OM Coaching Classes, Beed

Topic :- Carbon Compounds (DPP) Class :- 11th Science

[C = 12, H = 1, O = 16, M = 14, Na = 23, Ag = 108, Mg = 24, P = 31, Mo = 96,

Br = 80, Cl = 35.5, I = 127, Ba = 137, S = 32. ]

01) 0.25 g of an organic compound gave on

combusion 0.5 g of carbon dioxide and 0.2 06) 0.25 g of an organic sustance was heated with
g of water. Calculate the percentage of car- conc. H2SO4 and then distilled with excess of
bon and hydrogen in it. strong alkali. The ammonia gas evolved was
a) 30.40% b) 20.35% absorbed in 50 mL of M/10 HCl which re-
c) 54.55% d) 65.60% quired 20 mL of M/10 NaOH for
neutralisation at the end of the process. De-
02) An organic compound contains 69% carbon termine the percentage of nitrogen in the
and 4.8% hydrogen, the remainder being compound
oxygen. Calculate the masses of carbon di- a) 16.8 %
oxide and water produced when 0.20 g of b) 9.13 %
this substance is subject to complete combus- c) 25.18%
tion. d) 22.21%
a) 0.0325% b) 0.0426%
c) 0.0666% d) 0.0846% 07) 0.35 g of an organin substance was
Kjeldahlised and the ammonia obained was
03) On combustion of 0.25 g of an organic com- passed into 100 mL of M/10 H2SO4. the ex-
pound gave 0.2 g of carbon dioixide and 0.1 cess acid required 154 mL of M/10 NaOH
g of water calculate the percentage composi- for neutralistion. Calculate the percentage of
tion of carbon and hydrogen in the com- nitrogen in the compound
pound. a) 24.4 % b) 18.4 %
a) 21.81% b) 16.82% c) 12.2 % d) 30.0 %
c) 28.81% d) 40.91%
08) A sample of a 0.50 g of an organic compound
04) In a Duma nitrogen estimation 0.3 g of an was heated acording to Kjeldahl’s method.
organic compound gave 50 mL of nitrogen The ammonia evolved by absorbed in 50 mL
collected at 300 K and 715 mm pressure. of 0.5 M ammonia evolved by absorbed in
Calculate the percentage of nitrogen in the 50 mL of 0.5 M H2SO4. The residual acid re-
compound. (Vapour pressure of water at 300 quired 60 mL of 0.5 M solution of NaOH for
K is 15mm) neutralisation. Find the percentage compo-
a) 21.46% b) 14.48% sition of nitrogen in the compound.
c) 17.46% d) 25.45% a) 39% b) 66%
c) 56% d) 32%
05) During nitrogen estimation of an organic
compound by Kjeidahl method the ammo- 09) 0.15 g of an organic compound gave 0.12 g
nia evolved by 0.5 g of the compound Neu- of AgBr by Carius method. Find the percent-
tralized 10 mL of 1 M H2 SO4. Calculate the age of bromine in the compound.
perentage of nitrogen in the compound. a) 24.04 % b) 44.04 %
a) 35% b) 56% c) 55.06 % d) 34.04 %
c) 65% d) 46%

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10) 0.4 g of an organic compound by Carius 18) In the Carius method of estimation of halo-
method for the estimation of sulphur gave 0.6 gen, 0.08 g of an organic compound gave
g of BaSO4. Calculate the percentage of sul- 0.25 g of AgCl. Find the percentage of chlo-
phur in the compound. rine in the compound.
a) 20.60% b) 30.60% a) 50.34% b) 30.25%
c) 5.60% d) 10.60% c) 18.18% d) 77.30%

11) In sulphur estimation, 0.16 g of an organic 15) Glucose, a simple sugar, is the main compo-
compound gave 0.6 g of barium sulphate. nent of intravenous feeding liquids. Its com-
What is the percentage of sulphur in the com- mon name is dextrose. It is also one of the
pound? products of carbohydrate metabolism. An el-
a) 10.50 % b) 60.50 % emental analysis showed that glucose con-
c) 40.50 % d) 51.50 % tains only C, H and O. A 0.1 g sample of pu-
rified glucose was burned in a C - H combus-
12) 0.25 g of an organic compound ‘X’ contain- tion system to produce 0.15 g of CO2 and
ing carbon, hydrogen and oxygen was 0.06 g of H2O. Determine the % of C, H and
analysed by the combustion method. The O in the glucose.
increase in mass of calcium chloride tube and a) 40.9% , 6.66% and 52.44%
potash bulbs at the end of the experiment was b) 30.9% , 3.66% and 70.44%
found to be 0.15 g and 0.2 g respectively. c) 20.9% , 15.66% and 36.44%
Calculate the percentage of carbon and hy- d) 50.9% , 5.66% and 80.44%
drogen respectively
a) 21.81% and 6.66%
b) 10.81% and 3.66%
c) 30.81% and 12.66%
d) 21.81% and 14.66%

13) 0.25 g of an organic compound was analysed

for nitrogen by Duma’s method. 50 mL of
moist nitrogen was collected at 250C and 755
mm pressure. Calculate the percentage of ni-
trogen in the sample (aq. tension of water at
250C and 24 mm).
a) 9% b) 27%
c) 17% d) 22%

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