Professional Documents
Culture Documents
Design
Part One: Raw Material Preparation
1. General
The production of cement is started from quarrying the raw material. The main raw
materials are limestone, basalt, sand stone, pumice, gypsum. Site Exploration of suitable
deposits, for the raw material has three main aims:-
The method of removals and machinery usages are depend on the under listed factors
relating to the overburden material nature. For example rock over burden can be broken
by blasting or ripping, machineries such as back acting/dragline excavator; bulldozer can
be used for the overburden removal. Moreover, ground surface which is intact has better
bearing capacity than ground in which its top has been removed.
Blasting is the most widely used method to excavate limestone for cement production as
the rock is usually too hard to be ripped or dozed. After blast holes are drilled, they will
be charged with explosive and the charges are fired. The amounts of explosive to be
used depend on the specific explosive consumption. The specific explosive consumption
can be determined from reduced scale blasting measurements based initially on known
values from
1. Loading
Loading machines in the present technology is concentrated towards hydraulic
excavators and wheel loaders. The machines used for loading in open-pit quarrying for
solid rock such as excavators, hydraulic excavators, wheel loaders and others depending
on the nature of the quarry.
1. Haulage
Haulage comprises the transport of the fragmented rock pile material from the loading
point to the crushing plant. The choice of haulage system may be
The rock pile loaded to the loading machine is either fed to a primary crusher in the
quarry, the product of which is further transferred to the cement works, or to heavy
dump trucks to be transported to a crushing plant away from the quarry. This depends
on the particle size of the material.
1. Crushing
Crusher is a device that is designed to reduce large solid chunks of raw material into
smaller chunks. Crusher will be erected near to the limestone quarry. The limestone and
sandstone is transported from their respected quarry through the help of dump trucks to
the crusher, which is directly passes the crushed raw material to the ropeway so that the
size is reduced to 25 mm. The crushed limestone is stored in the stockpile through
stacker.
Crusher types
There is a lot of crusher used in cement industry such as;
Impact crusher
Hammer crusher
Jaw crusher
Gyratory and cone crusher
Mobile crusher
But, Debra cement factory uses only the first two (Impact crusher and Hammer
crusher).The raw material is crushed at quarry by primary crusher (impact crushers) Grain
size (75-90mm).
Hammer Crushers: –
In DMC, these are mainly used for crushing of correctives, pumice, coal and clinker. They
are used for size reduction of hard to medium grain size and sometimes for wet and
sticky material. Hammer mills work with reduction ratios as high as 1:40 to 1:60 as
primary and 15:1 as secondary crushers. It can be installed for single stage crushing,
primary crushing or secondary crushing. Types of hammer crushers used in DMC, double
shaft hammer crushers and work with the impact effect of the hammers. The material
crushed in double rotor hammer crushers is limited to certain characteristics of its
properties.
Impact Crushers: –
These crushers are suitable for non-abrasive, from soft to hard, slightly wet materials.
The predominant stress used is impact; however cut and attrition are also used. The
maximum reduction ratios are 40:1. There are two types; single rotor impact and double
rotor impact crushers. The specific power consumption of this crusher is 0.7 – 0.9 Kwh
per ton of material. The size reduction work of impact crushers is limited to certain
quality characteristics of the crusher feed.
4. Site Restoration
Environmental considerations demand the landscape of a quarry site to be restored after
any quarrying operation ceased on the site. The restoration involves restoring the
landscape to something like its original or to an environmentally friendly way and re-
cultivation of the surrounding to create a biologically and ecologically intact natural
habitat.
Belt conveyors are- used for transport of solid objects and bulk materials at great speed,
covering distance from crusher to cement mills (up to 6.4km). Belt Conveyor is also a
suitable means of transporting raw materials and other bulk materials in large quantities
within a short space of time.
Among the major raw materials required for cement production, limestone, sandstone,
and gypsum are abundantly available in Debra. As it was observed from the preliminary
geological survey of the raw materials study, [this study was conducted by company
during its establishment], that the deposit of the above materials is much more than
enough for the whole plant life for 5,000tpd clinker production capacity. After the
required raw materials are transported to the plant site, limestone and sandstone are
stored in temporary storage called vertical silo or twin silo.
Twin silos are used to store limestone and sandstone that are transported by belt.
Sandstone………6,000tons
Basalt……………12,000tons
Pumice…………..24,000tons
Gypsum…………..6,000tons
Moreover, the above stated raw materials, Basalt (contain clay and Fe 2O3), is extracted
very near the plant site and transported by track so that it is crushed by hammer crusher
at production site and then by using conveyor belt it is allowed to enter in to
longitudinal yard for storage.
1. Gypsum
Gypsum one of the raw materials which are added in the clinker and also some part of
Gypsum is inter-ground with the other raw materials in the raw materials preparation.
The addition of Gypsum is good for the settling time of the cement
1. Corrective components
Specifically enriched in one of the four main elements (bauxite, iron ore, sand, high-
grade limestone, etc.). Correctives are used in small quantities only to adjust the
chemical composition of the raw mix to the required quality targets. If an essential
chemical component needed in the cement raw mixture is not present in the required
amount, corrective ingredients are used as additives.
Moreover, drying oven is used to remove the free water (moisture) in a raw material like
Lime stone, Pumice, and Sand stone except Gypsum at 105 ◦C for one hour.
The energy amount and cycle-time that needed for drying and processing the raw
materials are proportional to the moisture contents. For example more energy is needed
to produce enough hot air in order to dry the raw materials with high moisture.
Therefore the moisture content affects and controls the productivity and performance of
the raw milling process,
Generally, the moisture content of raw materials for cement production are usually
prescribed by different specification is not to greater than 1 %.
Grading size (Sieve distribution): the other physical property of the raw material is its
grain size. Which matters the mechanism how to transport from the quarry and the type
of Crusher used to grind it.
Chemical composition
Portland cement is made up of four main compounds: tri-calcium silicate (3CaO ・SiO2),
dicalcium silicate (2CaO ・ SiO2), tri-calcium aluminates (3CaO ・ Al2O3), and tetra-
calcium aluminoferrite (4CaO ・ Al2O3Fe2O3). The percentage compositions of these
compounds vary according to the type of cement required. Small amounts of
uncombined lime and magnesia also are present, along with alkalis and minor amounts
of other elements. Trace amounts of hexavalent chromium are very often present in the
final product. Portland cement dusts less than 1% crystalline silica.
The elemental compositions of the basic raw materials used by DMC are labeled below
Sand (sio2)
Limestone(caco3)
Basalt(clay and shale) provides Al2 o3, Fe2o3 and sio2
DMC consume *Limestone (89-91%)
* Basalt (8%)
Pre-Blending
It is Blending of raw components on (integrated) pre-blending stock piles to a given
target composition.
Number of problems can occur and arise within the cement production line as a result of
materials compositions variations. For example
1. Corrosion problems: corrosion within this process has classified into two groups.
First, cold corrosion which can be occurred because of oxidation state. The cold
corrosion is resulted from the reaction of the equipment surface with water and
oxygen. Secondly, chemical corrosion which can be occurred as a result of the
chemical reaction between the corrosive gases and equipment. The raw materials
and fuel are counted as the major sources of the corrosive gases such as: sulphur
oxides (SOx), calcium chloride (CaCl2), and nitrogen oxides (NOx).Corrosion
situation affects the performance of raw milling system by increasing the
breakdown rates and reducing the equipment availability and reliability.
2. Build-up formation of materials and rings forming: Sulphur, Chlorine, and
alkali components may accumulate at the cold zone of the kiln obstructing the
raw meal flow leading to unstable operation. Number of factors can control and
keep values of these volatile components at minimum levels such as: chemical
properties of raw meal and fuels, Oxygen rates, and flame characteristics.
Raw Material Homogenization
There are a number of ways to stack limestone. Most common are the chevron or
windrow methods, in which the materials are stacked in many layers in the longitudinal
direction of the raw material pile. The material is reclaimed from the entire cross section
of the pile and the number of reclaimed layers in the cross section is the important
parameter for the blending efficiency.
The pre-homogenizing systems have two major operations: 1) storing or stacking and 2)
retrieval or reclaiming of materials. That is why the facilities are also often known as
“stacker-re-claimer systems,” Depending on their homogenizing capability, two broad
categories can be considered for these systems.
A limestone stockpile (closed stock pile) has been proposed at the plant site with stacker
and re-claimer. The re-claimer will help in feeding a homogenized limestone by mixing
rich quality LS with low grade mineral. By installing a re-claimer in the plant, the plant
can achieve not only the quality raw material input but also the conservation of natural
resources by utilizing low-grade raw material. The crushed limestone is sent to the
stacker and re-claimer, which will improve the pre-blending in the ratio of by these
means it, prepares the materials to the conveyer transported in to the proportion unit.
Reclaiming takes place at the opposite end of the pile to that beings tacked. A bridge re-
claimer works, to and fro, across the cross-section of the pile parallel with a radius line.
The sweeping movements of the raking harrow mounted on the re-claimer cause
limestone to
slide to the base of the pile. The chain system of there-claimer then drags the material
into a hopper beneath the central column of the stacker-reclaimer. Homogenized
limestone leaves from the central hopper on an underground conveyor.
Moreover, in Longitudinal yard there is Pumice (SiO2; Al2o3); Gypsum (caso4); Basalt
(SiO2; Al2o3, caso4) and Sandstone (caco3).
Pumice; is alight material(less dense than other ingredients like basalt), which is
extracted and transported from Eastern Shoa around Meki. It is used 25-30%
(30% in PPC and 5% in OPC).
Gypsum; is pure limestone, is about 95% of caco 3. It is used to for setting time or
to correct hydration rate.
After the raw materials are leaving from longitudinal and circular yards, they enter into
the hoppers or bins through belt conveyor. They are used for feeding crushers and mills.
There are four in numbers, three of the hoppers holds different raw materials like
Limestone (capacity of the hopper to hold 800 ton); Sandstone (capacity of the hopper
to hold 200 ton); and Basalt (capacity of the hopper to hold 200 ton). And the fourth one
i.e., high grade limestone or correcting material of the hopper has a capacity to hold up
to 200 tons.
Limestone…… 65%
Sandstone…….5-10%
Basalt………….20%
As well, for the corresponding hoppers, there existed a weigh feeder to proportionate
the raw materials prior to joining in to vertical raw meal for grinding.
Weigh feeders:
Weigh feeder is a machine which allows the raw material to the required quantity from
the hopper and sent it to the required area.
This stage continues after the crushed lime stone is stocked pile. A belt conveyor collects
the raw material from the stock pile with the help of hoppers below the stock pile. So
these belts are fixed under the stock pile to collect the raw material.
Silica modulus (SM), Alumina modulus(AM) etc. of desired clinker it would be possible to
calculate the proportion of the different raw materials in raw mix .The raw mix design
comprises raw mix proportioning standard specifications of the cement types to be
produced.
Corrective lime stone, sand stone and basalt are transported turn by turn to their
respective storage in silo. Now the proportioning process is done with the help of
varying speed belt conveyors. The amount of each material received by the raw mill
feeding of the belt conveyers depends on the speed of the belt conveyors which taken
the materials from their respective storage. A proper raw mix design is based on the
given raw material situation on the process design and on environmental consideration
and also used for a good product quality and smooth kiln operation.
The proportioning of raw mixes for ordinary Portland cement and Pozzolana Portland
cement are mostly based on the following specific criteria.
In order to produce good clinker the LSF is usually kept between 92 6%.If the LSF
is above 99% the raw mix CaO Become harder to burn, higher fuel consumption,
excess CaO in the clinker.
Desired value 92-98 %
If LSF below 92% the clinker is so easy to burn the refractory brick may be washed out,
infiltrate with coating rings. Free lime content is usually low…Form less porous & bally
clinker ….. Results, hard to grind, Excess of liquid phase in the burning Zone, there is a
tendency to ring formation and coating washing, The potential C 3S is lowered and the
C2S is increased proportionally……Reduce early strength of cement
In general high LSF has following effect
Fuel consumption increases
Burning zone temperature increase and heat loss by radiation increases.
Presence of free CaO affects the quality of clinker and produce unsound cement.
Clinker burning hard with high fuel consumption.
Free lime content is low and the high the early strength of the cement.
Difficult to combine with other oxide (hard to burn)….. a tendency to high free
lime
1. Silica Modulus (SM)
It’s the ratio sum of Fe2O3 and Al2O3 in the kiln blend; it characterizes the ratio of solid to
liquid in the clinker. So that the right amounts of the aluminates C 3A and Ferrite C4AF are
obtained in the clinker. The major effect of silica ratio is one the quantity of flux or liquid
phase potentially present at clinkering temperature.
The silica ratio falls between 2.0-2.4. At the clinkering temperature the silica is for the
most part contained in the solid phases Tri-calcium and Di-calcium silicate which absorb
only small amounts of alumina and iron oxide in solid solution.
When SR high:
more difficult the raw mix to burn due to lower content of Al 2O3 and Fe2O3
Clinker is hard to grind
Low cement strength
Difficult to combine with CaO …hard to burn
More fuel consumption
High heat loss by radiation
Reduces the amount of coating in the burning zone
Produces dusty clinker
When SR low:
Easy burning for the raw mix
Liquid phase high Al2O3 and Fe2O3
Kiln unstable and slow hardening cement
Excessive coating formation (ring formation)
Fast brick infiltration with clinker melt
Snowman formation in cooler
Resulting bally clinker which is hard to grind and its strengths are lowered
1. Alumina Modulus (AM)
The Alumina modulus establishes the relation between alumina and iron to determine
the viscosity of liquid phase
AR= Al2O3/Fe2O3
Desired value 1.4 – 1.60
As the alumina and the iron oxide are almost completely melted at clinkering
temperature, the iron modulus characterizes the composition of the melt.
When AM high: Viscous slag, hard burning, high early cement strength with low sulfate
resistance
Effect of high Alumina Modulus
1. The more viscous flux at a given temperatures
Decrease sintering rate due to decrease in reactant contact (decreases the kinetic
energy of the reactants)
Increase sintering temperature to make less viscous ( to increase sintering rate)
High fuel consumption to increase sintering temperature
1. High C3A formation
High heat of hydration (Reaction of C3A with water releases 900KCal energy per
mole of C3A)…… Results concrete thermal expansion
Tendency to high early strength due to high heat of hydration , consequently it
absorbs high amount of water for quenching
When AM low:-Fluid slag, easier burning and Low early cement strength with high
sulfate resistance and low heat of hydration.
Means high Fe2O3 content (less viscous clinker melt )
Hard to grind due to formation of less porous clinker
Form Dark in color of clinker
The proportioned raw material is feed first to a grinding mill. In the mill, particles ground
in to very fine sizes. In the grinding unit, drying, grinding and mixing takes place
simultaneously. Hot gas from clinker burning unit is passed into the grinding unit to
assist the drying and grinding process. The mill exerts mechanical action on the feed
particles and grinding takes place. The mechanical action in the mill also homogenizes
the raw material in the mill.
Mill separators use the gas from the mill and mechanical force to separate fine particles
from the coarse particles. A fine particle output from the separator is transported to
cyclone through a fan. The mill output usually contains some coarse particles and the
coarser ones have to be separated before storage. The coarse output returns to the mill
for regrinding by bucket elevator. Gas leaving the mill is drawn out by a fan called waste.
The gas exiting the cyclone still contains fine materials and goes to gas cleaning unit,
which can be bag filter. At cyclone, some dusts and gases are sucked by fan so that they
can be sent to bag filter to be de-dusted.
Centrifugal force ; Fc
Force of ascending air current force ; Fd
Force of gravity Fg.
Working principle
Raw mills uses pressure and shear generated between the rollers and rotating table to
crush and grind limestone, basalt and sandstone. The rotation of grinding table
accelerates the materials toward grinding track and passes it under the roller. The
ground material is supplied on to rotating grinding table connected to bevel spur
gearbox which is driven by an electric motor or hydraulic drive.
Hydraulic tensioning occurs when grinding roller with grinding table rotating during
operation. In hydraulic gas accumulator, nitrogen gas accumulator is used as a shock
absorber during operation.
Grinding
Drying
Separation
Transportation
The process is called a drying /grinding process, where most of the material/product is
transported pneumatically by drying gases.
Grinding: the material is ground between rollers and grinding table while passing
from the center of the table to the nozzle ring. The commnation method belongs
to the most efficient grinding processes applied in the cement manufacturing.
Separation: the ground and dried material is lifted up with the drying gases. In
the separator, the too coarse particles (tailings) are rejected to the grinding table.
The fines leave the mill and are conveyed to dust collector.
Drying: the process air consists mostly of waste gas from a kiln or cooler or is
supplied by a hot gas generator. Drying occurs during transport through the
grinding and separating process stage.
