Allen Jee Mains Che April-2024

FINAL JEE–MAIN EXAMINATION – APRIL, 2024
(Held On Thursday 04th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON
CHEMISTRY TEST PAPER WITH SOLUTION

SECTION-A 63. Match List -I with List II:
61. What pressure (bar) of H2 would be required to
List - I List - II
make emf of hydrogen electrode zero in pure water
Mechanism steps Effect
at 25ºC ?
 +
(1) 10–14 (2) 10–7 (3) 1 (4) 0.5 NH2 NH2
 (I) – E effect
Allen Ans. (1) 
(A)
NTA Ans. (3)
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Sol. 2e– + 2H+(aq)  H2(g) H
(II) – R effect
0.059 PH
(B) +H+
E  Eo  log 2 2 +
n [H ]
0.059 PH –
00 log 72 2 + CN
2 (10 ) (C) (III) + E effect
CN
PH2
log 0  
(107 ) 2 
 O
ON=O –  
N O
(D) (IV) + R effect
PH2 +
1
1014
PH2  1014 bar

Choose the correct answer from the options given
62. The correct sequence of ligands in the order of
below :
decreasing field strength is :
(1) (A) – (IV), (B) – (III), (C) – (I), (D) – (II)
(1) CO  H 2 O  F   S2 
(2) (A) – (III), (B) – (I), (C) – (II), (D) – (IV)
  
(2) OH  F  NH 3  CN
(3) (A) – (II), (B) – (IV), (C) – (III), (D) – (I)
– 4– –
(3) NCS > EDTA > CN > CO
(4) (A) – (I), (B) – (II), (C) – (IV), (D) – (III)
(4) S2– > –OH > EDTA4– > CO
Ans. (1)
Ans. (1)
Sol. According to spectrochemical series ligand field
strength is CO > H2O > F– > S2–
1
.. +
Sol. NH2 CH2Br NaOH(alc)
NH2 HBr
 66. B C
.. Ether
+ R effect (NH2 electron Br
donating)
Identify B and C and how are A and C related ?
O O O O–
N N
(B) (C)
+ – R effect (NO2 electron
withdrawing) Br OH functional
(1) group
H
+
+E Effect H electron OH OH isomers
+ H+ deficient
+
species)
Br Derivative
Br

 –
+ CN – E Effect (CN electron (2)
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CN deficient OH OH
species)
64. What will be the decreasing order of basic strength Br position
of the following conjugate bases ?
 (3) isomers
OH, RO, CH 3COO, C l
Br
(1) C l > OH > R O > CH3CO O Br
(2) R O >–OH > CH3CO O > C l Br chain
(3) –OH > R O > CH3 CO O > C l
(4) isomers
(4) C l > R O > –OH > CH3CO O Br Br
Ans. (2)
Sol. Strong acid have weak conjugate base Ans. (3)
Acidic strength :
H–Cl > CH3COOH > H2O > R–OH Sol.
Conjugate base strength : H
Br
Cl– < CH3COO– < OH < RO–
65. In the precipitation of the iron group (III) in CH2 NaOH
qualitative analysis, ammonium chloride is added alc.
before adding ammonium hydroxide to : Br (E2) Br
(B)
(1) prevent interference by phosphate ions (A)
(2) decrease concentration of –OH ions HBr ether
(3) increase concentration of Cl– ions (Electrophilic
Addition
(4) increase concentration of NH4+ ions
Reaction)
Ans. (2)
Br
Sol. NH4OH NH4  OH
NH 4 Cl  NH 4  Cl

Due to common ion effect of NH 4 , B (C)
[OH–] decreases in such extent that only group-III r
cation can be precipitated , due to their very low
Ksp in the range of 10–38. A and C are position isomer.
2
67. One of the commonly used electrode is calomel 69. Which one of the following molecules has
electrode. Under which of the following categories maximum dipole moment ?
calomel electrode comes ? (1) NF3 (2) CH4
(1) Metal – Insoluble Salt – Anion electrodes
(3) NH3 (4) PF5
(2) Oxidation – Reduction electrodes
Ans. (3)
(3) Gas – Ion electrodes
Sol. CH4 & PF5 , µnet = 0 (non polar)
(4) Metal ion – Metal electrodes
Ans. (1) µNH3  µNF3
Vector addition of bond Vector subtraction of bond
Sol. Theory based moment & lone pair moment moment & lone pair moment
68. Number of complexes from the following with 70. Number of molecules/ions from the following in
even number of unpaired "d" electrons is____. which the central atom is involved in sp3
[V(H2O)6]3+, [Cr(H2O)6]2+, [Fe(H2O)6]3+, hybridization is ________.
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3+ 2+
[Ni(H2O)6] , [Cu(H2O)6]
NO3–, BCl3, ClO2–, ClO3
[Given atomic numbers : V = 23, Cr = 24, Fe = 26,
(1) 2 (2) 4
Ni = 28, Cu = 29]
(3) 3 (4) 1
(1) 2 (2) 4
Ans. (1)
(3) 5 (4) 1
Ans. (1) O– Cl
Cl B
Sol. [V(H2O)6]3+  d2sp3 Sol. O = N Cl Cl
O
3 2
23V :- [Ar]3d 4s
2 sp2 O O–
sp sp 3
V+3 :- [Ar]3d2 , n = 2 (even number of unpaired e–)

[Cr(H2O)6]2+  sp3d2
·
Cl
O O
5 1
24Cr :- [Ar]3d 4s
O
sp3
Cr+2 :- [Ar]3d4 , n = 4 (even number of unpaired e–)
eg 71. Which among the following is incorrect statement?
(1) Electromeric effect dominates over inductive
t2g
effect
[Fe(H2O)6]3+  sp3d2
(2) The electromeric effect is, temporary effect
Fe3+  [Ar]3d54s0
(3) The organic compound shows electromeric
n = 5 (odd number of unpaired e–)
effect in the presence of the reagent only
[Ni(H2O)6] 3+  sp3d2
(4) Hydrogen ion (H+) shows negative electromeric
Ni :- [Ar]3d84s2
effect
Ni+3 :- [Ar]3d7 , n = 3 (odd number of unpaired e–)
[Cu(H2O)6]2+  sp3d2 Ans. (4)
Cu :- [Ar]3d94s0 Sol. Hydrogen ion (H+) shows positive electromeric

n = 1 (odd number of unpaired e–) effect.
3
72. Given below are two statements : 74. Which of the following is the correct structure of
L-Glucose ?
Statement I : Acidity of -hydrogens of aldehydes CHO
CHO
and ketones is responsible for Aldol reaction. OH
HO
Statement II : Reaction between benzaldehyde OH HO
(1) HO (2)
OH
and ethanal will NOT give Cross – Aldol product. HO HO
In the light of above statements, choose the most CH2OH CH2OH
appropriate answer from the options given below. CHO CHO

(1) Both Statement I and Statement II are HO HO
HO HO
correct. (3) OH (4) HO
(2) Both Statement I and Statement II are OH HO
®
incorrect. CH2OH CH2OH
Ans. (1)
(3) Statement I is incorrect but Statement II is Sol. Structure of L-Glucose is
CHO
correct.
HO
(4) Statement I is correct but Statement II is
OH
incorrect. HO
HO
Ans. (4)
CH2OH
Sol. Aldehyde and ketones having acidic
75. The element which shows only one oxidation state
-hydrogen show aldol reaction other than its elemental form is :
(1) Cobalt (2) Scandium
O
(3) Titanium (4) Nickel
H–C=O H–C=CH–C–H Ans. (2)
O Sol. Co, Ti, Ni can show +2, +3 and +4 oxidation state,
+ CH3–C–H
Base But 'Sc' only shows +3 stable oxidation state.

(Acidic H) 76. Identify the product in the following reaction :
Benzaldehyde Ethanal Cross aldol product O
Zn – Hg
H Product
73. Which of the following nitrogen containing HCl
compound does not give Lassaigne’s test ?
O
(1) Phenyl hydrazine (2) Glycene OH
(1) (2)
(3) Urea (4) Hydrazine
Ans. (4) OH O
OH
Sol. Hydrazine (NH2–NH2) have no carbon so does not (3) (4)
show Lassaigne’s test.

O
Ans. (4)
4
O 80. The correct order of first ionization enthalpy
Sol.
values of the following elements is :
H (A) O (B) N
Zn –Hg (Clemmensen (C) Be (D) F
HCl reduction) (E) B
O below :
(1) B < D < C < E < A (2) E < C < A < B < D
77. Number of elements from the following that (3) C < E < A < B < D (4) A < B < D < C < E
CANNOT form compounds with valencies which Ans. (2)
match with their respective group valencies is Sol. Correct order of Ist IE
______. Li < B < Be < C < O < N < F < Ne
B, C, N, S, O, F, P, Al, Si     
E<C < A<B<D
(1) 7 (2) 5 (3) 6 (4) 3
Ans. (4) SECTION-B
Sol. N,O, F can’t extend their valencies upto their
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81. The enthalpy of formation of ethane (C2H6) from
group number due to the non-availability of vacant
2d like orbital. ethylene by addition of hydrogen where the bond-
78. The Molarity (M) of an aqueous solution energies of C – H, C – C, H – H are 414 kJ, 347 kJ,
containing 5.85 g of NaCl in 500 mL water is : 615 kJ and 435 kJ respectively is - __________ kJ.
(Given : Molar Mass Na : 23 and Cl : 35.5 gmol–1)
Ans. (125)
(1) 20 (2) 0.2
(3) 2 (4) 4 Sol. C2H4(g) + H2(g)  C2H6(g)
Ans. (2) H = BE(C = C) + 4BE (C – H) + BE (H – H)
n NaCl – BE(C – C) – 6BE (C – H)
Sol. M
Vsol (in L) H = BE(C = C) + BE(H – H) – BE(C – C)
5.85 – 2BE(C – H)
M  58.5  0.2M = 615 + 435 – 347 – 2 × 414
0.5 = – 125 kJ
79. Identify the correct set of reagents or reaction
82. The number of correct reaction(s) among the
conditions ‘X’ and ‘Y’ in the following set of
transformation. following is ________.
‘X’ ‘Y’ O
CH3 – CH2 – CH2 – Br Product CH3 – CH – CH3
C CH2
Cl Anhyd.AlCl3
Br (A) +
(1) X = conc.alc. NaOH, 80°C, Y = Br2/CHCl3

O
(2) X = dil.aq. NaOH, 20°C, Y = HBr/acetic acid
C COOH
(3) X = conc.alc. NaOH, 80°C, Y = HBr/acetic Cl H2
(B)
Pd – BaSO4
acid
CHO
(4) X = dil.aq. NaOH, 20°C, Y = Br2/CHCl3 (C)
CO, HCl
Anhyd.AlCl3/CuCl
Ans. (3)
X conc.alc.NaOH CONH2 NH2
Sol. CH3–CH2–CH2–Br  H3O+
o
80 C (D) 
Y  HBr /Acetic acid
CH3–CH=CH2  CH3–CHBr – CH3
Ans. (1)
5
Sol. 85. Only 2 mL of KMnO4 solution of unknown
O molarity is required to reach the end point of a
C CH2
(A) Cl Anhy. AlCl3
+ (Incorrect) titration of 20 mL of oxalic acid (2 M) in acidic
O medium. The molarity of KMnO4 solution should

C Cl H2 COOH
(B) Pd –BaSO4
(Incorrect) be ________ M.
CHO Allen Ans. (8)

CO, HCl
(C) Anhy. AlCl3 / CuCl (Correct) NTA Ans. (50)
CONH2 H3O+ NH2 Sol. eq.(KMnO4) = eq.(H2C2O4)

(D) (Incorrect)

M × 2 × 5 = 2 × 20 × 2
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83. X g of ethylamine is subjected to reaction with M = 8M
NaNO2/HCl followed by water; evolved dinitrogen
86. Consider the following reaction
gas which occupied 2.24 L volume at STP.
MnO2 + KOH + O2  A + H2O.
X is ______ × 10–1 g.
Ans. (45) Product ‘A’ in neutral or acidic medium
Sol. disproportionate to give products ‘B’ and ‘C’ along

NaNO  HCl HO
CH3CH 2 NH 2 
2
 
2
 CH3CH2–OH + N 2 with water. The sum of spin-only magnetic
Mol.wt.45g 14 g
moment values of B and C is __________ BM.

given : N2 evolved is 2.24 L i.e. 0.1 mole.
i.e. CH3CH2NH2 (ethyl amine) will be 4.5 g (nearest integer)
(=0.1 mole) (Given atomic number of Mn is 25)

Hence the answer = 45 × 10–1 g Ans. (4)
84. The de-Broglie’s wavelength of an electron in the
Sol. MnO2 + KOH + O2  K2MnO4 + H2O
4th orbit is _______ a0. (a0 = Bohr’s radius)
Ans. (8) (A)
Sol. 2rn = nd Neutral/acidic solution

K2MnO4   KMnO4 + MnO2
n2
2a 0  n d
Z Mn+4 :- [Ar]3d3
42
2a 0  4d n = 3,  = 3(3  2) = 3.87 B.M.
1
d  8a 0 Nearest integer is (4)
6
87. Consider the following transformation involving Sol. 2 = 0.52 × m
first order elementary reaction in each step at 2
m
constant temperature as shown below. 0.52
AB
Step 1
C 
Step 2
P According to question, solution is much diluted
Step 3
P n
Some details of the above reaction are listed so o  solute
P n solvent
below.
P m
Step Rate constant Activation o
  M solvent
–1 P 1000
(sec ) energy (kJ mol–1)
m
1 k1 300 P  P o   M solvent
1000
2 k2 200
2
3 k3 Ea3
If the overall rate constant of the above  760  0.52  18 = 52.615
1000
kk
transformation (k) is given as k  1 2 and the P5 = 760 – 52.615 = 707.385 mm of Hg
®
k3
89. The number of different chain isomers for C7H16 is
overall activation energy (Ea) is 400 kJ mol–1, then
__________.
the value of Ea3 is ______ kJ mol–1 (nearest
integer) Ans. (9)
Ans. (100) Sol. (i) (ii)
KK
Sol. K  1 2
K3
 E a1  Ea2 (iii) (iv)
 Ea RT RT
A1e A 2e
Ae RT
  E a3
A3 e RT (v) (vi)
 Ea  (Ea1  Ea 2  Ea3 )
A1A 2
Ae RT  e RT (vii) (viii)
A3
Ea  Ea1  Ea2  Ea3 (ix)
400 = 300 + 200 – Ea3
Ea3 = 100 kJ/mole 90. Number of molecules/species from the following
88. 2.5 g of a non-volatile, non-electrolyte is dissolved having one unpaired electron is ________.
in 100 g of water at 25°C. The solution showed a O2 ,O21 , NO, CN 1 , O22 
boiling point elevation by 2°C. Assuming the
solute concentration in negligible with respect to Ans. (2)
the solvent concentration, the vapour pressure of
Sol. According to M.O.T.
the resulting aqueous solution is _______ mm
of Hg (nearest integer) O2  no. of unpaired electrons = 2
[Given : Molal boiling point elevation constant of O2–  no. of unpaired electron = 1
water (Kb) = 0.52 K. kg mol–1, NO  no. of unpaired electron = 1
1 atm pressure = 760 mm of Hg, molar mass of
CN–  no. of unpaired electron = 0
water = 18 g mol–1]
Ans. (707) O22  no. of unpaired electron = 0
7
(Held On Thursday 04th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A Sol. Br Br Me2.NH
.
Br NMe
.. 2
61. The equilibrium constant for the reaction SN2
+
1 –H
SO3  g  SO 2  g   O 2  g 
2
.. ..
is KC = 4.9 × 10–2. The value of KC for the reaction NMe2 Me2NH 
Me
 N
given below is NMe2 SN2
Me
2SO2  g   O2  g  2SO3  g  is H
–H+
®
(1) 4.9 (2) 41.6
NMe2
(3) 49 (4) 416
Ans. (4) NMe2
 1  
2
1 
2
The above mechanism valid for both cis and trans
Sol. K 'C     2  isomers. So the products are same for both cis and
 KC   4.9 10 
trans isomers.
K'C = 416.49 63. When MnO2 and H2SO4 is added to a salt (A), the
62. Find out the major product formed from the greenish yellow gas liberated as salt (A) is :
(1) NaBr (2) CaI2
following reaction. [Me: –CH3] (3) KNO3 (4) NH4Cl
Br Br Ans. (4)

Sol. 2NH 4Cl  MnO2  2H 2SO4   MnSO 4
(NH 4 )2 SO4  2H 2O  Cl2 
greenish
NMe2 NMe2 yellow
solution
(1) 64. The correct statement/s about Hydrogen bonding
is/are :
NMe2 A. Hydrogen bonding exists when H is covalently
(2) bonded to the highly electro negative atom.
B. Intermolecular H bonding is present in o-nitro
NMe2 phenol
NMe2 C. Intramolecular H bonding is present in HF.
NMe2
(3) D. The magnitude of H bonding depends on the
physical state of the compound.
E. H-bonding has powerful effect on the structure
NMe2 and properties of compounds.
(4) Choose the correct answer from the options given
below :
NMe2 (1) A only (2) A, D, E only
Ans. (2) (3) A, B, D only (4) A, B, C only
Ans. (2)
1
Sol. (A) Generally hydrogen bonding exists when H is 67. CH3 – CH2 – CH2 – Br + NaOH 
2 5
 Product 'A'
C H OH
covalently bonded to the highly

H2O
electronegative atom like F, O, N. Product "B"
H+
(B) Intramolecular H bonding is present in Product A
O O Diborane
Product "C"
N H H2O/H 2O2/–OH
O
Consider the above reactions, identify product B
and product C.
(C) Intermolecular Hydrogen bonding is present (1) B = C = 2-Propanol

in HF (2) B = 2-Propanol C = 1-Propanol
(D) The magnitude has Hydrogen bonding in solid (3) B = 1-Propanol C = 2-Propanol
state is greater than liquid state. (4) B = C = 1-Propanol
®
(E) Hydrogen bonding has powerfull effect on the
Ans. (2)
structure & properties of compound like
OH
melting point, boiling point, density etc. Sol. H 2O
CH3–CH–CH3
H+
O–Na+ 2-Propanol
[B]
“A” “B” C2H5OH
65. O O CH3–CH2–CH2–Br + NaOH CH3–CH=CH2
O Product
O
H H [A]
B2H6
H2O/H2O2/OH
CH3–CH2–CH2–OH
In the above chemical reaction sequence “A’’ 1-Propanol
and “B” respectively are : [C]
(1) O3, Zn/H2O and NaOH(alc.) / I2 68. The adsorbent used in adsorption chromatography
(2) H2O, H+ and NaOH(alc.) / I2 is/are
(3) H2O, H+ and KMnO4 A. silica gel B. alumina
(4) O3, Zn/H2O and KMnO4
C. quick lime D. magnesia
Ans. (1)
 Choose the most appropriate answer from the
“B” ONa
“A” options given below :
O3 , NaOH
Sol. O O (1) B only (2) C and D only
ZnH2O O (alc.)
I 2
O + CHI3
(3) A and B only (4) A only
H H
Ans. (3)
66. Common name of Benzene-1, 2-diol is
Sol. The most common polar and acidic support used is
(1) quinol (2) resorcinol
(3) catechol (4) o-cresol adsorption chromatography is silica. The surface
Ans. (3) silanol groups on their supported to adsorb polar
OH compound and work particularly well for basic
Sol.
substances. Alumina is the example of polar and
OH
basic adsorbent that is used in adsorption
IUPAC name : Benzene-1,2-diol
Common name : catechol chromatography.
2
71. The correct order of the first ionization enthalpy is
KOH  alc  (1) Al > Ga > Tl (2) Ga > Al > B
69. 
 major product "P"

Br (3) B > Al > Ga (4) Tl > Ga > Al
Ans. (4)
Product P is
Sol. (i) due to lanthanide contraction T has more I.E.
as compared to Ga and A

(ii) due to scandide contraction Ga has more I.E. as
(1)
compared to A
72. If an iron (III) complex with the formula
–
 Fe  NH3   CN   has no electron in its eg
(2)  x y
orbital, then the value of x + y is

