Professional Documents
Culture Documents
Advances in Power
Boilers
Edited by
Mamoru Ozawa
Faculty of Societal Safety Sciences,
Kansai University, Osaka, Japan
Hitoshi Asano
Kobe University, Kobe, Japan
Series Editor
Yasuo Koizumi
The University of Electro-Communications,
Chofu, Tokyo, Japan
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ISBN: 978-0-12-820360-6
List of contributors ix
About the editors xi
Preface of JSME Series in Thermal and Nuclear Power Generation xiii
Preface to Volume 2: Advances in Power Boilers xvii
2 Introduction to boilers 57
Mamoru Ozawa
2.1 Start of steam application to pumping water 57
2.2 Dawn of steam power 59
2.3 Classification of boilers 61
2.4 History of boiler development 61
2.5 Historical development of power generation boilers in Japan 99
2.6 Similarity law in boiler furnace and other various important issues 99
References 103
Index 479
List of contributors
Saburo Hara Central Research Institute of Electric Power Industry, Tokyo, Japan
Jun Inumaru Central Research Institute of Electric Power Industry, Tokyo, Japan
Naoki Noda Central Research Institute of Electric Power Industry, Tokyo, Japan
Hiromi Shirai Central Research Institute of Electric Power Industry, Tokyo, Japan
Electric power supply is a fundamental and principal infrastructure for modern soci-
ety. Modern society uses power generation through heat. This series of books consists
of eight volumes describing thermal and nuclear power generation, taking Japan as
the example, and referring the other countries. The Volume 1 discusses how power
supply is attained historically, focusing on the thermal and the nuclear power genera-
tion along with minimum-required scientific and technological fundamentals to
understand this series of books. Then, the present status of the thermal and the
nuclear power generation technique is displayed in detail in Volumes 2 through 8.
The rehabilitation and reconstruction of Japan after World War II was initiated
through the utilization of a large amount of coal for boilers of the thermal power
plants. Meanwhile, environmental pollution caused by coal combustion became
serious, and then oil was introduced to the boilers. Due to two worldwide oil crises
and because of carbon dioxide issues, natural gas has also begun to be used for boi-
lers. Current thermal power generation in Japan is based on coal and gas utilization.
As a result of enough power supply, Japan has become one of the leading countries
economically and technologically in the world. The thermal power technology that
started from introducing technology from abroad has been transfigured Japan into
one of the most advanced in the world through the research and development of
Japanese industry, government, and academia during this process.
Global warming related to excess carbon dioxide emissions has become a
worldwide issue in recent years. Reducing carbon dioxide emission in thermal
power generation is important to help cope with this issue. One direction is to
change the fuel of a boiler from coal to gas that exhausts less carbon dioxide.
Another important direction is to endeavor to enhance the thermal efficiency of
coal thermal power plants as well as oil and gas. Many developing countries in
the world need more thermal power plants in future. Although oil and/or gas ther-
mal power plants may be introduced into these countries, it is supposed that coal
thermal power plants will still be used due to economical reasons. Considering
these situations, the publication of this series of books that displays and explains
the developing history and the present status of the most advanced thermal power
plants in Japan and other advanced countries is a timely planning for engineers
and researchers in the advanced countries to pursue the further advancement and
for engineers and researchers in developing countries to learn and acquire this
knowledge.
xiv Preface of JSME Series in Thermal and Nuclear Power Generation
the unbiased and heartful comments given from many reviewers to make this series
superb. Special thanks should be given to Maria Convey and Sara Valentino of the
editorial staff at Elsevier.
Editors in Chief
Yasuo Koizumi
The University of Electro-Communications, Chofu, Tokyo, Japan
Mamoru Ozawa
Kansai University, Takatsuki, Osaka, Japan
March 16, 2020
Preface to Volume 2: Advances in
Power Boilers
Steam power has been constantly at the leading position of industrial technologies
since the beginning of the 18th century. At the first stage, steam power appeared as
the prime mover for the pumping system of coal mines. The advancement in steam
power engineering made it possible to lead the factory systems for the mass produc-
tion of textile products. The availability of steam engines extended their application
to steamboats and locomotives for the mass transportation of people and industrial
products. Such advancement is supported by the development of iron and steel tech-
nology, machine tool, control engineering, and, of course, by society and its econ-
omy. Following the development in electrical technology, steam power stations
were constructed, and since then the electrical network thus has been the fundamen-
tal and principal infrastructure of the society.
The development in steam power since the 18th century has been, in fact, depen-
dent on the development in boiler technology during this 300-year period. A drastic
increase in efficiency and unit output has been supported by the development in
thermo-hydraulic engineering, materials engineering, control engineering, and of
course chemical engineering while the development process was not straightfor-
ward. An increase in the unit power brought about many explosions together with a
tremendous number of fatalities. To reduce and mitigate losses from explosions, a
social system, that is, third-party inspection and regulations, has been introduced. In
reality, the boiler development was a battle with explosions.
A boiler is a system to generate steam by firing coal, oil, gas, and recently inciner-
ation. At the beginning, coal was a prime fuel, which continued to the 1950s for
about 250 years. During this period, various coal-treatment technologies have been
developed to raise efficiency and reduce the emission of smoke. Ash treatment was
also a very important task. Oil was introduced to boilers, so efficiency issue and ash
problems were in part resolved, while the mass consumption of oil for power genera-
tion brought about unstable oil prices due to economic and political situations.