Transport: the drying gasses are utilizing to serve as conveying media. The first
transport stage is the internal circulation and the second is the separator. At last,
the product is extracted from the separator and pneumatically conveyed to
cyclones or a filter where the product is collected and fed to a silo. The clean
gases are exhausted to the ambient and/ or re-circulated to the mill.
De dusting system
De dusting system is used to prevent the dust from escaping into the environment, most
of the cement plant machinery and equipment is working under negative pressure,
which requires the ventilation and cleaning of large volume of air gases respectively.
Mechanical collectors, i.e. cyclone separator
The use of cyclones strictly speaking is not warranted as pre collectors before bag filters
because both of them are capable of handling full load of dust content. But cyclones
help in emergencies to bypass the dust collector. By using gas tight dampers, it would be
Possible to attend to the maintenance and repairs of the dust collector without requiring
stopping the plant.
Air Slide
Air slide pneumatic conveying equipment used to convey dry and powder material. In
DMC it is used to convey fine material and cement powder. It is used to convey fine
materials from
Cyclone to homogenization silos by small induced draft (ID) fan under it.
De-dusting system using Cyclone relies on the action of the centrifugal forces on the
dust particles carried along in the swirling stream of gas. The particles are thus flung
radically outwards to the wall of the cyclone from where they fall into dust hopper. All
cyclones work by centrifugal force. Two main factors affect cyclone efficiency. These are:-
Velocity particle moves towards the wall or collection area of the cyclone where it is
theoretically collected and length of time available for collection: Residence Time.
Moreover, the two main metrics describe cyclone performance are Pressure drop and
Fractional efficiency curve (FEC). Most of the early cyclones were used to collect dust
created from mills that processed grains and wood products. In the decades that have
followed, however, cyclones have found application in virtually every industry where
there
is a need to remove particles from a gas stream. Figure below shows cyclones Basic Flow
Patterns (Reverse Flow Cyclone)
The bag filters are important equipment in cement factory. In these filters current flow
that includes gas and dust cross through the pores are located in the stuff filter and
filtrate by remaining on the bag. Afterward, by dust increase on the bag, the filter is
shaken until dust collecting leads to exist hopper. This system in the project is called
mechanical method. They are used extensively in cement works for cleaning the exhaust
air from tube mills, crushers, material handling installations, silos and bins, dispatch
loading plants. Since an accumulation of dust on the pores of the fiber occur, cleaning of
the filter media is necessary. Bag house (Bag Filter) is an air pollution control device that
removes particulates released from cyclone by using induced draft fan.
Housing or shell Material dropped from bag house and air conditioning tower is
transport by
Drag chain to homogenization silo.
Solenoid valve
Connection hopper
Filter cleaning device
Fan
Conditioning towers in the cement industry are used for cooling exhaust gases from the
kiln before they are conveyed to the bag house. Inlet temperature from pre-heater to
Gas Conditioning tower is 600 degree Celsius and outlet is 250 degree Celsius. This
temperature is used to drying material in vertical raw mill.
The hot exhaust gases enter the top section of the vertical, cylindrically-shaped and
insulated tower for cooling by water injection. The gases are drawn through the
conditioning tower by a fan.
Besides, additional object of the Gas Conditioning Tower is to condition and cool kiln
gas before it is de-dusted in bag house. The cooling of the gas protects the bag from
high temperatures and the higher humidity of the gas increases the performance of the
bag house. Furthermore, some of the dust in the kiln gas is separated from the gas by
gravity in the Gas Conditioning Tower.
Hot gas generators: are suitable for drying process and used in conjunction with
grinding
Plants when there is insufficient hot gas from conditioning tower. In this process air is
heated under high pressure.
Homogenizing silo (Raw meal silo)
This is an area where the raw meal is stored temporarily. It has two
roles: blending and storing
Here Blending is an act of mixing or homogenizing of raw meal using compressed air to
get uniform chemical composition and meal fineness.
In Cement Industry raw meal blending or homogenization is always done in silos. It is the
last homogenizing step in the line of the raw mix preparation processes installed with
the aim to reduce the residual (relatively short-term, high frequent) compositional
variations observed for the raw meal produced in the raw mill.
If the kiln is operated at a constant material residence time and temperature, such
variations regarding chemical composition and physical characteristics also will cause
variations in clinker composition like free lime.
When unintended variation in kiln feed composition (the raw meal reclaimed from such
silos will then be fed to the kilns without further homogenizing) causes large variation in
free lime, operators may make incorrect changes to kiln operation, assuming changes
are needed when they are not.
The operator may be obliged to increase the burning zone temperature to achieve the
desired free lime level; by keeping the kiln on the hot side, the maximum clinker free
lime is brought to the average value. Which results reduced brick life time, increased
NOx emission, production of dusty clinker, unstable kiln operation etc.
The fuel penalty for burning to an average of 0.8% free lime because of large variability
instead of an average of 1% can easily be on the order of 4% (high fuel consumption).
When the kiln is operated on the hot side, alkalis and sulfate become more volatile. This,
in turn, might increase the possibility for build-ups in the preheater and Kiln inlet
(increased tendency to ring and build up formation).
Hard burning tends to cause low clinker porosity, large crystals of alite, and often
contributes to generation of dust instead of good nodular clinker. Slows down the
cooling process because of high temperature and low-porous clinker, it is more difficult
to cool. Reduced clinker porosity can make the clinker harder to grind, increasing finish
mill power consumption or reducing mill production as well as reduce cement strength.
This is used as a prerequisite for achieving steady process conditions for the kiln.
Blending factor is the ratio of standard deviation of input raw meal to standard
deviation of output raw meal. The standard deviation is a measure of how widely values
are dispersed from the average value (the mean).
For calculation of blending factor of a silo, input and output raw meal samples are to be
collected in regular intervals and to be tested for example CaCO 3 content having a
standard deviation of 0.3% ( in DMC case).
Given a set of N measurements, X1, X2………… XN the mean value X is given by
The difference between each measurement X i and the mean value X are squared so that
positive and negative fluctuations above and below the mean do not cancel each other.
The square root of the sum of the squared variations is then divided by the number of
measurements N to obtain an average measure of variation, having the same units as
the measured quantity.
The natural and induced blending which occurs at a particular homogenizing stage may
be expressed by a Blending Factor BF defined as the ratio of the incoming and discharge
Standard Deviations:
The Standard Deviation needs correction for sampling and analyzing error for which
the silo can’t be blamed. For determining the sampling and analyzing error double
sampling method is proposed.
Easy burning raw mixes tolerate fluctuations in a wider range than difficult burning raw
mixes. Nevertheless it is useful to have some guide values regarding tolerable
compositional fluctuations at hand.
SR % ≤0.04 ≤0.06
AR % ≤0.06 ≤0.08
There are various types blending silos having blending factor from 6:1 to 15:1. The more
the blending factor, the blending is the more effective.
Process Concept
Continuous blending silos aim at raw meal homogenizing and intermediate storage in
one common silo. The system follows the concept of a blender. For that purpose the raw
meal is fed into the top of silo in horizontal layers. Horizontal layering of the raw meal is
achieved while feeding the silo via a spider-type air slide system. When reclaiming meal
from the silo a funnel will form on top of the discharge point at the product surface. The
declining funnel surface cause blending of particles originating from different layers
when sliding down the slope to into the transport channel.
Investment cost……………………………….……50-60%
Capacity to store……………………………….….24,000t
Power consumption…………………….….…..0.8KWh/t
Unfortunately the efficiency factor do not means that all compositional peaks fed into
the silo are reduced by the same factor. The compositional fluctuations of different kind
are reduced with different efficiencies.
Long-term fluctuations with periodical times exceeding 5hr are not reduced sufficiently.
A compositional oscillation for example with a periodical time of 20 h is reduced with a
low efficiency of just 1.16:1. In this case the silo has no chance to achieve a sufficient
blending result. The only way to improve the situation is to cut any long-term
fluctuations by frequent adjustment of raw mix composition, i.e. by frequent adjustment
of the weigh feeder set points. Continuous blending silos are not in a position to reduce
the peak disturbances sufficiently.
The only efficient measure to compensate for such peak disturbances is by creation of a
defined counter-peak by making adequate adjustments to the raw mix composition.
Problem Remedies
1. Lump formation due to water ingress -Empty and clean the silo completely
into the silo -Check silo roof and wall with regard to
leaks, seal the leaks and coat the silo wall
3. Raw meal lumps obstruct material -clean outlet boxes and install a lump
flow from the silo breaker
-install dryer for the aeration air
4. Reduced air supply to the aeration -check air aspiration filter on permeability
system and clean the filter
-check air distribution system on
permeability and clean the system
PYROPROCESSING
It is a process of heating of the raw meal to the required temperature so as to produce
the desired clinker compounds in an economic way at higher productivity in the
preheater and kiln. Or it is a process to convert natural mineral to hydraulic mixture
using high temperature.
In order to obtain clinker from a properly proportioned, grinded and homogenized raw
meal, it must be treated with heat obtained from burning fuels. The main processes and
chemical reactions that take place during clinker formation are:-
PREHEATER
Preheaters are cyclones are arranged vertically, in series, and are supported by a
structure known as the preheater tower. It can be considered as a heat transfer tower
supports a series of vertical cyclone chambers through which the raw material passes on
the way to the kiln. To save energy modern cement plants preheat the raw material
before they enter the kiln. Rising more than hundred meter, hot exit gases from the kiln
heat the raw meal as they swirl down the cyclone string.
Stages
Cyclone preheater kilns can have any number of stages between one and six, with
increasing fuel efficiency with more cyclone preheater stages. The feed to the kiln is
delivered to the top stage of the preheater and passes down through the successive
stages of the preheater to the precalciner and rotary kiln.
The more preheater stages the lower will be the thermal energy consumption of the kiln
as more of the heat from the kiln exhaust gases is recovered. Preheater exit gas
temperature will reduce by ~30°C for each additional preheater stage, from ~360°C for a
4-stage preheater, to ~330°C for a 5-stage preheater. Todays, five stage preheaters
represent the economical and optimum between investment cost (structure height,
foundation), pressure drop and heat Consumption to ~300°C for a six stage preheater.
But now in Japan and china seven stages preheater is under operation. However, civil
costs and pressure drop across the preheater tower rise with each additional preheater
stage. Gas temperatures should always be higher than material temperatures in any
preheater stage as the material is heated by the gas.
Note: Numbering of stages is always from top to bottom: top stage = stage 1.
When the number of preheater stages was decided the important considerations will
have been the
Cyclone
The key component of the gas-suspension preheater is the cyclone. A cyclone is a
conical vessel into which a dust-bearing gas-stream is passed tangentially. This produces
a vortex within the vessel. The gas leaves the vessel through a co-axial “vortex-finder”.
Each stage of the preheater consists of a gas riser duct and a collection cyclone. The raw
meal is led in to the riser duct of the first stage cyclone and the intake has a spreader
box for distribution of the raw meal in the gas stream. The exhaust gas is drawn out of
the rotary kiln and up through the gas riser ducts of the preheater. The rising gas lifts the
feed up through the gas riser ducts and into the collection cyclones where the swirl
created by the geometry of the cyclone and the central dip tube separates the feed from
the gas. Gas exits the cyclone up the preheater through the dip tube, while the cyclone
passes the feed down the preheater to the next stage.
Visualizing the gas flow path in the preheater demonstrates the resistance to drawing
the gases from the kiln created by every cyclone stage of the preheater which causes
pressure drop.
Equipment manufacturers have been successful in reducing the pressure drop across
preheater cyclones from ~20 mbar to ~7mbar by changes in cyclone geometry and
increasing the cross sectional area of the inlets and dip tubes exiting the cyclones.
Separation efficiency
Pressure drop
Part load operation capability
Size of the preheater
Cost of the project
Cyclones pressure drop reduction is achieved by
larger inlet and outlet area
less gas velocity and more space for gas flow
more length of central pipe
first stage is designed for high degree of separation by keeping more length of
cylindrical portion of cyclone
Size of cyclones
The selection of cyclone sizes is a balance of having the smallest cyclone dimensions
while maintaining the lowest overall pressure drop through the preheater. This is to
minimize the induced draft (ID) fan power consumption – the most power consuming
part of a kiln system.
The size of cyclones relates to the maintaining of desired gas velocity criteria and
efficiency. Increasing the preheater cyclone dimensions reduces the pressure drop. But
for any given cyclone geometry, stable preheater operation (without raw meal falling
through the riser ducts) requires a certain minimum gas velocity.
C2 -3 with 2 -ǿ7.4m
Cyclone efficiency
The collection efficiency of the cyclones is also dependent on the velocity of the gases
entering and exiting the cyclone, and the swirl induced by cyclone geometry. The
cyclones do not have 100% collection efficiency. Some of the feed entering the cyclone
is not collected and passes out of the cyclone, up the preheater tower with the exhaust
gas.
The cyclones in the middle of the tower may have collection efficiencies of 85% or lower
meaning that there is a considerable recirculating load of material in the preheater. Low
efficiency of the bottom stage cyclone means that calcined material can migrate up the
tower. That material can recarbonate liberating energy and elevating the preheater exit
temperature and the losses of thermal energy in the exhaust gases.
The top stage cyclones (tall cylindrical portion-slim cyclone) are designed to have higher
collection efficiency of 93~97%. Any feed not collected by the top stage cyclones exits
the preheater as dust and must be collected in the exhaust gas cleaning equipment like
bag house.
Splash Box
It is designed for optimum meal distribution across the gas duct cross section. The
principle is based on impact on a plate.
Meal Flap
Is designed to prevent gas from by passing up through the material pipes between the
cyclone stages, the pipes are equipped with sluice flaps (tipping valves) designed for full
opening. Good meal distribution in the cyclone riser ducts is ensured by adjustable
spreader plates in the distribution boxes.
clinging
bridging
rat-holing
arching
Compressors are also used for air blaster in preheater system to clean blockages due to
collections of material in cyclones and ducts.
The speed of the ID fan must also be adjusted to ensure that sufficient combustion air is
drawn into the kiln and precalciner from the cooler. The velocity (10-15 m/s) of the
gases must be sufficient to lift the feed up the gas risers and into the cyclones – if not
the feed will short-circuit preheater stages with major adverse impact on kiln stability
and thermal efficiency. The kiln operator must adjust the ID fan speed to have a small
excess of oxygen in the preheater exhaust gases. Whether that excess oxygen should be
2% or 4% will depend on the kiln feed system and the condition of the preheater and
kiln seals. Where there is air in leak at the kiln inlet seal and the preheater stages then
the preheater exit oxygen content will inevitably rise. ID fan consume 2500KW power
(in DMC).
The kiln operator should always be monitoring the temperatures and pressures in the
preheater and the excess oxygen in preheater exhaust gases. The preheater exhaust gas
oxygen content and temperature will be the parameters that the kiln operator is trying to
control to target to maintain the thermal energy efficiency of the kiln. These will be
controlled by the speed of the ID fan.
Pressure drop
It has been found that the total pressure drop of one cyclone stage is caused by about
1/3 by the gas duct (i.e. lifting of the meal) and 2/3 by the cyclone geometry. Both the
swirling of the gases and the changes of direction caused by the cyclones lead to
pressure drop across the cyclones.
Six preheater stages causes maximum pressure drop as compared to lower stages since
the pressure drop across the preheater tower increases with each additional preheater
stage. The higher the pressure drop across the preheater the larger must be the
preheater ID fan and the more electricity will that fan consume. This is why six preheater
stages is the maximum which needs high cost to install.
Production capacity is a function of the volume of the rotary section of the cement kiln.
As capacities of long kilns and preheater kilns raised the length and diameter of the
rotary sections of the kiln increased. With all the fuel fired at the front of the kiln and
thermal load on the refractories at the front of the kiln increased linearly with the
production capacity. Thermal load is a function of the amount of thermal energy input
per hour and the cross-sectional area of the kiln. Kiln linings with sufficient refractoriness
to withstand the burning zone thermal loads involved were and are not available. The
solution to this problem was delivered by precalcination technology.
In the conversion of kiln feed into clinker the evaporation of any residual water,
dehydration of clay minerals, calcination of limestone (CaCO 3) and clinker flux formation
are all energy consuming reactions. Calcination of the CaCO 3 is the most energy
consuming of these reactions. The solution to the burning zone thermal load problem
with high capacity kilns was to direct the thermal energy input to the point in the kiln
where this reaction is taking place, rather than inputting all the thermal energy through
the main burner. A precalcination furnace was added at the base of the preheater at
which 65% of fuel fired.
