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• If the outer surfaces of the heater are well insulated, all the heat
generated by the resistance heater will be transferred through the
material whose conductivity is to be determined.
• The thermal conductivities of liquids usually lie between those solids and gases.
• Like gases, the conductivity of liquids decreases with increasing molar mass
Solids :
Metal alloys :
• Pure metals have high thermal conductivities, and one would think that metal alloys should
also have high conductivities.
• One would expect an alloy made of two metals of thermal conductivities k1 and k2 to have
a conductivity k between k1 and k2. But this turns out not to be the case.
• The thermal conductivity of an alloy of two metals is usually much lower than that of either
metal, as shown in Table 1–2. Even small amounts in a pure metal of “foreign” molecules
that are good conductors themselves seriously disrupt the flow of heat in that metal.
• For example, the thermal conductivity of steel containing just 1 percent of chrome is 62
W/m · °C, while the thermal conductivities of iron and chromium are 83 and 95 W/m · °C,
respectively
• The thermal conductivities of materials vary with temperature (Table 1–3). The variation of
thermal conductivity over certain temperature ranges is negligible for some materials, but
significant for others, as shown in Fig. 1–28.
• For example, the conductivity of copper reaches a maximum value of about 20,000 W/m · °C at
20 K, which is about 50 times the conductivity at room temperature. The thermal
conductivities and other thermal properties of various materials are given in Tables A-3 to A-16