Professional Documents
Culture Documents
Download textbook Advanced Dairy Chemistry Volume 1B Proteins Applied Aspects Fourth Edition Mcsweeney ebook all chapter pdf
Download textbook Advanced Dairy Chemistry Volume 1B Proteins Applied Aspects Fourth Edition Mcsweeney ebook all chapter pdf
https://textbookfull.com/product/advanced-dairy-chemistry-
volume-1a-proteins-basic-aspects-4th-edition-o-t-oftedal-auth/
https://textbookfull.com/product/cheese-fourth-edition-chemistry-
physics-and-microbiology-paul-l-h-mcsweeney/
https://textbookfull.com/product/dairy-engineering-advanced-
technologies-and-their-applications-1st-edition-chavan/
https://textbookfull.com/product/applied-chemistry-and-chemical-
engineering-volume-1-mathematical-and-analytical-techniques-
first-edition-balkose/
Amino Acids Peptides and Proteins Volume 41 Maxim
Ryadnov
https://textbookfull.com/product/amino-acids-peptides-and-
proteins-volume-41-maxim-ryadnov/
https://textbookfull.com/product/biological-and-medical-aspects-
of-electromagnetic-fields-fourth-edition-barnes/
https://textbookfull.com/product/neotropical-social-wasps-basic-
and-applied-aspects-fabio-prezoto/
https://textbookfull.com/product/internal-combustion-engines-
applied-thermosciences-fourth-edition-allan-kirkpatrick/
https://textbookfull.com/product/analytical-chemistry-for-
technicians-fourth-edition-kenkel/
Paul L. H. McSweeney
James A. O'Mahony Editors
Advanced Dairy
Chemistry
Volume 1B: Proteins: Applied Aspects
Fourth Edition
Advanced Dairy Chemistry
Paul L. H. McSweeney
James A. O’Mahony
Editors
Advanced Dairy
Chemistry
Volume 1B: Proteins: Applied Aspects
Fourth Edition
Editors
Paul L.H. McSweeney James A. O’Mahony
School of Food and Nutritional Sciences School of Food and Nutritional Sciences
Cork, Ireland Cork, Ireland
Springer Science+Business Media LLC New York is part of Springer Science+Business Media
(www.springer.com)
Preface to the Fourth Edition
v
Preface to the Third Edition
Advanced Dairy Chemistry—1: Proteins is the first volume of the third edi-
tion of the series on advanced topics in dairy chemistry, which started in 1982
with the publication of Developments in Dairy Chemistry. This series of vol-
umes is intended to be a coordinated and authoritative treatise on dairy chem-
istry. In the decade since the second edition of this volume was published
(1992), there have been considerable advances in the study of milk proteins,
which are reflected in changes to this book.
All topics included in the second edition are retained in the current edition,
which has been updated and considerably expanded from 18 to 29 chapters.
Owing to its size, the book is divided into two parts; Part A (Chaps. 1–11)
describes the more basic aspects of milk proteins while Part B (Chaps. 12–29)
reviews the more applied aspects. Chapter 1, a new chapter, presents an over-
view of the milk protein system, especially from an historical viewpoint.
Chapters 2–5, 7–9, 15, and 16 are revisions of chapters in the second edition
and cover analytical aspects, chemical and physiochemical properties, bio-
synthesis and genetic polymorphism of the principal milk proteins. Non-
bovine caseins are reviewed in Chap. 6. Biological properties of milk proteins,
which were covered in three chapters in the second edition, are now expanded
to five chapters; a separate chapter, Chap. 10, is devoted to lactoferrin and
Chap. 11, on indigenous enzymes in milk, has been restructured and expanded.
Nutritional aspects, allergenicity of milk proteins, and bioactive peptides are
discussed in Chaps. 12, 13, and 14, respectively. Because of significant devel-
opments in the area in the last decade, Chap. 17 on genetic engineering of
milk proteins has been included. Various aspects of the stability of milk pro-
teins are covered in Chap. 18 (enzymatic coagulation), Chap. 19 (heat-
induced coagulation), Chap. 20 (age gelation of sterilized milk), Chap. 21
(ethanol stability), and Chap. 22 (acid coagulation, a new chapter).
