RESIN ALKYD

RESIN = BINDER ????

CAT
 ASAL USUL
ALKYD = ALCID = ALCOHOL + ACID
(R’ – OH) (R - COOH)

ESTER + AIR
(R – COO – R’ + H2O)

POLYOL + POLYACID = POLYESTER

OIL + POLYOL + POLYACID = OIL MODIFIED POLYESTER
(RESIN ALKYD)
 KLASIFIKASI RESIN ALKYD
1. BERDASARKAN KANDUNGAN OIL

GOLONGAN OIL LENGTH APLIKASI

SHORT OIL < 45% • ACID CURING (MELAMINE
PAINT)
• NC
• BAKING ENAMEL
MEDIUM OIL 46 – 55% • AIR DRYING
LONG OIL 56 – 70% • AIR DRYING
VERY LONG OIL > 70% • APLIKASI KHUSUS
MODIFIED STYRENE, PHENOLIC, • APLIKASI KHUSUS
EPOXY
 KLASIFIKASI RESIN ALKYD
2. BERDASARKAN JENIS OIL

GOLONGAN CONTOH OIL TIPE ALKYD

DRYING ALKYD LINSEED, TUNG, DHCO • LONG OIL
SEMI DRYING ALKYD SOYABEAN, TOFA • LONG, MEDIUM,
SHORT OIL
NON DRYING ALKYD COCONUT, CASTOR • SHORT OIL
PROSES PEMBUATAN RESIN ALKYD

1. DUA TAHAP PROSES

= OIL / ALCOHOLISIS PROCESS

2. SATU TAHAP PROSES

= FATTY ACID PROCESS
 PROSES PRODUKSI ALKYD
I. OIL / ALKOHOLISIS PROCESS

BAHAN BAKU:
A. OIL
POLYOL
CATALYST
B. POLYOL
POLYACID
ANTIOXIDANT
SOLVENT REFLUX

SOLVENT REFLUX
 PROSES PRODUKSI ALKYD
Temp°C
50 50 100 N2 (L/mt)

240°C
End point

2 – 3 jam

180°C
A

Time

MONITOR PROSES
1. CHECK ALKOHOLISIS
2. VISCOSITY
3. ACID VALUE
 OIL / ALCOHOLYSIS PROCESS
ALCOHOLYSIS

2 POLYOL 3 MONOGLYCERIDE
OIL
 OIL / ALCOHOLYSIS PROCESS
ETERIFIKASI

MONOGLYCERIDE POLYACID

+ AIR

ALKYD n
 ALKYD PRODUCTION PROCESSES
1. OIL ALCOHOLYSIS PROCESS

HEATING HEATING DILUTION

OIL
MONO
GLYCERIDE
POLYHYDRIC
ALCOHOL
POLYBASIC ALKYD RESIN
ACID
ALKYD
SOLUTION
POLYHYDRIC
ALCOHOL SOLVENT
 PROSES PRODUKSI ALKYD
II. OIL / ALKOHOLISIS PROCESS

BAHAN BAKU:
A. FATTY ACID
POLYOL
POLYACID
ANTIOXIDANT

SOLVENT REFLUX

SOLVENT REFLUX
 PROSES PRODUKSI ALKYD
Temp°C
50 50 100 N2 (L/mt)

220°C End point

2 – 3 jam
160°C

1.5 Hours

Time

MONITOR PROSES
1. CHECK VISCOSITY
2. CHECK ACID VALUE
 FATTY ACID PROSES

Polyol Fatty acid Polyacid

ALKYD + AIR
 ALKYD PRODUCTION PROCESSES
2. FATTY ACID PROCESS

HEATING DILUTION

FATTY ACID

POLYBASIC ALKYD RESIN

ACID
ALKYD
SOLUTION
POLYHYDRIC
ALCOHOL SOLVENT