General Chemistry Grade 12 Module

12
GENERAL
CHEMISTRY
2
QUARTER 1
LEARNING ACTIVITY
SHEET
Republic of the Philippines
Department of Education
COPYRIGHT PAGE
Learning Activity Sheet in GENERAL
CHEMISTRY 2 (Grade 12)
Copyright © 2020
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NOTE: Practice personal hygiene protocols at all times

i
Table of Contents
Page
Competency Code
number
Use the kinetic molecular model to explain
properties of liquids and solids
STEM_GC11IMFIIIa-c-99 1 - 13
Describe and differentiate the types
of intermolecular forces STEM_GC11IMFIIIa-c-100 14 – 29
Describe the following properties of liquids,
and explain the effect of intermolecular
forces on these properties: surface tension,
viscosity, vapor pressure, boiling point, and
molar heat of vaporization STEM_GC11IMFIIIa-c-102 30 – 50
Explain the properties of water with its

molecular structure and intermolecular
forces STEM_GC11IMFIIIa-c-103 51 - 67
Describe the difference in structure of

crystalline and amorphous solids STEM_GC11IMFIIIa-c-104 68 – 91
Interpret the phase diagram of water
and carbon dioxide STEM_GC11IMFIIIa-c-107 92 – 110
Determine and explain the heating and
cooling curve of a substance STEM_GC11IMFIIIa-c-109 111- 119
Use different ways of expressing
concentration of solutions: percent by
mass, mole fraction, molarity, molality,
percent by volume, percent by mass, ppm STEM_GC11PPIIId-f-111 120 – 142
Perform stoichiometric calculations for

reactions in solution STEM_GC11PPIIId-f-112 143 – 159
Describe the effect of concentration on the
colligative properties of solutions STEM_GC11PPIIId-f-115 160 – 170
Differentiate the colligative properties of
nonelectrolyte solutions and of electrolyte
solutions STEM_GC11PPIIId-f-116 171 – 187
Calculate boiling point elevation and

freezing point depression from the
concentration of a solute in a solution STEM_GC11PPIIId-f-117 189- 198
Calculate molar mass from colligative
property data STEM_GC11PPIIId-f-118 199 – 209
NOTE: Practice personal hygiene protocols at all times ii

Describe laboratory procedures in
determining concentration of solutions STEM_GC11PPIIId-f-119 210 – 224
Explain the first law of thermodynamics STEM_GC11TCIIIg-i-124 225 – 233
Explain enthalpy of reaction STEM_GC11TCIIIg-i-125 234 – 244
Calculate the change in enthalpy of a given
reaction using Hess Law STEM_GC11TCIIIg-i-127 245 – 255
Describe how various factors influence the
rate of reaction STEM_GC11CKIIIi-j-130 256 – 268
Differentiate zero, first- , and second-order
reactions STEM_GC11CKIIIi-j-132 269 – 293
Explain reactions qualitatively in terms of
molecular collisions STEM_GC11CKIIIi-j-136 294 – 313
Explain activation energy and how a catalyst
affects the reaction rate STEM_GC11CKIIIi-j-137 314 – 229
Cite and differentiate the types of catalysts STEM_GC11CKIIIi-j-138 230 – 249
NOTE: Practice personal hygiene protocols at all iii

times
GENERAL CHEMISTRY 2
Name: _ Grade Level:

Date:
Score:
LEARNING ACTIVITY SHEET
THE STRUCTURE OF CRYSTLLINE AND AMORPHOUS SOLIDS
Background Information for the Learners (BIL)
A solid interface is defined as a small number of atomic layers that separate
two solids in intimate contact with one another, where the properties differ
significantly from those of the bulk material it separates.
Based on their crystal structures, solids can be classified into the following
categories:
1. Crystalline solids
2. Amorphous solids
However, crystalline solids can be further classified into molecular, ionic, metallic, and
covalent solids.
An illustration detailing the classification of solids is provided below
.
Source:https://byjus.com/chemistry/classification-of-solids-based-on-crystal-structure/
5
Crystalline are solids featuring highly ordered arrangements of their particles
(atoms, ions, and molecules) in microscopic structures.
These ordered microscopic structures make up a crystal lattice that accounts
for the structure of the solid at any given point. Examples of crystalline solids include
salt (sodium chloride), diamond, and sodium nitrate.
Ionic solids, such as sodium chloride and
Figure 1. Sodium chloride is an
nickel oxide, are composed of positive and ionic solid.
negative ions that are held together by
electrostatic attractions, which can be quite
strong Figure 1. Many ionic crystals also have
high melting points. This is due to the very strong
attractions between the ions—in ionic compounds,
the attractions between full charges are (much)
larger than those between the partial charges in
polar molecular compounds. This will be looked at
in more detail in a later discussion of lattice
https://opentextbc.ca/chemistry/chapter/10-5-
energies. Although they are hard, they also tend to
be brittle,electricity;
conduct and they however,
shatter rather
they than bend. Ionic
do conduct when molten or dissolved because
solidsions
their do not
are free to move. Many simple compounds formed by the reaction of a
metallic element with a nonmetallic element are ionic.
Metallic solids such as crystals of copper,
aluminum, and iron are formed by metal atoms 2. Figure 2. Copper is a metallic solid.
The structure of metallic crystals is often described .

as a uniform distribution of atomic nuclei within a
“sea” of delocalized electrons. The atoms within
such a metallic solid are held together by a unique
force known as metallic bonding that gives rise to
many useful and varied bulk properties. All exhibit
high thermal and electrical conductivity, metallic
luster, and malleability. Many are very hard and
quite strong. Because of their malleability (the
https://opentextbc.ca/chemistry/chapter/10-5-the-
ability to deform under pressure or hammering),
they do and,
shatter not therefore, make useful construction materials. The melting points of the
metals vary widely. Mercury is a liquid at room temperature, and the alkali metals
melt
6
below 200 °C. Several post-transition metals also have low melting points, whereas
the transition metals melt at temperatures above 1000 °C. These differences reflect
differences in strengths of metallic bonding among the metals.
Covalent network solids include crystals of
Figure 3.
diamond, silicon, some other nonmetals, and some
covalent compounds such as silicon dioxide (sand)
and silicon carbide (carborundum, the abrasive on
sandpaper). Many minerals have networks of
covalent bonds. The atoms in these solids are held
together by a network of covalent bonds, as shown in
Figure 3. To break or to melt a covalent network
solid, covalent bonds must be broken. Because
covalent bonds are relatively strong, covalent
network solids are typically characterized by
hardness, strength, and highmelting points. For https://opentextbc.ca/chemistry/chapter/10-5-the-
solid- state-of-matter
example, diamond is one of the hardest substances
known
A and melts
covalent above
crystal 3500 °C.
contains a three-dimensional network of covalent bonds, as
illustrated by the structures of diamond, silicon dioxide, silicon carbide, and graphite.
Graphite is an exceptional example, composed of planar sheets of covalent crystals
that are held together in layers by noncovalent forces. Unlike typical covalent solids,
graphite is very soft and electrically conductive.
7
Molecular solids, such as ice, sucrose (table sugar),
Figure 4. Carbon dioxide.
and iodine, as shown in Figure 4, are composed of
neutral molecules. The strengths of the attractive
forces between the units present in different crystals
vary widely, as indicated by the melting points of the
crystals. Small symmetrical molecules (nonpolar
molecules), such as H2, N2, O2, and F2, have weak
attractive forces and form molecular solids with very

low melting points (below −200 °C). Substances
consisting of larger, nonpolar molecules have larger
attractive forces and melt at higher temperatures.
Molecular solids composed of molecules with
permanent dipole moments (polar molecules) melt at https://opentextbc.ca/chemistry/chapter/10-5-the-solid-
still higher temperatures. Examples include ice (melting point, 0 °C) and table sugar
(melting point, 185 °C).
Figure 4. Carbon dioxide (CO2) consists of small, nonpolar molecules and forms a molecular
solid with a melting point of −78 °C. Iodine (I2) consists of larger, nonpolar molecules and
forms a molecular solid that melts at 114 °C.

Type of Solid Type of Types of Properties Examples
Particles Attractions
hard, brittle,
conducts
electricity as a
ionic Ions ionic bonds liquid but not NaCl, Al2O3
as a solid, high
to very
high melting
points
shiny,
atoms of malleable,
Cu, Fe, Ti, Pb,
metallic electropositive metallic bonds ductile,
U
elements conducts heat
and
electricity
8
well, variable
hardness
and melting
temperature
covalent atoms of covalent very hard, not C (diamond),
network electronegative bonds conductive,
SiO2, SiC
elements very
high melting
points
molecular molecules (or MFs variable H2O, CO2, I2,
atoms) hardness,
C12H22O11
variable
brittleness, not
conductive,
low
melting points
https://opentextbc.ca/chemistry/chapter/10-5-the-solid-state-of-matter
Amorphous are solids in which the particles are not arranged in any specific
order or the solids that lack the overall order of a crystal lattice.
The term ‘amorphous’, when broken down into its Greek roots, can be
roughly translated to “without form”. Many polymers are amorphous solids. Other
examples of such solids include glass, gels, and nanostructured materials.
An ideal crystal is defined as an atomic arrangement that has infinite
translational symmetry in all the three dimensions, whereas such a definite
definition is not possible for an ideal amorphous solid (a-solid).
Features of Crystalline and Amorphous Solids
CRYSTALLINE AMORPHOUS
NATURE True Solids. Pseudo – Solids or super-

cooled liquids.
Geometry Particles are arranged in a Particles are arranged
repeating pattern. randomly. They do
They have a not have an
regular and ordered
9
ordered arrangement arrangement resulting in
result irregular shapes.
ing in a definite shape.
Melting They have a sharp melting  They do not have
point. sharp
melting points.
The
solid tends to
soften gradually
over a temperature
range.
Heat of Fusion (The They have definite heat of  They do not have
change in enthalpy fusion. definite
when a substance is heat of
heated to change its fusion.
state from solid to liquid.)
Isotropism Anisotropic in nature. i.e.,  Isotropic in nature.

