Neraca Massa Aktual 17 April 2023

Mixed Feed Gas

1
Feed Gas Mixer Mixed Feed

FRC-1 = 19.7 ton/jam

CH4 = 86.32%
C2 H 6 = 6.35%
C3 H 8 = 0.45%
i-C4H10 = 0.04%
n-C4H10 = 0.01% Syngas to CoMo
i-C5H12 = 0.02% FI-106 = 556 Nm3/hr
n-C5H12 = 0.01% CH4 = 1.14%
C6H14 = 0.08% H2 = 72.25%
CO2 = 6.08% N2 = 26.23%
H2 = 0.00% Ar = 0.38%
N2 = 0.64% Total = 100%
Ar = 0.00%
Total = 100%

1. Input Feed Gas

Inlet
BM BM rata-rata
Komponen Komposisi
kg/kmol % vol kg/kmol
CH4 16 86.32% 13.8112
C2 H 6 30 6.35% 1.9050
C3 H 8 44 0.45% 0.1980
n-C4H10 58 0.04% 0.0232
i-C4H10 58 0.01% 0.0058
n-C5H12 72 0.02% 0.0144
i-C5H12 72 0.01% 0.0072
C6H14 86 0.08% 0.0688
CO2 44 6.08% 2.6752
H2 2 0.00% 0.0000
N2 28 0.64% 0.1792
Ar 40 0.00% 0.0000
 Total 100% 18.888

Flow Rate = FRC-1

BM Campuran x 1000
= 19.7 ton/jam
18.888
= 1041.3 kmol

Inlet
BM
Komponen Komposisi Mol Massa
kg/kmol % vol kmol kg
CH4 16 86.32% 898.87 14381.87
C2 H 6 30 6.35% 66.12 1983.71
C3 H 8 44 0.45% 4.69 206.18
n-C4H10 58 0.04% 0.42 24.16
i-C4H10 58 0.01% 0.10 6.04
n-C5H12 72 0.02% 0.21 14.99
i-C5H12 72 0.01% 0.10 7.50
C6H14 86 0.08% 0.83 71.64
CO2 44 6.08% 63.31 2785.74
H2 2 0.00% 0.00 0.00
N2 28 0.64% 6.66 186.60
Ar 40 0.00% 0.00 0.00
H2O 18 0.00% 2.73 49.14
Total -H2O 100% 1041.32 19717.58

2. Syngas to CoMo
Syngas To CoMo = FI-106
Massa 22.4
= 556 Nm3/hr
22.414
= 24.81 kg/hr

Inlet
BM
Komponen Komposisi Mol Massa
kg/kmol % vol kmol kg
CH4 16 1.14% 0.2828 4.52
H2 2 72.25% 17.9223 35.84
N2 28 26.23% 6.5066 182.18
Ar 40 0.38% 0.0943 3.77
Total 100% 24.81 28.21

Komposisi Inlet Gas Proses

Feed Gas Syngas to CoMo Total Input
Komponen Mol Massa Mol Massa
Inlet Primary
(kmol) (kg) (kmol) (kg) Mol %vol
CH4 898.87 14381.87 0.28 4.52 899.15 84.34%
C2 H 6 66.12 1983.71 66.12 6.20%
C3 H 8 4.69 206.18 4.69 0.44%
n-C4H10 0.42 24.16 0.42 0.04%
i-C4H10 0.10 6.04 0.10 0.01%
n-C5H12 0.21 14.99 0.21 0.02%
i-C5H12 0.10 7.50 0.10 0.01%
C6H14 0.83 71.64 0.83 0.08%
CO2 63.31 2785.74 63.31 5.94%
CO 0.00 0.00 0.00 0.00%
H2 0.00 0.00 17.92 35.84 17.92 1.68%
N2 6.66 186.60 6.51 182.18 13.17 1.24%
Ar 0.00 0.00 0.09 3.77 0.09 0.01%
Total 1041.32 19668.44 24.81 226.32 1066.13 100%
A. Neraca Massa Primary Reformer 101-B

2 Steam = H₂O = 100 %

FRR-315
Rasio S/C = 3.47

P = 30.41 kg/cm²
T = 435.00 °C

Primary
1 Reformer 3
Mixed
Feed Output
Gas Primary
Gambar Blok Diagram Primary Reformer

Komposisi Mixed Feed: Komposisi:

CH4 = 84.34% CH4 = 12.32 %
C2 H 6 = 6.20% CO = 8.10 %
C3 H 8 = 0.44% CO2 = 9.54 %
i-C4H10 = 0.04% H2 = 69.70 %
n-C4H10 = 0.01% N2 = 0.33 %
i-C5H12 = 0.02% Ar = 0.01 %
n-C5H12 = 0.01% Total = 100 %
C6H14 = 0.08% Drivex (Dry Basis)
CO2 = 5.94%
CO = 0.00%
H2 = 1.68%
N2 = 1.24%
Ar = 0.01%
Total = 100%
 Input Primary Reformer
1. Stream 1 (Feed Gas)
Flow In Primary Reformer = 1066.13 kmol

Inlet
BM
Komponen Komposisi Gas Mol Massa
kg/kmol % volume Kmol Kg
CH4 16 84.34% 899.1495 14386.39
C2 H 6 30 6.20% 66.1238 1983.71
C3 H 8 44 0.44% 4.6859 206.18
n-C4H10 58 0.04% 0.4165 24.16
i-C4H10 58 0.01% 0.1041 6.04
n-C5H12 72 0.02% 0.2083 14.99
i-C5H12 72 0.01% 0.1041 7.50
C6H14 86 0.08% 0.8331 71.64
CO2 44 5.94% 63.3122 2785.74
CO 28 0.00% 0.0000 0.00
H2 2 1.68% 17.9223 35.84
N2 28 1.24% 13.1710 368.79
Ar 40 0.01% 0.0943 3.77
Total 100% 1066.13 19894.76

Stream 2 (Steam)
Rasio S/C = 3.47
Carbon Number= 0.989
Inlet Steam = Rasio S/C x Carbon Number x Total Flow x Mr H2O
= 3.47 x 0.989 x 1066.13
= 3657.719 kmol

Tabel Komposisi Steam

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
H2O 18 100 3657.72 65838.95
Total 100 3657.72 65838.95
 Komposisi Total Input (Stream 1+2) Primary Reformer
BM % volume Mol Massa
Komponen
(kg/kmol) (kmol) (kg)
CH4 16 19.03% 899.1495 14386.39
C2 H 6 30 1.40% 66.1238 1983.71
C3 H 8 44 0.10% 4.6859 206.18
n-C4H10 58 0.01% 0.4165 24.16
i-C4H10 58 0.00% 0.1041 6.04
n-C5H12 72 0.00% 0.2083 14.99
i-C5H12 72 0.00% 0.1041 7.50
C6H14 86 0.02% 0.8331 71.64
CO2 44 1.34% 63.3122 2785.74
CO 28 0.00% 0.0000 0.00
H2 2 0.38% 17.9223 35.84
N2 28 0.28% 13.1710 368.79
Ar 40 0.00% 0.0943 3.77
H₂O 18 77.43% 3657.72 65838.95
Total 100% 4723.84 85733.71

