11 Benzene reacts with fuming sulfuric acid to form benzenesulfonic acid.

Fuming sulfuric acid is

D A sulfuric acid with a concentration of 98 %

D 8 pure sulfuric acid

D C concentrated sulfuric acid containing dissolved sulfur dioxide

• D concentrated sulfuric acid containing dissolved sulfur trioxide 1/,

10 How many o bonds and 11 bonds are there in a molecule of benzene?

o bonds If bonds
D A .._ 6 3
- -- -
D 8 6 6

• 0
C
D
12

12
3

17 The structures of cocaine and Its metabolite benzoyleec:gonlne are shown.

cocaine benzoylecgonine

How would you expect the solubility of cocaine in waiter and the pH of its
aqueous solution to compare with benzoylecgonine?

Solublllty In woter pH of oqueouuotutlon

D A cocaine more soluble cocaine higher pH

D 8 cocaine mor(! soluble cocaine lower pH

□ C cocaine leS5 ~oluble ,ocnlne higher pH

• D cocaine less soluble cocaine lower pH

 Question 1

Delocalised electron systems are important in determining the chemical properties

of some compounds. Compare and contrast the chemical reactions of bromine with

benzene and cyclohexene, and with benzene and phenol, by considering the effe.c ts

of delocalised electrons. Detailed descriptions of the bonds or of the reaction

mechanisms involved are not req_uired. (6)

.... ~..~ ...... .~SJ.sb ....... c.J............6.......L....~

.. ~(~........ lfl... .. ..... ~ ......~~~- .....~ :............... .
..b.b. .... ~·~ ........ \.b ....~.......~........~.. pJ.....~ .
..P.i .....~.......~........ U;...... ~le.11L .....~..... ~ ·..
....8<:Q.~.~.~....... f~......~ ......~-Je:w.~f,6t.: .....~~.~......r~
..~.i.~........c.r:tt?.~......~.....~~. ...............................
..~ ...~~ ....lf.....~.....U1 .... ~~ ....•~ ...~....~'!'
· ·i · · ·~~. . ..
~ fktw~..~ ..~ .. ~....~1.~ .. ..r~..
...~~ 11. .....dt4r~ :lt.-1. :..................................................................
..c.w.Uo...~ ~····· Y.~ ...~~ ..... ~ .~Y.\(,,.. ... . ¥.;~ .~,;r.,
..~ .•.~ M., ...W~~ ........ ~.~..... t ...~P.~.......~B°····
-~~ . . ·'"·~~-~!. . . . . . . . . . . . . . . . . . . . . . . . . . . . ..
. 7ka..... ~...... ~ . . l!......... fH..~ ....! ~ I L..
.....P.bJ...... AOf......~......Nk .. ~... ,j.....~.~,t
.... in ....i.~ ... ..... r.•.,., ...... ~....:-::.....~ .i.Il... Jr.J.......4tth()~IM
....Mnl .....* ~·l···IJ$: ·····0.·~ ·····'f~····~ ······~ ······~ ·
.. .~f.... -,J ... ~......~.~ .....~.~....~ .....~.~ .... h.'8
.4: . kn~..................................................................................
~J........w1J.t ..... ~......~)Jb..... ~~...... t.~~~h.... ~.. .
~ ...... ~... ....~~ ........ W.~ . ...... ..................................
.~........ ~.....~..... ~ .......~~JJ. ....IMM.<J!I. ...... .
._eJ,,tli_(!~f(,_ .... -~ -" :~ .. .................................................. .

• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • -• •••••••••••• • ••••••••••••• • •••••••••••••••••••••• • ••••••••• ♦ •••••••••

• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • ♦ ••••••••••••••••••••••••••••••••••••••••••••••••

........ .............................. ............ ...........................................................

• • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • • ♦ ...... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..

• • • • • • • • • • • • • • • ♦ ••••• • ••••• • •••••••••••• • •••••••••••••••••••• ♦ ••• • ••••••••••••••••••••••••••••••••••

.. ........ . . . . .............. ....................... .......... ........................................

............. .. ...... . . . . . ...... ... ............... .. .................... .... . ....... . . . . ... ...........
................................... ............... ............................. ......... . . . . .........
................... .............. ........•·..........................................................
18 Benzenecarboxylic acid may be produced from benzene in a two-step synthesis.

0benzene
M,=78
Step 1

Yield 45%

methyl benzene
M, =92
Step 2

Yield60%

benzenecarboxylic acid
M,= 122

8.24 g of benzenecarboxylic acid was formed in this synthesis.

What mass of benzene was used?

•□
A 3.48 g
B 5.27 g

□ C 19.51 g

□ D 30.52 g