Mid phase CPK

1. A particular electroyte M
x
N
y
was dissolved is water. The degree of dissociation of salt in water was
found to be !" . The observed #olar #ass $ obtained by #easuring the %an&t 'off factor ( can be
corrected with the calculated #olar #ass using .
$a(
!. !.)$ (
M
x y + +
$b(
*!. !.)$ (+ M x y + +
$c(
!.) !.$ (
M
x y + +
$d(
*!.) !.$ (+ M x y + +
,. Two solutions- one containing !.1 M- 1!! #l Ag N.
/
and the other !., M- ,!! #l of NaCl were #ixed
together. 0f the change in the volu#e is negligible- pic1 out the correct state#ent .
$a( The f.p. of the solution is raised
$b( The f.p. of the solution is lowered
$c( No colligative property changes.
$d( 2.P. is lowered
/. KCl crystallises in the sa#e type of lattices as NaCl does. 0t
Na
K
r
r
+
+
3!.4 then the ratio of the sides of unit
cell for KCl to that for NaCl is
$a( 1.1 $b( !.5 $c( !.) $d( 1.4
). A !.!!1 #olal solution of *Pt$N'
/
(
)
Cl
)
+ in water had a free6ing point depression of !.!!7)
!
C. 0f K
f
for
water is 1.5 . the correct for#ulation of the above #olecule is
$a( *Pt$N'
/
(
)
Cl
/
+Cl $b( *Pt$N'
/
(
)
Cl
/
+Cl
,
$c( *Pt$N'
/
(
)
Cl
/
+cl
/ $8(
*Pt$N'
/
(
)
Cl
)
+
7. An ele#ent has a body centered cubic $bcc( structures with a cell edge of ,55 p#. The density of the
ele#ent is 4., g 9 c#
/
. 'ow #any ato#s are present in ,!5 g of the ele#ents.
$a( .!, x 1!
,)
ato#s $b( 1,.!: x 1!
,/
ato#s
$c( ,).1 x 1!
,/
ato#s $d( ,:.55 x 1!
,)
ato#s
. Calculate the #ole fraction of ethylene glycol $C
,
'

.
,
( in a solution containing ,!" of C
,
'

.
,
by
#ass.
$a( !.!:/ $b( !.!:/, $c( !.!5 $d( !.5
4. The correct expression relating #olarity $M( - #olality $#( - density $d( and #olar #ass $M( of solute
is
$a(
;
M
m
d MM
=

$b(
;
M
m
d MM
=
+

$c(
; d MM
m
M
+
= $d(
; d MM
m
M

=
5. The #ole fraction of <chott1y defects and =ren1el defect in a NaCl crystal at 1!!! K are respectively
* >iven energy re?uired to produce or for#s these defects are , e% and /e% respectively
$a(
) :
/., 1! and./, 1!

$b(
5
:.14 1! and/.:,) 1!


$c(
7 4
,.5 1! and)./5 1!

$d(
4 :
7.) 1! and5./ 1!


:. The free6ing point of a solution containing !., g of acetic acid is ,!.! g ben6ene is lowered by !.)7
!
C .
Calculate the degree of association of acetic acid in ben6ene. Assu#e acetic acid di#eri6es in ben6ene. K
f
for ben6ene is 7.1, K #ol
@1
1g.
$a( :1./" $b( :,." $c( :).7" $d( :4.5 "
1!. The pac1ing efficiency of the two A di#ensional s?uare unit cell shown
below is
$a( /:.,4 " $b( 5.!, " $c( 4).!7 " $d( 45.7) "

