1

ANSWER KEY
Class :11th [JEE MAIN]
DATE : [10.12.2023]
PHYSICS
SECTION - A
Q.1 (1) Q.2 (3) Q.3 (2) Q.4 (3) Q.5 (2) Q.6 (1) Q.7 (3) Q.8 (3) Q.9 (3) Q.10 (1)
Q.11 (4) Q.12 (2) Q.13 (2) Q.14 (2) Q.15 (3) Q.16 (2) Q.17 (1) Q.18 (1) Q.19 (1) Q.20 (1)

SECTION - B
Q.1 [25] Q.2 [10] Q.3 [9000] Q.4 [40] Q.5 [500] Q.6 [400] Q.7 [450] Q.8 [6] Q.9 [150] Q.10 [16]

CHEMISTRY
SECTION - A
Q.1 (2) Q.2 (1) Q.3 (1) Q.4 (3) Q.5 (2 ) Q.6 (2) Q.7 (2) Q.8 (3) Q.9 (2) Q.10 (2)
Q.11 (1) Q.12 (3) Q.13 (1) Q.14 (3) Q.15 (3) Q.16 (2) Q.17 (3) Q.18 (2) Q.19 (2) Q.20 (3)

SECTION - B
Q.1 [4] Q.2 [0] Q.3 [4] Q.4 [4] Q.5 [4] Q.6 [14.5] Q.7 [116] Q.8 [3] Q.9 [32] Q.10 [8]

MATHEMATICS
SECTION - A
Q.1 (2) Q.2 (4) Q.3 (2) Q.4 (3) Q.5 (3) Q.6 (2) Q.7 (1) Q.8 (2) Q.9 (2) Q.10 (1)
Q.11 (3) Q.12 (3) Q.13 (4) Q.14 (3) Q.15 (1) Q.16 (1) Q.17 (1) Q.18 (4) Q.19 (1)
Q.20 (2)
SECTION - B
Q.1 [52] Q.2 [53] Q.3 [240] Q.4 [90] Q.5 [540] Q.6 [485] Q.7 [660] Q.8 [4992] Q.9 [77] Q.10 [77]

PHYSICS
1
SECTION - A Again W' = m [(20)2 – (10)2]
Q.1 (1) From P to Q applying work energy theorem 2

1 = 150 m = 3W
mg  l  mv2
2 x2 0.15

Q.3 (2) W =  Fdx   kx dx

P x1 0.05

0.15
800 2 0
 W=  800xdx 
0.05
 x  kx dx
2  0
= 400 [(0.15)2 – (0.05)2] or W = 8J.
v
Q
 dv 
Q.4 (3) P = FV = m   v
v  2gl  2  9.8  dt 
= 4.43 t v
 v2 
Q.2 (3) By work energy theorom

