CTY2325 C Lot PT 3 Main

FIITJEE – JEE (Main)
PHYSICS, CHEMISTRY & MATHEMATICS

QP Code: 134853
Time Allotted: 3 Hours Maximum Marks: 300
 Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
Important Instructions
BATCHES –2325
Caution: Question Paper CODE as given above MUST be correctly marked in the answer OMR
sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be provided
for rough work.
6. No candidate is allowed to carry any textual material, printed or written, bits of papers, clip boards, log
tables, slide rule, calculator, cellular phones, pagers and electronic devices ext. except the Admit Card
inside the examination hall / room.
B. Filling of OMR Sheet:

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on OMR
sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
4. Do not fold or make any stray marks on the Answer Sheet.
C. Marking Scheme for All Two Parts:

(i) Part-A (01-20) – Contains Twenty (20) multiple choice objective questions which have four (4) options
each and only one correct option. Each question carries +4 marks which will be awarded for every correct
answer and -1 mark will be deducted for every incorrect answer.
(ii) Part-C (01-05) contains six (05) Numerical based questions with Single Digit Integer, as answer, (Ranging
from 0 to 9 both inclusive). Each question carries +4 marks for correct answer and there will be no negative
marking.
Name of the Candidate :_______________________________________________
Batch :_______________________ Date of Examination :____________________
Enrolment Number :___________________________________________________
FIITJEE Ltd., Rama Plaza, 12-C, Kailash Vihar, City Centre, Gwalior, Ph: 0751-4925888/4926888
www.fiitjeegwalior.com
Two Year CRP (2325)-(C-LOT) PH-III-JEE MAIN2
P hy s i c s
SECTION-I
PART – A
Straight Objective Type
This part contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
1. A massless sealed tank of inner volume V and containing a liquid of density  is moving on a
frictionless horizontal surface under the action of a constant force F as shown in the figure. The
difference in pressure between the points A and B is
(A) hpg (B) F / V (C) h g  (FV) (D) (F / V)  gh
2. A monoatomic gas (   5 / 3) is suddenly compressed to (1/8)th its volume adiabatically. The pressure
of the gas will change to k times its initial value, where k is
(A) 24/5 (B) 8 (C) 40/3 (D) 32
3. Which of the following is not a wave equation?


(A) y  A sink x 2  vt 2  (B) y  A cos[2(x /   t)]
  x t 
(C) y  A sin  2     (D) y  A sinkx cos t
   T 
4. A sonometer wire is to be divided into three segments having fundamental frequencies in the ratio
1:2:3. What should be the ratio of lengths?
(A) 4:2:1 (B) 4:3:2 (C) 6:3:2 (D) 3:2:1
5. Two identical containers A and B with frictionless pistons contain the same ideal gas at the same
temperature and the same volume V . The mass of gas contained in A is m A and that in B is mB .
The gas in each cylinder is now allowed to expand isothermally to the same final volume 2 V . The
change in the pressure in A and B are found to be P and 1.5 P , respectively, then
(A) 4 m A  9 mB (B) 2mA  3mB (C) 3 mA  2 mB (D) 9mA  4mB
6. A cylindrical tube, with its base as shown in the figure, is filled with water. It is moving down with a
constant acceleration a along a fixed inclined plane with angle   45. P1 and P2 are pressures at
points 1 and 2, respectively, located at the base of the tube. Let    P1  P2  / (gd) , where  is
density of water, d is the inner diameter of the tube and g is the acceleration due to gravity. Which of
the following statement is correct ?
(A)   0 when a  g / 2 (B)   0 when a  g / 2

2 1 1
(C)   when a  g (D)   when a  g / 2
2 2
7. Two soap bubbles of radii r1 and r2 equal to 4 cm and 5 cm are touching each other over a common
surface S1S2 (shown in figure). Its radius will be
(A) 4 cm (B) 20 cm (C) 5 cm (D) 4.5 cm
8. A wooden plank of length 1m and uniform cross-section is hinged at one end to the bottom of a tank
as shown in the figure. The tank is filled with water up to a height of 0.5 m . The specific gravity of the
plank is 0.5 . The angle  made by the plank in equilibrium position is
(A) 30 (B) 45 (C) 60 (D) 90
9. Three rods of same dimensions have thermal conductivities 3K, 2K and K. They are arranged as
shown, with their ends at 100 C,50 C and 0 C . The temperature of their junction is
 
