Professional Documents
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BACHLOR OF ENGINEERING
In
CHEMICAL ENGINEERING
Of
By
Department of Chemical
Engineering Sinhgad College of
Engineering,
Vadgaon (Bk.), Pune-411041
2023-24
CERTIFICATE
This is to certify that the Project Phase I report entitled
Submitted by
is a bonafide work carried out under the supervision of Prof.V.S. Ashtekar for the partial
fulfillment of Bachelor of Engineering in Chemical Engineering of Savitribai Phule Pune
University. This work has not been submitted elsewhere for any degree.
Dr. S. D. Lokhande
External Examiner Principal
ii SCOE BE (Chemical)
Pune.
DECLARATION
We declare that this written submission represents our ideas in our own words
and where others’ ideas have been included; We have adequately cited and
referenced the original sources. We also declare that We have adhered to all
principles of academic honesty and integrity and have not misrepresented or
fabricated or falsified any idea/data/fact/source in my submission. We
understand that any violation of the above will be cause for disciplinary action
by the Institute and can also evoke penal action from the sources which have
thus not been properly cited or from whom proper permission has not been
taken when needed.
Signature
Dalavi Shriyash
Navnath
Date:
Place: Pune
We hereby acknowledge all the help and guidance we received throughout the course of the
preparation of this seminar from various quarters. We cannot overstate the importance of the
guidance received from our guide Prof. V.S. Ashtekar & Head of the Chemical Engineering
Department Dr. S. R. Shirsath. Not only did they guided us in the choice of the topic but
also went out of their way to provide the background study material for the same. For all this
and more, we thank them.
Our sincere gratitude goes also to Dr. S. D. Lokhande, Principal, Sinhgad College of
Engineering, for the support and encouragement he provided to everyone in this department.
A word of thanks also for all the staff, teaching and non-teaching, because whether it be a
seminar or any other student activity, there’s always a contribution from them.
Lastly, we would like to thank all our classmates for their support during this seminar.
iv SCOE BE (Chemical)
Pune.
LIST OF TABLES
v SCOE BE (Chemical)
Pune.
ABSTRACT
Cement is the basic material for buildings and Civil Engineering constructions.
Portland cement, the most widely used cement in concrete construction, was
patented in 1824. Cement is a fine powdery material untwining silicates of
calcium, formed out of raw materials consisting calcium oxide, silica, aluminum
oxide and iron oxide. India has an installed capacity of 234 million tons per
year, making this is the second highest Cement producer in the whole world. As
is the case in the United States, several multinational Cement producers have
built up a larger share of India’s Cement production industry. Among many
countries India is the second highest producer of cement in the world, with 130
large cement plants and an installed capacity of 234 million ton per annum
(94% of which is from large cement plants). During 2006-2007 cement
production grew at a rate of 9.1% compared to the same period the previous
year. However, despite this growth, India’s per capita.
A production is 115 kg per annum, well under the world average of 250 kg
(World Cement 2007). The Cement manufacturing sector plays a vital role in
the nation’s economic development since cement is the most versatile and
widely used construction material. The cement industry has made phenomenal
progress in terms of volume, technology and product up gradation in recent
years.
vi SCOE BE (Chemical)
Pune.
G Manufacturing of Cement
CHAPTER-1
INTRODUCTION
Cement Manufacturing
Cement manufacturing uses energy to process raw materials consisting of mainly limestone
(calcium carbonate, CaCO3), clay (aluminum silicates), sand (silica oxide), and iron ore to produce
clinker, which is ground with gypsum, limestone, etc to produce cement. After an initial
preblending stage, the raw materials are mixed together and ground to form a homogeneous blend
with the required chemical composition (the raw meal). The fineness and particle size distribution
of the raw meal are important characteristics for the burning process. Following mixing, the
production process continues in a rotary kiln by calcining the raw meal (e.g. decomposing CaCO3
at about 900 °C), releasing carbon dioxide (CO2) and leaving CaO. This is followed by the
clinkering process, in which CaO reacts at a high temperature (1,400 °C to 1,500 °C) with silica,
alumina, and ferrous oxides. Other constituents may be added in the raw material mix to meet the
required composition (e.g. silica sand, foundry sand, iron oxide, alumina residues, blast furnace
slag, and gypsum residues).