the magnitude of physical i.e., the magnitude
properties (such of the physical
as refractive index, properties is the
electrical conductivity, same along with all
thermal directions of the
conductivity etc) solid.
is different along
with different directions of
the crystal.
Cleavage When cutting with a sharp  When cutting with a

edge, the two new halves sharp edge, the two
will have smooth surfaces. resulting halves will
have
https://byjus.com/chemistry/classification-of-solids-based-on-crystal-structure
irregular surfaces.
Rigidity They are rigid solids and They are not rigid, so mild
applying mild forces will effects may change the 10
NOTE: Practice personal hygiene
notprotocols
distort itsatshape.
all times shape.
Learning Competency:
Describe the difference in structure of crystalline and amorphous solids.
(STEM_GC11IMF-IIIa-c-104)
Activity 1: CRYSTALLINE SOLID

Objective: Identify the type of crystalline solid formed by a substance.
Materials: Paper and pen
Direction: Identify the type of crystalline solid (metallic, network covalent, ionic,
or molecular) formed by each of the following substances.
_1. CaCl2 6. CH3CH2CH2CH3
_2. SiC 7. HCl
_3. N2 8. NH4NO3
_4. Fe
9. K3PO4
_5. C (graphite)
10. SiO2
Q1. Explain why ice, which is a crystalline solid, has a melting temperature of 0 °C,
whereas butter, which is an amorphous solid, softens over a range of temperatures.
11
Activity 2: CONCEPTUAL PROBLEMS
Objective: Determine the difference in the structure of crystalline and
amorphous solids.
Directions: Read and answer the questions briefly but substantially. Write your
answer on the space provided.
a. Why is the arrangement of the constituent atoms or molecules more
important in determining the properties of a solid than a liquid or a gas?
b. A student obtained a solid product in a laboratory synthesis. To verify the

identity of the solid, she measured its melting point and found that the material
melted over a 12°C range. After it had cooled, she measured the melting point
of the same sample again and found that this time the solid had a sharp
melting point at the temperature that is characteristic of the desired product.
Why were the two melting points different? What was responsible for the
change in the melting point?
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Activity 3: CRYSTAL SYSTEMS
Objectives:
 describe the main points of difference between a crystalline solid and
an amorphous solid;
 recognize and identify at least 3 of the 7 crystal systems;
Introduction/background
Traditional ceramics are clay-based. Clays have a mineral composition and
minerals have a crystalline structure. A mineral is defined as a naturally occurring
inorganic substance with a certain chemical composition and set of physical
properties. Many minerals occur in characteristic crystal shapes.
A crystalline solid is made up of an orderly repeating pattern of

constituent atoms, molecules or ions extending in all 3 spatial dimensions.
A limited number of crystal shapes have been found in nature. There are
only 7 groups, or crystal systems, into which all naturally occurring crystals can be
placed. Careful observation of crystal shapes is one of the best ways to classify and
distinguish between different minerals. This activity focuses on three of these
crystal systems – cubic, triclinic and rhombohedral.
What you need

 Crystal systems diagram
 Copies of the student worksheet
 Small dropper bottles of 1 molL-1 solutions of sodium chloride (NaCl) and copper
sulfate (CuSO4)
 Clean ‘golden’ beach sand

 Simple light microscope plus microscope slides
 Electric hot plate
 Templates to construct models of cubic, triclinic and rhombohedral crystal
systems
 Paper glue
13
What to do
1. Hand out copies of the crystal systems diagram and discuss with the class.
Explain that they will be investigating 3 of these crystal systems – cubic,
triclinic and rhombohedral.
2. Make sure each student has the necessary materials and equipment and a
copy of the student worksheet and templates.
Student worksheet – Studying crystal systems
Note: Please refer to the figure below for the reference of cubic, triclinic and
rhombohedral crystals.
1. Cubic crystals:
 Place a drop of the sodium
chloride solution supplied in
the center of a microscope
slide.
 Gently heat the slide by
placing it on a hot plate (low
setting).
 When all the water has
evaporated, view the sodium
chloride crystals that remain
under the low power of a
microscope.
 Note the shape of the
crystals and sketch what
you see.
14
2. Triclinic crystals:
 Place a drop of the copper
sulfate solution supplied in
the center of a microscope
slide.
 Gently heat the slide by
placing it on a hot plate
(low setting).
 When all the water has
evaporated, view the
copper sulfate crystals that
remain under the low power
of a microscope.
crystals and sketch what
you see.
3. Rhombohedral crystals:
 Place a small sample of
beach sand in the center
of a microscope slide and
spread out the grains.
 View under the low power of
a microscope.
grains with a clear or whitish
appearance – these are
grains of the mineral quartz.
Sketch what you see.
4. Compare the sketches you have drawn to the crystal systems

diagram.
15
5. The mineral halite, a naturally occurring form of sodium chloride, has a cubic
crystal structure. Use the cubic crystal template to construct a model of a
halite crystal. Fold all edges. Glue the tabs and stick together.
6. The feldspar minerals plagioclase and orthoclase have a triclinic crystal structure.
Copper sulfate crystallizes out of solution as triclinic crystals just like the
feldspars. Use the triclinic crystal template to construct a model of a feldspar
mineral crystal. Fold all edges. Glue the tabs and stick together.
7. Quartz minerals are commonly found in beach sand. These tiny grains have
a rhombohedral shape (cubic system stretched along a body diagonal). Use
the rhombohedral crystal template to construct a model of a quartz crystal.
16
Crystal systems
17
Activity 4: BUILD ME UP
Objectives:
 use models to point out the angular and side length differences
that characterize the cubic, triclinic and rhombohedral crystal
systems.
Materials: template of cubic, triclinic and rhombohedral crystal system

Directions: Use the given template to point out the angular and side length
differences that characterize the cubic, triclinic and rhombohedral crystal systems
Cubic crystal template
All axes are of equal length. All axes are at 90° to one another.
All axes are of variable lengths. All axes are at variable

angles.
18
Rhombohedral crystal template
All the axes are equal. All axes are at angles other than
90°.
Activity 5: CRYSTALLINE AND AMORPHOUS SOLID (Pre-lab)

Objective: Distinguish between crystalline and amorphous substances.
Materials: Worksheet Students create
patterns using
Altair
designs.
Background: The atoms in crystalline solid matter
are arranged in regular, repeating .patterns. All other
types of solid matter are amorphous or without a
regular atomic arrangement. Metals and minerals
are
crystalline. Glass is amorphous. Depending upon its
composition, the crystalline pattern of a mineral may
not be visible in a hand sample. In this case minerals
are studied using X-ray diffraction, a technique that
uses the reflection of X-rays to determine crystal Electron level picture of tin
structure and composition.
19
Procedure:
1. Observe the following diagram below illustrating crystalline versus a non-
crystalline (amorphous) patterns.
Crystalline
Amorphous
2. On the worksheet, outline or fill in spaces on the Altair designs sheet to
create patterns. Your patterns are examples of order within the overall
structure of the design. This same type of organization generates
crystalline structures in minerals. The Altair designs sheet will naturally
guide your imagination through the maze of lines. Since no two students
are alike, none of you will see the same shapes, forms or patterns hidden
in these designs. You may create some very interesting artwork.
3. After finishing your patterns pair up with your seatmate and see if there
are
any similar patterns. The similarities and differences means that there are
many types of minerals, and hence many different crystal patterns.
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Activity 6: MULTIPLE CHOICE
Directions: Read each item carefully. Write the letter that corresponds to the correct
answer on the space provided.
_1. In amorphous solid, the atoms or molecules are held together in a

completely random formation.
A. True B. False
_2. Which of the following is true of solids?
A. Solids maintain a defined shape and size under all conditions.
B. All solids maintain a defined shape and size if conditions remain constant.
C. All solids have a lattice structure at atomic level.
D. All solids have a crystalline structure.
_3. One major difference between crystalline and amorphous solids is that
E. Crystalline solids have precise melting point.
F. Amorphous solids have a lattice structure.
G. Crystalline solids break unpredictably and can produce curved fragments.
H. Amorphous solids always behave consistently and uniformly.
_4. A friend in your chemistry class is struggling to understand why crystalline
solids are grouped into four main types: network, molecular, ionic, and
metallic. Which explanation below will best help him begin to understand why
chemists might have these groups?
I. Crystalline solids all share a lattice structure, but have different densities.
Chemists use the groups to organize the solids by density.
J. Crystalline solids all share a lattice structure and the same types of bonds,
but are composed of different elements. These elements affect the way
the solid conducts heat and electricity.
K. Crystalline solds all share a lattice structure, but behave differently under
similar conditions.
L. Crystalline solids all share a lattice structure, but the bonds that hold them
together at the atomic level differ. The elements that make up the solids
also differ. These differences affect how a solid conducts heat and
electricity, and its density.
21
_5. Solids have many different properties. _ solids are known for
their ability to be flattened into a sheet, stretched into a wire, and to conduct
energy well.
A. Molecular B. Metallic C. Network D. Ionic
_6. It is possible to tell the difference between a solid with a crystalline
structure and one with an amorphous structure just by looking at it.
A. True B. False
_7. An engineer is designing an electrical system and is looking for a material to
transmit energy. She has four solids available, each made with different
materials. To conduct energy most efficiently and effectively, she should use
material
A. Whose electrons are held with ionic bonds.
B. Whose electrons are held with covalent bonds.
C. Whose electrons are held with metallic bonds.
D. That is an electrical insulator.
_8. Which statement is true about the properties of solids?
A. Metallic solids have a high melting point.
B. Network solids are generally not soluble in water.
C. Molecular solids do not dissolve easily in water.
D. All ionic solids are similar in density.
22
Reflection
1. I learned that _
_
2. I enjoyed most on _
_
_
_
.
3. I want to learn more on

_
_
_.
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References:
https://opentextbc.ca/chemistry/chapter/10-5-the-solid-state-of-matter
https://byjus.com/chemistry/classification-of-solids-based-on-crystal-structure/
https://www.sciencelearn.org.nz/resources/1784-crystal-systems
Prepared by:
DIVINA S. RIBIACO
Baua National High School
24
GENERAL CHEMISTRY 2

Date:
Score:

PHASE DIAGRAM OF WATER AND CARBON DIOXIDE
Background Information for the Learners
A typical phase diagram consists of discrete regions that represent the

different phases exhibited by a substance (Figure 12.4.1). Each region
corresponds to the range of combinations of temperature and pressure over which
that phase is stable. The combination of high pressure and low temperature (upper
left of Figure 12.4.1) corresponds to the solid phase, whereas the gas phase is
favored at high temperature and low pressure (lower right). The combination of high
temperature and high pressure (upper right) corresponds to a supercritical fluid.
https://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_General_Chemistry_(Petrucci_et_al.)/12%3A_Intermolec
ular_Forces%3A_Liquids_And_Solids/12.4%3A_Phase_Diagrams
Figure 12.4.1: A Typical Phase Diagram for a Substance That Exhibits Three
Phases—Solid, Liquid, and Gas—and a Supercritical Region
The solid phase is favored at low temperature and high pressure; the gas
phase is favored at high temperature and low pressure.
25
The lines in a phase diagram correspond to the combinations of temperature
and pressure at which two phases can coexist in equilibrium. In Figure 12.4.1, the
line that connects points A and D separates the solid and liquid phases and shows
how the melting point of a solid varies with pressure. The solid and liquid phases
are in equilibrium all along this line; crossing the line horizontally corresponds to
melting or freezing. The line that connects points A and B is the vapor pressure
curve of the liquid, which we discussed in Section 11.5. It ends at the critical point,
beyond which the substance exists as a supercritical fluid. The line that connects
points A and C is the vapor pressure curve of the solid phase. Along this line, the
solid is in equilibrium with the vapor phase through sublimation and deposition.
Finally, point A, where the solid/liquid, liquid/gas, and solid/gas lines intersect,
is the triple point; it is the only combination of temperature and pressure at
which all three phases (solid, liquid, and gas) are in equilibrium and can therefore
exist simultaneously. Because no more than three phases can ever coexist, a phase
diagram can never have more than three lines intersecting at a single point.
Remember that a phase diagram, such as the one in Figure 12.4.1, is for a
single pure substance in a closed system, not for a liquid in an open beaker in
contact with air at 1 atm pressure. In practice, however, the conclusions reached
about the behavior of a substance in a closed system can usually be extrapolated
to an open system without a great deal of error.
The Phase Diagram of Water
Figure 12.4.2 shows the phase diagram of water and illustrates that the triple
point of water occurs at 0.01°C and 0.00604 atm (4.59 mmHg). Far more
reproducible than the melting point of ice, which depends on the amount of
dissolved air and the atmospheric pressure, the triple point (273.16 K) is used to
define the absolute (Kelvin) temperature scale. The triple point also represents the
lowest pressure at which a liquid phase can exist in equilibrium with the solid or
vapor. At pressures less than 0.00604 atm, therefore, ice does not melt to a liquid
as the temperature increases; the solid sublimes directly to water vapor.
Sublimation of water at low temperature and pressure can be used to “freeze-dry”
foods and beverages. The food or beverage is first cooled to subzero temperatures
and placed in a container in which the pressure is maintained below 0.00604 atm.
Then, as the temperature is increased, the water
26
sublimes, leaving the dehydrated food (such as that used by backpackers or
astronauts) or the powdered beverage (as with freeze-dried coffee).
Figure 12.4.2: Two Versions of the Phase Diagram of Water. (a) In this graph
with linear temperature and pressure axes, the boundary between ice and liquid
water is almost vertical. (b) This graph with an expanded scale illustrates the
decrease in melting point with increasing pressure. (The letters refer to points
discussed in Example 12.4.1).
The phase diagram for water illustrated in Figure 12.4.2b shows the boundary
between ice and water on an expanded scale. The melting curve of ice slopes up
and slightly to the left rather than up and to the right as in Figure 12.4.1; that is, the
melting point of ice decreases with increasing pressure; at 100 MPa (987 atm), ice
melts at
−9°C. Water behaves this way because it is one of the few known
substances for which the crystalline solid is less dense than the liquid (others
include antimony and bismuth). Increasing the pressure of ice that is in equilibrium
with water at 0°C and 1 atm tends to push some of the molecules closer together,
thus decreasing the volume of the sample. The decrease in volume (and
corresponding increase in density) is smaller for a solid or a liquid than for a gas,
but it is sufficient to melt some of the ice.
In Figure 12.4.2b point A is located at P = 1 atm and T = −1.0°C, within the

solid (ice) region of the phase diagram. As the pressure increases to 150 atm
while the temperature remains the same, the line from point A crosses the
ice/water boundary to point B, which lies in the liquid water region. Consequently,
applying a pressure of
150 atm will melt ice at −1.0°C. We have already indicated that 27 the
NOTE: Practice
pressure personal of
dependence hygiene protocolspoint
the melting at all of
times
water is of vital importance. If the
solid/liquid
boundary in the phase diagram of water were to slant up and to the right rather than
to the left, ice would be denser than water, ice cubes would sink, water pipes would
not burst when they freeze, and antifreeze would be unnecessary in automobile
engines.
Referring to the phase diagram of water in Figure 12.4.2:
a. Predict the physical form of a sample of water at 400°C and 150 atm.
b. Describe a changes that occur as the sample in part (a) is slowly
allowed to cool to -50°C at a constant pressure of 150 atm
Given: phase diagram, temperature, and pressure
Asked for: physical form and physical changes
Strategy:
 Identify the region of the phase diagram corresponding to the initial
conditions and identify the phase exist in this region.
 Draw a line corresponding to the given pressure. Move along that line in
the appropriate direction (in this case cooling) and describe the phase
changes.
Solution:
a. Locate the starting point on the phase diagram in part (a) in
Figure 12.4.212.4.2. The initial conditions correspond to point A, which lies in
the region of the phase diagram representing water vapor. Thus water at T =
400°C and P = 150 atm is a gas.
b. Cooling the sample at constant pressure corresponds to moving left along the
horizontal line in part (a) in Figure 12.4.212.4.2. At about 340°C (point B), we
cross the vapor pressure curve, at which point water vapor will begin to
condense and the sample will consist of a mixture of vapor and liquid. When
all of the vapor has condensed, the temperature drops further, and we enter
the region corresponding to liquid water (indicated by point C). Further
cooling brings us to the melting curve, the line that separates the liquid and
solid phases at a little below 0°C (point D), at which point the sample will
consist of a mixture of liquid and solid water (ice). When all of the water has
frozen, cooling the sample to −50°C takes us along the horizontal line to point
E, which lies within the region corresponding to solid water. At P = 150
atm and T = −50°C, therefore, the sample is solid ice.
28
The Phase Diagram of Carbon dioxide
In contrast to the phase diagram of water, the phase diagram of
CO2 (Figure 12.4.312.4.3) has a more typical melting curve, sloping up and to the right. The
triple point is −56.6°C and 5.11 atm, which means that liquid CO2 cannot exist at pressures
lower than 5.11 atm. At 1 atm, therefore, solid CO2 sublimes directly to the vapor while
maintaining a temperature of −78.5°C, the normal sublimation temperature. Solid
CO2 is generally known as dry ice because it is a cold solid with no liquid phase observed
when it is warmed.
Dry ice (CO2(s)CO2(s)) sublimed in air under room
temperature and pressure.
Also notice the critical point at 30.98°C and 72.79 atm. Supercritical carbon dioxide
is emerging as a natural refrigerant, making it a low carbon (and thus a
more environmentally friendly) solution for domestic heat pumps.
Figure 12.4.3: The Phase Diagram of Carbon Dioxide. Note the critical point,
the triple point, and the normal sublimation temperature in this diagram.
29
The Critical Point
As the phase diagrams above demonstrate, a combination of high pressure

and low temperature allows gases to be liquefied. As we increase the temperature
of a gas, liquefaction becomes more and more difficult because higher and
higher pressures are required to overcome the increased kinetic energy of the
molecules. In fact, for every substance, there is some temperature above which
the gas can no longer be liquefied, regardless of pressure. This temperature is the
critical temperature (Tc), the highest temperature at which a substance can exist as a liquid.
Above the critical temperature, the molecules have too much kinetic energy for the
intermolecular attractive forces to hold them together in a separate liquid

phase. Instead, the substance forms a single phase that completely occupies the
volume of the container. Substances with strong intermolecular forces tend to form a
liquid phase over a very large temperature range and therefore have high critical
temperatures. Conversely, substances with weak intermolecular interactions
have relatively low critical temperatures. Each substance also has a critical pressure (Pc),
the minimum pressure needed to liquefy it at the critical temperature. The combination
of critical temperature and critical pressure is called the critical point. The critical
Figure 12.4.1:
temperatures andCritical Temperatures
pressures andcommon
of several Pressures of Some Simple
substances Substances
are listed in Figure
12.4.1 Substance Tc (°C) Pc (atm)
NH3
132.4 113.5
CO2
31.0 73.8
CH3CH2OH (ethanol)
240.9 61.4
He −267.96 2.27
Hg 1477 1587
CH4
−82.6 46.0
N2
−146.9 33.9
H 2O
374.0 217.7
*High-boiling-point, nonvolatile liquids have high critical temperatures and vice versa.
30
Interpret the phase diagram of water and carbon dioxide (STEM_GC11IMFIIIa-c-
107)
Activity 1: WATER AND CARBON DIOXIDE

Objective: determine the state of water at each given temperature and pressure.
Figure A.
Figure B
courses.lumenlearning.com/wsu-sandbox2/chapter/phase-diagram-2/
A. Directions: Using the phase diagram (fig. a) for water, determine the state of H2O at the
following temperatures and pressures. Write your answer on the space

provided.
_1. -10 °C and 50 kPa

_2. 25°C and 90 kPa
_3. 50°C and 40 kPa
_4. 80°C and 5 kPa
_5. -10°C and 0.3 kPa
31
A. Directions: Using the phase diagram for carbon dioxide, determine the state of
CO2 at the following temperatures and pressures. Write your answer on the space provided.
6. −30 °C and 2000 kPa
_7. −60 °C and 1000 kPa
_8. −60 °C and 100 kPa
_9. 20 °C and 1500 kPa
_10. 0 °C and 100 kPa
Activity 2: CRITICAL THINKING (H2O and CO2)