Especially Japan got involved in the oil-crisis in 1973 and 1979. This oil-crisis intro-
duced natural gas firing and enhanced the construction of nuclear power plants.
Nuclear power stations constructed in Japan counted 54 units, while they drastically
reduced in number after the core meltdown in the Fukushima Daiichi power station.
Since then, the economy and social welfare in Japan have been supported by the
fossil-fuel firing power stations, that is, steam boilers. Such a situation is not just a
xviii Preface to Volume 2: Advances in Power Boilers
problem in Japan but rather universal in many developing countries. The importance
of steam boiler technologies is still a prime issue.
This volume is intended to present a state-of-the-art review of power boiler tech-
nology to help practical engineers and graduate student to build basic frameworks
of ideas with which they can understand and treat practical problems of power boi-
lers. Basic principles together with the practical state-of-the-art are described by the
specialists of boiler companies in Japan. As the way of approach to boiler technol-
ogy is not the same among university researchers, research institute members, and
engineers in industries, the editorial board members and authors held many discus-
sions in the course of writing manuscripts, so that the philosophy or common prin-
cipal view on the power boilers and related technologies would remain consistent
throughout this book while respecting the autonomy of each author. We would be
grateful if the essence of our experience in boiler technologies is shared by the care-
ful readers.
The editors are deeply indebted to editorial board members, Akira Yamada,
Atsuhiro Hanatani, Jun Inumaru and Toshihiko Yasuda for their valuable sugges-
tions in planning and editing processes of this book, and thanks are extended to all
the authors of the Central Research Institute of Electric Power Industry, Mitsubishi
Heavy Industries, Ltd., Mitsubishi Hitachi Power Systems, Ltd., IHI Corporation,
Research Institute for Advanced Thermal Power Systems, and Hitachi Zosen
Corporation. The editors are also grateful to Elsevier Inc. for allowing publication
and to Editorial Project Manager, Sara Valentino and Project Manager, Prasanna
Kalyanaraman for their editorial works of this volume. Without their contribution,
this volume could not have survived from the bustle of the ongoing pandemic of
coronavirus disease 2019.
April 2020
Mamoru Ozawa
Hitoshi Asano
Fossil fuels combustion and
environmental issues 1
Jun Inumaru, Takeharu Hasegawa, Hiromi Shirai, Hiroyuki Nishida,
Naoki Noda and Seiichi Ohyama
Central Research Institute of Electric Power Industry, Tokyo, Japan
Chapter outline
1.1 Introduction 1
1.2 Overview and properties of coal, oil, and gas 4
1.2.1 Coal 4
1.2.2 Oil 5
1.2.3 Gas 12
1.3 Combustion of fuels 16
1.3.1 Coal 16
1.3.2 Oil 23
1.3.3 Gas 27
1.4 Emission-induced environmental issues and protection 36
1.4.1 Flue gas treatment technology 36
1.4.2 Wastewater treatment 45
1.5 Remarks 49
Nomenclature 50
Notations 50
Greek letters 51
Subscripts 51
References 51
1.1 Introduction
Coal, oil, and gas are mainly used as fossil fuels for power generation. Fig. 1.1 [1]
shows shifts in global primary energy consumption by energy source. The global
primary energy consumption has been increasing in line with economic growth, and
oil is the highest in terms of consumption, followed by coal and then gas. The
increase in oil is mainly due to its use as transport fuel. For the purpose of power
generation, attempts are being made to substitute other energy sources for oil. Coal
is widely distributed around the world, and about 60% of coal consumption goes
toward power generation as a relatively cheap fuel. The consumption of coal had
been increasing year on year, but after peaking in 2013, it is more or less on the
decrease these days. This is due to the recent consumption decrease in China, which
had long been driving the increase in consumption. Gas fuel trends are detailed in
Section 1.2.3.
Advances in Power Boilers. DOI: https://doi.org/10.1016/B978-0-12-820360-6.00001-1
© 2021 Elsevier Inc. All rights reserved.
2 Advances in Power Boilers
Figure 1.1 Transition of primary energy consumption in the world (by energy source) [1].
Note: Figures may not add up to the totals due to rounding. Mtoe: Million tons of oil
equivalent
Figure 1.2 Power generation cost of each power source in Japan (in 2014) [2].
The matters to be considered in using these resources for power generation are
the stable procurement of fuel, power generation costs, including fuel cost, and
environmental characteristics such as emissions of carbon dioxide, nitrogen oxides,
sulfur oxides, and particulate matter. As a reference, Fig. 1.2 [2] shows the power
generation cost by fuel in Japan. The cheapest fuel is coal, followed by natural gas
and oil. Fig. 1.3 [3] shows the life cycle CO2 emissions in Japan by power source.
This takes into account not only the carbon dioxide from fuel combustion but also
that produced in the operation of fuel development drilling, transportation, and
power generation facilities. As for life cycle CO2 emissions, coal is the highest, fol-
lowed by oil and natural gas.
When using fossils fuel in power generation boilers, it is important to select
appropriate methods for fuel supply, operation, and maintenance with an under-
standing of the specific characteristics of these fuels. In this section, we describe
Fossil fuels combustion and environmental issues 3
Figure 1.3 CO2 emissions intensity over the entire life cycle by source [3].
the environmental characteristics of coal, oil, and gas from the viewpoint of
power generation fuel, including the characteristics of fuels, combustion charac-
teristics, and emission gas and wastewater, as well as technological development
issues.
