Code: 13100

NR

Set 1

JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY HYDERABAD II.B.TECH - I SEMESTER SUPPLEMENTARY EXAMINATIONS NOVEMBER, 2009 ORGANIC CHEMISTRY Time: 3hours Max.Marks:80 Answer any FIVE questions All questions carry equal marks --1. a) How many types of polar effects are exhibited by organic compounds? Explain. b) Discuss the effect of resonance and inductive effect on the following properties. i) Strengths of acids and bases. ii) Reactivity of organic compounds. [8+8] 2. By giving the reaction mechanisms explain the following reactions along with their applications. a) Elemen sons reduction b) Benzoin condensation. 3. Explain the following reaction by giving the name of the reaction, mechanism and applications. a) C6 H 5OH + CHcl3 + NaoH
alcoholicNH 3 b) C6 H 5CHO + CH 2 (COOH ) 2 puridine

[8+8]

[8+8]

4. a) Explain sequence rule and its significance. b) Assign R and S configurations to the following enantiomers. i) Glyceraldehydes ii) Lactic acid iii) 1-Bromo 2-Phenyl 3- hydroxyl butane. 5. a) What are geometrical isomers? Explain their nomenclature. b) Assign E-2 configurations to the following. i) C6 H 5CH = CHBr ii) CH 2 = CBr C (CH 3 ) = CHcl iii) BreH = C (cl ) I 6. Write short notes on the following. a) Mutarotation b) Glycosides

[6+10]

[6+10]

c) Wohls degradation

d) Kiliani synthesis. [4+4+4+4]

7. Explain the following reactions with mechanisms involved. a) Reaction of Pyridine with sodamide in liquid ammonia. b) Reaction of quinoline with fuming intricacies and sulphuric acid c) Reaction of pyrrole with maleic anhydride. d) Reaction of furan with Raney nickel in presence of H2 gas 8. Explain the synthetic methods, properties and applications of any two azodyes. *********

[8+8] [16]

Code: 13100

NR

Set 2

JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY HYDERABAD II.B.TECH - I SEMESTER SUPPLEMENTARY EXAMINATIONS NOVEMBER, 2009 ORGANIC CHEMISTRY Time: 3hours Max.Marks:80 Answer any FIVE questions All questions carry equal marks --1. Explain the following reaction by giving the name of the reaction, mechanism and applications. a) C6 H 5OH + CHcl3 + NaoH
alcoholicNH 3 b) C6 H 5CHO + CH 2 (COOH ) 2 puridine

[8+8]

2. a) Explain sequence rule and its significance. b) Assign R and S configurations to the following enantiomers. i) Glyceraldehydes ii) Lactic acid iii) 1-Bromo 2-Phenyl 3- hydroxyl butane. 3. a) What are geometrical isomers? Explain their nomenclature. b) Assign E-2 configurations to the following. i) C6 H 5CH = CHBr ii) CH 2 = CBr C (CH 3 ) = CHcl iii) BreH = C (cl ) I 4. Write short notes on the following. a) Mutarotation b) Glycosides

[6+10]

[6+10]

c) Wohls degradation

d) Kiliani synthesis. [4+4+4+4]

5. Explain the following reactions with mechanisms involved. a) Reaction of Pyridine with sodamide in liquid ammonia. b) Reaction of quinoline with fuming intricacies and sulphuric acid c) Reaction of pyrrole with maleic anhydride. d) Reaction of furan with Raney nickel in presence of H2 gas 6. Explain the synthetic methods, properties and applications of any two azodyes. 7. a) How many types of polar effects are exhibited by organic compounds? Explain. b) Discuss the effect of resonance and inductive effect on the following properties. i) Strengths of acids and bases. ii) Reactivity of organic compounds. 8. By giving the reaction mechanisms explain the following reactions along with their applications. a) Elemen sons reduction b) Benzoin condensation. *********

[8+8] [16]

[8+8]

[8+8]

