F2 2 B7

KEMENTRIAN RISET, TEKNOLOGI DAN PENDIDIKAN TINGGI
UNIVERSITAS BRAWIJAYA
LABORATORIUM SENTRAL ILMU HAYATI
Jl Veteran, Malang 65145, Indonesia
Telp/Fax. +62341 559054
http://lsih.ub.ac.id Email : laboratoriumsentral@Ub.ac.id ; laboratoriumsentral@gmail.com
Chromatogram F2.2.B7 C:\GCMSsolution\Data\Project1\09122020\F2.2.B7.qgd

TIC
17.472
5,000,000
17.309
15.915
17.695
19.909
20.017
19.130
16.0 17.0 18.0 19.0 20.0 20.5
min
Quantitative Result Table

ID# Name R.Time m/z Area Height Conc. Conc.Unit R.Index
1 .ALPHA.-TERPINOLENE 15.913 41.00 53555 17192 1.553 % 0
2 (-)-Isopulegol 17.308 41.00 54207 17844 1.572 % 0
3 CITRONELLA 17.472 41.00 3232827 879831 93.750 % 0
4 (-)-Isopulegol 17.694 41.00 32319 7429 0.937 % 0
5 DECANAL 19.127 41.00 9329 2781 0.271 % 0
6 .beta.-Citronellol 19.903 41.00 32991 10053 0.957 % 0
7 Z-Citral 20.018 41.00 33108 10114 0.960 % 0
Library
<< Target >>
Line#:1 R.Time:15.915(Scan#:2384) MassPeaks:405
RawMode:Averaged 15.910-15.920(2383-2385) BasePeak:41.05(16506)
BG Mode:Calc. from Peak Group 1 - Event 1 Scan
100 41
80 71
60
69 93
40
20
30 105121 147 164 195211 234249 269 287303 334 354 382 405 423 459475 492507 524 545 569 593 624 655 672 691 720736 769 797
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
Hit#:1 Entry:33854 Library:Wiley9.lib
SI:93 Formula:C10H16 CAS:586-62-9 MolWeight:136 RetIndex:0
CompName:.ALPHA.-TERPINOLENE $$ Cyclohexene, 1-methyl-4-(1-methylethylidene)- (CAS) $$ 1,4(8)-P-MENTHADIENE $$ 1-METHYLENE-4-ISOPROPYLENECYCLOHEXANE $$ Terpino
100 41 71
80
55
93
60
40 80
53
20 121
65 7785 97
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
SI:92 Formula:C10H18O CAS:78-70-6 MolWeight:154 RetIndex:0
CompName:1,6-OCTADIEN-3-OL, 3,7-DIMETHYL- $$ 3,7-DIMETHYLOCTA-1,6-DIEN-3-OL $$ (+-)-LINALOOL $$ (1)-3,7-DIMETHYL-1,6-OCTADIEN-3-OL $$ .BETA.-LINALOOL $$ 1, 6-OC
100 71
41
80
55 93 OH
60
40 27 80
20 53 121
72
65 84 96109 136
31
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
<< Target >>
100 41
80 71
60
69 93
40
20
30 105121 147 164 195211 234249 269 287303 334 354 382 405 423 459475 492507 524 545 569 593 624 655 672 691 720736 769 797
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:1,6-Octadien-3-ol, 3,7-dimethyl-, (.+-.)- (CAS) $$ 1,6-Octadien-3-ol, 3,7-dimethyl-, (.+/-.)- $$ 1,6-OCTADIEN-3-OL, 3,7-DIMETHYL- $$ 3,7-DIMETHYLOCTA-1,6-DIEN-3-OL $$ (+-)-
100 41
80
71
43
60 28
55
93
40 HO
80
20 53
32 77
65 84 96109 136
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:Linalool $$ 1,6-Octadien-3-ol, 3,7-dimethyl- (CAS) $$ Linalol $$ .beta.-Linalool $$ Linalyl alcohol $$ 2,6-Dimethyl-2,7-octadien-6-ol $$ allo-Ocimenol $$ p-Linalool $$ LINOLOOL (D)
100 41
OH
80 71 93
60 43 55
40 27
80
121
20 53 77
31 65 84 96109 136
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:L-LINALOOL $$ 1,6-OCTADIEN-3-OL, 3,7-DIMETHYL- $$ 3,7-DIMETHYLOCTA-1,6-DIEN-3-OL $$ (+-)-LINALOOL $$ (1)-3,7-DIMETHYL-1,6-OCTADIEN-3-OL $$ .BETA.-LINA
100 71
43
80 93
55 OH
60
69
40 80
39
121
20 83
96 136
31 5159
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
<< Target >>
100 41
80 67
55
60
40 71
93
20 31 111 136 154
191206 235251 268 291 313329 359 387 405420436 473 503 526 559 582 599 623 657 684700 727 754 781
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:(-)-Isopulegol $$ Cyclohexanol, 5-methyl-2-(1-methylethenyl)-, [1R-(1.alpha.,2.beta.,5.alpha.)]- (CAS) $$ l-Isopulegol $$ Isopulegol $$ p-Menth-8-en-3-ol, (1R,3R,4S)-(-)- (CAS) $$ iso-P
100 41
80
69
60 55 81
43
40 93 OH
97 111
20 136
65 7785
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
80
60
55 69 81