P dt = m 
0

 2 0

1 mv 2 2 2Pt ds 2P
W= m [(10)2 – 0] = 50 m Pt = ,v = ,v= = t
2 2 m dt m

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t
Work done by normal = 0
t

 
2P t dt ;s  t3/2
ds 
m Q.11 (4)
0 0
 
Q.5 (2) The block comes to rest means its velocity at that F .S (2i  3 j  4 k ).(3i  4 j  5k )
P 
point was 3m s–1. t 4
So at that point, kinetic energy of the spring block
system is, 6  12  20
  9.5watt
1 1 0.9 4
 mv 2   0.1  3   0.45J
2
K.E. =
2 2 2 Q.12 (2) Work done is displacing the particle
[ m=0.1kg]  
W= F = r
x 1 3
At displacement , P.E. = T.E.; K.E. = T.E. = (5 î + 3 ĵ + 2 k̂ ). (2 î – ĵ )
2 4 4
= 5 × 2 + 3 × (–1) + 2 × 0
4
So T.E. =  0.45  0.6J = 10 – 3
3 =7J
Q.6 (1) Given,
Q.13 (2) Mass per unit length
and M
=
L
Power=
4
= = 2 kg/m
2
The mass of 0.6 m of chain 0.6 m
= 0.6 × 2 = 1.2 kg
The centre of mass of hanging part
0 .6  0
Q.7 (3) = = 0.3 m
2
Hence, work done in pulling the chain on the table
W = mgh
200
= 1.2 × 10 × 0.3
F(N) 100 = 1.2 × 10 × 0.3
15 30 = 3. 6 J
x(m)
Q.14 (2) K = 5 × 103 N/m
Work = Area of F–x curve x = 5 cm
1 1 1
= 200 × 15 + (200  100)  15 W1 = k × x12 = 5 × 103 × (5 × 10–2)2
2 2 2
= 5250 J = 6.25 J
Q.8 (3) Work = PE
= mg(1 – cos60º) 
W2 = k(x1 + x2)2
2
 1
 1  10   1– 
2 
 = 5J
= × 5 × 103 (5 + 10–2 + 5 × 10–2)2
2
= 25J
Q.9 (3)
Net work done = W2 – W1
Q.10 (1) At x = 2 = 25 –6.25 = 18.75 J
= 18.75 N-m
dy
F2 – = –2x + 4 Q.15 (3) When a force of constant magnitude acts on
dx
F = 20 velocity of particle perpendicularly, then there is no
Stable equation change in the kinetic energy of particle. Hence, kinetic
energy remains constant.
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dU
Q.16 (2) F = – h
dx 30°
Between B and C
dU v 02 sin 2  1
Slope =
dx
= + ve  mg  mv 02 sin 2 
2g 2
So F = –ve i.e. attractive
mv  a    0  1
Q.17 (1) F = ma =    100  = 25 J
T  T  4
Instantaneous power = Fv Q.2 [10] Using work energy theorem,
= ma Wg = K.E.
mv mv v 1
= . at = . .t (10) (g) (5) = (10)v2 – 0
T T T 2
v = 10 m/s
mv 2
= .t
T2
1 1
w (M  m)gh Q.3 [9000] – FS = mv 2  mv 2
Q.18 (1) P   2 2
f t
800  20  .2 2Fs
  320w v2 
10 v= = 9000 m/s
m
Q.19 (1) According to work-energy theorem, Q.4 [40]
W - K = 0
2 kg
(Initial and final speed are zero 2m
Work done by friction + work done by gravity = 0 U= 0


0.5 m 1.5 m
+ mgl sin  = 0 1m 3 m,
– (mg cos) 3 kg
2 1 kg
  cos  = 2 sin 
  = 2 tan 

Q.20 (1) When block strikes the spring, the kinetic energy
of block converts into potential energy of spring From energy conseration
i.e., Ki + Ui = Kf + Uf
1 1  1  3
mv 2  kx 2 0 +  1 10    K f   3 10  
2 2  2   2
– 5 = Kf – 45
mv 2
Or x Kf = 40 J.
k
42 g
25  3 Q.5 [500] a = g=
42
2
9 3 3
   1.5m
100 4 2
2g
v1 = at1 =
When block returns to the original position, again 3
potential energy converts into kinetic energy of the
v2 = at2 = g
blocks, so velocity of the block is same as before but
its sign changes as it goes to mean position. 1
M ( v 2  v1 )
2 2
Hence v = – 3 ms–1 ka =
2
SECTION - B
1  2 4g 2  5g 2 500
× 6 g 
Q.1 [25] U = mgh
= 
2  9  = 3 = 3 J
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Q.6 [400]
10 1
WSpring    mv 2
100 2
1 1
0.5 m – kx 2  – mv 2
2 20

40000   20 
2
10g
k  16 105
10  1
2
Vmin =V
CHEMISTRY
V '  5gR  10  0.5  5m / s
SECTION - A
Conserving linear momentum
Q.1 (2) dsp2 hybridisation gives square planar structure with
m1V = m2 × 5 – m1 × 100
10 10 s, Px, Py and d x 2  y2 orbitals with bond angles of 90°.
V  5  100  V = 400 m/s .
100 100
Q.2 (1)
Q.7 [450] F = (5y + 20) ĵ
Species  Bond order
10
 5y  20  dy  0 (zero) (not possible)
W=  Fdy  
0
Be2

10
O 22   1 (one)
 5y 2  5
=  20y    100  20  10 = 250 + 200 = 450 1
 2 0 2 He2  (Half)
2
J
1
Q.8 [6] Let’s say the compression in the spring by : y. He2  (Half)
2
So, by work energy theorem we have Q.3 (1) sp hybridisation
1 1 2
 mv  ky
2