The temperature of the flame and produced gases is close to 2,000 °C. The hot clinker falls
from the kiln onto the cooler, where it must be cooled as quickly as possible to improve the clinker
quality and to recover energy by heating secondary air. Grate coolers are typically employed for this
purpose (as opposed to the use of satellite coolers). The cooled clinker is then ground with gypsum
and limestone to produce Portland cement and ground with other additional constituents to produce
composite or blended cements. Cement is then stored in silos or bags. The blending constituents are
materials with hydraulic properties (e.g. natural pozzolane, fly ash, blast furnace slag, and
occasionally bottom ash). In fly and bottom ashes, carbon residues (typically from coal-fired power
plants) should not be present. CaCO3 is sometimes added in small quantities as filler. Calcium is
found in limestone, which is one of the most common natural resources in the world. Limestone is
usually quarried in the vicinity of cement factories, where it is extracted through blasting
techniques. Step by step, these blasted stones are crushed to gravel before they are transported to the
cement factory and mixed with the two other basic ingredients of cement, clay and sand. At that
point, there are two different manufacturing processes, the dry and wet process.
In the dry process, the raw materials are ground, mixed and fed into a cement kiln, a
horizontal rotating cylinder. In the wet process, water is added to the raw materials before being fed
into the kiln, to create slurry. The dry process is more environmentally friendly and emits less CO2,
due to the additional use of fuel needed in the wet process. The cement kiln is heated to a
temperature of approximately 1450°C, and uses a variety of fuels, ranging from coal and biomass to
7 SCOE BE (Chemical) Pune.
G Manufacturing of Cement
waste materials such as old rubber tires. Only at these high temperatures do the chemical and
physical characteristics of the raw materials change. These changes create so-called ’Clinker’ that
come out of the kiln in small marble size pieces. After cooling, these clinkers are further ground to
create Portland cement.
Contents of Portland cement
Cement is a mixture of Calcium oxide (CaO) (62.66%), Silicon oxide (SiO2) (19-22%),
Aluminum tri-oxide (Al2O3 )(4-8%), Ferric oxide (Fe2O3)(2-5%), Magnesium oxide (MgO) (1-
2%).
Types of cement
The cement industry has been producing a range of six main varieties of cement like PSC (Portland
Blast Furnace Slag Cement), SRC (Sulphate Resisting Cement), PPC (Portland Pozzolana Cement),
OPC (Ordinary Portland Cement) Oil Well Cement and White Cement, besides 53S-43S(earlier
IRS-T40) for railway sleepers. Cement produced in India compulsorily conforms to Indian
Standards specification issued by the Bureau of Indian Standards (BIS). These are five certified
types of cement- Portland Cement, Portland blast furnace Cement, Sulphate-resisting Portland
Cement, Masonry Cement and Portland pulverized fuel ash Cement (BIS, 2005).
CHAPTER-2
LITERATURE REVIEW
The cement manufacturing process involves mining, crushing, grinding of raw materials
(principally limestone and clay), blending of raw meal, calcining the materials in a rotary
kiln, cooling the resulting clinker, mixing the clinker with gypsum, and milling, storing, and
bagging the finished cement. The raw materials used to make cement may be divided into
four basic components: lime (calcareous), silica (siliceous), alumina (argillaceous), and iron
(ferriferous).
Approximately 1450 kilograms (kg) of dry raw materials are required to produce one tonne
of cement. Approximately 35% of the raw material weight is removed as carbon dioxide
(CO2) and water vapour. The basic chemistry of cement manufacturing process begins with
the decomposition of clay minerals into SiO2 and Al2O3 on the one hand, and of calcium
carbonate (CaCO3) at about 900 °C to leave calcium oxide (CaO, lime) liberating CO2, on
the other hand.
The latter process is known as calcination. This is followed by the clinkering process, in
which the CaO reacts at high temperature (typically 1450 °C) with silica, alumina, and
ferrous oxide to form the silicates, aluminates, and ferrites of calcium. The resultant clinker
is then ground together with gypsum and other additives to produce cement. Naturally
occurring calcarrous deposits such as limestone, marl or chalk provide calcium carbonate
(CaCO3) and extracted from quarries, often located close to the cement plants.
