Presentasi Tugas

- Kelompok Fauget -
 Introduction

Ozone
> Ozon adalah zat pengoksidasi yang kuat yang mudah
bereaksi dengan sebagian besar bahan organic bahan,
termasuk lignoselulosa.

> Ozon digunakan dalam proses oksidasi komersial

menjadi pemutih tekstil, lilin, dan pati, serta untuk
mendisinfeksi udara dan air
 Introduction
Advantages/Disadvantage
Ozone

01 Advantages
• Powerful Oxidizer
• no chlorinated hydrocarbons generated

02 Disadvantages
• very low solubility in water (0.98 g/liter with
room temperature and atmospheric pressure)
• Ozone is toxic in small amounts, but its odor can
be detected at only 0.01-0.015 ppm.
• Ozone is less selective toward lignin than are
chlorine and chlorine dioxide and low charges are
required to prevent strength loss.
 Introduction

Ozone Conditions
Ozone generated from oxygen on air through an
ozone generator (electric discharge).

Ozone applied with air oxygen (4-14

%)

Ozone is used as a delignifer to replace Cl2 and ClO2

• Does not achieve the same level of delignification
• Requires addtional other stages
 Fundamental aspects of
ozone bleaching

Ozone reactions with lignin and cellulose

• Ozone functions as a electrophile under acidic conditions

• Aliphatic double bonds are cleaved
• Aromatic ring is cleaved forming muconic Acids
• Hydroxyl groups are introduced into the ring
• Another mode of ozone reaction is insertion of an oxygen atom into carbon-hydrogen
bonds in alcohol-, aldehyde-, and ether-type structures, resulting in fragmentation of the
residual lignin.
 Fundamental aspects of
ozone bleaching

Expression of ozone effectiveness and

selectivity
The response of pulp to an ozone treatment is :
• characterized by the amount of lignin removal (as measured by the kappa number),
• and carbohydrate degradation (as measured by pulp strength or, less desirably but more
conveniently, by viscosity).