Output Primary Reformer

2. Stream 3
a. Menghitung Neraca Atom Input
Tabel Neraca Atom Input Primary Reformer
Komponen Mol C H O
kmol kmol kmol kmol
CH4 899.15 899.15 3596.60 0.00
C2 H 6 66.12 132.25 396.74 0.00
C3 H 8 4.69 14.06 37.49 0.00
n-C4H10 0.42 1.67 4.17 0.00
i-C4H10 0.10 0.42 1.04 0.00
n-C5H12 0.21 1.04 2.50 0.00
i-C5H12 0.10 0.52 1.25 0.00
C6H14 0.83 5.00 11.66 0.00
CO2 63.31 63.31 0.00 126.62
CO 0.00 0.00 0.00 0.00
H2 17.92 0.00 35.84 0.00
N2 13.17 0.00 0.00 0.00
 Ar 0.09 0.00 0.00 0.00
H₂O 3657.72 0.00 7315.44 3657.72
Total 4723.84 1117.41 11402.73 3784.34

b. Menghitung Output Primary Reformer

% Total atom C output = 12.32 % + 8.10 % + 9.54 %
= 29.96 %

Neraca Karbon
Mol CH4 %CH4 Output
= x Total atom C input
Output %Total atom C output
12.32 %
= x 1117.4100
29.96 %
= 459.50 kmol

Mol CO₂ %CO₂ Output

= x Total atom C input
Output %Total atom C output
= 9.54 %
x 1117.4100
29.96 %
= 355.81 kmol

Mol CO %CO Output

= x Total atom C input
Output %Total atom C output
= 8.1 %
x 1117.4100
29.96 %
= 302.10 kmol

Atom O masuk = Atom O kelua

3784.34 = Atom O pada CO + Atom O pada CO₂+
Atom O Pada H₂O
3784.34 = 302.1 kmol + 2 x 355.81 kmol
Atom O Pada H₂O
= 3784.3 kmol - 1013.73 kmol
= 2770.6 kmol
Atom O Pada H2O
Maka,
H₂O Keluar = Atom O Pada H₂O
= 2770.6 kmol

Atom H Keluar = Atom H input - (Atom H pada CH4 output +

atom H pada H₂O output
 = ### - ( 4 x 459.5 kmol )
( 2 x 2770.6 kmol )
= 11402.7290 kmol - 7379.2198 kmol
= 4023.5 kmol

H₂ Keluar = 4023.5 kmol

2
= 2011.8 kmol

Reaksi :
CH4 H2O CO + 3H2
m: 899.15 + 3657.72
r: 439.65 439.65 439.65 1318.96
s: 459.50 3218.07 439.65 1318.96

CO + H2O CO2 + H2
m : 439.65 3218.07
r: 137.55 137.55 137.55 137.55
s: 302.10 3080.52 137.55 137.55

C₂H₆ + 4H2O 2CO2 + 7H2

m : 66.12 3080.52
r: 66.12 264.50 132.25 462.87
s: 0.00 2816.02 132.25 462.87

C₃H₈ + 6H2O 3CO2 + 10H2

m: 4.69 2816.02
r: 4.69 28.12 14.06 46.86
s: 0.00 2787.90 14.06 46.86

nC₄H₁₀ + 8H2O 4CO2 + 13H2

m : 0.42 2787.90
r : 0.42 3.33 1.67 5.41
s : 0.00 2784.57 1.67 5.41

iC₄H₁₀ + 8H2O 4CO2 + 13H2

m : 0.10 2784.57
r : 0.10 0.83 0.42 1.35
s : 0.00 2783.74 0.42 1.35
 nC₅H₁₂ + 10H2O 5CO2 + 16H2
m : 0.21 2783.74
r : 0.21 2.08 1.04 3.33
s : 0.00 2781.66 1.04 3.33

iC₅H₁₂ + 10H2O 5CO2 + 16H2

m : 0.10 2781.66
r : 0.10 1.04 0.52 1.67
s : 0.00 2780.62 0.52 1.67

C₆H₁₄ + 12H2O 6CO2 + 19H2

m : 0.83 2780.62
r : 0.83 10.00 5.00 15.83
s : 0.00 2770.62 5.00 15.83

Tabel Komposisi Total Output Primary Reformer

BM Mol Mol Massa
Komponen
(kg/kmol) % kmol kg
CH4 16 7.77 459.50 7351.93
CO2 44 6.02 355.81 15655.67
CO 28 5.11 302.10 8458.90
H2O 18 46.86 2770.62 49871.13
H2 2 34.02 2011.75 4023.51
N2 28 0.22 13.17 368.79
Ar 40 0.002 0.09 3.77
Total 100.00 5913.05 85733.71
 Tabel Neraca Massa Primary Reformer
Inlet Outlet
Komponen mol massa mol massa
(kmol) (kg) (kmol) (kg)
CH4 899.1 14386.4 459.5 7351.9
C2 H 6 66.1 1983.7
C3 H 8 4.7 206.2
n-C4H10 0.4 24.2
i-C4H10 0.1 6.0
n-C5H12 0.2 15.0
i-C5H12 0.1 7.5
C6H14 0.8 71.6
CO2 63.3 2785.7 355.81 15655.7
CO 0.0 0.0 302.10 8458.9
H2 17.9 35.8 2770.62 49871.1
N2 13.2 368.8 2011.75 4023.5
Ar 0.1 3.8 13.17 368.8
H₂O 3657.7 65838.9 0.09 3.8
Total 4723.84 85733.71 5913.05 85733.71

% konversi = ( CH₄ masuk - CH₄ keluarx 100

CH₄ masuk
= 14386.4 - 7351.9 x 100
14386.3914
= 48.90 %
B. Neraca Massa Secondary Reformer (103-D)
Basis : 1 Jam Operasi
Udara
5
FRC-3
Steam (H2O) = 100 % 4 Flowrate = 36800 Nm³/jam
FI-51 Komposisi:
Flowrate = 10 ton/jam N₂ = 78.08 %
P = 0.0 kg/cm² O₂ = 20.95 %
T = 773 °C Ar = 0.93 %
Total = 100 %
3
Secondary Reformer
Gas Input Gas Output 6
Secondary Secondary

Gambar Blok Diagram Secondary Reformer

Komposisi: Komposisi:
CH4 = 7.77 % CH4 = 0.66 %
CO = 5.11 % CO = 11.21 %
CO2 = 6.02 % CO2 = 8.19 %
H2O = 46.86 % H2 = 56.77 %
H2 = 34.02 % N2 = 22.91 %
N2 = 0.22 % Ar = 0.26 %
Ar = 0.002 % Total = 100 %
Total = 100 %

1. Input Secondary Reformer

a. Stream 3
Output Primary Reformer = Input Secondary Reformer
Tabel Komposisi Input Secondary Reformer
BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 7.77 459.50 7351.93
CO 28 5.11 302.10 8458.90
CO2 44 6.02 355.81 15655.67
H2O 18 46.86 2770.62 49871.13
H2 2 34.02 2011.75 4023.51
N2 28 0.22 13.17 368.79
Ar 40 0.00 0.09 3.77
 Total 100 5913.05 85733.71
b. Stream 4 (Steam)
Basis : 1 Jam Operasi
Berdasarkan Logsheet PUSRI IV
a. Menghitung Steam Masuk
Flowrate = 1000 kg
10 ton/jam x
1 ton
= 10000 kg/jam