The book includes four chapters on the scientific aspects of protein-rich
dairy products (milk powders, Chap. 23; ice cream, Chap. 24; cheese, Chap.
25; functional milk proteins, Chap. 26) and three chapters on technologically
important properties of milk proteins (surface properties, Chap. 27; thermal
denaturation aggregation, Chap. 28; hydration and viscosity, Chap. 29).
vii
viii Preface to the Third Edition
ix
Preface to the First Edition
Because of its commercial and nutritional significance and the ease with
which its principal constituents, proteins, lipids, and lactose, can be purified
free of each other, milk and dairy products have been the subject of chemical
investigation for more than a century. Consequently, milk is the best-described
in chemical terms, of the principal food groups. Scientific interest in milk is
further stimulated by the great diversity of milks—there are about 4000 mam-
malian species, each of which secretes milk with specific characteristics. The
relative ease with which the intact mammary gland can be isolated in an
active state from the body makes milk a very attractive subject for biosyn-
thetic studies. More than any other food commodity, milk is a very versatile
raw material and a very wide range of food products are produced from the
whole or fractionated system.
This text on proteins is the first volume in an advanced series on selected
topics in dairy chemistry. Each chapter is extensively referenced and, it is
hoped, should prove a useful reference source for senior students, lecturers,
and research personnel. The selection of topics for ‘Proteins’ has been influ-
enced by a wish to treat the subject in a comprehensive and balanced fashion.
Thus, Chaps. 1 and 2 are devoted to an in-depth review of the molecular and
colloidal chemistry of the proteins of bovine milk. Although less exhaus-
tively studied than those of bovine milk, considerable knowledge is available
on the lactoproteins of a few other species and an inter-species comparison is
made in Chap. 3. The biosynthesis of the principal lactoproteins is reviewed
in Chap. 4. Chapters 5–8 are devoted to alterations in the colloidal state of
milk proteins arising from chemical, physical, or enzymatic modification
during processing or storage, viz. enzymatic coagulation, heat-induced coag-
ulation, age gelation of sterilized milks, and chemical and enzymatic changes
in cold-stored raw milk. Milk and dairy products provide 20–30 % of protein
in ‘western’ diets and are important worldwide in infant nutrition: lactopro-
teins in particular are considered in Chap. 9. The increasing significance of
‘fabricated’ foods has created a demand for ‘functional’ proteins: Chaps.
10–12 are devoted to the technology, functional properties and food applica-
tions of the caseinates and various whey protein products.
xi
xii Preface to the First Edition
xiii
xiv Contents
xv
xvi Contributors
Abstract
Due to the high intrinsic perishability of milk, strategies for its preserva-
tion by partial or almost complete removal of water have been studied and
used commercially for over a century. Today, milk-based powders (e.g.,
whole and skim milk powders) represent a very large sector of dairy com-
modity production and export trade, and demand for these products, for a
range of applications, is increasing. The technology of production of these
powders, based around pre-concentration of milk by multi-stage thermal
evaporation followed by spray drying in a range of related dryer types,
which vary in terms of design, method of atomisation and number of dry-
ing stages, is today very sophisticated. Key properties of milk powders,
such as their ability to flow, remain stable on long-term storage, and recon-
stitute on addition to water, are influenced by drying parameters.
