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Coatings and Inhibitor CH 15
Coatings and Inhibitor CH 15
Corrosion Monitoring
• Weight loss coupons
• Electrical resistance
• Linear polarization
• Hydrogen penetration
• Galvanic current
Classification of corrosion protection methods
• Metallic coatings provide a layer that changes the surface properties of the workpiece
to those of the metal being applied. The workpiece becomes a composite material
exhibiting properties generally not achievable by either material if used alone. The
coatings provide a durable, corrosion resistant layer, and the core material provides
the load bearing capability. The deposition of metal coatings, such as chromium,
nickel, copper, and cadmium, is usually achieved by wet chemical processes that
have inherent pollution control problems. (corrosion costs study)
• Alternative metal deposition methods have replaced some of the wet processes and
may play a greater role in metal coating in the future. Metallic coatings are deposited
by electroplating, electroless plating, spraying, hot dipping, chemical vapor deposition
and ion vapor deposition. Some important coatings are cadmium, chromium, nickel,
aluminum and zinc.
• Plating and surface treatment processes are typically batch operations, in which
metal objects are dipped into and then removed from baths containing various
reagents to achieve the desired surface condition. The processes involve moving the
object being coated through a series of baths designed to produce the desired end
product. These processes can be manual or highly automated operations, depending
on the level of sophistication and modernization of the facility and the application.
• Organic Protective Coating
• Many paints, coatings and high performance
organic coatings have been developed as a
need to protect equipment from environmental
damage. Of prime importance in the
development of protective coatings was the
petroleum industry that produced most of the
basic ingredients from which most synthetic
resins were developed.
• Metal Cladding
• The corrosion resistance of a substrate can be improved by metallurgically bonding to the susceptible core alloy a surface
layer of a metal or an alloy with good corrosion resistance. The cladding is selected not only to have good corrosion
resistance but also to be anodic to the core alloy by about 80 to 100 mV. Thus if the cladding becomes damaged by
scratches, or if the core alloy is exposed at drilled fastener holes, the cladding will provide cathodic protection by corroding
sacrificially.
• Cladding is prevalently applied at the mill stage by the manufacturers of sheet, plate or tubing. Cladding by pressing, rolling
or extrusion can produce a coating in which the thickness and distribution can be controlled over wide ranges and the
coatings produced free of porosity. Although there is almost no practical limits to the thickness of coatings that can be
produced by cladding, the application of the process is limited to simple shaped articles that do not require much subsequent
mechanical deformation.
• Aluminum Cladding
• Among the principal uses are aluminum cladding in the aircraft industry, lead and cadmium sheathing for cables, lead-
sheathed sheets for architectural applications and composite extruded tubes for heat exchangers. The thickness of the
cladding is usually between 2% and 5% of the total sheet or plate thickness, and since the cladding is usually a softer and
lower strength alloy, the presence of the cladding can lower the fatigue strength and abrasion resistance of the product. In
the case of thick plate where substantial amounts of material may be removed from one side by machining so that the
cladding becomes a larger fraction of the total thickness, the decrease in strength of the product may be substantial.
• A clad finish being soft in nature is subject to damage during manufacturing and while in service. Caution must be exercised
while polishing or cleaning, since it is sensitive to harsh chemicals and abrasive materials.
• Cladding and Weld Overlaying
• Compared to carbon and alloy steels, all corrosion resistant alloys are expensive. In many cases, corrosion resistance is
required only on the surface of the material and carbon or alloy steel can be clad with a more corrosion resistant alloy.
Cladding can save up to 80% of the cost of using solid alloy. Cladding of carbon or low alloy steel can be accomplished in
several ways including roll bonding, explosive bonding, weld overlaying and “wallpapering”. Clad materials are widely used in
the chemical process, offshore oil production, oil refining and electric power generation industries. The use of clad steel is
not new. Corrosion resistant alloy clad steel has been available for over 40 years. Almost any corrosion resistant stainless
steel or nickel alloy can be bonded to steel. The steel can be clad on both sides or on one side only. The hot roll bonding
process is used to produce over 90% of clad plate products.
• Vapor Deposition (VD)
• Vapor deposition refers to any process in which materials in a vapor
state are condensed through condensation, chemical reaction, or
conversion to form a solid material. These processes are used to
form coatings to alter the mechanical, electrical, thermal, optical,
corrosion resistance, and wear properties of the substrates. They
are also used to form free-standing bodies, films, and fibers and to
infiltrate fabric to form composite materials. Vapor deposition
processes usually take place within a vacuum chamber. There are
two categories of vapor deposition processes:
•
• Physical vapor deposition (PVD)
• Chemical vapor deposition (CVD)
• Electroless plating
• Electroless nickel (EN) plating is a chemical reduction process
which depends upon the catalytic reduction process of nickel ions in
an aqueous solution (containing a chemical reducing agent) and the
subsequent deposition of nickel metal without the use of electrical
energy. Due to its exceptional corrosion resistance and high
hardness, the process finds wide application on items such as
valves, pump parts etc., to enhance the life of components exposed
to severe conditions of service ,particularly in the oil field and marine
sector. With correct pretreatment sequence and accurate process
control , good adhesion and excellent service performance can be
obtained from EN deposited on a multitude of metallic and non-
metallic substra6tes.