Steam Total Flowrate

=
Masuk BM
10000 kg/jam
=
18 kg/kmol
= 555.56 kmol/jam

b. Menghitung Massa Steam

Massa H₂O = Mol Komponen x BM
= 555.56 kmol x ###
= 10000 kg

Tabel Komposisi Steam

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
H2O 18 100 555.56 10000.00
Total 100 555.56 10000.00

c. Stream 5 (Udara)
Berdasarkan Logsheet PUSRI IV
1 m³ = 1 Nm³
Flowrate = 36800 Nm³/jam x 1 jam
22.4 m³/jam
= 1641.83 kmol

a. Menghitung Fraksi Mol Komponen Gas Masuk dari Udara

Fraksi Mol Mol Komponen (Hougen, hal 36)
=
Komponen Mol Total
20.95
O2 =
100
= 0.2095

b. Menghitung Mol Komponen Udara

Mol Komponen = Mol Total x Fraksi Mol
 O2 = 1641.83 kmol x 0.2095
= 343.96 kmol
c. Menghitung Massa Masing-Masing Komponen Udara
Massa = Mol Komponen x BM
O2 = 343.96 kmol x ###
= 11006.84 kg

Untuk komponen udara yang lain dapat di lihat pada Tabel.LB.7.

Tabel Komposisi Udara
BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
O2 32 20.95 343.96 11006.84
N2 28 78.12 1282.60 35912.75
Ar 40 0.93 15.27 610.76
Total 100 1641.83 47530.35

Tabel Total Input Secondary Reformer

Komponen BM Mol Mol Massa
kg/kmol % kmol kg
CH4 16 5.67 459.50 7351.93
O₂ 32 4.24 343.96 11006.84
CO 28 3.72 302.10 8458.90
CO2 44 4.39 355.81 15655.67
H2O 18 41.01 3326.17 59871.13
H2 2 24.80 2011.75 4023.51
N2 28 15.98 1295.77 36281.54
Ar 40 0.19 15.36 614.53
Total 100 8110.43 143264.06
2. Output Secondary Reformer
d. Stream 6
a. Menghitung Neraca Atom Input Secondary Reformer
Tabel Neraca Atom Input Secondary Reformer
Mol C H O
Komponen
kmol/jam kmol kmol kmol
CH4 459.50 459.50 1837.98 0.00
O₂ 343.96 0.00 0.00 687.93
CO 302.10 302.10 0.00 302.10
CO2 355.81 355.81 0.00 711.62
H2O 3326.17 0.00 6652.35 3326.17
H2 2011.75 0.00 4023.51 0.00
N2 1295.77 0.00 0.00 0.00
Ar 15.36 0.00 0.00 0.00
Total 8110.43 1117.41 12513.84 5027.83

b. Menghitung Output Secondary Reformer

% Total atom C output = 0.66 % + 11.21 % + 8.19 %
= 20.06 %
Neraca Karbon
%CH4 Output
Mol CH₄ Output = x Total atom C input
%Total atom C output
0.66 %
= x 1117.41 kmol
20.06 %
= 36.76 kmol

%CO₂ Output
Mol CO₂ Output = x Total atom C input
%Total atom C output
8.19 %
= x 1117.41 kmol
20.06 %
= 456.21 kmol

%CO Output
Mol CO Output = x Total atom C input
%Total atom C output
11.21 %
= x 1117.41 kmol
20.06 %
= 624.43 kmol
Atom O masuk = Atom O keluar
5027.83 kmol = Atom O pada CO + Atom O pada CO2 +
Atom O Pada H₂O
5027.83 kmol = 624.4 kmol + 2 x 456.2 kmol
Atom O Pada H₂O
= 5027.8263 kmol - 1536.86 kmol
Atom O Pada H₂O = 3490.9699 kmol

Maka,
H2O Keluar = Atom O Pada H2O
= 3490.9699 kmol

Atom H Keluar = Atom H input - (Atom H pada CH4 output +

atom H pada H₂O output)
= 12513.8 kmol - ( 4x 36.8 kmol )
( 2x 3491.0 kmol )
= 12513.84 kmol - 7129.00 kmol
= 5384.8434 kmol
5384.8434 kmol
H2 Keluar =
2
= 2692.4217 kmol

Reaksi :
CH4 + H2O CO + 3H2
m : 459.50 3326.17
r : 422.73 422.73 422.731 1268.19
s : 36.76 2903.44 422.731 1268.19

CO + H2O CO2 + H2
m : 724.83 3326.17
r : 100.40 100.40 100.4 100.4
s : 624.43 3225.77 100.4 100.4
 Tabel Total Komposisi Output Secondary Reformer
Komponen BM Mol Mol Massa
kg/kmol % kmol kg
CH4 16 0.427 36.76 588.23
CO 28 7.251 624.43 17484.18
CO2 44 5.297 456.21 20073.27
H2O 18 40.536 3490.97 62837.46
H2 2 31.264 2692.42 5384.84
N2 28 15.046 1295.77 36281.54
Ar 40 0.178 15.36 614.53
Total 100.00 8611.93 143264.06

Tabel Neraca Massa Secondary Reformer Reformer

Inlet Outlet
Komponen
mol (kmol) massa (kg) mol (kmol) massa (kg)

CH4 459.50 7351.93 36.76 588.23

O₂ 343.96 11006.84 0.00 0.00
CO 302.10 8458.90 624.43 17484.18
CO2 355.81 15655.67 456.21 20073.27
H2O 3326.17 59871.13 3490.97 62837.46
H2 2011.75 4023.51 2692.42 5384.84
N2 1295.77 36281.54 1295.77 36281.54
Ar 15.36 614.53 15.36 614.53
Total 8110.43 143264.06 8611.93 143264.06

% konversi = ( CH₄ masuk - CH₄ keluar) x 100%

CH₄ masuk
= 7351.9 - 588.2 x 100%
7351.9309
= 92.00%
C. Neraca Massa High Temperature Shift Converter (104-D)
Basis: 1 Jam Operasi

P = 38.15 kg/cm² P = 37.88 kg/cm²

Tin = 331.49 °C HTSC Tout = 399.50 °C
6 7
Gas Dari Gas Keluar
Secondary HTSC
Gambar Blok Diagram High Temperature Shift Converter

Komposisi: Komposisi:
CH4 = 0.43 % CH4 = 0.54 %
CO = 7.25 % CO = 1.74 %
CO2 = 5.30 % CO2 = 14.49 %
H2O = 40.54 % H2 = 63.06 %
H2 = 31.26 % N2 = 19.94 %
N2 = 15.05 % Ar = 0.23 %
Ar = 0.178 % Total 100 %
Total 100 %

