KENDRIYA VIDYALAYA SANGATHAN, BHUBANESWAR REGION SESSION ENDING EXAMINATION 2022 - 23 7 SS: XI MAX. MARKS SOE T :- CHEMISTRY TIME ALLOTED : 3 H! ;eneral Instructions: _ i | There are 35 questions in this question paper with internal choice. SECTION A consists of 18 multiple-choice questions carrying 1 mark each | SECTION B consists of 7 very short answer questions carrying 2 marks each. ) SECTION C consists of 5 short answer questions carrying 3 marks each ) SECTION D consists of 2 case- based questions carrying 4 marks each. SECTION E consists of 3 long answer questions carrying 5 marks each. ) All questions are compulsory. ) Use of log tables and calculators is not allowed 70 SECTION-A . fhe following questions are multiple-choice questions with one correct answer. Each question urries I mark. There is no internal choice in this section.] The number of orbitals in a given sub-shell is determined by the number of possible values of: (a) n () 1 © m (a) m, Which one of the following statements is incorrect in relation to ionization enthalpy? ) Jonization enthalpy increases for removal of each successive electron. )) The highest value of ionization enthalpy is experienced on removal of electron from core noble gas configuration. ) End of removal of valence electrons is marked by a big jump in ionization enthalpy. !) Removal of electron from orbitals bearing lower “ n” value is easier than from orbital having higher “n” value Arrange the following types of interactions in the order of increasing stability: covalent bond, vander waals force, dipole attraction , hydrogen bonding ) vander waals force > dipole attraction > hydrogen bonding > covalent bond ») vander waals force < dipole attraction < hydrogen bonding < covalent bond covalent bond > dipole attraction > hydrogen bonding > vander waals force }) dipole attraction > hydrogen bonding > vander waals force > covalent bond Ina molecule there are 12 electrons in bonding orbitals. If its bond order is 2, number of electrons inthe antibonding molecular orbitals are: (a) 10 (b)8 (c) 6 (d)4 “Heat of combustion of carbon ( graphite ) is the same as: ) heat of formation of carbon dioxide (b) heat of combustion of carbon ( diamond ) ‘)heat of atomisation of graphite (d) None of these "Change in internal energy of a process can be measured with help of : () calorimeter (b) bomb calorimeter (c) scanning calorimeter (d) Adiabatic Calorimeter jon, then equilibrium constant will in unchanged — (d) de 0; n creasing the concentration of reactants in a reversible re a) deper ; A ° ) depend on the concentration —(b) increase (o) re MON PAPER_CHEMISTRY 2022-23 Page 1 of 58.An aqueous solution of CHsCOONa will be (a) Acidic (b) Alkaline (c) Neutral (d) None of these 9.When iron is added to CuSO,, solution, copper is precipitated. It is due to (a) Oxidation of Cu? (b) Reduction of Cu’? (c) Hydrolysis of CuSO, (d) lonization of CuSO+ 10.The oxidation state of chromium in potassium dichromate is: (a) +5 (b) +6 (c) +7 (d) +8 11. The IUPAC name of CH2 = CH - CH: - CHO is (a) 1-formyl-2-propene (b) 3-formyl-I-propene (c) but-3-en-I-al_(d) but-I-en-3-al 12.Essential conditions for exhibiting metamerism are (a) same functional group (b) same homologous series (©) functional group should be at least divalent —_(d) all of the above 13.The shape of carbanion: (a) Linear (b)Trigonal planar _—_(c) trigonal pyramidal _(d) none of the above 14, The number of possible hyper conjugative structure in cis-but-2-ene is : @3 4 ©5 @6 Assertion (A) and Reason (R) type questions Given below are two statements labelled as Assertion (A) and Reason (R) Select the most appropriate answer from the options given below: a. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A c. Ais true but R is false. d. A is false but R is true 15.Assertion : All isotopes of a given element show the same type of chemical behaviour. Reason : The chemical properties of an atom are controlled by the number of electrons in the atom 16.Assertion : Some salts are sparingly soluble in water at room temperature. Reason : The entropy increases on dissolving the salts. : Tertiary carbocations are generally formed more easily than primary carbocations lyperconjugation as well as inductive effect due to additional alkyl groups stabilize tertiary carbocations 18,Assertion:Simple distillation can help in separating a mixture of propan-1-ol (boiling point 97°C) and propanone (boiling point 56°C) : Liquids with a difference of more than 20°C in their boiling points can be separated by simple distillation. SECTION -B:14 M (VERY SHORT ANSWER TYPE AND CARRY 2 MARKS EACH) [This section contains with internal choice in two questions. ] Reasoi 19.Calculate the amount of water produced by the combustion of 16 g of methane QUESTION PAPER CHEMISTRY | KVSANGATHAN BBSR REGION CLASS-XI __________—. = Page 20f5Te ponization energy of nitrogen is more than °O" and *C” both. why ? 204 nin reason- Cations are smaller in size than its parent neutral atom but anions are larger in si jnan its parent neutral atom ? 11.Calculate the number of kJ of heat necessary to raise the temperature of 60.0 g of alumi from 35"C to 55°C. Molar heat capacity of Al is 24 J mol"! K”! OR Enthalpy of combustion of carbon to CO) is - 393.5 kJ mol"', Calculate the heat released upon formation of 35.2 g of CO2 from carbon and dioxygen gas. (a) Define buffer solution (b) Give one example each of acidie and basic buffer. 3. While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in their reactions, ozone and nitric acid act only as oxidants. Why ? 4. Draw all the resonating structure of Phenol by showing electron movement through curved row. 5. What are the necessary conditions for any system to be aromatic? SECTION ~C (SHORT ANSWER TYPE AND CARRY 3 MARKS EACH) /his section contains 5 questions with internal choice in two questions. The following questions are. ae Sh Ifan electron in He" has angular momentum of <* associated with it d its energy and radius of orbit OR tate Heisenberg’s uncertainty principle. \ microscope using suitable photons is employed to locate an electron in an atom within a distance 0.1A°. what is the uncertainty involved in the measurement of 's velocity? 7. Define ionization enthalpy and electron gain enthal [ Element A\Hy = 1 1681 3374 a 1008 1846 : il 2372 5251 he data given in the table above and decide which is (a) The most reactive non-metal and (b) The least reactive element, _ give reason also 8.Describe the effect of (2) addition of Hy (b) addition of CHsOH__(c) removal of CO on the equilibrium of the reaction 2H2(g) +CO ==" CHO ntion whether the value of equilibrium constant will increase or decrease or remain same in ach case, OR ‘leulate the p'' value of the following solutions. ‘) Ammonium acetate solution when p* and p*® of acetic acid and ammonium hydroxide are 4.76 and 4.75 respectively WANG 47 ANGATHAN BBSR REGION CLA XI SEE QUE: !STION PAPER CHEMISTRY 2022-23 Page 3 of 5(b) 10° M H2SO.. (c) 10“ M NaOH 29. (a) Write the cis and trans form of but-2-ene (b) write the bond line formula of 4-chloro-2-methylpentane (c) Write functional isomer of ethanol. 30. Complete the Following reaction Baeyer's reagent aan Os Zn dust 7H20 - * KMnO4 / H a SECTION —D(CASE-BASED QUESTIONS CARRIES 4 MARKS EACH) 31 Read the following passage and answer the following questions: In 1887. German physicist Heinrich Hertz noticed that shining a beam of ultraviolet light onto a metal plate could cause it to shoot sparks. It wasn't the emission that was surprising. Metals were known to be good conductors of electricity. because the electrons are more loosely attached to the | atoms and could be dislodged by a sudden burst of incoming energy What was puzzling was that different metals required bursts of different minimum frequencies of light for the electron emission to occur. while increasing the brightness of the light produced more electrons. without increasing their energy. And increasing the frequency of the light produced electrons with higher energies. but without increasing the number produced. This became known as the photoelectric effect. and it would be understood in 1905 by