Code: 13100

NR

Set 3

JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY HYDERABAD II.B.TECH - I SEMESTER SUPPLEMENTARY EXAMINATIONS NOVEMBER, 2009 ORGANIC CHEMISTRY Time: 3hours Max.Marks:80 Answer any FIVE questions All questions carry equal marks --1. a) What are geometrical isomers? Explain their nomenclature. b) Assign E-2 configurations to the following. i) C6 H 5CH = CHBr ii) CH 2 = CBr C (CH 3 ) = CHcl iii) BreH = C (cl ) I [6+10] 2. Write short notes on the following. a) Mutarotation b) Glycosides

c) Wohls degradation

d) Kiliani synthesis. [4+4+4+4]

3. Explain the following reactions with mechanisms involved. a) Reaction of Pyridine with sodamide in liquid ammonia. b) Reaction of quinoline with fuming intricacies and sulphuric acid c) Reaction of pyrrole with maleic anhydride. d) Reaction of furan with Raney nickel in presence of H2 gas 4. Explain the synthetic methods, properties and applications of any two azodyes. 5. a) How many types of polar effects are exhibited by organic compounds? Explain. b) Discuss the effect of resonance and inductive effect on the following properties. i) Strengths of acids and bases. ii) Reactivity of organic compounds. 6. By giving the reaction mechanisms explain the following reactions along with their applications. a) Elemen sons reduction b) Benzoin condensation. 7. Explain the following reaction by giving the name of the reaction, mechanism and applications. a) C6 H 5OH + CHcl3 + NaoH
alcoholicNH 3 b) C6 H 5CHO + CH 2 (COOH ) 2 puridine

[8+8] [16]

[8+8]

[8+8]

[8+8]

8. a) Explain sequence rule and its significance. b) Assign R and S configurations to the following enantiomers. i) Glyceraldehydes ii) Lactic acid iii) 1-Bromo 2-Phenyl 3- hydroxyl butane. *********

[6+10]

Code: 13100

NR

Set 4

JAWAHARLAL NEHRU TECHNOLOGICAL UNIVERSITY HYDERABAD II.B.TECH - I SEMESTER SUPPLEMENTARY EXAMINATIONS NOVEMBER, 2009 ORGANIC CHEMISTRY Time: 3hours Max.Marks:80 Answer any FIVE questions All questions carry equal marks --1. Explain the following reactions with mechanisms involved. a) Reaction of Pyridine with sodamide in liquid ammonia. b) Reaction of quinoline with fuming intricacies and sulphuric acid c) Reaction of pyrrole with maleic anhydride. d) Reaction of furan with Raney nickel in presence of H2 gas [8+8] 2. Explain the synthetic methods, properties and applications of any two azodyes. 3. a) How many types of polar effects are exhibited by organic compounds? Explain. b) Discuss the effect of resonance and inductive effect on the following properties. i) Strengths of acids and bases. ii) Reactivity of organic compounds. 4. By giving the reaction mechanisms explain the following reactions along with their applications. a) Elemen sons reduction b) Benzoin condensation. 5. Explain the following reaction by giving the name of the reaction, mechanism and applications. a) C6 H 5OH + CHcl3 + NaoH
alcoholicNH 3 b) C6 H 5CHO + CH 2 (COOH ) 2 puridine

[16]

[8+8]

[8+8]

[8+8]

6. a) Explain sequence rule and its significance. b) Assign R and S configurations to the following enantiomers. i) Glyceraldehydes ii) Lactic acid iii) 1-Bromo 2-Phenyl 3- hydroxyl butane. 7. a) What are geometrical isomers? Explain their nomenclature. b) Assign E-2 configurations to the following. i) C6 H 5CH = CHBr ii) CH 2 = CBr C (CH 3 ) = CHcl iii) BreH = C (cl ) I 8. Write short notes on the following. a) Mutarotation b) Glycosides

[6+10]

[6+10]

c) Wohls degradation *********

d) Kiliani synthesis. [4+4+4+4]