(1) 5 (2) 6
®
(3) (3) 3 (4) 4
Ans. (2)
III

Sol. Complex is [Fe(NH3 ) 2 (CN) 4 ]
(4) x=2
y=4
Ans. (2) so x + y = 6
73. Fuel cell, using hydrogen and oxygen as fuels,
Sol. Alc.KO
H  A. has been used in spaceship
Br B. has as efficiency of 40% to produce electricity
(Major)
C. uses aluminium as catalysts
70. Correct order of stability of carbanion is D. is eco-friendly
E. is actually a type of Galvanic cell only
(1) A,B,C only (2) A,B,D only
(3) A,B,D,E only (4) A,D,E only
a b c d
Ans. (4)
(1) c > b > d > a (2) a > b > c > d Sol. Fuel cell is used in spaceship and it is type of
(3) d > a > c > b (4) d > c > b > a galvanic cell.
Ans. (4) 74. Choose the Incorrect Statement about Dalton's
Sol. As we know compound (d) is aromatic and the Atomic Theory
compound (a) is anti-aromatic. Hence compound (1) Compounds are formed when atoms of
(d) is most stable and compound (a) is least stable different elements combine in any ratio
among these in compound (b) and (c) carbon atom (2) All the atoms of a given element have
of that positive charge is sp3 hybridised they on the identical properties including identical mass
basis of angle strain theory compound (c) is more (3) Matter consists of indivisible atoms
stable than compound (b). (4) Chemical reactions involve recorganization of
.. atoms
 
 Ans. (1)
> > > Sol. In compound atoms of different elements combine
in fixed ratio by mass.
3
75. Match List I with List II 77. For a strong electrolyte, a plot of molar conductivity
LIST I LIST II against (concentration)1/2 is a straight line, with a
A. a- Glucose and a-Galactose I. Functional isomers
B. a- Glucose and b-Glucose II. Homologous negative slope, the correct unit for the slope is
C. a- Glucose and a-Fructose III. Anomers
(1) S cm2 mol–3/2 L1/2 (2) S cm2 mol–1 L1/2
D. a- Glucose and a-Ribose IV. Epimers
Choose the correct answer from the options given (3) S cm2 mol–3/2 L (4) S cm2 mol–3/2 L–1/2
below: Ans. (1)
(1) A-III, B-IV, C-II, D-I
Sol.  m   om  A C
(2) A-III, B-IV, C-I, D-II
(3) A-IV, B-III, C-I, D-II Units of A C = S cm2 mole–1
(4) A-IV, B-III, C-II, D-I Uits of A = S cm2 mole–3/2 L1/2
Ans. (3) 78. A first row transition metal in its +2 oxidation state
®
Sol. Based on biomolecules theory and structure of
has a spin-only magnetic moment value of 3.86 BM.
these named compounds –
The atomic number of the metal is
(A) a-Glucose and a-Galactose (IV) Epimers.
(1) 25 (2) 26
(B) a-Glucose and b-Glucose (III) Anomers
(3) 22 (4) 23
(C) a-Glucose and a-Fructose (I) Functional isomers
Ans. (4)
(D) a-Glucose and a-Ribose (II) Homologous
+2
76. Given below are two statements: Sol. 22Ti  [Ar]3d2
+2
Statement I : The correct order of first ionization 23V  [Ar]3d3
enthalpy values of Li, Na, F and Cl is Na < Li < Cl < F. 25Mn
+2
 [Ar]3d5
Statement II : The correct order of negative +2
26Fe  [Ar]3d6
electron gain enthalpy values of Li, Na, F and Cl is
79. The number of unpaired d-electrons in
Na < Li < F < Cl
In the light of the above statements, choose the [Co(H2O)6]3+ is______
correct answer from the options given below : (1) 4 (2) 2

(1) Both Statement I and Statement II are true (3) 0 (4) 1
(2) Both Statement I and Statement II are false Ans. (3)
(3) Statement I is false but Statement II is true Sol.  [Co(H2O)6]+3
(4) Statement I is true but Statement II is false
eg
Ans. (1)
d6
Sol.. (i) Na < Li < Cl < F
    Co+3
I.E.1 in kJ/mol 496 520 1256 1681
t2g
(ii) Na < Li < F < Cl
    No unpaired electrons
eg H in kJ/mol –53 –60 –328 –349
4
80. The number of species from the following that Sol. As isothermal U = 0
have pyramidal geometry around the central atom and process is irreversible
is________ Q = –W = – [– Pext (V2 – V1)]
Q = 5 (20 – 60) = – 200 atm-L
S2 O32 ,SO24 ,SO32 ,S2O27
84. From 6.55 g of aniline, the maximum amount of
(1) 4 (2) 3
acetanilide that can be prepared will be___×10–1 g.
(3) 1 (4) 2 Ans. (95)
Ans. (3) O
Sol.
S O O O NH2 NH – C – CH3
Sol. ··
S S S S O
, S
,
O O– O O– O O– O – O –
O
+ CH3 – C – Cl
O– O– O– O O
Pyramidal
tetrahedral with respect to central atom 93 g aniline form 135 gm acetanlide
®
135
SECTION-B so 6.55 g anilne form  6.55  9.5
93
81. The maximum number of orbitals which can be
95 × 10–1
identified with n = 4 and ml = 0 is_____ 85. Consider the following reaction, the rate
Ans. (4) expression of which is given below
n=4, A+BC
Sol. 4s 4p 4d 4f
rate = k [A]1/2 [B]1/2
m  1 1 1 1
The reaction is initiated by taking 1M
So answer is 4. concentration A and B each. If the rate constant (k)
82. Number of compounds/species from the following is 4.6 × 10–2 s–1, then the time taken for A to
with non-zero dipole moment is_____ become 0.1 M is_____sec. (nearest integer)
BeCl2, BCl3, NF3, XeF4, CCl4, H2O H2S, HBr, Ans. (50)
2.303 1
CO2, H2, HCl Sol. K log
t 0.1
Ans. (5)
2.303
4.6 × 10–2 =
Sol. Polar molecule : NF3 , H 2O, H 2S, HBr, HCl t
(µ  0)
t = 50 sec.
Non Polar molecule : BeCl2 , BCl3 , XeF4 , CCl4 , CO 2 , H 2
(µ  0) 86. Phthalimide is made to undergo following
So answer is 5. sequence of reactions.
83. Three moles of an ideal gas are compressed (i)KOH
isothermally from 60 L to 20 L using constant (ii)Benzylchloride
Phthalimide ' P'
pressure of 5 atm. Heat exchange Q for the
Total number of  bonds present in product 'P'
compression is – ____ Lit. atm.
is/are
Ans. (200) Ans. (8)
5
Sol. O O 89. 2.7 Kg of each of water and acetic acid are mixed,
.. +
K OH –
. . The freezing point of the solution will be –x °C.
N–H N K
Consider the acetic acid does not dimerise in
O O
(Phthalimide) water, nor dissociates in water x = ______(nearest
SN2
–KCl
CH2 – Cl integer)
[Given : Molar mass of water = 18 g mol–1,
O
acetic acid = 60 g mol–1]
.. Kf
N – CH2 H2 O : 1.86 K kg mol–1
Kf
O acetic acid : 3.90 K kg mol–1
(P)
freezing point : H2O = 273 K, acetic acid = 290 K]
Total number of -bonds present in product P is 8
Ans. (31)
87. The total number of 'sigma' and 'Pi' bonds in
®
Sol. As moles of water > moles of CH3COOH
2-oxohex-4-ynoic acid is____.
water is solvent.
Ans. (18)
T°F – (TF)S = KF × M
Sol. O
      2700 / 60
HO–C–C–CH2–C  C–CH3 0 – (TF)S = 1.86 ×
  2700 / 1000
O
2-Oxohex-4-ynoic acid (TF)S = –31°C.
90. Vanillin compound obtained from vanilla beans,
Number of -bonds = 14
Number of -bonds = 4 has total sum of oxygen atoms and  electrons is__
= 18 Ans. (11)
88. A first row transition metal with highest enthalpy Sol. Vanillin compound is an organic compound
of atomisation, upon reaction with oxygen at high molecular formula C8H8O3. It is a phenolic aldehyde.
temperature forms oxides of formula M2On (where Its functional compounds include aldehyde, hydroxyl
n = 3,4,5). The 'spin-only' magnetic moment value and ether. It is the primary component of the extract
of the amphoteric oxide from the above oxides of the vanilla beans.
is___ BM (near integer) H O
(Given atomic number : Sc : 21, Ti : 22, V : 23,
Cr : 24, Mn : 25, Fe : 26, Co : 27, Ni : 28 ,Cu : 29,
Zn : 30) OCH3
Ans. (0) OH
Sol. 'V' has highest enthalpy of atomisation (515 kJ/mol) Total sum of oxygen atoms and -electrons is 3 + 8 = 11
among first row transition elements. Total number of oxygen atoms = 3
V2O5
Total number of -bonds = 4
Here 'V' is in +5 oxidation state
 Total number of -electrons = 8
V+5  1s2 2s2 2p6 3s2 3p6 (no unpaired electrons)
6
(Held On Friday 05th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A 63. Identify compound (Z) in the following reaction
61. The incorrect postulates of the Dalton's atomic sequence.
Cl
theory are :
(A) Atoms of different elements differ in mass. 623 K
+ NaOH 300 atm X
HCl
Y
Conc. HNO3
Z
(B) Matter consists of divisible atoms.
(C) Compounds are formed when atoms of OH OH
NO2 NO2
different element combine in a fixed ratio. (1) (2)
(D) All the atoms of given element have different
®
properties including mass. NO2
(E) Chemical reactions involve reorganisation of OH

OH
atoms. O2N NO2
Choose the correct answer from the options given (3) (4)
below : NO2 NO2

(1) (B), (D), (E) only Ans. (3)
Cl ONa OH OH
(2) (A), (B), (D) only NO2 NO2
+ NaOH
(3) (C), (D), (E) only Sol.
(X) (Y)
NO2
(4) (B), (D) only (Z)
Ans. (4) 64. Given below are two statements : One is labelled
Sol. B, D as Assertion (A) and the other is labelled as
Reason (R)
62. The following reaction occurs in the Blast furnance Assertion (A): Enthalpy of neutralisation of strong
where iron ore is reduced to iron metal monobasic acid with strong monoacidic base is
–1
Fe2O3 s   3CO(g) Fe l   3CO2(g) always –57 kJ mol
Reason (R): Enthalpy of neutralisation is the
Using the Le-chatelier's principle, predict which +
amount of heat liberated when one mole of H ions
one of the following will not disturb the –
furnished by acid combine with one mole of OH
equilibrium. ions furnished by base to form one mole of water.
In the light of the above statements, choose the
(1) Addition of Fe2O3
correct answer from the options given below.
(2) Addition of CO2 (1) (A) is true but (R) is false
(2) Both (A) and (R) are true and (R) is the
(3) Removal of CO
correct explanation of (A)
(4) Removal of CO2 (3) (A) is false but (R) is true
Ans. (1) (4) Both (A) and (R) are true but (R) is not the
Sol. When solid added no effect on equilibrium. Ans. (2)
1
Sol. Enthalpy of neutralization of SA & SB is always 67. Given below are two statements :
–57 kJ / mol because strong monoacid gives one Statement I: In group 13, the stability of +1
mole of H+ and strong mono base gives one mole oxidation state increases down the group.
of OH– which form one mole of water. Statement II: The atomic size of gallium is greater
65. The statement(s) that are correct about the species than that of aluminium.
2– – + 2+ In the light of the above statements, choose the
O , F , Na and Mg .
(A) All are isoelectronic most appropriate answer from the options given
(B) All have the same nuclear charge below:
(C) O
2–
has the largest ionic radii (1) Statement I is incorrect but Statement II is
2+ correct
(D) Mg has the smallest ionic radii
(2) Both Statement I and Statement II are correct
Choose the most appropriate answer from the
(3) Both Statement I and Statement II are
options given below :
incorrect
(1) (B), (C) and (D) only
(2) (A), (B), (C) and (D)
incorrect
®
(3) (C) and (D) only
Ans. (4)
(4) (A), (C) and (D) only
Sol. Statement I : Number of d & f electrons, increases
Ans. (4)
down the group and due to poor shielding of d & f
Sol. O–2 F– Na+ Mg+2
e–, stability of lower oxidation states increases
(No. of e–) 10 10 10 10
down the group
(Ionic radius) O > F > Na > Mg+2
–2 – +
Statement II : The atomic size of aluminium is
Zeff O–2 < F– < Na+ < Mg+2
greater than that of gallium.
66. For the compounds:
68. Number of  and  bonds present in ethylene
(A) H3C–CH2–O–CH2–CH2–CH3
molecule is respectively :
(B) H3C–CH2–CH2–CH2–CH3 (1) 3 and 1 (2) 5 and 2
(C) CH3–CH2–C–CH2–CH3 (3) 4 and 1 (4) 5 and 1
Ans. (4)
O
H  H
(D) H3C–CH– CH2– CH2–CH3 Sol. ethylene is C=C , it has 5 bonds and
 H
OH H 
The increasing order of boiling point is : 1 bond.

Choose the correct answer from the options given 69. Identify 'A' in the following reaction :
below : O
(1) (A) < (B) < (C) < (D) (i) N2H4
C CH3 'A'
(2) (B) < (A) < (C) < (D) CH3 (ii) ethylene glycol / KOH
(3) (D) < (C) < (A) < (B)
(4) (B) < (A) < (D) < (C) CH3
(1) CH3 (2) CH3
Ans. (2) OH CH3
Sol. Compounds having same number of carbon atoms
follow the boiling point order as: CH3 CH3
(Boiling point)Hydrogen bonding >(Boiling point)high polarity > C=N–NH2 C=N–NH2
(Boiling point)low polarity > (Boiling point)non polar (3) (4)
H5C2 CH3
Ans. (2)
2
Sol.
O
 (i) N2 H 4
 Sol. Dipole moment is a vector quantity and for
(ii)ethylene glycol/KOH
CH3 compound net dipole moment is the vector sum of
CH3 all dipoles hence dipole moment of cis form is
CH3 – Wolf kishner reduction. greater than trans form.
CH3 CH3 CH3
:CH3 H
70. The reaction at cathode in the cells commonly used C=C > C=C
H H H
in clocks involves. Cis CH3 trans
(1) reduction of Mn from +4 to +3 ( > 0) ( = 0)
(2) oxidation of Mn from +3 to +4
(3) reduction of Mn from + 7 to +2 73. Given below are two statements :
(4) oxidation of Mn from + 2 to +7 Statement I: Nitration of benzene involves the
Ans. (1) following step –
Sol. In the cathode reaction manganese (Mn) is reduced
H
from the +4 oxidation state to the +3 state.  
71. Which one of the following complexes will exhibit H – O – NO2 H2O + NO2
®
••
the least paramagnetic behaviour ?
[Atomic number, Cr = 24, Mn = 25, Fe = 26, Co = 27] Statement II: Use of Lewis base promotes the
(1) [Co(H2O)6]
2+
(2) [Fe(H2O)6]
2+ electrophilic substitution of benzene.
2+ 2+ In the light of the above statements, choose the
(3) [Mn(H2O)6] (4) [Cr(H2O)6]
Ans. (1) most appropriate answer from the options given
Sol. below :
Number of   n(n  2) B.M. (1) Both Statement I and Statement II are
unpaired e– incorrect
2+ 3 3.87
[Co(H2O)6] (2) Statement I is correct but Statement II is
2+ 4 4.89
[Fe(H2O)6] incorrect
2+ 5 5.92
[Mn(H2O)6] (3) Both Statement I and Statement II are
2+ 4 4.89
[Cr(H2O)6] correct
2+
Least paramagnetic behaviour = [Co(H2O)6] (4) Statement I is incorrect but Statement II is
72. Given below are two statements : one is labelled correct
as Assertion (A) and the other is labelled as Ans. (2)
Reason (R). Sol. In nitration of benzene concentrated H2SO4 and
Assertion (A): Cis form of alkene is found to be HNO3 is used as reagent which generates
more polar than the trans form 
Reason (R): Dipole moment of trans isomer of electrophile N O2 in following steps:
2-butene is zero. H
correct answer from the options given below : H2SO4 + HNO3