Very small amounts of "corrective" additives such as re ores or clay can
be required to compensate Fe2O3, Al2O3 & SiO2 to ensure chemical composition. Raw
limestone is transported to crushers for breaching down into smaller pieces. Mixing of
different raw materials in fixed proportion to attain specific chemical composition and the
crushed pieces are then milled together to produce "raw meal" the quality of cement depends
on the chemistry of raw meal, which is monitored & controlled carefully. A pre heater is
series of vertical mounted cyclone from where feed is passed coming into contact with wet
gases moving antidirectional swirling hot kiln exhaust gases moving in the opposite
direction. In these cyclones, thermal energy is recovered from the hot flue gases and the raw
meal is preheated before it enters the kiln, so the necessary chemical reaction occurs faster
and more efficiently. The precalciner meal then enters the kiln. Fuel is fired directly into the
kiln to reach temperature of up to 1450 0C as the kiln rotates, at 3-5 RPM, times per minute,
the meal slides & vemes in hotter zone at other and the vigorous heat account to various
physical & chemical reactions producting clinker as product. Stored clinker is mixed with
gypsum & grounded into grey power. Earlier, inj cement mills; ball mills have been used as drinding
media, but in modern days efficient technology. The final product is homogenized and stored in
cement silos and dispatched from there to packing plant for getting packed.
Pre-Heater
Pre-Calciner
Raw material
processing Rotary kiln
Clinker Cooler
Fuel preparation
Final grinding
Chapter-3
Manufacturing Process
The process of cement making Cement is produced from suitable raw materials in six
stages (Figure 1). Mining limestone/raw materials; grinding, homogenisation, and blending
various raw mix components; the preheater phase; processing and pyro processing in the kiln;
clinkerizing; and grinding, packing, and transporting materials (Hewlett 2003; Peray and
Waddell 1986). In stage one, the essential raw materials-limestone, laterite, bauxite, kaolinite,
clay, iron ore, sandstone, etc-are mined. Limestone is a source of calcium, while bauxite and
kaolinite meet the requirement for aluminium. Laterite, red ochre, and iron ore fulfill the need
for iron and, to some extent, silica. Quartz-phyllite and sandstone provide a source for silica.
Because the requirement for limestone greatly outweighs that of other components, cement
kilns are usually located close to plentiful limestone supplies, with other raw materials being
transported to the plant. Erecting cement kilns near limestone mines allows easy handling of
the primary raw material, thereby saving energy and making cement production more
economical. In recent years, computer-aided mining plans have been widely adopted to assist
with quality limestone production. The extracted limestone boulders are crushed in crushers
for size reduction, with the advanced technology of modern crushers resulting in optimal
crushing. Piles of various raw materials stacked in stockpiles also receive further processing
as part of the mining process.
Stage two involves the characterisation of various raw materials. This quality control
process establishes the composition of the raw materials. Then, with the help of various
quality control tests, suitable raw mix designs are prepared. The raw materials are then
ground in suitable ball mills/vertical roller mills (VRMs), both of which are common
grinding mills, in order to achieve the targeted fine powder, which is stored in pre-
homogenisation silos (Aïtcin and Flatt 2015; Hewlett 2003). In stage three, the raw mix is fed
into a preheating chamber. This chamber consists of 5–6 vertical cyclones, through which
the raw material passes and undergoes decarbonation. The preheating chamber utilises
the hot gases emitted from the kiln, thus saving energy depending on the number of stages.
This approach makes the cement plant more environmentally friendly by reducing fuel
consumption by 30–50% (Wasilewski and Duda 2012). In stage four, the pre-heated
decarbonised raw mix is fed into the rotary kiln for clinkerization. The retention time of the
kiln feed also varies from plant to plant, taking into consideration the reactivity of the raw
mix and defining the production capacity, which is generally calculated as tons per day. The
kiln inlet temperature is usually maintained at around 900 °C, and the final temperature is
11 SCOE BE (Chemical) Pune.
G Manufacturing of Cement
around 1450 °C (Deolalkar 2016; Hewlett 2003; Peray and Waddell 1986). During heating, a
series of chemical reactions occurs between calcium, silicon, aluminium, iron, etc. resulting
in phase formation. Kilns are typically heated from the exit side, with fuel type depending on
availability and suitability. In stage five, the clinker exiting the kiln is rapidly cooled by
forced air. The resulting hot air is circulated back into the kiln or the pre-heater, thus reducing
energy demand. The cooled clinker is then ground in a suitable grinding mill with about 5%
gypsum or another calcium sulphate source and other trace components such as limestone and
stannous or ferrous sulphate. In the final stage, the ground cement is conveyed to storage silos
using a suitable transport system. The silos need to prevent contamination and hydration, for
example. Stored cement is then either packaged in waterproof bags of 20–50 kg or
transported in bulk.
