SR.

PCM CHEMISTRY CDF MATERIAL

2. ELECTRO CHEMISTRY
GALVANIC CELL
1. The cell which converts chemical energy to electric energy is called
a) Galvanic or Voltaic cell b) Photo cell
c) Primary cell d) Secondary cell
2. Galvanic or Voltaic cell redox reaction is

a) Mg ( s)  2 Ag   Mg 2  2 Ag  s  b) Ni ( s ) Ni  aq  Ag  aq  Ag
2 

2 2
c) Zn s  Cu aq  Zn aq  Cu s d) All

3. The example for Galvanic or Voltaic cell is

a) Primary cell b) Secondary cell
c) Photo cell d) Daniel cell
4. The cell notation of Daniel (Galvanic) cell is

a) Zn s  | Zn aq (C1 ) || Cu aq  C2  | Cu s 

2 2
b) Cu aq   C2  | Cu s  || Zn s  | Zn aq  (C1 )
2 2

c) Zn aq  | Zn s  (C1 ) || Cu aq   C2  | Cu s  d) Zn s  | Zn aq  (C1 ) || Cu s   C2  | Cu aq 
2 2 2 2

5. EMF of the cell is calculated by

a) Ecell  Eleft  Eright (or ) Ecell  Eanode  Ecathode

b) Ecell  Eleft  Eleft (or ) Ecell  Eanode  Eanode

c) Ecell  Eright  Eleft (or) Ecell  Ecathode  Eanode

d) Ecell  Eright  Eright (or ) Ecell  Ecathode  Ecathode

SINGLE ELECTRODE POTENTIAL
6. A metal (or) non-metal in contact with the solution of its ions tends to develop electric potential at
the metal ion (or) non-metal/non-metal ion interface is called
a) Single electrode potential b) Reduction potential
c) Cell potential d) Half cell
ELECTRODE POTENTIAL
7. The potential difference developed between the electrode and the electrolyte is called
a) Standered electrode potential b) Electrode potential
c) Cell electro motive force d) Cell Potential

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8. Single electrode potential is measured by combining with
a) Standered platinum electrode b) Standered mecury electrode
c) Standard hydrogen electrode d) Standered aurum electrode

ELECTROCHEMICAL SERIES
9. Arrangement of different metals in the increasing order of reduction potentials is known as
a) Galvanic cell b) Primary cell
c) Secondary cell d) Electrochemical series
10. High reduction potential metal ions undergo_______ and act as ________
a) Oxidation, Anode b) Reduction, Cathode
c) Reduction, Anode d) Oxidation, Cathode
11. Low reduction potential metal ions (high negative value) undergo______and act as ______
a) Oxidation, Anode b) Reduction, Cathode
c) Reduction, Anode d) Oxidation, Cathode

12. K  / K  2.93V , Ag  / Ag  0.80V , Hg 2 / Hg  0.79V ,

Mg 2  / Mg  2.37V , Cr 3 / Cr  0.74V
Arrange these metals in their increasing order of reducing power.

a) K  / K  Mg 2 / Mg  Cr 3 / Cr  Hg 2  / Hg  Ag  / Ag

b) Hg 2   Ag  / Ag / Mg  Cr 3 / Cr  K  / K  Mg 2 

c) Mg  Cr 3 / Cr  Hg 2  Ag  / Ag / K  / K  Mg 2

d) Mg  Cr 3 / Cr  K  / K  Mg 2  Hg 2  Ag  / Ag
NERNST EQUATION
13. The Nernst equation for metals is represented by

a)  r G  4 FE cell 

0.059 0.059
b) E  Ecell 
0
log  M n    or  E  Ecell
0
 log C
n n
c)  r G    RT ln K
0.059 0.059
d) E  Ecell 
0
log  M n    or  E  Ecell
0
 log C
n n

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14. The Nernst equation for non-metals is represented by

a)  r G    RT ln K

0.059 0.059
b) E  Ecell 
0
log  M n    or  E  Ecell
0
 log C
n n

c)  R G  4 FE cell 

0.059 0.059
d) E  Ecell 
0
log  An    or  E  Ecell
0
 log C
n n

15. Gibb’s energy change in the Galvanic cell  G  and electrode potential of the cell ( Ecell ) are
related as

a) G  nFE cell 

b)  r G    RT ln K

0.059 0.059
c) E  Ecell 
0
log  M n    or  E  Ecell
0
 log C
n n

0.059 0.059
d) E  Ecell 
0
log  An    or  E  Ecell
0
 log C
n n

16. Standard Gibb’s energy change of the reaction   r G 0  and standred electrode potiential of
the cell ( E 0 cell ) are related as ___________

a)  r G 0  nFEcell
0

b)  r G    RT ln K

c) G  nFE cell 

0.059 0.059
d) E  Ecell 
0
log  M n    or  E  Ecell
0
 log C
n n

17. For the general electro chemical reaction of the type aA  bB  cC+dD
a)  r G 0  RT ln K c where, K c is the concentration equilibrium constant.

b)  r G 0   RT ln K c where, K c is the concentration equilibrium constant.

c)  r G 0   RT ln K c where, K c is the equilibrium constant.

d)  r G 0  RT ln K c K c is the equilibrium constant.