(1) Both (A) and (R) are true but (R) is NOT the
(2) (A) is true but (R) is false
(3) Both (A) and (R) are true and (R) is the
(4) (A) is false but (R) is true Lewis acids can promote the formation of
Ans. (3) electrophiles not Lewis base
3
74. The correct order of ligands arranged in increasing Sol. Phenol is a highly activated compound which can
field strength. undergo bromination directly with Bromine
– – – –
(1) Cl < OH < Br < CN without any lewis acid.
– – –
(2) F < Br < I < NH3 79. Molar ionic conductivities of divalent cation and
– – anion are 57 S cm2 mol–1 and 73 S cm2 mol–1
(3) Br < F < H2O < NH3
– – respectively. The molar conductivity of solution of
(4) H2O < OH < CN < NH3
Ans. (3) an electrolyte with the above cation and anion will
– – be :
Sol. Experimental order Br < F < H2O < NH3
2 –1 2 –1
75. Which of the following gives a positive test with (1) 65 S cm mol (2) 130 S cm mol
ninhydrin ? 2 –1 2 –1
(3) 187 S cm mol (4) 260 S cm mol
(1) Cellulose (2) Starch Ans. (2)
(3) Polyvinyl chloride (4) Egg albumin
2
Ans. (4) Sol. C  57Scm 2 mol –1
Sol. Ninhydrin test is a test of amino acids. Egg
 A2  73Scm 2 mol –1
albumin contains protein which is a natural
®
polymer of amino acids which will show positive 2 2
Solution  C  A
ninhydrin test
76. The metal that shows highest and maximum = 57 + 73 = 130
number of oxidation state is: 80. The number of neutrons present in the more abundant
(1) Fe (2) Mn isotope of boron is 'x'. Amorphous boron upon
(3) Ti (4) Co heating with air forms a product, in which the
Ans. (2) oxidation state of boron is 'y'. The value of x + y is …
Sol. Mn shows highest oxidation state (Mn+7) in 3d (1) 4 (2) 6
series metals. (3) 3 (4) 9
77. Ail organic compound has 42.1% carbon, 6.4% Ans. (4)
hydrogen and remainder is oxygen. If its molecular Sol. More abundant isotope = B11
weight is 342, then its molecular formula is :
[Number of neutrons = 6]
(1) C11H18O12 (2) C12H20O12
x=6
(3) C14H20O10 (4)
C12H22O11 B + O2  B2O3
Ans. (4) Oxidation state of B in B2O3 = +3
Sol. only C12H22O11 has 42.1% carbon, 6.4% hydrogen So, y = 3
& 51.5 percent oxygen. Hence x + y = 9
78. Given below are two statement : SECTION-B
Statement I : Bromination of phenol in solvent –18
81. The value of Rydberg constant (RH) is 2.18×10 J.
with low polarity such as CHCl3 or CS2 requires –31
The velocity of electron having mass 9.1×10 kg
Lewis acid catalyst.
in Bohr's first orbit of hydrogen atom
Statement II : The lewis acid catalyst polarises the 5 –1
bromine to generate Br .
+ = ……… ×10 ms (nearest integer)
In the light of the above statements, choose the Ans. (22)
correct answer from the options given below : Z
Sol. V = 2.18 × 106 ×
(1) Statement I is true but Statement II is false. n
(2) Both Statement I and Statement II are true 1
(3) Both Statement I and Statement II are false. = 21.8 × 105 ×  22 × 105 (nearest)
(4) Statement I is false but Statement II is true.
1
Ans. (4)
4
A 85. The spin only magnetic moment value of the ion
B among Ti , V , Co
2+ 2+ 3+ 2+
and Cr , that acts as
82.
strong oxidising agent in aqueous solution is
……….. BM (Near integer).
In a borax bead test under hot condition, a metal
(Given atomic numbers : Ti : 22, V : 23, Cr : 24,
salt (one from the given) is heated at point B of the
Co : 27)
flame, resulted in green colour salt bead. The
spin-only magnetic moment value of the salt is Ans. (5)
…………. BM (Nearest integer) Sol. Strong oxidising agent = Co+3
[Given atomic number of Cu = 29, Ni = 28, No. of unpaired e– in Co+3[3d6] = 4
Mn = 25, Fe = 26]
Hence   n(n  2)  24 BM
Ans. (6)
Sol. Fe+3 will give green coloured bead when heated at Nearest integer = 5
®
point B. 86. During Kinetic study of reaction 2A + B  C + D,
Number of unpaired e– in Fe+3 = 5 the following results were obtained :
 = 5.92
Nearest integer = 6 A[M] B[M] initial rate of
83. The heat of combustion of solid benzoic acid at formation of D
I 0.1 0.1 –3
constant volume is –321.30 kJ at 27°C. The heat of 6.0 × 10
combustion at constant pressure is (–321.30 – xR) II 0.3 0.2 –2
7.2 × 10
kJ, the value of x is ……………. –1
III 0.3 0.4 2.88 × 10
Ans. (150)
IV 0.4 0.1 –2
2.40 × 10
15
Sol. C6H5COOH(S) + O2(g)  7CO2(g) + 3H2O()
2 Based on above data, overall order of the reaction
H = U + ngRT is ……….
1 R Ans. (3)
 321.30   300
2 100 Sol. r = K[A]x[B]y
= (–321.30 – 150R) kJ (I) 6 × 10–3 = K[0.1]x[0.1]y
84. Consider the given chemical reaction sequence : (IV) 2.4 × 10–2 = K[0.4]x[0.1]y
OH (IV)/(I)
4 = (4)x
Conc. H2SO4 Conc. HNO3
Product A Product B x=1
r = K[A]x[B]y
Total sum of oxygen atoms in Product A and (III) 2.88 × 10–1 = K[0.3]x[0.4]y
Product B are ……… (II) 7.2 × 10–2 = K[0.3]x[0.2]y
Ans. (14) (III)/(II)
Sol. Picric acid is prepared by treating phenol first with 4 = 2y
concentrated sulphuric acid which converts it to y=2
phenol-2,4-disulphonic acid and then with Overall order = x + y = 1 + 2 = 3
concentrated nitric acid to get 2, 4, 6 trinitrophenol.
5
87. An artificial cell is made by encapsulating 0.2 M 90. 9.3 g of pure aniline is treated with bromine water
glucose solution within a semipermeable at room temperature to give a white precipitate of
membrane. The osmotic pressure developed when the product 'P'. The mass of product 'P' obtained is
the artificial cell is placed within a 0.05 M solution 26.4 g. The percentage yield is ……… %.
of NaCl at 300 K is _______ × 10–1 bar. Ans. (80)
(Nearest Integer) NH2 NH2
–1 –1 Br
[Given : R = 0.083 L bar mol K ] Br
Assume complete dissociation of NaCl Sol.
Ans. (25)
Sol. Br
(white ppt)
0.2 M 0.05 M
Glucose NaCl Sol. 93 g of aniline produces 330 g of 2, 4, 6-
tribromoaniline. Hence 9.3 g of aniline should
®
produce 33g of 2, 4, 6-tribromoaniline. Hence
NaCl  Na+ + Cl– 26.4  100
percentage yield  80%
0.05M 0.05M 0.05M 33
Total C1 = 0.05 + 0.05 = 0.1 M (NaCl)
C2 = 0.2 M (glucose)
 = (C2 – C1) RT
= (0.2 – 0.1) × 0.083 × 300
= 2.49 bar
= 24.9 × 10–1 bar
88. The number of halobenzenes from the following
that can be prepared by Sandmeyer's reaction
is .......
F Cl Br I At
I II III IV V
Ans. (2)
Sol. In Sandmayer reaction only bromobenzene &
chlorobenzene are prepared
–
89. In the lewis dot structure for NO2 , total number of
valence electrons around nitrogen is …….
Ans. (8)
Sol.
N
–
O O
Number of valence e– around N-atom = 8
6
Final JEE-Main Exam April, 2024/05-04-2024/Evening Session

(Held On Friday 05th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A Sol. Fe+2 ions undergoes hydrolysis, therefore while
61. Match List - I with List - II. preparing aqueous solution of ferrous sulphate and
List - I List - II ammonium sulphate in water dilute sulphuric acid
(A) ICI (I) T -Shape
is added to prevent hydrolysis of ferrous sulphate.
(B) ICI3 (II) Square pyramidal
(C) CIF5 (III) Pentagonal 63. Identify the major product in the following
bipyramidal reaction.
(D) IF7 (IV) Linear Br
OH
®
below: CH3 Major Product
(1) (A)–(I), (B)–(IV), C–(III), D–(II) C2H5OH
(2) (A)–(I), (B)–(III), C–(II), D–(IV)
(3) (A)–(IV), (B)–(I), C–(II), D–(III) CH2
(1)
(4) (A)–(IV), (B)–(III), C–(II), D–(I)
Ans. (3) Br
Sol. A. I – Cl (iv) linear (2)
Cl
CH3
B. I – Cl (I) T-shape (3)
Cl
CH3
F (4)
F F
C. Cl (II) Square pyramidal Ans. (3)
F F
Sol. CH3 CH3
F Br
F F
D. I F (III) Pentagonal bipyramidal H
F F
F
64. The correct nomenclature for the following
62. While preparing crystals of Mohr's salt, dil. H2SO4 compound is:
is added to a mixture of ferrous sulphate and O
ammonium sulphate, before dissolving this mixture
OH
in water, dil. H2SO4 is added here to: OH O H
(1) prevent the hydrolysis of ferrous sulphate
(1) 2–carboxy–4–hydroxyhept–6–enal
(2) prevent the hydrolysis of ammonium sulphate (2) 2–carboxy–4–hydroxyhept–7–enal
(3) make the medium strongly acidic (3) 2–formyl–4–hydroxyhept–6–enoic acid
(4) increase the rate of formation of crystals (4) 2–formyl–4–hydroxyhept–7–enoic acid
Ans. (1) Ans. (3)
1
O 66. Given below are two statements:
7 5 3
CH2 Statement I : On passing HCl(g) through a
Sol. 2 1 saturated solution of BaCl2, at room temperature
OH
6 4 white turbidity appears.
OH C Statement II : When HCl gas is passed through a
O H
saturated solution of NaCl, sodium chloride is
precipitated due to common ion effect.
2-formly-4-hydroxyhept-6-enoic acid In the light of the above statements, choose the
65. Given below are two statements : one is labelled as most appropriate answer from the options given
Assertion (A) and the other is labelled as Reason (R). below:
Assertion (A) : NH3 and NF3 molecule have incorrect
pyramidal shape with a lone pair of electrons on (2) Both Statement I and Statement II are
nitrogen atom. The resultant dipole moment of incorrect
(3) Statement I is incorrect but Statement II is
NH3 is greater than that of NF3.
®
correct
Reason (R) : In NH3, the orbital dipole due to lone (4) Both Statement I and Statement II are correct
pair is in the same direction as the resultant dipole Ans. (1)
Sol. BaCl2, NaCl are soluble but on adding HCl(g) to
moment of the N–H bonds. F is the most
BaCl2, NaCl solutions, Sodium or Barium
electronegative element. chlorides may precipitate out, as a consequence of
In the light of the above statements, choose the the law of mass action.
correct answer from the options given below: 67. The metal atom present in the complex MABXL
(where A, B, X and L are unidentate ligands and M
(1) Both (A) and (R) are true and (R) is the correct 3
is metal) involves sp hybridization. The number of
explanation of (A) geometrical isomers exhibited by the complex is:
(2) (A) is false but (R) is true (1) 4 (2) 0
(3) 2 (4) 3
(3) (A) is true but (R) is false Ans. (2)
(4) Both (A) and (R) are true but (R) is NOT the Sol. Tetrahedral complex does not show geometrical
correct explanation of (A) isomerism.
68. Match List - I with List - II.
Ans. (1)
List - I List - II
(Pair of Compounds) (Isomerism)
(A) n-propanol and (I) Metamerism
Sol. N
F Isopropanol
F
F (B) Methoxypropane and (II) Chain Isomerism
ethoxyethane
Resultant dipole moment = 0.80 × 10–30 Cm (C) Propanone and (III) Position
propanal Isomerism
(D) Neopentane and (IV) Functional
N
H Isopentane Isomerism
H
H (1) (A)–(II), (B)–(I), (C)–(IV), (D)–(III)
(2) (A)–(III), (B)–(I), (C)–(II), (D)–(IV)
–30
Resultant dipole moment = 4.90 × 10 cm (3) (A)–(I), (B)–(III), (C)–(IV), (D)–(II)
(4) (A)–(III), (B)–(I), (C)–(IV), (D)–(II)
Ans. (4)
2
OH 71. Given below are two statements :
Sol. OH
⇒ Position isomers Statement I : The metallic radius of Na is 1.86 A°
&
and the ionic radius of Na+ is lesser than 1.86 A°.
OCH3
⇒ Metamers Statement II : Ions are always smaller in size than
&
O the corresponding elements.
O In the light of the above statements, choose the
& ⇒ Functional isomers correct answer from the options given below :
C—H
O
false
& ⇒ Chain isomers
(2) Both Statement I and Statement II are true
(3) Both Statement I and Statement II are false
neopentane isopentane
69. The quantity of silver deposited when one coulomb true
charge is passed through AgNO3 solution: Ans. (1)
(1) 0.1 g atom of silver Sol. rNa > rNa+
®
(2) 1 chemical equivalent of silver So, Statement (I) is correct but size of anions are
(3) 1 g of silver greater than size of neutral atoms.
(4) 1 electrochemical equivalent of silver So statement (II) is incorrect.
Ans. (4) 72. CH3CH2–OH (i) Jone's Reagent
Sol. W = ZIt P
(ii) KMnO4
W = ZQ (iii)NaOH, CaO,∆
W
Q= Consider the above reaction sequence and identify
Z
W = ZQ = (electrochemical equivalent) the major product P.
70. Which one of the following reactions is NOT (1) Methane (2) Methanal
possible? (3) Methoxymethane (4) Methanoic acid
OCH3
Ans. (1)
OH
O
Joner reagent (CrO3 + H⊕)
HBr CH3 — C — OH
(1) Sol. CH3 — CH2 — OH
KMnO4
Soda NaOH
lime CaI
OH Cl process ∆
HCl
(2) CH4 + Na2CO3
73. Consider the given chemical reaction :

Cl OH
NaOH KMnO4–H2SO4
(3) High Temp, H+
Product ''A''
Heat
OCH3 OCH3
Product ''A'' is :
Cl2/AlCl3
(4) (1) picric acid (2) oxalic acid
(3) acetic acid (4) adipic acid
Cl
Ans. (4)
Ans. (2) O
OH Cl
KMnO4, H2SO4 C — OH
Sol. sp2 Sol.
C — OH
Not Possible
O
3
74. For the electro chemical cell 77. The number of ions from the following that have
M|M2+||X|X2– the ability to liberate hydrogen from a dilute acid is
=
If E 0 2 + = V and E 0 2 −
M /M ( ) 0.46
( X/X) 0.34V. _______. Ti2+, Cr2+ and V2+
(1) 0 (2) 2
Which of the following is correct ?
(3) 3 (4) 1
(1) Ecell = –0.80 V
(2) M + X → M + X is a spontaneous reaction
2 2– Ans. (3)
(3) M + X → M + X is a spontaneous reaction
2+ 2– +2 +2 +2
Sol. The ions Ti , V Cr are strong reducing agents
(4) Ecell = 0.80 V and will liberate hydrogen from a dilute acid, eg.
Ans. (3) +2 + +3
+2 2–
2Cr(aq.) + 2H(aq.) 
→ 2Cr(aq.) + H2 (g)
Sol. M | M || X / X
=
E ocell E oM/M +2 + E oX/X −2 78. Identify A and B in the given chemical reaction
= –0.46 + 0.34 = – 0.12V sequence : -
®
O
As E ocell is negative so anode becomes cathode and
O
cathode become anode. Spontaneous reaction will be
O Zn–Hg H+
M + X → M + X A B
+2 2–
AlC3 HCl
75. The number of moles of methane required to produce O

11g CO2(g) after complete combustion is:
(Given molar mass of methane in g mol–1 : 16) A- ,B-
(1)
(1) 0.75 (2) 0.25 COOH CH2OH
(3) 0.35 (4) 0.5
Ans. (2) O
3n + 1
Sol. CnH2n+2 + O2 
→ nCO2 + (n + 1)H2O (2) A - ,B-
2 COOH COOH
CH4 + 2O2  → CO2 + 2H2O
O
4gm 11gm
0.25 mole 0.25 mole (3) A - ,B-
0.25 mole CH4 gives 0.25 mole (or 11gm) CO2
76. The number of complexes from the following with O
no electrons in the t2 orbital is _______. O OH
TiCl4, [MnO4]–, [FeO4]2–, [FeCl4]–, [CoCl4]2–
(1) 3 (2) 1 (4) A - ,B-
(3) 4 (4) 2
O OH
Ans. (1)
Sol. TiCl4 ⇒ Ti+4 Ans. (2)
Sol.
⇒ Mn+7 O
⇒ Fe+6 O O
C
O Zn, Hg H⊕
⇒ Fe +2 AlCl3
ESR C
HCl
Clemmension C
ESR
HO Reduction HO O
O O
⇒ Co +2
(A) (B)
4
79. The correct statements from the following are : SECTION-B
(A) The decreasing order of atomic radii of group 13 81. Combustion of 1 mole of benzene is expressed at
15
elements is Tl > In > Ga > Al > B. C6H6(1) + O2 ( g ) → CO2 ( g ) + 3H 2 O (1) .
2
(B) Down the group 13 electronegativity The standard enthalpy of combustion of 2 mol of
decreases from top to bottom. benzene is – 'x' kJ.
(C) Al dissolves in dil. HCl and liberate H2 but conc. x = ______.
HNO3 renders Al passive by forming a (1) standard Enthalpy of formation of 1 mol of
C6H6(1), for the reaction
protective oxide layer on the surface.
6C(graphite) + 3H2(g) → C6H6(1) is 48.5 kJ mol–1.
(D) All elements of group 13 exhibits highly (2) Standard Enthalpy of formation of 1 mol of
stable +1 oxidation state. CO2(g), for the reaction
(E) Hybridisation of Al in [Al(H2O)6]3+ ion is C(graphite) + O2(g) → CO2(g) is –393.5 kJ mol–1.
3
sp d .
2
(3) Standard and Enthalpy of formation of
®
1 mol of H2O(1), for the reaction
1
below : H2(g) + O2 ( g ) → H2O(1) is –286 kJ mol–1.
2
(1) (C) and (E) only Ans. (6535)
(2) (A), (C) and (E) only Sol. 6C(graphite)+3H2(g) → C6H6(); ∆H = 48.5 kJ/mol
(3) (A), (B), (C) and (E) only C(graphite)+O2(g)→ CO2(g); ∆H = –393.5 kJ/mol
(4) (A) and (C) only
H(2g ) +
1
( g ) → H2O() ; ∆H = – 286 kJ/mol
Ans. (1) 2
Sol. A. size order T > In > Al > Ga > B equation –(1) × 1 + (2) × 6 + (3) × 3
– 48.5 –6 × 393.5 – 3 × 286
B. Electronegativity order B > Al < Ga < In < T = – 3267.5 kJ for 1 mol
= – 6535 kJ for 2 mol
D. B, Al are more stable in +3 oxidation state Ans. 6535 kJ
So, only C, E statements are correct. 82. The fusion of chromite ore with sodium carbonate
80. Coagulation of egg, on heating is because of : in the presence of air leads to the formation of
products A and B along with the evolution of CO2.
(1) Denaturation of protein occurs
The sum of spin-only magnetic moment values of
(2) The secondary structure of protein remains
A and B is ___ B.M. (Nearest integer)
unchanged (Given atomic number : C : 6, Na : 11, O : 8,
(3) Breaking of the peptide linkage in the primary Fe : 26, Cr : 24]
structure of protein occurs Ans. (6)
(4) Biological property of protein remains Sol. 4FeCr2O4 + 8Na2CO3 + 7O2 →
8Na2CrO4 + 2Fe2O3 + 8CO2
unchanged
A B
Ans. (1) Spin only magnetic moment
Sol. Coagulation of egg give primary structure of For Na2CrO4 µB = 0
protein, which is known as denaturation of protein For Fe2O3 µB = 5.9
sum = 5.9
5
83. X of enthanamine was subjected to reaction with 86. In the Claisen-Schmidt reaction to prepare 351 g of
NaNO2/HCl followed by hydrolysis to liberate N2 dibenzalacetone using 87 g of acetone, the amount
and HCl. The HCl generated was completely
neutralised by 0.2 moles of NaOH. X is ____ g. of benzaldehyde required is _________g. (Nearest
Ans. (9) integer)
⊕ Θ
Sol. CH3—CH2—NH2 NaNO2 + HCl CH3—CH2—N2Cl Ans. (318)
0.2 mole HOH
MW of ethanamine = 45 Sol. Claisen Schmidt reaction
45 × 0.2 = 9 gm CH3—CH2—OH + N2 + HCl O H
(g) C O
O
0.2 mole ⊕Θ
+ CH3 NaOH
CH3 — CH = CH — C — CH = CH —
84. In an atom, total number of electrons having 2 mole 1 mole
Dibanzal acetone
1 mole
1 3 mole 1.5 mole 351 gm = 1.5 mole
quantum numbers n = 4, |ml| = 1 and ms = – is
2
mw of benzaldehyde = 106
Ans. (6)
®
Sol. n = 4 106 × 3 = 318 gm. Benzaldehyde is required to
 m give 1.5 mole (or 351 gm) product
0 0 87. Consider the following single step reaction in gas
1 –1, 0, +1 phase at constant temperature.
2 –2, –1, 0, +1, +2, +3
So number of orbital associated with 2A(g) + B(g) → C(g)
n = 4, |m| = 1 are 6 The initial rate of the reaction is recorded as r1
– 1 when the reaction starts with 1.5 atm pressure of A

Now each orbital contain one e with ms = –
2 and 0.7 atm pressure of B. After some time, the
85. Using the given figure, the ratio of Rf values of
rate r2 is recorded when the pressure of C becomes
sample A and sample C is x × 10–2. Value of x is
–1
__________. 0.5 atm. The ratio r1 : r2 is ________ × 10 .
12.5 cm Solvent front (Nearest integer)

10.0 cm Sample C Ans. (315)
6.5 cm Sample B Sol. 2A(g) + B(g) → C(g)