Objective: Interpret the phase diagram of water and carbon dioxide.
Directions: Read and analyze the given problem, then answer the questions below.
Write your answer on the space provided.
Problem: Imagine a substance with the following points on the phase diagram: a
triple
point at .5 atm and -5ºC; a normal melting point at 20ºC; normal boiling point at
150ºC; and a critical point at 5 atm and 1000ºC. The solid liquid line is “normal”
(meaning positive sloping). For this, complete the following:
1. Describe what one would see at pressures and temperatures above 5 atm
and 1000ºC.
2. Describe what will happen to the substance when it begins in a vacuum at -15
ºC and is slowly pressurized.
3. Describe the phase changes from -80ºC to 500ºC at 2 atm.
32
Activity 3: THE COOL CHEMISTRY OF DRY ICE
Objective: Interpret the phase diagram of water.
Directions: Read and analyze the given problem, then answer the question below.
Problem: Referring to the phase diagram of water in figure 12.4.2, predict the
physical form of a sample of water at -0.0050ºC as the pressure is gradually
increased from 1.0 mmHg to 218 atm. Write your answer on the space
provided.
_
_
_
.
33
Activity 4: DIHYDROGEN MONOXIDE
Objective: Interpret the phase diagram of water.
A phase diagram of water is shown below
B 4
C (374 °C, 218 atm)
1 2
3
A (0.01 °C,
0.00603 atm)
Temperature
https://scilearn.sydney.edu.anu...
1. Identify the four phases shown as 1-4 in the phase
diagram.
a. c.
b. d.
2. What names are given to the points A and

C?
a. b.
3. The boundary line A-B is slightly tilted to the left. What are the physical
and biological significances of this?
34
Activity 5: CARBON DIOXIDE
Objective: determine the state of water at each given temperature and pressure.
Directions: Answer the following questions based on the P-T phase diagram of
carbon dioxide.
Phase diagram of carbon dioxide
https://www.toppr.com/ask/question/answer-the-following-questions-based-on-the-pt-phase-diagram/
1. At what temperature and pressure can the solid, liquid and vapor phases
of CO2 co-exits in equilibrium?
2. What is the effect of decrease of pressure on the fusion and boiling point
of CO2?
3. What are the critical temperature and pressure for CO2? _.
35
Reflection
1. I learned that _
_
_
_
.
3. I want to learn more on _

_
_.
36
References:
https://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_General_Che
mistry_(Petrucci_et_al.)/12%3A_Intermolecular_Forces%3A_Liquids_And_Solids/12
.4%3A_Phase_Diagrams
https://msnucleus.org/membership/html/k-6/rc/minerals/3/rcm3_4a.html
https://chem.libretexts.org/Bookshelves/Physical_and_Theoretical_Chemistry_Textb
ook_Maps/Supplemental_Modules_(Physical_and_Theoretical_Chemistry)/Physical
_Properties_of_Matter/States_of_Matter/Phase_Transitions/Phase_Diagrams
https://www.toppr.com/ask/question/answer-the-following-questions-based-on-the-pt-
phase-diagram/
courses.lumenlearning.com/wsu-sandbox2/chapter/phase-diagram-2/
Prepared by:
DIVINA S. RUBIACO
Baua National High School
37
GENERAL CHEMISTRY 2
Name: Grade Level:
Date: Score:
HEATING AND COOLING CURVES

Heating Curve
Imagine that you have a block of ice that is at a temperature of -30°C, well
below its melting point. The ice is in a closed container. As heat is steadily added to
the ice block, the water molecules will begin to vibrate faster and faster as they
absorb kinetic energy. Eventually, when the ice has warmed to 0°C, the added
energy will start to break apart the hydrogen bonding that keeps the water
molecules in place when it is in the solid form. As the ice melts, its temperature
does not rise. All of the energy that is being put into the ice goes into the melting
process and not into any increase in temperature. During the melting process,
the two states – solid and liquid – are in equilibrium with one another. If the
system was isolated at that point and no energy was allowed to enter or leave, the
ice-water mixture at 0°C would remain. Temperature is always constant during a
change of state.
Continued heating of the water after the ice has completely melted will now
increase the kinetic energy of the liquid molecules and the temperature will rise.
Assuming that the atmospheric pressure is standard, the temperature will rise
steadily until it reaches 100°C. At this point, the added energy from the heat will
cause the liquid to begin to vaporize. As with the previous state change, the
temperature will remain at 100°C while the water molecules are going from the
liquid to the gas or vapor state. Once all the liquid has completely boiled away,
continued heating of the steam (remember the container is closed) will increase its
temperature above 100°C.
38
The experiment described above can be summarized in a graph called
a heating curve:
D E
B C
 Between A & B, the material is a solid. The heat supplied to the material is
used to increase the kinetic energy of the molecules and the temperature
rises.
 Between B & C, the solid is melting. Heat is still being supplied to the material
but the temperature does not change. Heat energy is not being changed into
kinetic energy. Instead, the heat is used to change the arrangement of the
molecules.
 At point C, all of the material has been changed to liquid.
 Between C & D, the heat supplied is again used to increase kinetic energy of
the molecules and the temperature of the liquid starts to rise.
 Between C & D, the liquid is heated until it starts to boil.
 Between D & E, the liquid is still being heated but the extra heat energy does
not change the temperature (kinetic energy) of the molecules. The heat
energy is used to change the arrangement of the molecules to form a gas.
 At point E, all of the liquid has been changed into gas.
 Between E & F, the gas is heated and the heat energy increases the kinetic
energy of molecules once more, so the temperature of the gas increases.
39
When a system contains only one phase (solid, liquid, or gas), the
temperature will increase when it receives energy. The rate of temperature
increase will be dependent on the heat capacity of the phase in the system. When
the heat capacity is large, the temperature increases slowly, because much energy is
required to increase its temperature by one degree. Thus, the slopes of temperature
increase for the solid, liquid, and gases are different.
In the heating curve of water, the temperature is shown as heat is continually

added. Changes of state occur during plateaus because the temperature isconstant.
The change of state behavior of all substances can be represented with a

heating curve of this type. The melting and boiling points of the substance can be
determined by the horizontal lines or plateaus on the curve. Other substances would
of course have melting and boiling points that are different from those of water. One
exception to this exact form for a heating would be for a substance such as carbon
dioxide which sublimes rather than melts at standard pressure. The heating curve for
carbon dioxide would have only one plateau, at the sublimation temperature of CO2.
Cooling Curves
Heating curves show how the temperature changes as a substance is heated

up. Cooling curves are the opposite. They show how the temperature changes as a
substance is cooled down. Just like heating curves, cooling curves have horizontal
flat parts where the state changes from gas to liquid, or from liquid to solid. These
are mirror images of the heating curve.
You will use lauric acid in a school lab to make your own cooling curve. Lauric
acid has a melting point of about 45°C and is easily melted in a test tube placed in a
beaker of hot water. The temperature can be followed using a thermometer or
temperature probe connected to a data logger. The liquid may be cooled by putting
the boiling tube in a beaker of cold water or just leaving it in the air.
40
Note: The melting and freezing occur at the same temperature. During
freezing, energy is removed and during melting, energy is absorbed.
Energy Changes
Since Temperature is a measure of "Average Kinetic Energy", any change in

temperature is a change in Kinetic Energy. All of the diagonal line segments on a
heating or cooling curve show a temperature change and therefore a change in
kinetic energy.
During these regions, a single state of matter exists and the sample is either
getting hotter or cooler. During the horizontal line segments, there is no change in
temperature, so kinetic energy remains constant. However, all the energy that is
absorbed or released is related to changes in potential energy.
Remember the 3 Ps: Plateau, Phase change and Potential Energy

Change.
Source: https://
www.rcboe.org/cms/lib/GA01903614/Centricity/Domain/1951/Heating%20and
%20Cooling%20Curves%20new.pdf
41
Learning Competency
Determine and explain the heating and cooling curve of a substance

(STEM_GC11IMFIIIa-c-109)
Activity 1: THE COOLING CURVE OF WATER
Directions: Using the curve below describe what is happening between each of
the points:
i. A-B
ii. B-C
iii. C-D
iv. D-E
v. E-F
42
Activity 2: THE HEATING CURVE OF WATER
Directions: Use the cooling curve below to answer the following questions.
Photo credit: https://sites.google.com/site/heatingandcoolingcurves/_/rsrc/1299042706797/curveexplanation/hEATING%20CURVE.png
1. In which region(s) does temperature remain constant?
2. In which region(s) does temperature increase?
3. In which region(s) of the graph does a phase change occur?
4. In which region(s) of the graph would the substance only be in one phase?
5. In which region(s) of the graph would the substance be a solid only?
6. In which region(s) of the graph would the substance be a solid and a

liquid?
7. In which region(s) of the graph would the substance be a liquid and a gas?
8. In which region(s) of the graph would the substance be a gas only?
9. In which region(s) of the graph does boiling take place?
10. In which region(s) of the graph does melting take place?
43
Reflection:
1. I learned that
2. I enjoyed most on
44
References:
 https://www.quora.com/How-do-you-determine-the-freezing-point-of-a-
solution-do-you-follow-this-process-for-every-solution
 Curriculum Guide and Teaching Guide. K to 12 Basic Education Curriculum

Senior High School – Science, Technology, Engineering and Mathematics
(STEM) Specialized Subject
 http://teachtogether.chedk12.com/teaching_guides/view/499
 courses.lumenlearning.com/cheminter/chapter/heating-and-cooling-curves-
also-called-temperature-curves/
 https://www.rcboe.org/cms/lib/GA01903614/Centricity/Domain/1951/Heating%
20and%20Cooling%20Curves%20new.pdf
 https://www.tes.com/teaching-resource/graphs-and-heating-cooling-curves-
worksheet-6064146
 https://chem.libretexts.org/Bookshelves/General_Chemistry/Map%3A_Chemis
try_The_Central_Science_(Brown_et_al.)
Prepared by:
JACKIE B. UBINA
Solana National High School
45
GENERAL CHEMISTRY 2
Name: Grade Level: _
Date:_ Score: _
WAYS OF EXPRESSING CONCENTRATION OF SOLUTIONS
The term solution is used in Chemistry to describe a homogeneous mixture in

which at least one substance (the solute) is dissolved in another substance (the
solvent). The solvent is the substance in greater quantity and the name of the of the
solution is taken from the name of the solute. For example, when sodium chloride is
dissolved in water, sodium chloride is the solute, and water is the solvent, and the
solution is called a sodium chloride solution.
There are different methods of expressing solution concentrations namely;

