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Siobhan Parish
Radioactivity
Chapter 9
Discovery of the nucleus
Rutherford’s experiment
1. Alpha particles had the same speed as otherwise
slow α particles would be deflected more than the
faster ones on the same initial path Evacuated
metal
container
2. Container must be evacuated or
α would be stopped by air α source Thin
metal
foil
molecules θ
Geiger tube
background radiation Source in
sealed
To
scaler
Incoming To pulse
particle counter
Tube wall R
About α, β and γ radiation
α radiation
• Composed of two protons and two neutrons
• Same as helium nucleus
• This was discovered by Rutherford
• 4x heavier than the nucleus of a hydrogen atom
About α, β and γ radiation
α radiation
• α particles collected as a gas in a glass tube fitted
with two electrodes
• When a voltage is applied to the electrodes the
gas conducted electricity and
Discharge
emitted light produced here -
High voltage unit
+
• Using a spectrometer Glass
can see that the tube is chamber
0
Mercury to Thin walled
filled with helium compress α glass tube
gas
About α, β and γ radiation
β radiation
• Consists of fast-moving electrons
• Proved by measuring the deflection of a beam of
particles using electric and magnetic fields
• Measured the specific charge, found to be the
same as electrons
• Created from a nucleus with too many neutrons
• Positron is emitted from an unstable nucleus
with too many protons
About α, β and γ radiation
γ radiation
• Photons with a wavelength with order 10-11m or
less
• Discovery made by using a crystal to diffract a
beam of γ radiation in a similar way to a beam of
light in a diffraction grating
I=
d0
d
Tube
To scaler
counter
γ photons
entering tube
Photons emitted in
Photons emitted in all directions
all directions
About α, β and γ radiation
α radiation β radiation γ radiation
Nature 2 protons + β- = electron Photon of energy of
2 neutrons β+ = positron order MeV
Range in air Fixed range Up to about 1m Follows inverse
depending on energy square law
Deflection in Easily deflected Opposite direction to Not deflected
magnetic field α; less easily
deflected
Absorption Stopped by paper or Stopped by ~ 5mm of Stopped by several
thin metal foil aluminium cms of lead
Ionisation Produces about 104 Produces about 100 Very weak ionising
ions per mm in air at ions per mm in air at effect
standard pressure standard pressure
Energy of each Constant for a given Varies up to a Constant for a given
particle/photon source maximum for a given source
source
About α, β and γ radiation
• emission
α
• XY+α
β- emission A γ photon is emitted if
a nucleus has excess
• X Y + β- + e energy after it has
emitted a α or β-
β+ emission particle
• X Y + β+ + νe
Electron capture
• X + e- Y + νe
Dangers of radioactivity
Ionising radiation affects living cells because:
• It can destroy cell membranes which causes cells
to die
• Can damage vital molecules such as DNA
directly or indirectly by created ‘free radical’
ions. Damaged DNA can cause cells to divide
and grow uncontrollably
There’s no evidence of the existence of a threshold
level where cells will not be damaged
Dangers of radioactivity
• If using equipment that produces ionising radiation
a film badge must be worn
• Badge contains a strip of photographic film in a
light-proof wrapper
• Different areas of the film are covered by absorbers
of different thicknesses
• The amount of exposure to each form of radiation is
estimated by the blackening of the film
• If the badge is overexposed the worker cannot
continue working with the equipment
Dangers of radioactivity
• Dose of radiation is measured by the energy
absorbed by unit mass of matter from the radiation
• Same dose of different types of radiation has
different effects
• Alpha particles produce more ions per mm than
gamma so it is more damaging
• Alpha radiation is more damaging inside the body
because it can’t penetrate the dead skin cells
outside the body
Dangers of radioactivity
Dose equivalent is the energy that would
need to be absorbed per unit mass of
matter from 250k of X-Radiation to have
the same effect as a certain dose of ionising
radiation, units: Sv (sievert)
Recommended limit of radiation exposure is
15mSv per year
Reality is much lower at the average radiation
exposure being exposed to 2mSv per year
Dangers of radiation
• All subjected to background radiation due to
cosmic radiation and radioactive material in
rocks, soil and in the air
10
83 Air (e.g. radon gas)
310
Medical