Sample A
5.0 cm r1 1.5 atm 0.7 atm
0.0 cm Base line
r2 0.5 atm 0.2 atm 0.5 atm
 r = K [PA] [PB]
2
Samples (A,B,C)
Fig : Paper chromatography of Samples
2
r1 = K [1.5] [0.7]
Ans. (50) 2
r2 = K [0.5] [0.2]
5 10
Sol. Rf of A = Rf of C =
12.5 12.5 r1 7
=9 × =31.5 =315 × 10 –1
r2 2
R f (A) 1
Ratio = = = 0.5 or 50 × 10–2
R f (C) 2 Ans. 315
6
88. The product © in the following sequence of Sol. Mass of CH3COOH = V × d
reactions has _________ π bonds. = 5 ml × 1.2 g/ml
= 6 gm
KMnO4–KOH H3O+ Br2
A B C
∆ FeBr3 6
=
n CH3COOH = 0.1mol
60
Ans. (4)
0.1
O m CH3COOH ≈ M CH3COOH = =
0.1M
1
Θ ⊕
C—OK CH3COOH CH3COO– + H+
Sol. A =
C
C – Cα Cα Cα
O
Cα 2
C — OH Ka =
1− α
®
B=
1 – α ≈ 1 ⇒ Ka = Cα2
O Ka 6.25 × 10 –5
=α = = 25 × 10–3
C — OH C 0.1
C= V.f. (i) = 1 + α(n – 1) = 1 + α(2 – 1) = 1 + α
= 1 + 25 × 10–3 = 1.025
Br ∆Tf = iKfm
π bonds = 4 = (1.025)(1.86)(0.1)
89. Considering acetic acid dissociates in water, its = 0.19
–5
dissociation constant is 6.25 × 10 . If 5 mL of = 19 × 10–2
acetic acid is dissolved in 1 litre water, the solution 90. Number of compounds from the following with
–2
will freeze at –x × 10 °C, provided pure water zero dipole moment is ___________.
freezes at 0 °C. HF, H2, H2S, CO2, NH3, BF3, CH4, CHCl3, SiF4,
x = _________. (Nearest integer) H2O, BeF2
–1
Given : (Kf)water = 1.86 K kg mol . Ans. (6)
–1
density of acetic acid is 1.2 g mol Sol. H2, CO2, BF3, CH4, SiF4 , BeF2
–1
molar mass of water = 18 g mol . are symm. molecule so dipole moment is zero
–1
molar mass of acetic acid = 60 g mol .
density of water = 1 g cm–3
Acetic acid dissociates as
CH3COOH  CH 3COO Θ + H ⊕
Ans. (19)
7
(Held On Saturday 06th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A 63. Given below are two statements :
61. Functional group present in sulphonic acid is : Statement I : Picric acid is 2, 4, 6-trinitrotoluene.
(1) SO4H (2) SO3H Statement II : Phenol-2, 4-disulphuric acid is
(3) – S – OH (4) – SO2 treated with conc. HNO3 to get picric acid.
O In the light of the above statement, choose the
Ans. (2) most appropriate answer from the options given
O below :
Sol. S OH (1) Statement I is incorrect but Statement II is
correct.
O
®
Group present in sulphonic acids incorrect.
62. Match List I with List II :
List I List II incorrect.
(Molecule / Species) (Property / Shape) (4) Both Statement I and Statement II are correct.
A. SO2Cl2 I. Paramagnetic Ans. (1)
B. NO II. Diamagnetic OH
C. III. Tetrahedral Sol. O2N
NO– 2
NO2
D. I3– IV. Linear
Choose the correct answer from the options given NO2

below :
picric acid
(1) A-IV, B-I, C-III, D-II
(2) A-III, B-I, C-II, D-IV (2, 4, 6 – trinitrophenol)
(3) A-II, B-III, C-I, D-IV OH OH
(4) A-III, B-IV, C-II, D-I SO3H
Conc. H2SO4
Ans. (2)
Sol.
(A) SO2Cl2 sp3 O SO3H
Tetrahedral
S Cl
Conc. HNO3
O Cl
(B) NO Paramagnetic OH
(C) NO  Diamagnetic O2N NO2
2
(D) I 3 sp3d I –
I
NO2
I Linear Picric acid
1
64. Which of the following is metamer of the given Ans. (3)
compound (X) ? NH2
O N C
NH – C Sol. C N  Adenine
HC
(X) N C CH
N
O H
(1)
NH – C O
(2) OHC C
NH H3C – C NH
 Thymine
O HC N C
(3) H O
NH – C
NH2
O
(4) C
NH – C HC N
®
 Cytosine
Ans. (4) HC N C
Sol. Metamer Isomer having same molecular H O
formula, same functional group but different
Are bases of DNA molecule. As DNA contain four
alkyl/aryl groups on either side of functional
group. bases, which are adenine, guanine, cytosine and
thymine.
65. DNA molecule contains 4 bases whoes structure
are shown below. One of the structure is not 66. Match List I with List II :
correct, identify the incorrect base structure.
LIST I LIST II
NH2
(Hybridization) (Orientation in
N C
(1) C N Space)
HC
N C CH A. sp3 I. Trigonal
N
H bipyramidal
O B. dsp2 II. Octahedral
3
C C. sp d III. Tetrahedral
(2) H3C – C NH
D. sp d3 2
IV. Square planar
HC N C
H O Choose the correct answer from the options given
O
below :
(1) A-III, B-I, C-IV, D-II
N C
(3) C NH (2) A-II, B-I, C-IV, D-III
H3C – C
N C C (3) A-IV, B-III, C-I, D-II
N NH2
H (4) A-III, B-IV, C-I, D-II
NH2 Ans. (4)
C Sol. sp3  Tetrahedral
HC N 2
(4) dsp  Square planar
HC N C 3
sp d  Trigonal Bipyramidal
H O sp3d2  Octahedral
2
67. Given below are two statements : 69. Match List I with List II :
Statement I : Gallium is used in the LIST I LIST II
manufacturing of thermometers. (Compound / (Shape / Geometry)
Statement II : A thermometer containing gallium Species)
is useful for measuring the freezing point (256 K)
A. SF4 I. Tetrahedral
of brine solution.
B. BrF3 II. Pyramidal
In the light of the above statement, choose the
C. BrO3– III. See saw
correct answer from the options given below :
(1) Both Statement I and Statement II are false. D. NH4 IV. Bent T-shape
(2) Statement I is false but Statement II is true.
(3) Both Statement I and Statement II are true. Choose the correct answer from the options given
(4) Statement I is true but Statement II is false. below :
Ans. (4) (1) A-II, B-III, C-I, D-IV
®
Sol. Statement - I  Correct (2) A-III, B-IV, C-II, D-I
Statement - II  False (3) A-II, B-IV, C-III, D-I
Ga is used to measure high temperature (4) A-III, B-II, C-IV, D-I
68. Which of the following statements are correct ? Ans. (2)
A. Glycerol is purified by vacuum distillation Sol.
because it decomposes at its normal boiling (A) SF4 sp3d F
point. F
hybridisation S F
B. Aniline can be purified by steam distillation as
F
aniline is miscible in water.
C. Ethanol can be separated from ethanol water (B) BrF3 sp3d F
mixture by azeotropic distillation because it hybridisation Br F
forms azeotrope. F
D. An organic compound is pure, if mixed M.P. is Bent T-Shape
remained same. (C) BrO3 sp
3
Pyramidal
Choose the most appropriate answer from the hybridisation Br
options given below : O–
O
(1) A, B, C only
(2) A, C, D only (D) sp3
NH 4 H +
(3) B, C, D only hybridisation N
(4) A, B, D only Tetrahedral
H
Ans. (2)
Sol. Option (B) is incorrect because aniline is
immisible in water.
3
70. In Reimer - Tiemann reaction, phenol is converted 72. Consider the following complexes.
into salicylaldehyde through an intermediate. The [CoCl(NH3)5]2+, [Co(CN)6]3–,
structure of intermediate is ______.
(A) (B)
– +
ONa [Co(NH3)5(H2O)]3+, [Cu(H2O)4]2+
CH3
(C) (D)
(1)
The correct order of A, B, C and D in terms of
OH wavenumber of light absorbed is :
CHCl2
(2) (1) C < D < A < B
(2) D < A < C < B
– + (3) A < C < B < D
ONa
CHO (4) B < C < A < D
(3)
®
Ans. (2)
– + Sol. As ligand field increases, light of more energy is

ONa
CHCl2 absorbed
(4)
Energy  wave number
 
Ans. (4)
OH O Na+
Sol. CHCl2 LIST I LIST II
CHCl3+ aq NaOH
(Precipitating reagent and (Cation)
conditions)
Intermediate
A. NH4Cl + NH4OH I. Mn2+
NaOH
B. NH4OH + Na2CO3 II. Pb2+
OH O Na+ C. NH4OH + NH4Cl + H2S gas III. Al3+
C–H C–H
H
+ D. dilute HCl IV. Sr2+
O O
below :
71. Which of the following material is not a
semiconductor. (1) A-IV, B-III, C-II, D-I
(1) Germanium (2) A-IV, B-III, C-I, D-II
(2) Graphite (3) A-III, B-IV, C-I, D-II
(3) Silicon
(4) A-III, B-IV, C-II, D-I
(4) Copper oxide
Ans. (2) Ans. (3)
Sol. Graphite is conductor Sol. Theory based question
4
74. The electron affinity value are negative for : 77. Which among the following aldehydes is most
A. Be  Be – reactive towards nucleophilic addition reactions?
B. N  N– O O
C. O  O2– (1) H – C – H (2) C2H5 – C – H
D. Na  Na– O O
–
E. Al  Al (3) CH3 – C – H (4) C3H7 – C – H
Choose the most appropriate answer from the Ans. (1)
options given below : O
(1) D and E only (2) A, B, D and E only
Sol. H – C – H has low steric hindrance at carbonyl
(3) A and D only (4) A, B and C only
carbon and high partial positive charge at carbonyl
Allen Ans. (4)
carbon.
NTA Ans. (1)
Sol. (A) Be + e–  Be– , E.A = –ive 78. At –20 °C and 1 atm pressure, a cylinder is filled
®
– –
(B) N + e N E.A = –ive with equal number of H2. I2 and HI molecules for
(C) O + e –
O – the reaction
O– + e–  O–2 E.A = –ive H2(g) + I2(g) 2HI(g), the KP for the process is
(D) Na + e –
 Na –
E.A = +ive x × 10–1. x = _________.
[Given : R = 0.082 L atm K–1 mol–1]
(E) A + e–  A– E.A = +ive
(1) 2 (2) 1
Ans. A,B and C only (3) 10 (4) 0.01
75. The number of element from the following that Ans. (3)
n g
do not belong to lanthanoids is : (n HI )2  PT 
Sol. ng = 0 Kp =  
Eu, Cm, Er, Tb, Yb and Lu n H2 n I 2  nT 
(1) 3 (2) 4
n HI  n H2  n I2 so KP = 1
(3) 1 (4) 5
1 = x × 10–1 x = 10
Ans. (3)
Sol. Cm is Actinide
LIST I LIST II
76. The density of 'x' M solution ('x' molar) of NaOH (Compound) (Uses)
is 1.12 g mL–1. while in molality, the concentration A. Iodoform I. Fire extinguisher
of the solution is 3 m (3 molal). Then x is B. Carbon II. Insecticide
(Given : Molar mass of NaOH is 40 g/mol) tetrachloride
(1) 3.5 (2) 3.0 C. CFC III. Antiseptic
(3) 3.8 (4) 2.8 D. DDT IV. Refrigerants
Ans. (2) Choose the correct answer from the options given
1000  M below :
Sol. Molality =
1000  d  M  (Mw)solute (1) A-I, B-II, C-III, D-IV
1000  x (2) A-III, B-II, C-IV, D-I
3= (3) A-III, B-I, C-IV, D-II
1000  1.12  (x  40)
(4) A-II, B-IV, C-I, D-III
x=3 Ans. (3)
5
Sol. Iodoform – Antiseptic Sol. HX  H+ + X– Ka = 1.2 × 10–5
CCl4 – Fire extinguisher 0.03M
CFC – Refrigerants 0.03 – x x x
x2
DDT – Insecticide Ka = 1.2 × 10–5 =
0.03  x
80. A conductivity cell with two electrodes (dark side)
0.03 – x  0.03 (Ka is very small)
are half filled with infinitely dilute aqueous solution x2
= 1.2 × 10–5
of a weak electrolyte. If volume is doubled by 0.03
adding more water at constant temperature, the x = 6 × 10–4
Final solution : 0.03 – x + x + x
molar conductivity of the cell will - = 0.03 + x = 0.03 + 6 × 10–4
 = (0.03 + (6 × 10–4)) × 0.083 × 300
(–)
= 76.19 × 10–2  76 × 10–2
(+)
®
1cm 82. The difference in the 'spin-only' magnetic moment
values of KMnO4 and the manganese product
1cm formed during titration of KMnO4 against oxalic
1cm acid in acidic medium is _____ BM. (nearest
integer)
(1) increase sharply Ans. (6)
(2) remain same or can not be measured accurately Sol. Spin only magnetic moment of Mn in KMnO4 = 0
Spin only value of manganese product fromed
(3) decrease sharply
during titration of KMnO4 aganist oxalic acid in
(4) depend upon type of electrolyte acidic medium is = 6
Ans. (2) Ans. 6
83. Time required for 99.9% completion of a first
Sol. Solution is already infinitely dilute, hence no
order reaction is _____ time the time required for
change in molar conductivity upon addition of completion of 90% reaction.(nearest integer).
water Ans. (3)
1  100  1  100 
Sol. K= n  n
t 99.9%  0.1  t 90%  10 

SECTION-B
n(103 )
81. Consider the dissociation of the weak acid HX as t99.9% = t90%
n10
given below t99.9% = t90% × 3
HX(aq) H+(aq) + X– (aq), Ka = 1.2 × 10–5
84. Number of molecules from the following which
[Ka : dissociation constant] can exhibit hydrogen bonding is ______. (nearest
The osmotic pressure of 0.03 M aqueous solution integer)
NO2
of HX at 300 K is _____ × 10–2 bar (nearest CH3OH, H2O, C2H6, C6H6, HF, NH3
integer). OH
[Given : R = 0.083 L bar Mol–1 K–1] Ans. (5)
NO2
Sol. CH3OH, H2O, HF, NH3
Ans. (76) OH
Can show H–bonding.
6
85. 9.3 g of pure aniline upon diazotisation followed 87. Frequency of the de-Broglie wave of election in
by coupling with phenol gives an orange dye. The Bohr's first orbit of hydrogen atom is ____ × 1013 Hz
mass of orange dye produced (assume 100% (nearest integer).
[Given : RH (Rydberg constant) = 2.18 × 10–18 J.
yield/ conversion) is ________g. (nearest integer)
h (Plank's constant) = 6.6 × 10–34 J.s.]
Ans. (20)
Allen Ans. (661)
NH2 +
N2 Cl NTA Ans. (658)
h
NaNO2 + HCl Sol. =
mv
Sol. T < 5°C
hv
=
OH mv 2
mv 2 v
   (frequency)
h 
®
1
Given mv2 = 2.18 × 10–18 J
2
N=N
h = 6.6 × 10–34
HO 4.36  10 18
= = 660.60 × 1013 Hz
Orange dye 6.6  10 34
Reaction suggests that 1 mole of aniline give 1  661 × 1013 Hz
mole of orange dye.

88. The major products from the following reaction
so (mol)aniline = (mole)orange dye
sequence are product A and product B.
9.3g mass of orange dye
1
 B
(i) Br2 (i) Br2
A
93g mol 199g mol 1 (ii) alc. KOH (3 eq.) (ii) O– Na+ (1.0 eq.)
mass of orange dye = 19.9 g 20 g The total sum of  electrons in product A and
product B are ______ (nearest integer)
86. The major product of the following reaction is P. Ans. (8)
CH3C  C – CH3   'P'

(i)Na/liq.NH3
(ii)dil.KMnO4 Br
273K Br2
Sol.
Number of oxygen atoms present in product 'P' is Br
_______ (nearest integer). +
HCC–CH2–O Na
Ans. (2)
Br
Sol. CH3 – C  C–CH3 
Na /liq.NH 3
 CH3 H
C=C
H CH3 O–CH2–CCH
(A)
dil. KMnO4
H H Br
alc KOH
CH3 C C CH3 (3 eq)
OH OH Br (B)
(Product P)
7
89. Among CrO, Cr2O3 and CrO3, the sum of spin-only 5
90. An ideal gas, CV  R , is expanded adiabatically
2
magnetic moment values of basic and amphoteric
against a constant pressure of 1 atm untill it
–2
oxides is ______ 10 BM (nearest integer). doubles in volume. If the initial temperature and
pressure is 298 K and 5 atm, respectively then the
(Given atomic number of Cr is 24)
final temperature is ______ K (nearest integer).
Ans. (877) [ CV is the molar heat capacity at constant volume]
Ans. (274)
Sol. CrO Basic oxide
Sol. U = q + w (q = 0)
Cr2O3 Amphoteric oxide nCVT = –Pext (V2 – V1)
V2 = 2V1
In CrO, Cr exist as Cr+2 and have  only = 4.90
nRT2 2nRT1

In Cr2O3, Cr exist as Cr+3 and have  only = 3.87 P2 P1
®
P1 = 5, T1 = 298
Sum of spin only magnetic moment
5T2
P2 =
= 4.90 + 3.87 = 8.77 2  298
5  nRT2 nRT1 
only = 877 × 10–2 n R(T2 – T1) = – 1   
2  P1 P1 
Ans. 877 Put T1 = 298
5T2
and P2 =
2  298
Solve and we get T2 = 274.16 K
T2  274 K
8
(Held On Saturday 06th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A Sol. Direct NCERT Based
CH3 OCH3 CF3 Cl
61. CH3
64. + NaOH
(I) (II) (III) (IV)
The correct arrangement for decreasing order of Consider the above chemical reaction. Product "A" is:
(1) CH3 (2) CH3
electrophilic substitution for above compounds
(1) (IV) > (I) > (II) > (III) OH
OH
(2) (III) > (I) > (II) > (IV) OH
®
(3) (II) > (IV) > (III) > (I) CH3
(3) CH3 (4)
(4) (III) > (IV) > (II) > (I)
Ans. (2)
Sol. OH
OMe(+M) CH3(+H/+I) CF3(–I)
Ans. (2)
> > > Sol.
Cl
+ CH3
62. Molality (m) of 3 M aqueous solution of NaCl is: CH3

NaOH/H 2O

(Given : Density of solution = 1.25 g mL–1, Molar S 1
N H
mass in g mol–1 : Na-23, Cl-35.5)
(1) 2.90 m (2) 2.79 m 1,2–(H–shift)
(3) 1.90 m (4) 3.85 m
 CH3
Ans. (2)
Sol. 3 moles are present in 1 litre solution
3  1000
molality = = 2.79 m CH3
1.25  1000  [3  58.5]
OH
63. The incorrect statements regarding enzymes are:
(A) Enzymes are biocatalysts. (Major Product )
(B) Enzymes are non-specific and can catalyse
different kinds of reactions.
(C) Most Enzymes are globular proteins. 65. During the detection of acidic radical present in a
(D) Enzyme - oxidase catalyses the hydrolysis of salt, a student gets a pale yellow precipitate soluble
maltose into glucose. with difficulty in NH4OH solution when sodium
Choose the correct answer from the option given carbonate extract was first acidified with dil. HNO3
and then AgNO3 solution was added. This
below:
indicates presence of:
(1) (B) and (C) (2) (B), (C) and (D) 2
(1) Br– (2) CO3
(3) (B) and (D) (4) (A), (B) and (C)
(3) I– (4) Cl–
Ans. (3) Ans. (1)
1
Sol. Ag+ + I–  AgI Yellow ppt. 69. The major products formed:
+ –
Ag + Cl  AgCl White ppt OCH3
+ –
Ag + Br  AgBr Pale yellow ppt
66. How can an electrochemical cell be converted into 
HNO3 ,H2SO4
 'A' 
Br2 (excess)
Fe
 'B'
an electrolytic cell ?
(1) Applying an external opposite potential greater
0
than E cell A and B respectively are:
(2) Reversing the flow of ions in salt bridge. OCH3 OCH3
NO2 Br NO2
(3) Applying an external opposite potential lower
0 (1) and
than E .
cell
(4) Exchanging the electrodes at anode and