4 Advances in Power Boilers
1.2.1.1 Formation
Coal is a combustible rock that is formed from decayed plants in the earth. The
underground heat and pressure cause the coalification of decayed plants, which
involves the loss of water, methane, and carbon dioxide from plants and an increase
in the proportion of carbon. As the coalification progresses, lignite (brown coal),
followed by subbituminous coal, bituminous coal, and finally anthracite, is formed.
Lignite and subbituminous coal, which have high water contents, are used to gener-
ate steam and electric power. Bituminous coal is used to not only generate steam
and electric power but also produce coke. Anthracite has a high carbon content and
burns with a smokeless flame, but it ignites with difficulty. Therefore it is used as
an ingredient of charcoal briquettes and filter media.
1.2.1.2 Classification
Coal consists of organic matter, minerals, and moisture. Organic matter contains
mostly carbon, hydrogen, oxygen, and a small amount of sulfur and nitrogen. Coal has
a wide range of properties, because the types of plant, the degree of coalification, and
the conditions of coalification vary in different locations around the world. Therefore
it is important to logically classify into different types for its optimal utilization.
In Japan, coal is classified on the basis of the calorific value, fuel ratio (the weight
ratio of fixed carbon to volatile matter), and agglomerating character, as shown in
Table 1.1 [4,5]. In the United States, it is classified on the basis of the content of
fixed carbon, that of volatile matter, and the agglomerating character, as shown in
Table 1.2 [5,6]. The calorific value and fuel ratio are important values in selecting
the type of coal appropriate for use in a boiler, and the agglomerating character is an
important value in selecting the type of coal for producing a coke, which is used for
iron manufacture. The coal used in a boiler is called thermal coal or steam coal, and
that for iron manufacture is called coking coal or metallurgical coal.
1.2.1.3 Properties
In the field of coal combustion the important combustion properties of coal are
determined by proximate and ultimate analyses [7,8], namely, calorific value [9],
Fossil fuels combustion and environmental issues 5
coal ash composition [10], ash fusibility [11], and grindability [11]. The composi-
tion of maceral (Fig. 1.4 [12]), which is a component from coalified plants that
remains preserved in coal, is also fundamental to the combustion properties, since
different maceral types (inertinite, vitrinite, and liptinite) combust at different tem-
peratures and rates.
In the proximate analysis the contents of moisture, ash, and volatile matter of
coal dried in air are measured, and the content of the remaining part is calculated as
the content of fixed carbon. In the ultimate analysis the contents of carbon, hydro-
gen, oxygen, total sulfur, combustible sulfur, and nitrogen are measured. The results
of proximate and ultimate analyses in various coals are shown in Table 1.3 [5]. As
coalification progresses, moisture and volatile matter decrease, and the calorific
value and carbon content increase. The contents of sulfur and nitrogen are indepen-
dent of coalification because they depend on the type of decayed plants present and
the sediment that covered and buried the plants.
1.2.2 Oil
In power plants in Japan, light oils, such as kerosene and diesel, are used for gas
turbines. Heavy oils, the prices of which are relatively cheap compared to kerosene
and diesel, are used for boilers. The quality requirements by the Japanese Industrial
Standards (JIS) for kerosene, diesel, and fuel oil (heavier oils such as banker oil,
marine fuel oil, and marine residual oil) are shown in Table 1.4 [13], Table 1.5
[14], and Table 1.6 [15], respectively. These standards are established mostly based
on flash point, viscosity, and sulfur content.
In addition to the physical properties for proper combustion, important aspects
of fuel use in power plants include the presence of corrosive materials that can
damage the local structure and contaminated matter that yields pollutants in the
fumes. Regarding corrosive materials, trace amounts of alkali metals, such as
sodium and potassium, produce detrimental impacts on the gas turbine. And
Table 1.2 Classification of coal in the United States [5,6].
Figure 1.4 Maceral types consisting of liptinite and vitrinite Reproduced by permission from
R. M. Flores, Coal and Coalbed Gas, Elsevier (2014),[12].
vanadium can also cause “vanadium attack” [16]. The sulfur content, which causes
sulfidation corrosion, also negatively impacts the boiler (fuels with sulfur are never
applicable to gas turbines).
The causative agents of pollutants in the fumes are nitrogen, which produces
nitrogen oxides (NOx), and sulfur, which produces PM2.5 (fine particulate matter)
and sulfur dioxide (SOx).
Due to the exceptional circumstances brought by SOx on the Yokkaichi asthma
[17] during one of the “Four Big Pollution Diseases of Japan” in 1960s1970s, the
desulfurizer or use of low-sulfur crude oil, which is expensive but avoids petroleum
refinery costs, became indispensable in Japan. Although the nitrogen content in the
fuel causes NOx emissions, which is as harmful as SOx because NOx causes photo-
chemical smog, there are no regulations of quality requirements for nitrogen emis-
sions. This is partly because not all nitrogen content is converted into NOx, which
is different for SOx, since all sulfur contents are converted into SOx.