a young scientist named Albert Einstein. He published a research paper on photoelectric effect in 1905 which profoundly influenced the development of physics and Finstein received Nobel prize in Physics in 1921 for | his explanation of the photoelectric effect Einstein's fascination with science began when he was 4 or 5. and first saw a magnetic compass. He was enthralled by the invisible force that caused the needle to alway’ point north, and the | instrument convinced him that there had to be "something behind things. something deeply hidden." He spent the rest of his life trying to decipher the arcane mysteries of the universe Today the name Einstein is synonymous with genius, but for years his parents thought their son was a bit "slow" because he spoke hesitantly and wasn't a stellar student | (a) Name the particles which exerts a sudden burst of energy to dislodge loosely held electrons on the surface of a metal? (b) What is the characteristic minimum frequency of light that required to burst on a particular type of metal surface to cause electron emission known as? (c) Surface of two different metals A and B were burst by a particular light which caused electron emission in both cases. If work function of metal A is higher , then electrons ejected by which metal have higher kinetic energy? (d)Why \creasing brightness of the light produces more number of elec [ eesancaTHan asa REGION CLASS-X! SE TION PAPER CHEMISTRY 2022-23 a “PagedofSce the enthalpy of hydration of any ion is the enthalpy change that occurs when one mole of "cous ions are added to water. So hydration enthalpy is a measure of atiractions between the ion Mi the surrounding water molecules. Lattice dissociation enthalpy is the enthalpy change needed to invert | mole of solid crystal into its scattered gaseous ions. Lattice dissociation enthalpy are iways positive. The enthalpy change of the solution isthe enthalpy change when | mole of an snic substance dissolves in water to give a solution of infinite dilution. The table shows the hy gihalpies of a number of ions. The values are taken from a data table on the Royal Society of syemistry Website, Please study carefully and answer the following questions | Species Hydration enthalpy (kj/mol 4 fo -338 ) Explain why the hydration enthalpy falls as you go down Group 1 from Li’ to K* . ) Explain why the value for Mg” is so much greater than that of Na* . ) Would the value for Ca®* be more negative or less negative than that of Mg”" ? Explain your easoning, SECTION -E [QUESTIONS ARE LONG ANSWER TYPE AND CARRY 5 (1+2+2)MARKS EACH] 33.(a) Which measurement is more precise 4.0g or 4.00g ? (b)16 g of an ideal gas SOx occupies 5.6 L at STP. What is its molecular mass ? What is the value of X ? (d) A compound contains 4.07% hydrogen, 24.27% carbon and 71.65% chlorine. Its molar mass is 98.96 g. What are its empirical and molecular formulas? 34. (a) Draw the Lewis dot structure of ozone molecule (b) Between NH3 and NF3 which having higher dipole moment and why? (c) Write the molecular orbital electronic configuration for oxygen molecule, also calculate bond order. OR (a) Why is sigma bond stronger than z-bond? (b) Why water is liquid and hydrogen sulphide is gas at room temperature. (c) Explain why Be2 molecule does not exist by using Molecular Orbital theory 35, (a) Suggest the name of a Lewis acid other than anhydrous aluminium chloride which can be used during ethylation of benzene. (b) An alkene *A* on ozonolysis gives a mixture of ethanal and pentan-3- one. Write structure and IUPAC name of “A? (c) Arrange benzene, n-hexane and ethyne in decreasing order of acidic behaviour. Also give reason for this behaviour. OR (@) What effect does branching of an alkane chain has on its boiling point” () Write structures of any two alkenes which on hydrogenation give 2-methylbutane. () Why is Wurtz reaction not preferred for the preparation of alkanes containing odd number of carbon atoms? Illustrate your answer by taking one example: ‘Wenean THAN BBSR REGION CLASS-XI SEE QUESTION PAPER CHEMISTRY ae 23 : a] Page 5 o}