40 27 43 OH
93
20 57 111 136
85 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:NEOISO(ISO)PULEGOL
100 41
OH
80
55 67
60
43 71 121
27 81 95
40 111
20 57 139
85 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:CYCLOHEXANOL, 5-METHYL-2-(1-METHYLETHENYL)-, [1R-(1.ALPHA.,2.BETA.,5.ALPHA.)]- $$ 2-ISOPROPENYL-5-METHYLCYCLOHEXANOL # $$ (-)-ISOPULEGOL $$ (-
100 41
80
69
55
60 27
29 56 81
40 43 95 121 OH
111 136
20 98 112 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:CITRONELLA $$ 6-Octenal, 3,7-dimethyl- (CAS) $$ Citronellal $$ Rhodinal $$ .beta.-Citronellal $$ 3,7-Dimethyl-6-octenal $$ 2,3-Dihydrocitral $$ 3,7 DIMETHYL 6 OCTENAL $$ Lev
100 41
69
80
60 O
55
40 27 43
95
7181
20 57 111
136 154
85
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
<< Target >>
100 41 69
80
60
55
40 95
20 70
111
30 136 154 192 216 235 263 281 307 330 352 374 392 411 444 463 482 507 528 555 587 604 622 646 663 684 708 734 754 780
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
80
69
60 O
55
40 95
43
27
20 57 71
84 111 136 154
85
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:6-OCTENAL, 3,7-DIMETHYL- $$ (R)-(+)-CITRONELLAL $$ .BETA.-CITRONELLAL $$ 2,3-DIHYDROCITRAL $$ 3,7 DIMETHYL 6 OCTENAL $$ 3,7-DIMETHYL-6-OCTEN-1-AL
100 41
80 69
60 O
40 27 55
95
20 43
81 110
24 59 136 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41 69
80
60 O
55 95
40
84 111
20 136 154
44 59 72 91
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
80 69
60 O
55 95
40
43
20 57 71
84 111
85 136 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41 69
80
60 O
55 95
40
27 43 71 84 111
20 57
154
85 123 155
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
<< Target >>
100 41
80 55 67
60
71
40 84
20 111 136
33 154169185201 232 264 291 321337352 377 402 432 451466 486 511 545 571 600 629 656 684 706 741 762777
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
80
69
60 55 81
43
40 93 OH
97 111
20 136
65 7785
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
80
60
55 69 81
40 27 43 OH
93
20 57 111 136
85 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:NEOISO(ISO)PULEGOL
100 41
OH
80
55 67
60
43 71 121
27 81 95
40 111
20 57 139
85 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
69
80
60 O
55
40 27 43
95
7181
20 57 111
136 154
85
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:CYCLOHEXANOL, 5-METHYL-2-(1-METHYLETHENYL)-, [1R-(1.ALPHA.,2.BETA.,5.ALPHA.)]- $$ 2-ISOPROPENYL-5-METHYLCYCLOHEXANOL # $$ (-)-ISOPULEGOL $$ (-
100 41
80
69
55
60 27
29 56 81
40 43 95 121 OH
111 136
20 98 112 154
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
<< Target >>
100 41 57
80
60
40 70
20 95
30 110 133 151167 195 220 242 274 306 334 353 384400415 432 452 481 513 532 551 579 598 617633 650 671687 711 730 750 770 792
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
CompName:DECANAL $$ CAPRALDEHYDE $$ 1-DECANAL $$ 1-DECANAL (MIXED ISOMERS) $$ 1-DECANAL(MIXED ISOMERS) $$ 1-DECYL ALDEHYDE $$ 3,4-DIHYDRO-5,7-DIHY
100 41
57
80
29
60 O
70
40 82
20 8495 112
31 53 6572 128
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
CompName:Decanal (CAS) $$ n-Decanal $$ Decyl aldehyde $$ Decaldehyde $$ Capraldehyde $$ Aldehyde C10 $$ Decanaldehyde $$ n-Decaldehyde $$ Caprinaldehyde $$ Capric aldehyde $$ Decylic
100 41
29 57
80
60 O
40 70
82
112
20 84 95
53 72 128
31 65
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
CompName:Dodecanal (CAS) $$ n-Dodecanal $$ 1-Dodecanal $$ Lauraldehyde $$ Aldehyde C-12 $$ n-Lauraldehyde $$ Dodecanaldehyde $$ Lauryl aldehyde $$ Lauric aldehyde $$ Dodecyl aldehyde
100 29 41 57
80