The constructions of new oil-fired thermal power plants are prohibited in Japan,
based on the communique adopted by the International Energy Agency (IEA) gov-
erning board meeting at ministerial level in May 1979, the “Principles for IEA
Action on Coal” [18]. Therefore both installed capacity of electric power and
amount of electricity power generation for oil-fired power plants started decreasing
with each passing year after the 1980s, as seen in Fig. 1.5 [19] and Fig. 1.6 [20].
However, some new oil-fired gas turbines were exceptionally introduced after the
Great East Japan Earthquake of 2011. This is also one of the causes of oil being
expensive compared with other fuels, such as coal and natural gas, as shown in
Fig. 1.7 [21].
Refineries in Japan also pursued scrap-and-build designs of refinery capacity and
“a shift toward white oil” (cleaner oils such as gasoline and naphtha) by improving
the performance of reformers of heavy distillates and residues and following the
Table 1.3 Coal properties[5
Country Coal Item
Australia Drayton 28.4 9.9 3.4 13.3 34.5 48.8 1.4 71.1 4.9 1.4 8.1 0.8 0.9
Newlands 28.0 8.4 3.0 15.0 26.6 55.4 2.1 69.1 4.1 1.4 7.0 0.4 0.4
Hunter Valley 29.6 8.0 3.5 11.2 34.0 51.3 1.5 72.7 4.5 1.6 9.3 0.3 0.6
Lemington 28.4 9.9 3.7 13.0 32.3 51.0 1.6 71.9 4.5 1.5 8.2 0.4 0.4
Warkworth 28.9 9.6 3.6 11.8 32.8 51.8 1.6 69.1 4.6 1.5 8.9 0.4 0.4
China Datong 29.6 10.1 5.1 7.0 28.1 59.8 2.1 78.2 4.5 0.8 8.8 0.6 0.7
Nantong 28.4 8.0 4.0 16.0 36.2 43.8 1.2 83.0 5.2 1.6 9.8 0.5 0.8
Canada Obedarsh 25.3 8.0 5.0 14.0 37.0 44.0 1.2 64.3 4.6 1.5 14.3 0.3 0.6
Coal Valley 26.1 11.3 6.4 10.7 33.5 49.3 1.5 69.7 4.7 0.9 13.1 0.1 0.3
Indonesia Satui 28.8 9.5 5.1 7.9 41.9 45.1 1.1 72.4 5.5 1.2 11.9 0.7 0.8
South Africa Ermelo 27.8 7.6 3.5 12.9 31.4 52.2 1.7 72.0 4.4 1.7 7.9 0.6 0.8
Optimum 28.5 8.2 3.8 10.7 32.4 53.1 1.6 72.9 4.9 1.6 9.1 0.5 0.6
The United Pinacle 27.2 8.3 4.6 13.4 40.9 41.1 1.0 68.2 5.6 1.4 0.3 0.6 0.7
States
Plato 25.1 9.8 6.0 9.3 41.8 42.9 1.0 72.8 5.5 1.5 11.2 0.7 0.9
Fossil fuels combustion and environmental issues 9
1.2.3 Gas
Examples of gaseous fuels for use in boilers that are being studied include natural
gas, blast furnace gas (BFG), biogas, and, with an eye toward a future hydrogen-
Fossil fuels combustion and environmental issues 13
using society, alternative fuels such as hydrogen and ammonia. However, BFG and
biogas tend to be for personal or local consumption in the areas where they are pro-
duced and are almost never sold internationally. In addition, unlike fossil fuels such
as natural gas, there is anticipation around the use of the secondary fuels, such as
hydrogen and ammonia, in the transportation sector and distributed power produc-
tion with environmental conservation in mind, and in the power generation sector
in more efficient power generation facilities. We discuss natural gas, which is
strongly influenced by external factors, as a fuel for gas-fired boilers, giving an
overview of supply and demand trends.
Figure 1.9 Trends and prospects of world natural gas: (A) demand outlook and (B) supply
outlook [23].
14 Advances in Power Boilers
Figure 1.11 Trends and prospects of primary energy demand by fuel in China [23].
expected to decrease, the entire global supply of natural gas is anticipated to rise
due to the production of shale gas in North America and China. Therefore the pro-
portion of unconventional natural gas (shale gas, coalbed methane, and so on) will
account for about 30% of the total in 2040. Although there are concerns about
delays in establishing more new facilities for LNG, increased production of shale
gas is expected to relax global supply and demand for natural gas.
Fig. 1.10 [23] and Fig. 1.11 [23] show the supply for natural gas to China (2017)
and China’s energy demand according to the IEA, respectively. In China, about
60% of natural gas demand is fulfilled by domestic production, and 22% is com-
posed of imported LNG. As China suffers from serious air pollution, the State
Council announced, “10 Measures to Prevent Air Pollution” in 2013 and is planning
a rapid transition from coal to natural gas. According to the IEA forecast, the
demand of natural gas in 2040 will be about three times higher than in 2016, and
the proportion of natural gas demand to primary energy demand will rise to about
14%. On the other hand, the proportion of coal demand to primary energy demand
Fossil fuels combustion and environmental issues 15
is expected to fall from 60% to 40%. Demand for energy and natural gas in China
is expected to continue being affected by policy, domestic gas production volume,
and import volume in the future, and there are concerns that these fluctuations
could affect the global supply of and demand for LNG.
