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Analytical Chemistry

EASY

This round is worth 3 pts.


10s TIME’S UP!

• A 0.7823 g of FAS hexahydrate (FW=392


g/mol) was used for standardization of KMnO4
solution and it required 26.20 mL for the
titration. What is the concentration of the
standard solution?
0.01523 M
5s TIME’S UP!

• This represents the total effect of the ions in


the solution and is affected by the charges of
the ions.
IONIC STRENGTH
20s TIME’S UP!

• A solution which contains 0.1 M NaNO3.


Calculate the activity coefficient of NO3- given
that α=0.30 nm.
0.754
1min TIME’S UP!

• A 1.4639-g sample of limestone was analyzed


for Fe, Ca, and Mg. The iron was determined
as Fe2O3 yielding 0.0357 g. Calcium was
isolated as CaSO4, yielding a precipitate of
1.4058 g, and Mg was isolated as 0.0672 g of
Mg2As2O7. Report the amount of Fe, Ca, and
Mg in the limestone sample as %w/w Fe2O3,
%w/w CaO, and %w/w MgO
Fe2O3=2.44
CaO=39.55
MgO=1.19
15s TIME’S UP!

• The CN- concentration of 10.0 mL of a plating


solution was determined by titration with
electrogenerated hydrogen ion to a methyl
orange end point. A color change occurred
after 4 min and 11 s with a current of 55.6
mA. Calculate the number of grams of NaCN
per liter of solution. Also calculate the number
of ppm of NaCN in the solution.
0.709 g/L
709 ppm
10s TIME’S UP!

• If there is an excess of one ion over the others,


the concentration of the others is suppressed and
the corresponding solubility decreases. What is
this effect called?
• A) Leveling effect
• B) Diverse ion effect
• C) Ionic strength
• D) Common ion effect
• E) Charge effect
D) COMMON ION EFFECT
15s TIME’S UP!

• What is the missing step in the following


gravimetric analysis: Solution Preparation→
Precipitation → _____ → Washing → Drying →
Weighing →Calculation?
• A) Digestion and Filtration
• B) Filtration and Washing
• C) Titration and Filtration
• D) Digestion and Heating
• E) Heating and Cooling
A) DIGESTION AND
FILTRATION
20s TIME’S UP!

• What is the wavelength of a photon that has 3


times as much energy of a photon whose
wavelength is 650 nm?
• A) 167 nm
• B) 217 nm
• C) 325 nm
• D) 650 nm
• E) 1950 nm
B) 217 nm
20s TIME’S UP!

• What is the most appropriate chromatographic


separation technique for Chromium (III) and
Chromium (VI) in spring water?
• A) Ion-exchange chromatography
• B) Paper chromatography
• C) Gel filtration chromatography
• D) Gel permeation chromatography
• E) Liquid chromatography
A) ION EXCHANGE
CHROMATOGRAPHY
15s TIME’S UP!

• What is the effect of injecting a sample of


large volume slowly?
• A) Decrease in resolution
• B) Increase in resolution
• C) Resolution remains unchanged
• D) Non-linear response
• E) None of the above
A) DECREASE IN RESOLUTION
END OF EASY
AVERAGE

This round is worth 5 pts.


1min TIME’S UP!

• What are the advantages of using diode array detector


(DAD)?
I. High Resolution
II. Simultaneous wavelength measurement
III. Higher radiation throughput
IV. Faster scanning
• A) II and III
• B) II and IV
• C) I, II, and IV
• D) II, III, and IV
• E) All of the above
D) II, III, and IV
1min30s TIME’S UP!

• The Na+ concentration of a solution was


determined by measurements with a sodium
ion-selective electrode. The electrode system
developed a potential of 20.2462 V when
immersed in 10.0 mL of the solution of
unknown concentration. After addition of 1.00
mL of 2.00x10-2 M NaCl, the potential changed
to 20.1994 V. Calculate the Na+ concentration
of the original solution.
3.5x10-4 M
15s TIME’S UP!

• Which of the following factors may affect the


fluorescence quantum yield of a compound?
I. Temperature
II. pH
III. Viscosity of the medium
IV. Polarity of the solvent
• A) I only
• B) II only
• C) I, II, and III
• D) II, III, and IV
• E) All of the above
E) ALL OF THE ABOVE
15s TIME’S UP!

• What is Type II error?


• I. Accepting the null hypothesis when it is false.
• II. Rejecting the null hypothesis when it is true.
• III. Null hypothesis of there is some analyte presented in the
sample. The results show that the analyte is presented, however, it
is actually not presented.
• IV. Null hypothesis of there is some analyte presented in the
sample. The results show that the analyte is not presented,
however, it is actually presented.
• A) I and IV
• B) II and IV
• C) II and III
• D) I and III
• E) None of the above
D) I and III
1min TIME’S UP!

