P3

LEMBAR PERHITUNGAN REAGEN

Menghitung Densitas Reagen
Asam Asetat
m picno kosong

= 22,257 gr

V picno

= 24,136 ml

m picno + Asam Asetat

= 47,648 gr

asam asetat

= 1,05199
Etanol
m picno kosong

= 22,257 gr

V picno

= 24,136 ml

m picno + Etanol

= 42,710 gr

Etanol

=
= 0,847

H2SO4
m picno kosong

= 22,257 gr

V picno

= 24,136 ml

m picno + H2SO4
H2SO4

= 66,329 gr
=
= 1,826

Menghitung Kebutuhan NaOH

NaOH 0,35 N
Basis

= 500 ml

N NaOH

x eq x kadar

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m NaOH

m NaOH

= 7,14 gram

Menghitung kebutuhan katalis H2SO4 0,25 N

N H2SO4

x ek x kadar

= 3, 19 gram

volume

volume

volume

= 1,75 ml

Menghitung kebutuhan Etanol dan Asam Asetat (Variabel 1)

V etanol + V asam asetat

= 250 ml V HCl
= 250 ml - 1,75 ml
= 248,25 ml

Mol asam asetat : mol etanol = 1 : 2,3

2,3

2,3

(0,0395 ml) Vasetat

= (0,01747 ml) Vetanol

Vasetat

= 0,44228 Vetanol

Vasetat + Vetanol

= 248,25 ml

0,44228 Vetanol + Vetanol

= 248,25ml

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1,44228 Vetanol

= 248,25 ml

Vetanol

= 172,1 ml
= 248,25 ml 172,1 ml

Vasetat
Vasetat

= 76,15 ml

Menghitung kebutuhan Etanol dan Asam Asetat (Variabel 2)

Mol asam asetat : mol etanol = 1 : 2,8
2,8

2,8

(0,04807 ml) Vasetat

= (0,01747 ml) Vetanol

Vasetat

= 0,36343 Vetanol

Vasetat + Vetanol

= 248,25 ml

0,36343 Vetanol + Vetanol

= 248,25ml

1,36343 Vetanol

= 248,25 ml

Vetanol
Vasetat
Vasetat

= 182,1 ml
= 248,25 ml 182,1 ml
= 66,15 ml

P3

LEMBAR PERHITUNGAN
Perhitungan Konversi Variabel 1
CH3COOH + C2H5OH CH3COOC2H5 + H2O
A
Gram asam asetat

= v kadar
= 1,05199

76,15 ml 0.98

= 78,447 gram
CAO

=
= 5,2254 mol/L
Gram etanol

= v kadar
= 0,847

172,1 ml 0.96

= 139,938 gram
CBO

=
=

= 12,15 mol/L

CA

=
=
= 0.07V 0,25

Xa

= 1-

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t(menit)

Volume NaOH

Ca= 0.07V-

Xa

(ml)

0,25

67

4,44

0,15

11

47,1

3,047

0,417

22

46,6

3,012

0,423

33

38,3

2,431

0,535

44

35,1

2,207

0,578

CH3COOH + C2H5OH CH3COOC2H5 + H2O

A

Stoikiometri
CA

= CAO (1-XA)
= CAO CAO.XA
= 5,2254 (1-XA)

CB

= CBO CAO.XA
= 12,15 5,2254 XA

CC

= CAO.XA
= 5,2254 XA

CD

= CAO.XA
= 5,2254 XA

= 2,325

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=
= k1(

= k1 (

= k1 (

= k1 (

= k1 .

= k1

= k1 .

.
(

)
/

/
/

Pada saat kesetimbangan

K=

Konstanta Kesetimbangan
K=

=
= k1

= k1

= 0,453
(

/
/

Mencari nilai
=
=
=

+
*

P3

Rumus ABC
= (XA + 3,35)(XA - 0,579)
-0,16

=
+

-0,579A + 3,35B

=1

=0

-0,579A

3,35B

=1

A = -0,254
B = 0,254
Sehingga persamaan menjadi
-0,16*
-0,16*

+ = k1 . t

-+

k1 . t

k1 . t
0,04 [
0,04[
0,04 [ ln (

]
-

] = k1 . t
) = k1 . t

k1. t

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0,04 [ ln (

) = k1 . t

0,04ln *
t(x)

+ = k1 . t y = mx
Xa

X2

Xy

0,15

0,0137

11

0,417

0,055

0,605

121

22

0,423

0,057

1,254

484

33

0,535

0,11

3,63

1089

44

0,578

0,26

11,44

1936

K=

k2 =

= 4,3.10-3 mol/menit
=

= 9,5.10-3mol/menit

Perhitungan Konversi Variabel 2

CH3COOH + C2H5OH CH3COOC2H5 + H2O
A
Gram asam asetat

= v kadar
= 1,05199

66,15 ml 0.98

= 68,197 gram

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CAO

=
= 4,543 mol/L
Gram etanol

= v kadar
= 0,847

182,1 ml 0.96

= 148,07 gram
CBO

=
=

= 12,856 mol/L

CA

=
=
= 0.07V 0,25

Xa

= 1-

t(menit)

Volume NaOH

Ca= 0.07V-0,25

Xa

(ml)

56,2

3,684

0,189

11

45,7

2,949

0,35

22

40,9

2,55

0,44

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33

36,0

2,27

0,5

44

30,8

1,906

0,580

CH3COOH + C2H5OH CH3COOC2H5 + H2O

A

Stoikiometri
CA

= CAO (1-XA)
= CAO CAO.XA
= 4,543 (1-XA)
= CBO CAO.XA

CB

= 12,856 4,543 XA
CC

= CAO.XA
= 4,543.XA

CD

= CAO.XA
= 4,543.XA

= 2,83

= k1 (

= k1 (

= k1 (

= k1 (

= k1 .

)
/

P3

= k1

= k1 .

/
/

Pada saat kesetimbangan

K=

Konstanta Kesetimbangan
K=

=
= k1

= k1

= 0,356
(

/
/

Mencari nilai
*

+
*

Rumus ABC
= (XA + 2,7)(XA 0,58)
-0,121

=
=1

P3

=0

-0,58A

2,7B

=1

A = -0,305
B = 0,305
Sehingga persamaan menjadi
-0,121*

+ = k1 . t

-0,121*

-+

k1 . t

k1 . t
0,037 [

0,037[

] = k1 . t

0,037 [ ln (

) = k1 . t

0,037 [ ln (

) = k1 . t

0,037ln *
t(x)

k1. t

+ = k1 . t y = mx
Xa

X2

Xy

0,189

0,017

11

0,35

0,039

0,43

121

22

0,44

0,058

1,276

484

33

0,50

0,08

2,64

1089

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44

0,58

K=

k2 =

= 2,88.10-4 mol/menit
=

= 8,1.10-4 mol/menit

1936