Figure 1.14 World crude oil, natural gas, and LNG price trends [24].
amount of LNG imported to Asia makes up 73% of all LNG imports, and, more-
over, 55% is imported by three countries: Japan, China, and Korea.
radiation from the combustion flame. When the particle temperature reaches the
thermal decomposition temperature, volatiles are released from coal particles and
ignite at approximately 250 C500 C [25]. The particle temperature increases dur-
ing the homogeneous combustion of volatiles. Before and after the combustion of
volatiles is completed, the heterogeneous combustion of char, which is the solid
material that remains after volatiles have been released from coal, starts. After char
combustion, ash particles and a small amount of unburnt carbon particles remain.
Ww and Wn are the contents of water and nitrogen in coal. It is assumed that nitro-
gen in coal is converted into N2.
In actual combustion the actual amount of air used to burn is larger than the the-
oretical amount of air. The ratio of actual amount of the combustion air to the theo-
retical amount is defined as the excess air ratio λ (). The actual amount of
18 Advances in Power Boilers
combustion air A (m3N/kg-coal) and the amount of flue gas G (m3N/kg-coal) are,
respectively, calculated by Eqs. (1.3) and (1.4) with λ . 1.0.
A 5 λA0 (1.3)
G 5 ðλ 2 1ÞA0 1 G0 (1.4)
In pulverized coal-fired power plants, coal is burned off at an excess air ratio of
about 1.2.
ejected from the center of the burner and burned. As this system uses coal particles
pulverized to 3040 µm, it provides high combustion efficiency and less excess air.
Furthermore, as it allows the easy scaling up of a boiler, this system is now mainly
used in coal-fired power plants.
U 5 A 3 Uc = ð1 2 AÞ 3 ð1 2 Uc Þ (1.5)
E512U (1.6)
The ratio of the amount of unburned carbon to that of the combustible matter
in coal U () is defined as the unburned fraction and calculated using Eq. (1.5).
Uc (kg-carbon/kg-ash) is the unburned carbon content in ash. A (kg-ash/kg-coal)
is the ash content, which is defined in terms of the weight of oxides in JIS 8812.
It should be noted that the ash content is different from the mineral content in
coal. The unburned fraction correlates with the fuel ratio as shown in Fig. 1.18
[28]; that is, the unburned fraction increases with the fuel ratio [27,28]. In other
studies, the unburned fraction correlates with the content of vitrinite in coal,
which is a maceral; this is, the unburned fraction increases as the content
decreases [29,30].
Figure 1.18 Correlation between unburned fraction and fuel ratio [28].
Fossil fuels combustion and environmental issues 21
Figure 1.19 Relationship between NOx concentration and nitrogen content in coal [28].
fuel NOx. Therefore the nitrogen content in coal FN (%) and the conversion ratio of
nitrogen CR (%) to NOx affect the NOx concentration. The NOx concentration cor-
relates with FN as shown in Fig. 1.19. However, the variation of the NOx concen-
tration is large. This variation is caused by the variation of CR. CR increases with
fuel ratio FR, and CR decreases as FN increase. Therefore FR/FN (1/%) and CR
have a strong correlation, as shown in Fig. 1.20 [27].
The two-stage combustion method is mainly used to reduce NOx. In this
method, part of the combustion air is injected from the two-stage combustion air
port, which is located downstream of the burner zone. In the burner zone, pulver-
ized coal burns with λ , 1.0. Part of generated NOx is reduced in the reducing
atmosphere downstream of the combustion flame, and the amount of unburned
carbon increases in the burner zone and is burned by two-stage combustion in air.
The effect of the two-stage combustion ratio on Uc and the NOx concentration are
shown in Fig. 1.21 [31]. The NOx concentration decreases as the two-stage com-
bustion ratio increases, but Uc increases. This result indicates that it is important
to select a suitable two-stage combustion ratio in accordance with the coal prop-
erties and the combustion characteristics of a boiler. Furthermore, various low-
NOx burners used in the two-stage combustion method are being developed
[3236].
22 Advances in Power Boilers
Figure 1.20 Correlation between conversion of N in coal to NOx and FN/FR [27].
Figure 1.21 Effects of two-stage combustion ratio on the NOx and unburned carbon
concentrations [31].
Fossil fuels combustion and environmental issues 23
1.3.2 Oil
The combustion of liquid fuels consists of four reactions, that is, atomization,
vaporization, mixing, and (combustion) reaction. For power plants the atomization
is achieved by the energy (i.e., pressure or velocity) which is (1) involved in the
fuel itself or (2) supplied by an external fluid. Fig. 1.22 shows the main examples
of (1): a plain-jet and a pressure-swirl atomizer. Fig. 1.23 shows the main examples
of (2), namely, an airblast atomizer [37] and a two-phase nozzle [38].
In both cases the droplets are formed by tearing large droplet, liquid column, or
liquid film by a shear stress, as shown in Fig. 1.24 [39]. Because the produced dro-
plets are uniform, the characteristics are evaluated using statistic values regarding
distribution of droplet size, average droplet size, its variance, and so on. The
NukiyamaTanasawa distribution [37] and the RosinRammler distribution [40]
are commonly used to represent these characteristics. The RosinRammler distri-
bution function is shown in Eq. (1.7), which describes the cumulative distribution
RM (d) of the mass or volume as a function of total mass or volume contained in
droplets of diameter d smaller than d. The differential fM (d) is also shown in
Eq. (1.8) that indicates the mass or volume content of droplets with diameter d.
