Chapter 10

Solutions
1. A binary liquid solution is prepared by mixing 5. A 5% solution of cane sugar (molar mass 342 is
n-heptane and ethanol. Which one of the following isotonic with 1% of a solution of an unknown
statements is correct regarding the behaviour of the solute. The molar mass of unknown solute in g/mol
solution? [AIEEE-2009] is [AIEEE-2011]
(1) The solution is non-ideal, showing +ve deviation (1) 34.2 (2) 136.2
from Raoult's Law (3) 171.2 (4) 68.4
(2) The solution is non-ideal, showing –ve deviation 6. Kf for water is 1.86 K kg mol–1. If your automobile
from Raoult's Law radiator holds 1.0 kg of water, how many grams of
(3) n-heptane shows +ve deviation while ethanol ethylene glycol (C2H6O2) must you add to get the
shows –ve deviation from Raoult's Law freezing point of the solution lowered to – 2.8°C?
[AIEEE-2012]
(4) The solution formed is an ideal solution
(1) 93 g (2) 39 g
2. Two liquids X and Y from an ideal solution. At 300
K, vapour pressure of the solution containing 1 mol (3) 27 g (4) 72 g
of X and 3 mol of Y is 550 mmHg. At the same 7. Consider separate solutions of 0.500 M
temperature, if 1 mol of Y is further added to this C2H5OH(aq), 0.100 M Mg3(PO4)2(aq), 0.250 M
solution, vapour pressure of the solution increases KBr(aq) and 0.125 M Na3PO4(aq) at 25°C. Which
by 10 mmHg. Vapour pressure (in mmHg) of X and statement is true about these solutions, assuming
Y in their pure states will be, respectively all salts to be strong electrolytes?
[AIEEE-2009] [JEE (Main)-2014]
(1) 300 and 400 (2) 400 and 600 (1) They all have the same osmotic pressure.
(3) 500 and 600 (4) 200 and 300 (2) 0.100 M Mg 3 (PO 4 ) 2 (aq) has the highest
3. If sodium sulphate is considered to be completely osmotic pressure.
dissociated into cations and anions in aqueous (3) 0.125 M Na3PO4(aq) has the highest osmotic
solution, the change in freezing point of water ('Tf), pressure.
when 0.01 mol of sodium sulphate is dissolved in
(4) 0.500 M C2H5OH(aq) has the highest osmotic
1 kg of water, is (Kf = 1.86 K kg mol–1) pressure.
[AIEEE-2010]
8. The vapour pressure of acetone at 20°C is 185 torr.
(1) 0.0186 K (2) 0.0372 K W hen 1.2 g of a non-volatile substance was
(3) 0.0558 K (4) 0.0744 K dissolved in 100 g of acetone at 20°C, its vapour
pressure was 183 torr. The molar mass (g mol–1)
4. On mixing, heptane and octane from an ideal
of the substance is [JEE (Main)-2015]
solution. At 373 K, the vapour pressures of the two
liquid components (heptane and octane) are 105 (1) 32 (2) 64
kPa and 45 kPa respectively. Vapour pressure of (3) 128 (4) 488
the solution obtained by mixing 25.0 g of heptane
and 35 g of octane will be (molar mass of heptane 9. 18 g glucose (C6H12O6) is added to 178.2 g water.
= 100 g mol–1 and of octane = 114 g mol–1) The vapor pressure of water (in torr) for this
[AIEEE-2010] aqueous solution is [JEE (Main)-2016]
(1) 76.0 (2) 752.4
(1) 144.5 kPa (2) 72.0 kPa
(3) 36.1 kPa (4) 96.2 kPa (3) 759.0 (4) 7.6

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10. The freezing point of benzene decreases by 0.45ºC 15. K2HgI4 is 40% ionised in aqueous solution. The value
when 0.2 g of acetic acid is added to 20 g of of its van’t Hoff factor (i) is [JEE (Main)-2019]
benzene. If acetic acid associates to form a dimer
in benzene, percentage association of acetic acid (1) 1.6 (2) 2.0
in benzene will be (Kf for benzene = 5.12 K kg (3) 2.2 (4) 1.8
mol–1) [JEE (Main)-2017]
16. Freezing point of a 4% aqueous solution of X is
(1) 74.6% (2) 94.6%
equal to freezing point of 12% aqueous solution of
(3) 64.6% (4) 80.4% Y. If molecular weight of X is A, then molecular
11. Which one of the following statements regarding weight of Y is [JEE (Main)-2019]
Henry's law is not correct? [JEE (Main)-2019] (1) 2A (2) 3A
(1) Different gases have different KH (Henry's law (3) A (4) 4A
constant) values at the same temperature
(Since density of solutions are not given therefore
(2) The value of KH increases with increase of
assuming molality to be equal to molarity and
temperature and KH is function of the nature of
the gas given % as % W/V)

(3) The partial pressure of the gas in vapour phase
is proportional to the mole fraction of the gas
in the solution
(4) Higher the value of KH at a given pressure,
higher is the solubility of the gas in the liquids.
17. Molecules of benzoic acid (C6H5COOH) dimerise in
benzene. ‘w’ g of the acid dissolved in 30 g of
benzene shows a depression in freezing point
equal to 2 K. If the percentage association of the
acid to form dimer in the solution is 80, then w is

12. Liquids A and B form an ideal solution in the entire (Given that Kf = 5 K kg mol–1, Molar mass of
composition range. At 350 K, the vapor pressures benzoic acid = 122 g mol–1) [JEE (Main)-2019]
of pure A and pure B are 7 × 103 Pa and 12 × 103 (1) 1.5 g (2) 2.4 g
Pa, respectively. The composition of the vapor in
equilibrium with a solution containing 40 mole (3) 1.8 g (4) 1.0 g
percent of A at this temperature is
18. The vapour pressures of pure liquids A and B are
[JEE (Main)-2019] 400 and 600 mmHg, respectively at 298 K. On
(1) xA = 0.76; xB = 0.24 (2) xA = 0.37; xB = 0.63 mixing the two liquids, the sum of their initial
volumes is equal to the volume of the final mixture.
(3) xA = 0.28; xB = 0.72 (4) xA = 0.4; xB = 0.6
The mole fraction of liquid B is 0.5 in the mixture.
13. Elevation in the boiling point for 1 molal solution of The vapour pressure of the final solution, the mole
glucose is 2 K. The depression in the freezing fractions of components A and B in vapour phase,
point for 2 molal solution of glucose in the same respectively are [JEE (Main)-2019]
solvent is 2 K. The relation between Kb and Kf is
(1) 500 mmHg, 0.4, 0.6 (2) 500 mmHg, 0.5, 0.5
[JEE (Main)-2019]
(3) 450 mmHg, 0.4, 0.6 (4) 450 mmHg, 0.5, 0.5
(1) Kb = 0.5 Kf (2) Kb = 2 Kf
19. For the solution of the gases w, x, y and z in water
(3) Kb = 1.5 Kf (4) Kb = Kf
at 298 K, the Henrys law constants (KH) are 0.5,
14. The freezing point of a diluted milk sample is found 2, 35 and 40 kbar, respectively. The correct plot for
to be –0.2°C, while it should have been –0.5°C for
the given data is : [JEE (Main)-2019]
pure milk. How much water has been added to
pure milk to make the diluted sample?
[JEE (Main)-2019]
(1) 3 cups of water and 2 cups of pure milk (1) Partial z
pressure y
(2) 1 cup of water and 2 cups of pure milk
x
(3) 2 cups of water to 3 cups of pure milk w
(0, 0) Mole fraction
(4) 1 cup of water to 3 cups of pure milk of water