1. Input HTSC 104-D1

a. (Stream 6)
Output Secondary Reformer = Input HTSC 104-D

Komposisi Input High Temperature Shift Converter

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.43 36.76 588.23
CO 28 7.25 624.43 17484.18
CO2 44 5.30 456.21 20073.27
H2O 18 40.54 3490.97 62837.46
H2 2 31.26 2692.42 5384.84
N2 28 15.05 1295.77 36281.54
Ar 40 0.18 15.36 614.53
Total 100.00 8611.93 143264.06
2. Output HTSC 104-D1
b. (Stream 7)
a. Menghitung Neraca Atom Input HTSC 104-D1
Tabel Neraca Atom Input HTSC 104-D1
Mol C H O
Komponen
kmol/jam kmol kmol kmol
CH4 36.76 36.76 147.06 0.00
CO 624.43 624.43 0.00 624.43
CO2 456.21 456.21 0.00 912.42
H2O 3490.97 0.00 6981.94 3490.97
H2 2692.42 0.00 5384.84 0.00
N2 1295.77 0.00 0.00 0.00
Ar 15.36 0.00 0.00 0.00
Total 8611.93 1117.41 12513.84 5027.83

b. Menghitung Input High Temperature Shift Converter

% Total atom C output = 0.54 % + 1.74 % + 14.49 %
= 16.77 %

Neraca Karbon
%CH₄ Output
Mol CH₄ Output = x Total atom C input
%Total atom C output
0.54 %
= x 1117.41 kmol
16.77 %
= 35.98 kmol

%CO₂ Output
Mol CO₂ Output = x Total atom C input
%Total atom C output
14.49 %
= x 1117.41 kmol
16.77 %
= 965.49 kmol

%CO Output
Mol CO Output = x Total atom C input
%Total atom C output
1.74 %
= x 1117.41 kmol
16.77 %
= 115.94 kmol
Atom O masuk = Atom O keluar
5027.83 kmol = Atom O pada CO + Atom O pada CO2 +
 Atom O Pada H₂O
5027.83 kmol = 115.9 kmol + 2 x 965.49
Atom O Pada H₂O
= 5027.83 kmol - 2046.92 kmol
Atom O Pada H₂O = 2980.91 kmol

Maka,
H2O Keluar = Atom O Pada H2O
= 2980.91 kmol

Atom H Keluar = Atom H input + (Atom H pada CH4 output +

atom H pada H₂O output)
= 12513.8 kmol - ( 4x 36.0 kmol
( 2x 2980.9 kmol )
= 12513.84 kmol - 6105.74 kmol
= 6408.10 kmol
6408.10 kmol
H2 Keluar =
2
= 3204.05 kmol

Reaksi pada High Temperature Shift Converter

CO + H2O CO2 + H2
624.43 3490.97
508.50 508.50 508.50 508.50
115.94 2980.91 508.50 508.50

Tabel Komposisi Output HTSC 104 D1

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.42 35.98 575.70
CO 28 1.35 115.94 3246.29
CO2 44 11.21 965.49 42481.57
H2O 18 34.61 2980.91 53656.33
H2 2 37.20 3204.05 6408.10
N2 28 15.04 1295.77 36281.54
Ar 40 0.18 15.36 614.53
Total 100 8613.50 143264.06
 Tabel Neraca Massa HTSC
Inlet Outlet
Komponen
mol (kmol) massa (kg) mol (kmol) massa (kg)
CH4 36.76 588.23 35.98 575.70
CO 624.43 17484.18 115.94 3246.29
CO2 456.21 20073.27 965.49 42481.57
H2O 3490.97 62837.46 2980.91 53656.33
H2 2692.42 5384.84 3204.05 6408.10
N2 1295.77 36281.54 1295.77 36281.54
Ar 15.36 614.53 15.36 614.53
Total 8611.93 143264.06 8613.50 143264.06

% konversi = ( CO masuk - CO keluar) x 100%

CO masuk
= 624.4 - 115.9 x 100%
624.4350
= 81.43%
D. Neraca Massa Low Temperature Shift Converter (104-D)

Basis = 1 Jam Operasi

P = 27.00 kg/cm² P = 26.30 kg/cm²

Tin = 212 °C LTSC Tout = 221 °C
7 8
Gas Masuk Gas Keluar
LTSC LTSC
Gambar Blok Diagram Low Temperature Shift Converter

Komposisi: Komposisi:
CH4 = 0.42 % CH4 = 0.58 %
CO = 1.35 % CO = 0.19 %
CO2 = 11.21 % CO2 = 17.14 %
H2O = 34.61 % H2 = 61.40 %
H2 = 37.20 % N2 = 20.44 %
N2 = 15.04 % Ar = 0.25 %
Ar = 0.178 % Total 100 %
Total 100 %

1. Input LTSC 104-D2

a. (Stream 7)
Output HTSC 104-D1 = Input LTSC 104-D2

Tabel Komposisi Input Low Temperature Shift Converter

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.42 35.98 575.70
CO 28 1.35 115.94 3246.29
CO2 44 11.21 965.49 42481.57
H2O 18 34.61 2980.91 53656.33
H2 2 37.20 3204.05 6408.10
N2 28 15.04 1295.77 36281.54
Ar 40 0.18 15.36 614.53
Total 100.00 8613.50 143264.06
2. Output LTSC 104-D2
b. (Stream 8)
a. Menghitung Neraca Atom Input LTSC 104-D2
Tabel Neraca Atom Input LTSC 104-D2
Mol C H O
Komponen
kmol/jam kmol kmol kmol
CH4 35.98 35.98 143.92 0.00
CO 115.94 115.94 0.00 115.94
CO2 965.49 965.49 0.00 1930.98
H2O 2980.91 0.00 5961.81 2980.91
H2 3204.05 0.00 6408.10 0.00
N2 1295.77 0.00 0.00 0.00
Ar 15.36 0.00 0.00 0.00
Total 8613.50 1117.41 12513.84 5027.83

b. Menghitung Output LTSC

% Total atom C output = 0.58 % + 0.19 % + 17.14 %
= 17.91 %

Neraca Karbon
%CH₄ Output
Mol CH₄ Output = x Total atom C input
%Total atom C output
0.58 %
= x 1117.41 kmol
17.91 %
= 36.19 kmol

%CO₂ Output
Mol CO₂ Output = x Total atom C input
%Total atom C output
17.14 %
= x 1117.41 kmol
17.91 %
= 1069.37 kmol

%CO Output
Mol CO Output = x Total atom C input
%Total atom C output
0.19 %
= x 1117.41 kmol
17.91 %
= 11.85 kmol

Atom O masuk = Atom O keluar

 5027.83 kmol = Atom O pada CO + Atom O pada CO2 +
Atom O Pada H₂O
5027.83 kmol = 11.9 kmol + 2 x 1069.37
Atom O Pada H₂O
= 5027.83 kmol - 2150.59 kmol
Atom O Pada H₂O = 2877.2333 kmol

Maka,
H2O Keluar = Atom O Pada H2O
= 2877.23 kmol

Atom H Keluar = Atom H input + (Atom H pada CH4 output +

atom H pada H₂O output)
= 12513.8 kmol - ( 4x 36.2 kmol
( 2x 2877.2 kmol )
= 12513.84 kmol - 5899.21 kmol
= 6614.63 kmol
6614.63 kmol
H2 Keluar =
2
= 3307.31 kmol

Reaksi pada Low Temperature Shift Converter

CO + H2O CO2 + H2
35.98 2980.91
24.13 24.13 24.13 24.13
11.85 2877.23 24.13 24.13

Tabel Komposisi Output LTSC 104 D2

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.420 36.19 578.98
CO 28 0.138 11.85 331.92
CO2 44 12.416 1069.37 47052.26
H2O 18 33.405 2877.23 51790.20
H2 2 38.399 3307.31 6614.63
N2 28 15.044 1295.77 36281.54
Ar 40 0.178 15.36 614.53
Total 100.00 8613.09 143264.06
 Tabel Neraca Massa LTSC
Inlet Outlet
Komponen
mol (kmol) massa (kg) mol (kmol) massa (kg)