" #
d λ
RM ðdÞ 5 1 2 exp 2 ; (1.7)
d0
" #
λ d λ21 d λ
f M ðd Þ 5 exp 2 ; (1.8)
d0 d0 d0
Figure 1.23 Airblast nozzle and two-phase atomizer: (A) NukiyamaTanasawa airblast
nozzle [37] and (B) two-phase mixing nozzle [38].
24 Advances in Power Boilers
Figure 1.24 Three mechanisms of breakup atomization [39]: (A) droplet, (B) fibrous, and
(C) film.
where λ and d0 are the distribution parameters. Fig. 1.25 shows the representative
RosinRammler distribution. The viscosity of the fuel oil is very important for the
formation of the droplets. For high viscosity oils, such as fuel oil specified in JIS,
the viscosity of the fuel is controlled by heating so that the fuel temperature
becomes suitable for atomization, as shown in Fig. 1.26 [41], which was drawn
based on the ASTM D341.
The evaporation of a fuel strongly depends on the heat flux to the droplets and
the diffusion rate of the fuel vapor around the droplets. The heat flux significantly
depends on the conformations of the flame fronts and the droplets. These conforma-
tions are discussed by Chiu et al. [42], who modeled them into four conformations
of combustion, as shown in Fig. 1.27. The group combustion number G is defined
Fossil fuels combustion and environmental issues 25
Figure 1.26 Correlation between viscosity and temperature of fossil fuels [41].
26 Advances in Power Boilers
Figure 1.27 Four group combustion modes of a droplet cloud [42]: (A) single droplet
combustion, (B) internal group combustion, (C) external group combustion, and (D) external
sheath combustion.
by the Lewis number Le and the Schmidt number Sc, as shown in the following
equation:
2=3 d
G 5 1:5Le 1 1 0:27Sc Re
1=3 1=2
nT (1.9)
l
Chiu et al. established that the group combustion can be expressed by the prod-
uct between the total number of droplets to the two-thirds power and the reciprocal
of the nondimensional separation S, as illustrated in Fig. 1.28 (where, to simplify,
Le 5 1) [42]. The nondimensional droplet separation S is defined by the following
equation:
Fossil fuels combustion and environmental issues 27
1.3.3 Gas
Unlike liquid fuels and solid fuels such as coal, gaseous fuels do not contain ash,
fixed nitrogen, or sulfur content and do not produce air pollutants other than
28 Advances in Power Boilers
Figure 1.29 Predicted NOx emission levels of various fuels in gas turbine combustors [43].
thermal NOx, which is formed by the oxidization of nitrogen in the air. A variety of
low-NOx combustion techniques have been developed because of relatively simple
combustion process in which a combustion reaction progresses through only a gas-
phase reaction with an oxidizing agent such as air. In addition, the demand for natu-
ral gas fuels has been steadily rising in recent years because of the low carbon con-
tent in fuel (when comparing the CO2 emissions per unit calorific value, coal: fuel
oil: natural gas 5 1:0.75:0.55, with natural gas being the lowest), i.e. low contribu-
tion to greenhouse effect. An outline of basic burner combustion technology in gas-
fired boilers for industrial or power generation purposes is provided in the follow-
ing sections.
Table 1.7 Typical properties of natural gas and city gas [4446].
city gas shown in the table, components such as propane gas are added to raw natu-
ral gas or LNG to adjust the fuel’s calorific value to 4346 MJ/m3N and make the
gas usable in standard household gas equipment. The adjusted gas is supplied
through the city’s pipeline network.
Fig. 1.30 [47] shows major gas-fired burner technology. A variety of burner
technologies are being developed to fit the fuel type, calorific value, and supply
pressure of gas fuels including high-calorie gases such as natural gas, LNG (includ-
ing city gas), LPG, refined petroleum gas, and COG (coke-oven gas), and mid- to
low-calorie gases such as BFG, LDG (LinzDonawitz converter gas), H2, and bio-
gas. All the burner technologies allow for cofiring of multiple gas fuel types and
cofiring with oil. In particular, various manufacturers have recently developed a
variety of low-NOx burners as an environment-friendly strategy for large-scale ther-
mal power generation. Specific examples will be discussed later in Section 1.3.3.4.
Fig. 1.31 [47] provides examples of oil/gas cofiring burner technology. In all the
burner technologies an oil-spray burner is placed in the center of the burner tile
with a gas burner positioned on the perimeter. A variety of combinations are possi-
ble depending on the fuel type, calorific value, and fuel supply pressure.
Figure 1.31 Example of dual-fuel burners [47]: (A) oil burner/low-NOx gas burner, (B) oil
burner/scroll-type burner, and (C) oil burner/multiple lance 1 ring-type gas burner.
components at about 90%, a calorific value of about 20 MJ/m3N, and makes up 1/2
of natural gas. LDG is around 70% CO, a combustible component, and is also com-
posed of the inert gases nitrogen (N2) and carbon dioxide (CO2). Its calorific value
Fossil fuels combustion and environmental issues 31
Table 1.8 Typical properties of blast furnace gas (BFG), coke-oven gas (COG), and
LinzDonawitz converter gas (LDG) [48,49].
