Professional Documents
Culture Documents
ASTM MEETING
June 2008
2
Ship Integrity & Performance (SEA 05P)
Group Director
Ship Integrity & Performance
Michael R. Kistler
WFC Developmental
Pre-decisional Key: “Pilot” Vacancy
3 Intern
ANTIFOULING COATING PROGRAM
Specifications & Requirements
Limits soluble and total metals Minimizes waste disposal & worker health issues.
Limits soluble and total metals Minimizes waste disposal & worker health issues.
Limits biocides and biocide toxicity Requires EPA registration & worker health issues.
Volatile Organic Compound / Hazardous Air Complies with 40 CFR 63 Shipbuilding & Ship Repair rules.
Pollutant limits
8
ANTIFOULING COATING PROGRAM
Need to Enhance Fuel Economy
• SEA 05 questioned from CNO & via congressional inquiry about technology
available to reduce ship fuel consumption.
4.00
CDP
Hybrid
3.00
SPC
Foul release
2.00
New, Low-speed,
foul-release
1.00
coating to be
demonstrated in
0.00 2009 by NAVSEA
Start AHR Year 1 Year 2 Year 3 Year 4 Year 5
International Paint Data, C. Anderson 9
ANTIFOULING COATING PROGRAM
Environmental Drivers Of Change
• World-wide antifouling coating environmental regulations are changing:
•• International Maritime Organization (IMO) tributyl tin (TBT) ban to come into
force on 17 Sept. 2008 – TBT paints are banned.
•• Canada, 40 ug/cm2/day limit on copper emissions from antifouling paints.
•• Sweden has copper emissions limits on antifouling coatings
in Baltic, 200 ug/cm2/14-day.
•• Netherlands bans cleaning or scrubbing of copper-bearing antifouling.
INTERNATIONAL PRECEDENTS ESTABLISHED FOR BIOCIDE & Cu REGULATION
11
Source: EPA UNDS OUTREACH BRIEF (Fall 2003).
ANTIFOULING COATING PROGRAM
Domestic Copper Discharge limits evolving
• UNDS Process is ongoing.
Identify and Joint EPA/DoD Final Report
Phase I Characterize Rule Published
Discharges
Develop
Phase III Implementing DoD Rule Negotiation
Instructions
12
ANTIFOULING COATING PROGRAM
Program Approach
ENVIRONMENTAL &
OPTION 3: FOUL-RELEASE
PERFORMANCE GOALS NON-TOXIC COATINGS
• COMMERCIAL COATINGS.
• NAVSEA SPECIFICATION
REVISION IN PROGRESS.
• TEST INSTALLATIONS
ON MCM-1 & MCM-14.
OPTION 1: NON-COPPER
• DEVELOPMENTAL
COATINGS. MIL-PRF-24647D INCLUDES
• NOT EPA REGISTERED. OPTION 2: LOW-COPPER CATEGORY.
• SHORT HALF-LIFE CO-BIOCIDE COATING
(e.g., 10-hour) BIOCIDES. • COMMERCIAL PRODUCTS International Intersleek 425 included
• SOME CO-BIOCIDES, on MIL-PRF-24647D Qualified Products List
NOT EPA REGISTERED.
• SHORT HALF-LIFE International Intersleek 900 started
MIL-PRF-24647D category
(e.g., 10-hour) BIOCIDES. ship trials.
Two products failed ship test,
Sherwin Williams HMF registered with
EPA 30 June 2008. State registration BEST OPTION 2 PRODUCTS
in place for VA, FL, SC.
Two other copper-free being Don’t currently meet Navy needs.
registered.
No product of interest under testing
13
ANTIFOULING COATING PROGRAM
SHIPBOARD TESTING TO DATE
• NAVSEA patch tests on navy ships & USCG craft in fouling-prone, warm
water.
USS ALDIE
(Option 1 & 2)
April 2006
June 2005
Cu Ablative
Cu-ablative
Option 1 16
Option 1
TYPE III, FOUL-RELEASE COATING TESTING
Advanced, Foul-release for Lower-speed Ships
● New, “second generation,” silicone-based
product introduced to Navy and commercial
industry in May 2007.
●● Fluorinated polymer with silicone resin.
●● Ampiphilic surface (i.e., with mixed
hydrophobic and hydrophilic areas)
inhibit organism settlement and adhesion.
●● Surface is smoother than conventional
silicone-based foul-release.
● International Paint states Intersleek 700 is a viable coating for ships operating
in excess of 15 knots, but Intersleek 900 is viable coating for ships operating
in excess of 10 knots. DDGs operate in excess of 15 knots 47% of the time,
while FFGs operate in excess of 15 knots 27% of the time.
80
70 Intersleek 900 Intersleek 700
recommended recommended
60
50
Percent Time
40
(Annual)
30
20
10
0
<10 11 13 15 17 19 21 23 25+
Speed (knots)
18
FOUL-RELEASE COATING TESTING
Plan to Collect “Real” Fuel Savings
• Given likely fouling in-port, foul-release coatings will need cleaning. Need to develop business
case that balances fuel savings against material cost premium and cleanings.
• “Black Box” Ship Power Condition Monitoring (SPCM) system to be installed on CG-73
by NSWC-CD would tie into:
- Global positioning system. - Shaft torque meters.