Understanding these relationships allows processes to be manipulated in
order to yield tailored functionality for each application. The technology
of drying milk to produce the principal dairy powders is reviewed in this
chapter, along with the principal changes to milk constituents induced by
such processes, and the potential for use of these powders in applications
such as cheese and yoghurt manufacture
Keywords
Milk powder • Spray drying • Properties of milk powders • Dairy ingredients
• Powder applications • Speciality milk powders
1.1 Introduction
(Hall and Hedrick, 1975). The earliest modern 1.2 Types of Milk Powders
commercial concentrated dairy products were air-
dried concentrated milk tablets, developed in 1809 A wide range of dry dairy products is produced
by Nicholas Appert, vacuum-concentrated sweet- worldwide, a selection of which are listed in
ened condensed milks by Gail Borden in 1856 and Table 1.1. Milk powder is produced for local con-
sterilized concentrated milk (evaporated milk) by sumption, some as reconstituted milk but usually
J.B. Meyenberg in 1884. During the period 1850– mainly for use as an ingredient in other foods or
1900, several ‘solidified milk’ products were pro- for export. Developments in end-use applications
duced, e.g., that patented in 1855 by T.S. Grimwade of milk and milk-based powders, and tailoring
(UK), by adding sucrose, sodium carbonate and functionality for individual applications, was
cereal to concentrated milk. Roller-dried milk was reviewed by Sharma et al. (2012).
first produced by J.R. Hatmaker in 1902 in the UK, Much milk powder is traded internationally,
and roller-drying was the predominant method for from milk-rich to milk-deficient regions. The prin-
drying milk products, including infant formula, until cipal milk powder importing countries are listed in
the 1960s (Pearse, 1998). Spray drying was intro- Table 1.2. About 3.8 and 3.6 million tonnes of
duced to the chemical industry by Samuel R. Percy whole and skimmed milk powder, respectively,
in 1872; the process was improved gradually and were produced in 2009. The principal producers of
used to dry milk by J.C. MacLachlan in 1905
(Hunziger, 1926). Today, spray drying is essen-
Table 1.1 Range of dried dairy products
tially the only process used to produce milk pow-
Skim milk powder Butter powder
ders, which have become major, and growing,
Instant Cheese powders
dairy products. There is an extensive literature on
Regular Buttermilk powder
milk powders, including the following textbooks
Low-, medium-, high-heat Whey powders
and review articles: Hunziker (1926), Hall and
Whole milk powder Normal
Hedrick (1975), Rothwell (1980), Masters (1991), Instant Demineralised
Caric (1994), Písecký (1997), Westergaard (2003), Regular Delactosed
Tamime (2009), Skanderby (2011) and Schuck High free fat Caseinates (sodium,
(2011a, b) and Schuck et al. (2012). potassium, calcium)
Spray dryers have evolved in design and appli- Filled milk powder Rennet casein
cation, and now a range of dryer types is avail- Infant formulae Acid casein
able, suitable for the production of a wide variety Total milk proteinates
of dairy products. One of the key driving forces in Casein coprecipitates
dryer development has been the requirement of
consumers for convenient, easily reconstituted Table 1.2 Imports of whole milk powder (WMP) and
(‘instant’) powders, produced from whole or skimmed milk powder (SMP), in thousands of tonnes
skimmed milk, and a range of other dairy prod- (IDF, 2010)
ucts, such as whey and buttermilk. Increased Country WMP SMP
understanding of the chemical and physical China 382 128
changes which occur in milk during drying have Japan 0 35
paralleled developments in drying technology Korea 1 10
and enable very fine control of the properties, and Turkey 15 12
hence potential applications, of milk powders. EU 1 6
The modern processes used for the production USA 22 0
of dairy powders, the effects of these processes Russia 20 52
on the proteins and other constituents of milk, Brazil 52 11
and the properties of milk powders will be Australia 17 6
considered in this chapter. Mexico 27 165
1 Manufacture and Properties of Dairy Powders 3
WMP in 2009 were China (977), New Zealand be produced for nutritional reasons but it is done
(790), EU (739), Brazil (473), Argentina (235) and mainly for economic reasons (Hayman, 1995;
Australia (126), with all figures being in thousands Vignolles et al., 2010). The fat used is normally
of tonnes. The principal producers of SMP were cheaper than milk fat, e.g., lard, tallow or vegeta-
EU (1200), USA (778), India (364), New Zealand ble oils, for calf-milk replacers or vegetable oils
(360), Australia (190) and Japan (167), in thou- produced in an importing country blended with
sands of tonnes. Total exports of WMP in 2009 reconstituted imported SMP. The influence of oil
were 2.13 million tonnes, of which New Zealand type (sunflower and palm oil) and spray dryer out-
supplied 37 %, EU 22 %, Argentina 7 %, Australia let temperature, in terms of properties of fat-filled
6 %, and the rest of the world 30 %. Total exports milk powders was reported by Kelly et al. (2014).