60 O
40 82
68
81 96
20 140
15 58 98 123 156
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
100 41
29 57
80
60 O
40 70
82
20 54 95 112
128
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
100 41
43 57
80
60 O
70 82
40
95 112
20 84
53 72
65 123
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
<< Target >>
100 41
80
69
60 55
40
81
20 95
31 109 138153 180195211 227 250 275 307 342 361 391 415 446 474 492 509 531 554 571 595611626 649 676 708 735 767 792
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
CompName:.beta.-Citronellol $$ 6-Octen-1-ol, 3,7-dimethyl- (CAS) $$ Citronellol $$ Rodinol $$ Cephrol $$ 3,7-Dimethyl-6-octen-1-ol $$ 2,3-Dihydrogeraniol $$ BETA-CITRONELLOL $$ D-CITR
100 41
80 69
60 HO
55
40 81
95
27 43 71
20 57 109
85 99 138 156
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
100 41
80 69
60 HO
55 82
40
95
20 27 53 71 109 156
19 86 138
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
100 41
80 69
60 HO
55
40 81
43 71 95
20 27 57 109 156
86 138
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
100 41
69
80
60 HO
55
71
40 28 81
95
29 43
20 57 109 138 156
85
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
100 41
80 69
60 HO
55 81
40 95
43 71
20 57 109 138 156
85 99
10 50 90 130 170 210 250 290 330 370 410 450 490 530 570 610 650 690 730 770
<< Target >>
100 41
80
60 69
40
20 43 81
31 109 134 155 194 215 246 267 305 329 346 374 405 432 451 473 494 514 545561 578 595 612 634 662677 697 722 747 776
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:Z-Citral $$ 2,6-Octadienal, 3,7-dimethyl-, (Z)- (CAS) $$ Neral $$ .beta.-Citral $$ cis-Citral $$ Citral b $$ cis-3,7-Dimethyl-2,6-octadienal $$ (Z)-3,7-Dimethyl-2,6-octadienal $$ citral-b $$
100 41
80 H
60 69
O
40 39
20 53 67
45 77 91 107
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
80 H
60 69
O
40
27
20 94
43 59 77 96 109 134
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:Citral $$ 2,6-Octadienal, 3,7-dimethyl- (CAS) $$ 3,7-Dimethyl-2,6-octadienal $$ 3,7-Dimethyl-1-2,6-octadienal $$ Citral,c&t $$ cis,trans-Citral $$ Geranial $$ NCI-C56348 $$ 3,7-Dimeth
100 41
69
80 H
60
O
40
27 39
84
20 53 67 81 94 109
24 96 137152
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
CompName:2,6-OCTADIENAL, 3,7-DIMETHYL- $$ 2,6-OCTADIENAL, 3,7-DIMETHYL-, (Z)- $$ (2E)-3,7-DIMETHYL-2,6-OCTADIENAL # $$ (2E)-3,7-DIMETHYL-2,6-OCTADIENAL $$ (2E)-
100 41
69
80 H
60
O
40
27 39
84
20 53 67 81 94 109
24 96 137152
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
100 41
80 H
60 69
O
40
20 8494
43 59
105 121 139
20 60 100 140 180 220 260 300 340 380 420 460 500 540 580 620 660 700 740 780
Method
[Comment]
===== Analytical Line 1 =====
[AOC-20i+s]
# of Rinses with Presolvent :2
# of Rinses with Solvent(post) :10
# of Rinses with Sample :2
Plunger Speed(Suction) :High
Viscosity Comp. Time :0.2 sec
Plunger Speed(Injection) :High
Syringe Insertion Speed :High
Injection Mode :Normal
Pumping Times :5
Inj. Port Dwell Time :0.3 sec
Terminal Air Gap :No
Plunger Washing Speed :High
Washing Volume :8uL
Syringe Suction Position :0.0 mm
Syringe Injection Position :0.0 mm
Solvent Selection :only A
[GC-2010]
Column Oven Temp. :40.0 °C
Injection Temp. :250.00 °C
Injection Mode :Split
Flow Control Mode :Pressure
Pressure :24.9 kPa
Total Flow :143.7 mL/min
Column Flow :0.70 mL/min
Linear Velocity :30.2 cm/sec
Purge Flow :3.0 mL/min
Split Ratio :200.0
High Pressure Injection :OFF
Carrier Gas Saver :OFF
Splitter Hold :OFF
Oven Temp. Program
Rate Temperature(°C) Hold Time(min)
- 40.0 3.00
5.00 250.0 5.00
< Ready Check Heat Unit >