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CONDUCTANCE OF ELECTROLYTIC SOLUTION
18. Carbon black, graphite and organic polymers are
a) Non conductors b) Electrolytic conductors
c) Electrical conductors d) Insulaters
19. Equation used to calculate resistance (R) is ___________

1 l
a) G  b) G 
*

R A

G* l
c) K  d) R
R A
20. Equation used to calculate specific conductance (K) =

l 1
a) G. b)
A R

* l G*
c) G d)
A R
21. The formulae used to calculate the conductance is G =

l G*
a) G. b)
A R

* l 1
c) G d)
A R

22. The formulae used to calculate specific resistance    =

RA l G* 1
a) b) G. c) d)
l A R R
23. Units of cell constant

a) ohm 1.Cm 1 b) Cm 1 (or )m 1

c) mho 1.Cm 2 .mol 1 d) mol.m 3

24. Units of specific conductance (K)
a) ohm 1.Cm 1

b) mho.Cm 1

c) ohm 1.m1 (or ) S .m1

d) All
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25. Molar conductivity  m

K
a) where, K is expressed in Sm 1 and concentration C in mol.m 3
C

K
b) where, K is expressed in Sm 1 and concentration C in mol.m 2
C

K
c) where, K is expressed in Sm 1 and concentration C in mol.m 1
C

K
d) where, K is expressed in Sm 1 and concentration C in mol
C

26. Units of molar conductivity  m

a) ohm 1.Cm 1 b) mho.Cm 1

c) ohm 1.Cm 2 .mol 1 (or ) S .Cm 2 .mol 1 d) Sm 1

27. 1 S m2mol-1
a) 10-4 S m2 mol-1 b) 104 S cm2 mol-1
c) 106 S m2 mol-1 d) 106 S cm2 mol-1
28. 1 S cm2mol-1
a) 10-4 S m2 mol-1 b) 104 S cm2 mol-1
c) 106 S m2 mol-1 d) 106 S cm2 mol-1

29. ^ m ( S .cm 2 .mol 1 ) 

K ( S .cm2 )
a)
1000( L.m 3 )  molarity (mol.L1 )

K ( S .cm2 )
b)
1000( L.m 1 )  molarity (mol.L2 )

K ( S .cm1 )
c)
1000( L.m 3 )  molarity (mol.L1 )

K ( S .cm 2 )
d)
1000( L.m)  molarity ( mol.L)

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30. Cell constant  G*  =
a) Conductivity / resistance b) Conductivity + resistance
c) Conductivity - resistance d) Conductivity x resistance
31. What is the effect of dilution, on conductivity________molar conductivity of a solution
a) Decreases, Increases b) Increases, Decreases
c) Increases, Increases d) Decreases, Decreases
32. Limiting molar conductivities of an electrolyte is equal to the sum of the individual contribution of the
anion and the cation of the electrolyte is called
a) Faraday’s first law b) Kohlrausch law
c) Faraday’s second law d) None of these
33. A n electrolyte on dissociation gives V + cations and V- anions then its limiting molar conductivity is

 
0
m

a)  v 0  v 0  ( 0 and 0 are the limiting molar conductivities of the cation and cation )

b)  v 0  v 0  ( 0 and 0 are the limiting molar conductivities of the anion and anion )

c)  v 0  v 0  ( 0 and 0 are the limiting molar conductivities of the cation and anion )

d)  v 0  v 0  ( 0 and 0 are the limiting molar conductivities of the anion and cation )

34. For strong electrolytes, molar conductivity  m 

 0 1


a)  m  AC 2
 where  0 m  limiting molar conductivity. C = concentration of the electrolytic
 
solution.

b)   0m  AC  where  0 m  limiting molar conductivity. C = concentration of the electrolytic solution.

c)  m  AC  where  0 m  limiting molar conductivity. C = concentration of the electrolytic solution.

 1

d)   m  AC  where  0 m  limiting molar conductivity. C = concentration of the electrolytic
2

 
solution.
35. Ratio between molar conductivity and limiting molar conductivity is called
a) Degree of association b) Degree of association and dissociation
c) Dissociation constant d) Degree of dissociation

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36. Dissociation constant of weak acidic electrolyte K a =

C  2m 1
a) 0 0 b)  0  AC 2
 m (m   m ) m

 Cm
c) 0 d) None of these
m

ELECTROLYTIC CELLAND ELECTROLYSIS

37. The amount of any substance that is deposited or liberated at an electrode is directly propor
tional to quantity of electricity passed through the electrolyte
a) Kohlrausch law b) Faraday’s first law
c) Faraday’s second law d) None of these

