Short Practice Test-01 Lakshya NEET (2024) 30/04/2023

CHEMISTRY

1. 2 m aqueous NaOH solution contains: 7. Relative lowering of vapour pressure of a dilute

(1) 40 g of NaOH dissolved in 250 g of water. solution is 0.2. What is the mole fraction of non-
(2) 20 g of NaOH dissolved in 250 g of water. volatile solute:
(3) 20 g of NaOH dissolved in 1000 g of water. (1) 0.8 (2) 0.5
(4) 40 g of NaOH dissolved in 1000 g of water. (3) 0.3 (4) 0.2

2. Vapour pressures of two liquids A & B are 100 8. Molarity is expressed as:
mm Hg and 60 mm Hg respectively, vapour (1) Gram/litre
pressure of the solution obtained by mixing equal (2) Moles/litre
moles of A and B will be: (3) Litre/mole
(1) 100 mm Hg (4) Moles/1000 gms
(2) 80 mm Hg
(3) 60 mm Hg 9. What is the molarity of 4.9% H3PO4 solution by
(4) 160 mm Hg mass (density of H3PO4 = 1.22 g/ml)?
(1) 0.61 M
3. Which set of thermodynamic parameters are (2) 4.9 M
correct for ideal solution? (3) 1.22 M
(1) Vsol > 0 Gsol > 0 and Hsol > 0 (4) 1 M
(2) Vsol < 0, Gsol > 0 and Hsol < 0
(3) Vsol = 0, Gsol < 0 and Hsol = 0 10. The molality of 1 M NaNO3 solution is
(4) Vsol > 0, Gsol > 0 and Hsol < 0 (d = 1.25 g/ml):
(1) 0.8 m
4. Which one of the following solutions exhibits (2) 0.858 m
highest boiling point? (3) 1.6 m
(1) 0.015M C6H12O6 (4) 1 m
(2) 0.01M Na2SO4
(3) 0.01M NaCl 11. The vapour pressure of pure liquid A is 70 torr at
(4) 0.015M NH2CONH2 27°C. It forms an ideal solution with another
liquid B. The mole fraction of B is 0.2 and total
vapour pressure of the solution is 84 torr at 27°C.
5. 12 g of urea is present in 1 litre of solution and The vapour pressure of pure liquid B at 27°C is:
68.4 g of sucrose is separately dissolved in 1 litre
of another sample of solution. The lowering of (1) 140 torr
vapour pressure of first solution is (2) 50 torr
(1) Equal to second (3) 14 torr
(2) Greater than second (4) 70 torr
(3) Less than second
(4) Double that of second 12. Which statement is correct for the boiling point of
solvent containing a dissolved solid substance?
6. An ideal solution is that which: (1) Boiling point of the liquid is depressed.
(1) Shows positive deviation from Raoult’s law. (2) Boiling point of the liquid is elevated.
(2) Shows negative deviation from Raoult’s law. (3) There is no effect on the boiling point.
(3) Has no connection with Raoult’s law. (4) The change depends upon the polarity of the
liquid.
(4) Obeys Raoult’s law.
 ANSWERS

1. (2) 7. (4)
2. (2) 8. (2)
3. (3) 9. (1)
4. (2) 10. (2)
5. (1) 11. (1)
6. (4) 12. (2)
 Hints and Solution
1. (2)
2m solution of NaOH means (c) 0.01 M NaCl
2 mol of NaOH is present in 1 kg (1000 g) water i = 2 [ = 1]
2 mol NaOH = 2 × 40 = 80 g Tb  2 × 0.01
1000 g water contains 80 g NaOH or 250 g water (d) 0.015 M NH2CONH2
contains 20 g NaOH. i = 1 [ = 1]
Tb  1 × 0.015
2. (2)
Boiling point  Tb  i M solution.
PA = 100 mm Hg  Na2SO4 solution will have highest B.P.
PB = 60 mm Hg
5. (1)
nA = nB = 1[let]  x A =
1 1
=  Particle concentration is same
 1+1 2
12 1 68.4 1
1  = 
 xA = xB = 60 1 342 1
2
According to Raoult’s law 6. (4)
Total vapour pressure of the solution, Ideal solution follows Raoult’s law.
PT = PA + PB
= PA x A + PB x B 7. (4)
p
1
= 100  + 60 
1 = 0.2 = ixsolute considering solute as non-
2 2 po
= 50 + 30 = 80 mm Hg. electrolyte.
x = 0.2
3. (3)
Mixing is a spontaneous process of G < 0. 8. (2)
For ideal solution, Number of moles of solute
V = 0 and H = 0.  Molarity =
Volume of solution in L
[No change in interactions before and after
Unit → mol/L
mixing]

9. (1)
4. (2)
%w/w  d  10
Tb = iKbm M=
M.M.
Tb  i m
4.9  1.22  10
Consider molality and molarity to be equal. =
98
Tb  i M
= 0.61 M.
(a) 0.015 M C6H12O6
i = 1 [ = 1]
10. (2)
Tb  1 × 0.015 1000M
(b) 0.01 M Na2SO4 m=
[1000d − M(M.M.)]
i = 3 [ = 1]
Tb  3 × 0.01 [Highest]
11. (1) 12. (2)
PTotal = PA XA + PB XB The boiling point of a solution of a solid solute
(non-volatile) is always higher than that of a pure
solvent because vapour pressure of such a solution
is lower than pure solvent.
1
Boiling point 
vapour pressure

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