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 22. Molal depression constant for a solvent is
4.0 K kg mol–1. The depression in the freezing
z
point of the solvent for 0.03 mol kg–1 solution of
y
(2) Partial K2SO4 is
pressure
x (Assume complete dissociation of the electrolyte)
w
(0, 0) Mole fraction [JEE (Main)-2019]
of water
(1) 0.36 K (2) 0.18 K
z
y (3) 0.12 K (4) 0.24 K

w 23. At room temperature, a dilute solution of urea is

x
prepared by dissolving 0.60 g of urea in 360 g of
(3) Partial water. If the vapour pressure of pure water at this
pressure
temperature is 35 mmHg, lowering of vapour pressure
will be : (molar mass of urea = 60 g mol–1)
(0, 0) Mole fraction
of water
[JEE (Main)-2019]

z (1) 0.031 mmHg (2) 0.017 mmHg

(3) 0.028 mmHg (4) 0.027 mmHg
y
Partial 24. 1 g of a non-volatile non-electrolyte solute is
(4) pressure
x dissolved in 100 g of two different solvents A and
w B whose ebullioscopic constants are in the ratio of
1 : 5. The ratio of the elevation in their boiling
(0, 0) Mole fraction
of water 'Tb A
20. Liquid ‘M’ and liquid ‘N’ form an ideal solution. The points, 'T B , is : [JEE (Main)-2019]
b
vapour pressures of pure liquids ‘M’ and ‘N’ are
450 and 700 mmHg, respectively, at the same (1) 1 : 5 (2) 10 : 1
temperature. Then correct statement is
(xM = Mole fraction of ‘M’ in solution; (3) 5 : 1 (4) 1 : 0.2
xN = Mole fraction of ‘N’ in solution; 25. A solution is prepared by dissolving 0.6 g of urea
yM = Mole fraction of ‘M’ in vapour phase; (molar mass = 60 g mol–1) and 1.8 g of glucose
yN = Mole fraction of ‘N’ in vapour phase) (molar mass = 180 g mol–1) in 100 mL of water at
27°C. The osmotic pressure of the solution is
[JEE (Main)-2019]
(R = 0.08206 L atm K–1 mol–1) [JEE (Main)-2019]
x yM
(1) M
xN yN (1) 1.64 atm (2) 2.46 atm
x M yM (3) 8.2 atm (4) 4.92 atm
(2) !
x N yN
26. A solution containing 62 g ethylene glycol in
x y 250 g water is cooled to –10°C. If Kf for water is
(3) M  M
x N yN 1.86 K kg mol –1 , the amount of water (in g)
(4) (xM – yM) < (xN – yN) separated as ice is [JEE (Main)-2019]

21. The osmotic pressure of a dilute solution of an (1) 64 (2) 32

ionic compound XY in water is four times that of a
(3) 16 (4) 48
solution of 0.01 M BaCl 2 in water. Assuming
complete dissociation of the given ionic compounds 27. At 35°C, the vapour pressure of CS2 is 512 mm Hg
in water, the concentration of XY (in mol L–1) in and that of acetone is 344 mm Hg. A solution of
solution is [JEE (Main)-2019] CS2 in acetone has a total vapour pressure of 600
(1) 16 × 10–4 (2) 4 × 10–4 mm Hg. The false statement amongst the following
(3) 6 × 10–2 (4) 4 × 10–2 is [JEE (Main)-2020]

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 (1) Raoult’s law is not obeyed by this system
(2) A mixture of 100 mL CS2 and 100 mL acetone
has a volume < 200 mL
(3) Heat must be absorbed in order to produce the
solution at 35°C
(4) CS2 and acetone are less attracted to each
other than to themselves
28. Two open beakers one containing a solvent and the
other containing a mixture of that solvent with a
non volatile solute are together sealed in a
container. Over time [JEE (Main)-2020]
(1) The volume of the solution and the solvent
does not change
30. An open beaker of water in equilibrium with water
vapour is in a sealed container. When a few grams
of glucose are added to the beaker of water, the rate
at which water molecules [JEE (Main)-2020]
(1) Leaves the solution increases
(2) Leaves the vapour increases
(3) Leaves the vapour decreases
(4) Leaves the solution decreases
31. The size of a raw mango shrinks to a much smaller
size when kept in a concentrated salt solution.
Which one of the following processes can explain
this? [JEE (Main)-2020]

(2) The volume of the solution increases and the (1) Osmosis
volume of the solvent decreases
(2) Reverse osmosis
(3) The volume of the solution does not
(3) Diffusion
change and the volume of the solvent
decreases (4) Dialysis

(4) The volume of the solution decreases and the 32. Henry’s constant (in kbar) for four gases D, E, J
volume of the solvent increases. and G in water at 298 K is given below
29. A graph of vapour pressure and temperature for
D E J G
three different liquids X, Y, and Z is shown below –5
KH 50 2 2 × 10 0.5
Vapour pressure

X Y Z (density of water = 103 kg m–3 at 298 K)

800
(mm Hg)