22 Q.4 (3)
SO2 OH2 SH2 NH3
m
 y  v Bond angle : 119.5° 104.5° 92.5° 106.5°
k
Q.5 (2) Molecular orbital configuration of
4
 y  10 O2 s)2 s)2 s)2 s)2 pZ)2 px)2
100 = py)2 px)1 = py)1
y = 2m
final length of spring = 8 – 2 = 6m 10  6
B. O. = =2
2
Q.9 [150.00] Initial velocity V02 = 2gh O2+   s)2  s)2 s)2 s)2 pZ)2 px)2
 V0 = 2 10  20  20 m / s = py)2 px)1
Now work done by the machnine. 10  5
B. O. = = 2.5
2
1 2
F.x = KE = mv0 O2–  s)2  s)2 s)2 s)2 pZ)2 px)2
2
= py)2 px)2 = py)1
2 1 15
F    400 10  7
10 2 100 B. O. = = 1.5
2
 F = 150
O22–  s)2  s)2 s)2 s)2 pZ)2 px)2
= py)2 px)2 = py)2
Q.10 [16] Work = K.E.
1 10  8
Wfriction + WSpring = 0 – mv 2 B. O. = =1
2 2
Hence increasing order of bond order is :
90  1 2 1 2
–  mv   WSpring   mv O22   O2  O2  O2
100  2  2

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Q.6 (2) Q.13 (1) s is more closer to nucleus i.e., shielding effect 
He2+ s)2 s)1, one unpaired electron distance from nucleus.
H2 s)2 s)0, no unpaired electron s>p>d>f
H2+ s)1 s)0, one unpaired electron
H2– s)2 s)1, one unpaired electron Q.14 (3) Chlorine being the group 17 element has maximum
Due to absence of unpaired electrons, H 2 will be affinity. ‘N’ has zero electron affinity because extra
diamagnetic. stability is associated with exactly half - filled orbitals.
Sulphur has more electron affinity than ‘O’ because
Q.7 (2) the effect of small size of O atom is more than by the
repulsion of electron already present in 2p-orbitals of
Q.8 (3) O atom.
S in SF4 possesses trigonal bipyramidal structure with
sp3 d hybridisation. Q.15 (3) On increasing effective nuclear charge ionic size
S in ground state decreases.
3s 3p 3d
1
rionic Z
eff

3s 3p 3d Q.16 (2)

H H
3
H
sp d hybridisation
B B
S in excited state
H H
H
Q.9 (2) Dipole-dipole interactions occur among the polar
molecules, as polar molecules have permanent dipoles. (Banana bond)
 momentary gain of octet
Q.10 (2)  assumed incomplete octet.
 electron deficient compound.
O O The compound of which central atom has incomplete
octet is known as electron deficient compound. Hence,
(I) H – O – S – S – O – H
B2H6 is electron deficient compound.
O O
No. of -bond = 4 Q.17 (3)
O
Q.18 (2) Cl have more electron gain enthalpy than F
(II) HO – S – OH {due to smaller size of F and 'O' it will show repulsion}
No. of - bond = 1 S have more electron gain enthalpy than O
O O  Order will be O  S  F  Cl
(III) H – O – S – S – O – H
Q.19 (2) Be has filled 2s subshell and the extra electron
O
goes into 2p sub-shell
No. of -bond = 3 Q.20 (3)
II < III < I
SECTION - B
Q.11 (1)
Q.1 [4]
Q.12 (3)
(a) Metallic radii increase in a group from top to Each oxygen atom will form 4 bonds i.e.
bottom.Thus, Li < Na < K < Rb is true(b) Electron O
gain of enthalpy of Cl > F and decreases along a H-bond
H H
group.Thus, I < Br < F < Cl is true.(c) Ionisation
enthalpy increases along a period left to right but due O
Covalent bond
to presence of half-filled orbital in N, ionisation H H
enthalpy of N > O. Thus B < C < N < O is incorrect.
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Q.2 [0] Because CCl4 symmetrical molecule Q.2 (4) Peaches 5 p1 , p2 , p3, p4, p5
Apples 3 a1 , a2 , a3
Q.3 [4]
(a) PCl6– (Coordinate Bond = 1) Hence number of ways = 3C1 × 5C3 = 30
(b) NH3 . BF3 (Coordinate Bond = 1)
(c) HNO3 (Coordinate Bond = 1) Q.3 (2) 4C2 . 12C3 . 43
(d) CO (Coordinate Bond = 1)
Q.4 (3)
Q.4 [4]
Total person = 8 = 8C6 – 5C5 × 3C1 = 28 – 3 =

25

Q.5 (3) If last two digits are 0, 0 the first digit can be filled
in 9 ways.
P4O10 If last two digit are non zero equal like 1 1 then first
digit can not be 0 and 1.
 number of ways = 9 × 8 + 9 = 81.

