TRNG I HC S PHM K THUT TP.

H CH MINH KHOA CNG NGH HA HC V THC PHM

GVHD: Ts. Nguyn Tin Lc

TN DNG PH PHM C TRA - BASA

L/O/G/O

M u
Theo s liu ca B Thy sn (MOFI) sn lng c Tra v c Basa Vit Nam vo khong 300000 tn (2004) ,400000 tn (2005), 825000 tn (2006) v 1 triu tn (2010).

Phn ph phm c Tra v c Basa trong ch bin phil (u, xng, m c) chim t 65 70%.

Nhu cu th trng
Du biodiesel Ngun du m, than v kh t nhin u c hn v vi tc s dng chng nh hin nay th s b cn kit hon ton vo cui th k 21. Biodiesel l mt s thay th y tim nng

Nhu cu th trng
Du biodiesel

ng Trnh Minh T, Gim c Cty TNHH Minh T - Green Biofuel Co.LTD cho bit: xut khu sang Singapore 200.000 lt/thng, sau s tng ln 2 triu lt/nm. Trong nc: tiu th 400-500 thng/thng (18 lt/thng), m bi trn ng c 10 tn/thng.

Nhu cu th trng
Du c:

Con ngi: 20.000 tn (2001), 90.000 tn(2009), 500.000 tn (2015). Thc n chn nui (2020 ): Hm lng du c 10% thiu 744.000 tn Hm lng du c 7,5% thiu 546.000 tn Hm lng du c 5% thiu 318.000 tn.

Nhu cu th trng
Collagen: Cc sn phm sa v ung cha collagen lun c ngi tiu dng quan tm mc d gi kh cao. Sa u nnh cha collagen (nhp khu t Thi Lan) ln n 7.000 ng 7.500 ng/hp (150 ml), cao hn gn gp i so vi sa u nnh ca cc doanh nghip sn xut trong nc.

Nhu cu th trng
Collagen:
Nc collagen (hng kiwi v cherry) ca mt doanh nghip trong nc sn xut c gi n 12.500 ng/lon 190 ml. C ph en collagen v c ph sa collagen (dnh cho ngi n king) th ln n 60.000 ng 65.000 ng/hp 10 gi nh.

Nhu cu th trng
Collagen:

Gi c tra ng lnh xut khu 2-4 USD/kg, gi collagen 25-30 USD/kg gi ph phm cao gp 8-10 ln gi chnh phm. Theo d bo kt qu kinh doanh nh my sn xut collagen ca Vnh Hon sn lng 2012 t khong 1.000 tn ch yu s xut khu sang M v cc nc thuc Lin minh chu u.

Tng quan ngun gc nguyn liu

C Tra: Tn ting Anh: Shutchi catfish Tn khoa hc: Pangasius hypophthalmus Thnh phn ha hc Calo (cal) Calo t Tng Cht cht bo
L/O/G/O

Chlesterol Natri (mg) (mg)

Protein (g)

cht

bo

bo(g bo ) ha(g)

124.5

30.84

3.42

1.64

25.2

70.6

23.42

Tng quan ngun gc nguyn liu

C tra c thn di, khng vy, mu en xm, bng hi bc, ming rng v c i ru di. Vy ngc vy lng c mt tia vy cng y l loi c nhit i nn c th sinh trng v pht trin nhit t 25-37.

Tng quan ngun gc nguyn liu

C Basa: Tn ting Anh: Yellowtail catfish Tn khoa hc: Pangasius bocourti Thnh phn ha hc

Protein(%)

Lipit (%)

Tro (%)

Nc(%)

12.2

16.04

18.8

66.8

Tng quan ngun gc nguyn liu

u c ba sa ngn, hi trn, dp bng, trn rng. C 2 i ru, ru hm trn bng chiu di u, ru mp di ti hoc qu gc vy ngc. Mt to, bng to, l m rt ln, phn sau thn dp bn, lng v u mu xm xanh, bng trng bc.