500 This table implies that [JEE (Main)-2020]

400
200 (1) The pressure of a 55.5 molal solution of J is 1
bar
0 293 313 333 353
(2) Solubility of J at 308 K is lower than at
Temp
298 K
The following inferences are made
(3) D has the highest solubility in water at a given
(A) X has higher intermolecular interactions pressure
compared to Y.
(4) The pressure of a 55.5 molal solution of G is 250
(B) X has lower intermolecular interactions bar
compared to Y
33. A set of solutions is prepared using 180 g of water
(C) Z has lower intermolecular interactions as a solvent and 10 g of different non-volatile
compared to Y. solutes A, B and C. The relative lowering of vapour
The correct inferences is/are [JEE (Main)-2020] pressure in the presence of these solutes are in
the order [Given, molar mass of A = 100 g mol–1;
(1) (B) B = 200 g mol–1; C = 10,000 g mol–1]
(2) (C) [JEE (Main)-2020]
(3) (A) and (C) (1) A > C > B (2) C > B > A
(4) (A)
(3) A > B > C (4) B > C > A
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34. How much amount of NaCl should be added to 600
g of water (U = 1.00 g/mL) to decrease the
freezing point of water to –0.2°C? ________.
(The freezing point depression constant for water =
2 K kg mol–1) [JEE (Main)-2020]
35. A cylinder containing an ideal gas (0.1 mol of
1.0 dm3) is in thermal equilibrium with a large volume
of 0.5 molal aqueous solution of ethylene glycol at
its freezing point. If the stoppers S1 and S2 (as shown
in the figure) are suddenly withdrawn, the volume
of the gas in litres after equilibrium is achieved will
be ________ .
(Given, Kf (water) = 2.0 K kg mol–1, R = 0.08 dm3
atm K–1 mol–1)
[JEE (Main)-2020]
36. If 250 cm3 of an aqueous solution containing 0.73
g of a protein A is isotonic with one litre of another
aqueous solution containing 1.65 g of a protein B,
at 298 K, the ratio of the molecular masses of A
and B is __________ × 10 –2 (to the nearest
integer). [JEE (Main)-2020]
37. At 300 K, the vapour pressure of a solution
containing 1 mole of n-hexane and 3 moles of n-
heptane is 550 mm of Hg. At the same temperature,
if one more mole of n-heptane is added to this
solution, the vapour pressure of the solution
increases by 10 mm of Hg. What is the vapour
pressure in mm Hg of n-heptane in its pure
state ______? [JEE (Main)-2020]
38. The osmotic pressure of a solution of NaCl is 0.10
atm and that of a glucose solution is
0.20 atm. The osmotic pressure of a solution
formed by mixing 1 L of the sodium chloride
solution with 2 L of the glucose solution is
x × 10–3 atm. x is _____. (nearest integer)
[JEE (Main)-2020]
39. The elevation of boiling point of 0.10 m aqueous
CrCl3.xNH3 solution is two times that of 0.05 m
aqueous CaCl2 solution. The value of x is ______.
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[Assume 100% ionisation of the complex and CaCl2,
coordination number of Cr as 6, and that all NH3
molecules are present inside the coordination sphere]
[JEE (Main)-2020]
40. A soft drink was bottled with a partial pressure of
CO2 of 3 bar over the liquid at room temperature. The
partial pressure of CO2 over the solution approaches
a value of 30 bar when 44 g of CO2 is dissolved in
1 kg of water at room temperature. The approximate
pH of the soft drink is ______ × 10–1.
(First dissociation constant of H 2 CO 3 =
4.0 × 10 –7 ; log 2 = 0.3; density of the soft
drink = 1 g mL–1) [JEE (Main)-2020]
41. 10.30 mg of O2 is dissolved into a liter of sea water
of density 1.03 g/mL. The concentration of O2 in
ppm is __________ . [JEE (Main)-2020]
42. W hen 9.45 g of ClCH 2 COOH is added to
500 mL of water, its freezing point drops by 0.5°C.
The dissociation constant of ClCH2COOH is x ×
10–3. The value of x is _______. (Rounded off to
the nearest integer)
[K f (H2O ) 1.86 K kg mol1 ] [JEE (Main)-2021]
43. C6H6 freezes at 5.5°C. The temperature at which a
solution of 10 g of C4H10 in 200 g of C6H6 freeze
is ____ °C. (The molal freezing point depression
constant of C6H6 is 5.12°C/m.)
[JEE (Main)-2021]
44. 1 molal aqueous solution of an electrolyte A2B3 is
60% ionised. The boiling point of the solution at 1
atm is __________ K. (Rounded-off to the nearest
integer)
[Given Kb for (H2O) = 0.52 K kg mol–1]
[JEE (Main)-2021]
45. If a compound AB dissociates to the extent of 75%
in an aqueous solution, the molality of the solution
which shows a 2.5 K rise in the boiling point of the
solution is ____ molal. (Rounded-off to the nearest
integer)
[Kb = 0.52 K kg mol–1] [JEE (Main)-2021]
46. 224 mL of SO2(g) at 298 K and 1 atm is passed
through 100 mL of 0.1 M NaOH solution. The non-
volatile solute produced is dissolved in 36 g of
water. The lowering of vapour pressure of solution
(assuming the solution is dilute)
PqH O is x × 10–2 mm of Hg, the
24 mm of Hg
2
value of x is _________. (Integer answer)
[JEE (Main)-2021]
47. When 12.2 g of benzoic acid is dissolved in 100 g
of water, the freezing point of solution was found to
be –0.93°C (Kf (H2O) = 1.86 K kg mol–1). The
number (n) of benzoic acid molecules associated
(assuming 100% association) is __________.
[JEE (Main)-2021]
48. AB2 is 10% dissociated in water to A2+ and B–.
The boiling point of a 10.0 molal aqueous solution
of AB2 is __________°C. (Round off to the Nearest
Integer)
[Given : Molal elevation constant of water Kb = 0.5
K kg mol–1 boiling point of pure water = 100°C]
[JEE (Main)-2021]
49. At 363 K, the vapour pressure of A is 21 kPa and
that of B is 18 kPa. One mole of A and 2 moles
of B are mixed. Assuming that this solution is
ideal, the vapour pressure of the mixture is
___________ kPa.
(Round off to the Nearest Integer]
[JEE (Main)-2021]
50. The mole fraction of a solute in a 100 molal
aqueous solution is ____ × 10–2.
(Round off to the Nearest Integer).
[Given : Atomic masses : H : 1.0 u, O : 16.0 u]
[JEE (Main)-2021]
51. The oxygen dissolved in water exerts a partial
pressure of 20 kPa in the vapour above water. The
molar solubility of oxygen in water is _________ ×
10–5 mol dm–3.
(Round off to the Nearest Integer).
[Given : Henry’s law constant = KH = 8.0 × 104 kPa
for O2.
Density of water with dissolved oxygen
= 1.0 kg dm–3]
[JEE (Main)-2021]
52. A 1 molal K4Fe(CN)6 solution has a degree of
dissociation of 0.4. Its boiling point is equal to that
of another solution which contains 18.1 weight
percent of a non electrolytic solute A. The molar
mass of A is ______ u. (Round off to the Nearest
Integer).
[Density of water = 1.0 g cm–3]
[JEE (Main)-2021]
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53. 2 molal solution of a weak acid HA has a freezing
point of 3.885°C. The degree of dissociation of this
acid is _____ × 10–3.
(Round off to the Nearest Integer).
[Given : Molal depression constant of water =
1.85 K kg mol–1
Freezing point of pure water = 0°C]
[JEE (Main)-2021]
54. A solute A dimerizes in water. The boiling point of
a 2 molal solution of A is 100.52°C. The percentage
association of A is ______. (Round off to the
Nearest Integer).
[Use : Kb for water = 0.52 K kg mol–1
Boiling point of water = 100°C]
[JEE (Main)-2021]
55. At 20°C, the vapour pressure of benzene is 70 torr
and that of methyl benzene is 20 torr. The mole
fraction of benzene in the vapor phase at 20°C
above an equimolar mixture of benzene and methyl
benzene is ________ × 10–2. [JEE (Main)-2021]
(Nearest integer)
56. The vapour pressures of A and B at 25°C are 90
mm Hg and 15 mm Hg respectively. If A and B are
mixed such that the mole fraction of A in the
mixture is 0.6, then the mole fraction of B in the
vapour phase is x × 10 –1 . The value of x is
________. (Nearest integer) [JEE (Main)-2021]
57. W hich one of the following 0.06 M aqueous
solutions has lowest freezing point?
[JEE (Main)-2021]
(1) Kl (2) Al2(SO4)3
(3) C6H12O6 (4) K2SO4
58. CO2 gas is bubbled through water during a soft
drink manufacturing process at 298 K. If CO 2
exerts a partial pressure of 0.835 bar then x m mol
of CO2 would dissolve in 0.9 L of water. The value
of x is _______. (Nearest integer)
(Henry’s law constant for CO2 at 298 K is 1.67 ×
103 bar) [JEE (Main)-2021]
59. When 3.00 g of a substance ‘X’ is dissolved
in 100 g of CCl4, it raises the boiling point by 0.60
K. The molar mass of the substance ‘X’ is
________ g mol–1. (Nearest integer)
[Given Kb for CCl4 is 5.0 K kg mol–1]
[JEE (Main)-2021]
60. 1.46 g of a biopolymer dissolved in a 100 mL monomer in acetone. The boiling point of the
water at 300 K exerted an osmotic pressure of 2.42 solution in acetone increases by 0.17°C. The
× 10–3 bar.
increase in boiling point of solution in benzene in
The molar mass of the biopolymer is ________ × °C is x × 10–2. The value of x is _______. (Nearest
104 g mol–1. (Round off to the Nearest Integer)
integer)
[Use : R = 0.083 L bar mol–1 K–1]
[Atomic mass : C = 12.0, H = 1.0, O = 16.0]
[JEE (Main)-2021]
[JEE (Main)-2021]
61. In a solvent 50% of an acid HA dimerizes and the
rest dissociates. The van’t Hoff factor of the acid is 68. The osmotic pressure of blood is 7.47 bar at 300 K.
______ × 10–2. (Round off to the Nearest Integer).
To inject glucose to a patient intravenously, it has
[JEE (Main)-2021]
to be isotonic with blood. The concentration of
62. Of the following four aqueous solutions, total
glucose solution in gL–1 is _______. (Molar mass of
number of those solutions whose freezing point is
lower than that of 0.10 M C2H5OH is _______. glucose = 180 g mol–1
(Integer answer) [JEE (Main)-2021]
R = 0.083 L bar K–1 mol–1) (Nearest integer)
(i) 0.10 M Ba3(PO4)2 (ii) 0.10 M Na2SO4
[JEE (Main)-2022]
(iii) 0.10 M KCl (iv) 0.10 M Li3PO4
63. 83 g of ethylene glycol dissolved in 625 g of water. 69. A company dissolves ‘x’ amount of CO2 at 298 K in
The freezing point of the solution is _____ K. 1 litre of water to prepare soda water. X = _____
(Nearest integer) [JEE (Main)-2021] × 10–3 g. (nearest integer)
[Use : Molal freezing point depression constant
(Given: partial pressure of CO2 at 298 K = 0.835 bar.
of water = 1.86 K kg mol–1,
Freezing point of water = 273 K, Henry’s law constant for CO2 at 298 K = 1.67 kbar.

