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log K
AHO
(kcallrAol)
H'+F=HP
log K
(kcall&ol)
3.18
3.18
+ F = AIFY*
AI"
1.06
7.0
3.76
AI"
+ 2 F = AIF,'
1.98
12.7
NB*+ F = N a P
---.
-0.24
AI"
+ 3 F = AIF;
2.16
16.8
+ F= C S
Mg" + F = MgP
4.12
0.94
AI"
+ 4 F = AIF,'
2.20
19.4
3.2
1.82
AI"
+ 5~
= AIF,"
1.04
20.6
----
0.84
AP+ 6 F = AIF,"
-1.67
20.6
---
1.O
2.7
6.2
-16.26
30.18
H'
+ 2 F = HF,'
Table lb. Summary of revised thermodynamic data. 11: Oxide and hydroxide species.
AHO
Reaction
4.55
Ca"
Mn"
Fe"
+ F = MnF
+ F = FeF
Fe" t F = FeF2'
Fe"
+ 2 F = FeF,'
4.8
Si(OH),
+ 4H' + 6 F
= SiF,"
10.8
5.4
14.0
----
0.14
Mn"
+ CI' = MnCI'
----
0.61
5.6
1.48
Mn"
+ 3CI' = MnCI,'
----
-0.3 1
+ 3CI' = FeCI;
----
1.13
FeL+3F=FeF;
Mineral
Fe"
AH o
Reaction
log K
o<cal/&ol)
Cryoliie
Na,AlF, = 3Na'
Fluoriie
CaF, = Ca1'
Rcdox Potentials
+ Al" + 6 F
t 2F
AH O
otcall&ol)
Fe" = Fe"
+ e'
E"
(volis)
9.09
-33.84
4.69
-10.6
log K
9.68
-0.770
-13.02
25.8
-1.51
-25.51
13.362 -14.000
0.0
K'
+ H,O = K O P + H'
Ca"
H'
-13.64
10.4
-2.19
17.1
-5.67
0.0
-14.18
-----
-14.46
---
-1 1.44
-----
-13.29
-13.47
-12.78
Fe"
-12.56
Fe"
-21.6
-13.49
Alh
39.89
-16.9
-9.5
Al"
+ 4H,O = AI(0H);
42.30
-22.7
14.4
-10.59
4H'
AH o
(lLcal/rAol)
Pnilandiie
Ca(OH),
B~cite
-27.1
16.84
Pyrolusirc
Hausmaniie
-65.11
-100.64
41.38
61.03
Manganite
MnOOH
Pyochroiie
Gibbsiie (crysialline)
AI(OH),
Ferrihydriie(morphous io
minocrysLalline)
-31O
.
+ 3H'
+ 3H20
AI(OH), + 3H' = Alh + 3H,O
= Al"
+ 3H10
22.8
----
25.34
.-.-
15.2
-22.8
8.1 1
(-24.5)
9.35
--.-
+ OH.
3.0
10 5.0
+ 14.327 log T
AI"
Al"
Al"
log K
Rcaction
AI"
-5.00
-10.1
---
Reaction
Gibbsile(micronysial1ine)
-2.95
-6.3
13.2
Mineral
H P = H'
CS, = Caz' t 2 F
AH: log K
o<cal/mol)
Reaction
Li'
Fe"
+ 4H10
Ay0 log K
(kcdlmol)
Reaction
- 27.121 log T
Ca"
CO,(g) = CO,(aq)
CO,(aq) + t4,O = H'
+ HCO;'
Sr"
+ HCO,'
Ba"
Fe"
= MgHCO;
+ HCO,'
+
= hlnHC0;
Mineral
3.545
3.224
2.713
2.98
Si(0H): = SiO,(OHhh
5.22
2.81
3.55
2.71
4.90
Kiolinile
AI,Si,O,(OH),
Na'
+ CO,"
= NaCO,'
8.91
1.27
Ctuysotile
Mg,Si,O,(OH),
Ni'
Sqiolite
Mg,Si,0,,(OH).3HlO
-0.25
1.07
CaCO, = Ca1'
Dolomite(0rdered)
CaMg(C0,h
+ CO,*
= Ci'' + Mg"
Dolomite(bisordered)
CaMg(C0,h = Ca"
Slrontianiie
S m , = Sr" + CO,"
Sideriie(crystalline)
FeCO, = Fe"
Sideriie(precipitaied)
FeC0, = Fe"
Wiiherile
aCO, = Ba1'
Rliodoaosife(crysia1Line)
MnCO,
Rhodonosiie(syntlietic)
MiiCO, = Mn"
Reaciion
log K
HCO; = H'
Mg"
+ CO,"
+ HCO;
+ Mg" + ZCO,"
+ CO,"
+ CO,"
+ CO,"
= SrHCO,'
logK'
lngK,'=
= 1209.120 + 0.31294T
+ HCO;
+ CO,"
= CaCO,'
logbm]
Mg"
+ CO,"
= MgCOP
1 0 g . K ~ ~=; 0.9910
= aHCO,'
logKhIm'
logK-:
logK,P
CaCO, = Ca"
+ CO,"
log&
CaCO, = Ca"
+ CO,"
logK,
-3.248
Ba"
RaCO, = Ba"
= -59.215
Ca1'
+ 0.00667T
+ 0.012826T
= 0.1 13 + 0.008721T
= -1.019
logKmomm
= -171.9065
= -171.9773 - 0.07'7993T
logKWlmm = 607.642
2Si(OH)P + H,O
+ 2Si(OH);
+ 4H' + 0.5
H,O = 2
+ 6H' t 3H,O
Kerolite
Mg,Si,O,(OHh.H,O
Quaru
SiO,
Chalcedony
SiO,
+ 2H,O = Si(Otl)?