Molarity, Molality, Percent by Mass, Percent by Volume, Mole fraction and Parts Per
Million. These methods are used to express relative amounts of solute and solvent in
a solution. In other words, the concentration of a solution is the amount of solute
present in a given amount of solvent, or a given amount of solution.
Percent by Mass
The Percent by Mass (also called percent by weight or weight percent) is the
ratio of the mass of a solute to the mass of the solution, multiplied by 100 percent:
Mass of solute
Percent by Mass = X 100%
Mass of solute + Mass of solvent
46
Or,
Mass of solute
Total mass of Solution
Let us consider the examples below;
Example 1: In a solution prepared by dissolving 24g of Sodium Chloride

(NaCl) in 152g of water, what is the mass percent of
Sodium Chloride (NaCl)?
Solution: First, identify the given.
Given: Solute = 24g of NaCl
Solvent = 152g of Water
Second, identify the unknown or what is being asked in

the problem.
Unknown = Percent by Mass of NaCl.
Third, write the formula and calculate the unknown.
Mass of solute
Mass of solute + Mass of
solvent
24g NaCl
Percent by Mass of NaCl= X 100%
24g NaCl + 152g Water
24g
Percent by Mass of NaCl= X 100% = 14%
176g
47
Example 2: A sample of 0.892 g of potassium chloride (KCl) is dissolved
in 54.6 g of water. What is the percent by mass of KCl in the
solution?
Given: Solute = 0.892g of KCl
Solvent = 54.6g of water

the problem.
Unknown = Percent by Mass of KCl.
Mass of solute
Percent by Mass Mass of solute + Mass of solvent
=
0.892g of KCl
Percent by Mass of KCl= X 100%
0.892g of Cl + 54.6g of Water
Percent by Mass of KCl= 0.892g

X 100% = 1.61%
55.492g
Percent by Volume
Percent by Volume or Volume Percent is a common expression used for

expressing concentration. It is related to the molar concentration but the difference is
that the volume percent is expressed with a denominator of 100. It is used for
reporting concentration of liquids solutes in solution. It is also called %V/V and it
is always expressed as percentage (%) and the units of the volume should be in mL.
. Percent
48
by volume is also widely use in pharmaceutical field for expressing the concentration
of different components in solution.
Volume of solute X 100%

Percent Volume =
Volume of solute +Volume of solvent
Or,
Percent Volume = Volume of solute X 100%
Total Volume of Solution
Example 1: A solution of propanol (CH3CH2CH2OH) is prepared by
dissolving 67 mL in enough water to have a final volume of

250 mL. What is the volume percent of the propanol?
Given: Solute = 67mL propanol
Solution = 250mL

the problem.
Unknown = Percent Volume of Propanol
49
Volume of solute
Percent Volume = X 100%
Percent Volume = 67 mL
X 100% = 26.8%
250mL
Example 2: How many mL of HNO3 concentrate are needed to prepare 250 mL
of solution 4%?
Solution: First, identify the given
Given: solution = 250mL
Volume = 4 percent by

the problem.
Unknown = Volume of solute (HNO3)
Third, write the formula and calculate the unknown. But in this
case we have to derive the formula.
From the mother formula;

Volume of solute
Percent Volume = X 100%
50
To derived formula to get the volume of solute.
(Percent by Volume) (Volume of Solution)
Volume of Solute =
100%
Thus,
Volume of Solute = (4%) (250mL)

= 10mL
100%
Parts per Million
When the amount of solute is very small, as with trace impurities in water,
concentration is often expressed in parts per million.
PPM is a term used in chemistry to denote a very, very low concentration of a

solution. One gram in 1000 ml is 1000 ppm and one thousandth of a gram (0.001g)
in 1000 ml is one ppm. Parts Per Million (ppm) is a measurement of the
concentration of a solution.
Gram of Solute X 106

Parts per Million =
Gram of
Solution
Example 1: What is the concentration of a solution in parts per million, if

0.02 grams of NaCl is dissolved in 1000 grams of solution?
Given: Solute = 0.02g of NaCl
Solution = 1000g
51
the problem.
Unknown = Concentration in parts per million
Third, write the formula and calculate the unknown
Gram of Solute X 106

Parts per Million =
Gram of
Solution
0.02 grams
Parts per Million = X 106 = 20 ppm
1000 grams
Example 2: What is the total mass of solute in 1000g of a solution

having a concentration of 5ppm?
Given: Solution = 1000 grams
Concentration in ppm = 5ppm

the problem.
Unknown = Mass of Solute
Third, write the formula and calculate the unknown. But in this
case we have to derive the formula.
52
Gram of Solute
Parts per Million = X 106
Gram of Solution
To derived formula to get the unknown which is the mass of solute.
(ppm) (gram of solution)

Gram of Solute =
1000000
Thus,
( 5 ppm) (1000 grams)

Gram of Solute = = .005g
1000000
Mole Fraction
It is a dimensionless quantity that expresses the ratio of the number of moles

of one component to the number of moles of all components present. For a mixture
of two substances, A and B, the mole fractions of each would be written as follows:
Mole fraction of component A: mol A

XA =
mol A + mol B
mol B
Mole fraction of component B:
XB =mo l A + mol
B
In general, the mole fraction of component “i” in a mixture is given

by;
ni
Xi =
nT
53
where ni and nT are the number of moles of component i and the total number of moles
present, respectively. The mole fraction is always smaller than 1.
*The mole fraction is unitless or dimensionless because it is a ratio of two similar

quantities*
Example 1: 0.100 mole of NaCl is dissolved into 100.0 grams of pure H2O. What is the
mole fraction of NaCl? What is the mole fraction of
H2O?
Given: 0.100 mole of NaCl
100.0 grams of pure H2O

the problem.
Unknown: mole fraction of H2O.
*Note that the component being asked in the problem is the water (H2O) component, but as
you may notice, the unit of water as stated in the problem is in grams. Before you
can finally input the all the given in the formula you have to make sure that units to
be used are appropriate. Since we are dealing with mole fraction, we have to
convert 100 grams of H2O into moles using the molar mass of H2O (18g/mol).*
Converting 100 grams of water into moles:

(1 mol H2O) = 5.56mol H2O
(100 grams of H2O) X
(18.0g H2O)
54
Xi = ni
nT
5.56 mol
= 0.982
Xi =
5.66 mol
Example 2: A solution is prepared by mixing 25.0 grams of water and 25.0
grams of ethanol (C2H5OH). Determine the mole fractions of each
substance.
Given: 25 grams of water
25 grams of ethanol
*As you may notice, all the given are in grams. You may think that you could solve
right away for the mole fraction since you will arrive in a unit less answer. But that is
not how it works in mole fraction because mole fraction deals with moles, and so we
need to convert this grams into moles first before we can be able to get the mole
fraction. In converting the given grams to moles, refer to the method shown in
example 1 and the molar mass of the substance can be summed up using the mass
of the atoms in that given substance.*
Thus, 25 grams of water = 1.34 mol of water
25 grams of ethanol = 0.543 mole of ethanol
Second, identify the unknown or what is being asked the

in problem.
55
Unknown: Mole fractions of each substance.
Therefore, for this problem we to treat water

as
have component A and ethanol
as component B.
Water as component A Ethanol as component B

mol A mol B
XA = XB =
mol A + mol mol A + mol B
B
1.34 mol 0.543 mol

XA = = 0.71 = 0.29
XB =
1.34 mol+ 0.543mol 1.34 mol + 0.543mol
Molarity
Otherwise known as “molar concentration”. It is defined as the number of moles

of solute per liter of solution. The SI unit for molarity is mol/m3; however, you will
almost always encounter molarity with the units of mol/L. A solution of concentration
1 mol/L is also denoted as “1 molar” (1 M). Mol/L can also be written in the
following ways (however, mol/L, or simply M, is most common)
It is important to keep in mind that molarity refers only to the amount of solute
originally dissolved in water and does not take into account any subsequent
processes, such as the dissociation of a salt or the ionization of an acid.
In equation form it is written as;

Moles of solute
M=
Liter of Solution
and can be expressed algebraically as;

n
M=
v
56
Where n, denotes the number of moles of solute. And v is the volume of solution
in liters. Note that the volume in the definition of Molarity refers to the volume of
solution and not the volume of the solvent. The reason for this is because one liter of
solution usually contains either slightly more or slightly less than 1 liter of solvent,
due to the presence of the solute.
Example 1: How many grams of potassium dichromate (K2Cr2O7) are required to prepare a
250-mL solution whose concentration is 2.16 M ?
Given: Molarity = 2.16M
Solution = 250mL
*Note that the solution must be converted into Liters and so

250 mL is equal to 0.250L.*

in problem.
Unknown = Potassium dichromate in grams
Third, write the formula and calculate the unknown. But in

this case we have to derive the formula.
From the mother formula; n

M= v
M
=
To derived formula to get the moles of potassium dichromate. (which later on be

converted into grams since the problem asks for the quantity of potassium
dichromate
in grams). N = (M) (v)
57
Thus,
N = (2.16M) (0.250L) = 0.54 mol of potassium dichromate.
The 0.54 mol potassium dichromate is not yet the final answer because we still must
convert it into grams. Using the molar mass of K2Cr2O7 which is 294.2 g.
Converting 0.540mol of K2Cr2O7 to grams we have;
294.2 g of K2Cr2O7 = 159g of K2Cr2O

(0.540mol of K2Cr2O7) X 1mol of K2Cr 2O
Example 2: In a biochemical assay, a chemist needs to add 3.81 g of

glucose to a reaction mixture. Calculate the volume in milliliters
of a 2.53 M glucose solution she should use for the
addition.
Given: 3.81 grams of glucose
2.53 M of glucose
*Glucose is given in grams and we must first convert it into moles using its molar
mass which is equal to 180.2 grams. Thus, 3.81 grams of glucose is equal to
2.114x10-2 mol of glucose.*

in problem.
Unknown: Volume in mL of a 2.53 M glucose solution
58
Third, write the formula and calculate the unknown. But in
this case we have to derive the formula.