Atomic masses : C : 12.0 u, O : 16.0 u, H : 1.0 u] Atomic mass of H, C and O is 1, 12, and 6 g mol–1,
64. 1 kg of 0.75 molal aqueous solution of sucrose can respectively) [JEE (Main)-2022]
be cooled up to –4ºC before freezing. The amount
70. Solute A associates in water. When 0.7 g of solute
of ice (in g) that will be separated out is _______.
(Nearest integer) [JEE (Main)-2021] A is dissolved in 42.0 g of water, it depresses the
freezing point by 0.2°C. The percentage association
[Given : Kf(H2O) = 1.86 K kg mol–1]
of solute A in water is :
65. 40 g of glucose (Molar mass = 180) is mixed with
200 mL of water. The freezing point of solution is [Given : Molar mass of A = 93 g mol–1. Molal
_____ K. (Nearest integer) [JEE (Main)-2021] depression constant of water is 1.86 K kg mol–1.]
[Given : Kf = 1.86 K kg mol–1; Density of water = [JEE (Main)-2022]
1.00 g cm–3; Freezing point of water = 273.15 K]
(1) 50% (2) 60%
66. W hich one of the following 0.10 M aqueous
solutions will exhibit the largest freezing point (3) 70% (4) 80%
depression? [JEE (Main)-2021]
71. A 0.5 percent solution of potassium chloride was
(1) Glycine (2) KHSO4
found to freeze at –0.24°C. The percentage
(3) Hydrazine (4) Glucose
dissociation of potassium chloride is ______.
67. 1.22 g of an organic acid is separately dissolved in (Nearest integer)
100 g of benzene (Kb = 2.6 K kg mol–1) and 100
(Molal depression constant for water is 1.80 K kg
g of acetone (Kb = 1.7 K kg mol–1). The acid is
mol–1 and molar mass of KCl is 74.6 g mol–1)
known to dimerize in benzene but remain as a
[JEE (Main)-2022]
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72. The osmotic pressure exerted by a solution prepared
by dissolving 2.0 g of protein of molar mass 60 kg
mol–1 in 200 mL of water at 27°C is _________ Pa.
[Integer value]
(use R = 0.083 L bar mol–1 K–1) [JEE (Main)-2022]
73. 2 g of a non-volatile non-electrolyte solute is
dissolved in 200 g of two different solvents A and B
whose ebullioscopic constants are in the ratio of
1 : 8. The elevation in boiling points of A and B are in
x 0.0405°C. Density of formic acid is 1.05 g mL–1.
the ratio y (x : y). The value of y is ______. (Nearest
Integer) [JEE (Main)-2022]
74. A solution containing 2.5 × 10–3 kg of a solute
dissolved in 75 × 10 –3 kg of water boils at
373.535 K. The molar mass of the solute is _____ g
mol–1. [nearest integer] (Given : Kb(H2O) = 0.52 K kg
mol–1 and boiling point of water = 373.15 K)
[JEE (Main)-2022]
75. The vapour pressures of two volatile liquids A and B
at 25°C are 50 Torr and 100 Torr, respectively. If the
liquid mixture, contains 0.3 mole fraction of A, then
the mole fraction of liquid B in the vapour phase is
x (3) 1 : 0.20
. The value of x is _______. [JEE (Main)-2022]
17
76. 2.5 g of protein containing only glycine (C2H5NO2)
is dissolved in water to make 500 mL of solution.
The osmotic pressure of this solution at 300 K is
found to be 5.03 × 10–3 bar. The total number of
glycine units present in the protein is _______.
(Given : R = 0.083 L bar K–1 mol–1)
[JEE (Main)-2022]
77. 1.2 mL of acetic acid is dissolved in water to make
2.0 L of solution. The depression in freezing point
observed for this strength of acid is 0.0198°C. The
percentage of dissociation of the acid is ____ .
(Nearest integer)
[Given: Density of acetic acid is 1.02 g mL–1
Molar mass of acetic acid is 60 g mol–1
Kf(H2O) = 1.85 K kg mol–1]
[JEE (Main)-2022]
Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456
78. Elevation in boiling point for 1.5 molal solution of
glucose in water is 4 K. The depression in freezing
point for 4.5 molal solution of glucose in water is
4 K. The ratio of molal elevation constant to molal
depression constant (Kb/Kf) is ___.
[JEE (Main)-2022]
79. The depression in freezing point observed for a
formic acid solution of concentration 0.5 mL L–1 is
The Van’t Hoff factor of the formic acid solution is
nearly (Given for water Kf = 1.86 k kg mol–1)
[JEE (Main)-2022]
(1) 0.8 (2) 1.1
(3) 1.9 (4) 2.4
80. Two solutions A and B are prepared by dissolving
1 g of non-volatile solutes X and Y, respectively in
1 kg of water. The ratio of depression in freezing
points for A and B is found to be 1 : 4. The ratio
of molar masses of X and Y is
[JEE (Main)-2022]
(1) 1 : 4 (2) 1 : 0.25
(4) 1 : 5
81. The elevation in boiling point for 1 molal solution
of non-volatile solute A is 3 K. The depression in
freezing point for 2 molal solution of A in the same
solvent is 6 K. The ratio of Kb and Kf i.e., Kb/Kf is
1 : X. The value of X is [nearest integer]
[JEE (Main)-2022]
82. Boiling point of a 2% aqueous solution of a non-
volatile solute A is equal to the boiling point of 8%
aqueous solution of a non-volatile solute B. The
relation between molecular weights of A and B is
[JEE (Main)-2022]
(1) MA = 4MB (2) MB = 4MA
(3) MA = 8MB (4) MB = 8MA
83. When a certain amount of solid A is dissolved in
100 g of water at 25°C to make a dilute solution,
the vapour pressure of the solution is reduced to
one-half of that of pure water. The vapour pressure
of pure water is 23.76 mmHg. The number of
moles of solute A added is _________. (Nearest
Integer) [JEE (Main)-2022]
84. 150 g of acetic acid was contaminated with 10.2 (Given : Henry’s Law constant for O2 at 303 K is 46.82
g ascorbic acid (C6H8O6) to lower down its freezing k bar and partial pressure of O2 = 0.920 bar)
point by (x × 10–1)°C. The value of x is ______.
(Assume solubility of O2 in water is too small, nearly
(Nearest integer)
negligible) [JEE (Main)-2022]
(Given : Kf = 3.9 K kg mol–1; molar mass of ascorbic
acid = 176 g mol–1) [JEE (Main)-2022] 87. 1.80 g of solute A was dissolved in 62.5 cm 3 of
85. A gaseous mixture of two substances A and B, ethanol and freezing point of the solution was
under a total pressure of 0.8 atm is in equilibrium
found to be 155.1 K. The molar mass of solute A
with an ideal liquid solution. The mole fraction of
substance A is 0.5 in the vapour phase and 0.2 in is ____ g mol–1.
the liquid phase. The vapour pressure of pure liquid
[Given : Freezing point of ethanol is 156.0 K.
A is ______ atm. (Nearest integer)
[JEE (Main)-2022] Density of ethanol is 0.80 g cm–3.
86. If O2 gas is bubbled through water at 303 K, the
Freezing point depression constant of ethanol is
number of millimoles of O2 gas that dissolve in 1
2.00 K kg mol–1] [JEE (Main)-2022]
litre of water is_______. (Nearest integer)

