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9.1 Introduction
9.2 Classification of Pollutants
9.3 Sources of Air Pollution
9.3.1 . Natural Sources
9.3.2 Anthropogenic Sources
9.4 Effects of Air Pollution
9.4.1 Health Effects
9.4.2 Ecological Effects
9.5 Air Quality Management
9.6 Conclusion
AIR POLLUTION
DEFINITION
(Presence of dust, smoke, fumes, mist, odour or gases (including oxides of carbon, sulphur & nitrogen)
in quantities or of a duration that unreasonably alters the average (acceptable purity) condition of the
atmosphere)
Pure and impure air
The composition (%) of fresh (pure) air by volume:
Component Percent
Nitrogen 20.946
◦ Oxygen 78.084
Argon 0.934
Total 99.964
Neon 0.0018
Helium 0.0005
Krypton and methane 0.0001
Hydrogen and Nitrous oxide 0.00005
Xenon 0.000008
Variable components:
Vapour 0-5
Carbon dioxide 0.01-0.1 (average 0.032)
Ozone 0-0.01
Sulphur dioxide 0-0.0001
Composition of air Cont…
◦ The composition:
Change of season,
Altitude &
Solar activity
1. Troposphere: 2. Stratosphere:
Immediately above surface of earth, Height from the earth: 40-50 km
A gradual decline in temperature
Thin layer above troposphere
Uniform temperature
Thickness: 10-20 km
The zone comprises of ozone layer
At 20 km the temperature falls to -56O C (from 150 C) Protects the earth against the ill-effects of UV
The rate of temperature drop: 6.40 C/100 m irradiation
The zone contains: 99% mass of gases found in the Ozone shield increases the temperature from -
atmosphere (nitrogen, oxygen and carbon dioxide) 560 C to -20 C at 50 km height
3. Mesophere: 4. Thermosphere:
Height from the earth: 70-80 km Height from the earth: above 80 km
Marked reduction in the temperature Temperature: very high (upto 12000 C)
At an altitude of 70 km,
Thickness of the zone is 500 km
the temperature falls to -92 C (from -2 C)
o 0
It contains O2, nascent oxygen & nitrogen oxide.
Influence
The atmospheric pollution is influenced:of metrological
meteorological conditions
conditions present in an area
Meteorological factors influences: magnitude of vertical & horizontal transfer of air pollution
• Natural Sources
e.g. smoke that comes from
wildfires, volcanoes, methane, dust
• Human Sources
e.g. power plants and automobiles,
fumes, burning wood stoves,
fireplaces, and furnaces
Pollutants
• Carbon Dioxide
• Carbon Monoxide
• Sulfur Dioxide
• Nitrogen Dioxide
MECHANISM
Primary Mechanism
• Formation of VOC
• Biological generation of VOC
• Formation of liquid aerosol droplets
• Anthropomorphic generation of particulate
aerosol
• Biological formation of particulate aerosols
• Particulate aerosol formation
Secondary Mechanism
• Condensation
• Adsorption
• Nucleation
Classification of air pollutants
3. Nation’s Economy
Each day, air pollution causes thousands of illnesses leading to lost days at work and school.
Air pollution also reduces agricultural crop and commercial forest yields by billions of dollars each year.
Thermal Inversions
Thermal inversion occurs when a layer of warm air
settles over a layer of cooler air that lies near the
ground. The warm air holds down the cool air and
prevents pollutants from rising and scattering.
There are two types of temperature inversions: surface inversions that occur near the Earth's surface, and aloft inversions
that occur above the ground. Surface inversions are the most important in the study of air quality.
The most common manner in which surface inversions form is through the cooling of the air near the ground at night. Once
the sun goes down, the ground loses heat very quickly, and this cools the air that is in contact with the ground. However,
since air is a very poor conductor of heat, the air just above the surface remains warm. Conditions that favor the
development of a strong surface inversion are calm winds, clear skies, and long nights. Calm winds prevent warmer air above
the surface from mixing down to the ground, and clear skies increase the rate of cooling at the Earth's surface. Long nights
allow for the cooling of the ground to continue over a longer period of time, resulting in a greater temperature decrease at
the surface. Since the nights in the wintertime are much longer than nights during the summertime, surface inversions are
stronger and more common during the winter months.
During the daylight hours, surface inversions normally weaken and disappear as the sun warms the Earth's surface. However,
under certain meteorological conditions, such as strong high pressure over the area, these inversions can persist as long as
several days. In addition, local topographical features can enhance the formation of inversions, especially in valley locations.