Figure 1.32 Example of manufacturing process scheme and energy flow of the steelworks
[50].
is about 8 MJ/m3N, and it makes up 1/5 of natural gas. COG and LDG are called
mid-calorie gases.
Fig. 1.32 [50] shows an example of the manufacturing process and energy flow
at a steelwork. The steelworks by-product gases BFG, COG, and LDG are supplied
to nonutility generation facilities for use as boiler fuel. Specifically, high-calorie
fuels such as coal, fuel oil, and LPG are supplied to and cofired in the nonutility
generation facilities for the auxiliary fuel firing of by-product gas. In recent years,
BFG single-fuel firing technology has also been put to practical use. In addition to
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CHAPTER XI
PARENTS IN COUNCIL
Part II
“We have listened to you, gentlemen, with great deference. We have
profited much, and perceive a great field of work before us. I hope
we may get a little outside help. I heard the other day of a young lady
learned in mosses who is in the habit of taking the children she
knows on ‘mossing’ expeditions. But what I wish to say is, education,
like charity, begins at home, and you have chosen to lead us far
afield at the very outset!”
“Truly, we did go off at a canter! But don’t you think ’tis a matter
for curtain discipline? If your son Tom had not ‘wondered what you
are’ we might have begun quite at the beginning, if there is one; or,
most likely, should have been till this moment wondering where to
begin. We are grateful to you, Henderson, for starting us anywhere;
and more so to Mrs. Henderson for her axiom, Education begins at
home.”
“I daresay experienced people get to know all about it,” said Mrs.
Clough; “but the mother of even two or three little ones has a sense
of being at sea without rudder or compass. We know so little about
children, or, indeed, about human beings at all! Parents before our
time had something to go upon; and the young mother could ask
counsel of her elders on all matters from ‘cinder tea’ to the choice of
a school. But now science is abroad; many of the old wise saws turn
out, not only mischievous, but ridiculous. We can’t keep hold of the
old, we can’t get hold of the new, and there we are, like Mahomet’s
coffin.”
“You have described our quandary exactly, Mrs. Clough! And what
you say accounts for many things. The older people complain that
the children of these days are growing up lax, self-pleasing,
disobedient, irreverent. Now, I think myself there is a great deal
that’s fine in our children. They are much more of persons than we
were at their age; but that they do pretty much what is right in their
own eyes, are neither obedient nor reverent, nor even respectful, is, I
am afraid, a true bill. But don’t you see how it is? We are afraid of
them. We feel as a navvy might, turned in to dust the drawing-room
ornaments! The mere touch of his clumsy great fingers may be the
ruin of some precious thing. We parents, no doubt, get tenderness
and insight from above to enable us for our delicate work; so I
suppose it is our own fault that the children are beyond us.”
“How do you mean, Mrs. Meredith? And if you, mothers, don’t
know what to do with the children, who does? The enlightened father
lays himself out for a snub if he sets up for an authority at home.”
“Oh, yes! you men make ludicrous blunders about children. But
that’s no help. A young mother gets a tender human creature into
her keeping, full of possibilities. Her first concern is, not only to keep
it in health, but, so to speak, to fill it with reserves of health to last a
lifetime. At once her perplexities begin. I shall not even ask to be
excused for venturing upon details; the affairs of a young human
being are important enough to engage the attention of Queen, Lords,
and Commons, did they but know it. Well, a mother I know wished
her child to be clothed delicately, as befits a first-born. She sent to
Ireland for a delicious baby trousseau of lace and cambric. You
gentlemen don’t understand. Hardly had the dear little garments
gone through their first wash, when somebody tells her that ’oo’ a’
’oo’ is the only wear for babies and grown ups. I doubt if to this day
she knows why, but there was a soupçon of science in the
suggestion, so the sweet cambrics were discarded and fine woollens
took their place. By-and-by, when the child came to feed like other
mortals, there was a hail of pseudo-science about her ears. ‘Grape-
sugar,’ ‘farinaceous foods,’ ‘saliva,’ and what not; but this was less
simple than the wool question. She could make nothing of it, so
asked her doctor how to feed the child. Further complications arose:
‘the child sees everything;’ ‘the child knows everything;’ ‘what you
make him now he will be through life;’ ‘the period of infancy is the
most important in his life.’ My poor friend grew bewildered, with the
result that, in her ignorant anxiety to do right, she is for ever
changing the child’s diet, nurse, sleeping hours, airing hours,
according to the last lights of the most scientific of her acquaintance;
and ’tis my belief the little one would be a deal better off brought up
like its mother before it.”
“Then, Mrs. Meredith, you would walk in the old paths?”
“Not a bit of it! Only I want to see where I’m going. I think we live
in an age of great opportunities. But my contention is, that you
cannot bring up children on hearsay in these days; there is some
principle involved in the most everyday matter, and we must go to
school to learn the common laws of healthy living and well-being.”
“Mrs. Meredith is right: here is serious work sketched out for us,
and of a kind as useful for ourselves as for our children. We must
learn the first principles of human physiology.”
“Would not it do to learn what is called Hygiene? I have a notion
that is physiology made easy; that is, you are just taught what to do,
without going fully into the cause why.”
“No, we must stick to physiology: I don’t believe a bit in learning
what to do, unless founded upon a methodical, not scrappy,
knowledge of why we do it. You see, all parts of the animal economy
are so inter-dependent, that you cannot touch this without affecting
that. What we want to get at is, the laws for the well-being of every
part, the due performance of every function.”