Calciner vessel (In Line Calciner) is built into the kiln riser pipe
Through the calciner, the kiln exit gas as well as the tertiary air from eta cooler
passes through
Degree of calcination is around 90 – 95% as the temperature is in the range of
870 – 900°C 9
Gas velocity is in the range of 5-7m/sec and retention time is around 4-8 seconds
Secondary air is around 900-1100°C and Tertiary air around 750 -900°C
The main advantages of precalcination are:
More stable kiln operation due to better kiln control via two separate fuel
feed/control
points
More stable kiln operation due to controlled meal conditions at kiln inlet
Reduced thermal load of burning zone
Higher kiln availability
Longer life of burning zone refractories
Larger capacity with given kiln dimensions; smaller kiln for given capacity
Possibility of increasing capacity of existing kilns
More favorable conditions regarding circulating element problems
Allows shorter kilns (L/D<16 with 3 supports)
Lower NOx emissions
There are three basic precalciner arrangements available from several suppliers:
In-line (installed in the kiln exhaust gas flow- precalciner as enlarged kiln riser
duct)
Offline(installed off the kiln exhaust gas flow)
Separate line(off-line calciner with a separate preheater string)
In-line calciner
Precalciner arrangement with the gas riser duct from the kiln inlet to the lower stage
cyclone was simply lengthened and a gooseneck introduced or a Precalcining chamber
was introduced within that riser duct. In this configuration all the gases exiting the rotary
section of the kiln pass through the precalciner, hence the designation as an in-line
precalciner. The feed from the second lower most cyclone of the preheater is directed to
the precalciner and carried to the lower most cyclones where the calcined material is
collected and passed to the inlet of the rotary section of the kiln.
Advantages are:
1. The simplicity of the arrangement
2. The in-line drafting of the preheater, precalciner and rotary section of the kiln
meaning
that only one preheater and induced draft fan is required
3. That with all the kiln exit gases passing through the precalciner, staged
combustion can be used to reduce NOx emissions from the kiln
Disadvantages of the in-line precalciner configuration
Precalciner firing takes place in the presence of the vitiated exhaust gas from the
kiln and the suspended feed to the kiln. Oxygen content of the gas in the
precalciner is therefore depleted and the combustion of the fuel is retarded. Poor
mixing of the kiln exhaust gas and tertiary air can exacerbate the problem of poor
combustion of the fuel resulting from local deficiency of oxygen.
Small residence time in the precalciner at ~900°C may be sufficient to achieve
>90% calcination of the feed, but is not necessarily sufficient to achieve 100%
burn-out of the fuel.
Not achieving 100% burn-out of the fuel in the precalciner can lead to
combustion continuing in the lowermost cyclone and be evidenced by meal
temperatures higher than gas temperatures and “sparkling” of the hot meal when
a sample is brought into the atmosphere. Lowermost cyclone gas exit
temperature rises and with it the temperatures up the preheater to the exit and
therefore the thermal energy losses from the kiln and energy consumption.
The latest development of precalciner technology was aimed at
Completes combustion of fuels even for low reactive fuel
Suitability for a wide range of fuels
Low emissions of NOx
Calcining of Raw Meal in calciner
Calcination of the CaCO3 is the most energy consuming of reactions. During the process
of heating up a raw meal, the Calcining does not happen suddenly at a well-defined
temperature, but starts at about 600 – 700°C and ends between 900°C and 1,000°C.
CaCO3 dissociation takes place from ~600°C but only at higher temperatures does the
speed of calcination become significant. When the temperature of the kiln feed powder
is raised to ~900°C this calcination reaction is completed within ~10 seconds. In kilns
equipped only with suspension preheaters ~30% of the calcination takes place in the
preheater with the rest taking place in the back section of the rotary kiln but with
precalciner >90% is completed. Among all reactions taking place when burning clinker,
the Calcining – also called Decarbonisation – requires the highest amount of energy; the
dissociation of carbonates, primarily calcium carbonate according to the reaction
CaCO3 + heat → CaO + CO2
Not only the temperature, but also the retention time of the raw meal is an important
parameter of Calcining. Heat transfer from gas to suspended raw meal in a preheater
stage is achieved in a fraction of a second; the complete calcination at a temperature of
about 900°C in suspension requires a reaction time of 3.3 – 8 seconds. However, as only
90 to 95% of the Calcining should take place in the precalciner in order to avoid
clogging problems, a residence time of about 3 to 4 seconds has proven to be sufficient.
To perform both above mentioned tasks, i.e. to keep raw meal in suspension for a few
seconds at 850 to 900°C in a stationary vessel without clogging, is the common process
target of all PC systems.
To overcome burning zone from cooling due to high excess air present in main burner
flame, separately ducting of combustion air from the cooler to the Precalcining furnace
via a tertiary air duct is crucial.
Decomposition rate of limestone is increased by
Good mixing of the fuel with the available oxygen (This is particularly difficult to
achieve with in-line calciner). Optimum fuel dispersion into the gas flow (liquid
fuel-atomization) is essential.
Retention time for combustion has to be sufficient. The combustion must be
completed in the PC stage. Otherwise, it will continue in the next stage (post-
combustion) where the temperature level is lower and therefore less favorable for
the calcination. This results in not optimum utilization of the heat which leads
eventually to higher fuel consumption.
The flow pattern of the air/gas mixture (resp. tertiary air) has to be favorable for
the combustion.
The meal distribution in the combustion zone has to be optimum, i.e. causing
minimum distortion of the combustion (CaCO 3 as well as CO2 can also react with C
– carbon from the fuel – to produce CO!).
Basic arrangements of precalcining systems
Air separate-AS (use tertiary air which is extracted from the kiln hood or from the cooler
roof and drawn via a separate tertiary air duct parallel to the kiln to the precalciner)
Air through-AT Systems (used only combustion air which is drawn through the kiln)
Tertiary air duct damper
To balance the combustion air flow between the kiln and calciner, a tertiary air duct
damper is provided for reliable regulation of the tertiary air gases. The damper design
features a solid refractory blade for long, reliable life.
The rotary kiln relies on the calcination degree of the feed entering the kiln being
consistent. Any variation in the calcination degree varies the thermal work that must be
completed in the rotary section of the kiln and leads to disturbances in the kiln
operation. For the precalciner to deliver that consistently calcined material to the rotary
kiln it relies on a consistent flow of preheated meal, fuel and tertiary air into the
precalciner.
Any interruption of flow of preheated feed into the precalciner will cause a spike in the
precalciner temperature. Fuel supply must be cut to control the precalciner temperature
but the fuel delivery must be restored as soon as the feed flow into the precalciner is
restored. Interruptions in the flow of preheated feed into the precalciner can be caused
by “stickiness” of
the feed due to the alkali cycle.
It must also be remembered that the calcination of the calcium carbonate in the
precalciner is an endothermic reaction, absorbing the thermal energy input to the
precalciner. The temperature therefore remains steady while this thermal energy is being
absorbed. Degree of calcination of the feed does not vary with the temperature in the
precalciner but with the amount of thermal energy input to the precalciner. The PID loop
therefore does not really achieve its primary objective of providing consistently calcined
feed to the rotary section of the kiln. To do that the amount of fuel fired in the
precalciner must be linked to the amount of feed to the kiln.
1. Additional installation (fuel dosing, calciner, tertiary air duct) as well as the
relatively
smaller rotary kiln sets a lower economical limit to PC systems for new plants at
around
1200 t/d.
2. Alternative fuels containing hazardous components can only be used in the main
firing
due to the high temperature level there. The potential to use such fuels is then
lower for
PC kilns.
3. Higher exhaust gas temperature and higher pressure drop can be a drawback in
specific cases.
4. Separate line calciners for new installations are only feasible if a two-string
arrangement is required for the capacity.
ROTARY KILN
The rotary kiln is a long steel cylinder, slightly inclined furnaces, lined with refractory to
protect the steel shell (due to its extremely high temperature) and supported by steel
tires and rollers. It rotates along its longitudinal axis, driven by a pinion and gear system.
It is also a type of high temperature oven used for clinker burning process. The raw
material mix enters the kiln at the elevated end but the combustion fuels introduced into
the lower end of the kiln.
The materials are continuously and slowly moved to the lower end due to the inclination
and rotation of the kiln. The raw materials are changed to cementitious or hydraulic
minerals as a result of the increasing temperature within the kiln.
It has ubiquitous fixtures of chemical process that involves different chemical reactions
and it can handle feed stocks with broad particle size distributions or whose physical
properties change significantly during processing, while the long residence time of the
material within the kiln promotes uniform product quality.
TYPES OF KILN
Wet process kilns (usually long kiln)
Grate preheater kilns
Cyclone preheater rotary kiln
Preheater- Precalciner kilns
Kiln can be vertical, horizontal, long or short
In modern kiln system the introduction of a Precalcining furnace at the base of the
preheaters a further >90% of the calcination was taken out of the rotary section of the
kiln.
From a process perspective the taking of the drying and preheating processes out of the
rotary section of the kiln and then most of the Calcining out of the rotary section has
had important implications.
A long kiln with all these processes taking place with the single, long rotary tube; the
rotational speed of the kiln had to be matched to the slowest processes (1rpm or less) of
the drying and preheating. It was very important to tie the rotational speed of the kiln to
the feed rate in order that an even load of material is maintained throughout the kiln
length.
Once the drying and preheating were taken out the rotary section of the kiln this tie
between feed rate and rotational speed became less important.
With the introduction of a Precalcining furnace and taking virtually all the calcination out
of the rotary section of the kiln the link between feed rate and rotational speed became
even less important. In fact there are advantages to bringing the CaO liberated by the
calcination of the CaCO3 into the sintering zone as quickly as possible to prevent it from
stabilizing and becoming “dead-burnt”. A high rotational speed of 3.5 rpm or more
became advantageous in order to
combine the CaO with the SiO2, Al2O3 and Fe2O3 as quickly as possible. On many
precalciner kilns it has proved to be a mistake to slow the kiln down in response to any
cooling in the burning zone as this allows stabilizing of the CaO and makes subsequent
combination into the clinker more difficult.
DMC use the modern preheater – precalciner kiln with the following features
Kiln clinker output …………………………………≥5000tpd
Kiln size………………………………………………….Diameter= 5.2m; length=78m
Pyro process heat consumption………………≤735 Kcal/kg.cl (coal)
≤745 Kcal/Kg.cl (HFO)
Power consumption……………………………….30KWh/t
Slope(inclination)…………………………………..40
Reaction among Lime, Alumina, silica and Iron are takes place to form temporary
intermediate products. As there is no heat consumption in this zone, the temperature
raises rapidly. Temperature reaches 13000 C at the end of the heating zone. In this zone
formation of a hard and dense coating as well as liquid phases begins.
Liquid zone
Its temperature is 1300 to 1350 0 c. Nodulisation of clinker starts here but its content
mainly depends on the raw mix composition.
Size of nodules depends on
Reduced clinker porosity can make the clinker harder to grind, increasing finish mill
power consumption or reducing mill production. The chemical and potential compounds
effect on grindability of clinker controlled by proper raw mix design.
Thus, there are three main mechanisms by which the heat can take place:-
Conduction
Convection
Radiation
1. Convection
Convection heat transfer is a heat transfer phenomena as a fluid body (hot gases) flows
over another body (raw meal). It is directly proportional the velocity of the fluid (hot
gases) medium and the surface area. In the preheater the dominant heat transfer
between the hot kiln gases and feed material is convection.
2. Conduction
Conduction is heat transfer within a given material or heat transfer from one body to
another due to contact. It is dependent on the type of material and the contact surface
area. This is commonly occurring along the bed of material in the kiln.
3. Radiation
Radiation is the transfer of heat from one material to another without contact. It is
dependent on the type of material and the surface area. In the burning zone, due to the
high temperature and luminescence of the flame, the dominant mode of heat transfer is
radiation.
Drying: The water present as uncombined moisture in the raw meal is driven out
at a temperature above 100 0c
Dehydration of clay minerals (preheating zone): The raw meal is heated up to
drive off the water which is combined in the crystal structure of silica, aluminum
and ferric oxides leaving these oxides hot and reactive. The temperature rises to
about 8500
De-carbonation Zone (Calcination zone): calcium carbonate is dissociated by
heat giving reactive lime and carbon dioxide gas. The temperature of the gas rises
to about 1000 0
Burning zone : The burning zone is where combination takes place among lime
( CaO), silica (SiO2 ), Alumina ( Al2O3 ) and ferric oxide (Fe2O3) to form the four basic
clinker components (i.e. C3S,C2S,C4AF and C3A).
The basic chemical reactions taking place in the burning zone are the following:
Temperature 0
c Chemical Process Chemical transformation
CaCO3 ——>CaO+CO2
CaO+ Al2O3 + 3 CaO+2
Decomposition of lime stone and SiO2+ Al2O3—–> 2(CaO.
formation CS and CA SiO2)+ CaO+ Al2O3
600-10000c
The high flow rate of kiln exhausted gases cause suspension situation of the fed meal at
the Precalciner. Consequently, excessive quantity of raw meal must be supplied in order
to maintain steady materials flow rates; however dramatic pressure drop cross is caused
by increase status of materials recirculation within the kilning system resulting high
energy consumption, low clinker quality, high production cost, and low efficiency.
Therefore, in order to enhance the overall performance an optimal flow rate of air has to
be maintained.
Flame Characteristics
Flame characteristics with in the kiln burning and calcination zones have a vital impact
on the clinker quality, processing time, break down time, and equipment performance.
Controlling of the flame features is extremely essential in order to avoid the main
troubles that may occur and improve the whole line performance.
There are a number of key factors have to be optimized in order to control and adjust
the flame characteristics; these key factors are
1. Flame temperature: is accounted as one of the most main key factors which
control the whole production line and specially the thermo-chemical process.
Therefore, the flame temperature has to be optimized through controlling and
adjusting the primary air flow rate and Oxygen concentration. For example high
levels of primary air flow rates reduce the flame temperature resulting low clinker
quality and affect production costs. An excessive primary air flow rate means high
heat loos by carrying extra heat to the preheating zone then released to the
atmosphere. On the other hand low tertiary air temperature reduces the flame
temperature at Precalciner. Overheating and forming rings situations within the
kiln are proportional to flame temperature at low levels rate of primary air and
high Oxygen concentration levels. These situations affect the product quality and
breakdown time. Consequently; the primary air flow rate, tertiary air temperature,
and Oxygen concentration have to be controlled and adjusted accurately in order
to optimize the flame temperature.
2. Flame length; Short burning zone minimizes the heat loss from shell and the kiln
far end. The short intensive flame improves the clinker quality through rapid
processes of heating and cooling the clinker i.e. it prevents attempt of any
undeserved crystallizing process. On one hand extremely short and intensive
flame causes an overheating case at the burning zone, while the kiln in general is
cooled. On the other hand long flame gives slow heating up and cooling
processes, which produce large clinker crystals. These large crystals affect the
quality and grindability of the clinker. Long flame produces more ring formation.
The flame length is reduced due to rising levels of primary air flow rate, Oxygen
concentration, reduction of tertiary air temperature and faster mixing process of
fuel and air.
3. Flame stability; Stable flame has vital impact on the thermo-chemical process.
Flame stability is important to achieve high clinker quality and process efficiency.
Unstable flame results in product quality and breakdown time through rapid
heating and cooling of the kiln refractory. Flame stability can be adjusted by
controlling the flow rate of primary air. An unstable flame and a long plume may
result if the fineness is not increased.
Volatile concentration-problem
Build-up is resulted from increase in concentration of volatile constituents at the
preheater during the process of heat exchange at high evaporating pressure. These non-
combustible volatiles are components that meet and/or evaporate with in temperature
range found in the kiln system. The significant volatiles are salts of alkali i.e. sulphate,
chlorides and hydroxides. A cycle of volatiles that evaporate in hot part of the kiln and re
condense in the cold part of kiln and preheater; trap the volatilities in the kiln system and
courses accumulation of volatiles with the circulation loop. Continual evaporation and
condensation increases the concentration of volatile components until the internal circuit
is closed. Volatile constituents are key factor of clinker quality, kiln reliability, capability,
and overall performance. In order to optimize the kiln performance the concentration of
volatile components should be kept at minimum levels.
silica ratio
percent liquid
C3S content (or lime saturation factor, LSF).
Silica ratio
Silica ratio, or silica modulus (SR), has greatest effects on burnability. As silica ratio
increases kiln feed becomes harder to burn (requires higher temperatures or more time
to chemically combine C2S with free lime to produce C3S). As silica ratio decreases kiln
feed becomes easier to burn. Typically a silica ratio above 3.0 is considered high and a
silica ratio below 2.3 is considered low. All else being equal, larger diameter kilns (i.e. 4-
meter diameter and larger) tend to operate better with a lower silica ratio and smaller
diameter kilns tend to operate better with a higher silica ratio.