CH4 35.98 575.70 36.19 578.98

CO 115.94 3246.29 11.85 331.92
CO2 965.49 42481.57 1069.37 47052.26
H2O 2980.91 53656.33 2877.23 51790.20
H2 3204.05 6408.10 3307.31 6614.63
N2 1295.77 36281.54 1295.77 36281.54
Ar 15.36 614.53 15.36 614.53
Total 8613.50 143264.06 8613.09 143264.06

% konversi = ( CO masuk - CO keluar) x 100%

CO masuk
= 115.9 - 11.9 x 100%
115.9388
= 89.78%
D. Neraca Massa Low Temperature Shift Converter (104-D)
Basis = 1 Jam Operasi

Raw Gas
Separator
8 9
Gas Masuk Gas Keluar
Condensate
Flow Condensate (FI-59) = 40.2 ton/jam

Gambar Blok Diagram Low Temperature Shift Converter

Komposisi:
CH4 = 0.42 %
CO = 0.14 %
CO2 = 12.42 %
H2O = 33.41 %
H2 = 38.40 %
N2 = 15.04 %
Ar = 0.178 %
Total 100 %

1. Input Raw Gas Separator

Output Low Temperature Shift Converter = Input Raw Gas Separator
Tabel Komposisi Input Raw Gas Separator
BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.42 36.19 578.98
CO 28 0.14 11.85 331.92
CO2 44 12.42 1069.37 47052.26
H2O 18 33.41 2877.23 51790.20
H2 2 38.40 3307.31 6614.63
N2 28 15.04 1295.77 36281.54
Ar 40 0.18 15.36 614.53
Total 100 8613.09 143264.06
a. Menghitung Kondensat Yang Keluar
Flowrate = 1000 kg
40 ton/jam x
1 ton
= 40200 kg/jam

Steam Total 40200 kg/jam

=
Keluar 18 kg/kmol
40200 kg/jam
=
18 kg/kmol
= 2233.3 kmol/jam

Tabel Komposisi Condensate Keluar

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
H2O 18 100 2233.3 40200
Total 100 2233.3 40200

Tabel Komposisi Output Raw Gas Separator

Inlet Condensate Outlet
Komponen mol massa mol massa mol massa mol
(kmol) (kg) (kmol) (kg) (kmol) (kg) (%)
CH4 36.2 579.0 36.19 578.98 0.57%
CO 11.9 331.9 11.85 331.92 0.19%
CO2 1069.4 47052 1069.4 47052.26 16.76%
H2O 2877.2 51790 2233.3 40200 643.90 11590.20 10.09%
H2 3307.3 6614.6 3307.3 6614.63 51.84%
N2 1295.8 36282 1295.8 36281.54 20.31%
Ar 15.4 614.5 15.36 614.53 0.24%
Total 151877 2233.3 6379.8 103064.06 100%
E. Neraca Massa CO2 Absorber (1101-E)
Basis : 1 Jam
9 Gas Keluar Absorber

Lean Benfield a
8
Gas Masuk CO2 Absorber Semi Lean Benfield b

c
Rich Benfield

Gambar Blok Diagram CO2 Absorber

Komposisi :
CH4 = 0.57%
CO = 0.19%
CO2 = 16.76%
H2O = 10.09%
H2 = 51.84%
N2 = 20.31%
Ar = 0.24%
Total 100%

1. Input CO2 Absorber 1101-E

a. Stream 8
Output LTSC 104-D2 = Input CO2 Absorber 1101-E
Tabel Komposisi Input CO2 Absorber
BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.57% 36.19 578.98
CO 28 0.19% 11.85 331.92
CO2 44 16.8% 1069.37 47052.26
H2O 18 10.1% 643.90 11590.20
H2 2 51.8% 3307.31 6614.63
N2 28 20.3% 1295.77 36281.54
Ar 40 0.2% 15.36 614.53
Total 100% 6379.76 103064.06
2. Output CO2 Absorber
a. Stream 9
Input Absorber = Output Absorber + Output Stripper
Output Absorber = Input Absorber - Output Stripper

Tabel Komposisi Output CO2 Absorber

Komp BM In 1101-E Out 1102-EOut 1101-E Massa Mol
kg/kmol (kmol) (kmol) (kmol) (kg) (%)
CH4 16 36.19 0.75 35.44 567.04 0.71%
CO 28 11.85 0.64 11.21 314.00 0.23%
CO2 44 1069.37 1053.49 15.88 698.51 0.32%
H2O 18 643.90 338.17 305.73 5503.20 6.14%
H2 2 3307.31 9.06 3298.25 6596.50 66.29%
N2 28 1295.77 2.13 1293.64 36221.84 26.00%
Ar 40 15.36 0.11 15.26 610.27 0.31%
Total 6379.76 1404.35 4975.41 50511.36 100%

% konversi = ( CO2 masuk - CO2 keluar x 100%

CO2 Absorber CO2 masuk
= 1069.4 - 1053.5 x 100%
1069.37
= 1.48%

% konversi = ( CO2 masuk - CO2 keluar x 100%

CO2 Stripper CO2 masuk
1069.4 - 15.9 x 100%
1069.37
= 98.52%
2. Inlet Lean Benfield
Basis : 1 Jam
Flow Rate = 200 m3
SG = 1.26
Densitas H2O = 997 kg/m3
Densitas Benfield = SG x Densitas H2O
= 1256.22 kg/m3
Massa Benfield = Flow Rate x Densitas Benfield
= 200 m3 x ###
= 251244 kg

Tabel BM Campuran Lean Benfield

BM Mol BM Campuran
Komponen
(kg/kmol) (%) (kg/kmol)
K2CO3 138 24.8% 34.3
DEA 105 2.8% 2.9
V2O5 182 0.9% 1.7
H2O 18 71.5% 12.9
Total 100% 51.7

Mol Campuran = Massa Benfield

BM Campuran
= 251244 kg = 4860.94 kmol
51.7 kg/kmol

Tabel Komposisi Massa Inlet Lean Benfield

Komponen BM Mol Mol Massa
(kg/kmol) (%) (kmol) (kg)
K2CO3 138 24.8% 1206.5 166495.0
DEA 105 2.8% 134.6 14138.0
V2O5 182 0.9% 44.2 8050.7
H2O 18 71.5% 3475.6 62560.3
Total 100% 4860.9 251244.0

3. Inlet Semi Lean Benfield

Flow Rate = 1005 m3
SG = 1.216
Densitas H2O = 997 kg/m3
Densitas Benfield = SG x Densitas H2O
= 1212.352 kg/m3
Massa Benfield = Flow Rate x Densitas Benfield
= 1005 m3 x ###
= 1218414 kg

Tabel BM Campuran Semi Lean Benfield

BM Mol BM Campuran
Komponen
(kg/kmol) (%) (kg/kmol)
K2CO3 138 21.5% 29.6
DEA 105 2.3% 2.4
V2O5 182 0.8% 1.4
H2O 18 75.5% 13.6
Total 100% 47.0

