid, mono-C12-14 (even numbered)-alkyl esters, C ≥ 20 % Eye Damage 1;H318 ECHA
compds. with triethanolamine
10 % ≤ C < 20 % Eye Irrit 2;H319 ECHA

The informa on in this safety data sheet is based on data and samples provided to BIG. The sheet was wri en to the best of our ability and
according to the state of knowledge at that me. The safety data sheet only cons tutes a guideline for the safe handling, use, consump on,
storage, transport and disposal of the substances/prepara ons/mixtures men oned under point 1. New safety data sheets are wri en from
me to me. Only the most recent versions may be used. Old versions must be destroyed. Unless indicated otherwise word for word on the
safety data sheet, the informa on does not apply to substances/prepara ons/mixtures in purer form, mixed with other substances or in
processes. The safety data sheet offers no quality specifica on for the substances/prepara ons/mixtures in ques on. Compliance with the
instruc ons in this safety data sheet does not release the user from the obliga on to take all m easures dictated by com m on sense,
regula ons and recommenda ons or which are necessary and/or useful based on the real applicable circum stances. BIG does not guarantee
the accuracy or exhaus veness of the informa on provided and cannot be held liable for any changes by third par es. This safety data sheet
is only to be used within the European Union, Switzerland, Iceland, Norway and Liechtenstein. Any use outside of this area is at your own
risk. Use of this safety data sheet is subject to the licence and liability lim i ng condi ons as stated in your BIG licence agreem ent or when
this is failing the general condi ons of BIG. All intellectual property rights to this sheet are the property of BIG and its distribu on and
reproduc on are limited. Consult the men oned agreement/condi ons for details.

Reason for revision: 1 Publication date: 2015-03-31

Date of revision: 2015-09-28

Revision number: 0101 Product number: 56128 20 / 20