Some kiln feeds may have a silica ratio over 3.0 and be relatively easy to burn for a
combination of other reasons such as when the mix has a low C 3S or LSF. Other factors
affect the impact of silica ratio on burnability, such as the type and size of the silica. Free
crystalline silica or quartz (such as from sand) is more difficult to combine than
amorphous silica or silicates or aluminosilicates from clays or shale. If the silica grains are
coarser, it is more difficult for them to chemically react.
Also, note that CaO is not involved in this silica modulus equation; therefore, lime and its
effects are not considered. The same silica ratio could exist with a large variation in lime
content. Silica modulus alone does not tell the complete story; other influences must
also be considered.
If we hold the silica content constant and decrease the silica ratio by increasing the iron
and/or
alumina, the amount of liquid phase increases. Also, if we hold the iron and alumina
content
constant but decrease the silica content, the silica modulus decreases while the amount
of liquid phase remains essentially constant.
In general, if a kiln produced a “dusty” clinker because of a low concentration of liquid
phase at the burning zone temperature, a decrease in the silica ratio achieved by adding
more iron and/or alumina would be expected to reduce dusty clinker conditions in the
kiln. However, if the silica ratio is further decreased by this method so that it becomes
too low, kiln difficulties could be encountered due to too much liquid phase being
formed in the kiln, potentially getting into the clinker cooler, and building snowmen or
large pieces of agglomerated
clinker. Decreasing the silica ratio (i.e., by having more liquid) from a known satisfactory
modulus will narrow the temperature range within which the kiln can be operated
without problems.
Liquid phase
The importance of the liquid phase is considerable in regard to having an effective
clinkering zone that will form the final cement compounds (high C 3S content with low
free lime). Melt development is also important for C 3S development because as the
clinker minerals are formed, the exothermic heat of formation is absorbed in the liquid
and can be transferred rapidly to other reacting species.
Lime saturation factor (LSF) or the C3S content
Lime saturation factor (LSF) or C3S content provide indications of how much calcium
oxide, or lime, is in the kiln feed relative to the other components. As C 3S content or LSF
increases, kiln feed becomes harder to burn; as they decrease, kiln feed becomes easier
to burn.
A kiln feed that is too “easy to burn” (requires lower temperatures or less time to
chemically combine C2S with free lime to produce C3S) may be an extremely difficult mix
for an operator to control in a kiln. A mix with low silica ratio and a high liquid, especially
with a low lime saturation factor, will be easy to over fuel and will tend to become sticky
in the burning zone if the kiln is overheated slightly. If kiln feed is too easy to burn,
clinker can easily melt and form a liquid, if it is allowed to flow into the cooler, can cause
serious damage to grates and other cooler components. An easy burning mix will tend
to build thick coating, but the coating is generally unstable and falls out if the
temperature profile or feed composition is slightly altered. Sometimes, making a mix
that is a little “harder” to burn will make stable operation of a kiln much easier.
Kiln Feed Chemical Uniformity
Good kiln feed chemical uniformity is required for stable operation and results in the
following
benefits: higher clinker production, reduced kiln downtime, improved brick life, and
reduced fuel consumption. The following table provides some guidelines on acceptable
variations in different kiln feed parameters.
C3S, % 3.0
Silica ratio 0.15
20 or less 90
20-25 85
25-30 80
30-35 75
35 or more 70
In general, a summary of some of the important factors in producing quality clinker can
be
outlined as follows:
The chemical composition of the kiln feed should be designed to obtain sufficient
liquid, but not too much, with components controlled to obtain desired clinker
composition.
Feeding a homogenous mix of the fine oxides is important so that these oxides
can be available to each other in the proper proportions to combine and form the
desired clinker compounds.
The proper degree of fineness required for the combination of the four principal
oxides (CaO, SiO2, Al2O3, and Fe2O3) must be maintained. The form of the silica and
limiting the maximum size of the silica entering the kiln are of particular
importance
A controlled kiln feed rate (including the moisture content) is important so that
the system energy requirement is constant.
Temperatures throughout the system must be controlled to develop and maintain
proper clinker temperature in the burning zone for the particular homogenized
mix to achieve complete compound formation, avoid uncombined silica and limit
free lime in the clinker.
Fuel heating value, fineness, and ash chemistry must be as constant as possible.
Fuel firing rate must be steady, repeatable and controllable.
Clinker cooler operation must be controlled and stable to supply a steady heat
input to the system.
The critical point in the operation of a rotary kiln producing cement clinker is when the
material
temperature reaches about 1250°C. Since this point establishes when the liquid phase
forms and most of the clinkering reactions begin, it also establishes the length of the
burning zone. If this temperature is reached close to the discharge of the kiln (nose), the
burning zone will be short; if this temperature is reached sooner, the burning zone will
be longer.
When kiln feed is placed into the kiln system, the material temperature remains relatively
constant at about 100°C until free water is evaporated. Once water is evaporated, the dry
kiln feed temperature rises quickly to about 600°C. Combined water in clay minerals is
vaporized in the temperature range of 200°C – 600°C. Decarbonation of calcium and
magnesium carbonate begins slowly at about 600°C, and is completed at about 1000°C –
1100°C. Most of the decarbonation occurs at about 900°C. As previously noted,
carbonate decomposition requires a substantial amount of energy; consequently, the
temperature increase of the materials as they undergo calcination, from about 600°C to
about 900°C, is very slow. Following the calciner vessel or the calcining zone, a relatively
short length of the kiln is used as a heating zone. The heat being added increases the
material temperature quickly, because the mass to be heated has been reduced by about
35%, and the endothermic reactions are relatively complete. At 1200°C – 1250°C iron and
alumina in the kiln feed begin to melt; the remaining reactions that form the clinker
minerals occur at material temperatures ranging between 1100°C – 1450°C. Formation of
most of the clinker minerals is exothermic (release heat) which rapidly increases material
temperature. Belite formation from lime and silica is strongly exothermic, as is the
formation of low-lime aluminates and ferrites. However, the formation of alite from
belite and free lime is almost thermally neutral.
Clinker Formation
Clinker formation is a time and temperature-controlled reaction.
In the clinkering zone, one of the main reasons that the amount of liquid phase increases
very rapidly is that some of these exothermic reactions take place and release heat
directly into the melt. An important point to help in understanding the exothermic
reaction effect is to realize that in the clinkering zone, this heat from the exothermic
reactions is released right where it is needed. The full heat release is in the material bed
as soon as the reaction temperature has been reached. If the material in the charge is
already completely calcined, and no endothermic reaction heat is required, this heat
goes into raising the bed temperature so that more reactions can proceed faster and
more heat will be developed in the bed.
Features of kiln
Kiln Shell
Kiln shell is the trunk of the rotary kiln. It is composed of several steel cylinders by
welding. Kiln shell bears the weight of all rotary parts such as shell, kiln coating, bricks
and material. And it
transfers the load to three support units by tyres. Kiln shell temperature is monitored.
Problem arises on the kiln due to shell temperature at which permanent damage of shell
begin are;
Kiln shell hot spot
Hot spot is isolated area on the kiln shell with abnormally high temperature. It is quickly
detected by a shell scanner or with a portable infra-red pyrometer. It can’t be seen
during the day, and can hardly be seen at night. Therefore, based on the visible radiation
spectrum for hot surfaces their maximum temperature must be below 550°C (maximum
red spot temperature on the shell which force kiln operator to change some parameter
immediately).
Red spot
Differ from hot spot in that it is visible at night. While a hot spot is just a warning, a red
spot always demands some kind of action from the kiln operator. It is visible with
temperature of 830°C.
Tyre
It is used to bear the kiln shell safely. Because the tyre inner diameter is bigger than the
shell outer diameter, there will be a slip between the tyre and the kiln. The slip should be
monitored and not exceed 20mm.
Kiln at its riding tyres the kiln shell is not permanently fixed to the riding tyres, but is
designed to “float” within the tyres. There is a permanent clearance between the shell
and the tyre which allows for thermal expansion of the kiln during light-up of the kiln.
During light-up the kiln shell heats up and expands much more quickly than the tyre, as
the tyre is only heated by thermal conduction from the shell, and the tyre has a much
greater heat capacity. This means that during light up there is significant danger of
closing the gap between the shell and the tyre.
If the shell closes on the tyre severely normally the shell will deform within it in the
manner of a coke bottle. Occasionally the tyre will crack. It is the deformation of the kiln
shell at the tyre caused by constriction within the tyre which gives rise to problems of
kiln shell Ovality.
The kiln shell inevitably assumes the profile of the inner diameter of the tyre at the
bottom of its rotation, but at the top of its rotation it slightly sags into an oval shape. All
kiln suppliers allow for some shell ovality in their designs, ovality is linked to shell
stiffness and thickness.
Once the shell: tyre gap is closed the further expansion of shell under the tyre can only
take place by deformation, while on either side of the tyre it can expand circumferentially
– the kiln shell becomes permanently deformed. When the heating of the tyre catches up
with the shell the shell: tyre gap reopens, but the gap is now much wider than designed
due to the deformation of the shell, the ovality of the shell has increased.
Excessive ovality is the stresses imposed on the refractory lining and the kiln shell(causes
longitudinal cracks), the radius of curvature of the shell is closing and opening as the
shell assumes its oval shape, the refractory lining joints are successively compressed and
opened up, making it very difficult to retain the refractory lining in the kiln.
Supporting Roller
Supporting rollers bear all the weight of the kiln and position the kiln to make it run
safely and stably. Supporting roller is supported by two self-align sliding bearings.
The sliding bearing includes thrust ring, roller shaft, bush, spherical lining and base. The
bearing is equipped with the hot resistance to monitor the bush temperature. The bush
temperature is very important. Once it rises abnormally, you had better deal with it
immediately.
Thrust Roller
Hydraulic thrust rollers shall be mounted under the tyres of the support. The thrust
rollers force the kiln shell to move upward and downward on the supporting rollers at a
very slow speed, which can make the tyres and supporting rollers wear equally along
width and improve their lifetime.
Three bearings bear the load on the thrust roller. When a fault occurs on the thrust roller
such as vibration, heating or noise, stop the thrust roller station and check the bearings
later.
Drive System
Auxiliary drives have to be provided to ensure the kiln can continue to be turned in any
circumstances. These auxiliary drives might be a diesel fuel donkey engine. If an electrical
auxiliary drive is provided then there must also be an emergency power supply to guard
against the situation where there is a power failure to the cement plant. During the kiln
runs, the main motor current is important. The abnormal current fluctuation can show
some problem that usually is vibration of girth gear or tyre.
To protect the steel shell against heat –Material and gas temperature inside the
rotary kiln surpass the maximum working temperature recommended for carbon
steel. Without refractories the kiln shell would be destroyed by heat. As a result,
as soon as the refractory lining fails, the kiln must be shut down for lining repair.
The overheated areas on the kiln shell are commonly known as “hot spots” or
“red spots”.
To protect the kiln shell against abrasion –Cement clinker is very abrasive and
without refractories the steel shell would be damaged by abrasion.
To minimize heat loss through the kiln shell – Part of the heat supplied to the kiln
system is lost as radiation through the steel shell. Refractories reduce heat loss
because of their relatively low thermal conductivity.
To control the flow of material through the kiln – The kiln load travels under the
combined action of kiln rotation and slope. Cam linings, dams, tumblers, and
trefoils in the kiln oppose material flow allowing some control of material
residence time.
To promote heat transfer to the kiln load – Tumblers, trefoils, and profiled linings
induce
material tumbling and mixing, which in turn promote heat transfer from gas to
solids, from refractory to load, and within the load itself through agitation and
surface renewal.
Types of refractories for cement kilns
Refractories used in the kiln, cooler and preheater are supplied either as pressed or fired
brick, unshaped as monolithic products or in pre-cast, pre-fired shapes. The rotary kiln is
almost entirely lined with bricks, while the preheater, cooler, and gas ducts are usually
lined with castables, plastics or pre-cast shapes held in place by metal or ceramic
anchors attached to the shell.
In the burning zone of the cement kiln a coating of clinker forms on the refractory lining
and this further insulates and protects the kiln shell allowing long kiln campaigns
between refractory lining repairs. The key to building up and maintaining this coating is
stable operation of the kiln. Again the key to this stable operation is lack of variability in
the feed and fuel supply rate, the chemistry of the feed and the calorific value of the fuel.
Disturbances in the kiln process can lead to the loss of the coating in the burning zone
and a sudden increase in the rotary kiln shell temperature. Shell cooling fans can be
applied to protect the steel of the shell and try to reestablish the coating on the
refractory lining. Small red spots on the shell might be coated over in this way, but
eventually the kiln has to be stopped to replace the worn sections of refractory lining.
Basic
high alumina
Fireclay
Special materials
Basic Bricks
Basic bricks have magnesia or dolomite as their major component and a secondary
mineral such as alumina, zircon, or spinel as a minor component. In most products the
major component concentration varies between 60% and 95% by mass.
Magnesia alone is not used in kiln brick manufacture because of its poor thermal cycling
properties. For this reason, magnesia is blended with a secondary mineral before it is
pressed and fired into bricks. The secondary mineral confers thermal shock properties or
modified chemical properties to the brick. Magnesia-chromium products were replaced
with magnesia-alumina spinel products (due to disposal problems caused by hexavalent
chromium rendered these products). Although magnesia-alumina spinel products do not
present the excellent coatability of their predecessors, their thermal spalling resistance
and alkali resistance far exceed those of chromium containing products. Magnesia-spinel
products also resist reducing conditions better than magnesia-chromium products.
The magnesia-alumina spinel content in commercial bricks varies from 3% to 18% by
mass. Higher magnesia products are usually more refractory but have higher thermal
conductivity than lower magnesia products of similar porosity. Higher spinel bricks are
more susceptible to chemical attack and fluxing than lower spinel bricks, but they exhibit
better coatability and higher resistance to thermal spalling. The spinel itself can be
sintered or fused, causing major differences in brick price and performance. Fused oxides
are less reactive and less expensive than sintered oxides. It becomes clear from the
previous facts that refractories cannot be compared only on the basis of their chemical
or physical composition.
Dolomite brick is another important member of the basic brick groups. Due to their
compatibility with clinker minerals, dolomite bricks have good affinity for coating,
making them an excellent choice for burning zone applications. Most dolomite bricks
receive additions of zirconia or other secondary minerals to improve their thermal shock
properties and also to delay brick infiltration with clinker melt and alkali salts. Some
modern dolomite bricks include additions of magnesia, while others include additions of
pitch or tar to decrease brick permeability and reduce its susceptibility to chemical
attack. Dolomite products offer the lowest direct cost among all basic brick, but their
application has been confined mostly to the burning zone where the clinker coating is
more stable. The most adverse property of dolomite products is their risk of hydration,
requiring special care in packaging, handling, and storage. The shelf life of dolomite
products has increased considerably by a special vacuum packaging and brick treatment.
High-Alumina Bricks
High-alumina products used in cement kilns vary in alumina content from 50% to 85%
by mass.
To assume that all 70% alumina bricks are just commodities which is a risky
generalization. For instance, a mullite based product presents greater thermal shock
resistance than its bauxite counterpart. Similarly, a 60% andalusite brick resists alkali
attack much better than its 60% bauxite equivalent. Higher alumina products, such as
80% or 85% are sometimes used in the discharge zone of the kiln because of their
superior mechanical strength and abrasion resistance. These bricks sometimes contain 1
to 3% phosphorus pentoxide to improve their hot strength and abrasion resistance.
Some phosphate-bonded bricks are called oven-cured rather than fired at high
temperatures. These products present better dimensional tolerances than their fired
equivalents and are called chemically-bonded brick, as opposed to clay-bonded or
ceramic-bonded.
In the calcining zone of the kiln, 70% alumina is the preferred choice unless alkali attack
is so
severe that a lower alumina product is required. As a general rule, the resistance to alkali
attack
increases as the alumina content decreases.
Fireclay Bricks
According to their alumina content and porosity, fireclay products are classified as high
duty, super duty and semi-silica. Although widely used in the upper part of the calcining
zone in the past, high-duty and super-duty bricks are gradually being replaced by high-
alumina and semi-silica products. One of the reasons is the difficulty of keeping fireclay
brick tolerances within acceptable limits. Another reason is loss of strength at higher
operating temperatures. During kiln upsets, fireclay products tend to react with the kiln
load, leading to abrupt lining failure. Semi-insulating products, although very low in
mechanical strength, have the unique ability to react with alkali vapors in the kiln to form
a thin glaze that protects it from abrasion and chemical attack. Their low thermal
conductivity significantly reduces kiln shell temperature, a major advantage over tires.
For best performance, these lightweight products must be installed with mortar.