‰‰‰

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Chapter 10

Solutions
1. Answer (1) 5. Answer (4)

Ethanol has H-Bonding, n-heptane tries to break the For isotonic solution
H-bonds of ethanol, hence, V.P. increases. Such a S1 = S2
solution shows positive deviation from Raoult's Law. C1 = C2
2. Answer (2) W1 W2
M1V1 M 2 V2
Let V. P. of pure X = x
and V. P. of pure Y = y 5 1
=
342 u100 M2 u100
1 3
Then, x + y = 550 ...(i) M2 = 68.4
4 4
6. Answer (1)
1 4 7. Answer (1)
and x + y = 560 ...(ii)
5 5 S i CRT
Solving (i) and (ii), we get SC2H5OH 1u 0.500 uR u T 0.5RT
x = 400 mm
SMg3 (PO4 )2 5 u 0.100 u R u T 0.5 RT
and y = 600 mm
3. Answer (3) SKBr 2 u 0.250 u R u T 0.5 RT

'Tf = i Kfm SNa3PO4 4 u 0.125 u RT 0.5 RT

i for Na2SO4 is 3(100% ionisation) 8. Answer (2)
0.01 Vapour pressure of pure acetone P°A 185 torr
'Tf = 3 × 1.86 ×
1
Vapour pressure of solution, PS = 183 torr
'Tf = 0.0558 K
Molar mass of solvent, MA = 58 g/mole
4. Answer (2)
P°A  PS nB
as we know
P XAPAo  XBPBo PS nA

25 185  183 WB MA
nheptane 0.25 Ÿ u
100 183 MB WA
35
noctane = 0.307
114 2 1.2 58
Ÿ u
183 MB 100
0.25 0.307
P u105  u 45
0.25  0.307 0.25  0.307 1.2 58
Ÿ MB u u183
= 47.127 + 24.84 = 71.96 2 100

| 72 kPa 63.68 g/mole

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9. Answer (2) 13. Answer (2)
'Tb = kbm Ÿ kb(1) = 2 Ÿ kb = 2 km–1
18
pº –ps nsolute 18 'Tf = kfm Ÿ kf(2) = 2 Ÿ kf = 1 km–1
180
ps nsolvent 178.2 17.82 kf = 0.5 kb Ÿ kb = 2 kf
18
14. Answer (1)
At normal boiling point of water V.P. = pº = 760 torr Freezing point of diluted milk = – 0.2°C

760 – ps 18 ' Tfc 0.2qC

?
ps 1782
Freezing point of pure milk = – 0.5°C
or, 1800 ps = 760 × 1782 'Tf = 0.5°C
ps = 752.4 torr
' Tf kf m
10. Answer (2) ' Tfc k f mc

0.2 / 60
0.45 = i(5.12) u 1000 0.5 w1c
20 Ÿ
0.2 w1
Ÿ i = 0.527

w1c 5
ZZZ
X
2CH3 COOH YZZ
Z CH3 COOH 2 Ÿ
1– D D w1 2
2
2 cups of pure milk mixed with 3 cups of water
D overall 5 cups of diluted milk.
Ÿ i 1–
2 15. Answer (4)

Z 2K  >HgI4 @
 2–
D ZZZ
X
K 2HgI4 YZZ
Ÿ 0.527 = 1 –
2
n=3
D
Ÿ = 0.473 i1
2 ' D
n 1
Ÿ D = 0.946
? % association = 94.6% i 1
0.4
3 1
11. Answer (4)
Solubility decreases with the increase in value of KH. i = 1.8

12. Answer (3) 16. Answer (2)

PA° = 7 × 103
4 12
PB° = 12 × 103 Mx My
XA = 0.4
Ÿ My = 3Mx
XB = 0.6
? My = 3A
? P = (7 × 0.4 + 12 × 0.6) × 103 = 104
(Since density of solutions are not given therefore
PA = 2.8 × 103, PB = 7.2 × 103
assuming molality to be equal to molarity and given
? YA = 0.28, YB = 0.72 % as % W/V)