Mol Campuran = Massa Benfield

BM Campuran
= 1218414 kg = ###
47.0 kg/kmol

Tabel Komposisi Massa Inlet Semi Lean Benfield

Komponen BM Mol Mol Massa
(kg/kmol) (%) (kmol) (kg)
K2CO3 138 21.5% 5566.3 768145.1
DEA 105 2.3% 594.0 62367.6
V2O5 182 0.8% 194.5 35405.2
H2O 18 75.5% 19583.1 352495.8
Total 100% 25937.9 1218413.8

5. Outlet Rich Benfield

Reaksi : K2CO3(l) + CO2(g) + H2O(l) 2KHCO3
Mula : 6772.75 1069.37 23058.67
Reaksi : 1053.49 1053.49 1053.49 2107
Sisa : 5719 15.88 22005.18 2107

Tabel Komposisi Massa Rich Benfield

Komponen BM Mol Mol Massa
(kg/kmol) (kmol) (%) (kg)
K2CO3 138 5719.26 52.06% 789257.90
DEA 105 728.63 5.05% 76505.68
V2O5 182 238.77 2.87% 43455.90
 H2O 18 22005.18 26.13% 396093.19
KHCO3 100 2106.99 13.90% 210698.85
Total 100.00% 1516011.51

Neraca Massa Benfield

Komponen BM Mol Massa Mol Mol
(kg/kmol)Lean Semi Lean Rich Benfield
K2CO3 138 1206 166495 5566.27 768145.13 5719.3
DEA 105 135 14138 593.98 62367.63 728.6
V2O5 182 44 8051 194.53 35405.21 238.8
H2O 18 3476 62560 19583.10 352495.79 22005.2
KHCO3 100 2107.0
Total 4861 251244 25937.88 ### 30798.8
 F. Neraca Massa CO2 Stripper (1102-E)
Gas Keluar Stripper 10

Rich Benfield Kondensat

c
CO2 Stripper
b

Semi Lean b
Gambar Blok Diagram CO2 Absorber

Flow Rate (FR-116) = 25500 m³/jam

Komposisi Outlet :
CH4 = 0.07%
CO = 0.06%
CO2 = 98.8%
H2 = 0.85%
N2 = 0.20%
Ar = 0.01%
Total = 100%

2. Output CO2 Stripper (1102-E)

a. Flow Rate = FR-116
22.4
= 25500 Nm3/hr
22.414
= 1137.7 kmol

Tabel Komposisi Output Stripper

Inlet
BM
Komponen Komposisi Mol Massa
kg/kmol % vol kmol
CH4 16 0.07% 0.75 11.94
CO 28 0.06% 0.64 17.91
CO2 44 98.81% 1053.49 46353.75
H2 2 0.85% 9.06 18.13
N2 28 0.20% 2.13 59.71
Ar 40 0.01% 0.11 4.26
H2O 18 71.5
Total 100% 1066.18 46465.70
 Total -H2O 1066.18

b. Condensate OSBL
Menghitung Condensate Masuk
Flowrate = 1000 kg
4.8 ton/jam x
1 ton
= 4800 kg/jam

Cond Total Flowrate

=
Masuk BM
4800 kg/jam
=
18 kg/kmol
= 266.67 kmol/jam

Tabel Komposisi Condensate

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
H2O 18 100 266.67 4800.00
Total 100 266.67 4800.00
789257.9
76505.7
43455.9
396093.2
210698.8
1516011.5
Perhitungan Neraca Energi Absorber (1101-E)

a Lean Benfield 9 Gas Keluar Absorber

8 10
Gas Masuk Absorber CO2 Absorber Rich Benfield

Semi Lean b

A. Input CO2 Absorber

1. Panas Sensibel Input Gas Absorber (Q1)
Temperatur Input Gas = 109.28 C
= 382.43 K
Temperatur Referensi = 25 C
= 298.15 K
∆T = 84.28 K

Tabel Komposisi Input CO2 Absorber

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.57% 36.19 578.98
CO 28 0.19% 11.85 331.92
CO2 44 16.8% 1069.37 47052.26
H2O 18 10.1% 643.90 11590.20
H2 2 51.8% 3307.31 6614.63
N2 28 20.3% 1295.77 36281.54
Ar 40 0.2% 15.36 614.53
Total 100% 6379.76 103064.06

a. Menentukan CP Input Gas

Cp = A x BT + CT^2 + DT^3
T Input = 382.43 K
 Tabel Kapasitas Panas Komponen Input Gas
Komponen Cp (Kj/kmolK) Cp Inlet
A B C D kJ/kmolK
CH4 19.238 5.21E-02 1.20E-05 -1.1E-08 40.28
CO2 19.78 7.34E-02 5.60E-05 1.71E-08 56.99
CO 30.869 -1.29E-02 2.79E-05 -1.3E-08 29.32
H2 27.143 7.35E-07 -1.4E-05 7.65E-09 25.55
N2 31.15 -1.36E-02 2.68E-05 -1.2E-08 29.23
Ar 20.804 -3.21E-05 5.17E-08 0 20.80
H2O 32.243 1.92E-03 1.06E-05 -3.6E-09 34.32

b. Menentukan Panas Sensibel Input Gas (Q1)

Q = n x Cp x ∆T

Tabel Panas Sensibel Input Gas

Mol Cp Inlet ∆T Q1
Komponen
(kmol) kJ/kmolK (K) (Kj)
CH4 36.19 40.28 122834.2
CO 11.85 56.99 56935.5
CO2 1069.37 29.32 2642716.3
H2O 643.90 34.32 84.28 1862504.7
H2 3307.31 25.55 7122131.9
N2 1295.77 29.23 3191775.3
Ar 15.36 20.80 26931.3
Total 15025829.1

2. Panas Sensibel Lean Benfield

Temperatur Input Lean = 54 C
= 327.15 K
Temperatur Referensi = 25 C
= 298.15 K
∆T = 29 K

a. Menentukan CP Input Gas

Cp = A x BT + CT^2 + DT^3
T Input = 327.15 K
 Tabel Kapasitas Panas Komponen Lean Benfield
Komponen Cp (Kj/kmolK) Cp Inlet
A B C D kJ/kmolK
K2CO3 97.08 9.42E-02 -2.05E-06 7.1E-10 127.70
DEA - - - - 137
V2O5 45.97 1.45E-02 6.20E-07 -1.77E-10 50.77
H2O 32.243 1.92E-03 1.06E-05 -3.6E-09 33.88

b. Menentukan Panas Sensibel Lean Benfield (Q2)

Q = n x Cp x ∆T

Tabel Panas Sensibel Lean Benfield

Mol Cp Inlet ∆T Q2
Komponen
(kmol) kJ/kmolK (K) (Kj)
K2CO3 1206.49 127.70 4468080.2
DEA 134.65 137.00 534956.6
29
V2O5 44.23 50.77 65132.8
H2O 3475.57 33.88 3414357.9
Total 8482527.5