When selecting a semi-insulating product, attention must be paid to its thermal
expansion properties. Some products shrink at temperatures above 1000°C, a great risk
in Precalcining kilns. Insulating bricks form a unique class of products. They are used only
as backup linings for denser products in the preheater, cooler, and tertiary air duct. They
lack the mechanical strength and refractoriness necessary to be used directly as the work
lining.
Thermal stress
In the thermal stress category, lining overheating and sudden coating loss are the most
common causes of brick failure. Overheating can be caused by many different factors
such as feed starvation, excess fuel, kiln stoppages with the burner on, slowing the kiln
down for long periods of time, defective burner pipe, and massive ash ring formation in
the upper transition zone. Lining overheating can be restricted to a given kiln zone or
even to a few rows of brick within the zone. Sudden coating loss, for instance, submits
the lining to damaging thermal shock.
Mechanical stress
In the mechanical stress category, brick crushing is the most common problem. The main
reasons for brick crushing are:
Refractory applications
Modern kiln systems are lined with refractories in four different areas:
Preheaters
Preheaters are lined with brick, castables, and combinations of brick and castables. The
best
performances are obtained from brick linings because bricks have more uniform
properties, are
fired at high temperatures, and do not require the use of anchors. Bricks also yield more
flexible linings than castables because of the larger number of joints in the brickwork.
Preheater linings consist of two layers of materials: a dense layer also called the work
layer, over a layer of insulating material such as insulating castable, firebrick, or
fiberboard. The insulation must be efficient to minimize heat loss through radiation
because the surface area of the preheater vessels and ducts is large. The combined lining
thickness rarely exceeds 250 mm, with the dense layer usually taking from 50% to 75% of
the total lining thickness.
The higher vessels and ducts in the preheater only require fireclay, low-alumina brick, or
castable.
Toward the kiln, where temperatures are higher, the lower stages 3, 4, and 5 work under
high
concentrations of chlorine, potassium, and sulfur. In these areas the refractory must be
less permeable and more resistant to alkali infiltration and attack. Care must be taken
not to sacrifice chemical resistance for refractoriness because the maximum temperature
in this part of the kiln rarely exceeds 900°C.
Another important requirement for refractories in this area is their ability to repel
buildups. As
alkali sulfate and alkali chloride vapors progressively condense as salts on the lining
surface, they reduce gas and solids flow, thus reducing preheater efficiency. If these
buildups are not removed periodically through air or water blasting, they can completely
block gas and material passage, thus forcing a kiln shutdown. Buildup removal with
water requires high resistance to thermal shock from the lining. The material of choice
for these areas is 60% or 70% alumina, low-cement castable, held in place by a
combination of metal and ceramic anchors. If buildups are severe, zirconia or silicon
carbide containing castables are much better alternatives since they do not hold
buildups strongly. The use of silicon carbide in this application is not recommended if
buildup removal is done with a water blast. Water promotes carbide oxidation at high
temperatures.
Precalciner
For the precalciner, the riser duct and the feed shelf, the same recommendations apply.
In
buildup areas the monolithic lining should not be gunned, shotcreted, or rammed, for
maximum coating repellency.
The lining inside cyclones and the flash calciner is usually a combination of brick on the
cylindrical surfaces and castables on the conical sections, roof, vortex finders, and inlet
chamber. The calciner lining must also resist reducing conditions created by incomplete
fuel combustion.
Rotary Kilns
Modern rotary kilns can be safely lined with just two types of bricks:
Kiln hood
The next area of concern is the kiln hood, a transition chamber between the kiln and the
clinker
cooler. Temperatures in the hood are higher than those in the preheater, and potassium
attack is a factor in refractory selection. Another factor of concern is the high
concentration of abrasive clinker dust that could penetrate behind the refractory lining,
pushing it in until it collapses. The most suitable material for hood walls is fireclay or
low-alumina brick, followed by pre-cast, prefired shapes and cast-in-place linings. On
average, shotcrete or gunning mixes do not outlast the previous alternatives because
they lack uniformity of properties. From a purely cost/benefit standpoint, brick lining is
the best alternative. Pre-cast, pre-fired shapes made with low-cement castables usually
last from 3 to 10 years without maintenance in cooler walls.
The back wall and the hood ceiling can be rammed with refractory plastic, gunned,
sprayed, or
formed, and cast. The main wear factors in these areas are clinker dust, alkali attack, and
anchor failure. In some kilns the back wall is equipped with air blasters to eliminate
clinker
buildup. The use of silicon carbide materials in this application could be advantageous.
Burner Pipe
The burner pipe is usually lined with 75 to 100 mm of plastic or castable, held in place by
metal anchors. Anchor failure and differential expansion are the most frequent reasons
for burner pipe failure. Consequently, it is important that the metal anchors are the
floating type. Usually only the first 500 mm from the tip of the burner become damaged
in service. This is the area that requires the most attention during material selection and
installation.
Clinker Cooler
With modern, high-efficiency coolers, the secondary air temperature surpasses 1000°C,
thus requiring more refractory products around the hood. Metal anchor failure under
thermal stress became common, requiring stainless steel of higher grade and caliber.
Ceramic anchors are required in the hottest areas. In some extreme cases, basic brick has
been successfully used in the hood. In the cooler, the three sidewalls before the bull nose
can be lined in many different ways. A cost effective alternative for this application is
pre-cast blocks individually anchored through the cooler shell. Anchoring the blocks
inside the shell defeats the main advantage of
this system: quick lining repair. The material of choice for the blocks is 70% alumina, low-
cement castable. If cooler buildups (“snowmen”) are severe, then the blocks can be cast
with silicon carbide to take advantage of its non-sticking properties. The air blasters are
still required between the carbide blocks.
The bull nose is one of the most difficult areas for lining stability. Usually the wear
mechanism is dust penetration behind the lining, followed by anchor overheating and
shearing. The best lining alternative is interlocking pre-cast shapes anchored to a hollow
box beam. Cold air is blown into the box to cool down the anchoring system. The
refractory material must resist constant abrasion from hot clinker dust and frequent
temperature changes.
At the grate level, refractory curbs are used to keep the clinker from eroding the walls.
Curbs are usually formed and cast in place, requiring careful heat up because of their
massive size. Here, too, pre-cast, pre-fired, high-alumina curbs make the best lining
alternative. The use of 2% by weight steel fibers in this application is highly
recommended. The fibers increase the tensile and flexural strength of the lining.
Walls in the cooler can be advantageously lined with inexpensive fireclay brick. Brick
linings in the cooler, when properly anchored and mortared, should last no less than 10
years without repairs.
The cooler roof is best lined with plastic or a good quality shotcrete mix, anchored by a
combination of metal and ceramic anchors. Another cost effective alternative is to use
pressed and fired shapes directly suspended from steel beams.
CLINKER COOLERS
In cement manufacturing, formation of clinker nodules occurs at the entrance to the
hottest part of the kiln with a material temperature of around 1280°C. The clinker is
preferably in the form of 10-mm to 25-mm size nodules that exit from the front end of
the kiln into the cooler. It is critical that cooling of the clinker is rapid to secure a phase
composition that imparts adequate cementitious properties. It is equally important that
the heat exchange between clinker and air is efficient to ensure proper cooling and at
the same time maximize the recovery of heat to secondary air, tertiary air and the related
process requirement.
At the discharge end of the kiln, the clinker is red hot and contains around 1.0 million
Btu per
short ton thermal energy. The clinker is also to some extent still reacting chemically
toward
creation of various clinker minerals. The purpose of the clinker cooling is to recoup some
of the
heat in the clinker, thereby making it cool enough to handle. We also want to stop the
chemical
reactions in the clinker at the point most favorable to the cement quality.
Design project would include some of the following requirements:
In the kiln after the material passes the burning zone region, and
In the specially designed clinker coolers after the material falls out of the kiln.
The rate of cooling can be critical to the clinker quality and performance of cement. The
rate of cooling in the kiln is determined by the flame and resulting heat flux, flame
temperature, and speed of material flow through the kiln. As the clinker temperature
exiting the kiln is normally 1200°C to 1250°C, the clinker characteristics have been
already largely established before the clinker enters the cooler. A long flame gives slow
heat-up and slow cooling of the kiln charge before it falls from the kiln.
2) Rotary Coolers
3) Shaft Coolers
4) Grate Coolers
Kiln drop zone; hot clinker from kiln is discharged onto this area.
Recuperation zone; cooling air from this zone flows back to kiln as secondary air
and to calciner as tertiary air.
After cooling zone; cooling air from this zone goes to exhaust air.
Kiln drop zone
Requirements:
Protecting against thermal and mechanical load
Fast quenching of clinker / Efficient heat exchanging
Distribution of clinker over cooler width
ETA Solution: HE Module
Static inlet section; Static clinker layer: heat + impact protection
Optimum contact between air and clinker
Inclination of the static grate; Support clinker transport
Narrowing at sides made of refractory
Distribution of clinker over cooler width
Recuperation zone
Requirements
Maximum heat exchange
Efficient transport of clinker
ETA Solution
Longitudinal walls in Chamber 1
Air can be directed to where it is required
Controlled Side Aeration-CSA; Controlled aeration in critical areas
Walking floor motion
Highly efficient clinker transport
Different stroke lengths of lanes possible
After cooling zone
Requirement
Clinker cooling to required outlet temperature
Efficient transport of clinker
ETA Solution
Walking floor motion
Highly efficient clinker transport
Different stroke lengths of lanes possible
Chamber aeration
Simple aeration, low maintenance
Active Controllability of Clinker Bed / Heat exchange
Static Inlet
The HE -Module opens up from the kiln drop point to the transport lanes by means of
refractory concert. Here an optimal clinker distribution over width is achieved. With the
HE-Module, which consists of astatic inclined grate the risk of snowman forming is
virtually eliminated, while also ensuring a protective clinker layer on the module itself.
The HE-Module is aerated via independent zones; each zone has its own flap to adjust
the air volume. Due to flexibility of the air distribution, it is possible to control the kiln
discharges conditions even with changing environment, due to the use of different fuels
and raw materials fluctuations. Depending on the required throughput capacity, a
corresponding number of parallel transport lanes are installed, each supported on
independent rollers.
Due to Independent Lane Movement (ILM) (parallel individually driven aerated lanes), the
flow behavior and material speed at the sides can be actively influenced. The slots for the
air supply are integrated in the transport lanes by utilizing the Mulden grate plate
principle. Each transport lane is sealed by means of labyrinth, which eliminates the need
for a dust removal system. This together with the fact that the transport lane system is
typically offered without any inclination makes the eta cooler design extremely compact.
Aeration concept
Since no installations are required inside the clinker layer the entire cooler bottom is fully
aerated leading to uniform cooling and optimum recuperation. Additionally the eta
cooler still makes use of the chamber aeration principles – a well proven aeration
concept in conventional grate cooler design. However, in contrast to reciprocating grate
cooler the eta cooler allows for longitudinal division in to chambers. This gives the
advantage of chamber side aeration (CSA) and Independent Lane (ILM) Claudius peters
can as no other cooler supplier, activity influence the two most important parameters in
clinker cooling. This gives us the possibility to virtually eliminate such problems as red
river.
Features
Extremely compact design
No dust removal system required
Complete autogenous wear protection
Long stroke = low grate speed
Variable stroke length over the cooler width
No conveying parts with in the clinker bed
1. Less wear significantly reducing maintenance
2. b) No obstructions to the clinker flow
3. Constant transport efficiency over cooler life
Controlled air distribution –chamber side aeration
Benefits
Low construction height
Modular design –quick to install
Optimum cooling and heat recovery
Optimal distribution of clinker across cooler width
Lower operating costs
High reliability
Drive system
The eta cooler is equipped with an independent hydraulic cylinder drive for each lane.
Depending on the number of transport lanes, the structure is modular and utilizes
standard part, which minimizes maintenance and adjustment. The hydraulic cylinders
attributed to each transport lane enable along lane stroke, which is controlled by an
integrated continuous position measuring system.
Eta motion Control Center controls and monitors all functions of the lane/ cylinder
motion. This hydraulic control system continuously measures the position of the cylinder
without contacts to ensure the stroke length required for each individual lane.
Cooler Efficiency
Cooler efficiency can be divided in to two groups
1.
1. Internal thermal efficiency
2. External thermal efficiency
1. Internal Thermal Efficiency is using the recovered heat in burning process
Secondary air heating in primary firing
Tertiary air heating in Calciner firing
1. External Thermal Efficiency is using the recovered heat for other process
Raw mill, Coal Mill and Cement mill drying
Heating and power generation
Speed of Clinker Cooling
Rapid cooling
prevents growth of crystals and its size; gives suitable clinker nodule
solidify the clinker in to glass state
Improve C3S and reduce C2S leads to
Easy grindability
Lower energy consumption
Improve hydration and cement Strength
The clinker cooler has the following tasks to fulfill:
Process internal heat recuperation by heat transfer from clinker to combustion air
Reduce clinker temperature to facilitate clinker handling and storage
Provide maximum cooling velocity to avoid unfavorable clinker phases and crystal
size
Typical Grate Cooler Problems
Red river
The infamous red river is one of the most feared problems with grate coolers. Due to
segregation, fine clinker has always its preferred side. Different bed resistance on either
side and only one air chamber across the entire width often cause fluidization of the fine
clinker lying on top. This fluidized clinker does no longer follow the speed of the grate,
but shoots much faster towards the cooler discharge end. Because the residence time of
that fine clinker is much reduced, it does not follow the general cooling curve and forms
a red hot layer on top of the regularly cooled, already black clinker; hence the term “red
river”.
It is not the missed heat recuperation, but the red hot material being in touch with
cooler walls
plates and side seals in the colder area where such temperatures should normally not
occur.
Premature destruction of those pieces results in poor availability, high maintenance and
ultimately in loss of production and sales revenues.
Snowman
The sticky consistence of the hot clinker leaving the kiln combined with the compaction
at the drop point often leads to formation of solid clinker mountains on the grate. Not
permeable for cooling air, they grow larger and disturb the flow pattern of the clinker in
any critical inlet area.
Segregation
Due to its physical properties, the clinker is lifted by the kiln rotation before it is
discharged into the cooler. Installation of the grate axis offset from the cooler axis
should compensate for this effect. However, since discharge behavior of finer and
coarser clinker particles differ from each other, the clinker fractions are not evenly
distributed across the grate. Fines are discharged later and are thus found predominantly
on the rising side of the kiln shell.
Primary air
Is the air which is required for proper functioning of the burner. Ambient air insufflated
by a separate small fan plus the air from a pneumatic transport system, amounting from
< 10% up to > 30% of the air required to combust that fuel. Some precalciner burners
are equipped with primary air fans (for cooling) as well.
Secondary air
Is the hot air entering the rotary kiln via clinker cooler. Its flow is determined by the
combustion of the burning zone fuel. While cooling the clinker, it reaches temperatures
of 600 to over 1000°C, depending on type and condition of the cooler.
Tertiary air
Is that part of the combustion air which is required for combusting the precalciner fuel. It
is extracted from kiln hood or cooler roof, and then taken along a duct (tertiary air duct)
parallel to the kiln to the precalciner. It reaches temperatures near or equal to the level
of the secondary air.
False air is cold air entering the system via kiln outlet seal, burner opening, casing or
clinker
discharge. It either dilutes secondary air thus reducing recuperated heat or adds load to
the waste air system of grate coolers.
Specific air volume
Is airflow per kg of clinker (m3/kg cli, Nm3/kg cli). Independent of the kiln size, air flows of
cooler systems can be directly compared.
Specific loads
Express the relation of clinker production to a characteristic dimension of the cooler (t/d
m, t/d m2, t/d m3). Exact definitions vary with cooler type.
Radiation losses
From the cooler casing/shell are particularly important for planetary coolers, where they
actively support the cooling of the clinker.
Efficiency
It expresses the quality of heat transfer from clinker to the air which is used for
combustion in the burning zone and precalciner firing.
FEUL TYPES
As Clinkerization process is an endothermic (heat absorbing) process it requires burning
of Suitable fuel. Remember almost 40 % of the total cost spent for manufacturing
cement is for fuel and power. The specific heat consumption of modern plant ranges 690
to 800 Kcal/kg clinkers.
The objective of firing in kiln is to convert the latent heat in the fuel to free heat and to
transfer this heat to the charge in the kiln.
In the cement industry, coal, fuel oil and natural gas are the fuels used for combustion
commonly. Optimum rate of combustion is achieved by appropriate time, temperature
and turbulence.
Heavy fuel oil is the mainly used oil in Cement kiln as it is comparatively cheaper. Fuel oil
Composition (% by weight) 85 % Carbon, 11-17 % Hydrogen and 1- 2 % Sulphur.