Column Oven : Yes
SPL1 : Yes
MS : Yes
< Ready Check Detector(FTD/BID) >
< Ready Check Baseline Drift >
< Ready Check Injection Flow >
SPL1 Carrier : Yes
SPL1 Purge : Yes
< Ready Check APC Flow >
< Ready Check Detector APC Flow >
External Wait :No
Equilibrium Time :3.0 min
[GC Program]
[GCMS-QP2010 Ultra]
IonSourceTemp :200.00 °C
Interface Temp. :250.00 °C
Solvent Cut Time :0.50 min
Detector Gain Mode :Relative to the Tuning Result
Detector Gain :1.04 kV +0.00 kV
Threshold :0
[MS Table]
--Group 1 - Event 1--
Start Time :4.00min
End Time :50.00min
ACQ Mode :Scan
Event Time :0.30sec
Scan Speed :3333
Start m/z :30.00
End m/z :800.00
Sample Inlet Unit :GC
[MS Program]
Use MS Program :OFF

F2 2 B7

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F2 2 B7

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KEMENTRIAN RISET, TEKNOLOGI DAN PENDIDIKAN TINGGI

Chromatogram F2.2.B7 C:\GCMSsolution\Data\Project1\09122020\F2.2.B7.qgd

Quantitative Result Table

===== Analytical Line 1 =====

< Ready Check Heat Unit >

Sample Inlet Unit :GC

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