of SMP in 2009 were 1.33 million tonnes, of Encapsulated milk fat powders (40–60 % fat)
which New Zealand supplied 30 %, USA 19 %, may be produced using a blend of emulsifying salts,
EU 17 %, Australia 13 %, and the rest of the world SMP and flour, starch or sucrose (Holsinger et al.,
21 %. Total exports of whey powders and whey 2000). Such powders, which have good flow prop-
products were 1.31 million tonnes, of which the erties and are resistant to oxidation, compared to
EU supplied 37 %, USA 30 %, New Zealand 7 %, other high-fat powders, may be used as substitutes
Switzerland 5 %, Australia 3 %, Canada 3 % and for vegetable shortenings in a range of food prod-
the rest of the world 15 %. ucts and in applications such as coffee whiteners.
The two principal commercial milk powders High-fat powders, which may be defined as
are SMP and WMP, which are generally classified powders with a fat content in the range 42–65 %
as either regular (non-instant) or instant. Food (Early, 1990; Munns, 1991), present certain prob-
applications of SMP and WMP are summarised in lems in drying due to the crystallisation of fat during
Table 1.3. Commercial SMP is also routinely clas- handling and storage. Pneumatic transport from
sified according to the pre-heat treatment applied dryers may not cool the powder sufficiently to crys-
(heat classification) as low- (or low-low-), tallise all the fat therein and some fat may crystallise
medium- or high-heat powders. Fat-filled, or subsequently on cooling in the package, releasing
filled, milk powders are products with a fat the latent heat of crystallisation and thus causes an
content close to that of WMP, produced by dry- increase in temperature, causing fat to melt and cak-
ing a blend of non-milk fat and skim milk ing of the powder, i.e., the formation of a solid mass
(Kelly et al., 2002). Fat-filled milk powder may of powder. This may be avoided by ensuring com-
plete fat crystallisation using a fluidised bed cooler
Table 1.3 Principal food applications of skim and whole
before packaging the powder (Early, 1998).
milk powders In recent years, a number of fractionated or
semi-refined milk protein powders have been
Skim milk powder
Reconstitution
developed for specific functional applications,
Cheesemaking (low-heat SMP) with many products arising from the selective use
Confectionery products of membrane technologies, such as microfiltra-
Ice cream and other desserts tion, ultrafiltration or diafiltration (Mistry and
Hot and cold beverages Hassan, 1991; Kelly et al., 2000). Kelly et al.
Recombined sweetened condensed milk (2000) described a method for the production of
Bakery products (high-heat SMP) native phosphocasein-rich powders using micro-
Calf milk replacers filtration and electrodialysis: the latter treatment
Recombined milk production improved the heat stability of the powder but seri-
Chocolate manufacture ously impaired its rennet coagulation properties.
Meat products Protein-enriched milk powders may be used as
Whole milk powder substitutes for SMP and have been shown to have
Reconstitution good functional properties for a range of food
Convenience soups and sauces applications (Mistry and Hassan, 1991). Garem
Milk chocolate (high free fat WMP) et al. (2000) described the manufacture of a milk
4 A.L. Kelly and P.F. Fox
powder with improved cheesemaking properties adding demineralised whey or whey protein
by partial removal of whey proteins by a combina- concentrate (WPC). Human milk lacks
tion of microfiltration and ultrafiltration. The pro- β-lactoglobulin, which is the most allergenic
duction of micellar casein powders with significant bovine milk protein for human infants. Bovine
potential application in cheese manufacture was whey proteins may be fractionated, and the
reviewed by Saboya and Maubois (2000). α-lactalbumin (α-la)-rich fraction used for
Hot tea or coffee is a rather hostile environ- infant formula. The β-lactoglobulin-rich frac-
ment (pH < 5, temperature up to 100 °C) for milk tion has better gelling properties than regular
and the SMP or WMP products produced in the WPC and is a valuable food ingredient;
1960s were unstable under these conditions. The • Lipids, e.g., sunflower oil, are added, to reflect
whey proteins were denatured and precipitated the fact that human milk fat is more unsatu-
on the surface of powder particles before they rated than bovine milk fat;
could dissolve; the particles flocculated and sedi- • The ash (mineral) content must be reduced, by
mented. Alternative ‘coffee whiteners’, made electrodialysis or membrane filtration of the
with sodium caseinate, vegetable oil, corn syrup dairy ingredient components, as it is around
and emulsifiers were developed and became four times higher than that of human milk and
widely used. Due to advances in understanding may cause renal overload;
the factors affecting coffee stability, modern • The blend may be fortified with vitamins and
SMP or WMP are suitable as coffee whiteners perhaps other important nutrients, e.g., lacto-
but casein-based products are still widely used, ferrin and milk oligosaccharides.
