• It is useful in illustrating the relationship among the pressure,
volume, temperature and number of moles of a gas.
• This equation is used to describe gases that behave ideally.
V = RnT / P or PV = nRT
• Where V = volume in L, P = pressure in atm, n = moles, T =
temperature in K and R = universal gas constant (0.0821 L.atm/mole.K) 1. What is the volume of a container that can hold 0.50 mole of gas at 25.0oC and 1.25 atm? Given: n = 0.50 mole T = 298.15 K P = 1.25 atm R = 0.0821 L.atm/mole.K RTF: volume Formula: V = nRT / P Solution: V = (0.50 mole)(0.0821 L.atm/mole.K)(298.15 K) / 1.25atm = 9.791246 L Final Answer: V = 9.8 L 2. Calculate the pressure exerted by a 0.25 mole sulfur hexafluoride in a steel vessel having a capacity of 1 250 mL at 70oC. Given: n = 0.25 mole T = 343.15 K R = 0.0821 L.atm/mole.K V = 1.25 L RTF: pressure Formula: P = nRT / V Solution: P = (0.25 mole)(0.0821 L.atm/mole.K)(343.15 K) / 1.25L = 5.634523 atm
Final Answer: V = 5.6 atm
3. Fermentation of glucose produce gas in the form of carbon dioxide, how many moles of carbon dioxide is produced if 0.78 L of carbon dioxide at 20.1oC and 1.00 atm was collected during the process? Given: P = 1.00 atm T = 293.25 K R = 0.0821 L.atm/mole.K V = 0.78 L RTF: amount of substance Formula: n = PV / RT Solution: n = (1.00 atm)(0.78 L)/(0.0821 L.atm/mole.K)(293.25 K) = 0.78 / 24.075825 = 0.0323976437 Final Answer: n = 0.032 mole 4. A sample of liquid acetone is placed in a 25.0 mL flask and vaporized by the heating to 75oC at 1.02 atm. Calculate the number of moles of the acetone. Given: P = 1.02 atm T = 348.15 K R = 0.0821 L.atm/mole.K V = 0.025 L RTF: amount of substance Formula: n = PV / RT Solution: n = (1.02 atm)(0.025 L)/(0.0821 L.atm/mole.K)(348.15 K) = 0.0255 / 28.583115 = 0.0008921351 Final Answer: n = 0.00089 mole or 8.9 x 10-4 mole 5. Calculate the pressure exerted by 0.300 mole of gas contained in an 8.00 L vessel at 18oC. Given: n = 0.300 mole T = 291.15 K R = 0.0821 L.atm/mole.K V = 8.00 L RTF: pressure Formula: P = nRT / V Solution: P = (0.300 mole)(0.0821 L.atm/mole.K)(291.15 K) / 8.00L = 0.8963780 atm Final Answer: n = 0.896 atm