cathode. Br
Ans. (1)
Sol. Applied external potential should be greater than OCH3 OCH3
E 0cell in opposite direction. Br
®
Br
and
67. Arrange the following elements in the increasing (2)
order of number of unpaired electrons in it.
(A) Sc (B) Cr
NO2 NO2
(C) V (D) Ti
(E) Mn
Choose the correct answer from the options given OCH3 OCH3
below: NO2 NO2
(1) (C) < (E) < (B) < (A) < (D) (3) and
(2) (B) < (C) < (D) < (E) < (A)
(3) (A) < (D) < (C) < (B) < (E)
(4) (A) < (D) < (C) < (E) < (B) Br
Ans. (4)
Sol. Unpaired electron OCH3 OCH3
Sc[Ar] 4s2 3d1 1
Br
Cr[Ar] 4s1 3d5 6 and
V[Ar] 4s2 3d3 3 (4)
Ti : [Ar] 4s2 3d2 2
Mn : [Ar] 4s2 3d5 5 NO2 NO2
68. Match List-I with List-II.
List-I List-II
Alkali Metal Emission Wavelength Ans. (2)
in nm OMe OMe
(A) Li (I) 589.2 Sol.
(B) Na (II) 455.5 HNO3–H2SO4
(C) Rb (III) 670.8
(D) Cs (IV) 780.0 NO2 (A)
below: OMe OMe
(1) (A)-(I), (B)-(IV), (C)-(III), (D)-(II) Br Br
(2) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) Br2 (Excess)
(3) (A)-(IV), (B)-(II), (C)-(I), (D)-(III) Fe
(4) (A)-(II), (B)-(IV), (C)-(III), (D)-(I) NO2 NO2 (B)
Ans. (2)
Sol. Fact Based
2
70. The incorrect statement regarding the geometrical 73. Identify the product A in the following reaction.
isomers of 2-butene is: NH2
(1) cis-2-butene and trans-2-butene are not A
interconvertible at room temperature.
(2) cis-2-butene has less dipole moment than
trans-2-butene. NH2
OH
(3) trans-2-butene is more stable than cis-2-butene.
(4) cis-2-butene and trans-2-butene are stereoisomers. (1) (2)
Ans. (2)
OH
Sol. CH3 CH3 H CH3
C=C C=C
H H
NH2 Cl
CH3 H
Cis–but–2–ene Trans–but–2–ene
(Polar) (Non Polar) (3) (4)
®
Cis–but–2–ene has higher Dipole moment than Cl OH
trans–but–2–ene.
71. Given below are two statements: Ans. (2)
Statement I: PF5 and BrF5 both exhibit sp3d NH2
+ –
N2Cl
hybridisation. Sol. NaNO2+HCl Cu2Cl2
Statement II: Both SF6 and [Co(NH3)6]3+ exhibit
sp3d2 hybridisation.
NO2
correct answer from the options given below: Cl OH
NaOH, 623K, 300 atm
H+
(3) Both Statement I and Statement II are false
(A)
(4) Statement I is false but Statement II is true
Ans. (3) 74. The correct statements among the following, for a
Sol. "chromatography" purification method is:
Hybridisation Hybridisation
3
(1) Organic compounds run faster than solvent in
PF5 sp d SF6 sp3d2
the thin layer chromatographic plate.
BrF5 sp3d2 [Co(NH3)6]+3 d2sp3
Both Statement (1) and (2) are false. (2) Non-polar compounds are retained at top and
72. The number of ions from the following that are polar compounds come down in column
expected to behave as oxidising agent is: chromatography.
Sn4+, Sn2+, Pb2+, Tl3+, Pb4+, Tl+ (3) Rf of a polar compound is smaller than that of a
(1) 3 (2) 4
non-polar compound.
(3) 1 (4) 2
(4) Rf is an integral value.
Ans. (4)
Ans. (3)
Sol. Due to inert pair effect; T+3 and Pb+4 can behave
Sol. Non polar compounds are having higher value of
as oxidising agents.
Rf than polar compound.
3
75. Evaluate the following statements related to group 77. Consider the given reaction, identify the major
14 elements for their correctness. product P.
(A) Covalent radius decreases down the group
4 (i) LiAlH (ii) PCC (iii) HCN/OH
from C to Pb in a regular manner. CH 3  COOH  "P"
(iv) H2O/OH,
(B) Electronegativity decreases from C to Pb down
the group gradually. (1) CH3 – CH2 – CH2 – OH
(C) Maximum covalence of C is 4 whereas other O
elements can expand their covalence due to
presence of d orbitals. (2) CH3 — CH2 — C — NH2
(D) Heavier elements do not form p-p bonds.
(E) Carbon can exhibit negative oxidation states. O
(3) CH3 — C — CH2CH3
below:
(1) (C), (D) and (E) Only (2) (A) and (B) Only
(3) (A), (B) and (C) Only (4) (C) and (D) Only OH
®
Ans. (1)
(4) CH3 — CH —COOH
Sol. (A) Down the group; radius increases
(B) EN does not decrease gradually from C to Pb.
(C) Correct. Ans. (4)
(D) Correct. Sol. CH3 COOH
LiAlH4
CH3–CH2–OH
(E) Range of oxidation state of carbon ; –4 to +4
PCC
76. Match List-I with the List-II O
List-I List-II
CH3–C–H
Reaction Type of redox reaction
HCN/OH
(A) N2(g) + O2(g)  2NO(g) (I) Decomposition
(B) 2Pb(NO3)2(s) (II) Displacement OH
 2PbO(s) + 4NO2(g) + O2(g) CH3—C—CN
(C) 2Na(s) + 2H2O(l) (III) Disproportionation H
 2NaOH(aq.) + H2(g)
H2O/OH , 
(D) 2NO2(g) + 2–OH(aq.) (IV) Combination
 
 NO2(aq.)  NO3(aq.)  H 2O(l) CH3—CH—COOH
Choose the correct answer from the options given OH
below:
78. The correct IUPAC name of [PtBr2(PMe3)2] is:
(1) (A)-(I), (B)-(II), (C)-(III), (D)-(IV)
(1) bis(trimethylphosphine)dibromoplatinum(II)
(2) (A)-(III), (B)-(II), (C)-(I), (D)-(IV)
(2) bis[bromo(trimethylphosphine)]platinum(II)
(3) (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
(3) dibromobis(trimethylphosphine)platinum(II)
(4) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
(4) dibromodi(trimethylphosphine)platinum(II)
Ans. (4)
Ans. (3)
Sol. A  (IV)
Sol. Dibromo bis(trimethylphosphine) platinum (II)
B  (I)
C  (II)
D  (III)
4
79. Match List-I with List-II SECTION-B
List-I List-II 81. An amine (X) is prepared by ammonolysis of
Tetrahedral Complex Electronic configuration
2 0 benzyl chloride. On adding p-toluenesulphonyl
(A) TiCl4 (I) e , t 2
4 3 chloride to it the solution remains clear. Molar
(B) [FeO4]2– (II) e , t 2
0 0 mass of the amine (X) formed is______ g mol–1.
(C) [FeCl4] –
(III) e , t 2
2 3 (Given molar mass in gmol–1 C : 12, H : 1, O : 16, N : 14)
(D) [CoCl4]2– (IV) e , t 2
Choose the correct answer from the option given Ans. (287)
below: Sol. CH2Cl
(1) (A)-(I), (B)-(III), (C)-(IV), (D)-(II) NH3
PhCH2 –N–CH2Ph
(2) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
(3) (A)-(III), (B)-(IV), (C)-(II), (D)-(I) (excess) CH2Ph
(4) (A)-(III), (B)-(I), (C)-(IV), (D)-(II) (X) (3° amine)
Ans. (4) Molar Mass of (X) is 287 g mol–1
®
0
TiC4  t20 82. Consider the following reactions
e0 NiS + HNO3 + HCl  A + NO + S + H2O
VI
FeO42–  A + NH4OH + H3C – C = N – OH
t20 B + NH4Cl + H2O
H3C – C = N – OH
e2
III The number of protons that do not involve in
FeC41–  t23
hydrogen bonding in the product B is______.
2
e Ans. (12)
II H
CoC42–  t23 O O
e4 H3C N N CH3
Sol.
C C
KP Sol. B  Ni
80. The ratio for the reaction: C
KC N N=C
1 H3C CH3
CO(g)  O 2(g) CO 2(g) is: O O
2
1/2 H
(1) (RT) (2) RT
1 3NiS + 2HNO3 + 6HCl
(3) 1 (4)
RT  3NiCl2 + 2NO + 3S + 4H2O
Ans. (4) H3C – C = N – OH
1 NiCl2 + 2NH4OH +
Sol. CO(g) + O2(g) CO2(g)
2 H3C – C = N – OH
 1 1
ng = 1 –  1   =   NH4Cl + H2O + (B)
 2 2
KP n 1
 (RT) g 
KC RT
5
83. When 'x' × 10–2 mL methanol (molar mass = 32 g; 85. Number of carbocation from the following that are
density = 0.792 g/cm3) is added to 100 mL
not stabilized by hyperconjugation is……….. .
water (density = 1 g/cm3), the following diagram is
obtained.  +
+ CH3
, (tert.-Butyl) (tert.-Butyl)'
Vapour pressure
+
+
, CH2 – OCH3 ,
+
+
N – CH2
270.65 273.15
Temperature/K  Ans. (5)
x =………………(nearest integer)
[Given: Molal freezing point depression constant Sol. +
C
of water at 273.15 K is 1.86 K kg mol–1]
®
+ + +
Ans. (543) CH3 CH2–O–CH3
Sol. Tf = 273.15 – 270.65 = 2.5 K
n
Tf = Kf m  2.5 = 1.86 ×
0.1 +
N–CH2
 n = 0.1344 moles
 w = 0.1344 × 32 = 4.3 g
4.3 86. For the reaction at 298 K, 2A + B  C. H
Volume = = 5.43 ml = 543 × 10–2 ml
0.792
OC2H5
= 400 kJ mol–1 and S = 0.2 kJ mol–1 K–1. The
reaction will become spontaneous above______ K.

84. 
HNO3 ,H 2SO 4
 P 
2Br2 ,Fe
Q
major
product
major Ans. (2000)
product
Sol. G = 0
The ratio of number of oxygen atoms to bromine
atoms in the product Q is_____ × 10–1. H 400
Ans. (15) T=  = 2000 K
S 0.2
OC2H5 OC2H5
Sol.
87. Total number of species from the following with
HNO3+H2SO4
central atom utilising 2p2 hybrid orbitals for

NO2
bonding is…………. .
2Br2–Fe
NH3, SO2, SiO2, BeCl2, C2H2, C2H4, BCl3, HCHO,
OC2H5 C6H6, BF3, C2H4Cl2

Br Br
Ans. (6)
NO2
Sol. Central atom utilising sp2 hybrid orbitals
SO2, C2H4, BCl3, HCHO, C6H6, BF3
6
88. Consider the two different first order reactions 89. For hydrogen atom, energy of an electron in first
given below
excited state is – 3.4 eV, K.E. of the same electron
A + B  C (Reaction 1)
P  Q (Reaction 2) of hydrogen atom is x eV. Value of x is______
The ratio of the half life of Reaction 1 : Reaction 2
is 5 : 2. If t1 and t2 represent the time taken to × 10–1 eV. (Nearest integer)
rd th
complete 2 and 4 of Reaction 1 and Ans. (34)
3 5
  2
Reaction 2, respectively, then the value of the ratio 90. Among VO2 , MnO 4 and Cr2O7 , the spin-only
t1 : t2 is________× 10–1 (nearest integer).
[Given: log10(3) = 0.477 and log10(5) = 0.699] magnetic moment value of the species with least
Ans. (17) oxidising ability is……………….BM (Nearest
(t1/2 ) I K 2 5
Sol.   integer).
(t1/2 ) II K1 2
1 (Given atomic member V = 23, Mn = 25, Cr = 24)
 K1t1 = n = n3
2 Ans. (0)
1
®
3
1 Sol. For 3d transition series;
K2t2 = n = n5
4 Oxidising power : V+5 < Cr+6 < Mn+7
1
5 V+5 : [Ar] 4s0 3d0
K1 t1 0.477
   Number of unpaired electron = 0
K 2 t 2 0.699
t1 0.477 5 0
   = 1.7 = 17 × 10–1
t 2 0.699 2
7
(Held On Monday 08th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A 62. Which among the following compounds will
61. Given below are two statements: undergo fastest SN2 reaction.
Cl
Statement I : (1)
O2N NO2 Br
Compound-A
IUPAC name of Compound A is 4-chloro-1, (2) Br

3-dinitrobenzene:
NH2
CH3 (3) Br
®
Statement II:
C2H5 (4) Br
Compound-B
IUPAC name of Compound B is Ans. (3)

4-ethyl-2-methylaniline.
In the light of the above statements, choose the Sol. 1 2 Br
Br
most appropriate answer from the options given
below:
(1) Both Statement I and Statement II are correct 3 Br 4 Br
correct 1°
2
(3) Statement I is correct but Statement II is fastest SN reaction give Br
incorrect
(4) Both Statement I and Statement II are incorrect Rate of SN2 is Me – x > 1° – x > 2° – x > 3° – x
Ans. (2) 63. Combustion of glucose (C6H12O6) produces CO2
6
Cl and water. The amount of oxygen (in g) required
Sol. Statement I : 5 1
O2N 4 2 NO2 for the complete combustion of 900 g of glucose is:
3
[Molar mass of glucose in g mol–1 = 180]
IUPAC name
(1) 480 (2) 960
 1-chloro-2, 4-dinitrobenzene
(3) 800 (4) 32
 statement-I is incorrect
Ans. (2)
NH
1
2 CH3 Sol. C6H12O6(s) + 6O2(g)  6CO2(g) + 6H2O()
6
Statement-II :
3
5
4 900
C2H5 180
  4-ethyl-2-methylaniline = 5 mol 30 mol

 statement-II is correct Mass of O2 required = 30 × 32 = 960 gm
1
64. Identify the major products A and B respectively in Sol. The relative stability of +1 oxidation state
the following set of reactions. progressively increases for heavier elements due to
CH3 inert pair effect.
CH3COCl Conc. H2SO4
B OH A
Pyridine  Stability of A+1 < Ga+1 < In+1 < T+1
CH3 CH3
66. Match List I with List-II
(1) A= and B= OCOCH3
List-I List-II
CH3 CH3 (Name of the test) (Reaction sequence involved)
(2) A= and B= OH
[M is metal]
CH3CO
A Borax bead I. MCO3 MO
CH2 CH3
(3) A= and B= COCH3 test Co(NO3 )2


CoO. MO
B. Charcoal II. MCO3  MCl2  M2+
®
CH2 CH3
(4) A= and B= OH cavity test
COCH3
C. Cobalt nitrate III MSO Na2B4O7
Ans. (1) 4
test 
CH3 CH3 M(BO2)2  MBO2  M
CH3COCl
Sol. OCOCH3 OH
pyridine D. Flame test IV MSO Na2CO3
(Acetylation) 4 MCO3 
(B) 
CH3 MO  M
Conc. H2SO4
 + H2O
Choose the correct answer from the option below :
E1 Reaction (A)
65. Given below are two statements : One is labelled as (2) A-III, B-II, C-IV, D-I
Assertion A and the other is labelled as Reason R: (3) A-III, B-I, C-II, D-IV
Assertion A : The stability order of +1 oxidation
state of Ga, In and Tl is Ga < In < Tl.
Ans. (4)
Reason R : The inert pair effect stabilizes the
Sol. Cobalt nitrate test
lower oxidation state down the group.
Co(NO3 )2
In the light of the above statements, choose the MCO3 MO 
 CoO. MO
correct answer from the options given below :
Flame test
(1) Both A and R are true and R is the correct
MCO3  MCl2  M2+
explanation of A.
Borax Bead test
(2) A is true but R is false.
(3) Both A and R are true but R is NOT the correct MSO4 Na2B4O7 M(BO2)2  MBO2  M

explanation of A.
Charcoal cavity test
(4) A is false but R is true.
Ans. (1) MSO4 Na2CO3 MCO3  MO  M

2
67. Match List I and with List II 69. Thiosulphate reacts differently with iodine and
List-I (Molecule) List-II(Shape) bromine in the reaction given below :
A NH3 I. Square pyramid
2S2 O32  I 2  S4 O62  2I¯
B. BrF5 II. Tetrahedral
C. PCl5 III Trigonal pyramidal S2 O32   5Br2  5H 2 O  2SO24  4Br¯ 10H 
D. CH4 IV Trigonal bipyramidal Which of the following statement justifies the
Choose the correct answer from the option below : above dual behaviour of thiosulphate?
(1) A-IV, B-III, C-I, D-II
(1) Bromine undergoes oxidation and iodine
(2) A-II, B-IV, C-I, D-III
undergoes reduction by iodine in these
(4) A-III, B-IV, C-I, D-II reactions
Ans. (3) (2) Thiosulphate undergoes oxidation by bromine
and reduction by iodine in these reaction
F F
®
Sol. N Br (3) Bromine is a stronger oxidant than iodine
H H F F (4) Bromine is a weaker oxidant than iodine
H F
Trigonal pyramidal Square pyramidal Ans. (3)
H Sol. In the reaction of S2O32– with I2, oxidation state of

Cl
Cl sulphur changes to +2 to +2.5
Cl P C
In the reaction of S2O32– with Br2, oxidation state
H H
Cl H
Cl of sulphur changes from +2 to +6.
Trigonal bipyramidal Tetrahedral  Both I2 and Br2 are oxidant (oxidising agent)
68. For the given hypothetical reactions, the and Br2 is stronger oxidant than I2.
equilibrium constants are as follows:
70. An octahedral complex with the formula
X Y ; K1 = 1.0
CoCl3nNH3 upon reaction with excess of AgNO3
Y Z ; K2 = 2.0 solution given 2 moles of AgCl. Consider the
Z W ; K3 = 4.0 oxidation state of Co in the complex is 'x'. The
The equilibrium constant for the reaction value of "x + n" is _____.
X W is (1) 3 (2) 6
(1) 6.0 (2) 12.0 (3) 8 (4) 5
(3) 8.0 (4) 7.0 Ans. (3)
Ans. (3) 3
Sol. X Y k1 = 1 Sol. Co(NH3 )5 Cl  Cl2 + excess AgNO3  2AgCl
Y Z k2 = 2 (2 moles)
x+0–1–2=0
Z  k3 = 4
x = +3
X  k1  k2  k3
n=5
k=1×2×4
 x+n=8
k=8
3
CHO 73. Which of the following are aromatic?
H OH
HO H A.
71. H OH
H OH
CH2OH B.
The incorrect statement regarding the given
structure is C.
(1) Can be oxidized to a dicarboxylic acid with Br2
water
(2) despite the presence of – CHO does not give D.
Schiff's test
(3) has 4-asymmetric carbon atom
(4) will coexist in equilibrium with 2 other cyclic (1) B and D only
structure (2) A and C only
®
Ans. (1) (3) A and B only
Sol. (4) C and D only
CHO COOH Ans. (1)
(1) H * OH H OH
HO * H Br2 HO H Sol.
H * OH H2O H OH A. Non aromatic
H * OH H OH
CH2OH CH2–OH
B. Aromatic
statement 1 is incorrect (monocarboxylic acid)
(2) correct
(3) c.c. is 4 (correct) C. Non aromatic
CH2–OH CHO CH2–OH
H–C–OH
H H H OH
H HO–C–H H
(4) OH H H–C–OH OH H D. Aromatic
HO OH HO H
H–C–OH
H OH H OH
-D-glucose CH2OH -D-glucose (correct)
72. In the given compound, the number of 2° carbon 74. Among the following halogens
atom/s is _____. F2, Cl2, Br2 and I2
CH3–C(CH3)–CH–C(CH3)–CH3 Which can undergo disproportionation reaction?
H H H (1) Only I2
(1) Three (2) One (2) Cl2, Br2 and I2
(3) Two (4) Four (3) F2, Cl2 and Br2
Ans. (2) (4) F2 and Cl2
1° 1°
CH3 CH3 Ans. (2)
Sol. 1° 2° 1°
CH3 – C – CH –C – CH3 Sol. F2 do not disproportionate because fluorine
3° 3°
H H H do not exist in positive oxidation state however
only one 2° carbon is present in this compound. Cl2, Br2 & I2 undergoes disproportionation.
4
75. Given below are two statements: 77. Iron (III) catalyses the reaction between iodide and
Statement I : N(CH3)3 and P(CH3)3 can act as persulphate ions, in which
ligands to form transition metal complexes. A. Fe3+ oxidises the iodide ion
Statement II: As N and P are from same group, the B. Fe3+ oxidises the persulphate ion
nature of bonding of N(CH3)3 and P(CH3)3 is always C. Fe2+ reduces the iodide ion
same with transition metals.
D. Fe2+ reduces the persulphate ion
Choose the most appropriate answer from the
most appropriate answer from the options given
below: options given below:
(1) Statement I is incorrect but Statement II is (1) B and C only (2) B only
correct (3) A only (4) A and D only
(2) Both Statement I and Statement II are correct Ans. (4)
(3) Statement I is correct but Statement II is Sol. 2Fe3+ + 2I–  2Fe2+ + I2
incorrect
(4) Both Statement I and Statement II are incorrect 2Fe2+ + S2O82–  2Fe3+ + 2SO42–
®
Ans. (3) Fe+3 oxidises I– to I2 and convert itself into Fe+2.
Sol. N(CH3)3 and P(CH3)3 both are Lewis base and acts This Fe+2 reduces S2O82– to SO42– and converts
as ligand, However, P(CH3)3 has a -acceptor itself into Fe+3.
character. 78. Match List I with List II
76. Match List I with List II List-I (Compound) List-II
List-I (Elements) List-II(Properties in
(Colour)
their respective groups)
A Fe4[Fe(CN)6]3.xH2O I. Violet
A Cl,S I. Elements with highest
electronegativity B. [Fe(CN)5NOS]4– II. Blood Red
2+
B. Ge, As II. Elements with largest C. [Fe(SCN)] III. Prussian Blue
atomic size D. (NH4)3PO4.12MoO3 IV. Yellow
C. Fr, Ra III Elements which show Choose the correct answer from the options given
properties of both below :
metals and non metal (1) A-III, B-I, C-II, D-IV
D. F, O IV Elements with highest (2) A-IV, B-I, C-II, D-III
negative electron gain
(3) A-II, B-III, C-IV, D-I
enthalpy
(4) A-I, B-II, C-III, D-IV
below : Ans. (1)
(1) A-II, B-III, C-IV, D-I Sol. Fe4[Fe(CN)6]3 .xH2O  Prussian Blue
(2) A-III, B-II, C-I, D-IV [Fe(CN)5NOS]4– Violet
(3) A-IV, B-III, C-II, D-I [Fe(SCN)]2+ Blood Red
(4) A-II, B-I, C-IV, D-III
(NH4)3PO4.12MoO3  Yellow
Ans. (3)
79. Number of complexes with even number of
Sol. Elements with highest electronegativity F, O
electrons in t2g orbitals is -
Elements with largest atomic size Fr, Ra [Fe(H2O)6]2+, [Co(H2O)6]2+, [Co(H2O)6]3+,
Elements which shows properties of both metal [Cu(H2O)6]2+, [Cr(H2O)6]2+
and non-metals i.e. metalloids Ge, As (1) 1 (2) 3
Elements with highest negative electron gain (3) 2 (4) 5
enthalpy Cl, S Ans. (2)
5
eg SECTION-B
81. A hypothetical electromagnetic wave is show
Sol. [Fe(H2O)6]2+ Fe+2d6
t2g below.
Electron in t2g = 4(even)
eg
+2
Co d 7 1.5pm
[Co(H2O)6]2+
t2g The frequency of the wave is x × 1019 Hz.
x = ______ (nearest integer)
Electron in t2g = 5(odd)
Ans. (5)
eg Sol.  = 1.5 × 4 pm
+3 6
[Co(H2O)6] 3+ Co d = 6 × 10–12 meter
t2g
 = C
®
Electron in t2g = 6(even) 6 × 10–12 × = 3 × 108
 = 5 × 1019 Hz
eg
+2 9
[Cu(H2O)6] 2+ Cu d
B
t2g 82.
90L
Electron in t2g = 6(even)
A
eg 10L
[Cr(H2O)6]2+ Cr+2d4
Consider the figure provided.
t2g
1 mol of an ideal gas is kept in a cylinder, fitted
Electron in t2g = 3(odd) with a piston, at the position A, at 18°C. If the
80. Identify the product (P) in the following reaction: piston is moved to position B, keeping the
COOH i) Br2/Red P temperature unchanged, then 'x' L atm work is
(P) done in this reversible process.
ii) H2O
x = ______ L atm. (nearest integer)
COOH COBr [Given : Absolute temperature = °C + 273.15,
(1) Br (2)
R = 0.08206 L atm mol–1 K–1]
COOH Ans. (55)