mainly because they are cheap.
Another highly specialised type of dried milk- The blend is pasteurised, homogenized and
based product is infant formula, which has been standardized, and then either spray-dried and pack-
produced as an alternative source of nutrition for aged or UHT-treated and aseptically packaged.
infants to breast milk since 1867, when Justus Formulae for healthy infants are normally of
van Leibig developed a product based on drying two types: ‘first-stage’ and ‘second-stage follow-
a mixture of whole milk, wheat flour, malt flour on’ formulae. Speciality formulae are available
and potassium carbonate in heated trays. The for infants with special needs, e.g., low birth-
commercial brand SMA (originally standing for weight, lactose intolerance, anti-regurgitation,
Synthetic Milk Adapted) was first produced in low-caloric, extensively hydrolysed and low phe-
the USA in the early twentieth century. nylalanine content (Maldonado et al., 1998;
Today, the manufacture of infant formulae is a Thompkinson and Khard, 2007).
highly specialised sector of the dairy industry
and these products are more properly referred to
as neutraceuticals rather than dairy products 1.3 Technology of Milk Powder
(O’Callaghan et al., 2011). The manufacturing Manufacture
protocol varies with the company and type of for-
mula, but a general protocol is shown in Fig. 1.1. The production of a number of common milk
The first step is preparation of the blend of powders has been described extensively (e.g.,
ingredients (mainly dry) with the following Písecký, 1997; Caric, 2003; Kelly, 2006; Schuck,
considerations: 2011a), and is summarised below.
Fig. 1.1 Schematic flowchart for the production of infant formula (from Montagne et al., 2009)
6 A.L. Kelly and P.F. Fox
milk powder of very high microbiological qual- approaches, such as steam-injection processes,
ity. Whole milk is usually standardised, typically have been developed (Murphy et al., 2013).
to a fat to solids-non-fat ratio of 1:2.76, to control As discussed in Sect. 1.2, skim milk powder
the fat content of the final powder. (SMP) is often classified according to the heat
treatment applied during preheating. There are
three principal heat categories: low heat (typi-
1.3.2 Preheating and Concentration cally heated at 75 °C for 15 s), medium heat (typ-
ically heated at 75 °C for 1–3 min) and high heat
Heating of milk immediately before evaporation (heated at 80 °C for 30 min or 120 °C for 1 min);
ensures the microbiological quality of the con- some manufacturers may also produce a low-low
centrate and of the final powder, but is also a criti- heat product, with even a milder heat treatment
cal step in the control of the functional properties than that for low-heat products (often minimum
of the powder; the exact conditions vary depend- pasteurisation). Whole milk powder (WMP) is
ing on the product in question, as discussed generally not heat-classified, but the concentrate
below. Preheating is usually the highest tempera- is heated at 85–95 °C for several minutes to
ture step applied during manufacture and is there- ensure inactivation of indigenous lipase and to
fore the step at which most whey protein expose sulphydryl groups with antioxidant activ-
denaturation occurs (Singh and Creamer, 1991). ity (Hols and Van Mil, 1991).