Q.6 (2) Total number of ways = (2C2 × 2C2 × 4C0) + 2 (2C1

× 2C2 × 4C1) + (2C1 × 2C1 × 4C2)
Q.5 [4] (1s)2 (*1s)2 (2s)2 (*2s)2 (2p2x = 2p2y ) = 1 + 2(8) + 24 = 41
2pz)2 ; number of anti bonding electrons in N2 is 4.
* represents antibonding molecular orbitals. Q.7 (1) Number of letters = 6
Number of vowels = 2 namely A & E. These alphabets
Q.6 [14.5] Generally in a period, IE increases but nitrogen can be arrange themselves by 2! ways
6!
due to the presence of half-filled -subshell (stable  Number of words =  360
configuration) has higher IE as compared to its 2!
Q.8 (2) S1 = {1, 3, 5, 7, 9}
consecutive elements. Thus, the IE of nitrogen is 14.5
S2 = {2, 4, 6, 8, 10}
 5C2 + 5C2 = 20.
Q.7 [116]
Un – 1 Q.9 (2) Required number of ways = number of positive
Un – 1 integral solution of equation x1 + x2 + x3 = 8
Hex – 6 So at no. = 116  ways = 8 1
C31 7 C 2 = 21 ways

Q.8 [3]
Q.10 (1) Total Integers = 999 – 99 = 900
2 Total Integers in which all distinct digits
62
Q.9 [32] Elements in 6th period =    32 9 9 8  648
 2 
So 900 – 648 = 252
Q.10 [8] rA + rA = 10Å ...(i)
rB + rB = 6Å ...(ii) Q.11 (3) S = {1, 2, 3, 4, ….…., 20}  3 nos. a, b, c  (abc)
(i) + (ii) divisible by 4
2(rA + rB) = 16Å = 20C3 – 10C3 – 5C1 · 10C2 = 795.
rA + rB = 8Å
Q.12 (3) A voter can vote one candidate or two or three of
MATHEMATICS four candidates.
SECTION - A  Required number of ways
Q.1 (2) If no two 2's are consecutive then All 3's = 1 = 10C1 + 10C2 + 10C3 + 10C4 = 385
Six 3's and one 2's = 7C1 = 7
five 3's and two 2's = 6C2 = 15 Q.13 (4) Given word is MISSISSIPPI
four 3's and three 2's = 5C3 = 10 Here , I = 4 times, S = 4 times ,
three 3's and four 2's = 4C4 = 1 P = 2 times
Hence number of numbers = 33
7
First arrange letters M, I, I, I ,I P, P in ways
4. 2
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Now arrange (S, S, S, S) in gaps so required number G1 = 4×4×3×2×1= 96 = G2 = G3 = G4
G5 = 5×4×3×2×1= 5! = 120
7!
of ways = 8C4 . 4 ! . 2 ! = 7. 6C4 . 8C4 Total no. of such numbers = 96 × 4 + 120
= 384 + 120 = 504
Q.19 (1) Let there be n men
Q.14 (3) The number of ways in which 4 novels can be se-  nC × 2 = nC × 2C × 2 + 66
2 1 1
lected = 6C4 = 15  n(n – 1) = 4n + 66
 n2 – 5n – 66 = 0
The number of ways in which 1 dictionary can be  (n – 11) (n + 6) = 0
selected = 3C1 = 3  n = 11
4 novels can be arranged in 4 ! ways.
The total number of ways = 15 × 4 ! × 3 = 15 × Q.20 (2) ACHREKAR .........................................
24 × 3 = 1080 8!
Required number of words = 3 × = (12) 7!
2!
Q.15 (1)
Case (I) : SECTION - B
Q.1 [0052]
5Q 8Q Case I : Unit place digits is '0'
4 6
5 5 0