“Why, man, you would have every one of us qualify to write M.D.
to his name.”
“Not so; we shall not interfere with the doctors; we leave sickness
to them; but the preservation of health, the increase in bodily vigour,
must be our care. In this way, we acquaint ourselves fully with the
structure of the skin, for example, with its functions, and the inter-
dependence between these and the functions of certain internal
organs. Now, secure vigorous action of the skin, and you gain
exhilaration of spirits, absolute joy for the time, followed by a rise in
the sense of general well-being, i.e., happiness. You remember how
a popular American poet sits on a gate in the sun after his bath,
using his flesh-brushes for hours, until he is the colour of a boiled
lobster, and ‘more so.’ He might be more seemly employed, but his
joy is greater than if daily telegrams brought him word of new
editions of his poems. Well, if due action of the skin is a means to a
joyous life, to health and a genial temper, what mother is there who
would not secure these for her child? But the thing is not so simple
as it looks. It is not merely a case of bath and flesh-brush: diet,
clothes, sleep, bedroom, sunshine, happy surroundings, exercise,
bright talk, a thousand things must work together to bring about this
‘happy-making’ condition. What is true of the skin is true all round,
and we cannot go to work with a view to any single organ or function;
all work together: and we must aim at a thorough grip of the subject.
Is it, then, decided ‘without one if or but,’ that we get ourselves
instructed in the science of living?”
“The ‘science of living’—yes, but that covers much beyond the
range of physiology. Think of the child’s mind, his moral nature, his
spiritual being. It seems to me that we already make too much of the
body. Our young people are encouraged to sacrifice everything to
physical training; and there is a sensuousness well hit-off in George
Eliot’s ‘Gwendoline,’ in the importance given to every detail of the
bath and the toilet. One is weary of the endless magnification of the
body and its belongings. And, what is more, I believe we are
defeating our own ends. ‘Groom’ the skin, develop the muscles, by
all means; but there is more to be thought of, and I doubt if to live to
the flesh, even in these ways, is permissible.”
“Right, Mrs. Meredith! But don’t think for a moment that
physiology lends itself to the cult of muscle. Here is a youth whose
biceps are his better part: like most of us, he gets what he aims at—
some local renown as an athlete. But what does he pay for the
whistle? His violent ‘sports’ do not materially increase the measure
of blood which sustains him: if the muscles get more than their
share, their gain implies loss elsewhere, to the brain, commonly,
and, indeed, to all the vital organs. By-and-by, the sports of youth
over, your brawny, broad-chested young fellow collapses; is the
victim of ennui, and liver, lungs, or stomach send in their requisition
for arrears of nourishment fraudulently made away with.”
“But, surely, Mr. Meredith, you do not think lightly of physical
development? Why, I thought it one of the first duties of parents to
send their offspring into the world as ‘fine animals.’”
“So it is; but here, as elsewhere, there is a ‘science of the
proportion of things,’ and the young people who go in violently and
without moderation for muscular feats are a delusion and a snare: in
the end they do not prove ‘fine animals;’ they have little ‘staying’
power.”
“But a child is more than an animal; we want to know how mind
and moral feelings are to be developed?”
“Even then, Mrs. Tremlow, we should find much help in the study
of physiology—mental physiology, if you like to call it so. The border-
line where flesh and spirit meet seems to me the new field, an
Eldorado, I do believe, opened to parents and to all of us concerned
with the culture of character. I mean, the habits a child grows up with
appear to leave some sort of register in his material brain, and thus
to become part of himself in even a physical sense. Thus it rests with
parents to ease the way of their child by giving him the habits of the
good life in thought, feeling, and action, and even in spiritual things.
We cannot make a child ‘good,’ but, in this way; we can lay paths for
the good life and the moral life in the very substance of his brain. We
cannot make him hear the voice of God; but, again, we can make
paths where the Lord God may walk in the cool of the evening. We
cannot make the child clever; but we can see that his brain is
nourished with pure blood, his mind with fruitful ideas.”
“I suppose all this would be encouraging if one were up to it. But I
feel as if a great map of an unknown country were spread before me,
where the few points one wants to make for are unmarked. How, for
instance, to make a child obedient, kind, and true?”
“Your question, Mrs. Tremlow, suggests further ground we must
cover: a few set rules will be of little service; we must know how
much there is in ‘human nature,’ and how to play upon it as a
musician on the keys of his instrument. We must add to our
physiology, psychology, and, to psychology, moral science. Complex,
yet most simple, manifold, yet one, human nature is not to be ticked
off in a lecture or two as a subject we have exhausted; but there is
no conceivable study which yields such splendid increase for our
pains.”
“And the spiritual life of the child? Does either of these ‘ologies’
embrace the higher life, or is it not susceptible of culture?”
“Ah, there we have new conditions—the impact of the Divine upon
the human, which generates life, ‘without which there is no living.’
The life is there, imparted and sustained from above; but we have
something to do here also. Spirit, like body, thrives upon daily bread
and daily labour, and it is our part to set before the child those ‘new
thoughts of God, new hopes of Heaven,’ which should be his
spiritual diet; and to practise him in the spiritual labours of prayer,
praise, and endeavour. How?—is another question for our Society to
work out.”
CHAPTER XII