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Design & Simulation (Assign 4)

Design & Simulation (Assign 4)

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Published by Saad Ahmed
Design & Simulation
Design & Simulation

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Published by: Saad Ahmed on Jul 18, 2013
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07/18/2013

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University Of Karachi
DESIGN AND SIMULATION
 
(Assignment 4)
Syed Saad Ahmed Roll no: 37 Seat no.: B-0933040 Enrolment no.: Sci/cht/ku-29754/2009B.E 4
th
Year Chemical EngineeringSubmitted To:Sir Zeeshan Zaki Sir Owais Iqbal 
 
 
 
Prepared By: SYED SAAD AHMED (B.E Final Year)
 
2
DESIGN AND SIMULATION 
Assignment #4
UNIQUAC Portion
Q: Calculate the activity coefficients of a mixture of 40 mol% Ethanol 60 mol% Ethane at 2 bargand 62°C.
Solution: 
Activity Coefficient 
 
Combinatorial Activity Coefficient 
Estimation for a known component
 
ETHANE
 = 2 x CH
3
Groups
 
So its calculated values are
 –
 
i
value from table = 2 x 0.9011 = 1.8022
 –
 
q
i
value from table = 2 x 0.848 = 1.696
 
ETHANOL
 = 1 x CH
3
+ 1 x CH
2
+1 x OH Groups
 
So its calculated values are
 –
 
i
value from table = 1 x 0.9011 + 1 x 0.6744 + 1 x 1.0 = 2.5755
 –
 
q
i
value from table = 1 x 0.848 + 1 x 0.540 + 1 x 1.2 = 2.588
 
 
Prepared By: SYED SAAD AHMED (B.E Final Year)
 
3
DESIGN AND SIMULATION 
 
ETHANE
 

 
 
 
 
ETHANOL
 



 
 
 
Components

 

 liEthane
1.6958 1.8020 0.6 1.0175 1.0812 0.5120 0.4956 -0.271
Ethanol
2.588 2.5755 0.4 1.0352 1.0302 0.4879 0.5043 -1.638
Sum2.0527
 
2.1114
 
Combination activity coefficient (ln
c
)
 
ETHANE
 
 ()      ()() 
 
 

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