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12 Properties of
Substances
12.1 Classification of Substances According to
Structures
12.2 Classification of Substances According to
the Nature of Bonding
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12.1
Classification of
Substances According
to Structures
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12.1 Classification of substances according to structures (SB p.302)
Some pre-knowledge
forces of
solid attraction liquid
between particles
weaken
forces of
attraction
between particles
broken
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12.1 Classification of substances according to structures (SB p.302)
Molecular structures
• Consist of discrete molecules
• Atoms in the molecules are held by strong
covalent bonds
• Molecules are held together by weak
intermolecular forces
• 2 types: simple molecular structures,
macromolecular structures
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12.1 Classification of substances according to structures (SB p.302)
Substances with simple molecular
structures may be solids, liquids
or gases at room conditions
Substances with
macromolecular
structures are always
solids at room conditions
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12.1 Classification of substances according to structures (SB p.302)
Giant structures
• All the atoms or ions are linked by strong
bonding
• Classified into 3 types: giant covalent, giant
ionic and giant metallic structures
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12.1 Classification of substances according to structures (SB p.302)
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12.1 Classification of substances according to structures (SB p.303)
liquid iodine
(by raising the temp.)
solid iodine
(at room temp.)
forces of attraction
between particles broken
Gaseous
(by further raising the
iodine
temp.)
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12.2 Classification of substances according to the nature of bonding
(SB p.304)
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12.2 Classification of substances according to the nature of bonding
(SB p.305)
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12.2 Classification of substances according to the nature of bonding
(SB p.305)
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12.2 Classification of substances according to the nature of bonding
(SB p.306)
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12.2 Classification of substances according to the nature of bonding
(SB p.306)
Macromolecules
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12.2 Classification of substances according to the nature of bonding
(SB p.307)
Ionic substances
• Cations and anions are held together by ionic
bonds which are
strong non-directional electrostatic attraction
• Oppositely charged ions are closely packed
together to give a 3-dimensional giant lattice
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12.2 Classification of substances according to the nature of bonding
(SB p.307)
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12.2 Classification of substances according to the nature of bonding
(SB p.307)
Metallic substances
• Consist of a regular lattice of metallic cations
and a “sea” of delocalized electrons
• The lattice is held by strong electrostatic
attraction between the delocalized electrons
and metallic cations known as metallic bonds
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12.2 Classification of substances according to the nature of bonding
(SB p.308)
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12.2 Classification of substances according to the nature of bonding
(SB p.308)
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12.2 Classification of substances according to the nature of bonding
(SB p.309)
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The END
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12.1 Classification of substances according to structures (SB p.303)
Back
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12.2 Classification of substances according to the nature of bonding
(SB p.305)
Back
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12.2 Classification of substances according to the nature of bonding
(SB p.306)
Answer
Unlike diamond and graphite, fullerenes can be
dissolved in various solvents. Why?
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12.2 Classification of substances according to the nature of bonding
(SB p.309)
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12.2 Classification of substances according to the nature of bonding
(SB p.309)
(a) In dry ice, the atoms are joined together within the molecules by
strong covalent bonds while only weak van der Waals’ forces exist
between molecules. The melting and boiling points of dry ice are low
since only weak van der Waals’ forces are needed to be overcome
during the processes of melting and boiling. Besides, dry ice
consists of simple molecules with no mobile electrons. Thus, it does
not conduct electricity. Carbon dioxide is only slightly soluble in
water because it is non-polar in nature.
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12.2 Classification of substances according to the nature of bonding
(SB p.309)
Back
33
12.2 Classification of substances according to the nature of bonding
(SB p.309)
34
12.2 Classification of substances according to the nature of bonding
(SB p.309)
35
12.2 Classification of substances according to the nature of bonding
(SB p.309)
36
12.2 Classification of substances according to the nature of bonding
(SB p.309)
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12.2 Classification of substances according to the nature of bonding
(SB p.309)
Back
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