(3) CHO (4) V 
Br Br Sol.  = –nRT ln  2 
 V1 
Ans. (1)
 100 
= –1 × 08206 × 29115 ln  
Sol. HVZ Reaction  10 
COOH i) Br2/Red P COOH = –55.0128
Br Work done by system  55 atm lit.
ii) H2O
6
83. Number of amine compounds from the following 86. Number of molecules from the following which
giving solids which are soluble in NaOH upon are exceptions to octet rule is _____.
CO2, NO2, H2SO4, BF3, CH4, SiF4, ClO2, PCl5,
reaction with Hinsberg's reagent is _____.
BeF2, C2H6, CHCl3, CBr4
O O
NH2
Ans. (6)
NH2 , H2NNH–C–NH2 NH–CH3
O
O Sol.
N NH2 NH2 O=C=O S
NH2 H2N–C–NH2 N
H complete HO OH
OCH3 O O O
1 octet exception to
N N NH2 exception to
octet rule octet rule
F H F
Ans. (5)
B C Si
Sol. Primary amine give an ionic solid upon reaction F F H H F F
with Hinsberg reagent which is soluble in NaOH. exception to H F
octet rule complete complete
NH2 NH octet octet
®
OCH3 Cl
H Cl
NH2 Cl P
N Cl Cl
NH2 F—Be—F
NH2 O O Cl
exception exception to exception to
84. The number of optical isomers in following to octet rule octet rule octet rule
compound is : _____. H Br
H H
CH3 H—C—C—H C C
Br Cl Cl Br Br
H H
Cl Br
complete
octet complete complete
octet octet
Ans. (32)
87. If 279 g of aniline is reacted with one equivalent of
CH3
Br benzenediazonium chloride, the mximum amount
Sol. * * of aniline yellow formed will be _____ g. (nearest
*
integer)
* *
(consider complete conversion)
Total chiral centre = 5 Ans. (591)
No. of optical isomers = 25 = 32. NH2
NH2 N2+Cl¯
85. The 'spin only' magnetic moment value of MO42– is
Sol. ESR
____ BM. (Where M is a metal having least +
metallic radii. among Sc, Ti, V, Cr, Mn and Zn). N
m.wt.=93
(Given atomic number : Sc = 21, Ti = 22, V = 23, N yellow dye
given wt.=279gm
Cr = 24, Mn = 25 and Zn = 30)
moles = 279
Ans. (0) =3
93
Sol. Metal having least metallic radii among Sc, Ti, V, moles formed =3
Cr, Mn & Zn is Cr. m.wt. = 197
Spin only magnetic moment of CrO42–. amount formed
=197 × 3 = 591 gm
Here Cr+6 is in d0 configuration (diamagnetic).
7
88. Consider the following reaction 90. A solution containing 10g of an electrolyte AB2 in
A+BC 100g of water boils at 100.52°C. The degree of
th
The time taken for A to become 1/4 of its initial ionization of the electrolyte () is _____ × 10–1.
concentration is twice the time taken to become 1/2 (nearest integer)
of the same. Also, when the change of [Given : Molar mass of AB2 = 200g mol–1. Kb
concentration of B is plotted against time, the (molal boiling point elevation const. of water)
resulting graph gives a straight line with a negative = 0.52 K kg mol–1, boiling point of water = 100°C ;
slope and a positive intercept on the concentration AB2 ionises as AB2  A2+ + 2B¯]
axis.
Ans. (5)
The overall order of the reaction is ____.
Sol. AB2  A+2 + 2B
Ans. (1)
Sol. For 1st order reaction i = 1 + (3 – 1) 
®
75% life = 2 × 50% life i = 1 + 2
So order with respect to A will be first order. Tb = kb im
[B] 10
0.52 = 0.52 (1 + 2) 200
100
1000
t 10
1 = (1 + 2)
20
So order with respect to B will be zero.
2 = 1 + 2
Overall order of reaction = 1 + 0 = 1
89. Major product B of the following reaction has  = 0.5
____ -bond. Ans.  = 5 × 10–1
CH2CH3
KMnO4–KOH HNO3/H2SO4
(A) (B)

Ans. (5)
Sol. Major product B is 
O O
CH2CH3 C–OK C–OH
KMnO4–KOH HNO3
 H2SO4
(A) N=O
(B)
O
Total number of  bonds in B are 5
8
(Held On Monday 08th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A Sol. Antibonding molecular orbitals are formed by
61. In qualitative test for identification of presence of destructive interference of wave functions.
(ABMO) * = A – B
phosphorous, the compound is heated with an
oxidising agent. Which is further treated with nitric 64. Which one the following compounds will readily
acid and ammonium molybdate respectively. The react with dilute NaOH?
yellow coloured precipitate obtained is : (1) C6H5CH2OH (2) C2H5OH

(3) (CH3)3COH (4) C6H5OH
(1) Na 3 PO4 .12MoO3
Ans. (4)
(2)  NH 4 3 PO 4 .12  NH 4 2 MoO 4
®
OH O¯Na+
(3)  NH 4 3 PO 4 .12MoO3
Sol. + NaOH + H2O
(4) MoPO4 .21NH4 NO3
Ans. (3) Stronger ACID than H2O
+
H
Sol. PO43– + (NH4)2MoO4 (NH4)3PO4.12MoO3  65. The shape of carbocation is :
Or HPO4– Ammonium Canary yellow ppt.
Molybdate (Ammonium phopho (1) trigonal planar (2) diagonal pyramidal
molybdate) (3) tetrahedral (4) diagonal
62. For a reaction A  B C
K1 K2
Ans. (1)
If the rate of formation of B is set to be zero then H
the concentration of B is given by : Sol. Carbocation C
(1) K1K2[A] (2) (K1 – K2)[A] H H
Trigonal planar
(3) (K1 + K2)[A] (4) (K1/K2)[A]
66. Given below are two statements :
Ans. (4)
Statement (I) : SN2 reactions are 'stereospecific',
Sol. Rate of formation of B is indicating that they result in the formation only one
d  B stereo-isomers as the product.
 k1  A   k 2  B
dt Statement (II) : SN1 reactions generally result in
0 = k1[A] – k2[B] formation of product as racemic mixtures. In the
light of the above statements, choose the correct
 k1 
   A    B answer from the options given below :
 k2  (1) Statement I is true but Statement II is false
63. When  and B are the wave functions of atomic (2) Statement I is false but Statement II is true
(3) Both Statement I and Statement II is true
orbitals, then * is represented by :
(4) Both Statement I and Statement II is false
(1) A – 2B (2) A – B Ans. (3)
(3) A + 2B (4) A + B Sol. SN2  Inversion
Ans. (2) SN1  Racemisation
1
67. Match List-I with List-II. 68. Match List-I with List-II.
List-I List-II List-I List-II
(Reactions) (Products) (Test) (Identification)
NH2 OH (A) Bayer's test (I) Phenol
CHO
(i) NaNO2 + HCl (B) Ceric ammonium (II) Aldehyde
(A) (I)
(ii) H2O, warm nitrate test
(C) Phthalein dye test (III) Alcoholic-OH
OH OH
group
Na2Cr2O7
(B) (II) (D) Schiff's test (IV) Unsaturation
H2SO4
OH OH below :
COOH
(i) CHCl3+aq NaOH
(1) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
(C) (ii) H+
(III) (2) (A)-(II), (B)-(III), (C)-(IV), (D)-(I)
®
(3) (A)-(IV), (B)-(I), (C)-(II), (D)-(III)
OH O (4) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
(i) NaOH Ans. (4)
(D) (IV)
(ii) CO2 Sol. (A) Bayer's test  Unsaturation
(iii) H+
O (B) Ceric ammonium nitrate test  Alcoholic-OH group
Choose the correct answer from the options given (C) Phthalein dye test Phenol
below : (D) Schiff's test Aldehyde
(1) (A)-(III), (B)-(II), (C)-(I), (D)-(IV) 69. Identify the incorrect statements about group 15
(2) (A)-(IV), (B)-(II), (C)-(III), (D)-(I) elements :
(3) (A)-(I), (B)-(IV), (C)-(II), (D)-(III) (A) Dinitrogen is a diatomic gas which acts like an
(4) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
inert gas at room temperature.
Ans. (4)
(B) The common oxidation states of these
NH2 OH
elements are –3, +3 and +5.
(i) NaNO2 + HCl (C) Nitrogen has unique ability to form p–p
Sol.
(ii) H2O, warm
multiple bonds.
OH O (D) The stability of +5 oxidation states increases
Na2Cr2O7 down the group.
H2SO4 (E) Nitrogen shows a maximum covalency of 6.
O
below.
OH OH
CHO (1) (A), (B), (D) only (2) (A), (C), (E) only
(i) CHCl3+aq NaOH (3) (B), (D), (E) only (4) (D) and (E) only
(ii) H+
Ans. (4)
OH OH Sol. (D) Due to inert pair effect lower oxidation state is
COOH more stable.
(i) NaOH
(E) Nitrogen belongs to 2nd period and cannot
(ii) CO2
(iii) H+ expand its octet.
2
70. IUPAC name of following hydrocarbon (X) is : Sol. Buffer solution is a mixture of either weak acid /
CH3 – CH – CH2 – CH2 – CH – CH – CH2 – CH3 weak base and its respective conjugate.
CH3 (X) CH3 CH3 Blood is a buffer solution of carbonic acid H2CO3
and bicarbonate HCO3
(1) 2-Ethyl-3,6-dimethylheptane
(2) 2-Ethyl-2,6-diethylheptane Statement 1 is false but Statement II is true.
73. The correct sequence of acidic strength of the
(3) 2,5,6-Trimethyloctane
following aliphatic acids in their decreasing order
(4) 3,4,7-Trimethyloctane is :
Ans. (3) CH3CH2COOH, CH3COOH, CH3CH2CH2COOH,
1 2 3 4 5 6 7 8 HCOOH
Sol. (1) HCOOH > CH3COOH > CH3CH2COOH >
CH3 – CH – CH2 – CH2 – CH – CH – CH2 – CH3
CH3CH2CH2COOH
CH3 CH3 CH3 (2) HCOOH > CH3CH2CH2COOH >
CH3CH2COOH > CH3COOH
2,5,6-Trimethyloctane
(3) CH3CH2CH2COOH > CH3CH2COOH >
®
71. The equilibrium Cr2 O27 2CrO24 is shifted to CH3COOH > HCOOH
the right in : (4) CH3COOH > CH3CH2COOH >
(1) an acidic medium CH3CH2CH2COOH > HCOOH
(2) a basic medium Ans. (1)
(3) a weakly acidic medium Sol. CH3CH2COOH, CH3COOH, CH3CH2CH2COOH,
(4) a neutral medium HCOOH
Ans. (2) The correct order is :
OH HCOOH > CH3COOH > CH3CH2COOH >
Sol. Cr2O27 2CrO24
H CH3CH2CH2COOH
72. Given below are two statements : 74. Given below are two statements :
Statement (I) : All the following compounds react
Statement (I) : A Buffer solution is the mixture of with p-toluenesulfonyl chloride.
a salt and an acid or a base mixed in any particular C6H5NH2 (C6H5)2NH (C6H5)3N
Statement (II) : Their products in the above
quantities. reaction are soluble in aqueous NaOH.
Statement (II) : Blood is naturally occurring In the light of the above statements, choose the
buffer solution whose pH is maintained by
H 2 CO3 / HCO3 concentrations. (2) Statement I is true but Statement II is false
In the light of the above statements, choose the (4) Both Statement I and Statement II is true
Ans. (1)
Sol. Hinsberg test given by 1° amine only.
(1) Statement I is false but Statement II is true 75. The emf of cell T1 T1 Cu 2  Cu is 0.83 V at
 0.001M   0.01M 
(2) Both Statement I and Statement II is true 298 K. It could be increased by :
(3) Both Statement I and Statement II is false (1) increasing concentration of T1+ ions
(2) increasing concentration of both T1+ and Cu2+ ions
(3) decreasing concentration of both T1+ and Cu2+ ions
Ans. (1) (4) increasing concentration of Cu2+ ions
3
Ans. (4) 77. Given below are two statements :
Sol. Statement (I) : Kjeldahl method is applicable to
Anodic Reaction  T s  T  aq  e   2 estimate nitrogen in pyridine.

    
Cathodic Reaction 2 
Cu  aq   2e  Cu s Statement (II) : The nitrogen present in pyridine
Overall Redox Reaction 2T  Cu 2 aq   2T 

 Cu s can easily be converted into ammonium sulphate in
s  aq 
Kjeldahl method.
 T  
2
0.0591
E cell  E o
cell  log correct answer from the options given below.
2  Cu 2 
+2
Ecell increases by increasing concentration of [Cu ] (2) Statement I is false but Statement II is true
ions. (3) Both Statement I and Statement II is true
76. Identify the correct statements about p-block (4) Statement I is true but Statement II is false
®
elements and their compounds. Ans. (1)
(A) Non metals have higher electronegativity than Sol. Nitrogen present in pyridine can not be estimated
metals. by Kjeldahl method as the nitrogen present in
(B) Non metals have lower ionisation enthalpy pyridine can not be easily converted into
than metals. ammonium sulphate.
(C) Compounds formed between highly reactive 78. The reaction ;
nonmetals and highly reactive metals are
1  
generally ionic. H2(g)  AgCl(s)  H(aq)  Cl(aq)  Ag(s)
2
(D) The non-metal oxides are generally basic in nature.
(E) The metal oxides are generally acidic or occurs in which of the following galvanic cell :
neutral in nature. (1) Pt H2(g) HCl(soln.) AgCl(s) Ag

(1) (D) and (E) only (2) (A) and (C) only
(2) Pt H2(g) HCl(soln.) AgNO3(aq) Ag
(3) (B) and (E) only (4) (B) and (D) only
Ans. (2) (3) Pt H2(g) KCl(soln.) AgCl(s) Ag

Sol. As electronegativity increases non-metallic nature
(4) Ag AgCl(s) KCl(soln.) AgNO3(aq.) Ag
increases.
Along the period ionisation energy increases. Ans. (3)
High electronegativity difference results in ionic Sol. Anodic half cell
bond formation. Gas – gas ion electrode
Oxides of metals are generally basic and that of 1

H 2  H   aq   e 
2  g
non-metals are acidic in nature.
4
Cathodic Reaction 80. Match List-I with List-II.
Metal-metal insoluble salt anion electrode List-I List-II
Agaq   e  Ags (Complex ion) (Spin only magnetic
moment in B.M.)
AgCls Agaq   Claq 
(A) [Cr(NH3)6]3+ (I) 4.90
AgCls  e  Ags  Claq  (B) [NiCl4]2– (II) 3.87
Overall redox reaction (C) [CoF6]3– (III) 0.0

1
H 2  g   AgCls  H   aq   Cl  aq   Ags  (D) [Ni(CN)4]2– (IV) 2.83
2
Cell Representation Choose the correct answer from the options given
®
below :
Pt | H2(g) | kCl(sol) | AgCl(s) | Ag
(1) (A)-(I), (B)-(IV), (C)-(II), (D)-(III)
79. Given below are two statements : (2) (A)-(IV), (B)-(III), (C)-(I), (D)-(II)
Statement (I) : Fusion of MnO2 with KOH and an
(3) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
oxidising agent gives dark green K2MnO4.
Statement (II) : Manganate ion on electrolytic (4) (A)-(II), (B)-(III), (C)-(I), (D)-(IV)
oxidation in alkaline medium gives permanganate Ans. (3)
ion. Sol. (A) [Cr(NH3)6]3+
In the light of the above statements, choose the Cr3+ : 3d3
correct answer from the options given below. n = 3 (unpaired electrons)
 3.87 B.M. (II)
(1) Both Statement I and Statement II is true
(B) [NiCl4]2–
Ni2+ : 3d8
n=2
 2.83 B.M. (IV)
Ans. (1)
(C) [CoF6]3–
fused
Sol. MnO2 + 4KOH + O2   2K2MnO4 + 2H2O Co3+ : 3d6
Dark green n=4

 4.90 B.M. (I)
Electrolytic oxidation in alkaline medium :
(D) [Ni(CN)4]2–
At anode : Ni2+ : 3d8
n=0
MnO24  MnO4  e 
 = 0 B.M. (III)
5
SECTION-B 42
B.O. = 1
81. vap H for water is +40.49 kJ mol–1 at 1 bar and 2
100°C. Change in internal energy for this Ne2
vapourisation under same condition is ______ kJ (20e–) : 1s2,*1s2,2s2,*2s2,2pz2
mol–1. (Integer answer)

