Professional Documents
Culture Documents
Energy
journal homepage: www.elsevier.com/locate/energy
a r t i c l e i n f o a b s t r a c t
Article history: In order to reduce the cost of thermal energy recovery, a packed bed closed loop thermal energy storage
Received 21 November 2013 system has been proposed and is investigated. The main components of the system include a closed air
Received in revised form cycle, a heat exchanger, and a packed bed storage column. This paper is aimed at analyzing the per-
22 September 2014
formance of the packed bed in the system. Packed bed column experiments have been carried out to
Accepted 27 September 2014
provide a basic understanding of the thermal energy storage process in the closed loop system with
Available online 23 October 2014
different flow directions in the packed bed and different energy storage temperatures. The detailed
temperature distributions in the interior of the packed bed and the temperature differences along the
Keywords:
Thermal energy
axial and radial directions are presented. The influence of flow direction within the packed bed and
Packed bed structure of the gas distributer on the temperature distribution are also analyzed. The performance of
Closed loop packed beds in the closed loop thermal energy storage system is then evaluated based on energy and
Energy efficiency exergy analyses. These experimental results would be useful in the optimal design of the structure of
Exergy efficiency packed bed columns and thus closed loop thermal energy storage systems.
© 2014 Elsevier Ltd. All rights reserved.
1. Introduction coefficient as a function of the surface area to volume ratio, and cost
[5e7].
In energy systems, where a temporal difference exists between Herrmann [5] and Hasnain [8] reviewed the development of
the supply of energy and its utilization, thermal energy storage is available sensible heat energy storage materials and techniques.
necessary to ensure the continuity of many thermal processes, and Sensible heat storage is divided into two classifications based on
is of particular interest and significance in solar thermal applica- heat storage media: liquid media storage (such as water, oil based
tions [1,2]. Thermal energy storage systems are classified into three fluids, molten salts etc.), and solid media storage (such as rocks,
types: sensible heat storage, latent heat storage, and thermo metals and others). In liquid media storage, water has a higher
chemical heat storage. Among the three types of thermal energy specific heat than other materials, and while it is cheap and widely
storage, sensible heat storage is the most simple and inexpensive. available, it cannot be used above 100 C due to its high vapor
Although phase change energy storage has a few advantages over pressure. Silicone oil is quite expensive, though it does have the
sensible heat storage, the technological and economic aspects of environmental benefit of being a non-hazardous material while
sensible heat storage make it superior [2,3]. Sensible heat storage synthetic oils usually fall under the hazardous materials classifi-
systems commonly use rocks, water, oil, or salt as the storage cation. And the expense would decrease significantly by the oil/
medium and are available for short and long-term storage [4]. For a pack bed system. Mawire [9] experimentally measured the volu-
material to be useful in a sensible heat energy storage application, it metric heat transfer coefficient between oil and glass pebbles. At
must be inexpensive and have a good thermal capacity. In addition present, molten salt is considered a mature energy storage tech-
to the density and specific heat of the storage material, other nology with well understood costs. Unfortunately, the costs for a
properties key to sensible heat storage include: operational tem- molten salt thermal energy storage system are still high. Moreover,
peratures, thermal conductivity and diffusivity, vapor pressure, molten salt is highly corrosive and can be difficult to contain at high
chemical compatibility of the materials, stability, heat loss temperatures; an important factor as utilities tend to be notoriously
reticent when it comes to investing in high risk projects [10,11]. In
addition, molten salt generally has a higher melting point, and
* Corresponding author. Tel.: þ86 10 82543148.
parasitic heating is required to keep it liquid at night, during low
E-mail address: chen_hs@iet.cn (H. Chen). insolation periods, or during plant shutdowns. In solid media
http://dx.doi.org/10.1016/j.energy.2014.09.073
0360-5442/© 2014 Elsevier Ltd. All rights reserved.