Sulphur in HFO goes up to 5% and it is the major cause for built ups in cyclones / riser
ducts. Viscosity of HFO varies according to oil type and temperature. A viscosity of 12-18
centistokes is required for satisfactory atomization of oil in most of the burners.
3) Oil preheating temperature limit: 110 0C, as it is the flash point of heavy fuel oil
4) Interlock arrangement for oil flow to avoid explosion problem for safety
Coal Characteristics
Coal represents widest range of qualities
Compared to Oil and Gas, the Hydrogen in coal is fairly less
As the coal becomes older, gas forming elements (H,N,O) reduces and fixed
carbon increases
Coal firing gives less dew point of flue gas
The difference between Gross and Net Calorific value of Coal shall be 200 – 300
Kcal / kg only
Calorific value of Coal depends on the contents of inert substance like moisture
and ash
For aged coals like Bituminous and Anthracite coals increase of hydrocarbons
(Volatiles) will increase the Calorific value.
For young coals, increase of Volatiles will decrease the Calorific value due to
presence of more of inactive O2 and N2 in the volatile
Sulfur in coal is a vital factor for coating build up in preheater. This will vary from
1 to 1.5% and may go as high as 5%
Major classes of coal are
Anthracite
Bituminous
Ligneous
The Concept of rank
Rank is an expression of the Fixed Carbon Content of the Coal. Fixed Carbon is the
amounts of Carbon left after treating the coal to a specific temperature say 925 or
950 0C. General Ranking is Peat, Lignite, Bituminous, and Anthracite with corresponding
Fixed Carbon contents increasing from about 29% to about 95 %.
The rank of coal implies
Progressive increase in Fixed Carbon content
Progressive decrease of volatile content
Progressive decrease of the Hydrogen and Oxygen content
Progressive increase of the Calorific value
Proximate analysis which gives the amount of moisture, volatile matter, ash and
fixed carbon in coal
Ultimate analysis which gives the amount of elements namely Carbon, Hydrogen,
Oxygen and Sulphur
Coal is also analyzed for
Calorific value
Contents of alkalis and chloride
Grindability, Abrasion and Safety Index
Coal ash is also analyzed chemically which is very vital for raw mix design.
Moisture in Coal
Reduces calorific value
Hinders the ignition
Reduces the flame temperature
Slows down the rate of combustion
Increases the burn out time
Increases the flame envelope
Increases the risk of flame instability
Caking problem in fine coal bin and disturbed coal flow
Increases the specific heat consumption
Increases exhaust gas quantity and ID fan power
Free moisture
The moisture removed by air drying just above the room temperature and determined
by drying of coal of a standard amount for 24 hours at 30 0C.
Hygroscopic moisture
Moisture bound in the air dried sample and determined by heating for some time at a
temperature above 100 0C.
Total moisture
Sum of free moisture and hygroscopic moisture
Volatile Matter
Rough indicator of the combustivity of coal
Volatile matter is the hydro carbons present in the coal, which evaporates first
when a dried coal is heated
Higher Volatile matter leads to rapid oxidation and shorter flame
As the rank approaches anthracite, the ignition temperature raises and ignition
becomes difficult and the volatile matter is lesser
A minimum of 22% is required for flame stability
Volatile matter is determined by heating the coal sample in a special oven at
900 0C for 7mins
VM = (The % loss of mass) – (% of total moisture)
Ash in Coal
It is residue left after combustion which is merely an inert diluent and influenced by
mainly chemical composition and thermal properties. Ash differs in mass as well as
composition depending upon the mineral matter from which it was formed. It can also
Influences the reactivity of coal and lowering the calorific value and delaying the ignition
of coal which intern affects the specific heat consumption and clinker to raw meal ratio
in clinker production.
For low grade coals with high moisture, the NCV will differ significantly from GCV
Moisture
Reduces the heat value as it absorbs heat for vaporization and to reach the
exhaust gas temperature
Reduces the flame temperature by cooling effect
Increases the specific heat consumption
Ash
High ash reduces the heat value and flame temperature
Higher ash content delay the combustion
Reduction in clinker production
Volatile Matter
Increase in VM increases the reaction of fuel
Shorter flame and reduction in bloom length
Effect of C, H, N and O2
Higher the hydrogen content, higher will be the CV
Moisture Content
Important role in firing process and safer operation of the coal mill plant
Higher the hygroscopic moisture in the raw coal, higher will be the residual
moisture in the fine coal
Fineness
Important to achieve a complete combustion in Kiln and Calciner
Calciner coal to be ground finer as the firing temperature is lower
The optimal fineness is a function of volatile matter as the burn out time for
higher volatile coal is lesser
Coal having a higher Hard groove index is easier to grind and the power
consumption for grinding is more
Low Grade Coal
* Grade of coal
Primary air
Secondary air
False air
Primary air, Secondary air, false air provides theoretical combustion air but if excess air is
included it gives actual combustion air.
Quantity of combustion air in kiln system is adjusted by the preheater fan speed. Lack of
combustion air in kiln is indicated by kiln inlet O 2 analyzer (<1%)
For efficient combustion O2 should be
0.5 to 1.0 % at Kiln inlet
ALTERNATE FUELS
Other than the indigenous high ash coal, alternate fuels used are
Imported coal
Natural gas
Pet coke
Rubber tyres
Bagasse
Rice husk
Natural gas comprised mainly methane (70-90 %) and propane (0-20%) and the
calorific value will be in the range of and 8000 – 9700 Kcals / m 3
BURNER
The function of the burner is to introduce the fuel into the burning zone. The
propagation of the combustion process depends on how fast the combustible comes
into contact with oxygen. It is therefore the essential function of the burner to regulate
this mixing process adequately in order to achieve a correct flame shape. This process
must take place in such a fashion that the heat is released at exactly the right place
without producing any damaging effects and without producing excessive pollutant
elements such as NOx, SOx and CO. Consequently, any optimization of the burning
process must start with the correct adjustment of the flame.
In the sintering zone of rotary kiln, where the temperatures is highest over 1400°C
required in the of a cement kiln to make the final combination of the clinker. The thermal
energy to reach these process temperatures is input to the kiln through the main burner
of the kiln, through the kiln hood and into the rotary section of the kiln.
To deliver the required fuel in a stable, consistent, thermally efficient and safe
manner
To allow the amount of fuel delivered to be adjustable to the needs of the
process
To operate reliably over the long interrupted campaigns of days, weeks and
months that are required of cement kilns
To deliver that fuel in a way that does not compromise the ability of the other
elements of the cement kiln process to operate over the required long,
uninterrupted campaigns.
To be adjustable to ensure the production of the clinker to the required quality in
terms of combination and hydraulic reactivity.
To minimize, as far as possible, the emissions from the cement kiln.
To allow the burning of multiple traditional and alternative fuels on the kiln.
The fuels are injected into the kiln through the main burner, together with the primary
combustion air, and spontaneously ignite as they encounter the high temperature in the
kiln. Ensuring this ignition close to, but not on the burner tip is the first requirement for
stable and safe operation. Fuel oil must be adequately atomized and coal must be
ground to a residue on a 90µ sieve equivalent to half the volatile content and a residue
of <2% on a 200µ sieve for stability. Position of the burner in the kiln is parallel with the
kiln axis and in the center of the kiln cross-section but in large diameter kilns the burner
is sometimes positioned offset from the center of the kiln cross-section towards the bed
of material to increase the heat transfer by radiation to the charge from the flame.
Efficient combustion in a cement kiln flame is dependent on the availability and mixing
of sufficient combustion air with the fuel for these reactions to take place in the flame.
Only a minor part of the combustion air is provided by the primary air, which is blown
into the kiln through the burner pipe. The remainder of the combustion air must be
entrained into the flame and mixed with the fuel from the preheated secondary air which
is drawn into the kiln from the cooler. The secondary air carries the thermal energy
recovered from the clinker in the cooler back into the kiln. Maximizing secondary air and
minimizing primary air is therefore the theoretically most thermally efficient way to
operate the kiln.
The correct flame shape and burner adjustment has to be inferred from the clinker
quality, shell temperature profile, coating tendency and the kiln inlet temperature, which
should be <1100°C and the lower the better. The adjustment of the burner will be a
critical factor in obtaining a stable and even coating on the refractory lining in the kiln,
which in turn will assist in achieving the long, uninterrupted campaigns of operations
that are required of a cement kiln. Generally burner can be divided in to two; Mono-
channel and Multi-channel burner
High amount of primary air (In combination with direct firing systems for coal, up
to 50% primary air)
Very limited flame shaping possibility
High NOx formation
Long and stable flame
Multi-channel Burner
For optimum flame shaping, when considering changing coal quality and different
requirements from the point of view of raw mix burnability, burners with adjustable
flame are to be preferred. In such burners, the primary air is usually divided into an axial
and a radial component with the coal also introduced via a concentric ring tube. These
burners are called multi-channel burners and are usually suitable for alternate or
combined firing of coal, oil or even gas.
Axial air is injected in the direction of the kiln axis (similar to a mono channel
burner where all the air is injected in axial direction).
Radial air (or swirl air) is injected with a direction towards the kiln wall. The swirl
component of the radial air creates a rotating air flow along the kiln axis (similar
to the threat of a screw) which is also pushing towards the outside, in direction of
the kiln wall.
Since the radial air channel is located inside the axial air channel (both are concentric
ring
channels), the radial air is opening up / widening the flow of the axial air. An increase of
radial air versus axial air therefore creates a shorter flame. An increase of axial air versus
radial air creates a longer flame. Besides flame shaping, the primary air (especially the
axial air) also has to cool the burner
pipe.
Some of new generations of multi-channel burners are
Kiln capacity, heat consumption and clinker qualities are defined by:
Correct composition of raw meal
Chemistry
Burnability
Meal fineness
Correct burning conditions
Fuel input and fuel distribution (kiln-calciner)
Process control
Clinker cooling
The three Stages of clinker burning optimization with M.A.S. burner
1st Stage: Control of flame shape by flame setting device
2nd Stage: Control of combustion intensity by adjustment of the M.A.S.-air pressure
1. high pressur 180 mbar hot,short flame
2. medium pressure 130-180 mbar
3. low pressure < 130 mbar soft, long flame
3 Stage: Control of flame core temperature by adjustment of the central air pressure
rd
1. By increasing the central-air pressure, the flame gets stable and the pressure in
the flame root drops
Optimization of coal firing
Adjustment of coal dust injection velocity with coal nozzle setting.
Wide, short flame: increase the radial gas pressure by opening of the radial gas flap
Long, narrow flame: increase the axial gas pressure by opening of the axial gas flap
Keep the axial and radial gas pressure over 0.8 bar g
If the radial gas flap is already 100% open, but the flame is not sufficient short, increase
the cross section of the swirl gas nozzle.
Poor clinker burning, high free lime content in clinker, high CO-content in flue gas
Trouble shooting
Increase the M.A.S.-air pressure
Find the maximum flame core temperature with central air pressure
Adjust wide, short flame by flame setting device
For solid secondary fuel burning – change pressure of Pneumoswirl-air
Check oxygen content in flue gas and pressure difference through the kiln.
Increase the secondary air flow. (If ID fan doesn‘t have sufficient power, decrease
tertiary air flow)
Check the fuel quality: coal dust fineness, moisture (<1%) Increase coal dust
fineness.
Brown clinker, reducing burning condition
Trouble shooting
1. Check oxygen content in flue gas and pressure difference through the kiln.
Increase the secondary air flow. (If ID fan doesn‘t have sufficient power, decrease
tertiary air flow)
2. Increase pressure of the M.A.S.-air and central air
3. Change the position of the burner tip in kiln
4. Check the fuel quality: coal dust fineness, moisture (<1%) Increase coal dust
fineness.
5. For solid secondary fuel burning- change pressure of Pneumo swirl-air
6. For solid secondary fuel burning – decrease the particle size or fuel quantity
High kiln shell temperature, poor coating
Trouble shooting
1. Adjust soft, long flame by flame setting device
2. Decrease the central air pressure
3. Decrease the M.A.S.-air pressure
4. Change the position of the burner tip in kiln. Adjust the flame in kiln center
5. Check the fuel quality: coal dust fineness, moisture (<1%).Increase coal dust
fineness.
6. Decrease the secondary air flow with ID fan
7. Use the outer cooling of kiln shell with auxiliary fans
8. Change chemistry of the raw meal
Parameters affecting NOx:
Burning zone temperature
Free lime
LSF
Secondary air temperature
air flow characteristics (cooler type)
Thermal kiln loading
Kiln design –staged combustion in calciner
Fuel grinding size and volatiles content
Burner tip position in kiln
Fuel surrounded by primary air (staged combustion)
Low primary air amount (momentum)
Close fuel ignition distance
Mixing intensity of fuels (swirl number)
Burner settings (avoid oxygen inside flame root)
Trouble shooting
Decreasing of NOx Emissions
Decrease M.A.S.-swirl on the swirl setting device to a narrow, long flame shape
Decrease pressure of the M.A.S.-air
Adjust pressure of central-air (try the upper and lower limit)
Increase coal-dust injection velocity
For solid secondary fuel burning – decrease pressure of Pneumoswirl-air
Change the position of the burner tip in kiln
Decrease temperature of secondary air (if possible)
Burner position in rotary kiln
Initial position X=0 up to 1000mm
for coal- following kiln axis or fuel oil- horizontal (rotate around fix point)
Further optimization
move the burner tip to the clinker
keep the flame away from the coating
find the best axial position of the burner
General considerations to burner axial position
Burner tip deep inside the kiln >> 0.5 m
risk of reduced kiln capacity and high flue gas temperature at kiln inlet
more straight flame
better fuel ignition
reduced risk of ring formation at kiln outlet
increase of kiln capacity and reducing of the flue gas temperature at kiln inlet
risk of uneven flame due to kiln outlet eddy (high turbulence of section air)
worse fuel ignition
risk of ring formation at kiln outlet or snowman in cooler
Axial burner position in rotary kiln
Especially for rotary kiln with grate cooler a proper axial position of the burner is
very important
20 cm movement of the burner moves the sinter zone up to 1m
Sometimes NOx – emissions depends on burner position drastically
The clinker mass composition as well clinker characteristics depend on length of
the cooling zone within the kiln, means also defined by burner axial position. We
recommend keeping 1200-1250°C clinker temperature at the kiln edge.
ELECTROSTATIC PRECIPITATORS
An electrostatic precipitator (ESP) is a particle control device that uses electrical forces to
move the particles out of the flowing gas stream and onto collector plates. The particles
are given an electrical charge by forcing them to pass through a corona, a region in
which gaseous ions flow. The electrical field that forces the charged particles to the walls
comes from electrodes maintained at high voltage in the center of the flow lane.
Once the particles are collected on the plates, they must be removed from the plates
without re-entraining them into the gas stream. This is usually accomplished by knocking
them loose from the plates, allowing the collected layer of particles to slide down into a
hopper from which they are evacuated. They can collect particles sized 0.1 to 10 microns
very efficiently. They are generally more efficient at collecting fine particles than
scrubbers or cyclones.
Electrostatic precipitators take advantage of the electrical principle that opposite charges
attract each other. A high voltage electrode negatively charges airborne particles in the
exhaust stream. As the exhaust gas passes through this electrified field, the particles are
charged. Typically 20,000 to 70,000 volts are used. A large, grounded flat metal surface
acts as a collection electrode. Microscopic particles are attracted to this surface where
they build-up to form a dust cake. Periodically, a rapper strikes the plate to knock the
dust cake into a collection hopper.
Particle Charging
Our typical ESP has thin wires called discharge electrodes, which are evenly spaced
between large plates called collection electrodes, which are grounded. Think of an
electrode as something that can conduct or transmit electricity. A negative high-voltage,
pulsating, direct current is applied to the discharge electrode creating a negative electric
field. You can mentally divide this field into three regions. The field is strongest right next
to the discharge electrode, weaker in the areas between the discharge and collection
electrodes called the inter-electrode region, and weakest near the collection electrode.
The region around the discharge electrode is where the particle charging process begins.
Corona Discharge: Free Electron Generation
Several things happen very rapidly (in a matter of a millisecond) in the small area around
the discharge electrode. The applied voltage is increased until it produces a corona
discharge, which can be seen as a luminous blue glow around the discharge electrode.
The free electrons created by the corona are rapidly fleeing the negative electric field,
which repulses them. They move faster and faster away from the discharge electrode.
This acceleration causes them to literally crash into gas molecules, bumping off electrons
in the molecules. As a result of losing an electron (which is negative), the gas molecules
become positively charged, that is, they become positive ions. So, this is the first thing
that happens—gas molecules are ionized
and electrons are liberated. All this activity occurs very close to the discharge electrode.
This process continues, creating more and more free electrons and more positive ions.
