MEDICOS-30

p-Block (XI) DPP-01

1. In BF3 :
(1) B-F bond has double bond character and this bond is delocalised.
(2) All the B–F bonds are single covalent in nature.
(3) Bond energy and bond length of B–F bond indicate its single bond character.
(4) All the bonds are ionic.

2. Which of the following structures correctly represents the boron trifluoride molecule :

(1)

(2)

(3)

(4)

3. Ga+ acts as a reducing agent because :

(1) Ga3 state is less stable than Ga1
(2) Ga3 state is more stable than Ga1
(3) Ga3 convert into Ga1 by reduction
(4) None of the above

4. In inert pair effect which pair of electrons are said to be inert :

(1) 2 electrons of (n–1)s
(2) 2 electrons of (n–1)d
(3) 2 electrons of np
(4) 2 electrons of ns

[1]
 MEDICOS-30

5. Total number of compounds showing back bonding in the following :

(a) BF3 (b) NH3 .BF3 (c) BF4– (d) NH2BH2
(e) OF2 (f) NF3 (g) (SiH3 )2 O (h) (CH3 )2 O
(1) 3
(2) 5
(3) 2
(4) 1

Answer Key

Question 1 2 3 4 5
Answer 1 1 2 4 1

[2]
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p-Block (XI) DPP-02

1. Which of the following halides does not hydrolysed ?

(1) NCl3
(2) SiCl4
(3) CCl4
(4) PCl3

2. The product formed in the reaction

 Product is :–
BCl3 + H2 O 
(1) H3BO3  HCl
(2) B2O3  HOCl
(3) B2H6  HCl
(4) No reaction

3. The molecule with complete octet is ?

(1) BeCl2 (dimer)
(2) BeH2 (dimer)
(3) BeH2 (s)
(4) BeCl2 (s)

4. In which of the following molecule, vacant orbitals do not participate in bonding :-

(1) B2H6
(2) Al2Cl6
(3) [H3N . BF3 ]
(4) Si2H6

5. The correct order for extent of hydrolysis is :

(1) NaCl  MgCl2  AlCl3  SiCl4  PCl5
(2) CCl4  SiCl4  GeCl4  SnCl4  PbCl4
(3) LiCl  BeCl2  BCl3
(4) All of these

Answer Key

Question 1 2 3 4 5
Answer 3 1 4 4 4