872 L. Chai et al. / Energy 77 (2014) 871e879
storage, rock is a good sensible heat storage material due to its wide air cycle, the heat exchanger, and the packed bed storage column
available temperature range, good mechanical properties, long as the three main components of the newly proposed storage
term stability under thermal cycling, compatibility with its system. In the closed air cycle, the air is circulated by a centrifugal
containment and, most importantly, low cost. Difficulties such as fan to absorb the heat from the heat exchanger and carry the heat
the high vapor pressure of water and the limitations of other liquids into the packed bed storage column. The centrifugal fan with
can be avoided by storing thermal energy as sensible heat in rocks. frequency converter is used to adjust the speed of the closed air
Moreover, solids do not leak from their container [12]. stream and to increase the pressure of the closed air stream to
Kelly [13] studied the thermal storage commercial plant design preserve the circulation in the cycle. A plate-fin heat exchanger is
of two-tank indirect molten salt systems and found that the costs of used to transfer the heat from the primary heat transfer fluid to
two tank systems were dominated by the salt expense, which could the closed air cycle. The plate-fin heat exchanger uses plates and
account for as much as 49% of the system's capital cost. In order to finned chambers to transfer heat between fluids and is often
reduce the cost of two-tank storage systems, several schemes categorized as a compact heat exchanger to emphasize its rela-
involving stratification in liquid tanks and packed beds have been tively high heat transfer surface area to volume ratio. The packed
proposed [14e16]. In these storage systems, the molten salt flows bed storage column provides efficient thermal storage due to its
uniformly through the packed bed made up of randomly packed high heat transfer effectiveness, which is also simple in design and
particles, and then through a recovery operation. Considering the relatively inexpensive. When the hot air flows through the packed
potential for further cost reductions, we propose a closed loop bed, heat is stored in its pebbles. Direct contact between the
thermal energy storage system with a rock packed bed substituted pebble and the closed air minimizes the cost of heat exchange
for the molten salt solar energy storage system. In the newly pro- with the solid storage medium. Furthermore, the use of rocks for
posed storage system, air is used as an intermediate heat transfer thermal storage provides advantages such as being both non-toxic
fluid, and distributes the energy transferred from the primary HTF and non-flammable, as well as acting as both heat transfer surface
(heat transfer fluid) throughout the storage volume at low veloc- and storage medium.
ities with the advantages of low expense (much lower cost of The packed bed storage set-up used in this newly proposed
thermal storage material), less pump power of HTF and high reli- storage system is shown in Fig. 1(b). The cylinder was made of
ability (no corrosion and blockage under low temperatures). In this stainless steel, had an interior diameter of 800 mm, an external
paper, we will begin with a brief description of the process using diameter of 820 mm, and a height of 1500 mm. The cylinder must
the closed loop thermal energy storage system in the next section both contain the storage material and prevent the loss of thermal
and then examine the more comprehensive experimental infor- energy. In order to decrease the heat loss and heat absorption of the
mation regarding the temperature field of the interior of the packed stainless steel wall, 100 mm thick magnesium silicate wool was
bed. Lastly, energy and exergy analyses are performed based on the wrapped around the internal and external wall of the cylinder. In
experiment's results, investigating the performance of the packed addition, both sides of the thermal insulation layer were coated
bed. with silver paper to reduce the radiation heat loss. Thus, the final
interior diameter of the packed bed column (bed area) used to
2. Description of closed loop thermal energy storage system contain the porous media was 600 mm. The granite pebbles,
with rock packed bed serving as the thermal energy storage medium, were packed into
the cylinder in a random manner. The thermal energy was stored in
The design of the thermal energy storage system under the packed bed by forcing heated air into the bed, and was utilized
investigation is described in Fig. 1(a). This figure shows the closed again by recirculating the cooled air back into the heated bed.
Fig. 1. Thermal energy storage system: (a) closed loop, (b) Packed bed.
L. Chai et al. / Energy 77 (2014) 871e879 873
3. Experimental setup
the electric heater flowed into the heat exchangers in the opposite
direction of the charging process, absorbed the heat from the closed
thermal energy storage cylinder. The Pt100 platinum-thermal re-
air cycle, and was then discharged directly into the atmosphere
sistors had an accuracy of ±0.1 C in the 200 C to 450 C range.
after being measured for temperature, pressure, and volume flow
The volumetric flow rates of the primary dry air and the closed loop
rate. In the closed loop air cycle, the direction of circulation of the
air were measured by two Collihigh vortex flow meters with a
closed air was in the opposite direction of the charging process. The
range of 36e320 m3/h and accuracy of ±1%. All gas flow rates and
cooled air from the heat exchanger was drawn into the vacuum
temperature signals were collected by a data acquisition system
centrifugal fan, got power for recirculation, flowed through and
(cDAQ, National Instruments) with four NI9203 series digital
absorbed the heat from the packed bed, and then transferred the
output and relay modules inside a PC.
heat to the primary dry air. In order to decrease heat loss to the
Prior to the performance study of the packed bed in the closed
surroundings, high quality heat insulation material was wrapped
loop thermal energy storage system, the thermal properties of the
around the heat exchanger, the electric heater, the tube down-
pebble in the packed bed were first measured. The average equiv-
stream of the electric heater, and the pipe of the closed loop.