200 100
(A) 75 C (B)
C (C) 40 C (D) C
3 3
10. Which graph represents the variation of surface tension with temperature over small temperature
ranges for water?
(A) (B) (C) (D)
11. A liquid in a beaker has temperature (T) at time t and 0 is temperature of surroundings, then
according to Newton's law of cooling, the correct graph between loge    0  and t is
(A) (B)
(C) (D)
12. Two rods with the same dimensions have thermal conductivities in the ratio 1:2. They are arranged
between heat reservoirs with the same temperature difference, in two different configurations, A and
I
B . The rates of heat flow in A and B are IA and IB , respectively. The ratio A is equal to
IB
(A) 1:2 (B) 1:3 (C) 2:5 (D) 2:9
13. A gas undergoes A to B through three different processes 1, 2 and 3 as shown in the figure. The heat
supplied to the gas is Q1,Q2 and Q3 respectively, then
(A) Q1  Q2  Q3 (B) Q1  Q2  Q3 (C) Q1  Q2  Q3 (D) Q1  Q3  Q2

14. One mole of a monoatomic gas is carried along process ABCDEA as shown in the diagram. Find the
net work done by gas.
3 1
(A) J (B) 1J (C) J (D) 0 J
2 2
15. The fundamental frequency of a vibrating organ pipe is 100 Hz . Select the correct alternative.
(A) The first overtone is 200 Hz (B) The first overtone may be 400 Hz
(C) The first overtone may be 300 Hz (D) None of the above
16. A sound source emits sound waves in a uniform medium. If energy density is E and maximum speed
of the particles of the medium is v max . The plot between E and v max best represented by
(A) (B)
E
(C) vmax (D)
17. A wave motion has the function y  a0 sin( t  kx) . The graph in figure shows how the displacement y
at a fixed point varies with time t. Which one of the labelled points shows a displacement equal to that

at the position x  at time t=0 ?
2k
(A) P (B) Q (C) R (D) S

18. In the given figure, the velocity v 3 will be
(A) 2 m/s (B) 4 m/s (C) 1 m/s (D) 3 m/s
19. If cross- sectional area of limb I is A1 and that of limb II is A 2 , then velocity of the liquid in the tube
will be, (cross-sectional area of tube is very small)
A1
(A) 2g(x  y) (B) 2g(x  y)
A2
A2
(C) 2g(x  y) (D) None of the above
A1
20. If a water drop is kept between two glass plates, then its shape is
(A) (B) (C) (D) None of these
PART – C: (Integer Type)

Single digit integer type questions, the answer of which may be from 0 – 9 each question carries
+4 marks for correct answer and there will be no negative marking.
1. The pressure of an ideal gas varies according to the law P = P0 – AV2 where P0 and A are positive
6P P0
constants. The highest temperature that can be attained by the gas is, Tmax  4 0 . The value
x mR A
of x is.
2. Sound level/loudness at any point in a room is increased from 50 dB to 60 dB, when pressure
K2
amplitude changes from p0 to Kp0 . Find the value of .
5
3. A train with cross-sectional area St is moving with speed v t inside a long tunnel of cross-
sectional area S0  S0  4S t  . Assume that almost all the air (density  ) in front of the train
flows back between its sides and the walls of the tunnel. Also, the air flow with respect to the
train is steady and laminar. Take the ambient pressure and that inside the train to be p0 . If
the pressure in the region between the sides of the train and the tunnel walls is p , then
7
p0  p  v 2t . The value of N is ______
2N
4. On a TP diagram, two moles of ideal gas perform process AB and CD. If the work done by
the gas in the process AB is two times the work done in the process CD then what is the
value of T1/T2?
T
A
T1
B
T2 C
D
5. A steel rod of length 1m and cross-sectional area 104 m2 is heated from 0 C to 200 C
without being allowed to extend or bend. The compressive force produced in the rod is
_____ 104 N . (Given Young's modulus of steel  2  1011Nm2 , coefficient of linear expansion
 105 K 1 .
Chemistry
SECTION-I
PART – A
1. The correct IUPAC name of
CH 3  CH 2  C  COOH
|| is -
CH 2
(A) 2-methyl butanoic acid (B) 2-ethyl-prop-2-ene-oic acid
(C) 2- carboxy-1- butene (D) None of the above
2. The IUPAC name of compound

