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  • Diazotization HCL + Nano: NH N N CL

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    Charles Jeff Doria
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    1. Aniline is diazotized with HCl and NaNO2 to form phenyldiazonium chloride. 2. Phenyldiazonium chloride is coupled with β-naphthol in the presence of NaOH to form the azo dye 1-phenylazo-2-naphthol. 3. The document describes the synthesis of an azo dye from aniline through diazotization and coupling reactions.

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    1. Aniline is diazotized with HCl and NaNO2 to form phenyldiazonium chloride. 2. Phenyldiazonium chloride is coupled with β-naphthol in the presence of NaOH to form the azo dye 1-phenylazo-2-naphthol. 3. The document describes the synthesis of an azo dye from aniline through diazotization and coupling reactions.

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    8 views8 pages

    Diazotization HCL + Nano: NH N N CL

    Uploaded by

    Charles Jeff Doria
    1. Aniline is diazotized with HCl and NaNO2 to form phenyldiazonium chloride. 2. Phenyldiazonium chloride is coupled with β-naphthol in the presence of NaOH to form the azo dye 1-phenylazo-2-naphthol. 3. The document describes the synthesis of an azo dye from aniline through diazotization and coupling reactions.

    Copyright:

    © All Rights Reserved
    Download as PPTX, PDF, TXT or read online from Scribd
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    of 8

    N

    NH2 Cl- +
    N

    diazotization
    HCl + NaNO2
    aniline phenyldiazonium
    chloride
    N N
    Cl- +
    N N
    OH OH
    coupling
    +
    NaOH
    phenyldiazonium β-naphthol 1-phenylazo-2-
    chloride naphthol
    N
    NH2 Cl- +
    N

    diazotization
    HCl + NaNO2
    aniline phenyldiazonium
    chloride
    N
    Cl- +
    N
    OH
    coupling N
    + N
    NaOH OH
    phenyldiazonium β-naphthol
    chloride

    1-phenylazo-2-
    naphthol
    .. N HCl N HCl N
    Na+ O - O O O ≡O + H2O
    +N
    ..

    .. HO H2O+

    ..
    ..

    .. ..
    1

    .. N HCl .. N HCl
    Na+ O O
    ..

    ..
    O - ..
    .. HO..
    ..

    ..

    -H2O 2
    N +N ≡O

    ..
    H2O+ O
    ..

    ..
    ..
    H H H H
    1 .. 2
    N N+  N=O

    ..
    .. 
    NaNO2
    ..
    +N ≡O

    3 ..
    H H 4
    .. .. ..
    ..
    N N=O N+=N..
    OH
    ..

    HCl  Cl⊖
    nitrosoamine

    5 6
    .. .. .. 
    N =NOH2 -H O
    .. ..
    N =N..
    OH 2
    ..
    HCl
    n-hydroxyazo
    compound
    ⊖
    Cl 
    N≡N
    7
    phenyldiazonium chloride
    .. ⊖ ..
    O OH

    ..
    ..
    ..

    Na I I
    .. N HCl .. N HCl
    O O
    ..

    ..
    ⊖
    .. O ⊖
    ..
    ..

    ..
    .. ..

    -H2O 2
    N +N ≡O

    ..
    H2O+ O
    ..

    ..
    ..
    .. ⊖
    O--H  ⊖ O

    ..
    ..
    Na OH

    .. .. N≡N
    O
    ..


    ⊖

    N
    N
    O

    N
    1-phenylazo-2-
    N
    naphthol
    OH

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