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17. Answer (2) 20. Answer (2)
2C6H5COOH o (C6H5COOH)2
PMo 450 mmHg, PNo 700 mmHg
t=0 1 0
t 1 – 2D D PM PMo XM YMPT
Moles at equilibrium = 1 – 2D + D = 1 – D
o YM
2D = 0.8, D = 0.4 Ÿ PM (PT )
XM
Moles at equilibrium = 0.6
i = 0.6 YN
Similarly, PNo (PT )
§ w · XN
u 1000
'Tf = ikfm Ÿ 2 = 0.6 × 5 × ¨ 122 ¸
¨ ¸
© 30 ¹ Given, PMo  PNo
w = 2.4 g
18. Answer (1) YM Y
Ÿ  N
P = xBpB° + xAp°A XM XN

= 0.5 × 600 + 0.5 × 400 = 300 + 200 = 500

YM XM
pB = yBPTotal Ÿ 
YN XN
pB 300 3
yB = P 0.6 21. Answer (3)
Total 500 5
SXY 4SBaCl2
pA 200 2
yA = P 0.4 ? 2[XY] = 4 u(0.01)u 3
Total 500 5

19. Answer (1) 2 mol

[XY] = 0.06 = 6 u 10
L
According to Henry’s law,
P = KH ˜ Xgas 22. Answer (1)

' x gas 1– xH2O K 2SO4 o 2K   SO24

P KH – KH ˜ XH2O i (van’t Hoff Factor) = 3

?
? 'Tf = iKfm
y = C + mx
= 3 × 4 × 0.03
= 0.36 K
23. Answer (2)
Partial z Relative lowering of VP is given by
pressure y
x PBº  PB nA n
w xA  A
(0, 0) xH2O PBº n A  nB nB
gas KH
w 0.5 PBº  PB 0.6 u 18 1
x 2 35 60 u 360 2000

y 35
On solving, 'PB PBº  PB 0.017
z 50

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24. Answer (1) 29. Answer (1)
'Tb = kb × m Vapour pressure of a liquid at a given temperature is
inversely proportional to intermolecular force of
(kb )A 1 attraction. At the same temperature, vapour pressure
(k b )B 5 of X is higher than that of Y.
Therefore (X) has lower intermolecular interactions
( 'Tb )A (k b )A 1 compared to Y. Statement (B) is correct.
? ( 'Tb )B (k b )B 5 30. Answer (4)
The rate at which water molecules leaves the solution
25. Answer (4)
decreases.
Osmotic pressure (S) = CRT
31. Answer (1)
Solute : urea and glucose Osmosis can explain the given process. There are
? S = (C1 + C2) RT many phenomena which we observed in nature or at
home. Raw mango shrivel when pickled in brine.
§ 0.6 1.8 · The solvent molecules will flow through the
= ¨ + ¸ × 0.0821 × 300
© 60 × 0.1 180 × 0.1 ¹ membrane from pure solvent to the solution. This
process of flow of the solvent is called osmosis.
= 0.2 × 0.0821 × 300
32. Answer (2)
= 4.926 atm
W ith temperature, the value of K H (Henry’s
26. Answer (1) constant) increases and solubility of gas in liquid
'Tf = Kf × m decreases
Ideally Henry’s law is applicable for dilute solutions.
62 u 1000
Ÿ 10 = 1.86 × ? 55.5 molal solution of G at 250 bar will not follow
62 u w A
Henry’s law.
33. Answer (3)
1.86 u 1000
Ÿ wA =
10 Relative lowering in vapour pressure (RLVP)
P – Ps n
= 186 g
P nN
Given amount of H2O is 250 g
n o moles of solute
? The amount of water separated as ice
N o moles of solvent
= 250 – 186 = 64 g
27. Answer (2) 10 10 10
nA ,n B ,n C
100 200 10000
Since the vapour pressure of the solution is greater
than individual vapour pressure of both pure From the above relation
components, the solution shows a positive deviation RLVP (A) > RLVP (B) > RLVP (C)
from Raoult’s law.
A>B>C
28. Answer (2) 34. Answer (1.76)
There will be lowering in vapour pressure for solution 'Tf = 0.2°C
containing non-volatile solute. So, there will be
'
'Tf = ikf˜m
transfer of solvent molecules from pure solvent to
solution and hence, volume of beaker containing i = 2 for NaCl
solvent (pure) will decrease and volume of beaker
W NaCl u 1000
containing solution will increase. ? 0.2 = 2 u 2 u
58.5 u 600

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 58.5 u 600 u 0.2 38. Answer (167.00)
Ÿ W NaCl
4 u 1000
0.10
= 1.755 For NaCl: S1 = iC1RT Ÿ C1 = 2 RT
= 1.76
35. Answer (2.18) 0.20
For Glucose: S2 = C2RT Ÿ C2 =
For aqueous solution RT
'Tf = Kf.m = 2 × 0.5
When 1 L of NaCl solution and 2 L glucose solution
? Temperature of solution = –1°C = 272 K
are mixed.
nRT
? Final volume of ideal gas = 0.10 0.20 u 2 0.40
P ? Cc1 and Cc2
6 RT 3 RT 3 RT
0.1u 0.08 u 272
=
1 0.10 0.40 0.50
? S Total iCc1RT  Cc2RT 
| 2.18 L 3 3 3
36. Answer (177)
Isotonic solutions have the same osmotic pressure. S Total  167 u 10 3 atm
0.73 u 1000
SA C A RT; C A 39. Answer (5.00)
M A u 250
Molality of CaCl2 solution = 0.05 m
1.65
SB C BRT; C B 'Tb = i Kb m = 3 × Kb × 0.05 = 0.15 Kb
MB
Molality of CrCl3.xNH3 = 0.10 m
SA SB Ÿ C A CB
'Tbc i K b u 0.10; 'Tbc 2'Tb
0.73 u 1000 1.65
? iKb × 0.10 = 2 × 0.15 Kb Ÿ i = 3
M A u 250 MB
Since, co-ordination number of Cr is 6.
MA 2
1.77 177 u 10 ? The complex is [Cr(NH3)5Cl]Cl2
MB
? x=5
37. Answer (600)
40. Answer (37)
If X 1 and P1D are the mole fraction and vapour
At 30 bar pressure mass of CO2 in 1 kg water = 44 gm
pressure of n-hexane in solution and X2 and P2D At 3 bar pressure mass of CO 2 in 1 kg water
are the mole fraction and vapour pressure of n- = 4.4 gm
heptane in solution then
Moles of CO2 in 1 kg water = 0.1
550 X 1P1D  X 2P2D
H 2 CO 3 U H  HCO 3
P1D 3P2D 0.1(1– D ) 0.1D 0.1D
 Ÿ P1D  3P2D 2200 }(1)
4 4 [H  ][HCO 3 ]
Ka 1
On addition of 1 more mole of n-heptane [H 2CO 3 ]

560 Xc1 P1D  Xc2P2D 0.1D 2

4 u 10 –7  0.1D 2
1– D
P1D 4P2D
 Ÿ P1D  4P2D 2800 }(2) D = 2 × 10–3
5 5
[H+] = 0.1 D = 2 × 10–4 ; pH = 3.7
From (1) and (2), P2D 600 mm Hg = 37 × 10–1