environmental concern (Deolalkar 2016; Uwasu, Hara, and Yabar 2014). Today, however, very few
wet process plants remain. Appropriate environmental protection laws, and norms and emission
limits are formulated by every country, and the adoption of a proper environmental management
plan (EMP) can minimise ecological degradation. Most cement plants worldwide take adequate
steps to protect the environment, and assessments of environmental norms are improved and
modified annually
Figure 3 Simplified flow sheet of clinker and cement manufacture. The heart of the process is the
pyro processing line, where most of the raw materials and fossil fuels are consumed. Electricity
consumption is dominated by the raw material crushing and, particularly,
CHAPTER
MASS AND ENERGY BALANCE
CLAY
5% 0.05
M2 Loss
M1 CLAY M3
IN = LOSS + OUT
M1 = M2 + M3
15 = 15*0.05 + M3
M3=14.25 Kg/day
CRUSHER
5% 0.05
M2 Loss
M4 CRUSHER M6
IN = LOSS + OUT
M4 = M5 + M6
85 = 85*0.05 + M6
M6=85.75 Kg/day
RAW MILL
5% 0.05
M8
M3 RAW MILL M7
M6
LOSS
IN = OUT + LOSS
M3+M6 = M8 + M7
14.25+80.75 = M8 + 0.475
M8=94.525 Kg/day
Composition of M7 & M8
KILN
EXHAUST GASES
5% 0.05
KILN
M8
M9
Analysis of M8
M wt of Component
Moles of Component
Analysis of M9
% 20 60 12 8
REACTION IN KILN
3 + 4 ------------- 5
X1 = Y1 = 0.764563 kmol/day
X2 = Y2 = 0.021106 kmol/day
Y3 = 0.384065 kmol/day
X3 = 0.192032 kmol/day
Z4 = 0.032783 kmol/day
Y4 = 0.008196 kmol/day
X4 = 0.008196 kmol/day
Y5 = 0.022001 kmol/day
X5 = 0.007334 kmol/day
Z5 = 0.036668 kmol/day
C3S C2S
3CaO.SiO2 2CaO.SiO2
60% 20%
Weigh Ratio 3 1
Mwt 228.3 172.22
Mole Ratio 0.013141 0.005807 weigh ratio / mwt
2.263 1 Divided by 0.005806
kg/day
Component kmol/day Mwt kmol/day * Mwt %
C2S 0.058851 177.22 10.429662 17.3
C3S 0.133181 228.3 30.405208 50.4
C3A 0.022001 270.3 5.946735 10
C4AF 0.008196 485.95 3.982729 6.6
Inert - - 9.520970 15.8
Sum - - 60.285304 100.0
Check
M8 = M9 + Exhaust Gases
94.525 = 60.285304 + 34.577271
94.525 = 94.862575
CEMENT MILL
M9
CEMENT MILL
M10
M11
5% 0.05
Real Quantities
Converted Balance
Annual Production 1000000 ton/year
Working Days 300 day/year
Basis
X = 5282620.2 kg/day
CLAY
M2 Loss
5% 0.05
0.75
M1 = 15 CLAY M3=14.25
CRUSHER
M2 Loss
5% 0.05
4.25
M4=85 M6=80.75
CRUSHER
Chapter-7
Cost Estimation
In the project management lifecycle, the pre-design stage plays a crucial role in shaping the
project’s success. During this phase, detailed equipment specifications and plant facility information
are not yet available. However, it is essential to estimate costs accurately even before these specifics
are finalized. At this point, the project design is complete, and critical decisions have been made.
With detailed information on equipment and facility requirements, we can now proceed to cost
estimation.
Manufacturers can provide direct price quotations based on these detailed specifications.
Cost Estimation Throughout Early Stages:
o Waiting until the final stages to estimate costs is not advisable. Instead, cost evaluation
should occur throughout the early design phases.