Electroless Plating
• Due to its unique properties of excellent corrosion resistance, combined
with a high wear resistance and uniformity of coating, EN finds extensive
applications in a number of fields. Some of the prominent areas of
application are :--
• Oil & Gas: Valve components, such as Balls, Gates, Plugs etc. And other
components such as pumps, pipe fittings, packers, barrels etc.
• Chemical Processing: Heat Exchangers, Filter Units, pump housing and
impellers, mixing blades etc.
• Plastics: Molds and dies for injecting and low and blow molding of plastics
components, extruders, machine parts rollers etc.
• Textile: Printing cylinders, machine parts, spinneret's, threaded guides etc.
• Automotive: Shock Absorbers, heat sinks, gears, cylinders, brake pistons
etc.
• Aviation & Aerospace: Satellite and rocket components, rams pistons,
valve components etc.
• Food & pharmaceutical: Capsule machinery dies, chocolates molds, food
processing machinery components etc.
Corrosion Inhibitors
•
Corrosion Inhibitors
• The use of chemical inhibitors to decrease the rate of
corrosion processes is quite varied. In the oil production
and processing industries, inhibitors have always been
considered to be the first line of defense against
corrosion. A great number of scientific studies have been
devoted to the subject of corrosion inhibitors. However,
most of what is known has grown from trial and error
experiments, both in the laboratories and in the field.
• Rules, equations or theories to guide inhibitor
development or use are very limited. A synergism, or
cooperation, is often present between different inhibitors
and the environment being controlled, and mixtures are
the usual choice in commercial formulations.
Classification of inhibitors
These inhibitors are the most effective and consequently the most widely used.
Chromate based inhibitors are the least expensive inhibitors and were used until
recently in a variety of applications, e.g. recirculation-cooling systems of internal
combustion engines, rectifiers, refrigeration units, and cooling towers. Sodium
chromate, typically in concentrations of 0.04-0.1% was used for these applications.
At higher temperatures or in freshwater with chloride concentrations above 10
ppm higher concentrations are required. If necessary, sodium hydroxide is
added to adjust the pH to a range of 7.5-9.5.
If the concentration of chromate falls below a concentration of 0.016%
corrosion will be accelerated. Therefore it is essential that periodic colorimetric
analysis be conducted to prevent this from occurring.
• In general, passivation inhibitors can
actually cause pitting and accelerate
corrosion when concentrations fall below
minimum limits. For this reason it is
essential that monitoring of the inhibitor
concentration be performed.
Cathodic inhibitors
Both anodic and cathodic effects are sometimes observed in the presence of organic
inhibitors but, as a general rule, organic inhibitors affect the entire surface of a
corroding metal when present in sufficient concentration. Organic inhibitors usually
designated as 'film-forming', protect the metal by forming a hydrophobic film on the
metal surface.
The effectiveness of these inhibitors depends on the chemical composition, their
molecular structure, and their affinities for the metal surface. Because film formation
is an adsorption process, the temperature and pressure in the system are important
factors.
Organic inhibitors will be adsorbed according to the ionic charge of the inhibitor and the
charge on the surface. Cationic inhibitors, such as amines, or anionic inhibitors, such
as sulfonates, will be adsorbed preferentially depending on whether the metal is
charged negatively or positively. The strength of the adsorption bond is the dominant
factor for soluble organic inhibitors.
For any specific inhibitor in any given medium there is an optimal concentration. For
example, a concentration of 0.05% sodium benzoate, or 0.2% sodium cinnamate, is
effective in water with a pH of 7.5 and containing either 17 ppm sodium chloride or
0.5% by weight of ethyl octanol.
The corrosion due to ethylene glycol cooling water systems can be controlled by the use
of ethanolamine as an inhibitor.
Precipitation Inhibitors
• Precipitation inducing inhibitors are film forming compounds that
have a general action over the metal surface, blocking both anodic
and cathodic sites indirectly. Precipitation inhibitors are compounds
that cause the formation of precipitates on the surface of the metal,
thereby providing a protective film. Hard water that is high in calcium
and magnesium is less corrosive than soft water because of the
tendency of the salts in the hard water to precipitate on the surface
of the metal and form a protective film.
• The most common inhibitors of this category are the silicates and
the phosphates. Sodium silicate, for example, is used in many
domestic water softeners to prevent the occurrence of rust water. In
aerated hot water systems, sodium silicate protects steel, copper
and brass. However, protection is not always reliable and depends
heavily on pH and a saturation index that depends on water
composition and temperature. Phosphates also require oxygen for
effective inhibition. Silicates and phosphates do not afford the
degree of protection provided by chromates and nitrites, however,
they are very useful in situations where non-toxic additives are
required.
Volatile Corrosion Inhibitors