Tng quan ngun gc nguyn liu

Da c M c Tra, Basa Thnh phn ch yu ca m c Tra v Basa
Axit bo khng no (%) Axit bo no

C Tra

57,97

28,87

C Basa

64,17

25,30

Tinh ch du c
Mu sc Mi v

Thnh phn

Tinh ch du c
Du c th

M c

Trung ha bng NaOH

Ct khc
Ra du Kh mu bng than hot tnh Lng, ly tm

Lm tan chy
Lm lnh

Tch chit

Tch m cng

Kh mi bng hi nc

Sy loi nc

Du c th

Du tinh ch

Metyl este ha biodiesel t m c

S chung tng hp biodiesel t du, m ng thc vt bng phng php trao i este c s dng xc tc
Ru

Ru thu hi
Du thc vt hoc m ng vt

Phn ng

Lng

Ra

Tinh ch

Sy kh

Xc tc

Axit v c

Trung ha Chng ct

Lng

Sy kh

Axit bo

Metyl este ha biodiesel t m c

Cho nguyn liu v xc tc vo thit b phn ng dng khuy l tng c gia nhit thc hin phn ng trao i este. Sn phm ca phn ng c chuyn sang thit b lng trng lc, ti y sn phm tch thnh 2 pha. + Pha nng cha ch yu l glyxerin nn c chuyn sang qu trnh thu hi glyxerin. + Pha nh cha ch yu l biodiesel, c bm vo thit b ra bng nc loi b metanol, glyxerin v cc cu t tan khc b ln vo. Nc ra c em chng thu hi metanol, cn sn phm biodiesel c lm sch v chuyn sang thit b sy chn khng sy kh. Cng ngh sn xut biodiesel c th thc hin gin on hoc lin tc.

Metyl este ha biodiesel t m c

Cc yu t nh hng n phn ng trao i este: nh hng ca lng nc v axit bo t do trong nguyn liu nh hng ca tc khuy nh hng ca t l metanol/du (m) nh hng ca nhit nh hng ca lng xc tc nh hng ca thi gian phn ng

HOT HA DU C LM GIU DHA

Acid docosahexaenoic (DHA) l mt acid bo bt bo ha a thuc nhm -3. Tc dng: Bo thai v tr s sinh. Th gic v mng t bo. Thnh phn cu to nn mng t bo cht xm v no. Bnh tim mch. Bnh thp khp. Bnh vim khp mn tnh. Huyt p v hm lng lipid trong huyt tng

HOT HA DU C LM GIU DHA

S dng phng php ethanol gii bng lipase kt hp chng ct phn on. Nguyn tc: Thc hin phn ng ethanol gii c hiu du c nh lipase => acylglycerol (nhiu DHA) v ethyester(nhiu a.bo bo ha & khng bo ha 1 ni i) Chng ct phn on thu DHA cha trong acylglycerol

HOT HA DU C LM GIU DHA

S quy trnh hot ha DHA t du c

HOT HA DU C LM GIU DHA

M c th hm lng DHA 0,59% => sn phm du c DHA 12,2%. Thch hp b sung vo thc phm v thc phm chc

nng

Phn tch collagen t da c

Nghin cu tch chit collagen t da c
Kho st thnh phn da c m, tro, cht hu c: xc nh bng phng php sy nung n khi lng khng i Bo: xc nh bng phng php soxlet Cc nh hng ca sn phm collagen: bo, tp cht noncollagen, sc t, mi Hydroxyproline: xc nh bng phng php so mu Loi bo, tp cht noncollagen bng LasNa1% v NaOH0.5%

Chn phng php x l

Kho st thnh phn da c sau x l

Ty mu, mi bng H2O2% v NaOH 0.01M

Kho st qu trnh tch chit collagen bng acd acetic

Cc yu t nh hng n qu trnh tch chit Chn thng s tch chit

Nhit : 30C, 100C, 170C Nng : 0.25M, 0.5M, 0.75M, 1M Ch : tnh, ng (tc khy, t l d/D) T l rn/lng; 1/50 Thi gian: 24h

