LEMBAR PERHITUNGAN

A. Kebutuhan Reagen
Basis : 350 ml
Densitas Pati
Pati =

=



= 1 gr/ml
Densitas HCl
Berat picno kosong (m
1
) : 23,256 gr
Berat picno + HCl (m
2
) : 51,254 gr
HCl =

=



= 1,12 gr/ml
Densitas H
2
SO
4
Berat picno kosong (m
1
) : 23,256 gr
Berat picno + HCl (m
2
) : 68,302 gr
HCl =

=



= 1,8 gr/ml
Variabel I ( HCl 0,15 N )
Kebutuhan HCl 0,15 N dalam 350 ml
V HCl =



=



= 6,9 ml

V basis = V HCl + V pati + V aquadest
350 ml = 6,9 ml + V pati + V aquadest
350 6,9 = V pati + V aquadest
343,1 ml = V pati + V aquadest
V pati =

x 343,1 ml
= 24,5 ml
V air =

x 343,1 ml
= 318,6 ml
W pati = pati x V pati
= 1 gr/ml x 24,5 ml
= 24,5 gr
Variabel II ( H
2
SO
4
0,15 N )
Kebutuhan H
2
SO
4
0,15 N dalam 350 ml
V H
2
SO
4
=



=



= 1,5 ml

V basis = V H
2
SO
4
+ V pati + V aquadest
350 ml = 1,5 ml + V pati + V aquadest
350 1,5 = V pati + V aquadest
348,5 ml = V pati + V aquadest
V pati =

x 348,5 ml
= 24,9 ml
V air =

x 348,5 ml
= 323,6 ml
W pati = pati x V pati
= 1 gr/ml x 24,9 ml
= 24,9 gr
B. Kadar Pati Awal
Standarisasi Larutan Fehling
F = 18,6 ml
Kadar Pati Awal Variabel I
M HCl = 14,5 ml
Xpo =
()

=
()

= 0,029
Kadar Pati Awal Variabel II
M H2SO4 = 16,8 ml
Xpo =
()

=
()

= 0,024

C. Perhitungan Pati Terhidrolisa
Xp =
()

X
A
=

D. Penentuan Harga Konstanta Laju Reaksi
-rA = k CA

dimana CA = CAO (1 xA), sehingga diperoleh :
-In (1xA) = kt + c
y = m.x + c
Variabel I
F = 18,6 ml
N glukosa = 0,002 gr/ml
W = 24,5 gr
Xpo = 0,029
t (menit) (x) M (ml) Xp X
A
-In (1X
A
) (y) x.y x
2
0 11,5 0,0104 0,3597 0,4459 0 0
5 10,8 0,0115 0,3952 0,5029 2,5145 25
10 9,3 0,0137 0,4712 0,6372 6,372 100
15 8,4 0,0150 0,5168 0,7274 10,911 225
20 7,5 0,0163 0,5624 0,8265 16,53 400

y =mx +c, dimana m =k (konstanta kecepatan reaksi)
m =

()

=
()()()()
()()()

= 0,0197
y = 0,0197 x + c
k = 0,0197

Variabel II
F = 18,6 ml
N glukosa = 0,002
W = 24,9 gr
Xpo = 0,024
t (menit) (x) M (ml) Xp X
A
-In (1X
A
) (y) x.y x
2
0 14,1 0,0065 0,2711 0,3162 0 0
5 13,5 0,0074 0,3072 0,3670 1,834 25
10 12,2 0,0093 0,3855 0,4870 4,870 100
15 11,6 0,0101 0,4217 0,5476 8,214 225
20 9,4 0,0133 0,5542 0,8079 16,158 400


m =

()

=
()()()()
()()()

= 0,013
y = 0,013x + c
k = 0,013/menit