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LAKSHYA JEE (2024)

Solutions DPP-08

1. If liquids A and B form an ideal solution, the 7. Positive deviation from Raoult’s law is shown by
(1) Enthalpy of mixing is zero which of the following mixtures?
(2) Entropy of mixing is zero (1) Benzene and toluene
(3) Free energy of mixing is zero (2) CHCl3 and Acetone
(4) Free energy as well as the entropy of mixing are (3) Ethanol and Water
each zero
(4) HCl and Water

2. The mixture that forms maximum boiling azeotrope

8. When two liquids A and B are mixed then their
is:
(1) Water + Nitric Acid boiling points becomes greater than both of them.
(2) Ethanol + Water What is the nature of this solution?
(3) Acetone + Carbon disulphide (1) Ideal solution
(4) Heptane + Octane (2) Normal solution
(3) Negative deviation from ideal solution
3. An azeotropic mixture of two liquids has (4) Positive deviation from ideal solution
boiling point lower than either of them, when it
(1) Shows a negative deviation from Raoult’s law 9. The diagram given below is a vapour pressure
(2) Shows no deviation from Raoult’s law
composition diagram for a binary solution of A and B.
(3) Shows positive deviation from Raoult’s law
(4) Is saturated

4. A non-ideal solution was prepared by mixing 30 mL

chloroform and 50 mL acetone. The volume of
mixture will be
(1) > 80 mL (2) < 80 mL
(3) = 80 mL (4)  80 mL In the solution, A – B interactions are
(1) similar to A – A and B – B interactions
5. Which pair from the following will not form an ideal (2) greater than A – A and B – B interactions
solution?
(3) smaller than A – A and B – B interactions
(1) CCl4 + SiCl4 (2) H2O + C4H9OH
(4) unpredictable
(3) C2H5Br + C2H5I (4) C6H14 + C7H16
10. Which of the following is not a characteristic of non-
6. The azeotropic mixture of water (b. pt.100oC) and ideal solution with positive deviation?
HCl (b.pt. 85oC) boils at 108.5oC. When this mixture
(1) Vmix > 0
is distilled it is possible to obtain
(1) Pure HCl (2) Hmix > 0
(2) Pure water (3) Smix < 0
(3) Pure water as well as HCl (4) Gmix < 0
(4) Neither HCl nor H2O in their pure states
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11. A solution of strong acid and water is an 12.

o
A container contains component A with PA = 200
(1) ideal solution o
(2) non-ideal solution with positive deviation mm and component B of PB = 500 mm. If moles of
(3) non-ideal solution with negative deviation A = 2 and moles of B = 3, find vapour pressure of
(4) none of the above solution if solute is volatile.
(1) 120 mm (2) 520 mm
(3) 380 mm (4) 420 mm
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.

Answer Key
1. (1) 7. (3)
2. (1) 8. (3)
3. (3) 9. (3)
4. (2) 10. (3)
5. (2) 11. (3)
6. (4) 12. (3)

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