COOH CH COOH
COOH
(A) Propan-1,2,3-tricarboxylic acid (B) Propane trioic acid
(C) Tributanoic acid (D) Methane tricarboxylic acid
COOC2H5
3. The IUPAC name of is:
COCl
(A) 2-chlorocarbonyl ethylbenzoate (B) 2-carboxyethyl benzoyl chloride
(C) ethyl-2-(chlorocarbonyl) benzoate (D) ethyl-1-(chlorocarbonyl) benzoate
4. Given compound shows which type of isomerism
O O
S O and S O
O O
(A) Chain isomerism (B) Positional isomerism
(C) Metamerism (D) Functional group isomerism
5. Which will form geometrical isomers -

Cl
(A) (B) CH3CH = NOH (C) (D) All
Cl
6. Tautomerism is not shown by -

O
(A) O O (B) CH NOH (C) O (D) O
O
7. Which is optically inactive -

CH3
CH3
a a a a
(A) b C C C C
b (B) b C C C
b (C) (D)
N–H
CH3 CH3
8. What will be the effect on observed rotation of an optically active substance containing 0.5 gm/ml in
10 cm tube, if its concentration and length of the tube is doubled -
(A) Remain same (B) Doubled
(C) Halved (D) Becomes four times
9. For the reaction
(I) Cl  + Cl–, H1º (II) Cl  + Cl–, H2º
(III) CH2Cl CH2 + Cl–, H3º (IV) Cl  + Cl–, H4º
The correct decreasing order of enthalpies of reaction for producing carbocation is

(A) H1º > H2ºH3º >H4º (B) H4º > H1ºH2º >H3º
(C) H3º > H2ºH1º >H4º (D) H2º > H1ºH4º >H3º
10. The correct order of increasing dissociation constant of the following compound is:
OH OH OH OH
NO2 NO2 NO2
NO2
NO2 NO2 NO2
I II III IV
(A) II < IV < I < III (B) IV < III < I < II (C) IV < II < I < III (D) IV < I < II < III
COOH
11. , pKa value of the compound decreases if X is:
X
(A) –NO2 (B) – NH2 (C) – OH (D) – OCH3
(I) (II) (III)
12.
Compare carbon-carbon bond rotation across I, II, III.
(A) I > II > III (B) I > III > II (C) II > I > III (D) II > III > I
NH, N–H, N
13. (x) (y) O (z)
The correct order of decreasing basic strengths of x, y and z is:

(A) x > y > z (B) x > z > y (C) y > x > z (D) y > z > x
14. Rank the following alkenes in order of decreasing heats of hydrogenation (largest first)
(I) (II) (III) (IV)
(A) II > III > IV > I (B) II > IV > III > I (C) I > III > IV > II (D) I > IV > III > II
C  CH
15. Hydration of in presence of H2SO4 / HgSO4 gives (as a major product) -
OH
C = CH2 CH= CH COCH3 CH2CHO
(A) (B) (C) (D)
OH
BD
16. CH3CH = CH2 
3