38. Faraday’s first law mathematical form  w  =

a) Z / it (or ) Z / Q  Z  electrochemical equivalent 

b)  Zit  or  ZQ   Z  electrochemical equivalent 

c)  Zit  or  ZQ   Z  atomic number 

d) Z / it (or ) Z / Q  Z  atomic number 

39. Chemical equivalent weight =
a) Valency/ Atomic mass b) Atomic number / Valency
c) Atomic mass / valency d) Valency / Atomic number
40. One Faraday is equal to
a) 96500 b) 96500 c.mol
c) 96500 c d) 96500 c.mol-1

41. How much charge required for 1 mol of MnO4 to Mn+2

a) 4F b) 5F c) 2F d) 10F
42. Quantity of current in coloumbs
a) W = Zit b) ZQ
c) Q = Current (in amp) x time (in seconds) Q= It d) None of these
43. The amounts of different substances liberated by the same quantity of electricity passing through the
electrolytic solution are proportional to their chemical equivalent weights is __________
a) Faraday’s second law b) Faraday’s first law

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SR. PCM CHEMISTRY CDF MATERIAL
c) Kohlrausch law d) None of these
44. Faraday’s second law mathematical form =

w2 E1 w2 E2
a) w  E b) w  E
1 2 1 1

w1 E w1 E2
c)  1 d) w  E
w2 E2 2 1

45. When an aqueous solution of sodium chloride electrolyses the gases liberated at cathode is
__________ and at anode is __________
a) Cl 2, H2 b)Cl2,Cl2
c) H2,H2 d) H2,Cl2
BATTERIES
46. In a dry cell the space between the electrodes is filled by moist paste is

a) NH4Cl and ZnCl2 b) CuSo4 and ZnCl 2

c) ZnSo4 and ZnCl 2 d) H 2 So4 and ZnCl2

47. Dry cell and Mercury cell the cell potential is approximately
a) 3.0V, 4.00 V b) 2.5 V, 2.70V
c) 1.5V,1.35 V d) 1.5 V, 2.35 V
48. ______ cells can be recharged.
a) Primary b) Secondary
c) Both 1 & 2 d) None of these
49. Lead storage battery and Nickel-Cadmium cell ______ cells.
a) Secondary b) Primary
c) Both 1 & 2 d) Fuel cells
50. Lead storage battery recharged ____ is anode and ____is cathode.
a) Carbon rod, Zinc cup
b) lead (Pb); lead dioxide (PbO2)
c) Oxizition, Hydrogen
d) Zinc-mercury amalgam, paste of Hgo and carbon
51. In lead storage battery _____ solution used as Electrolyte
a) 38% of H2SO4
b) 98% of H2SO4
c) 50% of H2SO4
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SR. PCM CHEMISTRY CDF MATERIAL
d) 68% of H2SO4
52. Galvanic cells that convert energy of combustion of fuels like H 2,CH4,CH3OH directly into electrical
energy are called
a) Fuel cells b) Daniel Cells
c) Voltaic Cells d) Galvonic Cells
53. _____catalyst are used in H2and O2 fuel cell.
a) Molybinum b) Iron
c) Platinum (Pt) or Palladium (Pd) d) Aurum
54. ______ solution are used in H2 and O2 fuel cell.
a) Concentrated aqueous Sulphuric acid
b) Concentrated aqueous Hydrochloric acid
c) Concentrated aqueous Nitric acid
d) Concentrated aqueous Sodium hydroxide
CORROSION
55. The natural tendency of conversion of metal into its mineral compound form on interaction with
environment is called
a) Corrosion b) Galvanisition
c) Tinning d) Electro plating
56. The rusting of iron, tarnishing of silver, development of green coating on copper and bronze are
examples of
a) Electro plating b) Galvanisition
c) Tinning d) Corrosion
57. The Corrosion of iron is called
a) Rusting b) Electro plating
c) Galvanisition d) Tinning
58. What is the chemical formulae of rusting of Iron

a) Fe2O3.xH2O b) Fe2 O 4 .xH 2 O

c) Fe3O2 .xH 2O d) Fe3O4 .xH 2O

59. The reaction occuring during rusting of iron at anode

 1 
a) O 2 (g)  4H  (aq)  4e   2H 2 O(l ) b) H 2 O(l )  e  H 2 (g)  OH (aq)
2
2 
c) Fe s   Fe aq   2e d) O 2  2H  (aq)  4e   2OH  (aq)

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KEY
1) a 2) d 3) d 4) a 5) c 6) a 7) b 8) c 9) d 10) b
11) a 12) a 13) b 14) d 15) a 16) a 17) b 18) c 19) d 20) a

21) d 22) a 23) b 24) d 25) a 26) c 27) b 28) a 29) c 30) d

31) a 32) b 33) c 34) a 35) d 36) a 37) b 38) b 39) c 40) d

41) b 42) c 43) a 44) c 45) d 46) a 47) c 48) b 49) a 50) b

51) a 52) a 53) c 54) d 55) a 56) d 57) a 58) a 59) c

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