sO GD&DTPH1J YEN

Kl THICHQN

HQC SINH GI(:n cAp TINH LOP 12 THPT NAM HQC 2009-2010.

THC1JGIAN: 180 PHUT (khong

kd thili gian philt

.

(jJ)

thi sinh:

BD:

(2,5 di~m) .. a. Nguyen tu ella nguyen t6 X co di~n h:;ttnhan bfu1g+41,652.10cJ9C; nguyen cua n,guyent6 Y co kh6i lUQ'ngb~ng 1,794.1 0-22gam. Xae dinh X, Y va d1,ra.trencAu hinb electron, hay cho bi~t gi:ii thfeh) muc hoa bell11h~t eua X va Y trong hqp cht? b. Chq bi~t tf?ng thai r.So sanh va giai thich v~n t~t nbi~t dQsoicua:pentan_C_a_u_2.(2,5 di~m) B6 tuc dic fu1 cMit, vi~t cae (m6i mUi ten chi vi6t 01 phUOTIg trinh
C2HsOH ~
(I)

va
dS hoan thanh sa d6 sau

C4Ho--> A-.. B

(2)

(3)

i'i
F~
... ~.

L--11>- M--11>-

(12)(P)

R~

(18)

+CHz

__

(2,0 di~m) 14,224gam iot 112gaIll bilfh l(lIl dllng tich 1,12lit (}nhi~t dQ400C. T6c dQ ban d~u cua phan (rug Ia IIlQt~qi gia11"athai di~m t) p6ng dQ cua ( la 0,04moI/Ht va khi phim img H2(k) + h(k) can bang thi nong dQ cua HI bang O,06mollIit. a. Tiuh h~ng s6 t6e dQ clm phim ling thu~n va phan U'ngnghieh. b. T6e dQt:;tothanhHI a thai diSm tJabao.nhieu?

__~ 4. (2,0 di~m) C__ a

Nhi9t phan 104gam hQ'p X g6m A(N03)2 va B(N03)2 (A la kim lo?i kiem th6, B Ia kim lo?i ehuy~n ti~p) eho t&ikhi die phantmg XaYra gqantpan, thudu'Q'ech~t r~n y chI g6m .nhungoxit, .h6n hqp khf Z g6m N02 va O2 co tieh31 ,36lft.(do a OOC;latm) v&idz/co, Xae dinh cac kim lo:;tiA, B (bi6t s6 mol CllaB(N03)2 nhieu hO'ns6 mol cua A(N03)2).
______ (3,0 diSm) Ca u 5.

D6t chay hofm toan 3,24gam mQt clohidrocacbon X (m<;lchcacbon khong phan nbanh) bing lUQ'ilgoxi du va cho tt ca sim phftm chay (C02, HCl va hO'iH20) vao binh kin chlra 60cm3 dung dich NaOH 20% (kh6i Iuc;mgrieng d = 1,22gam/cm3). Sau khi eac san ph~m chay duQ'c h~p hoan toan vao dung dich NaOH, t~o thanh dung dich Y va xac dinh duQ'ckh6i luc;mgdung dich tang len 7,73gaI11. Dung dich Y duQ'c pha loang bing nuoe cAt thanh 250em3, eli 20em3 dung dich nay tac dl,mg vlra du veri 24,828cl1l3 dung dich HCIl,O 15M. a. Xac dinh cong thuc phan t11cua X. b. Vi~t t~t ca cong thuc c~u t?O cae ch~t d6ng phan eua X, gQi ten theo danh phap thay th~.
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____ 6. (2,0 di~rn) ~a Au__ 3. Cho biSt d<,1ngl5TIg h daY.Giai thich vik tit co sa cho sv IvachQn do. a. Lysin HzN[CH2HCH(NH:~)COOH ~. Axit aspatic HOOC-CHz-CH(NHz)-COOH 1. Arginin HzN-C(=NH)-NH[CI-IzhCl-I(NHz)~COOH O.Tyrozin p-HO-C6H4-CHz-CH(NHD"'COOH b. Cho bang cac gia tri h&ng s6di~n diSm d~ng,di~n>c1Ja m9t s6 cac amino axit duai day. ChQn de tach cac ch~t tir m9t h6n hQ'Pgbm threonin, axit aspatic va tyrozin bfulg phuong phap di~n Giai thich S1} h,rachQn do?--_.~ ~ ...pI pKj Amino3xit pKl pKl
-,

Threonin, H3C-CH( OH)-CH(NHz)-COOH

2,09 1,99 2,20

9,10 3,90 9,11

'-

5,60
-

--. ,.,,Tyrozin, p-HO-C6H4-CHz- CH(NHz)-COOH

~ __ ~ __ . (3,0 ag__ 7
---

Axit aspatic, HOOC-CHz-CH(NH2)-COOH

-----~-

10,00 10,07

3,90 10,07

diella) H6n hQ'PX gbm mQt 10<,1i Rvamu6i cacbonat !uqt tuang lmg,la 2:1). Hoa tan hoan toan ?8,4gam h6n hQ'PX trong dung dich " du, thfiy thoat ra hon hQ'Pkhi Y gorn NO (san ph~m khu duy nhfit) va COz. H6n khi Y lam mfitmau vua du 420ml dung dich KMn04 1,OMtrong l-hS04{du)Iqang; khi con l:,1i(sau khi Yqu~d~ng dichKMn04) cho qua dung dich Ca(OH)z du th~y xu~t hi~n m garn kSt tua, dbng thai kh6i 1ugng dung dich giam 16,8gam. 3. Vi~t cac phuong phan ung xay ra duai d<,1ngonthugQn. i theo kh6i lugng m6i ch~t b. Xacdinhcong tl1uc mU6i, cacbonat cua va tinhthanh phlin phlin trong h6n hQ'~ X.' __ 8. (3,0 diSm) ~ __ au Hai hQ'Pchfit hUll co da chuc A va B d~u co cong thuc phan tu CSH604 va Ia dbng phan l?p thS cua nhau. Ca A, B d~u khong co Hnh quanw 49:,1t, co nhi~LdQ soi th~p hon B. A, B (l~u tac dvng vai NaHC03 giaj phong khi COz.f;hLhidro hoa A hay B b&ng Hz vai xuc tac Ni dugc h6n hQ'PX, gbm cac ch~t co cong thuc CSHS04. Co thb tach X th;1nl1haid~l1g 0;6iquang cuarillau. lu~n xac dinh c~u t<,10, hinh cua A va B. cfiu cua hai d<,1ng quang Ctla X. d6i th(rc Fisher, gQi c~u ViStcd chS phan (mg, viSt cong th(rc B lli111ugt tac Fisher, gQi san phftn1 t1;lO thanh.

dU'9'cphep d1.Jng13dl1gtudnhoiinVdina)ltinhcdmtay (theo danh mljC may tinhB(J GD&DT cho phep dljngtrong cacki thi qu6c gia).

HQ va ten Giam thi 1:

; Chuky:

HQ va ten Giam th1 2: .

..... ; ChftkY:

.. . ~

... " . "

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