800 Ground and buildings
370 Food and drink
Cosmic rays
Nuclear weapons
380 Air travel
500 Nuclear power
Dangers of radiation
Storage of radioactive materials
• Should be in lead-lined containers. Most produce
gamma radiation as well as alpha and beta
• Lead lining of containers must be thick enough to
contain gamma radiation to about the
background level
• Regulations require the containers are kept under
‘lock and key’ and records are kept of contents
Dangers of radiation
Using radioactive materials
• No source should come into contact with the
skin
• Solid sources transferred using handling tools
such as tongs or a glove-box/robots. Ensures
that it is kept as far as practical from the skin
and beyond range of alpha/beta radiation
• Liquid/gas should be in sealed containers
Radioactive decay
The half life, T1/2, of a radioactive isotope is
the time taken for the mass of the isotope to
decrease to half the initial mass
• Curve of the graph is a decay curve
• Mass of initial isotope decreases gradually as the
number of nuclei of the isotope decrease
• Mass of the isotope decreases
with time at a slower and
slower rate. Decrease
• exponentially
Radioactive decay
• After n half lives from the start:
0.5nm0
• Decreases exponentially because radioactive
decay is random
• Number of nuclei that decay in a time is
proportional to the number of nuclei remaining
Radioactive decay
The activity, A, of a radioactive isotope is
the number of nuclei of the isotope that
disintegrate per second, units: Bq
• Activity is proportional to mass of the isotope
• Activity decreases with time
• For a radioactive source of activity A that emits
particles or photons of the same energy E, the
energy per second or Power of the source = AE
Theory of radioactive decay
• Every nucleus of a radioactive isotope has an
equal probability of undergoing radioactive decay
in a given time
• The number of nuclei that disintegrate in a certain
time interval depends only on the number of
nuclei present
• Number of nuclei that disintegrate is ΔN, it’s
proportional to:
- N, number of nuclei of X remaining at time, t
- the duration of the time interval Δt
A =λN
Detector reading
Electron beam
θ
Amplifier and
meter θmin
Angle of diffraction
Nuclear radius
• Scattering of beam electrons is due to charge-
same as alpha scattering but electrons are
attracted not repelled by the nuclei. Causes
intensity to decrease as angle increases
• Diffraction of beam electrons by each nucleus
causes intensity maxima and minima to be
superimposed on the effect above
• Happens provided the de Broglie wavelength of
the electrons in the beam is no longer than the
dimensions of the nucleus
Nuclear radius
• Superimposed intensity variations are similar to
concentric bright and dark fringes in a
monochromatic light diffraction grating
• Angle of the first minimum from the centre θmin,
is measured and used to calculate the diameter
of the nucleus- provided wavelength of the
incident electrons is known
Nuclear radius
• The radius, R, of different nuclides can be
measured by using samples of different elements
• Graph of lnR against lnA gives a straight line
with gradient 1/3 and y-intercept r0
• Graph of R against A1/3 gives a straight line
through the origin with gradient
• Graph of R3 against A gives a straight line
through the origin with gradient r0
V= V =
V =
Nuclear radius
• Nuclear volume, V, is proportional to the mass of
the nucleus- therefore density is constant and
independent of the radius
• Can conclude that nucleons are separated by the
same distance regardless of the size of the
nucleus and are therefore evenly separated
inside the nucleus
• In the volume formula above, m = Au where 1u =
1 atomic mass unit = 1.661 x 10-27kg
Nuclear Energy
Chapter 10
E = mc2
Absolute
zero
0˚C 100˚C
-273˚C 273K 373K
0K
Rheostat
A
Thermometer
V
Heater Tx TY
Solid Heater
Insulation
= (m1c1) x (mcalccal
m1 x c1 x Tx TY
Lid
• Energy needed to heat the
calorimeter = mcal x ccal x
Insulation
Heater
Liquid
Change of state
• Density of a gas is less than the density of the
same substance as a liquid or solid molecules
are separated by large distances in a gas
• Atoms in a solid are locked together by strong
force bonds and so solids cannot flow like a
liquid or a gas. In a liquid or gas they are not
locked together because they have too much
kinetic energy
Change of state
Solid or liquid heated = more kinetic energy
Solid heated at its melting point: atoms
vibrate so much they break free from each other.
