Preparatory Test-1, 2024

Chemistry 2nd paper, 2nd Chapter

Topics: Chemistry of Alkane, Amine and Carboxylic acid
Marks: 40 Time: 35 minutes
Date: 02.04.2024
1. Complete the reactions.
Zn + HCl
i. CH3-I + 2[H] A + HI
NO2
Sn + conc. HCl
ii. + [H] B + H2O

Sn + conc. HCl
iii. CH3-N=C + [H] D + H2 O

Strong ox Mild ox ox
iv. G R-OH n=2 E F
n=1

2. Write the chemical equations for preparation of

a) Butane from sodium ethanoate.
b) Propanoic acid from ethyl iodide.
c) Ethanol from ethanoyl chloride.
d) Benzoic acid from benzene diazonium chloride.
e) o-nitroaniline and p-nitroaniline from aniline.

3. Write short answers.

a) What is Grignard reagent?
b) What is secondary amine?
c) What is glacial acetic acid?
d) Why is chloro ethanoic acid stronger than ethanoic acid?
e) Phenyl amine is weaker than methyl amine why?
f) Why dry ether is used in Wurtz reaction?

Multiple Choice Question (15 × 1 =15)

1. Which one is liquid at room temperature?
a) CH4 b) C3H8 c) C10H12 d) C20H42
Answer 2 and 3 based on the reaction.
Pd+BaSO4 Pd; 30 °C
G CH3–C≡CH + H2 E
2. BaSO4 is
a) Positive catalyst b) Negative catalyst
c) Catalyst promoter d) Catalyst poison
3. As per the reaction-
i. E is CH3-CH2-CH3
ii. G is CH3-CH=CH2
iii. In case of Ni 200 °C temp.
Which one is correct? a) i, ii b) ii, iii c) i, iii d) i, ii, iii
Zn.Hg conc. HCl
4. CH3-CO-CH3 + 4[H] CH3-CH2-CH3 + H2O
The reaction is
a) Decarboxylation b) Wurtz-fatigue reaction c) Clemmensen reduction d) Aromatization
5. In Kolbe synthesis of CH3COONa the product produced in cathode is.
a) H2 b) C2H6 c) CO2 d) O2
Answer 6 and 7 as per the reaction.
Br2+NaOH
CH3-CO-NH2 A + CO2
6. A is
a) CH3NH2 b) CH3CH2NH2 c) CH3CH2OH d) NH2-CO-NH2
7. In case of A
i. Basic in nature
ii. Positive carbylamine test
iii. Produces diazonium salt
Which one is correct?
a) i, ii b) ii, iii c) i, iii d) i, ii, iii
LiAlH4
8. R-CN + [H] D ; D is-
a) 1° Amine b) 2° Amine c) 3° Amine d) Aniline
9. Yellow precipitation is produced with HCl + NaNO2 by-
a) 1° Amine b) 2° Amine c) 3° Amine d) Aniline
10. Correct orcer of basic nature of amine is-
a) 1° > 2° > 3° > NH3 b) 2° > 1° > 3° > NH3
c) 3° > 2° > 1° > NH3 d) NH3 > 1° > 2° > 3°
Answer 11 and 12 as per the reaction.
H2O
CO2 + CH3MgI → Intermediate A + Mg(OH)I
11. What is A?
a) CH3OOH b) CH3CHO c) CH3CH2OH d) CH3CH2Cl
12. In case of A-
i. Acidic in nature
ii. Reacts with Na metal
iii. Reddish brown ppt with Fehling solution
Which one is correct?
K) i, ii L) ii, iii M) i, iii N) i, ii, iii
13. Which one is not acidic?
a) CH3CH2OH b) HCOOH c) C6H5OH d) HCN
14. Which one can oxidize Tollen’s reagent?
a) HCOOH b) CH3-COOH c) C6H5-COOH d) ClCH2-COOH
15. The highest value of Ka is for-
a) CCl3-COOH b) CH2Cl-COOH c) CHCl2-COOH d) CH3-COOH