-35.3
46.8
t H,O
+ ~3~i(0ll)P
"
7.435
32.20
-10.7
15.76
-..
25.79
5.99
-3.98
= 3Mg2' + 4Si(OH):
2H,O = Si(0H)P
+ CO,"
= Mn" + CO,"
logKarn'
= 3Mg"
ZCO,"
+ HCO; = MgHCO;
Sr"
= 2AI"
+ 6H'
log K
CO,@) = CO&)
CO,(aq) + H,O =
H' + HCO;
+ 6H'
2.5
o<cal/Aol)
CaCO, = Ca2' + CO,"
AH:
(kcalhol)
4.38
---
-23.0
Reaction
..-
HCO,' = NaIlCO,'
-9.83
17.6
---
= MnCO;
AH
Aragonite
6.12
+ 2H'
= FeCO,'
+ CO,"
Reaction
Calcile
Mineral
log K
(kcailmol)
+ CO:
tlCO; = FeHCO;
Ayo
Reaction
Fe"
Mn"
+ HCO; = SrHCO,'
+ HCO,' = aHCO;
Mn1'
= CaCO,'
+ CO: = MgC0,O
Sr" + CO,' = SKO,'
Ba2. + CO,&= BaCO;
+ CO,"
HCO; = H'
+ CO,'
Mg"
AH: log K
(kcal/mol)
Reaction
log T
Reaction
Mg,Si,O,(OH), + 6H' =
3Mg" + 2Si(Otl)P + H,O
logK,
logKWARrz= 0.41
2H10 = Si(0ll)P
SiO,
SiO,
+ 2H,O = Si(0H)P
13Wfl
= -0.09 /- 1032/T
logKa
g
~ = -0.26
~
~731fl
~
490 Geoclreniistry,gro~itid~~nter
andpollrrrion
Table 2a. Trace elements: Arsenic.
AH,' log K
O<cal/mol)
Reaction
+ SO,* = HSO;
H'
Mn"
+ SO," = NaSO,'
Na'
+ SO,"
K'
C P
= KSO;
+ SO,"
t
Fe1'
+ SO,"
Fe"
+ HSO;
Fey'
= MnSOf
= FeSOf
= FeHSO,'
SO," = FeSO,'
Fe"
Al"
= BaSOP
+ 2S0,"
= AI(SO,),'
Mineral
Reaciion
Arsenoliie
As406
SO," = RaSOP
+ 3H10
Asl,
Mineral
Ruction
Gypsum
CaS0,.2H ,O = Ca1'
+ SO," + 2H,O
+ SO,%
-0.109
-4.58
Anhydriic
CaSO. = Ca"
Celestik
SrSO, = Sr"
Bariie
6.35
-9.97
Radium sulfau
RaSO, = Ra"
+ SO,"
9.40
-10.26
+ SO,"
+ SO,'. + 7H10
Melanierite
FeS0,.7H10 = Fe"
Aluniic
-1.71
-4.36
-1.037
-6.63
4.91
+ 6H10
+ 6H20
A s o 5 + 3H10
= HSO;
logK2 = -56.889
As,06
4H3As0,
2H3As03
logK
+ SO,"
BaSO, = Ba"
+ SO,"
logKl-
RaSO. = Ra"
+ SO,"
SrSO, = Sr"
logK
l0gK-
= 197.52 8669.8n
13.29
+ 3HS' + 3H*
82.89
-5.405
e 2H3As0,
-1.4
B~,(AsO,)~ 6H'
19.8858 log T
+ 0.006473T + 2307.9n +
1.875
14.33
A$S3
Zn,(As0,),*2.5H20
+ SO.*
+ 3P + 3HC
4H3As0,
Claudeiiie
-2.209
40.25
e H,AsO,
+ 61i20 rt
Orpiinent
Reaction
H'
log K
FeL
Ra"
+ SO,"
AHP
(kcalliiiol)
+ 2S0,' = Fe(SO,),'
+ HSO; = FeHSO,"
AlL + SO," = AISO.'
+ SO,* = CaSOf
Ba"
Reaciion
Reaction
Realgar
Redox Poieniial
ASS
+ 3H10
+ 6Ht
#
r~ 2H3As0,
3Ba2'
+ 2H3As0,
e H3As03 + HS'
+ ZH* + e'
30.545
AH,'
(kcallmnl\
log K