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41. Answer (10) 44. Answer (375)

wt. of O 2 A2 B 3 2A 3+ + 3B 2– (Assuming A – cation,

ppm of O 2 u 10 6 1 – 0.6 2 × 0.6 3 × 0.6 B – anion)
wt. of H 2 O
? van’t Hoff factor = 1 – 0.6 + 1.2 + 1.8 = 3.4
10.3 mg 'Tb = ikb ˜ m
= u 10 6
1.03 u 10 6 mg
= 3.4 × 0.52 × 1
= 10 ppm = 1.768
42. Answer (35) Tb = 373 + 1.768

9.45 = 374.77
Moles of ClCH2COOH = 0.1 moles
94.5 | 375
45. Answer (3)
ClCH2 COOH U ClCH2COO   H
At eqm C(1  D ) CD CD ZZZ
X n
ZA  B
AB YZZ n
1D D D
van’t Hoff factor (i) = 1 + D
i = 1 + D = 1 + 0.75 (' D = 0.75)
0.1 = 1.75
C 0.2 M
0.5
'Tb = i Kb m
Assuming molarity = molality
2.5
'Tf ik f ˜ m (1  D )1.86 u 0.2 m 2.75 mol / kg  3
1.75 u 0.52
0.5 46. Answer (24)
Ÿ (1  D ) 1.344 | 1.34
0.2 u 1.86
1 u 0.224
Ÿ D = 0.34 nSO 2 | 0.0092 | 0.01 moles
0.082 u 298
C D ˜ CD
Ka of (ClCH2COOH) = NaOH + SO2 o NaHSO3
C(1  D )
nNaHSO3 0.01
CD 2 0.2 u (0.34)2
1 D 1  0.34 NaHSO3 o Na  HSO3
= 35 × 10–3 Ignoring the dissociation of HSO3 into H+ and
43. Answer (1) SO32 
'Tf ik f m van’t Hoff factor (i) = 2

i 1 for C4H10 ; Tfo 5.5qC PHo2O  PS inNaHSO

3

PHo2O nH2O  inNaHSO

10 u 1000 50 3
m
58 u 200 58
as nHSO  nH2O
Kf 5.12qC / m 3

50 Lowering in vapour presssure

'Tf 5.12 u 4.41 qC
58
2 u 0.01
= u 24
2  2 u 0.01
Tfo  Tf 4.41

Tf 5.50  4.41 1.09  1qC = 23.76 u 10 2 mmHg | 24 u 10 2 mmHg

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47. Answer (02.00)
100 100 u 18
'Tf iK f m Mole fraction of solute = 100  1000 2800
18
12.2 u 1000
0.93 i u 1.86 u = 0.6428 = 64.28 × 10–2
122 u 100
 64
i = 0.5
51. Answer (25)
n(Benzoic acid) o (Benzoic acid)n
PO2 (over water) = 20 kPa
Total number of particles after association
i
Number of particles before association KH for O2 = 8.0 × 104 kPa

If XO2 is the mole fraction of O2 in soution, then

1
0.5 according to Henry’s law
n
PO2 K H (XO2 )
n=2
48. Answer (106)
20
XO 2 2.5 u 10 4
AB2 U A + 2B 2+ – 8.0 u 104

1–D D 2D Mass of 1 kg of water containing O2 = 1 L

i=1+D ? Molarity of O2 in solution = 25 × 10–5 M
i = 1.1 52. Answer (85)

'Tb = Ts –T° = i × K b × molality i for K4[Fe(CN)6] = 1 + (5 – 1) 0.4 = 2.6

'Tb1 2.6 u K f u 1
Ts – 100 = 1.1 × 0.5 × 10
i for A = 1.
Ts = 105.5
18.1u 1000
| 106qC 'Tb 1u u Kf
A
A u 81.9
49. Answer (19)
Equating these two
An ideal solution is prepared by mixing 1 mol of A
and 2 moles of B A = 85

Using Raoult’s law 53. Answer (50)

Ps F A PAo  FBPBo ZZZ

HA YZZ X
Z H

 A
1 D D D
1 2
= u 21  u 18
3 3 (D – degree of dissociation)
van’t Hoff factor (i) = 1 + D
= 19 kPa
Assuming given freezing point is –3.885°C
50. Answer (64)
'Tf = ikf ˜ m
Molality of an aqueous solution of a solute = 100
m Ÿ 3.885 = (1 + D) × 1.85 × 2
Ÿ (1 + D) = 1.05
1000
Number of moles of solvent = D = 0.05
18
= 50 × 10–3
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54. Answer (100) 57. Answer (2)

2A o A2 'TF v i (for equimolar solutions)

D Solute i
1 D
2 KI 2
Al2(SO4)3 5
D
i = 1 D  C6H12O6 1
2
K2SO4 3
Also
58. Answer (25)
'Tb iKbm
According to Henry’s law
0.52 = i × 0.52 × 2
Pgas = Xgas × KH
1
i= 0.835
2 Xgas 5 u 10–4
1.67 u 103
1 D
1 D  ngas ngas
2 2 Xgas |
ngas  nH2O nH2O
D 1
Ÿ 1
2 2 900
ngas 5 u 10 –4 u 0.025 mole or 25 mmol
% of association of A is 100% 18
55. Answer (78) 59. Answer (250)
PTotal XBPBq  XMBPMB
q 'Tb = Kb m

XB – mole fraction of benzene in solution phase 5.0 u 3.00 u 1000

0.60 = M u 100
XMB – mole fraction of methyl benzene in solution
phase M = 250
Molecular weight of the substance = 250
YBPTotal XBPBq
60. Answer (15)
YB – mole fraction of benzene in vapor phase
S = iCRT
0.5 u 70
YB 0.7777 1u 1.46 u 1000 u 0.083 u 300
0.5 u 70  0.5 u 20 2.42 × 10–3 =
M u 100
= 77.77 × 10–2
M = 150223 g mol–1
| 78 u 102
M = 15.0223 × 104 gmol–1
56. Answer (1) 61. Answer (125)
xA = 0.6
total number of particle after dissociation / association
i
PT = xAPAº + xBPBº total number of particle before dissociation / association

= 0.6 × 90 + 0.4 × 15 let ‘a’ is total moles of HA

= 54 + 6 = 60
o H  A 
HA 
xAPAº = yAPT 0.5a 0.5a 0.5a

0.6 × 90 = yA(60) HA 
o (HA)2
0.5a 0.5a
Ÿ yA = 0.9 2

§ 0.5 ·
yB = 0.1 = 1 × 10–1 ¨ 0.5  0.5  ¸a
© 2 ¹
?x=1 i 1.25 = 125 × 10–2
a

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62. Answer (4)
§ Mass of water = 200 g · = 2.06
i for C2H5OH is 1. ¨ ¸
© as d = 1 g/mL ¹
'Tf = ikfm
? Freezing point = Tf – 'Tf
'Tf v i (considering molarity = molality)
= 273.15 – 2.06
Ba3(PO4)2 i=5
= 271.09
Na2SO4 i=3
 271
KCl i=2
66. Answer (2)
Li3PO4 i=4
'Tf v i × m
63. Answer (269)
greater the value of i, greater will be the 'Tf value.
'Tf (T0  Ts ) i u Molality u k f
Solute i