 2p2x  2p2y    * 2p2x   * 2p2y   * 2pz2
–1 –1    
(Given R = 8.3 JK mol )
Ans. (38) 10  10
B.O. = 0
2
Sol. H2 O( ) H2O(g) H 0vap  40.79 kJ / mole
N2
H 0vap  U vap
0
 n g RT
 8.3  373.15 (14e–) : 1s2,*1s2,2s2,*2s2  2p2x  2p2y  2p 2z

40.79  U 0vap 
1000
10  4
B.O. = 6
®
U 0vap  40.79  3.0971 2
 37.6929 He2
U 0
vap 38
(4e–) : 1s2,*1s2
82. Number of molecules having bond order 2 from
22
B.O. = 0
the following molecule is _______. 2
C2, O2, Be2, Li2, Ne2, N2, He2 83. Total number of optically active compounds from
Ans. (2) the following is _______.
Sol. C2 CH3 OH OH CH3 – CH2 – CH2 – CH2 – OH,
CH3 – CH2 – CH – CH3
(12e–) : 1s2,*1s2,2s2,*2s2  2p2x  2p2y  H C OH ,
, Cl
OH
H C OH
84 CH3 – CH2 – CH2 – CH2 – Cl,
B.O. = 2 (CH3)2CH – CH2 – CH2 – Cl
2 CH3
O2 Ans. (1)
– 2 2 2 2 2
(16e ) : 1s ,*1s ,2s ,*2s ,2pz
Sol. CH3 – CH2 – CH – CH3
 2p2x  2p2y    * 2p1x   * 2p1y  Cl
   
84. The total number of carbon atoms present in
10  6
B.O. = 2 tyrosine, an amino acid, is _______.
2
Ans. (9)
Be2
(8e–) : 1s2,*1s2,2s2,*2s2 Sol. Tyrosine
44 O
B.O. = 0
2
OH
Li2 HO NH 2
Number of carbon atoms = 9
(6e–) : 1s2,*1s2,2s2
6
85. Two moles of benzaldehyde and one mole of 88. Total number of unpaired electrons in the complex
acetone under alkaline conditions using aqueous
ion [Co(NH3)6]3+ and [NiCl4]2– is
NaOH after heating gives x as the major product.
Ans. (2)
The number of  bonds in the product x is
Ans. (9) Sol. Co+3 : 3d6 t 2,2,2
2g e 0,0
g
O Unpaired e– = 0
Ph Ph
Sol. C = O + CH3–C–CH3 + O = C
H H Ni+2 : 3d8 e 2,2 t 2,1,1
2
NaOH/
O Aldol Unpaired e– = 2
Ph Ph condensation
C = CH–C–CH = C 89. Wavenumber for a radiation having 5800 Å
H H reaction
wavelength is x × 10 cm–1. The value of x is
®
86. Total number of aromatic compounds among the _____.
following compounds is _______.
 Ans. (1724)
, , , , ,
1 1
N Sol.  (wave no.) =  = 17241
 5800  10 8 cm
Ans. (1)
OR
Sol.
1724  10 cm 1 x = 1724
N
90. A solution is prepared by adding 1 mole ethyl
87. Molality of an aqueous solution of urea is 4.44 m.
Mole fraction of urea in solution is x × 10–3. alcohol in 9 mole water. The mass percent of
Value of x is _______. (integer answer) solute in the solution is _______ (Integer Answer)
Ans. (74)
(Given : Molar mass in g mol–1 Ethyl alcohol : 46,
Sol. Molality of urea is 4.44 m, that means 4.44 moles
water : 18)
of urea present in 1000 gm of water.
Ans. (22)
4.44
 X urea  Sol. Mass percent of Alcohol
1000
4.44 
18
Mass of ethyl alcohol
= 0.0740 =  100
Total mass of solution
OR
1  46 4600
=  100 =
74 10 3
1  46  9  18 208
X = 74 = 22.11 Or 22
7
(Held On Tuesday 09th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

SECTION-A Sol.
61. The molar conductivity for electrolytes A and B Na/Et2O
Cl Br Cl Cl
are plotted against C1/2 as shown below. Wurtz
Electrolytes A and B respectively are : Reaction (A)
m(Scm2 mol–1)
A CoF2 (i) Mg/Et2O

400 Swart (ii) D2O
Reaction
200
B F D
F D
0
0.2 0.4 (C) (B)
0
1/2
C (mol L–1)1/2
®
A B
(1) Weak electrolyte weak electrolyte 64. Correct order of basic strength of Pyrrole N ,
H
(2) Strong electrolyte strong electrolyte
(3) Weak electrolyte strong electrolyte
(4) Strong electrolyte weak electrolyte Pyridine and Piperidine is:
N
Ans. (3) N H
Sol. A  Weak electrolyte (1) Piperidine > Pyridine > Pyrrole
B  Strong electrolyte
(2) Pyrrole > Pyridine > Piperidine
62. Methods used for purification of organic
compounds are based on : (3) Pyridine > Piperidine > Pyrrole
(1) neither on nature of compound nor on the (4) Pyrrole > Piperidine >Pyridine
impurity present. Ans. (1)
(2) nature of compound only.
Sol. Order of basic strength is
(3) nature of compound and presence of impurity.
(4) presence of impurity only. N(sp3, localized lone pair) > N(sp2, localized lone
Ans. (3) pair) > N(sp2, delocalized lone pair, aromatic)
Sol. Organic compounds are purified based on their  Piperidine > Pyridine > Pyrrole
nature and impruity present in it.
63. In the following sequence of reaction, the major 65. In which one of the following pairs the central
products B and C respectively are : atoms exhibit sp2 hybridization ?
Cl Br
Na/Et2O
A
(i) Mg/Et2O
B (1) BF3 and NO2
(ii) D2O
CoF2 (2) NH 2 and H2O
C (3) H2O and NO2

(4) NH 2 and BF3
(1) D D and F F
Ans. (1)
(2) D D and F F Sol. BF3  sp2
NO2–  sp2
(3) D D and F F
H2O  sp3
(4) and F F NO2  sp2
Ans. (1) NH2–  sp3
1
66. The F– ions make the enamel on teeth much harder Sol. Oxidation state of an element in a particular
by converting hydroxyapatite (the enamel on the
compound is defined by the charge acquired by its
surface of teeth) into much harder fluoroapatite
having the formula. atom on the basis of electronegativity
(1) [3(Ca3(PO4)2).CaF2]
consideration from other atoms in molecule.
(2) [3(Ca2(PO4)2).Ca(OH)2]
(3) [3(Ca3(PO4)3).CaF2] 69. Given below are two statements : one is labelled
(4) [3(Ca3(PO4)2).Ca(OH)2]
as Assertion (A) and the other is labelled as
Ans. (1)
Sol. Fluoroapatite  [3Ca3(PO4)2.CaF2] Reason (R) :
67. Relative stability of the contributing structures is :
Assertion (A) : SN2 reaction of C6H5CH2Br occurs
–
O O O+
+ –
more readily than the SN2 reaction of CH3CH2Br.
CH2=CH–C–H CH2–CH=C–H CH2–CH=C–H
(I) (II) (III) Reason (R) : The partially bonded unhybridized
®
(1) (I) > (III) > (II) p-orbital that develops in the trigonal bipyramidal
(2) (I) > (II) > (III) transition state is stabilized by conjugation with the
(3) (II) > (I) > (III)
(4) (III) > (II) > (I) phenyl ring.
Ans. (2) In the light of the above statements, choose the
Sol. (1) Neutral structures are more stable than
charged ones. Therefore I is more stable than most appropriate answer from the options given
II and III.
(2) +ve charge on less electronegative atom is below :
more stable i.e., Cis more stable than O (1) (A) is not correct but (R) is correct
  Order is I > II > III
68. Given below are two statements : (2) Both (A) and (R) are correct but (R) is not the
Statement (I) : The oxidation state of an element
in a particular compound is the charge acquired by
its atom on the basis of electron gain enthalpy (3) Both (A) and (R) are correct and (R) is the
consideration from other atoms in the molecule.
Statement (II) : p-p bond formation is more
prevalent in second period elements over other (4) (A) is correct but (R) is not correct
periods.
Ans. (3)
most appropriate answer from the options given Sol. The benzyl group acts in much the same way using
below :
the -system of the benzene ring for conjugation
incorrect with the p-orbital in the transition state.
(2) Statement I is correct but Statement II is 
incorrect RO OR
Br
correct
benzyl bromide
correct
Ans. (4)
2
70. For the given compounds, the correct order of Sol. Oxygen can form 2p-2p multiple bond with
increasing pKa value : itself due to its small size while sulphur cannot
form multiple bond with itself as 3p-3p bond
(A) OH
will be unstable due to large size of sulphur, but
sulphur can form multiple bond with small size
(B) O2N OH atom like C and N.
eg. S=C=S
OCH3 S=C=N–  S  C  N
72. Given below are two statements : one is labelled as
(C) HO Assertion (A) and the other is labelled as Reason (R).
Assertion (A): The total number of geometrical
isomers shown by [Co(en)2Cl2]+ complex ion is three
(D) NO2
Reason (R): [Co(en)2Cl2]+ complex ion has an
octahedral geometry.
®
OH In the light of the above statements, choose the most
appropriate answer from the options given below :
(E) HO OCH3
(1) Both (A) and (R) are correct and (R) is the
(1) (E) < (D) < (C) < (B) < (A) correct explanation of (A).
(2) (D) < (E) < (C) < (B) < (A) (2) (A) is correct but (R) is not correct.
(3) (E) < (D) < (B) < (A) < (C) (3) (A) is not correct but (R) is correct.
(4) (B) < (D) < (A) < (C) < (E) (4) Both (A) and (R) are correct but (R) is not the
Ans. BONUS correct explanation of (A).
NTA Ans. (4) Ans. (3)
Sol. Acidic strength order :- Sol. [Co(en)2Cl2]+ has octahedral geometry with two
B>D>C>A>E
Correct pKa Order : geometrical isomers.
B<D<C<A<E + +
All options are incorrect. N Cl
N C N N
Co Co
71. Given below are two statements : one is labelled as N N N
C
Assertion (A) : and the other is labelled as Reason (R). N Cl
Assertion (A) : Both rhombic and monoclinic cis trans
sulphur exist as S8 while oxygen exists as O2.
Reason (R) : Oxygen forms p-p multiple bonds
73. The electronic configuration of Cu(II) is 3d9
with itself and other elements having small size
and high electronegativity like C, N, which is not whereas that of Cu(I) is 3d10. Which of the
possible for sulphur. following is correct ?
In the light of the above statements, choose the (1) Cu(II) is less stable
most appropriate answer from the options given (2) Stability of Cu(I) and Cu(II) depends on nature
below :
of copper salts
(1) Both (A) and (R) are correct and (R) is the
correct explanation of (A). (3) Cu(II) is more stable
(2) Both (A) and (R) are correct but (R) is not the (4) Cu(I) and Cu(II) are equally stable
correct explanation of (A). Ans. (3)
(3) (A) is correct but (R) is not correct. Sol. Cu(II) is more stable than Cu(I) because hydration
(4) (A) is not correct but (R) is correct.
energy of Cu+2 ion compensate IE2 of Cu.
Ans. (3)
3
O Sol. Energy level can be determined by comparing (n + )
values
74. + O AlCl3 A Zn-Hg B (A) n = 4,  = 1  (n + ) = 5
HCl
(B) n = 4,  = 2  (n + ) = 6
O Conc.H2SO4
C (C) n = 3,  = 1  (n + ) = 4
What is the structure of C ? (D) n = 3,  = 2  (n + ) = 5
O (E) n = 4,  = 0  (n + ) = 4
For same value of (n + ), orbital having higher
(1)
value of n, will have more energy.
(B) > (A) > (D) > (E) > (C)
O
C OH 76. Identify major product "X" formed in the
C following reaction :
(2)
®
CO, HCl
O X
Anhydrous
CH2 (Major product)
OH AlCl3/CuCl
C
O O
(3)
O C C
O (1) Cl (2)
(4)
CHO CH2Cl
(3) (4)
Ans. (1)
O O
Ans. (3)
AlCl3 Zn-Hg Sol. This is Gattermann-Koch reaction
+O
Sol HO
HCl CHO
O AlCl3
(A) O + CO + HCl
CuCl
Conc.H2SO4 77. Identify the product A and product B in the
following set of reactions.
HO
H2O, H+
(C) O Major
(B) O
product A
75. Compare the energies of following sets of quantum CH3–CH=CH2
numbers for multielectron system. (BH3)2
(A) n = 4, 1 = 1 (B) n = 4, l = 2 Major
H2O, H2O2, OH
(C) n = 3, l = 1 (D) n = 3, l = 2 product B
(E) n = 4, 1 = 0 (1) A-CH3CH2CH2–OH, B-CH3CH2CH2–OH
Choose the correct answer from the options given (2) A-CH3CH2CH2–OH, B- CH3CH–CH3
below : OH
(1) (B) > (A) > (C) > (E) > (D)
(3) A- CH3–CH–CH3 , B-CH3CH2CH2–OH
(2) (E) > (C) < (D) < (A) < (B)
(3) (E) > (C) > (A) > (D) > (B) OH
(4) (C) < (E) < (D) < (A) < (B) (4) A-CH3CH2CH3, B-CH3CH2CH3
Ans. (4) Ans. (3)
4
Sol. (1) Hydration Reaction : Sol. KMnO4 & NaOH  Secondary standard.

Primary standard should not be Hygroscopic.
CH 3  CH  CH 2  H  
 CH 3  CH  CH 3
(More stable)
+ + 80. 0.05M CuSO4 when treated with 0.01M K2Cr2O7

CH3–CH–CH3 + H2O (CH3–CH–CH3) + H
gives green colour solution of Cu2Cr2O7. The
OH
(A) [SPM : Semi Permeable Membrane]
K2 Cr2 O7 CuSO4
(2) Hydroboration Oxidation Reaction :
Side X SPM Side Y
3CH3–CH=CH2 + B2H6 
 THF
Due to osmosis :
2(CH3CH2CH2)3B
(1) Green colour formation observed on side Y.
OH 
(CH3CH 2CH 2 )3 B  3H 2O2 
 (2) Green colour formation observed on side X.
®
3CH 3CH 2CH 2OH  H 3BO3 (3) Molarity of K2Cr2O7 solution is lowered.
(B)
(4) Molarity of CuSO4 solution is lowered.
78. On reaction of Lead Sulphide with dilute nitric
acid which of the following is not formed ?
Ans. (4)
(1) Lead nitrate (2) Sulphur
Sol. Only solvent Molecules are allowed to pass
(3) Nitric oxide (4) Nitrous oxide
through the SPM.
Ans. (4)
Sol. PbS + HNO3  Pb(NO3)2 + NO + S + H2O
K2Cr2O CuSo4
Nitrous oxide (N2O) is not formed during the
reaction. V V
 
79. Identify the incorrect statements regarding
primary standard of titrimetric analysis
(A) It should be purely available in dry form.
SECTION-B
(B) It should not undergo chemical change in air. 81. The heat of solution of anhydrous CuSO4 and
(C) It should be hygroscopic and should react
CuSO45H2O are –70 kJ mol–1 and +12 kJ mol–1
with another chemical instantaneously and
respectively.
stoichiometrically.
The heat of hydration of CuSO4 to CuSO45H2O is
(D) It should be readily soluble in water.
–x kJ. The value of x is_____.
(E) KMnO4 & NaOH can be used as primary
Ans. (82)
standard.
(1) CuSO4 (s)  5H2 O  x
 CuSO4 .5H 2 O
Sol. (2) CuSO4 .5H2 O  H 2 O  CuSO4 (aq)
12
below : 70
CuSO4  H2 O  CuSO4 (aq)
(1) (C) and (D) only (2) (B) and (E) only
from (1) & (2)
(3) (A) and (B) only (4) (C) and (E) only –70 = x + 12
Ans. (4) x = –82
5
82. Given below are two statements : NO2
Statement I : The rate law for the reaction Sol. , ,

A + B  C is rate (r) = k[A]2[B]. When the O
concentration of both A and B is doubled, the
NO2 COCH3
reaction rate is increased “x” times.
Statement II : CH3
,
[Ro] 84. The standard reduction potentials at 298 K for the
Contration of R
following half cells are given below :

–K = Slope Cr2O72– + 14H+ + 6e–  2Cr3+ + 7H2O, E° = 1.33V
Fe3+ (aq) + 3e– Fe E° = –0.04V
2+ –
Ni (aq) + 2e  Ni E° = –0.25V
o Time Ag+ (aq) + e–  Ag E° = 0.80V
The figure is showing “the variation in Au3+ (aq) + 3e–  Au E° = 1.40V
Consider the given electrochemical reactions,
concentration against time plot” for a “y” order
®
The number of metal(s) which will be oxidized be
reaction. Cr2O72–, in aqueous solution is __________.
The value of x + y is ______________. Ans. (3)
Ans. (8) Sol. Fe, Ni, Ag will be oxidized due to lower S.R.P.
Sol. r = K[A]2|B|
if conc. are doubled 85. When equal volume of 1M HCl and 1M H2SO4 are
r' = K[2A]2[2B]1 separately neutralised by excess volume of 1M
NaOH solution. X and y kJ of heat is liberated
r' = 8r  x = 8
respectively. The value of y/x is _________.
Ans. (2)
C Sol. H+ + OH–  H2O  x
–K 2H+ + 2OH–  2H2O  2x = y
y/x = 2
t
  Zero order, y = 0 86. Molarity (M) of an aqueous solution containing x g
x+y=8 of anhyd. CuSO4 in 500 mL solution at 32 °C is
83. How many compounds among the following 2 × 10–1 M. Its molality will be _______ × 10–3 m.
compounds show inductive, mesomeric as well as (nearest integer).
hyperconjugation effects? [Given density of the solution = 1.25 g/mL.]
OCH3 Allen Ans. (164)
NTA Ans. (81) BONUS
, , Sol. Msoln  v soln  d soln
O
 500  1.25  625g
NO2
Mass of solute (x) = 0.2 × 0.5 × 159.5
, = 15.95
, ,
Cl nsolute = 0.1,
NO2 Mass of solvent = Mass of solution – Mass of solute
CH3 COCH3 = 625 – 15.95
, , = 609.05
0.1
CH3 m
CH3 609.05
1000
Ans. (4) m  0.164  164  10 3
6
87. The total number of species from the following in 89. Total number of essential amino acid among the
given list of amino acids is _______.
which one unpaired electron is present, is _______.
Arginine, Phenylalanine, Aspartic acid, Cysteine,
N2 ,O2 ,C2 ,O2 ,O22  , H 2 ,CN  , He 2 Histidine, Valine, Proline
Ans. (4) Ans. (4)
Sol. Essential Amino acids are :-
–    
Sol. One unpaired e is present in : C ; O ; H ; He
2 2 2 2 Arginine, Phenylalanine, Histidine, Valine
88. Number of ambidentate ligands among the 90. Number of colourless lanthanoid ions among the
following is _________.
following is ________.
Eu3+, Lu3+, Nd3+, La3+, Sm3+
NO2 ,SCN  , C2 O24 , NH3 ,CN  ,SO24 ,H2 O. Ans. (2)
Sol. La+3 – [Xe]4f0
Ans. (3) Nd+3 – [Xe]4f3
Sm+3 – [Xe]4f5
®
Sol. Ligands which have two different donor sites but at
Eu+3 – [Xe]4f6
a time connects with only one donor site to central
Lu+3 – [Xe]4f14
metal are ambidentate ligands. La+3 and Lu+3 do not show any colour because no
Ambidentate ligands are NO2– ; SCN– ; CN– unpaired electron is present.
7
(Held On Tuesday 09th April, 2024) TIME : 3 : 00 PM to 6 : 00 PM

