Data for Standard Sample :

Composition of standard sample :

Hydrogen 20.07%
Methane 9.99%
Nitrogen 69.94%
Observation Table :
Component Retention Height

Area

Height % Area %

Pk Ty

Time

Peak
Width

Hydrogen

0.35

13284

2327923

77.1339

65.3733

BB

0.123

Nitrogen

0.96

248

29444

1.440

0.8269

BB

0.076

Methane

2.45

3690

1203601

21.4261

33.7998

BB

0.208

2e+04

3560968

100

100

Area

Height % Area %

Pk Ty

Peak

Observation table :
Sample
Component Retention Height
Time

Width

Hydrogen

0.34

12770

2107523

77.5302

65.9693

BB

0.112

Nitrogen

0.93

274

33563

1.6635

1.0506

BB

0.076

Methane

2.35

3427

1053619

20.8063

32.9802

BB

0.199

2e+04

3194705

100

100

Calculation :
Using Hydrogen as basis for calculation :
Areai/Areas = (molesi/moless)*(TRi/TRS)
(i denotes the component in consideration and s denotes the base component, here hydrogen)

TR Thermal response factor

Component

Hydrogen

Nitrogen

Methane

Moles

20.07

69.94

9.99

Molei/Moles

3.4848

0.4977

Area

2327923

29444

1203601

Areai/Areas

0.0126

0.5170

TRs/TRi

275.5

0.9627

Unknown Mixture :
Component

Hydrogen

Nitrogen

Methane

Area

2107523

33563

1053619

Areai/Areas

0.0159

0.4999

TRs/TRi

275.5

0.9627

Molei/Moles

4.3804

0.4812

molei/moles = 1+4.3804+0.4812 = 5.8616

% mole = (molei/moles)/ molei/moles
Wt.fraction = (mol.wti*mol.fractioni)/ (mol.wti*mol.fractioni)

Component

Hydrogen

Methane

Nitrogen

Mole

(1.00/5.8616) =

(0.4812/5.8616) =

(4.3804/5.8616)

fraction

0.1706

0.08209

=0.7473

Mol.wt

16

28

Wt.fraction

0.01511

0.5817

0.9267

Result :
% mole H2 = (1/5.8616)*100 = 17.06
%mole CH4 = (0.4812/5.8616)*100 = 8.209
%mole N2 =(4.3804/5.8616)*100 = 74.73
% by wt. H2 = 1.511
% by wt.CH4 = 5.817
% by wt.N2 = 92.67