alent diameter and specific surface area of the pebble analyzed by
The temperature profiles in the packed bed were measured with
the Germany Retsch Camsizer were 9 mm and 0.672 mm-1
Pt100 platinum-thermal resistors embedded at the proper loca-
respectively. The average pebble density was tested as 2688 kg/m3
tions as shown in Fig. 1(b). The top-most thermal resistor was
by a Mettler Toledo analytical balance. The relationship between
placed a distance of 188 mm below the top of the packed bed and
the specific heat capacity and temperature measured by the TA DSC
the bottom-most thermal resistor was placed a distance of 186 mm
Q2000 was as follows:
above the bottom of the packed bed, and the other thermal re-
sistors used in measuring the central axial temperature distribu-
cp ¼ 0:00248$T þ 0:691 (1)
tions were distributed at equal distances of 188 mm along the
height of the storage tank. For the radial temperature distributions, All the measured data points fell well within ±3% of the corre-
three thermal resistors were installed at equal distances of 150 mm lating equation.
in two planes at depths of 564 and 752 mm, respectively. Lastly, In the experiments, for better heat transfer characteristics, the
two thermal resistors were installed in the inlet and outlet of the heat exchanger adopted the counter flow style, the mass flux of the
primary heat transfer air and the closed loop air were both
133.55 kg/h. The gas inlet temperature of the heat exchanger (Tin,ex)
was set to 75, 110, and 145 C. The flow direction of the closed loop
air in the packed bed was either upwards or downwards.
Fig. 4. Transient axial temperature distribution with hot gas downwards and cold gas
upwards as Tin,ex ¼ 75 C. Fig. 6. Transient axial temperature difference for discharging process as Tin,ex ¼ 75 C.
L. Chai et al. / Energy 77 (2014) 871e879 875
more apparent when the hot gas flows upwards than downwards.
These phenomena can be attributed to the thermal conduction of
the packed bed and the structure of the gas distributer. The thermal
conductivity of a packed bed is thus not merely a material property,
but depends on the flow and heat transfer conditions and the size
and shape of its particles as well [18]. Therefore, this property is
called ‘the effective thermal conductivity’, which contains the effect
of natural convection. When the hot or cold gas flows through the
packed bed, three regions take shape: a cold region, a hot region,
and a temperature gradient region. For the hot gas flowing upwards
case, the larger velocity resulting from the natural convection leads
to a larger Reynolds number and thus a higher forced convective
heat transfer coefficient, causing the temperature gradient region
to be thinner and the gradient larger. As the charging process
continues, in the presence of the temperature gradient, energy
transfer by conduction occurs in the direction of decreasing tem-
perature, and when the temperature gradient region becomes
thicker, the gradient becomes smaller and more gradual, and the
temperature difference decreases at a slightly slower rate. Fig. 7. Transient axial temperature distribution with hot gas upwards and cold gas
Furthermore, the structure of the distributer at the bottom better downwards as Tin,ex ¼ 110 C.
facilitates the temperature variation for the gas flowing upwards,
and as the variation tendency is in accord with that resulting from
natural convection in the charging progress, thus the changing hot gas flowing upwards and the cold gas flowing downwards
trend is more apparent in the hot gas flowing upwards than cases, the tendencies of temperature change at R ¼ 150 mm coin-
downwards case. In addition, mostly resulting from the natural cide closely with those at R ¼ 0; however, those at R ¼ 300 mm are
convection, the time for the charging process is shorter and the different. For the hot gas flowing upwards and the cold gas flowing
temperature difference along the axial direction becomes smaller downwards cases, the temperature at R ¼ 300 mm firstly changes
as the charging process finishes for the hot gas flowing upwards as the gas reaches it, but the overall temperature change is less than
case than downwards. As shown in Fig. 6, in the discharging pro- those at R ¼ 0 and 150 mm. As shown in Fig. 11, the direction of gas
cess, along the axial direction of cold gas flow, the amplitude of flow has significant influence on the transient radial temperature
temperature difference decreases gradually, and the time span profiles. For the hot gas flowing downwards and the cold gas
becomes larger, but the difference in trends between the gas flowing upwards cases, the temperatures at different radial loca-
flowing upwards and downwards cases is not pronounced. The tions change almost as soon as the gas reaches them, and, the rate
energy transfer by conduction with time results in the decline of of temperature decreases or increases, respectively, as the radius
the amplitude of temperature difference and the broadening of the increases. The above tendencies of temperature change can be
time span. For the cold gas flowing downwards case, the natural attributed to the combination of porosity distribution and the
convection results in a larger amplitude of temperature difference structure of the distributer. The disturbance of the statistical par-
and a narrower time span, but the structure of the distributer at the ticle arrangement adjacent to the wall creates a higher void fraction
top leads to a uniform velocity distribution, and thus limits the than that in the interior of the packed bed, according to the
above mentioned tendencies in contrast to those when the dis- experimental observations by Bey et al. [19] and Ding et al. [20].
tributer is at the bottom. For the cold gas flowing upwards case, This creates higher velocity conditions near the wall, which is of
while the effect of natural convection is weak, the structure of the importance to the local flow, heat, and mass transfer in this region
distributer at the bottom leads to a higher gas velocity at the center and thus leads to earlier temperature variation at R ¼ 300 mm
and results in a larger amplitude of temperature difference and a
narrower time span. Therefore, there is no significant difference
between the cold gas flowing upwards and downwards cases in the
discharging process.