EFFECTS
• Human Effects
e.g. diseases
• Environmental Effects
Acid rain
Eutrophication
Haze
Wildlife
Ozone Depletion
Crop and forest damage
Global Climate Change
Effects of pollutants
◦ Direct bearing on the health of animals & man, & planetary bio-diversity
The quality of environment within animal houses: on the health of animals & their productivity
High densities of animals: not well ventilated lead to accumulation of excessive moisture and carbon
dioxide
Atmospheric oxygen level to 10-12% may not prove fatal to animals,
An increase of atmospheric Carbon dioxide level to 6.0% may lead to asphyxia
A concentration of Carbon dioxide 30% for some hours could result in death
In horses Carbon dioxide concentration of 3-5% may cause rapid breathing
A combination of high moisture & carbon dioxide makes animals uncomfortable & leads to a reduction in
production
◦ Major gases: include ammonia, hydrogen sulphide & methane besides carbon dioxide
◦ Ammonia: irritating gas that is frequently found in the dirty farm houses
◦ Concentration between 0.04% and 0.5% of the gas causes much irritation of mucous membranes,
asphyxia and death.
◦ Hydrogen sulphide (0.01 - 0.14%): irritation of eyes, throat & nose, & lung oedema
◦ Excessive amounts of methane may prove explosive
◦ Turbulence activity may also lead to production of harmful particulate pollutants
Microbial pollution of air
◦ A variety of microbes are carried by air
◦ Meteorological conditions (temperature, humidity, solar radiation)
◦ Amount of particulate & gaseous pollutants contribute immensely to the variation in the load
and type of microbes
◦ Most of the atmospheric microflora emanates from the soil or due to stirring action induced by
animal/human activity within the animal houses
◦ The microbes are adsorbed on the dust particles
◦ Carried over long distances under favorable weather conditions (high wind velocity) especially
during outbreaks of diseases
◦ A large numbers of organisms (many of them pathogens) can be transmitted through air in an
area
◦ Animals suffering from respiratory diseases discharge the microorganisms during sneezing &
coughing
◦ In man:
Sneeze can release upto 10,000-10,00,000 droplets
Microbes released by animal & human sources survive in the environment for varying
lengths of time
Some organisms may not survive for more than few minutes (Leptospira in dry
atmosphere),
Can resist the adverse environmental conditions for as long as 28 years (spores of
Bacillus anthracis in soil)
Brucellae can survive in soil for about one month
Exposure to sunlight causes destruction of many environmental microorganisms
(Mycobacterium spp)
In soil: mycobacteria can survive for upto 6 months
Measurement of air contamination
◦ The microbial load of moving air is determined
To assess the level of contamination within a building or given area
2. Impaction
Collecting the atmospheric particles on the surface of a solid/semi-solid agar
medium
Air centrifuge is used
The air flow on the sides of a rotating cylinder lined with a culture medium
Suitable for large sized particles
A better known device called slit sampler is preferred by many to test air quality
The air is sucked through a slit onto a rotating culture plate kept underneath the
device
The flow rate one cu ft .( 28.3 cu cm)/min
Rotation rate is kept at 0.5, 2 or 6 min/revolution
Methods of air sampling
3. Impingement
To collect atmospheric particles in a liquid medium
The air is sucked through a glass instrument at a defined rate into the fluid
The microbial load: determined by examining the fluid
4. Precipitation
The precipitation of atmospheric particles in two ways:
1. Thermal precipitation
A slowly moving air current (3 lit/min) is directed between heated & cooled
surfaces (distance 0.038 cm)
The heated wire/surface repulses the particles towards cold surface
They get collected in cold surface
The organisms are then transferred on to the agar medium
2. Electrostatic precipitation
Collects the organisms on the basis of their electric charge
It is a highly efficient instrument for collecting the airborne particles
Methods of air sampling
5. Filtration
The microorganisms are trapped on a filter (cotton, glass wool or paper) or membrane
filter
Membrane filter technique is considered to be better for the purpose
Air is filtered through the membrane
The particles (with microbes) are impunged on this membrane
The membrane is then placed on a paper saturated with an appropriate medium &
incubated
New
Lower
Technologie
Combustion
s, Recycling
How You Can Help Reduce Air
Pollution?
Conserve Energy
■Turn off appliances and lights when you leave the room.
■ Recycle paper, plastic, glass bottles, cardboard, and aluminum cans. (This conserves
energy and reduces production emissions.)
■Wash clothes with warm or cold water instead of hot.
■ Choose products that have less packaging and are reusable.
■ Shop with a canvas bag instead of using paper and plastic bags.
Drive Wise
■Plan your trips. Save gasoline and reduce air pollution.
■ Keep tires properly inflated and aligned.
■ Join a carpool or vanpool to get to work.
CONCLUSION AND RECOMMENDATIONS