Hiu sut tch chit

Phn tch hm lng hydroxyproline trong dch chit Kt ta NaCl 0.9M Lc Bm chn khng

Thu nhn collagen

Lc Ly tm lc

Tinh sch collagen sau chit

Thm tch

Mng cellophan

Sy thng hoa

T l rn/lng trong mng, thi gian, nhit CO2 siu ti hn

Tch bo

Kho st sn phm

Cu trc sn phm

Thnh phn

Ch tiu nh gi cht lng biodiesel

Ch tiu nh gi T trng nht (40oC, mm2/s) Nhit chp chy, oC Hm lng nc, % th tch Glyxerin t do, % khi lng Hm lng lu hunh, % khi lng Hm lng photpho, % khi lng Ch s axit, mg KOH/g nhin liu n mn tm ng (3h, 50oC) Tr s xetan Cn cacbon, % khi lng Tng lng glyxerin, % khi lng Gi tr 0,8 - 0,9 1,9 - 6,0 min 130 max 0,05 max 0,02 max 0,05 max 0,001 max 0,8 < No3 > 47 < 0,05 max 0,24

LA CHN BAO B, NHN HIU

Du biodiesel

La chn bao b, nhn hiu

La chn bao b, nhn hiu

Cc sn phm DHA

La chn bao b, nhn hiu

Cc sn phm DHA

Hiu qu kinh t
U IM
Tr s xetan cao Gim lng cc kh pht thi c hi Kh nng bi trn cao nn gim mi mn C kh nng phn hy sinh hc An ton v chy n tt hn Ngun nguyn liu cho tng hp ha hc C kh nng nui trng c

Hiu qu kinh t
U IM
a dng ha nn nng nghip v tng thu nhp vng min nng thn Hn ch nhp khu nhin liu diesel, gp phn tit kim cho quc gia mt khong ngoi t ln NHC IM Biodiesel c nhit ng c cao hn diesel mt t gy kh khn cho cc nc c nhit vo ma ng thp

HIU QU KINH T
NHC IM Biodiesel c nhit tr thp hn so vi diesel Chi ph sn xut cao, do lm cho gi thnh biodiesel kh cao. Biodiesel thng c sn xut ch yu l theo m nn nng sut thp, kh n nh c cht lng sn phm cng nh cc iu kin ca qu trnh phn ng. Nhng sn phm c tinh ch v hot ha ln l nguyn liu tt cho cc sn phm nh sa,.mang li gi tr kinh t cao cho sn phm v gip a dng ha sn phm

Tnh hnh sn xut biodiesel trn th gii

Biodiesel bt u c nghin cu v s dng mt s nc tin tin vo nhng nm 1980. Hin nay c hn 28 quc gia tham gia nghin cu, sn xut v s dng biodiesel
Nc c Php Italia o Ty Ban Nha an Mch Anh Thy in Tng lng Sn lng 1.088.000 502.000 419.000 100.000 70.000 44.000 15.000 8.000
2.246.000

Tnh hnh sn xut biodisel trong nc

Cc nh khoa hc Vit Nam cng bt tay vo nghin cu v sn xut biodiesel phng th nghim v quy m sn xut nh Nc ta ang c nhng d kin sau: Giai on 2011-2015 Vit Nam s bt u sn xut ph gia v enzyme cng nh cc nguyn liu cho sn xut nhin liu sinh hc v m rng sn xut, m rng quy m cc nh my sn xut nhin liu sinh hc n nm 2015, sn lng ethanol v biodiesel trong nc t 250 nghn tn, p ng 1% nhu cu xng du ca c nc. n nm 2025, Vit Nam c mt ngnh cng nghip nhin liu sinh hc hin i, sn lng nhin liu sinh hc t 1,8 triu tn, p ng 100% nhu cu ca quc gia v xng E5 v B5, p ng 5% nhu cu xng du ca c nc.

Tnh hnh sn xut biodisel trong nc

Du sinh hc khng ch c sn xut t m c m cn t mt s nguyn liu khc nh: Cy Jatropha curcas.L, qu ca cy bi li,.

Cc sn phm c b sung colagen

Cc sn phm c b sung DHA

Cm n thy v cc bn lng nghe bi bo co ca nhm 2.Chc cc bn hc tt

Ngi trnh by: Nguyn Th Bo Khnh Hunh Th Bch Hnh Nguyn Th Kim Hng Phan Th Bch Nga Lm Nguyn Duy Anh Phm Huyn Ngn L Th Kiu