Solutions to the Conversions

A H2/ Pd/BaSO4 /Quinoline ( Lindlar catalyst) N Friedel Crafts alkylaton

CH3Cl : Methyl carbocation, (Electrophile)
B Ethene O Fuming sulphuric acid ( oleum,H2S2O7), Electrophile is SO3
C HBr P Br2 / AlBr3 : Electrophile is Bromonium ion, Br+
D Aq.KOH Q Friedel Crafts acylation, Ethanoyl chloride (acetyl chloride),
Ethanoyl (acetyl) carbocation, (Electrophile)
E Alc.KOH R Aniline
F Sodium ethoxide, (CH3CH2ONa)Williamson S Benzene diazonium chloride
synthesis
G O3/ Zn-H2O T Cu2Cl2/HCl; Sandmeyer reaction
H AgNO2 U Cu/HCl; Gatterman reaction
I Br2 / CCl4 V KI
J Alcoholic KOH W HBF4 / Heat : Balz Schiemann reaction
K NaNH2 / Mineral oil X CuCN/KCN
L Red hot iron tube,873K Y H3PO2
M Conc.HNO3/Conc and H2SO4: Electrophile is Z H2O ( Steam)
Nitronium ion,

1 KMnO4 /KOH and heat 28 CH3-CH2-CN (Propanenitrile)

2 Chromic acid 29 Propanamide
3 CrO2Cl2 /CS2 and H3O+ (Etards oxidation) 30 Propanoic acid
4 CrO3 / Ac2O and H3O+ 31 Propanoyl chloride
5 Zn-Hg /HCl (Clemmensen reduction) 32 Cl2 /Red P (Hell Volhard Zelinsky (HVZ) reaction)
6 NH2-NH2 , KOH/Ethylene glycol/Heat ( Wolf- 33 H2/Pd/BaSO4 (Rosenmund reduction)
Kishner reduction)
7 NaOH and CO2/H+ (Kolbe’s reaction) 34 LiAlH4 or NaHB4 or H2 / Ni or Pt or Pd
8 H3PO2 35 Propene
9 CHCl3/NaOH and H+ (Reimer-Tiemann 36 Propan-1-ol
reaction)
10 1,4-Benzoquinone 37 Br2/NaOH; (Hoffmann bromamide reaction
11 Cl2/UV/500K 38 CHCl3/KOH; (Carbylamine reaction)
12 Cl2/Anhydrous AlCl3/Dark/Cold 39 Zn/HCl or PCl3 or PCl5 or Red P/X2 or SOCl2
13 Benzaldehyde 40 Zn /HCl or Zn-Cu/ Ethanol or
Zn /Acetic acid or LiAlH4
14 Conc.Alkali 41 Ph-Br and Na/Dry ether (Wurtz -Fittig reaction)
15 Cold conc.H2SO4 42 CrO3 / Aq.H2SO4 ( Jones reagent) or pyridinium chlorochromate
(PCC) or PDC ( Pyridinium dichromate)
16 Cold, dil. Aq. KMnO4 (Baeyer’s reagent) 43 PhMgBr
17 Hg2+/H+ 44 I2/KOH ( Haloform reaction)
18 Acetaldehyde 45 HNO3, KMnO4, K2Cr2O7, or mild oxidizing agents like Tollens’
reagent and Fehlings’ reagents
19 Disodium acetylide 46 Dil.Alkali ( Aldol condensation)
20 But-2-yne 47 Na or NaOH or NaHCO3
21 Li or Na / Liq.NH3 48 Methane
22 CH3-I 49 Ethane (Kolbes electrolysis)
23 CH3-CH2-OH 50 Ethyl acetate (Fischer esterification
24 Ethyl ethanoate 51 Acetaldehyde oxime
25 Ethane 52 Zn / Ethyl alcohol
26 NaI (Finkelstein reaction) 53 1,1-Dibromoethane
27 AgF or Hg2F2 or CoF2 or SbF (Swarts reaction) 54 Acetaldehyde