- Shaft Speed - Speed Log – Propeller Pitch
- Wind Speed/Direction – Gyro Heading
- Roll & Pitch
- The SPCM is NOT integrated into ship’s network (it is a temporary installation)
• SPCM will collect average speed/power over a long periods of time and plot as
Shaft Horsepower (SHP) over Speed cubed = SHP/V^3
2.00
1.00
0 50 100 150 200 250 300 350 400
Elapsed time (days)
NAVSEA interested in improved means of monitoring ship hull drag & fuel economy. 19
NAVY ANTIFOULING PROGRAM
Foul-Release Coatings, Damage Limits Service Life
DAMAGE OF OPTION 3 FOUL-RELEASE COATINGS
70
60 ACCUMULATION ON
50 EXPOSED PANEL
40
30
20
10
0
1 2 3 4 5 6 7 8 9 10 11 12
Exposure Cycles
80
FOULING 70
60
RELEASE IN 50
FLOW CHANNEL 40
30
20
10
0
1 2 3 4 5 6 7 8 9 10 11 12
Exposure Cycle
70
Percent Remaining Fouling
60
50
40
30
20
10
0
1 2 3 4 5
Exposure Cycles
22
NAVY ANTIFOULING PROGRAM
State of the Art
• NAVSEA learned that Econea biocide has been registered by U.S. EPA
on 23 April 2007.
•• Registration of one new biocide took 7 years.
•• Registration of new biocides unlikely, high cost, long payback period.
Biocidal coatings development limited in near term.
• NAVSEA has renewed level of interest in Option 3 coatings that are being
formulated to function well on slower vessels and that can withstand the
mechanical damage that can occur on Navy ships.
Coatings that shed fouling, repel fouling, or that release fouling are
potentially significant area for research:
1. Duty cycle key, need to prevent fouling while static for months.
2. Durability is key, need to withstand tugs, fenders, cleaning.
3. Producability is key, cannot radically increase docking time or cost.
• NAVSEA interested in working with R&D community and coating vendors
to looking in new directions. Biocides are limited by cost to bring to market,
paint chemistry may have to change to ensure long-term performance.
Coatings that are “out of the box” of interest to NAVSEA:
1. 100% solids, hydrolysable coating to rapidly polish and deliver
newer biocides.
2. Single-coat paints taking over tank coating, antifouling?
3. Surface chemistry that repels fouling in a hard, tough layer.
4. Hull-bug to keep coating clean an boost performance.
23
NAVY ANTIFOULING PROGRAM
Future Navy Ship Developments
• NAVSEA needs to reduce operating costs and improve ship performance.
• NAVSEA needs to develop copper-free coatings to address evolving
environmental regulations.
•• Development & testing of additional copper-free coatings.
•• Conduct additional tests of foul-release coatings.
•• Monitor already initiated tests.
24
Backup slides
25
TOTAL ANNUAL COPPER LOADINGS
Non-Oily
Total Cu Load = 345,480 lb/yr
Machinery
Wastew ater U/W Ship (156,707 kg/yr)
Firem ain <1% Husbandry
System s 485 lbs 1%
2% (220 kg) 4,279 lbs
8,618 lbs Other
(1,941 kg)
(3,909 kg) <1%
691 lbs
(314 kg)
Hull Coating
S/W Cooling
Leachate
Discharge
64%
32%
216,657 lbs
112,100 lbs
(98,274 kg)
(50,847 kg)
Distillation &
RO Brine
<1%
2,649 lbs
(1,201 kg)
*Estimates are for all discharges and vessels covered by Source: Technical Development Document Phase I
UNDS within contiguous zone (<12 nm) Uniform National Discharge Standards for
Vessels of the Armed Forces26
EPA 821-R-99-001, April 1999
INTERNATIONAL INTERSLEEK 900
System Application
Application of final anticorrosive (AC) epoxy
coat* {after substrate blast-cleaning} Application of tie coat*
(*Intergard 264 – black) (*Intersleek 731 – light pink/gray)
28
NAVSEA ANTIFOULING COATING PROGRAM
GOALS
VOC < 400 g/l
CAN USE OXOL.
SUPPORT 12-year DOCKING
Cu RELEASE < 10 ug/cm2/day
WITHOUT CLEANING
OR 50% OF BRA-640
CAN ACCEPT CLEANINGS
OR NO COPPER ANALOGOUS TO CURRENT
ASTM-D-6442 METHOD, COATINGS.
90-DAY PERIOD. COATING THAT
MEETS NAVSEA
NEEDS
29
ANTIFOULING COATING PROGRAM
Application Specifications
• NAVSEA Standard Item 009-32 defines how a coating will be applied as a “turn-key”
document for contracting for coating removal, application, and repair.
Requirement Rationale
Requires use of MIL-PRF-24647 system One vendor liable for entire system performance.
& vendor-supplied ASTM-F-718 data sheet.
Requires dry film thickness checks on each coat Validates adequate paint is applied.
in accordance with SSPC PA-2.
Requires surface preparation for replacement Key parameter for coating adhesion.
& repair using SSPC, SP-1, SP-3, SP-10 or SP-11.
Requires 2-4 mils of surface profile. Key parameter for coating adhesion.
Defines allowable levels of soluble salts on Parameter minimizes level of in-service blistering.
Defines number & sequence of coats. Ensures desired service life and supports husbandry.
Defines allowable application temperature Parameter ensures cure & working time.
Defines allowable Dew point relative to Prevents application over condensate and coating failure.
Surface temperature