SECTION-A O
61. The candela is the luminous intensity, in a given Sol. CH3–CH=CH–CH (III)
direction, of a source that emits monochromatic 
Non Polar R.S.
radiation of frequency 'A' × 1012 hertz and that has More No of covalent bond
1 O
a radiant intensity in that direction of watt per 
' B' CH3–CH–CH=CH (II)
steradian. 'A' and 'B' are respectively 
Having –ve charge on more
1 electronegative atom
(1) 540 and
®
683
O
(2) 540 and 683 
CH3–CH–CH=CH (I)
1 
(3) 450 and
683 Having –ve charge on less
electronegative atom
(4) 450 and 683
Stability order III > II > I
Ans. (2)
Sol. The candela is the luminous intensity of a source 63. Total number of stereo isomers possible for the
that emits monochromatic radiation of frequency given structure:
Br
radiation of frequency 540 × 1012 Hz and has a Br
1
radiant intensity in that direction of w/sr. It is
683
(1) 8 (2) 2
unit of Candela. (3) 4 (4) 3
Ans. (1)
Br
62. The correct stability order of the following
resonance structures of CH3 –CH = CH–CHO is Br
O  O Sol.
  Br
CH3–CH–CH=C–H CH3–CH–CH=C–H
I II There are three stereo center
O So No of stereoisomer = 23 = 8
 CH3–CH=CH–C–H 64. The correct increasing order for bond angles
III among BF3, PF3 and CF3 is :
(1) II > III > I (1) PF3 < BF3 < CF3 (2) BF3 < PF3 < CF3
(2) III > II > I
(3) I > II > III (3) CF3 < PF3 < BF3 (4) BF3 = PF3 < CF3
(4) II > I > III Ans. (3)
Ans. (2)
1
Sol. 66. Match List I with List II
F LIST-I LIST-II
F Cl (Cell) (Use/Property/Reaction)
F
120º 87.5º
B A. Leclanche I. Converts energy
F F F
cell of combustion into
electrical energy
P
B. Ni-Cd cell II. Does not involve
F 97º F
F any ion in solution
Order of bond angle is and is used in
ClF3 < PF3 < BF3 hearing aids
C. Fuel cell III. Rechargeable
65. Match List I with List II
D. Mercury IV. Reaction at anode
®
LIST-I LIST-II
(Test) (Observation) cell Zn  Zn2+ + 2e–
A. Br2 water test I. Yellow orange or
orange red Choose the correct answer from the options given
precipitate below:
formed (1) A-I, B-II, C-III, D-IV
B. Ceric II. Reddish orange
ammonium colour (2) A-III, B-I, C-IV, D-II
nitrate test disappears (3) A-IV, B-III, C-I, D-II
C. Ferric chloride III. Red colour
test appears
D. 2, 4-DNP test IV. Blue, Green, Ans. (3)
Violet or Red Sol. A-IV, B-III, C-I, D-II
colour appear
below: LIST-I LIST-II
A. K2[Ni(CN)4] I. sp3
(3) A-III, B-IV, C-I, D-II B. [Ni(CO)4] II. sp3d2
(4) A-IV, B-I, C-II, D-III C. [Co(NH3)6]Cl3 III. dsp2
Ans. (2)
Sol. (A) Br2 water test is test of unsaturation in which D. Na3[CoF6] IV. d2sp3
reddish orange colour of bromine water Choose the correct answer from the options given
disappears. below:
(B) Alcohols given Red colour with ceric
(1) A-III, B-I, C-II, D-IV
ammonium nitrate.
(C) Phenol gives Violet colour with natural ferric (2) A-III, B-II, C-IV, D-I
chloride. (3) A-I, B-III, C-II, D-IV
(D) Aldehyde & Ketone give Yellow/Orange/Red (4) A-III, B-I, C-IV, D-II
Colour compounds with 2, 4-DNP i.e., 2,
4-Dinitrophenyl hydrazine. Ans. (4)
2
+2 69. The incorrect statement about Glucose is :
Sol. (A) K2 [Ni(CN)4]  (1) Glucose is soluble in water because of having
–
Ni2+ [Ar]3d8 4sº , (CN is S.F.L) aldehyde functional group
Pre hybridization state of Ni+2 (2) Glucose remains in multiple isomeric form in
its aqueous solution
3d 4s 4p (3) Glucose is an aldohexose
dsp 2 (4) Glucose is one of the monomer unit in sucrose
Ans. (1)
(B) [Ni(CO)4]
Sol. Glucose is soluble in water due to presence of
Ni  [Ar] 3d8 4s2
alcohol functional group and extensive hydrogen
CO isS.F.L , so pairing occur
bonding.
Pre hybridization state of Ni
Glucose exist is open chain as well as cyclic forms
in its aqueous solution.
3d 4s 4p
®
3 Glucose having 6C atoms so it is hexose and
sp
having aldehyde functional group so it is aldose.
(C)  Co(NH3 )6  Cl3
Thus, aldohexose.
Co 3 :[Ar]3d 6 4s0 Glucose is monomer unit in sucrose with fructose.
With Co3+, NH3 act as S.F.L Br
OCH3  Major Product 'P'
KCN(alc)
70. 
In the above reaction product 'P' is

3d 4s 4p
OCH3
d2sp3 CN CN
(d) Na3 [CoF6] (1) OCH3 (2)

Co3+ : [Ar] 3d6 ( F W.F.L) CN CN
3d 4s 4p 4d (3) OCH3 (4) OCH3

sp3d2
Ans. (1)
Sol.
68. The coordination environment of Ca2+ ion in its
complex with EDTA4– is :
(1) tetrahedral Br +
OCH3
(2) octahedral
OCH3
(3) square planar
(4) trigonal prismatic CN–
Ans. (2)
CN
Sol. EDTA4– Hexadentate ligand
[Ca(EDTA)]2– OCH3
So Coordination environment is octahedral
Due to NGP effect of phenyl ring Nucleophilic
substitution of Br will occurs.
3
71. Which of the following compound can give 73. Major product of the following reaction is
positive iodoform test when treated with aqueous CN
KOH solution followed by potassium hypoiodite.

(i) CH3MgBr(excess)
(ii) H O
O 3
(1) CH3CH2–C–CH2CH3 CO2CH3

Cl CN
(2) CH3CH2–C–CH3
Cl (1)
(3) CH3CH2CH2CHO
HO CH
O CH3 3
(4) CH3CH2–CH–CH2 O CH3
C
Ans. (2)
Sol.
(2)
®
HO CHCH3
Cl OH 3
O CH3
CH3 – CH2 – C – CH3
aq. KOH CH – CH – C – CH
3 2 3
C
Cl OH (3)
–H2O O CO2CH3
CN
CH3 – CH2 – C – CH3
KOI
(4)
CH3 – CH2 – COOK + CHI3↓
C
Yellow ppt O CH3
Ans. (2)
72. For a sparingly soluble salt AB2, the equilibrium
Sol.
concentrations of A2+ ions and B– ions are
–+
1.2 × 10–4 M and 0.24 × 10–3 M, respectively. The CH3 NMgBr
CN C
solubility product of AB2 is :
CH3MgBr (excess)
(1) 0.069 × 10–12
–
(2) 6.91 × 10–12 C BrMgO C CH3
–12 O OCH3
(3) 0.276 × 10
CH3
(4) 27.65 × 10–12
H3O+
Ans. (2)
Sol. AB2(s) A 2(aq)  2B(aq) O = C – CH3
K sp  [A 2 ][B ]2
 1.2  10 4  (2.4  10 4 )2 HO – C – CH3
 6.91  10 12 M3
CH3
4
74. Given below are two statements : 76. Match List I with List II
Statement I : The higher oxidation states are more List-I List-II
stable down the group among transition elements (Element) (Electronic Configuration)
unlike p-block elements. A. N I. [Ar] 3d104s2 4p5
Statement II : Copper can not liberate hydrogen B. S II. [Ne] 3s2 3p4
from weak acids. C. Br III. [He] 2s2 2p3
In the light of the above statements, choose the D Kr IV. [Ar] 3d10 4s2 4p6
correct answer from the options given below : Choose the correct answer from the options given
(1) Both Statement I and Statement II are false below :
(1) A-IV, B-III, C-II, D-I
(2) A-III, B-II, C-I, D-IV
(3) A-I, B-IV, C-III, D-II
®
Ans. (3) (4) A-II, B-I, C-IV, D-III
Sol. On moving down the group in transition elements, Ans. (2)
stability of higher oxidation state increases, due to Sol. (A) 7 N :[He]2s2 2p3
increase in effective nuclear charge. (B) 16 S :[Ne]2s2 3p 4
  E o Cu 2 /Cu  0.34 V (C) 35 Br :[Ar]3d10 4s2 4p5
  E o H /H = 0 (D) 36 Kr :[Ar]3d10 4s2 4p 6

2

 SRP : Cu2+ > H+
List-I List-II
Cu can't liberate hydrogen gas from weak acid.
Melting
75. The incorrect statement regarding ethyne is A. I. Tl > In > Ga > Al > B
point [K]
(1) The C–C bonds in ethyne is shorter than that Ionic
in ethene B. Radius II. B > Tl > Al  Ga > In
+3
[M /pm]
(2) Both carbons are sp hybridised
iH1
(3) Ethyne is linear C. III. Tl > In > Al > Ga > B
[kJ mol–1]
(4) The carbon-carbon bonds in ethyne is weaker Atomic
than that in ethene D Radius IV. B > Al > Tl > In > Ga
Ans. (4) [pm]
Sol. The carbon-carbon bonds in ethyne is stronger than
below :
that in ethene.
(H–CC–H) Ethyne is linear and carbon atoms are (2) A-II, B-III, C-IV, D-I
SP hybridised. (3) A-IV, B-I, C-II, D-III
Ans. (3)
5
Sol. Melting point B > A > T> In > Ga Sol. HA(aq) H+ (aq) + A– (aq)
Ionic radius (M+3/pm) T> In > Ga > A > B 2C

Ka 
1 
 kJ 
(  IE H)1   B > T > A Ga > In 2 C  K a   K a  0
 m ol 
2
Atomic radius (in pm)  T> In > A> Ga > B  m  m
   C  Ka   Ka  0
 m  m
 
2
78. Which of the following compounds will give silver  2m C  K a  m  m  K a  m 0
mirror with ammoniacal silver nitrate?
80. The electronic configuration of Einsteinium is :
(A) Formic acid
(Given atomic number of Einsteinium = 99)
(B) Formaldehyde
(1) [Rn] 5f12 6d0 7s2 (2) [Rn] 5f11 6d0 7s2
(C) Benzaldehyde
(3) [Rn] 5f13 6d0 7s2 (4) [Rn] 5f10 6d0 7s2
®
(D) Acetone
Ans. (2)
below : Sol. Einsteinium (atomic No = 99) [Rn] 5f11 6d0 7s2
(1) C and D only
(2) A, B and C only SECTION-B
(3) A only 81. Number of oxygen atoms present in chemical
(4) B and C only formula of fuming sulphuric acid is _______.
Ans. (2) Ans. (7)
O Sol. Fuming sulphuric acid is a mixture of
Sol. Apart from aldehyde, Formic acid conc. H2SO4 + SO3 Or H2S2O7
H—C—OH
So, Number of Oxygen atoms = 7
also gives silver mirror test with ammonical silver 82. A transition metal 'M' among Sc, Ti, V , Cr, Mn
nitrate. and Fe has the highest second ionisation enthalpy.
The spin only magnetic moment value of M+ ion is
79. Which out of the following is a correct equation to ______ BM (Near integer)
show change in molar conductivity with respect to (Given atomic number Sc : 21, Ti : 22, V : 23, Cr :
concentration for a weak electrolyte, if the symbols 24, Mn : 25, Fe : 26)
carry their usual meaning :
Ans. (6)
2
(1) 
2
mC  K a  m  K a  m m 0 Sol. Among given metals, Cr has maximum IE2
1
 because Second electron is removed from stable
(2)  m   m  AC 2 0
configuration 3d5
1

(3)  m   m  AC 2  0 Cr+ [Ar] 3d5 4s0
 2  No of unpaired e– in Cr+ is 5, n = 5
(4)  m C  K a  m  K a  m  m  0
2
So, Magnetic moment = n(n  2) B.M

Ans. (1)
= 5(5  2) = 5.92 BM  6
6
83. The vapour pressure of pure benzene and methyl 85. Consider the following first order gas phase
benzene at 27°C is given as 80 Torr and 24 Torr, reaction at constant temperature
respectively. The mole fraction of methyl benzene A(g)  2B(g) + C(g)
in vapour phase, in equilibrium with an equimolar If the total pressure of the gases is found to be
mixture of those two liquids (ideal solution) at the 200 torr after 23 sec. and 300 torr upon the
–2
same temperature is____× 10 (nearest integer) complete decomposition of A after a very long
Ans. (23) time, then the rate constant of the given reaction
Sol. Xmethylbenzene = 0.5 is____× 10–2 s–1 (nearest integer)
Pmethylbenzene [Given : log10(2) = 0.301]
Ymethylbenzene 
Ptotal Ans. (3)
0.5  24 Sol. A(g)  2B(g) + C(g)
Ymethylbenzene 
0.5  80  0.5  24 P23  P0  2x  200
®
12 P  3P0  300
  0.23  23  10 2
40  12 P0 = 100
84. Consider the following test for a group-IV cation. 1 P  P0
K  ln 
M2+ + H2S  A (Black precipitate) + byproduct t P  Pt
A + aqua regia  B + NOCl + S + H2O 2.3 300  100

K log
23 300  200
B + KNO2 + CH3COOH  C + byproduct
2.3  0.301
The spin only magnetic moment value of the metal   0.0301  3.01  10 2 sec –1
23
complex C is ______BM.
(Nearest integer) Top
86.
Ans. (0) 1cm
2+
Sol. Co + H2S  CoS  (Black) Solvent
B front
(A) 10cm
A
CoS + Aqua-regia Co2+ (aq) + NOCl + S +H2O
(A) (B) 1cm
2+
Co (aq) + KNO2 + CH3COOH
Bottom

In the given TLC, the distance of spot A & B are
K3[Co(NO2)6] + NO + S + H2O
5 cm & 7 cm, from the bottom of TLC plate,
In K3[Co(NO2)6]  Co+3d6 4s0
Co3+ : d2sp3 Hybridisation respectively.
Number of unpaired e–= 0 Rf value of B is x × 10–1 times more than A. The
n(n  2) = 0 B.M
value of x is_____.
Magnetic moment =
Ans. (15)
7
Sol. Sol. Compounds which can not undergo Friedel Crafts
Distance moved by substance from base line reaction are
Rf =
Distance moved by solvent from base line NO2 NH2 NH2 NO2
Top
1cm NO2 NO2
Nitrobenzene Aniline
Solvent m-nitroaniline m-dinitrobenzene
B front
10cm
6cm 8cm
A 89. Total number of electron present in (*) molecular
4cm
 
1cm orbitals of O2 , O 2 and O 2 is_______.
Bottom Ans. (6)

Base line
Sol. O2(16e)  1s   1s*   2s   *2s 
2 2 2 2
4 6
 R f A   R f B 
®
          
 ,  *
     
1 1
8 8 2 2 2
*
2p 2p 2p   2 p 2p
 R f B 6 8
 
 R f A 8 4  
Number of e– present in * of O2  2
(Rf)B = 1.5 (Rf)A Number of e present in    of O

– * 
2  1
x = 15
Number of e present in    of O
– * –
2  3
87. Based on Heisenberg's uncertainty principle, the
So total e in    = 2 + 1 + 3 = 6
– *
uncertainty in the velocity of the electron to be
found within an atomic nucleus of diameter
10–15 m is ______× 109 ms–1 (nearest integer) 90. When Hvap = 30 kJ/mol and Svap=75 J mol–1 K–1,
then the temperature of vapour, at one atmosphere
[Given : mass of electron = 9.1 × 10–31 kg,
is ______K.
Plank's constant (h) = 6.626 × 10–34 Js] Ans. (400)
(Value of  = 3.14) Sol. At equilibrium GPT = 0
Ans. (58) H vap  TSvap
h 30  1000  T  75
Sol. mV.x 
4 T  400K
34
6.626  10
V 
9.1  10 31  10 15  4  3.14
 57.97  10 9 m/sec
88. Number of compounds from the following which
cannot undergo Friedel-Crafts reactions is :____
toluene, nitrobenzene, xylene, cumene, aniline,
chlorobenzene, m-nitroaniline, m-dinitrobenzene
Ans. (4)

Allen Jee Mains Che April-2024

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FINAL JEE–MAIN EXAMINATION – APRIL, 2024

(Held On Thursday 04th April, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

CHEMISTRY TEST PAPER WITH SOLUTION

PH2  1014 bar

Sol. According to spectrochemical series ligand field

strength is CO > H2O > F– > S2–

V+3 :- [Ar]3d2 , n = 2 (even number of unpaired e–)

Cu :- [Ar]3d94s0 Sol. Hydrogen ion (H+) shows positive electromeric

appropriate answer from the options given below. CHO CHO

(2) Both Statement I and Statement II are OH HO

show Lassaigne’s test.

(1) X = conc.alc. NaOH, 80°C, Y = Br2/CHCl3

O medium. The molarity of KMnO4 solution should

CHO Allen Ans. (8)

CONH2 H3O+ NH2 Sol. eq.(KMnO4) = eq.(H2C2O4)

Sol. disproportionate to give products ‘B’ and ‘C’ along

moment values of B and C is __________ BM.

(=0.1 mole) (Given atomic number of Mn is 25)

Ans. (8) (A)

Sol. 2rn = nd Neutral/acidic solution

CHEMISTRY TEST PAPER WITH SOLUTION

covalently bonded to the highly

(C) Intermolecular Hydrogen bonding is present (1) B = C = 2-Propanol

as compared to Ga and A

orbital, then the value of x + y is

correct answer from the options given below : (1) 4 (2) 2

CHEMISTRY TEST PAPER WITH SOLUTION

(E) Chemical reactions involve reorganisation of OH

below : NO2 NO2

The increasing order of boiling point is : 1 bond.

FINAL JEE–MAIN EXAMINATION – APRIL, 2024

CHEMISTRY TEST PAPER WITH SOLUTION

73. Consider the given chemical reaction :

= –0.46 + 0.34 = – 0.12V sequence : -

75. The number of moles of methane required to produce O

n = 4, |m| = 1 are 6 The initial rate of the reaction is recorded as r1

– 1 when the reaction starts with 1.5 atm pressure of A

12.5 cm Solvent front (Nearest integer)

6.5 cm Sample B Sol. 2A(g) + B(g) → C(g)

CHEMISTRY TEST PAPER WITH SOLUTION

Choose the correct answer from the options given NO2

– + Sol. As ligand field increases, light of more energy is

Sol. Graphite is conductor Sol. Theory based question

Reaction suggests that 1 mole of aniline give 1  661 × 1013 Hz

mole of orange dye.

CH3C  C – CH3   'P'

CHEMISTRY TEST PAPER WITH SOLUTION

(4) Exchanging the electrodes at anode and

reaction will become spontaneous above______ K.

central atom utilising 2p2 hybrid orbitals for

OC2H5 C6H6, BF3, C2H4Cl2

SO2, C2H4, BCl3, HCHO, C6H6, BF3

CHEMISTRY TEST PAPER WITH SOLUTION

IUPAC name of Compound A is 4-chloro-1, (2) Br

IUPAC name of Compound B is Ans. (3)

  4-ethyl-2-methylaniline = 5 mol 30 mol

B. Charcoal II. MCO3  MCl2  M2+

H Sol. In the reaction of S2O32– with I2, oxidation state of

Electron in t2g = 4(even)

COOH Ans. (55)

CHEMISTRY TEST PAPER WITH SOLUTION

yellow coloured precipitate obtained is : (1) C6H5CH2OH (2) C2H5OH

Anodic Reaction  T s  T  aq  e   2 estimate nitrogen in pyridine.

Overall Redox Reaction 2T  Cu 2 aq   2T 

vapourisation under same condition is ______ kJ (20e–) : 1s2,1s2,2s2,2s2,2pz2

 8.3  373.15 (14e–) : 1s2,1s2,2s2,2s2  2p2x  2p2y  2p 2z