Required ways of first case = 5 C 4  8 C6  140

 Required ways for case (ii) 5 4
Number of numbers = 20
8 7  6
= C5  C5   56
5 8
Case II : Unit place digit is '4' or '6'
3  2 1
Total number of ways = 140 + 56 = 196 4 or 6

Q.16 (1)
4 4 2
Alphabetical order of these letters is B, E, K, R, U Number of numbers 4×4×2 = 32
So, total number of numbers = 32 + 20 = 52
Total words starting with 'B' = 4! = 24
Total words starting with 'E' = 4! = 24 Q.2 [0053]
Total words starting with 'KB' = 3! = 6 P 's = 2 ; O 's = 2 ; A, S, L, R . Now when A is in the
Total words starting with 'KE' = 3! = 6
middle
Total words starting with 'KR' = 3! = 6
Next word will be KUBER (both like  2 ways) + both different
Thus rank of the word "KUBER" = 24 + 24 + 18 + 1  5C2 . 2 ! = 20 ; when O is in the middle
= 67 ( both alike  1 way) + both different
 C2 . 2 ! = 30
6
Q.17 (1) number of different words= 31+22=53
3 5 4 2 1 6
Q.3 [0240] | H | U | E | Y |
M O N D A Y Number of ways = 5C2 × 4! = 10 × 24 = 240
2 3 2 1 0 0
6!
5! 4! 3! 2! 1! 0! Aliter : Number of ways = – 5!
2!
 Rank = (2 × 5! + 3 × 4! + 2 × 3! + 1 × 2!) + 1
= 240 + 72 + 12 + 2 + 1 = 327 = 360 – 120 = 240

Q.18 (4) Q.4 [0090] Total number of ways in which 6 persons can
Selection of digit can be be arranged = 6!
G –1 0, 1, 2, 3, 6 Sum = 12 Number of ways when wife is always ahead of his
G –2 0, 1, 3, 4, 7 Sum = 15 6!
G –3 0, 1, 4, 6, 7 Sum = 18 husband
G –4 0, 2, 3, 6, 4 Sum = 15
2! 2! 2! = 90.
G –5 1, 7, 3, 4, 6 Sum = 21
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Q.9 [0077] Possible cases are
6!
Q.5 [0540] = 180 ××××××5 7!
2! 2! 3211111   42
5!
6!
= 360 7!
2! or 2 2 2 1 1 1 1   35
4!·3!
Number of distinct ways= 180 + 360 = 540
 number of 7 digits number is 42 + 35 = 77
Q.6 [0485]
Q.10 [0077]
4L 3L Method - 1
Man – 7 ; Wife – 7 Case -1
3G 4G Delegation consists of 5 members
3L and 3G are to be invited. (a) 1 Boy + 4 Girls 2C × 6C = 30
1 4
Man’s Wife’s Total Ways (b) 2 Boys + 3 Girls 2C × 6C = 20
2 3
3L 3G 4C · 4C = 16
3 3
3G 3L 3C · 3C = 1
3 3 50
2L + 1G 1L + 2G (4C2 · 3C1) × (3C1 · 4C2) Case -2
= 324 Delegation consists of 6 members
1L + 2G 2L + 1G (4C1 · 3C2) × (3C2 · 4C1) (a) 1 Boy + 5 Girls 2C × 6C =
1 5 12
= 144 (b) 2 Boys + 4 Girls 2C × 6C = 15
2 4
Total = 485. ______

Q.7 [0660] 77 ways

______
xKxAxAxMxNx –xKx AA x M x N x Method - 2
Case -1
5! Deligation consists of 5 members.
6 5
2! × C2 – 4! × C2 Total number of ways of selecting 5 member team –
= 60 × 15 – 240 = 900 – 240 = 660 number of ways when no boy is selected
= 8C5 – 6C5 = 50
Q.8 [4992] Case -2
m = 6! 23 Deligation consists of 6 members  Total - no boy
is selected
H1W1 H 2W2 H 3W3 M1F1 M 2F2 = 8C6 – 6C6 = 27
Total = 50 + 27 = 77
n = 4! · 25 M1F1 M 2F2

H1W1 H 2 W2 H 3 W3
m – n = 23 · 4![30 – 4]
= 8 · 24 · 26 = 4992

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