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Log c
Experimental work
To study the adsorption of oxalic acid on kaolin & see the effect of
increasing the concentration of oxalic acid on adsorption.
Procedure:
1- Prepare 50 mls of the following conc. of oxalic acid 0.2, 0.4, 0.6, and
0.8 N from stock solution 1 N oxalic acid by dilution method.
C1 V1 =C2 V2
2- Put 50 ml of each concentration & the stock solutions in 5 conical
flask,
3- Introduce 2 g of kaolin into each flask.
4- Shake for 15 min. and set aside for. 15 min. to achieve equilibrium.
5- Filter, reject the first portion of the filtrate after washing the receiver
with it.
6- Pipette 20 ml of the filtrate containing the non adsorbed oxalic acid
(free) and titrate them N/2 NaOH using phenolphthalein as
indicator.( E.P. is colorless to pink)
7- Calculate the amount adsorbed in each flask and plot Freundlich
adsorption isotherm. Find the values of K & n.
Calculation:-
Total amount of oxalic acid — free amount = adsorbed
amount. During titration:
1 mole oxalic acid + 2 mole NaOH = product
1 M.Wt of Ox.A = 2 M.Wt of NaOH
(M.Wt of Ox.A ) / 2 = 1 M.Wt of NaOH
1 eq. Wt. of Ox.A =1 eq. Wt. of NaOH
126/2 = 63= 1000 ml of 1 N NaOH
63/1000 = 1 ml of 1 N NaOH
(63/1000) x (1/2)= 1 ml of 1/2 N NaOH
1M1 of 1/2 N NaOH = 0.0315 g ox. acid
E.P x 0.0315 = g ox. acid (free)/20 ml.
Calculate the amount of total ox.acid in each flask as follows:-
Flask no.1:- if there is no kaolin present and we take 20 ml of solution
and titrate with N/2 NaOH theoretically it take 40 ml NaOH
20 x 1 N = v x 1/2N
V = 40 ml of NaOH we needed if there is no kaolin present in the flask.
40 x 0.0315 = gm ox.acid/20 ml (total)
X = amount adsorbed = ( 40 x 0.0315) - (E.p 1 x 0.0315) = g/20 ml
x = ( 40 x 0.0315) - (E.p1 x 0.0315) x 50/20