–
product X
H 2 O 2 / OH
X is -
(A) CH3 – CH – CH2D (B) CH3 – CH – CH2OH (C) CH3– CH – CH3 (D) None is correct
OH D OD
17. OsO
4  A, A is -
NaHSO 3
(A) meso diol (B) racemic diol (C) both correct (D) none is correct
18. During the preparation of ethane by Kolbe's electrolytic method using inert electrode the pH of the
electrolyte -
(A) Increases progressively as the reaction proceeds
(B) Decreases progressively as the reaction proceeds
(C) Remains constant throughout the reaction
(D) May decrease as the concentration of the electrolyte is not very high
AlCl
19. + CH2CH2CH2Cl  3  hydrocarbon (X) major product X is -
CH3
CH3
(A) CH2CH–CH3 (B) C–CH3
CH3 CH3
(C) CH2CH2CH2CH3 (D) None is correct
CH2–CH2–CH–CH2–OH
|
20. CH3
dil. H SO
 2  4
 ?
what will be the major product in this reaction?
CH2–CH2–C=CH2 CH3
|
(A) CH3 (B)
CH3
(C) (D)
CH3
CH3 CH3
PART – C: (Integer Type)
1. The heat of hydrogenation of benzene is 51 kcal/mol and its resonance energy is 36 kcal/mol. If the heat of
hydrogenation of cyclohexene is x Kcal/mol, find x/10 (Round off to the nearest integer).
2. An organic molecule has x C=C bonds (heat of hydrogenation for C=C bond is 28.8 kJ mol–1).
Experimental value for heat of hydrogenation and resonance energy are 99 kJ mol–1 and 45 kJ mol-1
respectively. Find x.
3. Find the difference between sigma-bonds and pi-bonds in a benzene molecule?
4. Number of  electrons present in naphthalene is (4n + 2) where n is...
5. Number of isomers of C7H7Cl is –
Mathematics
SECTION-I
PART – A
x2 y2
1. Let P be a parabola with vertex (2, 3) and directrix 2x + y = 6. Let an ellipse E : 2
  1, a  b , of
a b2
1
eccentricity pass through the focus of the parabola P. Then, the square of the length of the latus
2
rectum of E, is
512 385 656 347
(A) (B) (C) (D)
25 8 25 8
x2 y2
2. P is a variable point on the ellipse 
 1 whose eccentricity is e and foci are the points S1 and
a 2 b2
S2 . The locus of the incentre of PS1S2 is a conic whose eccentricity is
1 e 2e 1 e
1 e 1 e 1 e
3. Tangents are drawn to x 2  2y 2  2 . The locus of mid-point of intercept made by tangents between
the axes is
1 1 1 1 1 1 1 1
(A) 2  2  1 (B) 2
 2 1 (C) 2
 2 1 (D) 2
 2 1
x 2y 4x 2y 2x 4y 2x y
4. The line passing through the extremity A of the major axis and extremity B of the minor axis of the
ellipse x 2  9y 2  9 meets its auxiliary circle at the point M . Then the area of the triangle with
vertices at A, M and the origin O is.
31 29 21 27
(A) sq. unit (B) sq. unit (C) sq. unit (D) sq. unit
10 10 10 10
5. An ellipse has OB as semi minor axis, F and F are its foci and the angle FBF is a right angle. The
eccentricity of the ellipse is
1 1 1
2 4 2
6. A hyperbola, having the transverse axis of length 2 sin  , is confocal with the ellipse 3x 2  4y 2  12 .
Then its equation is
(A) x 2 cosec 2   y2 sec 2   1 (B) x 2 sec 2   y 2 cosec 2   1
(C) x 2 sin2   y 2 cos2   1 (D) x 2 cos2   y 2 sin2   1
7. Which one of the following is independent of  in the hyperbola (0     / 2)

2 2 2 2
x sec   y cosec   1
(A) Eccentricity (B) Abscissa of foci (C) Directrix (D) Vertex
x2
8. Consider a branch of the hyperbola  y 2  1  0 with vertex at the point A . Let B be one of the
3
end points of its latus rectum nearest to the point A. If C is the focus of the hyperbola nearest to the
point A , then the area of the triangle ABC is
1  2  1  2 
(A)   1 sq. unit (B)   1 sq. unit
3 3  3  3 
 2
(C)  1   sq. unit (D) none of these
 3 

x2 y2
9. Let two perpendicular chords of the ellipse   1,a  b each passing through exactly one of the
a2 b2
x2 y2
foci meet at a point P . If from P two tangents PQ and PR are drawn to the hyperbola 2
  1,
a b2
then QPR 
   b
(A) (B) (C) (D) 2 tan1
4 3 2 a
z(1 z)
10. Suppose z = x + i y such that z  1 , |z|=1 and arg(z)=  .Let  then Re(  ) is
z(1 z)
2cos2 
  
(A) 1  cos (B) 1 sin (C) 2sin2 (D)
2 2 2 2
2z  n
11. Let z  C with Im(z)  10 and it satisfies  2i  1 for some natural number n , then
2z  n
(A) n  40 and Re(z)  10 (B) n  20 and Re(z)  10
(C) n  20 and Re(z)  10 (D) n  40 and Re(z)  10
12. If z1  3  5i; z2  5  3i and z is a complex number lying on the line segment joining z1 and z2
then arg z can be:
3 5  
(A)  (B) (C)  (D) 
4 6 4 6
13. Three boys and three girls are to be seated around a table in a circle. Among them the boy X does
not want any girl neighbour and the girl Y does not want any boy neighbour. The number of such
arrangements possible is:
(A) 8 (B) 9 (C) 6 (D) 4
2
 x 2 x3 xn 
14. The coefficient of xn in  1  x    ....   is
 2! 3! n! 
n
n
1 1 2n
(A) (B) (C) (D)
n! n! n!2 n!
5
15. The value of the expression 47
C4   52 jC3 is
j 1
47 52 52
(A) None of these (B) C5 (C) C4 (D) C5
16. If 20
C1  22  20
 