Preheating may be performed using any of a After pre-heating, the milk is concentrated to
range of heat exchangers, including plate heat 45–50 % or 42–48 % total solids (TS) for whole
exchangers, spiral heat exchangers wrapped or skim milk, respectively. Typically, evaporation
around the tubes in the evaporator itself or using is performed in a multiple effect (stage) falling-
very short-time steam injection heating systems. film evaporator, where thermal efficiency is max-
Direct heat exchangers are preferred over indi- imised by maintaining each subsequent effect at
rect systems, as biofilms of thermophilic bacteria progressively lower pressure, and thus reduced
may develop within indirect heat exchangers boiling point, allowing the vapour from each
(Early, 1998). In recent years, new technological effect to be used as the heating medium for the
Fig. 1.2 Schematic diagram of a triple effect evaporator mix vapour from the first effect with steam and compress
showing (1) first effect, (2) second effect, (3) third effect, (4) the mixture, thereby increasing its temperature and allowing
thermocompressor, (5) vapour condenser and (6) vacuum its use as heating medium for the first effect and reducing
pump; calandria (A) and vapour-liquid separating cyclone the overall consumption of steam
(B) are shown. The function of the thermocompressor is to
1 Manufacture and Properties of Dairy Powders 7
such as the production of WMP with a high free Particle size and, in particular, the distribution of
fat content, which is desirable for chocolate particle sizes is very important in determining the
manufacture (Clarke and Augustin, 2005). properties of milk powder, as will be discussed in
Today, the majority of milk powder is pro- Sect. 1.5. Atomisation may be achieved using
duced by spray drying, as summarised briefly in nozzles under pressure or by centrifugal force
the following section. For more detail on techno- using a rotating disk or wheel. Pressure nozzle
logical and engineering aspects of this process, atomisers have either grooved core inserts or swirl
comprehensive descriptions have been given by chambers to impart rotary motion to the feed
Hansen (1985), Masters (1991), Westergaard (Masters, 1991). The selection of atomiser type is
(1994, 2003), Caric (1994), Písecký (1997) and critical in determining the properties of the pow-
Refstrup and Bourke (2011). der produced. For maximum flexibility, different
In spray dryers, concentrate is taken from the types of atomiser can be used interchangeably in
evaporator, using a positive displacement pump, to many spray dryers. The influence of pressure noz-
an atomiser, usually located at the top of a spray zle and centrifugal atomisers on the properties of
drying chamber, which produces a spray of drop- milk powder is compared in Table 1.4.
lets which contact hot air and are dried to individ- There are three principal classes of spray
ual powder particles. The concentrate is generally dryer, based on the number of separate drying
heated to ~72 °C before atomisation, to reduce stages (one, two or three) used to achieve the final
viscosity and obtain optimal atomisation. The moisture content of the powder (typically 3–5 %;
objective of atomisation is to convert the liquid Woodhams and Murray, 1978). These spray dryer
feed to a spray of droplets, 10–400 μm in diameter. types are illustrated in Fig. 1.4.
Fig. 1.4 (continued) dryer (CSD, three stage) with annu- rotary), (3) main drying chamber, (4) cyclone, (5) external
lar integrated and external fluidised beds; (vi) multi-stage fluidised bed cooler, (6) external fluidised bed dryer, (7)
spray dryer (MSD, three stage) with circular integrated integrated annular bed dryer and (8) integrated circular
and external fluidised beds. Dryer components indicated bed dryer
include (1) hot air inlet, (2) atomiser (may be nozzle or
1 Manufacture and Properties of Dairy Powders 9
Single Stage
(i) Feed In (ii) 1 Feed In
1
2
4 4
2
3
3
5
Product Out
Product Out
Two Stage
(iii) Feed In (iv) Feed In
1 1
4 4
2 2
4
3 3
7
Product Out
Product Out
Three Stage
(v) Feed In (vi) 1 Feed In
1
4
4
4
2 2
3
3
7 8
6
6
Product Out
Product Out
Fig. 1.4 Common spray dryer configurations used for the fluidised bed cooling and conveying; (iii) two-stage dryer
manufacture of milk powder: (i) single-stage dryer with with external fluidised bed dryer; (iv) two-stage dryer
pneumatic powder conveying; (ii) single stage dryer with with integrated fluidised bed dryer; (v) compact spray
10 A.L. Kelly and P.F. Fox
In single-stage dryers, the whole drying pro- results in poor-quality non-instant, dusty powder.
