GREEN PARK INTERNATIONAL SENIOR SECONDARY SCHOOL, NAMAKKAL

XII* (CBSE) – CHEMISTRY – ASSIGNMENT – 2

SOLUTIONS
Topics : Henry law, Raoult’s law, Ideal, Non-ideal & Azeotropic mixture
Choose the correct answer :
1. The vapour pressure of pure liquid A is 70torr a) Vapour pressure of A in the pure state is
at 27oC it forms an ideal solution with another 50mm Hg
liquid B. The mole fraction of B is 0.2 and b) Vapour pressure of B in the pure state is
total vapour pressure of the solution is 84 torr 650mm Hg
at 27oC. The vapour pressure of pure liquid B c) Ratio of final vapour pressure to the initial
at 27oC is vapour pressure is 1 : 0.5
1) 140 torr 2) 50 torr d) Ratio of vapour pressure of pure B to the
3) 14 torr 4) 70 torr vapour pressure of pure A is 13 : 1
2. Equal moles of benzene and toluene are mixed 1) a, b 2) a, b, d
the V.P of benzene and toluene in pure state
3) b, c, d 4) b, c, d
are 700 and 600mm Hg respectively. The
6. An ideal solution was obtained by mixing
mole fraction of benzene in vapour state is
methanol and ethanol. If the partial vapour
1) 0.7 2) 0.47
pressure of methanol and ethanol are 2.619
3) 0.50 4) 0.54
kPa and 4.556 kPa respectively. The
3. The solubility of N2(g) at 593 mm of Hg is composition of vapour (interms of mole
5.3 x 10–4 in water. Its solubility at 860 mm fraction) will be
and at the same temperature in water is
1) 0.635 MeOH, 0.365 EtOH
1) 5.3 x 10–4 2) 7.68 x 10–4
2) 0.365 MeOH, 0.635 EtOH
3) 9.0 x 10–4 4) 1.2 x 10–3
3) 0.574 MeOH, 0.326 EtOH
4. The Henry’s law constant for the solubility of
4) 0.173 MeOH, 0.827 EtOH
N2 gas in water at 298K is 1.0 x 105 atm. The
mole fraction of N2 in air is 0.8. The number 7. Henry’s constant of four gases A, B, C and D
of moles of N2 from air dissolved in 10moles in water are 40.3, 1.67, 0.413 and 0.611 298 K
of water at 298K and 5atm pressure is and 1 atm. The gas which has maximum
solubility in water at 298K and 1 atm is
1) 4.0 x 10–4 2) 4.0 x 10–5
3) 5.0 x 10–4 4) 4.0 x 10–6 1) A 2) B

5. At 300K, the vapour pressure of an ideal 3) C 4) D

solution containing 1mole of A and 3 moles of 8. Henry’s law constant for CO2 in water is
B is 500 mm Hg. At the same temperature, 2 1.67 x 108 pa at 298K. Calculate the quantity
moles of B are added to the solution. The of CO2 in 500mL of soda water when packed
vapour pressure of solution increases by 10% under 2.5 atm CO2 pressure at 298K.
of the original vapour pressure correct 1) 0.0422 moles 2) 0.0822 moles
statements about the vapour pressure are 3) 0.0622 moles 4) 0.0122 moles
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9. Raoult’s law is not valid in 13. Choose the correct statement
1) Non-ideal solution showing positive 1) Azeotropic mixture can be separated into
deviation their components by fractional distillation
2) Non-ideal solution showing negative 2) For ideal solutions enthalpy of mixing is
deviation always greater than zero
3) Mixture of two immiscible liquid 3) Components of all non-ideal solution
4) All of these showing positive deviation cannot be
10. A mixture of two liquids A and B having separated out by fractional distillation
boiling point of A is 70oC and boiling point of 4) Non-ideal solution showing positive
B is 100oC, distills at 101.2oC as single liquid deviation enthalpy of mixing is greater than
hence the mixture is zero
1) Ideal solution 14. A and B forms non-ideal solution showing
2) Non–ideal solution showing +ve deviation positive deviation. Boiling point of pure A and
3) Non-ideal solution showing –ve deviation B is 350K and 380K respectively. The
solution will boil at (approximate)
4) Immiscible solution
1) 350 K 2) 380 K
11. Match the following
3) > 380 K 4) < 350 K
Column – I
15. Assertion (A) : Henry’s law and Raoult’s law
A) Ethanol + acetone
are not independent i.e., one can be derived
B) Chloro benzene + bromo benzene
from the other.
C) Ethanol + water
Reason (R) : The partial pressure of
D) Acetone + chloroform component is inversely proportional to the
Column – II mole fraction of that component in an ideal
p) form maximum boiling azeotrope solution.
q) ptotal = PAo + PBo 1) Both (A) and (R) are true and the (R) is a
correct explanation of the (A)
r) form minimum boiling azeotrope
2) Both (A) and (R) are true but (R) is not a
s) does not form azeotrope
correct explanation of the (A)
1) A-p, B-s, C-r, D-r
3) (A) is true but the (R) is false
2) A-r, B-q, s, C-p, D-r
4) Both (A) and (R) are false
3) A-r, B-q, s, C-r, D-p
16. 1kg of water under a nitrogen pressure of
4) A-s, B-p, s, C-p, D-r
1 atmosphere dissolved 0.02 gm of nitrogen at
12. Vapour pressure of mixture of liquid A and 293K. Calculate Henry’s law constant
liquid B at 70oC is given by PT = 180 XB + 90
1) 7.7 x 104 atm 2) 7.7 x 103 atm
(in mm), where XB is the mole fraction of B in
3) 2 x 10–5 atm 4) 2 x 10–2 atm
the liquid mixture. Calculate the vapour
pressure of pure A and pure B 17. Total vapour pressure of mixture of 1 mol X
1) 90, 270 2) 180, 90 ( PXo = 150 torr) and 2 mol Y ( PYo = 300 torr)
3) 120, 360 4) 0, 90 was found to be experimentally 240 torr. In
this case
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1) There is a negative deviation from Raoult’s 1) 0.549 2) 0.200
law 3) 0.786 4) 0.478
2) There is a positive deviation from Raoult’s 20. Which of the following curve represents the
law Henry’s law? (Units of ‘K’ is gm bar–1 and
3) There is no deviation from Raoult’s law m = mass of gas)
4) Cannot be decided
18. Two liquids A and B have PAo and PBo in the
1) 2)
ratio of 1 : 3 and the ratio of number of moles
of A and B in liquid phase are 1 : 3 then mole
fraction of “A” in vapour phase in equilibrium
with the solution is equal to 3) 4)
1) 0.1 2) 0.2
3) 0.5 4) 1.0
19. A solution has a 1 : 4 mole ratio of pentane to
hexane. The vapour pressure of the pure
hydrocarbons at 20oC are 440mm Hg for
pentane and 120mm Hg for hexane. The mole
fraction of pentane in the vapour phase would
be