C2  3 2
20
C3    202   20
 
C20  A 2 , then the ordered pair (A,  ) is equal to
(A) (420,18) (B) (380,18) (C) (380,19) (D) (420,19)
17. Number of triangles that can be made using vertices of a polygon of 10 sides as their vertices and
having exactly one side common with the polygon is:
(A) 35 (B) 60 (C) 32 (D) 64
25
18. If   50 Cr 50r C25r   K  50 C25  , then K is equal to:
r 0
(A) (25)2 (B) 225 (C) 225  1 (D) 224
19. For r  0,1,,10 , if A r ,Br and Cr denote respectively, the coefficient of xr in the expansions of
10
(1  x)10 ,(1  x)20 and (1  x)30 . Then,  Ar B10Br  C10 Ar  is equal to
r 1
(A) C10  B10 (B) B10  C10 (C) 0 2

(D) A10 B10 
 C10 A10 

      
6 6
20. The coefficient of x 2 in the expansion of the product 2  x 2   1  2x  3x 2  1  4x 2  is:
 
(A) 107 (B) 106 (C) 108 (D) 155
PART – B
x2 y2
1. The line y  2x  1 is tangent to the hyperbola 
 1 . If this line passes through the point of
a2 b2
intersection of the nearest directrix and x -axis, then the eccentricity of the hyperbola is
2. Number of ordered pair(s) (z, ) of the complex numbers z and  satisfying the system of equations,
z3  7  0 and z5  11  1 is:
r 20
3. The value of for which Cr 20 C0  20 Cr 120 C1  20 Cr  220 C2    20 C020 Cr is maximum, is
4
3  5i
4. Evaluate: 2x3  2x 2  7x  72 , when x  .
2
5. Let m be the smallest positive integer such that the coefficient of x 2 in the expansion of
(1  x)2  (1  x)3    (1  x)49  (1  mx)50 is (3n  1)51C3 for some positive integer n . Then, the value
of n is
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FIITJEE – JEE (Main)

PHYSICS, CHEMISTRY & MATHEMATICS

B. Filling of OMR Sheet:

C. Marking Scheme for All Two Parts:

Name of the Candidate :_______________________________________________

Batch :_______________________ Date of Examination :____________________

Enrolment Number :___________________________________________________

(A) hpg (B) F / V (C) h g  (FV) (D) (F / V)  gh

3. Which of the following is not a wave equation?

(A)   0 when a  g / 2 (B)   0 when a  g / 2

(A) 4 cm (B) 20 cm (C) 5 cm (D) 4.5 cm

(A) 30 (B) 45 (C) 60 (D) 90

(A) (B) (C) (D)

(A) 1:2 (B) 1:3 (C) 2:5 (D) 2:9

(A) Q1  Q2  Q3 (B) Q1  Q2  Q3 (C) Q1  Q2  Q3 (D) Q1  Q3  Q2

(C) vmax (D)

(A) P (B) Q (C) R (D) S

(A) 2 m/s (B) 4 m/s (C) 1 m/s (D) 3 m/s

(A) (B) (C) (D) None of these

PART – C: (Integer Type)

2. The IUPAC name of compound

4. Given compound shows which type of isomerism

5. Which will form geometrical isomers -

6. Tautomerism is not shown by -

7. Which is optically inactive -

9. For the reaction

(I) Cl  + Cl–, H1º (II) Cl  + Cl–, H2º

(III) CH2Cl CH2 + Cl–, H3º (IV) Cl  + Cl–, H4º

The correct decreasing order of enthalpies of reaction for producing carbocation is

11. , pKa value of the compound decreases if X is:

(I) (II) (III)

13. (x) (y) O (z)

The correct order of decreasing basic strengths of x, y and z is:

(I) (II) (III) (IV)

(C) CH2CH2CH2CH3 (D) None is correct

7. Which one of the following is independent of  in the hyperbola (0     / 2)

(A) (25)2 (B) 225 (C) 225  1 (D) 224

(A) C10  B10 (B) B10  C10 (C) 0 2

Space For Rough Work

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