B
A-2-C-8 are centre of circle
A 2
C
8
11. A solid co#pound contains C-D and E ato#s in a above lattice with C ato#s occupying the corners D
ato#s in the body centred position and E ato#s at the centers of faces of unit cell. Fhat is the e#pirical
for#ula of the co#pound
$a(
, /
CD E
$b(
/
CDE
$c(
, , /
C D E
$d(
5
C DE
$e( CDE
1,. Bithiu# for#s body centered cubic structures . The length of the side of its unit cell is /71 p#.
Ato#ic radius of Bi will be
$a( 47 p# $b( /!! p# $c( ,)! p# $d( 17, p#
1/. Total volu#e of ato#s present in a face centered cubic unit cell of a #etal is $r is ato#ic radius (
$a(
/
,!
/
r $b(
/
,)
/
r $c(
/
1,
/
r $d(
/
1
/
r
1). An ele#ent $ at #ass 3 1!! ( having bcc structures has unit cell edge of )!! p# -the density of the
ele#ent is
$a( 1!./4 of g9 c#
/
$b( 4.,5: g9c#
/
$c( 7.155 g9c#
/
$d( ,.1)) g9c#
/
17. <tructures of a #ixed oxide in cubic closed pac1ed $ CCP( . The cubic unit cell of #ixed oxide is
co#posed of oxide ions. .ne fourth of tetrahedral voids are occupied by A
,G
and octahedral voids one
occupied by #ono valent #etal 2
G
. The for#ula of #ixed oxide is
$a( A2.
,
$b( A
,
2.
,
$c( A
,
2
/
.
)
$d( A2
,
.
,
1. Fhich of the following !.1 M a?ueous solutions will have the least free6ing point H
$a( K
,
<.
)
$b( NaCl $c( Irea $d( >lucose
14. A6eotropic #ixture of 'Cl and '
,
. have JJJJJJ " 'Cl
$a( )5 $b( ,,., $c( / $d( ,!.,
15. Fhen ,!g of naphthoic acid $ C
11
'
5
.
,
( is dissolved is 7! g of ben6ene $ K
f
3 1.4, K Kg #ol
@1
( a
free6ing point depression of , K is observed . The van&t 'off factor $i( is JJJJJ
$a( !.7 $b( 1 $c( , $d( /
1:. 0f sodiu# sulphate is considered to be co#pletely dissociated into cations and anions in a?ueous
solution- the change in free6ing point of water$KT
f
(-when !.!1 #ol of sodiu# sulphate is dissolved in 1
1g of water is $ K
f
31.5 1 1g #ol
@1
(
$a( !.!4)) K $b( !.!15 K $c( !.!/4,K $d(!.!775 K
,!. P
A
are P
2
are the %.P of pure li?uid co#ponents A and 2 respectively of an ideal binary solution - 0f
C
A
represents the #ole fraction of co#ponents $A( - the total pressure of the solution will be L
$a( P
A
GC
A
$P
2
A P
A
( $b( P
A
GC
A
$P
A
A P
2
(
$c( P
2
GC
A
$P
2
A P
A
( $d( P
2
GC
A
$P
A
A P
2
(
,1. The hard shell of an egg was dissolved in 'Cl. The egg was then placed in a concentrated solution of
NaCl . Fhat will happen
$a( The egg will shrin1 $b( The egg will swell
$c( The egg will beco#e harder $d( There will be hardly any visible change
,,. The average os#otic pressure of hu#an blood is 4.5 bar at /4
!
C. Fhat is the concentration of an
a?ueous NaCl solution that could be used in blood strea# H
$a( !.17 #ol9B $b( !./ #ol9B $c( !.)7 #ol9B $d( !. #ol9B
,/. The free6ing point of e?ui#olal a?ueous solution will be highest for
$a(
7 /
C H NH Cl
$b(
/ ,
$ ( C NO
$c(
/ /
$ ( La NO
$d(
1,
$ cos ( C H O glu e
,). Mvolution of deep red vapours when an inorganic salt is #ixed with powdered K
,
Cr
,
.
4
and heated
with conc. '
,
<.
)
confir#s the presence of a
$a( chloride $b( fluoride $c( borate $d( phosphates
,7. A solution of white crystals gives a precipitates with AgN.
/
but no precipitates with a solution of Na
,
C.
/
. The action of conc '
,
<.
)
on the crystals yields a brown gas. The crystals are of
$a( NaN.
/
$b( KCl $c( Ca$N.
/
( $d( Na2r
,. Fhich gas gives yellow precipitate with chloroplatinic acid
$a( <.
,
$b( N'
/
$c( C. $d( N.
,
,4. To detect
,
)
SO ion in presence of
,
Pb
+
ion the precipitating agent used is
$a( 2aCl
,
$b( 2a$N.
/
(
,
$c( NaCl $d( MgCl
,
,5. 2ro#ide and nitrates both give brown fu#es with conc. '
,
<.
)
. Fhich of the following reagent will
be used to distinguish between the# H
$a(
, , 4
K Cr O
$b( 2aCl
,
$c( =e<.
)
$d( K
)
$=e$CN(

,:. Fhich co#pound does not dissolve in hot dilute 'N.

/
H
$a( 'g< $b( Pb< $c( Cu< $d( Cd<
/!. 'ypo is not used in
$a( 2leaching industry $b( %olu#etric Analysis for deter#ining iodine
$c( Photography
$d( Cyanide process for recovery of Ag fro# Argentite ores.
NNNNNN
Answer Key L
1 D
1
1 B
2
1 A
2 C
1
2 D
2
2 A
3 A
1
3 D
2
3 D
4 B
1
4 C
2
4 A
5 C
1
5 D
2
5 D
6 C
1
6 A
2
6 B
7 A
1
7 D
2
7 B
8 B
1
8 A
2
8 C
9 C
1
9 D
2
9 A
1
0 D
2
0 D
3
0 D
Concept Code L
1
C12060
4
1
1
C12030
5
2
1
C12060
5
2
C12060
9
1
2
C12030
3
2
2
C12060
5
3
C12030
4
1
3
C12030
3
2
3
C12060
7
4
C12060
7
1
4
C12030
3
2
4
C12020
7
5
C12030
2
1
5
C12030
3
2
5
C12020
7
6
C12060
1
1
6
C12060
1
2
6
C12020
7
7
C12060
3
1
7
C12060
3
2
7
C12020
5
8
C12030
5
1
8
C12060
9
2
8
C12020
3
9
C12060
7
1
9
C12060
2
2
9
C12020
9
1
0
C12030
3
2
0
C12060
2
3
0
C12020
9
OP0 1@1! 11@1!! 1!1@,!! ,!1@7!! 7!1@1!!! 1!!1@,!!! ,!!1@Bast Oan1
Midphase Above 57 5)@45 44@47 4)@7 )@77 7)@7! 2elow ):