3. Panas Sensibel Semi Lean Benfield

Temperatur Input SL = 123.7 C
= 396.85 K
Temperatur Referensi = 25 C
= 298.15 K
∆T = 98.7 K

a. Menentukan CP Input Gas

Cp = A x BT + CT^2 + DT^3
T Input = 396.85 K

Tabel Kapasitas Panas Komponen Lean Benfield

Komponen Cp (Kj/kmolK) Cp Inlet
A B C D kJ/kmolK
K2CO3 97.08 9.42E-02 -2.05E-06 7.1E-10 134.18
DEA - - - - 137
V2O5 45.97 1.45E-02 6.20E-07 -1.77E-10 51.81
H2O 32.243 1.92E-03 1.06E-05 -3.6E-09 34.44
b. Menentukan Panas Sensibel Semi Lean Benfield (Q3)
Q = n x Cp x ∆T

Tabel Panas Sensibel Lean Benfield

Mol Cp Inlet ∆T Q3
Komponen
(kmol) kJ/kmolK (K) (Kj)
K2CO3 5566.27 134.18 73719849.3
DEA 593.98 137.00 8031703.7
98.70
V2O5 194.53 51.81 994796.1
H2O 19583.10 34.44 66573790.7
Total 149320139.9

B. Output CO2 Absorber

1. Panas Sensibel Output Gas Absorber (Q4)
Temperatur Input Gas = 68.48 C
= 341.63 K
Temperatur Referensi = 25 C
= 298.15 K
∆T = 43.48 K

Tabel Komposisi Input CO2 Absorber

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.71% 35.44 567.04
CO 28 0.23% 11.21 314.00
CO2 44 0.3% 15.88 698.51
H2O 18 6.1% 305.73 5503.20
H2 2 66.3% 3298.25 6596.50
N2 28 26.0% 1293.64 36221.84
Ar 40 0.3% 15.26 610.27
Total 100% 4975.41 50511.36

a. Menentukan CP Output Gas

Cp = A x BT + CT^2 + DT^3
 T Input = 341.63 K

Tabel Kapasitas Panas Komponen Output Gas

Komponen Cp (Kj/kmolK) Cp Output
A B C D kJ/kmolK
CH4 19.238 5.21E-02 1.20E-05 -1.1E-08 37.98
CO2 19.78 7.34E-02 5.60E-05 1.71E-08 52.07
CO 30.869 -1.29E-02 2.79E-05 -1.3E-08 29.23
H2 27.143 7.35E-07 -1.4E-05 7.65E-09 25.84
N2 31.15 -1.36E-02 2.68E-05 -1.2E-08 29.18
Ar 20.804 -3.21E-05 5.17E-08 0 20.80
H2O 32.243 1.92E-03 1.06E-05 -3.6E-09 33.99

b. Menentukan Panas Sensibel Output Gas (Q4)

Q = n x Cp x ∆T

Tabel Panas Sensibel Output Gas

Mol Cp Inlet ∆T Q4
Komponen
(kmol) kJ/kmolK (K) (Kj)
CH4 35.44 37.98 58523.3
CO 11.21 52.07 25387.4
CO2 15.88 29.23 20174.0
H2O 305.73 25.84 43.48 343449.2
H2 3298.25 29.18 4184104.3
N2 1293.64 20.80 1169891.8
Ar 15.26 33.99 22546.3
Total 5824076.4

5. Panas Sensibel Output Rich Benfield (Q5)

Temperatur Output RB = 115.3 C
= 388.45 K
Temperatur Referensi = 25 C
= 298.15 K
∆T = 90.3 K
a. Menentukan CP Input Gas
Cp = A x BT + CT^2 + DT^3
T Input = 388.45 K

Tabel Kapasitas Panas Komponen Rich Benfield

Komponen Cp (Kj/kmolK) Cp Output
A B C D kJ/kmolK
K2CO3 97.08 9.42E-02 -2.05E-06 7.1E-10 133.40
DEA - - - - 137
V2O5 45.97 1.45E-02 6.20E-07 -1.77E-10 51.69
H2O 32.243 1.92E-03 1.06E-05 -3.6E-09 34.37
KHCO3 - - - - 87.61

b. Menentukan Panas Sensibel Semi Lean Benfield (Q3)

Q = n x Cp x ∆T

Tabel Panas Sensibel Lean Benfield

Mol Cp Inlet ∆T Q5
Komponen
(kmol) kJ/kmolK (K) (Kj)
K2CO3 5719.26 133.40 68896499.2
DEA 728.63 137.00 9013898.8
V2O5 238.77 51.69 90.30 1114385.6
H2O 22005.18 34.37 68298452.0
KHCO3 2106.99 87.61 16668771.5
Total 147323235.6

6. Panas Reaksi Absorbsi

Reaksi : K2CO3(l) + CO2(g) + H2O(l) 2KHCO3
Mula : 6772.75 1069.37 23058.67 0.00
Reaksi : 1053.49 1053.49 1053.49 2106.99
Sisa : 5719 15.88 22005.18 2106.99

Tabel Panas Pembentukan Standar (∆H⁰F)

Komponen ∆H⁰F
(kJ/kmol)
 K2CO3 -1146.12
CO2 -393.51
H2O -285.84
KHCO3 -1150.18
(Hougen, 297)

Qr = ∑∆H⁰Produk + ∑∆H⁰298 - ∑∆H⁰Reaktan) (Hougen, 348)

∑∆H⁰298 = ∑∆H⁰Produk - ∑∆H⁰Reaktan

= (n. ∆H⁰F KHCO3) - (n. ∆H⁰F K2CO3 + n. ∆H⁰F CO2 + n. ∆H⁰F H2O)
= -2423420 kJ - -1923122 kJ
= 500298.095 kJ

∑∆H⁰Produk = ∑n.Cp.∆T
= ∑n KHCO3.Cp KHCO3.∆T
= 2106.99 x 87.61 x 90.3
= 16668771 kJ

∑∆H⁰Reaktan = ∑n.Cp.∆T
= (n K2CO3 . Cp K2CO3 . ∆T) + (n CO2 . Cp CO2 . ∆T)
+ (n H2O .Cp H2O . ∆T)
= 2.12E+07 + 2.35E+04 + 2.16E+07
= 42821692 kJ

Q reaksi = ∑∆H⁰298+ (∑∆H⁰Produk - ∑∆H⁰Reaktan)

= 500298.09481 + 16668771 kJ - 42821692.306
= -25652623 kJ
= 25652623 kJ

7. Panas Hilang (Qloss)

Qinput = Qoutput
Q1 + Q2 + Q3 + QR = Q4+Q5+ Qloss
Q loss = (Q1 + Q2 + Q3 + QR) - (Q4+Q5)
Q loss = 198481119 - 153147312
Q loss = 45333807
∆H⁰F CO2 + n. ∆H⁰F H2O)
G. Neraca Massa Methanator (106-D)

9 Gas Masuk Methanator Gas Keluar 13

Methanator

Gambar Blok Diagram Methanator (106-D)

Komposisi : Komposisi:
CH4 = 0.71% CH4 = 1.14 %
CO = 0.23% H2 = 72.25 %
CO2 = 0.32% N2 = 26.23 %
H2O = 6.14% Ar = 0.38 %
H2 = 66.29% Total 100 %
N2 = 26.00%
Ar = 0.31%
Total 100%