cess occurs in the main cylindro-conical chamber In two- and three-stage drying the powder exits
of the spray dryer itself. Critical parameters the main drying chamber at a higher moisture
which determine both the quality of the final content (~10–15 %) than in a single-stage pro-
powder and the efficiency of the drying process cess, and drying is completed in additional dry-
are the temperature of the drying air on entry to ing stages. Thus, in two-stage drying, the main
and exit from the main chamber [Tinlet (typically chamber is followed by a fluidised bed dryer
160–220 °C) and Toutlet (typically 70–90 °C)]. while in three-stage spray dryers, the spray dryer
During drying, milk droplets are cooled continu- chamber is followed sequentially by an integrated
ously by loss of the latent heat of evaporation, fluidised bed and an external plug-flow fluidised
and generally never reach a temperature greater bed (Boersen, 1990). The two main categories of
than 70 °C during drying. Initially, droplets lose three-stage spray dryers used for milk powders
moisture at a constant rate, while saturation con- are those with an internal annular fluidised bed
ditions exist at the surface, but eventually satura- surrounding the air outlet (compact spray dryers,
tion can no longer be maintained and the rate of CSD) or dryers with an internal circular fluidised
drying decreases as a hard dry shell forms at the bed (multi-stage dryers, MSD).
droplet surface. If this shell becomes too solid or Separation of drying into two or three stages
thick, case-hardening occurs, preventing further allows for improved control of powder proper-
drying. If exposed to a high air temperature at the ties, greater efficiency of the drying process and,
end of drying (Toutlet), steam and air within pow- because the rate of heat introduction is adjusted to
der particles may expand, forming large vacuoles the rate of evaporation, the process is milder than
and, potentially, fracturing the powder particles, single-stage processes (Písecký, 1997). Another
resulting in an increased level of small, light advantage of two- or three-stage spray drying is
powder fragments (fines). The rate of drying that such processes are suitable for drying high
should be controlled so that the end of the falling TS concentrates without deterioration of product
rate drying period coincides with the end of heat- solubility. Two- and three-stage drying systems
ing and drying. The use of advanced process con- also have reduced stack losses (Písecký, 1997).
trol technologies in spray drying to optimise Movement of powder within the drying plant
processes based on understanding the thermody- may be achieved either by using a fluidised bed
namic properties of concentrated foods and rheo- or pneumatic system, although the latter method
logical properties during atomisation, among breaks up agglomerates, and is suitable only for
other factors, was reviewed by O’Callaghan and powders of high bulk density. Milk powder may
Cunningham (2005). be sifted for size classification, and then either
Air exiting the chamber carries a significant packaged directly, filled into intermediate trans-
amount of light powder particles and fines, which portation containers, or transferred to silos for
are removed from the air by passage through storage before packaging. Milk powder may be
cyclone separators and/or by using bag filters or packaged into wholesale, catering or retail packs
occasionally wet-scrubbing systems. Recovered (Warren, 1980). Generally, milk powder is pack-
powder is added to the main bulk of powder, aged in multi-layer paper bags with a polyethyl-
which is removed from the base of the drying ene inner lining. WMP may be packaged in an
chamber, either by a pneumatic conveying sys- inert atmosphere, where air is displaced by N2 or
tem or a fluidised bed using cold air to cool and a mixture of N2 and CO2, to improve oxidative
transport the powder. stability during storage. Occasionally, WMP may
Completion of drying in a single stage neces- be packed in tins or plastic containers, or in bags
sitates the use of a high air temperature (the air is consisting of multi-layer laminates incorporating
typically indirectly heated using steam-filled metal foil and high density plastic films (Varnam
tubular heat exchangers to 200–250 °C), which and Sutherland, 1994).