• Which of the following equations describes


the titration of H2O2 with KMnO4?
• A) 𝑀𝑛𝑂4− +5𝐻2 𝑂2 +6𝐻+→ 5𝑂2 +𝑀𝑛2+ +8𝐻2𝑂
• B) 2𝑀𝑛𝑂4− +5𝐻2 𝑂2 +6𝐻+→ 5𝑂2 +2𝑀𝑛2+ +8𝐻2𝑂
• C) 2𝑀𝑛𝑂4− +𝐻2 𝑂2 +𝐻+→ 𝑂2 +𝑀𝑛2+ +𝐻2 𝑂
• D) 2𝑀𝑛𝑂4− +5𝐻2 𝑂2 → 5𝑂2 +2𝑀𝑛2+ +8𝐻2𝑂
• E) 𝑀𝑛𝑂4− +10𝐻2 𝑂2 +12𝐻+ → 10𝑂2 +𝑀𝑛2+ +16𝐻2 𝑂
B) 𝟐𝑴𝒏𝑶− +
𝟒 +𝟓𝑯𝟐 𝑶𝟐 +𝟔𝑯 → 𝟓𝑶𝟐 +𝟐𝑴𝒏
𝟐+ +𝟖𝑯 𝑶
𝟐
15s TIME’S UP!

• Peptization is a process which a coagulated colloid


returns to its original dispersed state as a consequence
of a decrease in the electrolyte concentration of the
solution in contact with the precipitate. How to avoid
this situation in gravimetric analysis?
• A) Wash the coagulated colloid with pure water
• B) Wash the coagulated colloid with an electrolyte
solution
• C) Was the coagulated colloid with hot water
• D) Wash the coagulated colloid with alcohol
• E) Nothing to do
B) WASH THE COAGULATED
COLLOID WITH AN
ELECTROLYTE SOLUTION
10s TIME’S UP!

• In normal-phase HPLC,
• A) A polar stationary phase is combined with a
hydrophobic mobile phase
• B) A non-polar stationary phase is combined with
a hydrophobic mobile phase
• C) A polar stationary phase is combined with a
hydrophilic mobile phase
• D) A non-polar stationary phase is combined with
a hydrophilic mobile phase
• E) None of the above
A) A POLAR STATIONARY
PHASE IS COMBINED WITH A
HYDROPHOBIC MOBILE
PHASE
5s TIME’S UP!

• Which of the following functional groups is


the principal chromophore in an azo-dye?
• A) N=N
• B) N≡N
• C) C=N
• D) C≡N
• E) C=C
A) N=N
10s TIME’S UP!

• What is the most appropriate


chromatographic separation technique for
odorants in wine and brewed coffee?
• A) Gel permeation chromatography
• B) Liquid chromatography
• C) Affinity chromatography
• D) Gas chromatography
• E) Thin layer chromatography
D) GAS CHROMATOGRAPHY
5s TIME’S UP!

• What is the most suitable technique to


analyze mercury in fish at level of 0.010 to 0.1
mg kg-1?
• A) X-ray fluorescence
• B) Flame atomization
• C) Electrothermal atomization
• D) Hydride atomization
• E) Cold-vapor atomization
E) COLD-VAPOR
ATOMIZATION
END OF AVERAGE
DIFFICULT

This round is worth 7 pts.


10s TIME’S UP!

• Who invented capillary columns in gas


chromatography?
MARCEL GOLAY
10s TIME’S UP!

• Which of the following


ionization techniques is
shown in the figure?
• A) Electron impact
ionization
• B) Fast atom
bombardment
• C) Field ionization
• D)Electrospray ionization
• E)Laser-desorption
ionization
B) FAST ATOM
BOMBARDMENT
15s TIME’S UP!

• A chemist works on an unknown herbal sample. The table below


summaries the possible identity of the herbal material and its
associated information:
Radix Polygoni Multiflori (Heshouwu)
Chemical composition:
Anthraquinones, quinones, stilbene glycosides

• Which of the following can serve as a physiochemical test?


• A) Oil test, use ethyl acetate to extract, give a fluorescent spot
• B) Bornträger reaction, produce a red coloration in alkaline medium
• C) Flame test, produce a brick red flame
• D) Chen’s test, gradually turns to yellow or orange color
• E) Simon’s test, give a deep blue color
B) BORNTRÄGER REACTION,
PRODUCE A RED COLORATION
IN ALKALINE MEDIUM
5s TIME’S UP!

• A structurally significant ion that


demonstrates a linear response over a broad
range of concentrations. What is this ion?
• A) Fragment ion
• B) Molecular ion
• C) Precursor ion
• D) Quantitation ion
• E) Qualifier ion
D) QUANTITATION ION
10s TIME’S UP!

• This is an analytical technique that separates


ions in the gas phase in which, ions are
separated in atmospheric pressure under the
influence of an electric field, according to their
size and shape.
ION-MOBILITY
SPECTROMETRY
15s TIME’S UP!

• This model explains the propagation of light,


specifically diffuse reflectance, through
inhomogenous samples.
KUBELKA-MUNK MODEL

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