83 u 1000 glycine 1
273  Ts 1u u 1.86
62 u 625 KHSO4 3

Ts = 269 hydrazine 1

64. Answer (518) glucose 1

Molality of sucrose solution = 0.75 m 67. Answer (13)

Mass of sucrose = 0.75 × 342 g = 256.5 g Kb (benzene) = 2.6 K kg mol–1

Mass of solutions = 1256.5 g Kb (acetone) = 1.7 K kg mol–1

Mass of sucrose in 1 kg solution In acetone

1u 1.7 u 1.22 u 1000

0.17
256.5 u 1000 M u 100
204.1 g
1256.5 M = 122 g/mol
Mass of water in 1 kg solution = 1000 – 204.1 In benzene
= 795.9 g
1 1.22
'Tb u u 2.6 u 10
After colling the solution to –4°C 2 122

1.86 u 204.1 u 1000 = 0.13 ºC

4 ;w Bc 277.5 g
342 u w Bc = 13 × 10–2 ºC
68. Answer (54)
( w Bc is the mass of water left)
7.47 = C × 0.083 × 300
Mass of ice separated = 795.9 – 277.5
(S = CRT)
518.4  518 g
(Where C represents the concentration of glucose
65. Answer (271)
solution and S represents osmotic pressure)
40
Moles of glucose = 7.47
180 C (mol L1 )
0.083 u 300
'Tf iK f m (i = 1 for glucose)
7.47
which in gm/L = u 180
40 u 1000 0.083 u 300
= 1u 1.86 u
180 u 200
= 54 gm/l

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69. Answer (1221)
1 x
According to Henry’s law, partial pressure of a gas 8 y
is given by
? y 8
Pg = (KH) Xg
74. Answer (45)
where Xg is mole fraction of gas in solution
Wsolute = 2.5 × 10–3 kg
0.835 = 1.67 × 103 XCO2
W solvent = 75 × 10–3 kg
XCO2 5 u 104
'Tb = 373.535 – 373.15
Mass of CO2 in 1 L water = 1221 × 10 g –3
= 0.385 K
70. Answer (4)
Kb(H2O) = 0.52 K kg mol–1
Since, 'Tf = ikfm

0.7 1000 Kb u 103 u Wsolute

m u 'Tb =
93 42 Msolute u Wsolvent

0.7 u 1000 0.52 u 103 u 2.5 u 10 3

0.2 i u 1.86 u
93 u 42 Msolute =
75 u 103 u 0.385
i = 0.6
= 45.02
i 1 0.6  1 | 45
D 0.8
1 1
1 1 75. Answer (14)
n 2

Hence, percentage association of solute A is 80%. PT PA0 .x A  PB0 .xB

71. Answer (98) = 50 × 0.3 + 100 × 0.7

'Tf iK bm = 85 mm Hg

0.24 u 99.5 u 74.6 70 x

i = 1.98 yB
1.80 u 0.5 u 1000 85 17

i 1 0.98 x
D 0.98 14
n 1 1 17
72. Answer (415) 76. Answer (330)
S = i CRT (i = 1)
Since,
2 u 1000
S= u .083 u 300 S = icRT
60 u 103 u 200
S = .00415 atm 2.5 1000
5.03 × 10–3 = u u 0.083 u 300
M 500
S = 415 Pa
73. Answer (8) Molar mass of protein = 24751.5 g/mol

'Tb = kbm 24751.5

Number of glycine units in protein =
75
( 'Tb )A (k b )A
( 'Tb )B (kb )B = 330

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77. Answer (5) 80. Answer (2)

'Tb = i × Kb × m 'Tf = i kf × m

1.2 u 1.02 ΔTf A 1

Moles of solute (acetic acid) =
60 ΔTf B 4

As moles of solute are very less.

1
So, take molarity and molality same. i × Kf u ×1
MA
1
1.2 u 1.02 1 =
i u Kf u ×1 4
0.0198 = i × 1.85 × MB
60 u 2

i = 1.05
MB 1
=
MA 4
i 1 0.05
D 0.05
n 1 1 MA : MB = 4 : 1
78. Answer (3) 81. Answer (1)

'Tb = i × Kb × m Molality of a solution of non volatile solute (A) = 1

'Tf = i × Kf × m i=1 Elevation in boiling point is given by

4 = 1 × Kb × 1.5 'Tb = Kb m

–––––––––––––––––––––– 3 = Kb × 1 ... (1)

4 = 1 × Kf × 4.5 Molality of (A) in the same solvent = 2

Depression in freezing point is given by

Kb
3
Kf 'Tf = Kf m

79. Answer (3) 6 = Kf × 2 ... (2)

'Tf of formic acid = 0.0405°C
Dividing (1) by (2)
Concentration = 0.5 mL/L
Kb 1 1
and density = 1.05 g/mL Kf X 1
? Mass of formic acid in solution = 1.05 × 0.5 g ? X=1
= 0.525 g 82. Answer (2)

? According to Van’t Hoff equation, ('Tb)A = ('Tb)B

'Tf = ikf ·m Kb·MA = Kb·MB

0.525 Ÿ MA = MB
0.0405 i u 1.86 u
46 u 1
2 8
(Assuming mass of 1 L water = kg) MA MB
Ÿ u 1000 u 1000
100 100
0.0405 u 46
i 1.89 | 1.9
1.86 u 0.525 Ÿ MB = 4MA

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83. Answer (06.00) We know that PA = YA × PT

Po  Ps nA PA = 0.5 × 0.8 = 0.4

Ps nB
0.4
Now PA = XA × PAo Ÿ PAo = = 2 atm
0.2
nA
1
nB 86. Answer (1)
From Henry’s law,
nA nB
p oxygen 0.920
? Moles of solute added considering it as a X oxygen 1.96 u10–5
KH 3
46.82 u10
non- electrolyte
As 1 litre of water contains 55.5 mol of it, therefore,
100 o n represents moles of O2 in solution.
=  5.55
18
n n
6 X oxygen  n  55.5
n  55.5 55.5
84. Answer (15)
n
M.wt. of Acetic acid = 60 g 1.96 u 10 –5
55.5
M.wt. of Ascorbic acid = 176 g
n = 108.8 × 10–5 = 1.08 ×10–3 moles
'Tf Kf m m moles of oxygen = 1.08 × 10–3 × 103 = 1 m mole

3.9 u 10.2 u 1000 87. Answer (80)

'Tf
176 u 150 'Tf = kf m

'Tf 1.506 2 u 1.8 u 1000

0.9 =
62.5 u 0.8 u M
= 15.06 × 10–1

= 15 2 u 1800
M=
85. Answer (2) 62.5 u 0.8 u 0.9

Given that XA = 0.2, YA = 0.5, PT = 0.8 atm = 80 g/mol

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