Utilities and Maintenance: Regular expenses for utilities (electricity, water, etc.) and
maintenance of machinery.
Inventory: Maintaining stock levels of finished goods.
Other Operational Costs: Administrative expenses, marketing, and distribution costs.
1. Direct Costs:
Direct costs are expenses directly tied to the production of specific goods or services. They can
be traced to a specific cost object, which could be a product, service, or department.
Purchased Equipment: Includes items like columns, heat exchangers, pumps, and
tanks.
Equipment Installation: The cost of installing machinery and tools.
Piping (Including Insulation): Expenses related to piping systems.
Instruments and Control: Costs associated with control systems and instrumentation.
Electrical Equipment: Expenses for electrical components.
Buildings: Covers process buildings, administration buildings, and maintenance shops.
Site Preparation: Costs for preparing the site (e.g., levelling, excavation).
Service Facilities: Includes utilities (steam, water, air, fuel), waste treatment, fire
control, and office spaces.
Land: The cost of acquiring land for the plant.
2.Indirect Costs
Indirect costs are fixed expenses incurred to keep the company running, regardless of the
activity level. They are more challenging to assign to a specific product. They are generally
related to the business Operations.
Engineering and Supervision: Administrative and design expenses, supervision, and
inspection.
Construction Expenses: Costs related to the construction process.
Contractor’s Fee and Contingency: Additional fees and allowances for unforeseen
events.
Start-Up Expenses: Necessary for initiating plant operations.
o This method involves creating a detailed list of all items required for the project, including
equipment, materials, and labour costs.
2. Unit Estimate:
o In this approach, costs are estimated based on a standard unit (e.g., cost per square meter of
construction, cost per machine, etc.).
o A percentage (often around 30-40%) of the total equipment cost is added to account for
installation, commissioning, and other related expenses.
o Lang’s factor method estimates total project cost based on the capacity (size) of the facility.
Factors are derived from historical data.
o This method calculates the total investment cost per unit of capacity (e.g., cost per megawatt
for power plants).
The accuracy of an estimate depends on the amount of design detail available; and the ac curacy of
the cost data available; and the time spent on preparing the estimate. In the early stages of a project
only an approximate estimate will be required an justied by the amount of information by then
developed
Here for costing of our Plant we will use Percentage of delivered Equipment cost to calculate the
overall costing of Plant. This method does not require the detailed design of the Equipment We can
estimate the overall cost of the plant by roughly estimating the Equipment cost before the detailed
design of equipment is made.
BASIS AND PRESUMPTION
1. It may be assumed that the unit will be working on single shift basis for 300 days in a year with a
production capacity of 3,00,000 sq ft cement jallies per annum.
2. The basis for calculation of production capacity is on single shift basis, working of 25 days per
month on 75% efficiency. The time required for achieving envisaged capacity utilization is assumed
as one year.
3. BEP for the scheme has been calculated on full capacity utilization.
4. Rate of interest has been taken as 16% on an average. This however, is likely to vary depending
upon the financial outlay and location of the unit.
5. The cost of machinery & equipment as indicated in the scheme are approximate to those ruling at
the time of preparation of the scheme. The entrepreneur may check up the exact price for specific
make and model of the machine selected.
6. Non-refundable deposits, cost of preparation of projec profile, etc. may be considered under pre
operative expenses.
7. The provisions may in other respects vice-versa raw materials, labour wages, utilities, overheads,
etc. are drawn on the basis of standard variation and output. The cost indicated against each are
approximate based on local market conditions and observation. The entrepreneur may find out the
exact cost from the concerned sources.
FINANCIAL ASPECTS
1. FIXED CAPITAL:
TOTAL 1,40,000/-
TOTAL 3,59,000/-
TOTAL 1,40,000/-
FINANCIAL ANALYSIS
It is envisaged that the unit can achieve production capacity of 300000 sq ft cement jallies per
annum valued at Rs. 63,00,000/-
Profit/annum * 100
Net Profit Ratio = ---------------------------
Sales/annum
7,04,000 * 100
=
63,00,000
= 11.17%
Profit/annum * 100
(e) Rate of Return
= --------------------------
Total Capital
investment
7,04,000 * 100
= 19,00,000
= 37.05%
TOTAL 7,23,840/-
7,23,840 * 100
=
7,23,840 +
7,04,000
= 50.69%
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