1. Input Methanator 106-D

a. Stream 9
OutputAbsorber 1101-E = Input Mehanator 106-D
Tabel Komposisi Input Methanator
BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 0.71% 35.44 567.04
CO 28 0.23% 11.21 314.00
CO2 44 0.32% 15.88 698.51
H2O 18 6.14% 305.73 5503.20
H2 2 66.29% 3298.25 6596.50
N2 28 26.00% 1293.64 36221.84
Ar 40 0.31% 15.26 610.27
Total 100% 4975.41 50511.36
2. Output Methanator 106-D
b. Stream 13
a. Menghitung Neraca Atom Input Methanator 106-D
Tabel Neraca Atom Input Absorber 1101-E
Mol C H O
Komponen
kmol/jam kmol kmol kmol
CH4 35.44 35.44 141.76 0.00
CO 11.21 11.21 0.00 11.21
CO2 15.88 15.88 0.00 31.75
H2O 305.73 0.00 611.47 305.73
H2 3298.25 0.00 6596.50 0.00
N2 1293.64 0.00 0.00 0.00
Ar 15.26 0.00 0.00 0.00
Total 4975.41 62.53 7349.73 348.70

b. Menghitung Output Methanator 106-D

% Total atom C output = 1.14 %
= 1.14 %

Neraca Karbon
%CH₄ Output
Mol CH₄ Output = x Total atom C input
%Total atom C output
1.14 %
= x 62.53 kmol
1.14 %
= 62.53 kmol

Atom O masuk = Atom O keluar

348.70 kmol = Atom O keluar

Atom O Pada H₂O = 348.70 kmol

Maka,
H2O Keluar = Atom O Pada H2O
= 348.70 kmol

Atom H Keluar = Atom H input + (Atom H pada CH4 output +

atom H pada H₂O output)
= 7349.7 kmol - ( 4 x 62.5 kmol
( 2x 348.7 kmol )
 = 7349.73 kmol - 947.51 kmol
= 6402.21 kmol
6402.21 kmol
H2 Keluar =
2
= 3201.11 kmol

Reaksi pada Methanator

CO + 3H2 CH4 + H2O
11.21 3298.25
11.21 33.64 11.21 11.21
0.00 3264.61 11.21 11.21

CO2 + 4H2 CH4 + 2H2O

15.88 3298.25
15.88 63.50 15.88 15.88
0.00 3234.75 15.88 15.88

Tabel Komposisi Output Methanator 106-D

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
CH4 16 1.27 62.53 1000.47
H2O 18 7.09 348.70 6276.57
H2 2 65.05 3201.11 6402.21
N2 28 26.29 1293.64 36221.84
Ar 40 0.31 15.26 610.27
Total 100.00 4921.23 50511.36

Tabel Neraca Massa Methanator

Inlet Outlet
Komponen
mol (kmol) massa (kg) mol (kmol) massa (kg)

CH4 35.44 567.04 62.53 1000.47

CO 11.21 314.00 0.00 0.00
CO2 15.88 698.51 0.00 0.00
H2O 305.73 5503.20 348.70 6276.57
H2 3298.25 6596.50 3201.11 6402.21
N2 1293.64 36221.84 1293.64 36221.84
Ar 15.26 610.27 15.26 610.27
Total 4975.41 50511.36 4921.23 50511.36
% konversi = ( CH4 keluar - CH4 masuk) x 100%
CH4 CH4 keluar
= 62.5 - 35.4 x 100%
62.530
= 43.32%
H. Neraca Massa Ammonia Converter (105-D)
Basis : 1 Jam

Gas Masuk Ammonia Conv Gas Keluar Amm Conv

Ammonia Converter
14 15

Gambar Blok Diagram Ammonia Converter

Flow Rate (FR-15) = 414000 Nm3/hr
Komposisi : Komposisi:
H2 = 67.14% H2 = 54.70%
N2 = 20.33% N2 = 18.53%
CH4 = 7.88% CH4 = 9.23%
NH3 = 1.81% NH3 = 14.04%
Ar = 2.84% Ar = 3.50%
Total 100% Total 100%

Flow Rate Input = FR-15

Massa 22.4
= 414000 Nm³/jam
22.4
= 18482.14 kmol

1. Input Ammonia Converter

a. Stream 14
Tabel Komponen Input Ammonia Converter
BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
H2 2 67.1% 12408.91 24817.82
N2 28 20.3% 3757.42 105207.75
CH4 16 7.9% 1456.39 23302.29
NH3 17 1.8% 334.53 5686.96
Ar 40 2.8% 524.89 20995.71
Total 100% 18482.14 180010.53
a. Menghitung Neraca Atom Input Methanator 106-D
Tabel Neraca Atom Input Absorber 1101-E
Mol C H N
Komponen
 Komponen
kmol/jam kmol kmol kmol
H2 12408.91 24817.82 0.00
N2 3757.42 7514.84
CH4 1456.39 1456.39 5825.57
NH3 334.53 1003.58 334.53
Ar 524.89 0.00 0.00 0.00
Total 18482.14 1456.39 31646.97 7849.37

b. Menghitung Output Methanator 106-D

% Total atom N output = 18.53% + 14.04%
= 32.57%

Neraca Karbon
%N2 Output
Mol N2 Output = x Total atom N input
%Total atom N Output
18.53%
= x 7849.37 kmol
32.57%
= 4465.73 kmol

%N2 Output
Mol NH3 Output = x Total atom N input
%Total atom N Output
14.04%
= x 7849.37 kmol
32.57%
= 3383.64 kmol

Atom O masuk = Atom O keluar

#REF! = Atom O keluar

Atom O Pada H₂O = #REF!

Maka,
H2O Keluar = Atom O Pada H2O
= #REF!

Atom H Keluar = Atom H input + (Atom H pada CH4 output +

atom H pada H₂O output)
= 31647.0 kmol - ( 4x ###
( 2x #REF! )
= 31646.97 kmol - #REF!
= #REF!
 #REF!
H2 Keluar =
2
= #REF!

Tabel Komponen Input Ammonia Converter

BM Mol Mol Massa
Komponen
kg/kmol % kmol kg
H2 2 54.7% #REF! #REF!
N2 28 18.5% #REF! #REF!
CH4 16 9.2% #REF! #REF!
NH3 17 14.0% #REF! #REF!
Ar 40 3.5% #REF! #REF!
Total 100% #REF! #REF!

Reaksi pada Ammonia Converter

N2 + 3H2 2NH3
3757.42 12408.91
3757.42 11272.26 7514.84
#REF! #REF! 7514.84

Tabel Neraca Massa Ammonia Converter

Inlet Outlet
Komponen
mol (kmol) massa (kg) mol (kmol) massa (kg)

H2 12408.91 24817.82 #REF! #REF!

N2 3757.42 105207.75 #REF! #REF!
CH4 1456.39 23302.29 #REF! #REF!
NH3 334.53 5686.96 #REF! #REF!
Ar 524.89 20995.71 #REF! #REF!
Total 18482.14 180010.53 #REF! #REF!

% konversi = ( N2 masuk - N2 keluar) x 100%

N2 N2 masuk
= 3757.4 - #REF! x 100%
3757.420
= #REF!

% konversi = ( H2 masuk - H2 keluar) x 100%

H2 H2 masuk
= 12408.9 - #REF! x 100%
12408.911
= #REF!
Gas Keluar Amm Conv