n
M= v
To derived formula;
n
V= M
Thus,
2.114x10-2 ol of glucose
m
= 8.36x10-3 L
V= 2.53M
*Notice that our units is in Liter and the problem is asking for the uni to be in mL, that
is why we must convert 8.36x10-3 L into mL which is equivalent to 8.36 mL solution.
And 8.36 mL is the final answer for this problem.*
Molality
It is an intensive property of solutions, and it is calculated as the moles of a solute

divided by the kilograms of the solvent. Unlike molarity, which depends on the
volume of the solution, molality depends only on the mass of the solvent.
Molality is the number of moles of solute dissolved in 1 kg (1000 g) of solvent—that
is,
Moles of solute
m=
Mass of solvent
The SI unit for molality is mol/kg. A solution with a molality of 3 mol/kg is often
described as “3 molal” or “3 m.” However, following the SI system of units, mol/kg or
a related SI unit is now preferred.
59
Example 1: Calculate the molality of a sulfuric acid solution containing

24.4 g of sulfuric acid in 198 g of water. The molar mass
of sulfuric acid is 98.09 g.
Solution: First,identify the given
Given: Solute = 24.4 grams of sulfuric acid
Solvent = 198 grams of water
*Always be mindful with the units, the solute given is in grams and it should be first
converted into moles (that is 0.249 molH2SO4) and also the solvent is expressed in grams
that should be in kilograms so, solvent must be 0.198 kg).*
Second, identify the unknown or what is being asked in the

problem.
Unknown: Molality of sulfuric acid
m= Moles of
m=
m
solute
=
Thus, Mass of solvent
0.249 molH2SO4
m= = 1.26m
0.198 kg
Example 2: 80.0 grams of glucose (C6H12O6 ) is dissolved in 1.00 kg of solvent.
What is its molality? Molar mass of (C6H12O6 ) is
equal to 180g/mol.
Solution: First, identify the given;
Given: Solute = 80.0 grams of glucose
Solvent = 1.00kg
60
*Remember that, molality should be in the units of moles and kilogram. So, 80.0
grams of glucose should be converted first into moles. Thus, glucose is equal to
0.444 mol.*

in problem.
Unknown: Molality of Glucose solution
Moles of
m=
solute
Thus, Mass of solvent
m= 0.444 mol glucose

= 0.444m
1.00kg
Use different ways of expressing concentration of solutions: Molarity, Molality,
Percent by mass, Percent by volume, mole fraction and ppm. (STEM_GC11PP-IIId-
f-111)
Activity 1: Choose The “RIGHT” One
Directions: Read and analyze the following questions and choose from the
given options the best correct answer.
1. Which of the following is not the unit of concentration?

a. Mole/m3
b. Molar
c. N/m3
d. ppm
61
2. Which of the following material present in a solution is largest in amount?
a. Salt
b. Solute
c. Solvent
d. Molecules
3.Which of the following is defined as the relative amount of solute and solvent in a
solution?
a. Polarity
b. Solubility
c. Miscibility
d. Concentration
4. Which of the following describes a solvent in a solution?
a. Always a water
b. Always a liquid
c. The substance being dissolved
d. The substance present in the greatest amount
5. Which of the following is defined as the quantity of solute per unit

volume?
a. Density
b. Concentration
c. Mole
d. None of the above mentioned
62
Activity 2: CONCEPTUAL ANALYSIS
Directions: Base on what you have learned from this lesson and from other previous
lessons. Analyze the given statement and scientifically discuss your claim.
A solution is prepared at 20oC and its concentration is expressed in two different

units; Molarity and Molality. The solution is then heated to 88oC. Which of the
concentration units will change?
Activity 3: MATCH ME!
Directions: Read and analyze the following questions and compute for what is
unknown in the given problem. Choose the correct numerical value from the
response list on the right. Responses on the right may be used more than once or
need not be used at all.
B. 58.44g
1.What is the percent by volume concentration of a
solution in which 75.0mL of ethanol is diluted to a volume A. 1.43mL
of 250mL?
D. 12.39%
2.What volume of acetic acid is present in a bottle
containing 350.0mL of a solution which measures 5.00% C. 1gram
concentration.
E.17.5mL
3.Find the percent by mass in which 41.0g of NaCl is
dissolved in 331g of water. F.2.0x1010ppm
4.How many grams of NaCl would you need to prepare
G. 30%
200.0mL of a 5M solution.
5. What is the ppm concentration of 6.00 mL sample of J. 60ppm
solution that has 3.6 x 10-4 g of sodium ions?
I. 8.07%
H. 33.3%
63
Activity 4: Calculate The Unknown
Directions: Read and analyze the following questions and compute for what is
unknown in the given problem. Show complete solution by stating the given and
unknown, and show the process from writing the formula to unit conversion (if
applicable).
1.Suppose you added 4.0 moles of sugar to 10.0 L of solution. Calculate the molar
concentration of the solution.
2.A sample of water taken from a nearby lake is found to have 0.0035 mol of salt in a
100mL solution. Determine the molar concentration of the solution in the lake.
3.You dissolve 30.0g of sodium sulfate (Na2SO4(s)) into 300mL of water. Calculate the molar
concentration of the solution.
4.What is the Molality of a solution containing 7.78g of Urea [(NH2)2CO2] in 203g of water?
5.Lead is a poisonous metal that especially affects children because they retain a
larger fraction of lead than adults do. Lead levels of 0.250ppm in a child cause
delayed cognitive development. How many moles of lead present in 1.00g of
child’s blood would 0.250ppm represent.
6.Acetone, C3H6, is the main ingredient of nail polish remover. A solution is made up by adding
35.0mL of acetone (d=0.790g/mL) to 50.0mL of ethyl alcohol, C2H6O (d=0.789g/mL).
Assuming volumes are additive, calculate (a) the mass percent of acetone in the
solution. (b) the volume percent of ethyl alcohol in the solution. (c) the mole fraction
of acetone in the solution.
Activity 5: Expressing Concentration in Different Units
Directions: Read and internalize the short story below and answer the questions
that follow. Complete solution is required.
“The coronavirus disease (COVID-19) is an infectious disease caused by a new

strain of coronavirus. This new virus and disease were unknown before the
outbreakbegan in Wuhan, China, in December 2019.
64
On 30 January 2020, the Philippine Department of Health reported the first case of
COVID-19 in the country with a 38-year-old female Chinese national. On 7 March,
the first local transmission of COVID-19 was confirmed. WHO is working closely with
the Department of Health in responding to the COVID-19 outbreak.” Aki and her
family were alarmed with the news they watched and so first thing in the morning
they rush to the nearest convenient store to secure disinfectant and sanitizers but
unfortunately the store already had empty shelves of the essentials they needed.
They went to other stores searching and to their dismay they acquired nothing.
They were on their way home when she suddenly remembered her past lesson on
“solutions”, and so she immediately ran back to the store and purchase the things
she needed for her simple experiment. She bought a bleach (Zonrox), gloves and
measuring spoon and cups. Arriving at home she then put her gloves on and
prepared the things she needed such as; 5tbsp bleach (0.0739L), 1 gallon of water
(3.8L), pail and stirring rods. Using the pail with 3.8L of water, she carefully poured
the 5tbsp bleach solution and then mixed it with the stirring rod. And they now have a
disinfectant.
In connection to her home made disinfectant and with our lesson, we will express
her solutions’ concentration into different units; Molarity, Molality, Percent by
mass, Percent by volume, mole fraction and ppm.
Questions:
1.What is the molar concentration of Aki’s disinfectant if she dissolved 5Tbsp. of
NaClO (sodium hypochlorite) in 3.8 liters of H2O (water)?
2.Compute for the molality of her disinfectant if she dissolved 5Tbsp. of NaClO
(sodium hypochlorite) in 3.8 liters of H2O (water).
3. Calculate the percent by mass of sodium hypochorite in her disinfectant solution.
(
5Tbsp. of NaClO (sodium hypochlorite) and 3.8 liters of H2O (water). In units of grams for both of
the solute and solvent.

4.Calculate the mole fraction of sodium hypochorite and water in Aki’s solution.
( 5Tbsp. of NaClO (sodium hypochlorite) and 3.8 liters of H2O (water).
5. Calculate the percent by volume of the disinfectant Aki made. Units in mL.
6.What is the concentration of her solution in parts per million? ( 5Tbsp. of NaClO
(sodium hypochlorite) and 3.8 liters of H2O (water).
65
Reflection
1. I learned that _
_
2. I enjoyed most on
_
_ _
_.

_
_
_.
References:
Masterton, William and Cecille Hurley. Chemistry Principles and Reactions.

Solutions.Fifth Edition, Thomson Books/Cole,2004.
Hein,Morris et.al. Foundations of Chemistry in the Laboratory for Sciences.

