LAMPIRAN

A. PERHITUNGAN KURVA STANDAR ETANOL-AIR (%MOL)

1. DENSITAS ETANOL-AIR 20%

Massa pikno kosong = 15,8235 g

Massa pikno + isi = 25,0332 g

Volume pikno = 10 mL

ρ = (Massa pikno + isi) - (Massa pikno kosong)

Volume Pikno

= (25,0332 g – 15,8235 g)

10 mL

= 0,94757 g/mL

2. % VOLUME MENJADI % MOL

Basis : 50 mL larutan etanol 20%

Volume Etanol = 10 mL

Volume air = 40 mL

Massa Larutan = volume larutan x densitas larutan

= 50 mL x 0,94757 g/mL

= 47,379 g

Massa air = volume air x densitas air(28°C)

= 40 mL x 0,996233 g/mL

= 39,849 g

Massa Etanol = massa larutan – massa air

= 47,379 g – 39,849 g
 = 7,529 g

𝑀𝑎𝑠𝑎 𝐴𝑖𝑟
Mol Air = 𝐵𝑚 𝐴𝑖𝑟

39,849 𝑔
= 18 𝑔/𝑔𝑚𝑜𝑙

= 2, 214 gmol

𝑀𝑜𝑙 𝐸𝑡𝑎𝑛𝑜𝑙
Mol Etanol = 𝐵𝑚 𝐸𝑡𝑎𝑛𝑜𝑙

7,529 𝑔
= 46,07𝑔/𝑔𝑚𝑜𝑙

= 0,163 gmol

𝑀𝑜𝑙 𝐸𝑡𝑎𝑛𝑜𝑙
% Mol Etanol = 𝑀𝑜𝑙 𝑎𝑖𝑟+𝑀𝑜𝑙 𝑒𝑡𝑎𝑛𝑜𝑙 𝑥 100%

0,163 𝑔𝑚𝑜𝑙
=(2,214+0,163)𝑔 𝑥 100%

= 6,875 %

B. PERHITUNGAN KONSENTRASI UMPAN, DESTILAT DAN BOTTOM (%

MOL)

1. UMPAN/FEED

Regresi Kurva standar

y = -436,67x + 424,48

y = % mol etanol-air

x = densitas

densitas umpan/feed = 0,90043 g/mL

y = -467,41 x + 424,48

y= -467,41(0,90043)+ 424,48

y= 31,289%
 2. DESTILAT

Regresi Kurva standar

y = -436,67x + 424,48

y = % mol etanol-air
x = densitas
densitas destilat = 0,82268 g/mL

y = -436,67x + 424,48

y = -436,67(0,82268) + 424,48

y = 65,240%

3. BOTTOM

Regresi Kurva standar

y = -467,41x + 469,02

y = % mol etanol-air
x = densitas
densitas bottom = 0,95867 g/mL

y = -436,67x + 424,48

y = -436,67 (0,95867) + 424,48

y = 5,858%

C. NERACA MASSA TOTAL

1. MASSA UMPAN/FEED

Feed = densitas x volume

= 0,90043 g/mL x 3000 mL

= 2701,29 g
 2. MASSA DESTILAT

Destilat = densitas x volume

= 0,82268 g/mL x 8,2 mL

= 6,746 g

3. BOTTOM

Bottom = densitas x volume

= 0,9587 g/mL x 1900 mL

= 1821,473 g

4. NERACA MASSA TOTAL

F =D+B

2701,29 g = 6,746 g + 1821,473 g

2701,29 g ≠ 1828,219 g

D. NERACA MASSA KOMPONEN ETANOL TOTAL

1. FRAKSI MASSA ETANOL PADA FEED

𝑀𝑎𝑠𝑠𝑎 𝑒𝑡𝑎𝑛𝑜𝑙
𝑋𝑑 =
(𝑚𝑎𝑠𝑠𝑎 𝑒𝑡𝑎𝑛𝑜𝑙) + (𝑚𝑎𝑠𝑠𝑎 𝑎𝑖𝑟)
1206,941 𝑔
=
(1206,941 𝑔) + (1494,350 𝑔)

= 0,45

2. FRAKSI MASSA ETANOL PADA DESTILAT

𝑀𝑎𝑠𝑠𝑎 𝑒𝑡𝑎𝑛𝑜𝑙
𝑋𝑑 =
(𝑚𝑎𝑠𝑠𝑎 𝑒𝑡𝑎𝑛𝑜𝑙) + (𝑚𝑎𝑠𝑠𝑎 𝑎𝑖𝑟)
5,476 𝑔
=
(5,476 𝑔) + (1,270)

= 0,81
 3. FRAKSI MASSA ETANOL PADA BOTTOM
𝑀𝑎𝑠𝑠𝑎 𝑒𝑡𝑎𝑛𝑜𝑙
𝑋𝑏 =
(𝑚𝑎𝑠𝑠𝑎 𝑒𝑡𝑎𝑛𝑜𝑙) + (𝑚𝑎𝑠𝑠𝑎 𝑎𝑖𝑟)
283,538 𝑔
=
(283,538 𝑔) + (1537,935 𝑔)

= 0.16

4. NERACA MASSA TOTAL KOMPONEN ETANOL

F.xf = D.xd + B.xb

1206,941 x 0,45 = (6,746 x 0,81) + (283,538 x 0,16)

539,2629 = 4,444585011 + 44,1367899

539,2629 ≠ 48,58137491

E. NERACA PANAS
Untuk t = 20 menit
Massa etanol = volume destilat (mL) x Densitas(g/mL)

= 3,4 mL x 0,7820 g/mL

= 2,659 g
𝜆 = 624.564 kal/g
Tin = 21,500 oC
Tout = 27 oC
𝑇𝑜𝑢𝑡
∫ 𝑐𝑝 𝑑𝑇
𝑇𝑖𝑛

27𝑜 𝐶
=∫21,5𝑜 𝐶 33,46 + 0,688. 10−2 𝑇 + 0,7604. 10−5 𝑇 2 − 3,59. 10−9 𝑇 3 𝑑𝑇

=184,135 kal/gmol
 7,834 𝑔
Laju Alir Etanol = 15 𝑚𝑒𝑛𝑖𝑡

= 0,5223 g/menit

𝑇𝑜𝑢𝑡
Massa etanol x λ = mol air ∫𝑇𝑖𝑛 𝑐𝑝 𝑑𝑇

7,834 g x 624,564 kal/g = mol air x 184.135 kal/gmol

kal
0,5223 g/menit x 624,564 g
𝑚𝑜𝑙 𝑎𝑖𝑟 =
kal
184,135 gmol

= 1,771 gmol/menit

massa air = mol air x BM

= 1,771 gmol/menit x 18 g/gmol

= 31,888 g/menit