Energy needed to melt a solid at its melting point
is the latent heat of fusion
• Latent heat because no temperature change
happens even though the solid is being heated
• Fusion because the solid ‘fuses’ into a liquid as it
melts
Change of state
Liquid heated at its boiling point: molecules
gain enough energy to overcome the bonds that hold
them together; form bubbles of vapour in the liquid.
This is the latent heat of vaporisation
• Latent heat released when a vapour condenses-
vapour molecules slow down as the vapour is
cooled- move slowly enough for the force bonds to
pull molecules together to form a liquid
• If solid vaporises directly when heated it’s known as
sublimation
Q =ml
Change of state
DEFINITIONS
Specific latent heat of fusion, lf: energy
needed to change the state of unit mass of
the substance from solid to liquid without
change of temperature, units: Jkg-1
Change of state
¿
Graph showing what will happen if a pure solid is
heated to its melting point and beyond
Temp, T
uid
Liq
Melting
point
l id
So ΔT
Δt
Time, t
T3
T2
T1
Volume
V
= constant
T
The experimental gas laws
Charles’ law
Measured the volume of a fixed mass of gas at
constant pressure varies with absolute
temperature- leads to the idea of absolute zero. No
matter how much gas is used, if the gas is an ideal
gas, it’s volume would be zero at absolute zero
Volume
Heater
The ideal gas law
• Molecules in a gas move at random with
different speeds
• When molecules collide they bounce off each
other/the surface without loss of speed
• Pressure of gas on a surface is due to the gas
molecules hitting the surface
• Each impact causes a tiny force on the surface
• Overall result is that the gas exerts a measurable
pressure on the surface
The ideal gas law
• The effect of individual molecules in a gas can be
seen if smoke particles are observed using a
microscope
• Their motion is called Brownian motion
• Motion of each particle is due to it being
bombarded unevenly at random by individual
molecules
• They’re subjected to a force due to the impacts
which changes its magnitude and direction
The ideal gas law
Brownian motion
Observer
Path of one
Microscope smoke
particle
Smoke in
glass cell
Field of view
Smoke
particles
Lamp Lens
The ideal gas law
• Avogadro constant
The
• The Avogadro constant, NA, is the number of
atoms in exactly 12g of the value of NA is:
6.023 x 1023
• One atomic mass unit, u, 1/12th of the mass of a
atom:
1u = 1.661 x 1027kg
The ideal gas law
Molar mass
• A mole of a substance is the quantity of the substance
that contains NA particles
• Number of moles in a certain quantity of a substance
is its molarity
• The molar mass is the mass of 1 mole of the
substance
1. Number of moles in mass MS of a substance =
MS/M where M is the molar mass of the substance
2. Number of molecules in MS = NAMS/M
pV = nRT
Molecular speeds
• Molecules in an ideal gas have a continuous spread
of speeds
• Speed of an individual molecule changes when it
collides with another gas molecule
• This is providing the distribution and temperature
stay the same
• Above equation shows the root mean square speed
of the molecules where N is the number of
molecules
The kinetic theory of gases
• If the temperature of a gas is raised the
molecules move faster on average
• Root mean square speed of the molecules
increases
• Distribution curve becomes flatter and broader
No. of
molecules
Low
temp High
temp
Speed, v
pV
= 1/3 Nm c2 ´rms
The kinetic theory of gases Really
Angry
Eels
Assumptions Don’t
Vote
1. Molecules move with Random continuous
motion
2. Molecules do not Attract each other
3. The collide Elastically
4. The Duration of the collisions are negligible
compared to the time between collisions
5. The Volume of one molecule is negligible
compared to the volume of the whole gas
y
l y
The kinetic theory of gases z l x l
z
x
Proof of
• 1) For N molecules p =
1) Ft = 2mu1 ∴ F = + +…+
2) Time between collisions = p= + +…+)
=)
Combining equations =
3) Pressure, p = p= or or
p for one molecule =
2) Combining these equations by
adding together means
3p = ( + + )
+ + =
∴ 3p =
3) pV = 1/3Nm