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Syllabus
• Introduction to Advanced Ceramics-Barium
Titanate, Ferrites, Silicon Carbide, Alumina,
Ceramics, its classifications and their
applications, Introduction to Cermets and its
application
Introduction to Advanced Ceramics
Advanced ceramic materials include the area
of materials having their own characteristics
e.g., magnetic, electrical, dielectric,
pyroelectric, piezoelectric, conductivity,
semiconductivity, superconductivity and other
areas.
CLASSIFICATION OF ADVANCED CERAMICS
Based on Chemical composition
Oxide ceramics Al2O3, SiO2, ZrO2, MgO, Fe2O3, BeO, CaO, TiO2, SnO2, ThO2,
PuO2, UO2 and oxides of rare earth elements
Non-oxide Carbides (SiC, B4C, TiC, ZrC, Mo2C, VC, WC, ThC, HfC, NbC)
ceramics Nitrides (BN, Si3N4, TiN, ZrM, TaN, UN, ThN, SiAlON),
Borides (Ti2B, ZrB2, TaB2, HfB2, ThB2)
Silicides (MoSi2, ZrSi, ZrSi2, Ti5Si3, TaSi2, TiSi2)
Titanic ceramics BaTiO 3 , SrTiO 3 , CaTiO 3
(Titanium
Sulphidic ceramics BaS, CeS, US, ThS, CdS, ZnS
Metal ceramics Al2O3, ZrO2, MgO, BeO, ThO2, Y2O3 + W, V, Mo, Ta, Ti, Zr, Si,
(Cermets) Cr, Co, Ni, Nb
Barium Titanate,
• Barium titanate is a member of a large family of
compounds with the general formula ABO3 called
perovskites.
• The perovskite family includes many titanates used in
various electro-ceramic applications, for example,
electronic, electro-optical, and electro-mechanical
applications of ceramics.
• Barium titanate, perovskite structure, is a common
ferroelectric material with a high dielectric constant, widely
utilized to manufacture electronic components such as
mutilayer capacitors (MLCs), PTC thermistors, piezoelectric
transducers, and a variety of electro-optic devices.
• Pure barium titanate is an insulator whereas
upon doping it transforms into a
semiconductor. It is also used in sensor
applications.
• The ferroelectricity observed in barium
titanate is utilized in memory applications, i.e
RAMs. The pyroelectricity and piezoelectricity
are also used in the passive infrared detectors
and Sonars (Sound Navigation and Ranging).
BaTiO3 Properties
•Perovskite Structure
•Piezoelectricity
BaO + TiO2
BaTiO3
Uses for BaTiO3
• Underwater Sonar • Ultrasonic Therapy
• Guided Missiles • Electronic Materials
• Acoustic Mines • Ultrasonic Cleaning
• Sound Reproduction • Filters
Ceramic Capacitors
• Multilayer Ceramic Capacitors (MLCC)
Iron-Silicon Alloys The addition of too much silicon makes the material
used for extremely brittle and difficult to produce, giving
transformer cores a practical limitation of 4wt%
The main advantage of ferrites is that they are extremely low cost, due to
the ease of processing and the low cost of raw materials, which makes
them the most widely used permanent magnet material.
Most common applications for SiC ceramics utilize their high hardness,
chemical resistance, and abrasion resistance.
Applications include
Seals and valves,
Rocket nozzles,
Wear plates for spray drying,
Wire dies.
Thrust bearings, Ball bearings,
Pump impeIlers, Extrusion dies.
Heat exchanger tubes.
Silicon carbide heating elements are widely used for years
Metal Oxides Ceramics
Alumina
• Alumina was originally developed for refractory tubing and high-
purity crucibles for high-temperature use and now has wide
application
• Exhibits rhombohedric crystal structure
• Alumina has high hardness, wear resistance, high modulus, inertness,
refractoriness and adequate strength
• Alumina serves well at temperature as high as 19000C
• Above 20000C, its strength drops
• Alumina have good creep resistance up to 8200C
• Mineral name: corundum, sometimes termed sapphire after the blue
gemstone variety of corundum
Alumina
Aluminum oxide is
commonly doped
with magnesium oxide,
cold-pressed, and sintered,
producing the type of
microstructure shown
in Fig.
Equiaxial ZrO2
particles (bright)
dispersed in
alumina (ZTA).
Alumina
Applications of Alumina
A classic example of the
application of alumina is
in spark plug insulator material
Alumina is commonly used for high-quality electrical
applications where low dielectric loss and high
resistivity are needed
Alumina is used as bio-inert material in various
orthopedic devices such as knee joint etc.
Abrasives
Fuel cell parts
Metal Oxides Ceramics
Zirconia
Since the mid-1980s, zirconia is used as high-
performance ceramics
Has extreme inertness to most metals
Retain its strength up to 22000C
Pure zirconia is polymorphic.
Cermets
• The objective to combine the properties of ceramics,
such as hardness resistance to oxidation heat
resistance with the properties of metals, such as
toughness impact strength in order to create an ideal
cutting material, produces “cermets“.
• The first tungsten-carbide-free hard metal – the first
cermet – was patented by PLANSEE in the year 1931
(inventors: P. Schwarzkopf and J. Hirschl).
• This alloy (TiC, Mo2C, Ni [Co,Cr]) was considerably
more brittle than the cermets of today, demonstrating
erratic performance due to unsuitable conditions and
processes of the time.
Electrical components: can get extremely hot, they
need to behave like ceramics but, since they also need
to conduct electricity, it helps if they work like metals.
Ex. resistors and vacuum tubes (valves).
Machine tools: Titanium carbide (TiC), is a popular
choice of cermet for tools used in milling, turning and
boring, and for making threads and grooves.
Typically cermet tools are made from either titanium
carbide alone, titanium carbide and titanium nitride
(TiN), or titanium carbonitride (TiCN). They provide
higher cutting-tool speeds, better surface finish, than
traditional tool parts. Unlike tools coated in carbide,
cermet-coated tools do not wear in the same way but
effectively regenerate themselves.