The axial temperature profiles with respect to time for
Tin,ex ¼ 110 and 145 C are shown in Figs. 7 and 8, respectively. In
contrast with Fig. 3, where Tin,ex ¼ 75 C, while the variation ten-
dency of axial temperature is accordant, the rates of temperature
rise and drop differ. At higher energy storage temperatures, due to
the presence of a larger temperature gradient, a larger mass density
gradient arises and thus the natural convection has a more signif-
icant influence on the thermal energy storage process. Fig. 9 pre-
sents the temperature difference DT43 for different energy storage
temperatures. With an increase in energy storage temperature, the
axial temperature difference increases and the rate of temperature
rise and drop increases, but the time span of the temperature
gradient increases only slightly.
The radial temperature profiles at L ¼ 564 and 752 mm for Fig. 8. Transient axial temperature distribution with hot gas upwards and cold gas
Tin,ex ¼ 75 C are shown in Figs. 10 and 11. As shown in Fig. 10, in the downwards as Tin,ex ¼ 145 C.
876 L. Chai et al. / Energy 77 (2014) 871e879
Fig. 9. Transient axial temperature difference as Tin,ex ¼ 75, 110, 145 C. Fig. 11. Transient radial temperature distribution with hot gas downwards and cold
gas upwards as Tin,ex ¼ 75 C.
Fig. 10. Transient radial temperature distribution with hot gas upwards and cold gas
downwards as Tin,ex ¼ 75 C. Fig. 12. Transient radial temperature difference for charging process as Tin,ex ¼ 75 C.
L. Chai et al. / Energy 77 (2014) 871e879 877
Fig. 15. Transient radial temperature distribution with hot gas upwards and cold gas
Fig. 13. Transient radial temperature difference for discharging process as downwards as Tin,ex ¼ 145 C.
Tin,ex ¼ 75 C.
and thus the temperature differences all decrease. For the cold gas there is a relatively slow heat diffusion process from the packed bed
flowing upwards, the major difference in temperature difference to the insulation layer and a small amount of thermal energy has
profile occurs at the beginning of the discharging process, which been stored in the insulation layer. In the discharge process, when
has no the declining stage, resulting from the different structure of the temperature of the packed bed is lower than that of the insu-
the distributer. The bottom distributer is conical, and there is no lation layer, heat transfers from the insulation layer to the packed
space between the distributer and the packed bed, which leads to a bed very slowly due to its very low thermal conductivity. At a
higher velocity gas flow along the wall and in the center. Therefore, higher energy storage temperature, the temperature of the insu-
there is very little declining stage at the beginning of the dis- lation layer is higher and more thermal energy is stored there, so
charging process and the rapid change of temperature difference the temperature difference near the wall is larger in the discharging
appears much earlier in the gas flowing upwards case than process after the cold gas arrives. Furthermore, Fig. 16 presents the
downwards. temperature differencesDT3b and DTba for different energy storage
The radial temperature profiles with respect to time for temperatures. As shown in Fig. 16, as energy storage temperature
Tin,ex ¼ 110 and 145 C are shown in Figs. 14 and 15, respectively. In increases, the temperature difference patterns remain similar, but
general, the variation tendencies of the radial temperatures are in the amplitude of variation becomes greater, with the temperature
accordance with those when Tin,ex ¼ 75 C due to the gas mass rate differences also becoming greater as the charging and discharging
and flow direction being the same. It also can be observed that the processes come to their conclusions.
temperature near the wall gradually becomes higher than that in
the interior of the packed bed in the discharging process; a pattern 4.3. Energy and exergy analyses of the packed bed
that becomes more pronounced as the energy storage temperature
increases. This can be explained as follows: in the charging process, A powerful tool in evaluating the performance of a system is the
energy and exergy analysis pertaining to the first and second laws
Fig. 14. Transient radial temperature distribution with hot gas upwards and cold gas
downwards as Tin,ex ¼ 110 C. Fig. 16. Transient radial temperature difference as Tin,ex ¼ 75, 110, 145 C.