Properties of Solutions. Twelfth Edition, John Wiley and Sons Inc.,2007.
Whitten, Kenneth et.al. General Chemistry. Solutions. Seventh Edition, Thomson

Books/Cole,2004.
Chang, Raymond. Chemistry. Concentration Units. Tenth Edition, McGraw-Hill,

2010.
Prepared by:
ANGELIKA TORRES
Sta Ana Fishery National High School
66
GENERAL CHEMISTRY 2

Date:
Score:
STOICHIOMETRIC CALCULATIONS FOR REACTIONS IN SOLUTION
Stoichiometry is the calculation of reactants and products in a certain

chemical reactions. It applies the law of conservation of mass wherein the total
mass of the reactants is always equal the total mass of the products, leading to the
insight that the relations among the value or amount of reactants and products
typically produce a ratio of positive numbers. This implies that if the amounts of the
separate reactants are known, then the amount of the product can be calculated and
vice versa.
This image here, shows that the chemical reaction is balanced.
Source: https://en.wikipedia.org/wiki/Stoichiometry#/media/File:Combustion_reaction_of_methane.jpg
It shows that one molecule of methane, CH4 reacts with two molecules of
oxygen gas, O2 to produce one molecule of carbon dioxide, CO2 and two molecules of water,
H2O. This chemical reaction is an example of complete combustion. Stoichiometry
measures these numerical relationships and is used to calculate the amount of

products and reactants that are produced or needed in a given reaction.
Describing the mathematical relationships of the substances that contributed in
chemical reactions is what we call reaction stoichiometry. It measures the
67
relationship between the amount of methane and oxygen that react to form carbon
dioxide and water.
Elements in the periodic table have a different atomic mass, and ascollections
of single atoms or molecules have a fixed molar mass, measured with the unit mole
(6.02 × 1023 individual molecules, Avogadro's constant). Carbon-12 has a molar
mass of 12 g/mol. Thus, to compute the stoichiometry by mass, the number of
molecules needed for each reactant is expressed in moles multiplied by the molar
mass of each to give the mass of each reactant per mole of reaction. The mass
ratios can be computed by dividing each by the total number in the whole reaction.
Stoichiometry is often used to balance chemical equations. For example, the
two diatomic gases, hydrogen and oxygen, when it combine H2 and O2, it produce a liquid,
water, in an exothermic reaction, as described by the following equation:
2 H2 + O2 →2 H2O
It shows the 2:1:2 ratio of hydrogen, oxygen, and water molecules in the
above equation.
The molar ratio permits for conversion between moles of one
substance and
moles of another. For example,
2 CH3OH +3 O2 →2 CO2 +4 H2O
the amount of water that formed by the combustion of 0.27 moles of CH3OH is
obtained using the molar ratio between CH3OH and H2O of 2 to 4.
Stoichiometry is also used for determining the molar proportions of elements

in
stoichiometric compounds. For example, the stoichiometry of hydrogen, H2 and
oxygen, O2 in H2O is 2:1. In stoichiometric compounds, the molar proportions should be whole
numbers.
Determining the Amount of Product

The term stoichiometry can be used to find the quantity of a product produced
by a reaction. If a piece of solid copper (Cu) were added to an aqueous solution
of silver nitrate (AgNO3), the silver (Ag) would be substituted in a single displacement reaction
forming aqueous copper(II) nitrate (Cu(NO3)2) and solid silver. How many silver, Ag
68 is
formed if 16.00 grams Cu is added to the solution of excess silver nitrate, AgNO3?
The following steps would be used:
1. Write and balance the chemical equation
2. Mass to moles conversion: Convert grams of Cu to moles of Cu
3. Mole ratio determination: Convert moles of Cu to moles of Ag produced
4. Mole to mass conversion: Convert moles of Ag to grams of Ag
produced The complete balanced equation would be:
Cu +2 AgNO3 → Cu(NO3)2 + 2 Ag
For the mass to mole conversion, the mass of copper (16.00 g) would be
converted to moles of copper by dividing the mass of copper to its molecular mass:
63.55 g/mol.
Now that the amount of Cu in moles (0.2518) is form, we can set up the mole
ratio. This is done by looking at the coefficients in the balanced equation: Cu and Ag
are in a 1:2 ratio.
Now that the moles of Ag produced is known to be 0.5036 mol, this amount
can be converted into grams of Ag produced to determine the final answer:
This set of calculations can be further shortened into a single

step:
Stoichiometric Calculations
The coefficients in the balanced equation give the ratio of moles of reactants
and products.
69
Source: https://www2.chemistry.msu.edu/courses/cem151/chap3lect_2009.pdf
From the mass of Substance A, you can use the ratio of the coefficients of A
and B to determine or calculate the mass of Substance B formed (if it’s a product) or
used (if it’s a reactant).
Example: 10 grams of glucose (C6H12O6) react in a combustion reaction. How many
grams of each product are produced?
C6H12O6(s) + 6 O2(g) 6 CO2(g) + 6 H2O(l)
10.g ? + ?
Starting with 10. g of C6H12O6, we calculate the moles of C6H12O6. Use the coefficients to
find the moles of H2O 10.g

& CO2 and then turn the moles to
? grams+ ?
MW: 180g/molC6H12O6(s) + 6 O2(g) 44 g/mol 18g/mol 6 CO2(g) + 6 H2O(l)
#mol: 10.g(1mol/180g)
0.055 mol 6(.055) 6(.055mol)
6(.055mol)44g/mol 6(.055mol)18g/mol
#grams: 15g 5.9 g
70
Reaction Stoichiometry in Solutions
We can perform stoichiometric calculations for aqueous phase reactions just
as we can for reactions in solid, liquid, or gas phases. Much of chemistry takes
place in solution. Stoichiometry allows us to work in solution by giving us the concept
of solution concentration, or molarity. Molarity is a unit that is often abbreviated as
capital M. It is defined as the moles of a substance contained in one liter of solution.
Almost always, we will use the concentrations of the solutions as conversion
factors in our calculations. For instance, if a solution has a concentration of 1.20 M
NaCl, this means that there are 1.20 moles of NaCl per liter of solution.
Example 1: What mass of Aluminum (Al) is needed to react completely with
35.0 mL of 2.0 M Hydrochloric acid?
Solution:
6 HCl + 2 Al 2 AlCl3 + 3 H2
35.0 mL HCl x 1L HCl x

2 mol HCl x
2 mol Al x 26.98 g Al 1000 mL
1L HCl
6 mol HCl 1 mol Al
Al = 0.63 g
1000 mL
148 g Na2CO
Example x 1mol
2. 3What Na2CO
volume 3 x of
(mL) 1 mol Ca(NO
0.75 3)2 x 1Lnitrate
M calcium Ca(NOwould
3) 2 x react completely with
1L
148g of carbonate?
105.99 g Na2CO3 1mol Na2CO3
Solution: 0.75mol Ca(NO3)2
CaCO3 = 1.900 mL
Ca(NO3)2 + Na2CO3 CaCO3 + 2 NaNO3
Perform stoichiometric calculations for reactions in solution (STEM_GC11PP-IIId-f-
112)
71
Activity 1: FILL THE EMPTY LINE
Directions: Read the following statement below and solve the problem. In the
equation that follows each problem, write on the space provided for the mole ratio
that can be used to solve the problem. Write the correct answer on the space
provided for.
The reaction of sodium peroxide and water produces sodium
hydroxide and oxygen gas. The following balanced chemical equation
represents the
reaction.
2 Na2O2(s) + 2 H2O(l) → 4NaOH(s) + O2(g)
1. How many moles of NaOH are produced when 1.00 mol sodium peroxide
reacts with water?
1mol Na2O2 x _ = mol NaOH
2. How many moles of oxygen gas are produced when 0.500 mol sodium
peroxide reacts with water?
0.5 mol Na2O2 x _ = _ mol O2
3. How many moles of sodium peroxide are needed to produce 1.00 mol
NaOH? 1 mol NaOH x = _ mol NaOH
4. How many moles of water are required to produce 2.15 mol oxygen gas?
2.15 mol O2 x = _ mol H2O
5. How many moles of water are needed for 0.100 mol of sodium peroxide to
react completely?
0.100mol Na2O2 x _ = _ mol H2O
Activity 2: SIMPLE STOICHIOMETRY
Directions: Solve the following stoichiometry grams – grams problems.
The combustion of a sample of butane, C4H10 (lighter fluid), produced 2.64 grams of
water.
2 C4H10 + 13O2 8CO2 + 10H2O
a. How many moles of water formed?
72
___
b.How many moles of butane burned?
_
c. How many grams of butane burned?

_
d. How much oxygen was used up in moles?

_
e. How much oxygen was used up in grams?

_
_
Activity 3: THINK ABOUT IT!
Directions: Solve the following simple stoichiometry problems.
1.123 mL of a 1.00 M solution of NaCl is mixed with 72.5 mL of a 2.71 M solution of
AgNO3. What is the mass of AgCl(s) formed in the precipitation reaction?
AgNO3(aq) + NaCl(aq) AgCl(s) +

NaNO3(aq)
2.What volume (mL) of 0.70 M Sodium hydroxide (NaOH) is needed to
neutralize 270 mL of 0.40 M Sulfuric acid (H2SO4)?
2 NaOH + H2SO4 Na2SO4 + 2 H2O
73
3. Hydrogen gas can be produced through the following reaction.
Mg(s) + 2HCl(aq) 
MgCl 2 (aq) +
H2(g)
a. How many grams of HCl are consumed by the reaction of 2.50 moles
of magnesium?
b. What is the mass in grams of H2 gas when 4.0 moles of HCl is added to the reaction?
4.Acetylene gas (C2H2) is produced as a result of the following reaction.

CaC 2 (s) + 2H2O(l)  C2H2(g) +
Ca(OH) 2 (aq)
a. If 3.20 moles of CaC2 are consumed in this reaction, how many grams of H2O are
needed?
b. How many grams of Ca(OH)2 would be formed with 3.20 moles of CaC2?
5.Laughing gas (nitrous oxide, N2O) is sometimes used as an anesthetic in dentistry. It is
produced when ammonium nitrate is decomposed according to the following

reaction.
NH4NO3(s) 
N2O(g) + 2H2O(l)
a. How many moles of NH4NO3 are required to produce 33.0g of N2O?

b. How many moles of water are produced with 45.0g of N2O?
74
Activity 4: GIVE ME MY VALUE
Directions: Complete the equation by writing the correct value on the space
provided for.
For questions 1 – 3, refer to the equation below
4 Fe + 3 O2 
2 Fe 2 O 3
1. How many moles of Fe2O3 are produced when 0.275 moles of Fe is reacted?
0.275 mol Fe
mol Fe2O3
2. How many moles of Fe2O3 are produced when 31.0 moles of O2 is reacted?
3. How many moles of O2 are needed to react with 8.9 moles of Fe?
For questions 4 – 6, refer to the equation below

2 KClO 3  2 KCl + 3 O2
4. How many moles of O2 will be formed from 1.65 moles of KClO3?
1.65 mol KClO3 mol O2

mol O2
mol KClO3
3.50moles
5. How many mol KCl
of KClO3 are needed to make 3.50 moles of KCl?
_ mol KClO3
75
Activity 5: GIVE ME THE SOLUTION
Directions: Solve the following problems based on the chemical reaction below
4 Fe + 3 O2  2
Fe 2 O 3
1. How many grams of Fe2O3 are produced when 42.7 grams of Fe is reacted?
2. How many grams of Fe2O3 are produced when 17.0 grams of O2 is reacted?
3. How many grams of O2 are needed to react with 125 grams of Fe?
76
Reflection:
1. I learned that _
_
_ _
3. I want to learn more on _