1 Manufacture and Properties of Dairy Powders 11
component mainly responsible for self-heating. in milk proteins during drying and subsequent
Contamination with NaOH residues left after storage, and implications for nutritional quality,
cleaning reduces MIT. The causes of fires in in terms of the level of available lysine, were
spray dryers and their prevention are also dis- reviewed by Higgs and Boland (2008), while Le
cussed by Písecký (1997). et al. (2013) studied the impact of cross-linking
The potentially most serious problem with due to the Maillard reaction on protein solubility
spray drying milk powders is dust explosions, during storage of powder. The Maillard reaction
which occur when finely dispersed combustible is discussed in more detail in Sect. 1.4.2 below.
solids are exposed to an ignition source. The rate of the increase in temperature during
They occur under the following conditions preheating may affect whey protein interactions.
(Písecký, 1997): Indirect heating (with a slower heating rate)
favours whey protein-whey protein interactions
• Sufficient concentration (usually around 50 g/ and higher overall denaturation of whey proteins
m3) of an explosive airborne dust; than more rapid direct heating methods, which
• A source of ignition; favour extensive casein-whey protein interac-
• Presence of oxygen in the surrounding tions (Early, 1998). This may be related to the
atmosphere. fact that when milk is heated at a relatively low
temperature, formation of disulphide bonds pre-
dominates, while a higher temperature is required
1.4 Physico-Chemical Changes for the thermal reduction of disulphide bonds and
to Milk Constituents During thus sulphydryl-disulphide interchange reactions
Drying (de Wit, 1981). Therefore, as caseins do not pos-
sess free sulphydryl groups (Swaisgood, 1992),
1.4.1 Proteins more gentle heating will favour whey protein-
whey protein interactions.
On preheating at a temperature above 75°C at Holding concentrate at a temperature above
pH ~ 6.5, β-lactoglobulin is denatured, causing 60 °C for an extended period before spray drying
significant alterations to its secondary and ter- can cause aggregation of casein micelles, increas-
tiary structures, and at a temperature above 90°C, ing the viscosity of the concentrate and affecting
extensive whey protein denaturation occurs. the reconstitution properties of SMP (Muir,
Denatured β-lactoglobulin and, to a lesser extent, 1980). During the actual processes of evapora-
α-lactalbumin, complex via disulphide bond for- tion and spray drying, relatively little denatur-
mation with κ-casein (Noh and Richardson, ation of whey proteins occurs, as the final
1989; Corredig and Dalgleish, 1999; Fairise temperature of milk generally does not exceed
et al., 1999). When milk is heated at a pH < ~6.8, 70 °C (Singh and Creamer, 1991). Oldfield
the complexes remain attached to the surface of (1998) reported only small decreases in the levels
the micelles but, on heating at more alkaline pH of native α-lactalbumin and BSA during evapora-
values, the complexes are found in the serum tion, and no apparent denaturation of
phase (Creamer and Matheson, 1978; Mohammed β-lactoglobulin. However, association of whey
and Fox, 1987; McKenna et al., 1999). Oldfield proteins with casein micelles can occur during
(1998) showed that, as well as interacting with evaporation, probably because decreasing pH
casein micelles, β-lactoglobulin forms disulphide- reduces protein charge, facilitating association
linked aggregates with bovine serum albumin reactions (Oldfield, 1998). Singh (2007) reviewed
(BSA) during the manufacture of milk powder, the interactions of milk proteins during milk
while α-lactalbumin mainly forms hydrophobic- powder manufacture, and related changes during
bonded aggregates. The roles of Maillard reac- drying to changes in micelle structure during the
tions and isopeptide bond formation in changes concentration of milk.
Another random document with
no related content on Scribd:
A BUBBLE REPUTATION
One crowded hour of glorious life
Is worth an age without a name.
Or take, once more and to end, the sentence: “The Past is that
paradoxical possession, a Shadow which we would not drop for the
Substance”; which evoked the following from “One who has felt the
Weariness, the Fever, and the Fret”—