The name for all this electron generation activity is avalanche multiplication
The electrons bump into gas molecules and create additional ionized molecules. The
positive ions, on the other hand, are drawn back toward the negative discharge
electrode. The molecules are hundreds of times bigger than the tiny electrons and move
slowly, but they do pick up speed. In fact, many of them collide right into the metal
discharge electrode or the gas space around the wire causing additional electrons to be
knocked off. This is called secondary emission. So, this is the second thing that happens.
We still have positive ions and a large amount of free electrons.
Charging of Particles
These negative gas ions play a key role in capturing dust particles. Before the dust
particles can be captured, they must first acquire a negative charge. This is when and
where it happens. The particles are traveling along in the gas stream and encounter
negative ions moving across their path. Actually, what really happens is that the particles
get in the way of the negatively charged gas ions. The gas ions stick to the particles,
imparting a negative charge to them. At first the charge is fairly insignificant as most
particles are huge compared to a gas molecule. But many gas ions can fit on a particle,
and they do. Small particles (less than 1 µm diameter) can absorb “tens” of ions. Large
particles (greater than 10 µm) can absorb “tens of thousands” of ions. Eventually, there
are so many ions stuck to the particles, the particles emit their own negative electrical
field. When this happens, the negative field around the particle repulses the negative gas
ions and no additional ions are acquired.
This is called the saturation charge. Now the negatively-charged particles are feeling
the inescapable pull of electrostatic attraction. Bigger particles have a higher saturation
charge (more molecules fit) and consequently are pulled more strongly to the collection
plate. In other words, they move faster than smaller particles.
Particle Charging Mechanisms
Particles are charged by negative gas ions moving toward the collection plate by one of
these two mechanisms: field charging or diffusion charging. In field charging (the
mechanism described above), particles capture negatively charged gas ions as the ions
move toward the grounded collection plate. Diffusion charging, as its name implies,
depends on the random motion of the gas ions to charge particles.
In field charging as particles enter the electric field, they cause a local dislocation of the
field. Negative gas ions traveling along the electric field lines collide with the suspended
particles and impart a charge to them. The ions will continue to bombard a particle until
the charge on that particle is sufficient to divert the electric lines away from it. This
prevents new ions from colliding with the charged dust particle. When a particle no
longer receives an ion charge, it is said to be saturated. Saturated charged particles then
migrate to the collection electrode and are collected.
Diffusion charging is associated with the random Brownian motion of the negative
gas ions. The random motion is related to the velocity of the gas ions due to thermal
effects: the higher the temperature, the more movement. Negative gas ions collide
with the particles because of their random thermal motion and impart a charge on the
particles. Because the particles are very small (submicrometer), they do not cause the
electric field to be dislocated, as in field charging. Thus, diffusion charging is the only
mechanism by which these very small particles become charged. The charged particles
then migrate to the collection electrode.
Particle Collection
When a charged particle reaches the grounded collection electrode, the charge on the
particle is only partially discharged. The charge is slowly leaked to the grounded
collection
plate. A portion of the charge is retained and contributes to the inter-molecular adhesive
and cohesive forces that hold the particles onto the plates. Adhesive forces
cause the particles to physically hold on to each other because of their dissimilar
surfaces.
Newly arrived particles are held to the collected particles by cohesive forces; particles are
attracted and held to each other molecularly. The dust layer is allowed to build up on the
plate to a desired thickness and then the particle removal cycle is initiated.
Particle Removal
Dust that has accumulated to a certain thickness on the collection electrode is removed
by
one of two processes, depending on the type of collection electrode. Collection
electrodes in precipitators can be either plates or tubes, with plates being more
common. Plates can be cleaned either by water sprays or a process called rapping.
Rapping is a process whereby deposited, dry particles are dislodged from the collection
plates by sending mechanical impulses, or vibrations, to the plates. Precipitator plates
are
rapped periodically while maintaining the continuous flue-gas cleaning process. In other
words, the plates are rapped while the ESP is on-line; the gas flow continues through the
precipitator and the applied voltage remains constant. Plates are rapped when the
accumulated dust layer is relatively thick (0.08 to 1.27 cm or 0.03 to 0.5 in.). This allows
the dust layer to fall off the plates as large aggregate sheets and helps eliminate dust re-
entrainment.
Dislodged dust falls from the plates into the hopper. The hopper is a single collection
bin
with sides sloping approximately 50 to 70° to allow dust to flow freely from the top of
the
hopper to the discharge opening. Dust should be removed as soon as possible to avoid
(dust) packing. Packed dust is very difficult to remove. Most hoppers are emptied by
some
type of discharge device and then transported by a conveyor.
Figure.19. Electrostatic precipitator (ESP)
Material transporting system
There are at least six means of material transporting system from section to section
in DMC, such as
1. Deep Drawn pan conveyor
2. Belt conveyor
3. Bucket elevator
4. Drag chain
5. Air slide
6. Screw conveyor
DEEP DRAWN PAN CONVEYOR WITH BUCKET ELAVETYOR
For clinker handling the Pan Conveyor type suits conveying routes with an inclination up
to 30°.
This Pan Conveyor type is the ideal direct connection between cooler and clinker stock
especially for applications with eta coolers. The design allows the Pan Conveyor to be
arranged underneath the whole cooler length and to collect the fines from the dust
collecting hoppers same as the clinker from the crusher.
The cold clinker are output from the eta cooler, then transported by deep pan conveyor
and stored in clinker silo.
Features
Accepts temperatures to 700°C
Designed as a modular structure with standard components
Profiled pans for high rigidity
Minimum spillage
Highly wear resistant chains with high yield strength
High quality standards on all components
Benefits
Efficient and reliable operation
Reduced installation time
Low operating costs
Minimum and easy maintenance
Low power consumption
Low overall investment cost
Outstanding service life
The characteristic profile of the pans with their contact-free overlapping offers high
rigidity with large pan widths and a closed surface in the return stations. Stiffeners
pressed into the side plates combined with a sealing edge of special design provide the
tight fitting to avoid spillage. The coupling between motor and gear box can be
hydraulic or flexible for soft start-up. Frequency converters adapt the conveying speed to
the actual conveying capacity
Belt Conveyor
The main material transporting system consists of belt conveyor. The belt conveyor
transporting system includes:-
Raw material like limestone, gypsum and sand are conveyed from the place they are
naturally found to the main plant where their storage place is located,
The material design that includes strength and temperature resistance of the belt
depending on the line where the belts are arranged .For instance if the conveyor belt is
supposed to cover a long distance or to transport material against gravity, the tension
that develops on the belt will be high. Hence the designer of the belt should give
emphasis to strength. Whereas the belt is
Going to transport clinker needs to have high temperature resistance. Hence the
selection for the production of such type of belt must take the thermal property of the
material in to consideration.
The capacity of belt, this is directly related to the width of the belt i.e. how much amount
of material it transports per unit speed and time .in the DMC transport systems, cross
country belt conveyor, 1000ton/hr. transported from quarry to receiving silo.
Bucket elevator
Bucket elevator is one of the popular means transporting system in DMC cement
factory. Wherever there is certain inconvenience for belt conveyors, it is worth going for
bucket elevator. The fast-running bucket elevators can handle can withstand
temperatures up to 350oC
There are three bucket elevator transported from cement mill to air slid
Three bucket elevator transported from air slid to cement silo
There are six bucket elevators transported from air slid to packer machine. And
also
From drag chain output and air slide output to raw meal silo
From cement air slide output to cement silo are accompanied by bucket elevator
From homogenizing silo to preheater
Therefore, it is better to use the technology of bucket elevator. The drive mechanism
looks almost the same as that of belt conveyors. The flow of material from this, it is
possible to see that bucket elevators are intended to do their task as per the reason of
selection mentioned earlier. Parts of belt bucket elevator
Belt
Belt clamping connection
Bucket
Drum disc
Air slide
As the name itself indicates air slide transporting system uses air blown by blower fans
just below a material holding industrial cloth which is known as martin cloth. As the air
vibrates the martin cloth due to the slope of the air materials including raw meal and
cement it is used to convey fine materials by small ID fan under it
From raw meal cyclone output to raw meal bucket elevator
From cement meal cyclone output cement meal bucket elevator
There are six air slid transported from cement silo to cement bucket elevator.
Screw conveyor
Screw conveyors are used for horizontal, inclined, or vertical transport of bulk and
granulated materials. Screw Conveyors are designed for inclined transport (up to 8o’) of
material with temperatures below 300oC this type of conveying mechanism is selected
specially for material which appears to be semi-wet. Usually materials extracted from
deducting process are transported with the help of screw conveyors. This system
transports materials there are six screw conveyors transport materials
From cement bag filter outlet and cyclone to cement bucket elevator.
The output product from the grate cooler is stored in clinker silo before it is fed to the
cement mill for conversion to cement. This storage is called clinker storage. The storage
may be of silo type. Silo type clinker storage has the advantage that there is no dust
pollution and spillage of clinker. The capacity of silo may vary from factory to factory. In
DMC factory the capacity is 47500ton. Clinker will be discharged from the silo and
transported to belt conveyor by deep pan conveyor and clinker bin in cement grinding
plant by belt conveyer
Ball Mill
Vertical Roller Mill
Roller Press
Horizontal Mill
The basic role of a cement mill is to grind the clinker produced in the cement kiln into a
fine powder. This increases the surface area of the cement and the rate of reaction when
the cement is mixed with water.
The clinker will be extracted from the clinker silo or storage and conveyed to the cement
mill by belt conveyor. Clinker will age and lose some of its hydraulic potential in storage.
The cement mill operator may well need to extract clinker from different points in the
clinker silo to ensure this turn-over of the clinker stock. Perhaps some off-specification,
or outside stored clinker must be blended back into the cement with the clinker.
Controlling the rate of that blending of different clinkers will be an important task for the
cement mill operator.
Dependent on the type of cement being produced other ingredients of the recipe will
need to be loaded into the cement mill feed bins Ingredients such as pumice, gypsum
and high grade lime stone 3-4% without change physical and chemical the clinker.
Different materials and differently stored clinkers have different “grind abilities”, meaning
that some materials are harder to grind than others. Difficulty of grinding rises from
gypsum<limestone<clinker When materials of different grind ability are being ground
together then the softer material will be preferentially ground and concentrate in the
finer fractions, while the harder material will concentrate in the coarser particles. As it is
the clinker that mainly gives the strength development of the cement then it is the
surface area of the clinker that is important.
This is why control should be residue as this ensures that the clinker particles are ground
sufficiently fine, irrespective of the surface area which will derive from the preferentially
ground limestone and gypsum. The problem of different grind abilities and preferential
grinding of the softer materials is the reason why separate grinding and then blending of
the finely ground materials is sometimes the strategy. In that way the fineness of the
individual components of the recipe can be controlled with more consistent strength
development of the cement. For the cement mill operator attaining these fineness
targets is achieved by adjustment of the feed rate to the mill and the separator speed in
closed circuit cement mills. Just as in raw grinding the finer the cement must be ground
the lower the feed rate to the mill must be to reach that fineness. The mill motor
continues to draw virtually the same amount of electricity so the unit electricity
consumption in kWh/t rises with increasing fineness of grinding. However, cements are
ground much more finely that kiln feed, and clinker is harder to grind than limestone.
The unit electricity consumption for cement grinding is therefore much higher than for
raw grinding. The majority of cement around the world continues to be ground on
closed circuit ball mills. For cement grinding roll presses are sometimes employed as pre
grinders pressing the clinker feed to the mill into slabs which are then finish ground in a
single chamber ball mill. These combined roll press and ball mill circuits can have
different configurations of separators in circuit with the roll press, ball mill or both
dependent on the fineness of the cement being ground.
These combined roll press and finish ball mill circuits are most efficient with the ball mill
having only one chamber and being charged with fine media for the finish grinding of
the pressed slabs of clinker from the press. However, if the ball mill is set up in this way
then it cannot operate without the roll press pre-grinding the clinker as there is no
coarse media in the ball mill to initially crush the clinker.
The feed rate to a cement mill and the separator speed will be adjusted in response to
quality control testing of the surface area or residue of the cement being ground.
However, changing grind ability of the clinker or other components of the recipe can
lead to changes in the residence time of the material in the mill. With a ball mill this is
monitored via the small variations in the power drawn by the mill main motor, the sound
of the balls striking the liner plates of the mill as the mill turns, the power drawn by the
elevator to the separator, and the
Weight of rejects from the separator, PID loops controlling the feed rate to the mill in
response to variations in mill motor kW, the sound detected by an electronic ear or the
kW drawn by the elevator have been successfully employed on some cement factories.
Sometimes the “total feed” to the mill is controlled by varying the fresh feed rate to the
mill in response to variation in the weight of rejects being sent back to the mill by the
separator.
If the material becomes easier to grind then the amount of material being recirculates
from the separator to the grinding table will reduce and the pressure drop across the
mill will fall. The PID loop then increases the fresh feed rate to the mill to bring the
pressure drop across the mill back to target. Recipe control and fineness control via
adjustments in the feed rate to the mill and separator speed are the main jobs of the
cement mill operator. Temperature control is also important to dry any wet components
of the recipe and to dehydrate the gypsum in the mill.
In addition to effective length of mill shells are the first chamber is 4.215m and the
second chamber is 8.715m, its usage pulverizing cement by closed circuit pulverizing
method and production capacity are 3*120t/hr. cement fineness is 3200±100cm2/g. the
mills rotational speed is 14.9r/min, and maximum charging capacity of grinding media is
280ton, power of motor 4500kw.and also the bin feeder hopper capacity clinker hopper
capacity 890ton, pumice capacity 310ton and gypsum capacity 610ton.
First chamber
Second chamber
First chamber: the diameter of steel ball is 60-95mm
Plate used in the first chamber for rising material is raising plate
Unground material in the cement mill is transport by bucket elevator chain to separator,
which
The characteristic of these mills is that the size reduction is effected by rollers on
comparable grinding elements traveling over a circular bed of material. The material
after passing under the rollers is subjected to a preliminary classifying action by a stream
of air sweeping through the mill. The air at high velocity lifts the material to the classifier
which separates the coarse and fine particles. The fine particles are entrained and the
separated coarse particles fall back to the table. The separator could be either static or
dynamic. The fine particles are collected later in a cyclone.
Structure of mill
Mill is mainly composed of
Feeding device
Slipper bearing
Rotary part
Discharging device
Slipper bearing’s lubricating device and so on.
Feeding device
Materials are directly fed into mill through feeding device. Feeding device
is composed of feed pipe, air-inlet pipe and support frame. In the end of
air-inlet pipe, there sets an adjustable valve and adjusting shims used between feeding
and air-inlet pipe and supporting frame to adjust the center mark of feeding device if
necessary.
Slipper bearing
There is a mobile sliding bearing at the side of inlet; a one end fixed sliding bearing at
the discharging side. The two support bushes of the sliding bearing support the slip
ring at the direction of 30o to upright direction. There is a suit of concavo-convex sphere
under each support bush. The structure of concavo-convex sphere can make the mill
automatic control its position when the mill is running. The supporting bush is supported
by supporting roller through sphere. When the shell expands with heat and contract with
cold, the supporting bush can move with rotary device at axial direction. On the
discharge end, the supporting bush nearly upside of the slip ring is fixed on the
supporting frame. So the sliding bearing on the driving side can be fixed. This
supporting structure ensures the bush and the slip ring’s well contact.
The bush is cast with white metal in it. In order to form oil wedge, the inner diameter of
bush shall be bigger than the outside diameter of sliding ring. The roughness of the
bush is high. There is oil box on the bush to make the high-pressure oil enter into the
bush and sliding ring. There is a suit of lubrication system for each bush of sliding
bearing. The high-pressure lubrication system is used for supplying of oil for bush and
sliding ring when the mill’s start, stop and repair. That is to say, by the way of static
pressure, a layer of oil slick should be formed respectively between bush and sliding ring.
Low pressure lubrication system is that recycled oil is delivered to two oil plate by low
pressure pump .One is under the sliding ring ,the other is in front of one bush (in front of
the direction of rotation) .The sliding ring can be immersed into the oil plate . Oil can be
taken between the sliding ring and bush when the mill is running, that is dynamic
pressure lubrication. In order to prevent the temperature of the bush become too high
and ensure the mill work well, the bush shall be cooled by water. The entrance of the
water is on the bottom of the bush. Through pipe and soft pipe joint, water is discharged
to a water tank, which is out of the bearing cover. The cover of the sliding bearing is
welded with plates; also there are inspection holes, which are for daily operation,
maintenance and examination.