_
77
References:
Hill, Petrucci. General Chemistry: An integrated approach, second edition.
New Jersey: Prentice Hall, 1999.
https://courses.lumenlearning.com/introchem/chapter/solution-stoichiometry/
https://chem.libretexts.org/Bookshelves/Inorganic_Chemistry/Modules_and_Website
s_(Inorganic_Chemistry)/Chemical_Reactions/Reactions_in_Solution
https://www2.chemistry.msu.edu/courses/cem151/chap3lect_2009.pdf
http://www.calhoun.k12.al.us/teacherpages/teacherfiles/Stoichiometric
https://iasmisserica.weebly.com/uploads/4/2/6/4/42642303/escanear0094.pdf
http://www2.ucdsb.on.ca/tiss/stretton/CHEM1/stoicwk2.html
https://www.murrieta.k12.ca.us/cms/lib5/CA01000508/Centricity/ModuleInstance/868
1/Stoichiometry_-_mole_to_mass.doc
Prepared by:
SHAROLYN T. GALURA
Licerio Antiporda Sr National High School- Dalaya Annex
78
GENERAL CHEMISTRY 2

Date:
Score:
Effects of Concentration on the Colligative Properties of Solutions
Colligative properties of solutions are properties that depend upon the
concentration of solute molecules or ions, but not upon the identity of the solute.
Colligative properties include vapor pressure lowering, boiling point elevation, freezing
point depression, and osmotic pressure.
Lowering the Vapor Pressure
Vapor pressure is the pressure of a vapor in thermodynamic equilibrium with
ts condensed phase in a closed container. When non-volatile solute is dissolved
in solvent, the vapor pressure of solvent is lowered. The presence of solute
decreases the rate of escape of solvent molecules resulting to lower vapor pressure.
Boiling Point Elevation
The boiling point of a liquid is defined as the temperature at which the vapor
pressure of that liquid equals the atmospheric pressure (760mm Hg). The addition of
the solute increases the boiling point of the solution. The atmospheric pressure
remains the same while the vapor pressure of the solution is lowered resulting in the
increase of the difference in atmospheric pressure and vapor pressure of the
solution. Therefore, a higher temperature is required to boil the solution.
Freezing Point Depression
Normal freezing or melting point is the temperature at which solid and liquid
are in equilibrium under 1 atm. Addition of solute will decrease the vapor pressure
and so will decrease the freezing point. In order for a liquid to freeze it must achieve
a very ordered state that results in the formation of a crystal.
If there are impurities in the liquid, i.e. solutes, the liquid is inherently less
ordered. The presence of impurities in a liquid or in a substance makes variation in
the
79
freezing point by making them low or high. Therefore, a solution is more difficult to
freeze than the pure solvent so a lower temperature is required to freeze the liquid.
Osmotic Pressure
This is the external pressure that must be applied to the solution in order to
prevent it being diluted by the entry of solvent via osmosis. Diffusion in liquids,
substance tend to move or diffuse from regions of higher concentration to region of
lower concentration. The overall effect is to equalize concentration throughout the
medium.
Osmosis, on the other hand is the movement of solvent particles across a
semipermeable membrane from a dilute solution into concentrated solution. The
solvent moves to dilute the concentrated solution and equalize the concentration on
both sides of the membrane.
Osmotic pressure is directly proportional to the concentration of the solution.
Therefore, doubling the concentration will also double the osmotic pressure. The
osmotic pressure of two solutions having the same molal concentration are
identical.
Learning Competency
Describe the effect of concentration on the colligative properties of solutions
(STEM- GC11-PPIIId-f-115)
Activity 1: FACT OR BLUFF

Directions: Read each statement carefully. Identify whether the statement isa FACT
or BLUFF. Draw  on the space if it is a FACT and  if it is a BLUFF.
1. Colligative properties arise from the fact that solute affects the concentration
of solvent. _
2. Vapor pressure is a colligative property.
3. Lowering of vapor pressure is not dependent on the number of species
present in the solution.
4. Colligative properties of solution depend on the nature of the solute and
the solvent.
5. Colligative molality is the molality times the number of solute particles
per formula unit. _
80
6. Osmotic pressure is directly proportional to the concentration of the solution.
_
7. Relative lowering of vapor pressure is a colligative property. _
8. The boiling point of a solution decreases in direct proportion to the molality
of the solute._
9. When non-volatile solute is dissolved in solvent, the vapor pressure of
solvent is lowered.
10. The depression of the freezing point is directly proportional to the molality of
the solvent. _
Activity 2: 1 PIC, 4 SENTENCES

Directions: The pictures below illustrate the different effects of colligative properties
to solutions. Using four (4) sentences, answer the question that each picture depicts.
Write your answer on the spaces provided.
1. Why adding salt to water increases the boiling point?
_
Source: https:/
/www.thoughtco.com/thmb/Wlx0HpISUQfVc401y0XNpBdcms
=/768x0/filters:no_upscale():max_bytes(150000):strip_icc():for
mat( webp)/GettyImages-1166175911-
_
_
81
2. Why does seawater have lower freezing point than pure water?
_
https://www.google.com.ph/url?sa=i&url=https%3A%2F%2Ftwitter.co
m%2 Fmpi_meteo%2Fstatus
%2F1074242734129434624&psig=AOvVaw0l K2WkzZ
5BHXZeNI34w3fI&ust=1596870848098000&source=images&cd=vfe
&ved=0 CAIQjRxqFwoTCIDOpu7EiOsCFQAAAAAdAAAAABAD _
_
3.
_
_ _
_
_
_ _
_
_
_ _
_
https://www.google.com/search?sxsrf=ALeKk03ZiIKudLOeyQ1ocit_OtM
P6JIKQw:1596790694111Eq
4. Which sample has the lowest vapor pressure? Why?
_ _
_ _ _
_ _
_ _
_ _
82
5. How can you regain the crispyness of a carrot and celery that have become
limp? What colligative property is involved in the process?
_
_
_
_
_
_
_
_
_
https://opentextbc.ca/chemistry/chapter/11-4colligative-properties
83
Activity 3: WHO WANTS TO BE A CHEMIST?
Directions: To become a chemist and receive a score, you need to answer the
question in each level. Your score increases as you go to a higher level.
Compare the properties of 1.0 M aqueous

LEVEL 5 sugar solution to a 0.5 M aqueous
solution of NaCl.
Why is vapor pressure lowering a

LEVEL 4
colligative property?
LEVEL 3 What is needed for a liquid to freeze?
What do colligative properties of solutions

LEVEL 2 depend on?
What are the different colligative

properties of solution?
LEVEL 1
84
Reflection:
1. I learned that _
_
_
_.
3.
I
w
a
nt
to
le
ar
n
m
or
e
o
n
_
_
_.
85
References
Books
Santos, Gil Nonato S., Danac, Alfonso C., O-Chemistry III,
2009 Mortimer Charles E., Chemistry 6th Edition
Hagad, Hilda R., Phoenix Next Century Chemistry, 2003
Websites
https://chem.libretexts.org
https://opentextbc.ca
https://www.sparknotes.com
https://www.bhsu.edu
Prepared by:
LOVEJOICE L. AMBABAG
Tuao Vocational and Technical School
86

General Chemistry Grade 12 Module

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General Chemistry Grade 12 Module

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12

NOTE: Practice personal hygiene protocols at all times

Explain the properties of water with its

Describe the difference in structure of

Perform stoichiometric calculations for

Calculate boiling point elevation and

NOTE: Practice personal hygiene protocols at all times ii

NOTE: Practice personal hygiene protocols at all iii

Name: _ Grade Level:

The structure of metallic crystals is often described .

molecules), such as H2, N2, O2, and F2, have weak

attractive forces and form molecular solids with very

forms a molecular solid that melts at 114 °C.

NATURE True Solids. Pseudo – Solids or super-

Isotropism Anisotropic in nature. i.e.,  Isotropic in nature.

Cleavage When cutting with a sharp  When cutting with a

Activity 1: CRYSTALLINE SOLID

_1. CaCl2 6. CH3CH2CH2CH3

_2. SiC 7. HCl

b. A student obtained a solid product in a laboratory synthesis. To verify the

A crystalline solid is made up of an orderly repeating pattern of

What you need

 Clean ‘golden’ beach sand

Student worksheet – Studying crystal systems

4. Compare the sketches you have drawn to the crystal systems

Materials: template of cubic, triclinic and rhombohedral crystal system

Cubic crystal template

All axes are of variable lengths. All axes are at variable

Activity 5: CRYSTALLINE AND AMORPHOUS SOLID (Pre-lab)

structure and composition.

_1. In amorphous solid, the atoms or molecules are held together in a

3. I want to learn more on

Name: _ Grade Level:

LEARNING ACTIVITY SHEET

Background Information for the Learners

A typical phase diagram consists of discrete regions that represent the

The Phase Diagram of Water

In Figure 12.4.2b point A is located at P = 1 atm and T = −1.0°C, within the

Referring to the phase diagram of water in Figure 12.4.2:

In contrast to the phase diagram of water, the phase diagram of

maintaining a temperature of −78.5°C, the normal sublimation temperature. Solid

As the phase diagrams above demonstrate, a combination of high pressure

intermolecular attractive forces to hold them together in a separate liquid

Activity 1: WATER AND CARBON DIOXIDE

following temperatures and pressures. Write your answer on the space

_1. -10 °C and 50 kPa

6. −30 °C and 2000 kPa

_7. −60 °C and 1000 kPa

_8. −60 °C and 100 kPa

_9. 20 °C and 1500 kPa

_10. 0 °C and 100 kPa

Activity 2: CRITICAL THINKING (H2O and CO2)

A phase diagram of water is shown below

2. What names are given to the points A and

Phase diagram of carbon dioxide

of CO2 co-exits in equilibrium?

3. What are the critical temperature and pressure for CO2? _.

3. I want to learn more on _

LEARNING ACTIVITY SHEET

HEATING AND COOLING CURVES

In the heating curve of water, the temperature is shown as heat is continually

The change of state behavior of all substances can be represented with a

Heating curves show how the temperature changes as a substance is heated

Since Temperature is a measure of "Average Kinetic Energy", any change in