There are rubber and sealing gum between sliding bearing cover and seat. Seal it well
when the mill run to prevent leak
Rotary part
Rotary part consists of separate plate, discharge grate, shell and liners. The shell is weld
by 60mm roll steel plate; the sliding ring and the shell are welded together on inlet and
outlet ends. The separate plate is composed of liner, supporting plate, central plate and
grate. The outlet grate is composed of grate and supporting plate. The first barn is the
wave liner and the second barn is double wave liner. The separate plate, outlet grate, end
liners at inlet side
Discharge device
The discharge device is a steel cover. There is a screen in it, which is rotating with the
shell together and let the steel rubbish out. There is a wind exclude mouth up of the
discharge device and a material discharge mouth below it.
Ball Charging
Designed in modular sections comprising storage hopper, kibble chute and either slot
or star feeder means all duties can be accommodated.
Tones of grinding media, normally in the form of steel balls, are consumed by all process
plants having mills as part of their comminution process. The handling of heavy steel
balls can be a safety issue when drums of balls are hoisted and tipped, often manually,
into chutes and mils inlets. a range of systems available to safely store and feed balls
from simple kibbles through to complex handling systems comprising of storage
hoppers connected to ball feeders of the cassette or ‘star feeder’ type. These devices can
feed directly into mill feed chutes or conveyors which are often the most cost effective
solution. For larger plants we incorporate side wall ‘pocket belt’ conveyors to elevate the
balls within the plant and then transfer to flat belt conveyors incorporating multiple mill
feed stations in the form of pneumatic ploughs and gates to feed multiple mills on
demand.
To control the setting of the cement there will be target for cement SO3 content that will
be set by the chemist. The amount of gypsum ground with the clinker and other
components of the cement will be rationed to the total feed to the cement mill to give a
constant percentage gypsum addition. Gypsum is calcium sulphate with two molecules
of water of crystallization, (CaSO4.2H2O,) and therefore a constant percentage gypsum
addition will mean a constant SO3 addition to the cement. The chemist will set the target
for cement SO3 content based on the physical Testing results of the cement when it is
made into a standard mortar. That target will depend on the typical temperatures
experienced and residence time that the cement and gypsum spend in the cement mill.
Ball mills for cement grinding are very in efficient Machines and >90% of the electrical
energy input from the mill motor is converted into heat as the mill is turned and the
media in the mill tumbles and impacts on one-another and the lining plates of the
cement mill.
If the clinker that is being ground is fresh from the kiln then it is likely to be at a
temperature of 80°C, or higher. The combination of these two heat energy inputs
operating a Cement Factory Cement Mill Temperature Control means that temperatures
in ball mills for cement grinding can rise to well above 100°C. At these temperatures the
gypsum is not stable and progressively loses water of crystallization to first form
hemihydrate, then soluble anhydrite and eventually natural anhydrite. These different
mineral forms of calcium sulphate dissolve in the mixing water at different rates when
the cement is mixed with water to make Mortar or concrete.
For cement setting control it is important that the amount of sulphate dissolving in the
mixing water is matched with the reactivity of the cement clinker and particularly the
C3A in the cement clinker. The chemist will set the cement SO3 target based on the
typical mineral form of the calcium sulphate after it has been ground in the cement mill.
It is therefore important that the temperature to which the gypsum is raised and the
time spent at that temperature is consistent as this will lead to the gypsum always being
in the same mineral form and having the same solubility.
This is why temperature control in cement mills is important. With ball mills for cement
grinding the requirement is normally to cool the cement mill to control the temperature
and the gypsum dehydration. Ambient air is drawn into and through the mill by an
induced draft fan (id fan) to cool the mill. The pressure drop across the mill is monitored
to control the volume of air being drawn through the mill. However, the amount of air
that can be drawn through the mill is limited as the velocity of that air should not exceed
2.5m/s. If a greater volume is drawn through the mill then the velocity rises and coarse
material is pulled out of the mill with the air stream before it has been sufficiently
ground. This limitation on the velocity of the air sweeping the mill means that if the
diameter of the ball mill is more than ~3.5m then not enough air can be drawn through
the mill to adequately cool the mill and control the temperature.
Additional cooling by means of water injection sprays into the mill has to be introduced.
The normal arrangement is for the mill exit air temperature to be monitored and
controlled to a target of 110~115°C by varying the amount of water that is sprayed into
the mill. In large mills water might be sprayed first into the outlet chamber of the mill up
a maximum amount and then also into the inlet of the mill if the temperature cannot be
controlled by the outlet chamber water injection. The injected water must be vaporized
as it is sprayed into the mill and cools the mill by Operating a Cement Factory. Cement
Mill Temperature Control evaporative cooling. The heat energy in the mill is absorbed to
evaporate the water. To ensure that the water is vaporized the water is injected at high
pressure or with compressed air through atomization nozzles. These arrangements have
worked well for many years with ball mills for cement finish grinding. Provided that the
temperature control in the mill and the residence time of the gypsum in the mill is
constant then the gypsum mineral form and solubility is controlled and the setting of the
cement controlled. Residence times in ball mills for cement grinding are typically 20
minutes or more
Sandstone……..6000tons
Basalt……….12000tons
Pumice…….24000tons
Gypsum………..6000tons
Gypsum
It consist of sand, calcareous sand and limestone. It used for setting, but also other of
limestone, gypsum influences not only the setting, but also other cement properties
such as grind ability sensitivity to storage volume stability and strength, So3 contents
3% or more are required for using gypsum as setting time controller by inter grinding
with clinker
Pumice
To increase the quantity of cement, too finer; by decreasing the strength and also
decrease the cost
Girth gear
Support
Gearbox
Motor
Pulse jet bag filter
33 OPC
43 OPC
MHPC,WC
SSC Clinker + GBFS (70%) + CaSO4 Acid resistant, Lin seed oil resists and
sea water resistant
OWC Reduced C3A clinker and Used in high pressure and high
coarse grinding temperature in sealing water and gas
pockets
WC Clinker with Fe2O3<1% and C3A Architectural purpose and pastel finish
(15-18%)
Masonry cement Clinker +Pozzolana materials + Slow hardening, high workability and
Gypsum + air entraining high water retentivity
plasticizer Used for masonry mortals for brick,
stone and plastering
Depend on addition of pumice DMC cement factory produce two types of cement
It has high quality used for constriction industry such as bridge, dams etc.
Pozzolana Portland cement (with pumice)
It has relatively low quality used for ground house. Additive pumice and gypsum to
clinker results is called PPC. This type of cement has low strength relative to OPC and it is
the usual Dmc product. A pozzolanic material is essentially a siliceous or aluminous
material which while in itself possessing no cementitious properties, which will, in finely
divided form and in the presence of water, react with calcium hydroxide, liberated in the
hydration process, at ordinary temperature, to form compounds possessing cementitious
properties. The pozzolanic materials generally used for manufacture of PPC are calcined
sandstone or basalt. The pozzolanic action is shown below:
Portland Pozzolana cement produces less heat of hydration and offers greater resistance
to the attack of aggressive waters than ordinary Portland cement. Moreover, it reduces
the leaching of calcium hydroxide when used in hydraulic structures. It is particularly
useful in marine and hydraulic construction and other mass concrete constructions. Uses:
Clinker 67%
Pumice 28%
PPC Gypsum 5%
Due to conformity to the cement and raw mill quality requirement should be verified
and monitored by quality control.
for cement mill by:-
setting time depend on additive of gypsum
by test soundness
by the composition required to ensure high sulphate resistance
by test compressive strength and flexure
by insoluble residue and content of sulphate(SO3)
SETTING TIME
Setting refers to a change from a fluid to a rigid stage Cement paste setting time is
affected by a number of items including: cement fineness, water-cement ratio, chemical
content (especially gypsum content) and admixtures. Setting tests are used to
characterize how a particular cement paste sets. For construction purposes, the initial set
must not be too soon and the final set must not be too late.
Cement + water → cement paste → lose its plasticity gradually→ when it lose its
plasticity completely → setting occurs. There are four main stages during setting time
First stage
Takes only few minutes after the addition of water to the cement
The rate of heat generation is high, due to wetting of cement particles with water,
and the beginning of hydrolysis and reaction of the cement compounds. After
that the rate decreases to relatively low value.
Second stage (dormant period)
Takes 1-4 hours with relatively low speed
The initial layer of the hydration begins slowly to build on the cement particles.
Bleeding and sedimentation appears at this period.
Third stage
Heat of hydration begins to rise again due to the dissolution of the weak gel layer
formed in the beginning (first) on the surface of C3S crystals – so the water able
to surround the particles surfaces again – and forming gel of calcium silicates with
enough amount to increase setting.
The activity reach its peak after about 6 hours for cement paste, with standard
consistency, and might be late for paste with higher w/c ratio.
At the end of the stage, the paste reaches the final setting stage.
Fourth stage
Hardening and gain of strength
Vicat apparatus
Use to measure the setting time for cement paste.
Initial setting time – refers to the beginning of the cement paste setting.
Final setting time – refers to the beginning of hardening and gain of strength.
Iraqi Standard Specification No. 5 limits:
Initial setting time not less than 45 minutes
Final setting time not more than 10 hours
Factors affecting the setting time
Water/cement (w/c) ratio – The setting time of cement increase with the increase
of w/c ratio.
Temperature and relative humidity – The setting time of cement decreases with a
rise in temperature and decrease of relative humidity.
Fineness of cement – The setting time of cement decreases with a rise in fineness
of cement.
Chemical composition
Flash setting- It is abnormal premature stiffening of cement within a few minutes of
mixing with water – It differs from flash set in that:
No appreciable heat is evolved.
Remixing the cement paste without addition of water restores plasticity of the
paste until it sets in the normal manner and without a loss of strength.
Occurs when there is no gypsum added or exhausting the gypsum (added with little
amount). So C3A reacts with water causing liberation high amount of heat causing rapid
setting of cement, and leading to form porous microstructure that the product of
hydration of the other compounds precipitate through unlike the normal (ordinary)
setting that have much lower porosity microstructure.
Fineness of cement
Fineness or particle size of Portland cement affects Hydration rate and thus the rate of
strength gain. The smaller the particle size, the greater the surface area-to-volume ratio,
and thus, the more area available for water-cement interaction per unit volume the
effects of greater fineness on strength are
Generally seen during the first seven days when the cement particles are coarser,
hydration starts on the surface of the particles. So the coarser particles may not be
completely hydrated. This causes low strength and low durability. For a rapid
development of strength a high fineness is necessary. The last steps in the manufacture
of cement are the grinding of clinker mixed with gypsum.
It reduce the water layer separate one the mixture surface due to bleeding On the other
hand the fineness of cement has disadvantages:
Sieve Method
It is the classical method to measure the cement fineness, in which the residue percent of
cement on sieve No.170 (90 µm) according to BS (British Standard) shall not exceed 10%
for ordinary Portland cement. According to American Standards ASTM the residue
percentage on sieve No.200 (74µm) shall not exceed 22%
Blaine Method
The Blaine air-permeability method is the most commonly used method. In the Blaine
air- permeability method, given volume of air is passed through a prepared sample of
definite density. The number and size of the pores in a sample of given density is a
function of the particles and their size distribution and determines the rate of air flow
through the sample.
By determination of specific surface (total surface area of all the particles in one gram of
cement by air-permeability apparatus).cm2/gm. or m2/kg, the quality of cement is
measured by the surface area or the Blaine index. The unit of the Blaine index is m2/kg,
and this index is determined by the Blaine air permeability test. The surface area of the
cement powder depends on size distribution of cement particles; smaller particles have
larger surface area The cement clinker grinding circuit reduces the feed from 80%
passing size between 10 and 20 mm to 100% passing 90 microns. The size reduction
takes place in a two compartment tube mill; the first compartment of the mill is shorter
than the second Compartment. The coarse clinker is ground in the first compartment
where larger balls (80, 60, 50 mm) are used and the fine grinding is done in the second
compartment where smaller balls (below 25 mm) are used.
A diaphragm separates the two compartments and allows only particles below a certain
size to pass to the second compartment. Ground material exits the mill through the
discharge grate which prevents grinding balls from leaving the mill. A proportion of
material, mostly fines, is “air-swept” out of the mill. The final product is the fine fraction
of the air classifier and the coarse fraction returns to the mill.
K=factor in (g/cm3.s)
t=in second
K=37.88
t=2.28min=2min+28second=120second+28second=148second
Blaine Area =K t
=39.25
=477.49686cm2/g
Blaine for OPC, 3500 with filler and 3300 without filler
Pumice 800
Soundness test
The testing of soundness of cement to ensure that the cement does not show any
appreciable subsequent expansion is of prime importance which could result in a
disruption of the hardened cement paste (namely the cement paste, once it has set, does
not undergo a large change in volume).
Cement strength
Whatever type of cement is being produced it will be being produced to a strength
specification, for PPC 32.5, and for 42.5. This strength specification is the strength which
a standard mortar made with the cement will attain 28 days after the cement is mixed
with sand and water to produce the mortar. Different recipes will allow these strengths
to be attained and the cement chemist will set the recipes. Attaining the strength with
the particular recipe is then a question of grinding the cement finely enough. Usually the
cement must be ground to a surface area target. With blended cements with multiple
components sieve residue targets are sometimes used in addition to, or instead of
surface area targets. This can also be best if outside stored clinker is being ground as pre
hydration of that clinker will create some “false surface” in the cement mill.
The compressive strength of hardened cement is the most important of all the properties
for structural use. The strength of mortar or concrete depends on the cohesion of the
cement paste, and its adhesion to the aggregate particles and to certain extends on the
strength of the aggregate itself. The last factor is not considered at this stage, and is
eliminated in tests on the quality of cement by the use of standard aggregates.
Strength tests are not made on a neat cement paste because of difficulties of molding
and testing with a consequent large variability of test results. Cement sand mortar and,
some cases, concrete of prescribed proportions and made with specific materials under
strictly controlled conditions, are used for the purpose of determining the strength of
cement. There are several forms of strength tests:
Direct compression
Direct tension
Flexure
Direct tension strength and flexure strength of concrete are generally of lesser interest
than compressive strength. Nowadays the compressive strength of cement that
considered being crucial.
Responsible for the grey color of OPC, White Portland cement is made from raw
materials containing little or no iron or manganese, the substances that give
conventional cement its gray color. So the secret of the White cement is raw material.
Apart from that only whitest chalk is used together with light colored sand in production
of white cement. White cement production needs usually 40% higher energy than the
normal grey cement and the difference between ordinary cement and while cements are
as follows: The amount of chromium, manganese, iron compounds is significantly less in
white cement in comparison to gray cement Production. White cement consumes
significantly more energy in comparison to gray cement Kindly note that the setting
behavior and strength development of white cement is almost equivalent to grey
cement. Further, Gypsum is used in the making of both white and ordinary grey cement.
Cement silo
Cement silos are used to store cement elevated by buckets elevator chain and pour in it.
There three cement silos used in DMC factory, each of them have 10000tons storing
capacity. Cement silos uses compressors and root blowers for: blending and aeration in
cement silo will be transported by bucket elevator and air slides by pneumatic conveyor.
Figure.27. cement silos
PACKING
The cement discharged from silo is transported to air slides and bucket elevator and
discharge into a screen which is located above the receiving hopper of the packing
machines to separate foreign matters. The cement is packed with the help of a rotary
packer and finally dispatched to the market
Packaging of cement
Cement extracted from the storage silos is fed to the packing machines from where
packing in sacks, bags and in bulk is done. The cement silos should have a blower
extraction system to reduce power consumption. Packing machines are of two types
such as stationary and rotary packer. The packing line of products in powder form is
equipped with different element or machine. Power consumption for packing system are
2-2.2KWh/t and capacity 100-120t/h.
The principal elements of the packing line are
Vibrating screen
Feed hopper
Rotary feeders
Discharging belt
Flow of material in the packing plant
The flow of material rises from the chain bucket elevator to reach the vibrating screen.
This vibrating screen is equipped with control systems (called sensor) placed inside the
hopper, then the flow of material passes through the rotary vane feeder equipped with
alternate gear to adjust the level of material in the packer machine. The flow of material
is then directed to the spouts.
Most parts of the packer in the bag, where as a very small of scraps, in form of dust and
overflows. The dust is sucked up and collected by means of a sucked chute in the lower
hopper and rejected by separator.
The dust is gathered by a screw conveyor and led back into the conveying cycle
position sensors
proximity sensors
level sensors and
Weight sensors are found to be work together to put out the final products.
BULK LOADING
Cement is shipped through bulk (powder form) directly from the silos, by marine these
are least expensive and easiest form of transport, & 80% of cement is shipped by this
method. Bulk is shipped to terminals for an on ward distribution to the customer
The factory use modernized dust recycle device which reduce environmental pollution.
Totally cement production of Derba cement factory start from quarry to cement packing
plant. The cement production capacity of Derba cement factory is 7000tons/day